letter regarding development of treatment …daacription, and contaainant charactariaation of tha...

36
) .... ... ·-- -- ""'\ leAIICO HAVICES INCORPORATED 21tc;onrgrnfiltrMt._,floor,loMOn.MA02110.2410, tl1n45H201 Juna ll, 1990 ARCS I 90•200 Raaponaa Required )(r, David Lederer R-ial PrOject 1W1&9or u.s . Environaantal Protection Aqancy JPit Federal 11U1ldin9 (IIRI - CAII2) aoaton, xaaaaohuaatta 02203 lubje<:tl .UCI I - EPA COJITRACT 110 . 61•119·0034 IIORit loSIIGIICEIIT 110 . 06•lLl5 IIYAIIIA II RI/H 'l'UATUILITY STUDY ZVALUATIOII oear oava1 &ncloaecl are thr.. CO'Pi•• of tba lfyanaa Treatability study &valuation report for yO\lr review. Tha report ia a auaaary and ... uation of beneh-a:ala taatint perfonecl by E. c, Jordan be incorporatecl into dll raaaibility St\ldy (FS) report, aa appropriate. lec:tiona 1.0 and a.o .,f the report include a brief hbtory, daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and. in ferred areal liaita of qrounclvatar contaaination in tha )Mdrock an4 overburden. section 3 . o provide• a au-ary of preliainary reaadial re•ponae objectivea, and section 4.0 providaa a liat of technoloqiaa potentially capable of aaatinq thoee objectiv••· Tha raaulta of the Ph••• I and II treatability teat pr09ra• conducted by Jordan are evaluated in &action 5.0 of the report . A diacuaaion of tha tachnoloti•• evaluated and tha teat procedure• ia providei. Influent (rav vatar) and affluent (treated water) data ara coaparad to •••••• tha relative of tha tachnolot1•• in traatin9 tha contuinatecl vater pr ••nt at tha aite . concluaiona raqar4in9 co-.plated taatint and tha naad to teat additional tachnoloti•• are diacuaaed. in sactlon 1.0. fie raaulta of tha treatability atudiaa conducted by Jordan in41cata that convent i onal traataant tach.nolot 1•• ara c apable of or a

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Page 1: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

) middot---shy

leAIICO HAVICES INCORPORATED 21tconrgrnfiltrMt_floorloMOnMA021102410 tl1n45H201

Juna ll 1990 ARCS I 90bull200 Raaponaa Required

)(r David Lederer R-ial PrOject 1W1amp9or us Environaantal Protection AqancyJPit Federal 11U1ldin9 (IIRI - CAII2) aoaton xaaaaohuaatta 02203

lubjelttl UCI I - EPA COJITRACT 110 61bull119middot0034 IIORit loSIIGIICEIIT 110 06bulllLl5 IIYAIIIA II RIHlUATUILITY STUDY ZVALUATIOII

oear oava1 ampncloaecl are thr COPibullbull of tba lfyanaa Treatability study ampvaluation report for yOlr review Tha report ia a auaaary and a~_ uation of beneh-aala taatint perfonecl by E c Jordan

~r--=Itl~~~~ro~lo~ I~~m~ya~~u~~ ~i~1mon be incorporatecl into dll raaaibility Stldy (FS) report aa

appropriate lectiona 10 and ao f the report include a brief hbtorydaacription and contaainant charactariaation of tha Nyanampa alta Thb includaa a coapilation of Phaaa I qroun4vatar aabullplin9 data and inferred areal liaita of qrounclvatar contaaination in tha )Mdrock an4 overburden section 3 o providebull a au-ary of preliainary reaadial rebullponae objectivea and section 4 0 providaa a liat of technoloqiaa potentially capable of aaatinq

thoee objectivbullbullmiddot Tha raaulta of the Phbullbullbull I and II treatability teat pr09rabullconducted by Jordan are evaluated in ampaction 50 of the report A diacuaaion of tha tachnolotibullbull evaluated and tha teat procedurebull ia providei Influent (rav vatar) and affluent (treated water) conta~inant data ara coaparad to bullbullbullbullbullbull tha relative affactivena~tbull of tha tachnolot1bullbull in traatin9 tha contuinatecl vater pr bullbullbullnt at tha aite concluaiona raqar4in9 co-plated taatint and tha naad to teat additional tachnolotibullbull are diacuaaed in sactlon 1 0

fie raaulta of tha treatability atudiaa conducted by Jordan in41cata that convent i onal traataant tachnolot1bullbull ara c apabl e o f

~=~~M~middot~~~~~n~~i~ir~r~~~rth~v~pent or a

)

Kr oavid IAdarar June 13 ltto Paa TWo

bulltenaric traataellt VampiA or aevaral aora apaoific traataant traina that voul4 be oapUala of reducint contaainant lavale to tarvat alMnUP lev~

lavaral tacbnoloviu tlgtampt ware idantifia4 bullbull bail potentiallyapplicable to tba M)ansa alta ware not taate4r bovevar uny of thaaa are vall ~raven tecbnolotiaa and taatinq voulcl be bullora

=~tmiddotr~ur ~rc1~r rmiddot~iu~n potantifly autabla for tha lfyampnlamp alta ware identified Thaaa vill be looked at in turtber detail durlnt tha next acraanin atata of the Pl Tba UCI teaamp voul4 lUta to further dbcuaa tha approach tha PI will taU re~jardint innovative tachnolotibullbull for trutaantof~middot

