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062565/02DIN Safety Data SheetDate of issue: November 16. 1989 Page 01 of 03

Company Bayer AG. Sektor Landw1rtschaftPF-P/Stab Umweltschutz und S1cherheit. Geb. M 164047 Dormagen 1

Commercial product nameFol;cur EC 250 Prod.-Nr. 003918

1.1 Chemical characterisation: Emulsifiable concentrate contains250 g/l tebuconazo1e (proposed). dimethyl formam;de

1.2 Form: liquid1.3 Colour: clear. yellow1.4 Odour: aro.atic

tested in accordance with

at approx. 155 .C (dimethyl formam;de)approx. 1.06 g/cm3 at 20 .C5 mbar at 20 .C

2. Physica1 and safety data2.1 Change in physical state:

Initial boiling point:2.2 Density:2.3 Vapour pressure:2.4 Viscosity:2.5 Solubility in water: emulsifiable

Water-miscibility to VbF § 3(1) no2.6 pH value:2.7 Flash point: 62.C2.8 Ignition temperature: > 440 .C2.9 Explosive limits:2.10 Thermal deco.position:2.11 Hazardous decomposition products:

develop.

DIN 51758

DIN 51794

In case of fire nitrogen oxides may

2.12 Hazardous reactions:2.13 Further information:

3. TransportGGVSee/IMDG Code:. UN No.: ND MFAG: EmS:GGVE/GGVS: Class 3 No. 32C RID/ADR: Class 3 No. 32CADNR: Class 3 No.4 Cat 3 ICAD/IATA-DGR: NOT RESTR.Other infor.ation: CA.36~ DIMETHYLFORMAMIDFlammable. flash point +62 .C. Slightly smelling. Keep dry. Avoid heatabove +40 .C. Irritating to the eyes. Keep separated from foodstuffs.

4. Regu1ationsLabelling according to appendix I No. 2.3 (Pesticides) of the Federa1German Regulation on Dangerous Substances (GefStoffV) dated August 26. 1986and the corresponding EEC directives:Sy.bo1: Xi. hazard description: irritantContains 250 g/1 tebuconazole (proposed). dimethyl formamide(EEC H2. 616-001-00-X).R 41: Risk of serious damage to eyes.S 2: Keep out of reach of children.S 13: Keep away fro. food. drink and animal feeding stuffs.S 20/21: When using do not eat. drink or smoke.S 26: In case of contact with eyes. rinse immediatelY with plenty of

water and seek medical advice.S 44: If you feel unwell. seek medical advice (show the label where

possible).(to bQ continued)

DIN 52900 (Ob)

Agrochemicals Sector

DIN Safety Data Sheet 062565/02Date of issue: November 16. 1989 Page 02 of 03

Commercia1 product nameFol1cur EC 250 Prod.-Nr. 0O3~'8

4. Regu1at1ons (Continuation)VbF (Federa1 German Regu1ation on Flammab1e liquids) Class A III

380:BAYER-Storage class

5. Protective measures. storage and hand1ing5.1 Technical protective measures: Keep at te.peratures not exceeding 40 .C.

Keep away from food. drink and animal feeding stuffs. Keep dry.5.2 Personal protective equipment:

Respiratory protection: Keep gas mask with filter A2 - P3 ready.

Eye protection: gogglesHand protection: rubber glovesOther protective equipment: Wear protective clothing.

\.3 Industrial hygiene: When using do not eat. drink or smoke. Avoid contactwith eyes and skin. 00 not breathe vapour.Cleaning of working chlothes/protective equipment: water an.d soap

5.4 Protection against fire-and explosion: Keep away from sources of ignition -

No slloking.5.5 Disposal: May be transported to controlled incinerator if local official

regulations are observed. Where large quantities are concerned. consult thesupplier.

8. Measure. in ca.. o~ accidents and fire.6.1 After spillage/leakage/gas leakage: Do not empty into drains or waters.

Take up with absorbent material for example sawdust. peat. binding agentfor che.icals. Fill Materials taken up into closable container. To cleanthe f100r and a1l objects contaminated by this 8aterial. use water anddetergents.

6.2 Extinguishing media: sprayed water jet. foam. extinguishing powder. CD26.3 First aid: Take off immediately a11 contaminated clothing. After contact

with skin. wash i.mediately with plenty of water and soap. In case of eye~ contact rinse with p1enty of water. In case of swa1lowing. seek medical

advice i..ediate1y. Show the package and labe1. and if possible theinstructions for use.

6.4 Further information: Fire-men have to wear se1f-conta1ned breathing appara-tus.

7. Information on toxicityLDso oral. rat: > 4000 mg/kgLDso dermal. rat: > 4000 mg/kg

Irritation of the skin/rabbit: non-irritantIrritant to the mucous membranes/rabbit: moderately irritant - severelyirritant

Symptomes of poisoning: unknown.Information for the physician: Basic aid. decontamination. symptomatictreatment.Antidote: unknown.

DIN 52900(gb)

Agrochemicals Sector

062565/02DIN Safety Data SheetDate of issue: November 16. 1989 Page 03 of 03

Commercia1 product nameFolicur EC 250 Prod.-Nr. 003918

8. Information on ec010g;ca1 effectsFish toxicity: (active ingredient)LCso: 8,7 mg/l (96 h); Golden orfe (Leuciscus idus)LCso: 6,4 mg/l (96 h); rainbow trout (Salmo gairdneri)

Further ;nfor.at;onApplication: fungicide

9.

Adresses: Supplier:Forwarding agent:Importer:

~

In case of general inquiries: Bayer AG: PF-P / Stab0 4047 Dormagen: Tel. 02106/515421

In case of poisoning, fireor damage:

Bayer AG: FeuerwehrD-4047 Dormagen: Tel. 02106/514233

The data given here is based on current knowledge and experience. The purposeof this Safety Data Sheet is to describe the products in terms of their safetyrequirements. The data does not signify any warranty with regard to theproducts' properties.

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