It VG114 appear pzUIIelrt tbat tAe rantbull of altamativaa ahould focnae on atrat1 tor ~al of troundvatar rather than on a larta nuber of treatMDta for tha extracted vatar Tba PI tau viahea to 4111CN8amp vith you tbeH aapecta of tha faaaibility atu4y follovint arMnin9 of technolotY procaaa optiona

cthimtbull=r~Yu~tP~middotv~~~~that potential - for tlgtamp llyampDampa alta

If you have any tpUtiDM or caaentbull plbullbull call M at (617) 451-1201

CCI Jta llay II aana~tian D Grotlintbull r Jt Gleabull OI D Itaad

middot luena

PILl I tJtCI PIC 11 IIYAIIIt 104

EPA WORK ASSIONMENf NUMBERo Q61Ll5 EPA COtmlACT NUMBER 61-WWJllt poundBASCO SERVICpound5 INCORpORATED

middotATAium mJDY EVALUATION NYANZA CHEMICAL sm

OPERAILI UNIT 11 ASHLAND MASSACHUSETTS

JUNE 1990

~~gt)_ FS~ S I ACOMbullItaacablt

)

NYANZA OIEMICAI SITE

ntEATABILITY SIJDY EVALUAnON

oPEAABLE UNIT II

ASHLAND MASSAOIUSETIS

JUNE 1990

) WORK ~tGNMENT NO 06-ILlS

NOnCE

------ tM UtS $UWI EPiroAIIWAlll PtoMCltlgta ~ (USIPA) -AilCS I ea- No61--IO--IK (EboOCO~

l TABU 01 co1lt111lt1S

UK

~1ST Of T-BUS bullbullbullbullbullbullbullbullbull bull bull bull bull bull bull bull bull bull bull bull bull bull II~OF FIOUIIES bull bull bull II

nmgtoDucnoN 1 10

OYEJIVIEW OF ENVIRONMENTAL CONTAMINATION bullbullbullbull 10

PREl-IMINARY 11poundMEDW RESPDNSE oaJECI1VES bullbullbullbull bull 30

IOpoundNTIFICATI0N AND SCREENINO OF TECgtINOLOOIES bull 40

41 Tetb~M)k)D 14catUkatioa 9 41Teclo__ 10

PIIASE lAND ll TREATAIIIUTY TEST PROORAM bull bull bull bull bull bull 10

50 Sl TecbaoOiiC EIIIUIIWIL 17 51 Tat ObjeetW bull 1 B Exptri~MDampII oip aDd Proccd1tiCI bull bull 11 54 Tbullt EvaltioM latcrprclltkMI 26

CONCLUSIONS 30 60

urf OF TAIIIJS

Orovodwater CoalaluDt frtllIUitf u4 eocntntiOn Rill 1

1-1 - SaeampDiq SUliWY for orouacr 1dMidialioa Tedutotoael ll _o__ Tpo ll

4-l PrectpicaliOa TreauiiY Daampa bullbull bullbullbull bullbullbullbullbullbull bullbullbullbull bullbull bull 19

H 20 Pbllamp II IUW Water Qarttteriltkl

S-l ll ldlliyen1 EfiiCtiveMI or PUle 11 TN~reDl T~

S-l 12 loa~ middot Tllbiliqt DILl

s ll Dithled ~- middot TbullUibilitJ Data bullbullbull

S-S cano~ - TrallbiliYOra bullbullbull 24

S-6

S-7 __ T -[)ola

= urr OF PIOUUS

l middotl Sloa_-~ middotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotbullmiddotmiddotmiddotmiddotmiddotmiddotmiddotbull middot middotmiddotmiddotmiddot--middot l l-1 - _ Map

l-l TCIIIo~ IOiiWIIII middot loueCoiiiOyen -- S

l_ TCIIIo o- - Wclll bull loUO CoiiiOII bullbullbullbullbullbull 6

middotI

) 10 JNIRODUCDON

Tbe Nyanza II bull Orouodwlttr Remedial ht~tlpdolllftuibiUty Study (RllfS) il the MCOnd of thtec operable uaiampS ldcaliaecl for he Nyaua site ne objeeliWI of tbe Nyua URlFS are to evahate the uturt aid diltrlb~ampdol ot poudniM coawaludol -- tM lilt ueodaled wilb tiUI coa~CiliDilkiD and coa~plete a CellibUcy atu4y or applicable remedJal allcmattvamp Tbe ftnt phaM ot remedial iallltiptloll lbr lM site bu beeA COfllpllted AddhioBII puadwatet IQW~~tlptiou (Ptwc It) aa4 uaociattd rillr aaMtill art cumatty lD _ IM remedial la_tlpUoa aaMllel were coDdICted 11adU he REM Ul coaUK The RIFS repoN will bt completed uDikr the ARCS coatrtCL

AJ put ol tile uuoilloa- 1M REM lll 10 ARCS__ tile ARCS-~~ otudy wllll EC Jordla eompuy penoDKI to obcala uatabWty ~ttdJ daca coDducted SU the REM 111 coatrKl iD support ot RllfS actMU 1il IICUkll meiiDCifUd~ampa il aa Cll~amp~Uol ot MK stiMS u weU 11 u cvalaltkla of DIW UOloi ideatiBell lfacl coaWO ot lM ueatabWIJ lilts

Sectioa 20 of Uil bullmoranclulll proW a summl) dilculltoa of tM coodltton of tbe site inclldiq kgtCltioa lnfcned CllampIU of cotnamludoa aacl type of coetaalaldoa Slttioo l O deCIMI preliminary rcbullbullllal fCI900M objective~ T~ powatiaUy capable ot aidptlq COiltamlulioa 11 the site aad rnectillamp tM Sill re~ponat objecti- are MatiW il SICtiol 40 A brief deleriptioll of cadl ~ udlM statbull atw ~iS abO provided iD SKtioa 40 SectiOa SO dlsnlla and evahata tbe EC Jordu ampNaampability 1llt prosram wllkll aaaiMd till appUcabWIY of cartlia ICCbDOIOI tO 1M tfyuD sUamp lltd_ hi Sealoa 50 is a dilaalampioa of tilt ~ cxpatJMtllll dalip aDd procedura u4 dati evaamp-lioL cod~ troe tcdlDOloampY tbulltiaamp _ idaaUIIkatioa of 1lttMr ampe~lilll opttolll Is

-iaSoctloo60

10 QYiRytEW Of J5lMRONMfNIAL CONTAMINADQN

The Nyaua cMekal site is loclted off of Mtpako RCI u4 ~CM~tll ot M SwlbUY NN aM _ Streit ta AMIUd MIIUdiiiMta 11 _ oa Rprc 1middot1 A ore dtlliS view or tbe site is shawl Oil

r Aaure 1middot1 Tbe she wu thl locatiobull of dlalkal _~De~ lldlltilllor 61 )1111 ud il cunudy occvp5ed bJ

- - - DouioiiM 6l portoO - ol- -- shydilpoMd ot oa the Pte indltdina peniltty-trutl4 Pf011 cM~t~kalll_p frCHft tM wu~ewata trtlllftUI ~ IOU4 fKO ta dnabull (tor cMiakal predpltata ucl filter caka) ancl orf-speciftcadol pro4uas PTOCI cMaicU tUt coUd at be rtCI(Ied or rcIMII lnchadina pMDOlDiuob~UeM u4 IDifWrie sutfatc wac aro dilpOIIIl ol oa-litt 1c ampDOlt recent dye rnanldacturct

t1ya011 lac -plod tile sloe- 1965 10 1971 1MJ- shyA--oopdlai-----II 1M slto _be fouo41a llle lDIIampJ4~~=~-sm=~~=nrcoataaiaalt _ dlleded Ia ~~~~ tipdoM at NJUII ar _ ta hbM l-1 tporwat

_ coa~lll-~ Sourlta of Ofpaic udillorpak ooa~IbullUoa Mea 6ecected wltllia tM fonlU propttiJ ttovldampria COIItllliaalioa ol pouldwaltt Ul ocnrr4 Ia boO tbe bedrOCk ~ F1pNI lJ ulll 1 allOW lM attal ateat ol coatalliaatiol fix tc il sol aM Wrodt wdll ~middot heM limits ol CIOIIwaitioa OPical JAUIIJ tepNMAampalM of CMMI CIOIIlliniOCI II well

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UOioampJ-1 CoDtamiDIUid pouoctwawr bullPI to t11 alJrttial to a moor exteftt ta bull oonbettY dircdoa 10WUi M ~Ill) Jliyenel Ml Dow i1 priiMriiY lD U tut) 4irecdOft towani tMIUia put oftMTOWI of~ IM 4alamp aiiO IU mit COIIuaaat 411Uibvllol lD JfOUDdwaU ru be prtMDt II coDCUtnted iDClM4dl plllll llptrimposed 01 I __pl

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Maxlmlm MCL01 foloof Mlnlmtntt

MCL1 ~ ~llllllol~llllllolQwlilll 39200

IIJQIIIIill 33050 29 (MW-109)0 4 (lloO 1400- 50 lOOO ll

Blri 01000

6 (MW-114 A 302) 33 -Beryllhua 14 (10114)l 302000 II (MW-IOl)

10 2230~middotmiddot

50 100 26 (Ul) 26lColdbullbull ll3~middotmiddot lJOO 90400cdlolt

1000 ~ l20300 l 2(MW-1048) 29 (Oil)roo 73600ldL )(1100 ~- 31050 02 (MW-201)32 (ll10)2 93

100 39l00 2 -N- 12

- 50 IJOOOO _ 1170middotmiddot - 10

l OOO

100000 9 (MW-301) - ll(ll)0 761l00~ 70 40 (36) 12000(MWmiddot98) l 9(MW) 100 l (MW-101) 36 (20)~ 70 23a- 7012middot__ 7 I7l l middot DklaoiOitla)MM 48l

0 3 (3) 600(MWJOlA)9 (MW-2038)

l ll (MWmiddot2048) 2000 2 9 (MW-2041) 2000Tol- 440 I 1JOO1000 l20 (MW-JOlA)Xylnll 2_

---_1-1(-dal GrovedMW CoosaaiDUl Freq ud CoeQIOlna Raa

NyUrampa-iltOI$110

ll(MW-1111) I 30 (MW-IISA) ~-tsladl- 10 (MW-107)l~ S6000 (MW-lllA)

tJamiddotJ)iaOrObeaiampM - bull 19 (MW-30S8)7SO 30 (3) SIOOOO (MW-113A)

14-p-- 41 (11)s 63 (MW-6A)600 610 16

tlo-~nc 3UlODOO(MW-lllA)100 (MW-1048)4-MampIgtyplloool IS SIOO(MW-11)IS (MW-30S8)NiuoliCIUIampM n SS100 (MW-113A)124-TricbiorobeftiCM - I3S (MW-10lt8)11 l30(MW-IISA) 170 (MW-611)

6N_ s 0 189 - 9 (MW-lll8) llmiddotDkhkKOitbaM 100 Ill100 l

111-TriCWofOitUIIamp 0 90 (MW-111) Vi ell- I 650 (MW-1048)ll(MW-117A)Mot~ 10 180 (MW-IIlA)96 (MW-96)1 a-NitMIOmiddotDimiddotbullmiddot 41000(MW-113A) s

ElMlt shyOil(lashy

ottbi eefJQ) 0001 (MW-118) iS (MW-108)

04 1 (37) 016 (MW-IOlA)Hololt I S4(MW-llll) 03S (MW-611)bullbullmiddot-ooT 3 OSS (MW-EAT-15)0011 (MW-IOS)- -IHC l 01 (MW-301)DelcamiddotIHC I 17(MW-9A)Dlol4rin ookgtfdabull Soutc~ Flftll WOfk Plla Jolyaaza 11 - orouactwater Sl14) Dcamber t917

Ortfl Prclilllinlty Suamary o( Site CbatKCriutioO NJUrampIIOIOO_St_ 191amp

1MO bull MM~d- Milia eoa-at tAYtl or EPA MO wtlkbcYCf is lllOfC ltriftstftL

1MCLO bull Mllfllbull eoaIIUMtt lAYtl 0oe1~ o( 63 ~ WIUI tS wdl polaU llllpkcent almbcn ia p~rcotMMS repraeat ~ampmpkl with

-ndoO _ MQ or MQO Wed_ aftM _ lioO ~ Ia - shy

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middot~ r

I

I I

) 0 WLIMINMY RfMEPIAl RpoundSPON$E OIJgcnyES

~po oOJoCiiOI for the Nyonu II middot Orobull- StY ~llf1 will be on the potential ror rokS to pbullblk ao4 the ca-roamltnL ~~~po objeCI not nnal and await completion of alltc-specilc tilt aiMU_L KoweYtr bUI4 01 CliltiOI dl~ wveral patbWI)l throuamph which humans

or tht eampMroruacll cou~ be tllpOie4 tO contamlnalll Ia pouactwatu bM been toeatlfiecl

o ttumaa cqu~~te tO coawainall pouactwaW wouP laiUoft Genna contaCt aR40r iobaiatloa if a water aupply aoune if dcwklfl at or bullr tbe 1Ue Ia tJre Mure

o cxpCIItiN 10 cootanUutell pou4WI W0MP 4Lrecl Qermal oonKl witb aDCl iobaltioD a( coowaiaUll lo eqMOYI or vapor lonD -piOI iato relideftdal ~~~ dodpdicnt rroca tbc lite

o u4 ~~tal apcllllfC 10 coocaalDUU froa poctwatcr once It ttiscUraeamp lato

wcda or tbe SuclbUIJ RiYef

Prtlhllinary ruS-1 rcspobull objecliwl tUt td4raamp tbelt poceatial apo~ure pathways inchiCampe

o Utaitilll pracatancl Murc riiD to humans cauMil b) apotUto to ooataminatc4 po~aactwatcr sltffacamp waterl aM -eau

o Ubullltilll deJfldltiol of tM Sltdb~try River aacl wetU41 liltamp to dischltp of coo~iaa- pouftdWiter and

o - appliltlgtbull ao4 rcplltlonl _ and ror PPY

MdltloNI- objeltIIWS may be 10pe4 on dall colleete4 In the Nyonull field intlplloa -middot aM 1M rilt performld bull ptn of tM RlFS

40 1QENDfJCampJON ANQ genNJNO OF DCtfNQIOOIE$

-- o( -middot-middot P- -torY o( tedlootol o(toldpdrll -inatiOn 11 1M Nytnaa _ EP teellnoloampY was evalolled on the - o( _ potclllal delnmiddotbullP -bull bull 11 MCU aod red- 1M potcntiol threat 10 poblllt

lbeuYitoii-L

Treat ~ pocealillly sllitab1 tor tM Nyaua liM wae ldPtifted Nled oa ~middot bull -n o( tM ~til oootaaiaatiol ull prcllnliIJ tctponsc objectiva The tcdtno~ - diYide4 iato ail calfIOI ucl catefMY rqwet~Rtilamp bull pp at re~pomamp actioU tblt covkl ___ -oOJoCiiOI

Sita eoauo1 COIItaillftlftl Treat_ ExtraciiOO

SlltdJIHiftthlll

)

lnncgtbulltll tedlooiOIa were identlllad rltgtntn4or JIIormampIIOD oa4 1ltc Superfloa4 ln_t TclthnOIOI)

Emiddotauadon Pro-= TtchnoloampY Proftlcs fJovember 1919 from tM EPA

42 TECHNOLOGY SCREENINO The laitlll scnertlol of~elthnolOampiOI wos - oa enampirinllelliblllry on4 oppllcobillry to tlto lOCidon or tlto NyortJA olte _ ntlytltotechnolOjlll wore-- oa agtnstroinu Imposelt by the rype or agtatomlnoau -middotc physkll agtn41tOns oltlto ute on4 _ or rettt~inlnl bull rault or tlto uurmenr p- croctcrlstlcl oltlto bullIre thll may or 11m1r tlto eKect_ o 1 tcchnOIOI) obtol - _ ltiptlOno Pbyskll propettY doll oltlto agtatominoau bullliCit olltllity bOiUal polaC -ry worc to oay lbolu Pttgte agtatominoau tbcmKIIIIY lmpaoe oabull ~todlaolOampYmiddot Wbullte ~- ldlatllod todelae - ltor ltlODII waste uatmcaL TiiM ~GftOIOIel wto1t a WM deatt) precluded by Wlll6 or site cUractcriitkl were elimltll rora--loa Tbc ults of this oltOill- _ rtsilmjp(Y Sqscoinl llfllms4i11TKbullIil (-May 1911~ TM ARCS te~a ldlatiGid odditlOnll toe~~aoOjielthll were

not coWdcred la ~ report Tobie 4middot1 Is 1 - o the remediatiOn tcchnoOjllltbat relftll after nln~ Tbc EbUltO-AilCS the )9techaoOjlllllstod oa Tobie 4-1 by-~ prodtKt lltCTIIUIC en4or inOrntltlOn pertonao doll -middot FSbull on4 bullhrobullJh dirlaquo agtnoultotiOO with n40ro A brie dOIltriptlOn of each

-~~-lnToblel-~

50 WASpound 1 ANQ u IRFAItBil m 1QT rsooRAM - Tbc tr0111hlliry _-1bull-to~ re-opodftlt -riOO reprdialthe perlormonlaquo

of--middot-ooiOilabullbull- shy ialtiol scneo~ POIIOtlll ftuncial rlsa on4 delaY lo - KtiOO oro _ with the --of 1 le(hnolOD lOr lmptementotlOn witbOIIt fl WfPOdaamp pcrfonMftCC data For tM uutabUity tCit PfOI-middot on-site bench-5CIIt telll wcro - oo troot-r -aoOjlll ooly II ipiOltoDI lt-1 lalOrmotiOO roprdinl the te(bldOI(i coM dketiyent- Of lrepkmotn~tbility cou4 M obtliaed at a rutOftlble eo~t P-I ud _U oltgte tlbiliry otudy ro-llad OltpDicl rrootmeftl pcctlvltly throop bettdt_ ~ lo ltloD _ relt~bull_ worc ideotltlcd durin the rroatobility otudy ud doll colieltrltd to_ the iDII_t_te otrubull u be to In evoiUitlnl

the applklbilicy o( MYCrtl ~~ tUt were aot btlldlmiddotbullbull From loorntltlOa ptherad ill - otudiOI dtamp woste dllrKterotlcl likely to lmplltt _-implemltDtobillry oadof-lalrroorrtechnolOIIOihbullbullicleifted

ThM -tlcs ladshyldiM rqeegliql middot A all llIIDbtr ol orpak alld iaorpllk contaminanu 1avt bctn ia 1t u- O~ ~~~ crronsmllkdJ to lavotw a ueaU1181 (a CCblalbull ol ubull- ) speorc proccu- oalpcd _ -----middot ()onlla _ shytlfiCdW fCIIiatlM CIOIIllaludoa

Ullf pracW middot Dtftdceciel Ia laflnlbulldol rcatilll 0 Ntk wttfl propen- sd pH oplaquotftlt Mry cooBOD TOC C DOl alii TM Rl ud ueaiblhlJ It~bull ld4rtU theM ~ ao4 flrthct We1Uify lmportut niMCtl li ely to illft lM trfectiveiIM o( UbullUMIIIII at~rNii-

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$11tOgtouol XFcaciaiiSP X X

loltihlioUl Coauoll ~- X5latfacc Waw Coluol

~ XCpplbulll XH)dnulkBarrilt Oroddw~MI lalaeeptor T~ftdl X

XFnaOIOIItiqo_ lajocdoll X

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Wet Alr ()ddadoll1 X

~ XPNdplampl~lioiISediNalldol X -Locll w n~t FtdUa X XOI~WTNa-tFKIMtJ X -Potarilld ~ ()Ddaat ~o~J

DJiilll X sai-Fioill- XTllibull Fla EYapORlioas NltSiripplacc_-loa- X

-~ XMed6l FUusliol X ---X

X X

II

)

I

IJ r

-~ ~- Dnla - (_

lMIIWI IIPDES lllodWJO ~kMIIO Orouftdwltcr

shyDlll-CaUilloll ---middot lelt FUIIr FlloorPIW Onvlty1gtidtal01 v nmtiol

Rcta1M4 xa lfll

X X

X X X

X X

X X X X

1 tucwetM TtcUooD tbat il paR ot EPA Silamp OOMUIioll Proanbull middot turrcatty btiq rldd 1 1M Towll of AIJI)a ot M11 I p11bUdJ opaatcd _let UUIIMilt fidtlty

3 lllMMlM TdiiOkgtD

11

--

----

-I )

lllllo_Z ~ ot Orww Re8ldiadol T_

llyua QcUal Silo

FeocfAtSipl

llldaltioul ColiUOII

~loll Molltortq

Slllflcr Water Cotluol

ClppUit

tfJaiiUc Ianier

Groundwater lnjeaion

Reltrkt ~wt~ fuKll poll watIUill tlpl

11 lud or otMt NllricdoU to proltibh tbc use ol JfOIIIIChILtriiiMIMtilt

EYihaale mlpaliol ud dillriiMaUoll of eo~~~amp~~luaamps Oyener tiiDC ~a~ina 11orina 10 aapll lM CMIHnlal alliS bedroct aquller

ConUOI slllflct waw ru4 owr Ike 1114 lbuefore lallltrat6oa to poundwttar

Pmat iaftltraliiMI ot _doll iiiO coatlaiuted ZOIIII wiU a RCilA 111dtimiddotlayet cap or OlMr cappWc bullterilil

OMrt ltMItMUda pouctwaamper ftow aroud contlmintted zona willa limy Wlwat piliq

ampLiblillrl 1 bedroct ~ _ulictlly bullptradient of the site 10 tower JfOUMwalel dMidoll il coaaaaiuS

Pmut JfOUDdwalef _ tlarotaP COIItlflliMtcd IODa by poutiq Mdrock traura

laect wttrr Into the Jf0111Mh1W to bydnulkllly prevtnt the funhct miJfltioo ot COGtamiauq

ltiuod abulllriull ld 01J111 iiiiO liM JfOUMIWIIer aiGJ I uix of atiKI~ wdll lid redmd1Ui01 amnktues 10 stimulate

~middot- __ _ _ _ICampMIM _or~bull lltIHolopcal NeQOr

(ampJ I trictllq IUICf tOCatilt ~ CIOIIIKtOII)

I)

IIitr 1~

bullbull

) I ~

t~r~

Acrltioft

_ Otf-tlbull wT

FtciiiY

PolarU4 Mlt4iiJ()WolvOd QDdall 1M

()llidbe orpakl ill atJICUIIII pouadMIU willa I llal1tiOCO

applklt of ll~ upt aad a rona oQdilcr

Otatroy orpaic co~wafuall La aa aq~~M~Gtll IOiudOD by iDdMiaJ ollidadoll aiMI laydtolylil reeaiOM at lllP waperauuc aDd prt~Suramp Olyp at ekWUid _ cabaDC tbamp oddat~D of orpak

coapoddlto carbOa diolidamp bullbullmiddot

AI1111C tM lfOIadWatlt 10 ~ iaoJpClk itOft and mlfiMM andmiddot-middot- middot-eo-t dillotvd 10 aa tolubae font (lc metal sulftde W ~or boa aauta) padld tOiiclltiUOUIJI

ftoealladoa settle out IOl6dl ~ plilJmiddot

Dildlotl atroaed --to-- ()wOOdTNat_t WOJIII (POTWl for ubulltbullat Water mISt rr preutbullat llllldl141 bdofC diiCIW 10 tillamp fadlicy

adDente ubullbullbullbullbull _ (sl cartiOII) at aa ol-liw

Killty 1rllff coaUUMII CK (OIICIampIItrtlld wu~ to offmiddotslte (tctlity rot flnhcr ubulltmcnt

Olddizt orpnicS and c~rot)kll~ ftltcr ioM dint ionized OIYfll u4 aiuotta and llltflliokl IJbL

___ - --Ia aM it8ptn-~ Ofkl taps pUtt

coa-w toa bullrx pedwlta bJ liOUiaJ oft WI OOII(IIIItnlioM or VOC SVOO ill a cohama partedwilllt~enbulltlriiL w -doflfaucotbull bull-ait lxltl tllll _ bull plaquo dle - anMfw of VOOJSVOCI frola u oq_ _ shy

I )

~

~t-tiaed)

naiiiampUlliWIIIIilcu-_

loa-middot _ Me4il fltratioa

flltntioa

OfOIwhmpiaamp

Or~ialrucrotptor

llillllll Loodlll

NPOES OllcUrl

Rod---o1- 0lt _ orpako tJuobullP tdiOrpdoa oato paa ~Mwd cartMML Mey be ased u a poUsblaamp ~~ aMr uea~l tla 111 UVOIOUttoll or tir atrippinampW reiDOyenC

~allfdClld CQIIdta

Separate CODCCIUIwd Cl)lllaiUaU rro- mtiClld water ISinabull semimiddot

--- RcmcM bull sol fJOM tlrl WMteWllet iltum by fordbullamp

water nwP a aM tu~a or cartridbullmiddotYfC filter

ttclftOYamp sol aacl bullWI frOil wuaew~tcr auum 111in1 1 mcrnbraM _ fltract pvftdWttcf frOCft Cl Of lfiOfS cstrectiotl - tO CORtrol Of rcWM tM UlkrW CCMI _ Qf0111141w1 wouMI be uealld oa-Mat UUifONd 10 bullbull olaquo-tiw ~licy or diKNrJICllnto ~n lor

-J()IW Colkld JfOIIdwiiCt Ia ~pawl Drtin to allow treampUMIIt to

take pLaee

saare ue~-t rtiM~tamp ( _ thadae ipCil caWft) Ia aa oCImiddot

JtCilA rdliJmiddot OllcUtl P hlw tiM atona draiM ttWU MtfliiOfk or latO 1M ltMf hi tttal OIICraquorp OCitiOI wid M ___ -~u flooltftlotwiUIIoo

to ~toe tM rtetM

lei~ Utamptarou Net Wlwt the JfOIII sinamp OM or ~wtlll

II

)

lfu Use cutrtrpl torce 10 _ tM MdlJMllltioa rate of thtdJI

Dtwaters illldp by dfliUII giDlP lM ahadJC Nil aDd tv~poratioa frolltMwrc IOaitmiddot

()ewaterstl~IC by ~~Mill a coatLa- tuw belt tNt nbull over a drive aDd auide roUir 11uca llld Ukamp I (II)IIW70I MIL Shtdp is cootifliIOampSly diWiwed btCWMI lM IUW bella

otMten lllldfl _ ~ whll ~ Wlef 0 _ - _ - -Uto4-~ dcWitcritll IMlbOdl belli

Reduce tM IOiubull of 11-bull -cwal o( supetnltllll liquMt

Ocwatcn st~ae usiaa bull roampary cbullbullbull nuer

16

)

l l nCHNOLOOlES EVALUAreD l ao4llbelldl IAiiq wu 10 dcmOnsttalCthc cffcttln ol 1 tcthnoloJY In rc4ocinamp

poo-m coataonloanl that Clbt ao Nya to tbe MCUmiddot lie ronowlnamp oclttions daCribC bullbullbull UOIUDIGl ~eotalti~Md aDd lbC raOOoale lor cMIOIIDI ltlCII

lll EMIIJIIIIl l belldlmiddotIAiiq prcclpllltiooftOCltIIlaiiOalc4(tDCnlllioD and oa14atlonlflt40Cilon (-) ttquiR- 1llil wu tloDamp 10 delCrtniDC -1 and ooo41tiODI lor optimum rem o -_colloidal ao4 - - 1bC co11101lnatetl poutcr Hy4_ aetl 101idamp prodpilltiOtiWU -tlpte4 lo tbC PPM llludiiL ()aldatlottftetloctiDI rtqUitemCIII I

pK raaF for optimum metab reatQyenal wM abO bullgttilbOLIt~ IIUlytt preucat-14 be 10 _and rod 110bull conccnttatlons _ Ibull po ao Nyan belorlt othet lampdtoO _be _ Wit preucattneDI inorpnicllllll plbulll ca- _ IQlinl In alfoltripplol __ rod UV cftlclcncicS or ao nely lmpoct bioloPltl --bullbull perlortnl_ will abO tnellb loetli on polbullhlnamp proocUOI (I~ loa ()( rcverM 01100111) A _- o pacoot rlt-la i quoJilll _tiODI o( --lalioo (OrtMiloD led 10 IIIC -tillcatiOO o -F nnp (Or by4- polJIIIC (prodpllltiOO) ltyd-bull pcOildlt (-l icll_ ulllntbCCIeCI -o(lnoltPDicl D-pranpwerlt-olttbe p__ ill _ ll tina Table l middot l - tile tAl roo prod tbe boll r ulll

l ll Olll)llJIIlDurinamp ll lour etlditlonoltcchnololi boftdtmiddotICI oliOOIDI prcucattnCDI o arooICr 10 rc4uca- ampnorpnicl ThiiO lour_ were ioD altOinFo dlft bubble _oo ca____ ___L _ bull-bullbull- olt blllllll

-(LL bull 11rippln1 prior to actlvatc4 ca- Of ICiiVIte4 ca- ollor ___) _etiOI-1--Iol- loO_DF_ te41orinorpa1Crc-looly ea- _aott aoddiffuetl __ _ rororpolc -L BioloampICO__ tawd for botb i801pntt aD4 orpaic rcmovab lie PhiiC ll ideatlllcd tltc need to aetl lmplctneat ucattnCOI mcthOdl lor rc-1 o orpnicl For wmplc combibull bullbullabull 11rippin1 with acttvatc4 carbObull ucatmcat may be n_ary bullroomo cootantloaall arc dgtft~Cullto 11rip but -Uy 10 carbOn Altcrnatly c4 carbOn tniY be a pol~biDI 11cp ~ bioloalel ucatmcat bull cmplo)_ Tablel l-lto l -1 dcocribe Utbullt _ TIMamp 5-1 ilkoliftll tM water ctalily o( ttlamp r- Wllel priot ampa precipiudcm prcucaunenL

U 1Uf OBIECttvES _ o l ao4 ll beodt - 10 middot-- o - -o( ao4 -ubullilllbullbullbullbull pou-tallmpliiOOlshy11 1M tltyaua to beloW MOI TM bulltillamp- abO- 10 _1-middot-_---middot- piClypC o cacUaac - teiCOI ua- TbullriDI- oooductc4 to _ I rltllablt o IM tceJIOlOIYS abnity to _ contambullbullbull Ia the poutcr 11 the tlyaOJO 1111 TM olall col- - 001 iatcndc4 lor cftlclcY

I I I I

r~n hll

middot ll ~~l =~~Irrl l ~lil

f fl I

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 2: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

)

Kr oavid IAdarar June 13 ltto Paa TWo

bulltenaric traataellt VampiA or aevaral aora apaoific traataant traina that voul4 be oapUala of reducint contaainant lavale to tarvat alMnUP lev~

lavaral tacbnoloviu tlgtampt ware idantifia4 bullbull bail potentiallyapplicable to tba M)ansa alta ware not taate4r bovevar uny of thaaa are vall ~raven tecbnolotiaa and taatinq voulcl be bullora

=~tmiddotr~ur ~rc1~r rmiddot~iu~n potantifly autabla for tha lfyampnlamp alta ware identified Thaaa vill be looked at in turtber detail durlnt tha next acraanin atata of the Pl Tba UCI teaamp voul4 lUta to further dbcuaa tha approach tha PI will taU re~jardint innovative tachnolotibullbull for trutaantof~middot

It VG114 appear pzUIIelrt tbat tAe rantbull of altamativaa ahould focnae on atrat1 tor ~al of troundvatar rather than on a larta nuber of treatMDta for tha extracted vatar Tba PI tau viahea to 4111CN8amp vith you tbeH aapecta of tha faaaibility atu4y follovint arMnin9 of technolotY procaaa optiona

cthimtbull=r~Yu~tP~middotv~~~~that potential - for tlgtamp llyampDampa alta

If you have any tpUtiDM or caaentbull plbullbull call M at (617) 451-1201

CCI Jta llay II aana~tian D Grotlintbull r Jt Gleabull OI D Itaad

middot luena

PILl I tJtCI PIC 11 IIYAIIIt 104

EPA WORK ASSIONMENf NUMBERo Q61Ll5 EPA COtmlACT NUMBER 61-WWJllt poundBASCO SERVICpound5 INCORpORATED

middotATAium mJDY EVALUATION NYANZA CHEMICAL sm

OPERAILI UNIT 11 ASHLAND MASSACHUSETTS

JUNE 1990

~~gt)_ FS~ S I ACOMbullItaacablt

)

NYANZA OIEMICAI SITE

ntEATABILITY SIJDY EVALUAnON

oPEAABLE UNIT II

ASHLAND MASSAOIUSETIS

JUNE 1990

) WORK ~tGNMENT NO 06-ILlS

NOnCE

------ tM UtS $UWI EPiroAIIWAlll PtoMCltlgta ~ (USIPA) -AilCS I ea- No61--IO--IK (EboOCO~

l TABU 01 co1lt111lt1S

UK

~1ST Of T-BUS bullbullbullbullbullbullbullbullbull bull bull bull bull bull bull bull bull bull bull bull bull bull II~OF FIOUIIES bull bull bull II

nmgtoDucnoN 1 10

OYEJIVIEW OF ENVIRONMENTAL CONTAMINATION bullbullbullbull 10

PREl-IMINARY 11poundMEDW RESPDNSE oaJECI1VES bullbullbullbull bull 30

IOpoundNTIFICATI0N AND SCREENINO OF TECgtINOLOOIES bull 40

41 Tetb~M)k)D 14catUkatioa 9 41Teclo__ 10

PIIASE lAND ll TREATAIIIUTY TEST PROORAM bull bull bull bull bull bull 10

50 Sl TecbaoOiiC EIIIUIIWIL 17 51 Tat ObjeetW bull 1 B Exptri~MDampII oip aDd Proccd1tiCI bull bull 11 54 Tbullt EvaltioM latcrprclltkMI 26

CONCLUSIONS 30 60

urf OF TAIIIJS

Orovodwater CoalaluDt frtllIUitf u4 eocntntiOn Rill 1

1-1 - SaeampDiq SUliWY for orouacr 1dMidialioa Tedutotoael ll _o__ Tpo ll

4-l PrectpicaliOa TreauiiY Daampa bullbull bullbullbull bullbullbullbullbullbull bullbullbullbull bullbull bull 19

H 20 Pbllamp II IUW Water Qarttteriltkl

S-l ll ldlliyen1 EfiiCtiveMI or PUle 11 TN~reDl T~

S-l 12 loa~ middot Tllbiliqt DILl

s ll Dithled ~- middot TbullUibilitJ Data bullbullbull

S-S cano~ - TrallbiliYOra bullbullbull 24

S-6

S-7 __ T -[)ola

= urr OF PIOUUS

l middotl Sloa_-~ middotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotbullmiddotmiddotmiddotmiddotmiddotmiddotmiddotbull middot middotmiddotmiddotmiddot--middot l l-1 - _ Map

l-l TCIIIo~ IOiiWIIII middot loueCoiiiOyen -- S

l_ TCIIIo o- - Wclll bull loUO CoiiiOII bullbullbullbullbullbull 6

middotI

) 10 JNIRODUCDON

Tbe Nyanza II bull Orouodwlttr Remedial ht~tlpdolllftuibiUty Study (RllfS) il the MCOnd of thtec operable uaiampS ldcaliaecl for he Nyaua site ne objeeliWI of tbe Nyua URlFS are to evahate the uturt aid diltrlb~ampdol ot poudniM coawaludol -- tM lilt ueodaled wilb tiUI coa~CiliDilkiD and coa~plete a CellibUcy atu4y or applicable remedJal allcmattvamp Tbe ftnt phaM ot remedial iallltiptloll lbr lM site bu beeA COfllpllted AddhioBII puadwatet IQW~~tlptiou (Ptwc It) aa4 uaociattd rillr aaMtill art cumatty lD _ IM remedial la_tlpUoa aaMllel were coDdICted 11adU he REM Ul coaUK The RIFS repoN will bt completed uDikr the ARCS coatrtCL

AJ put ol tile uuoilloa- 1M REM lll 10 ARCS__ tile ARCS-~~ otudy wllll EC Jordla eompuy penoDKI to obcala uatabWty ~ttdJ daca coDducted SU the REM 111 coatrKl iD support ot RllfS actMU 1il IICUkll meiiDCifUd~ampa il aa Cll~amp~Uol ot MK stiMS u weU 11 u cvalaltkla of DIW UOloi ideatiBell lfacl coaWO ot lM ueatabWIJ lilts

Sectioa 20 of Uil bullmoranclulll proW a summl) dilculltoa of tM coodltton of tbe site inclldiq kgtCltioa lnfcned CllampIU of cotnamludoa aacl type of coetaalaldoa Slttioo l O deCIMI preliminary rcbullbullllal fCI900M objective~ T~ powatiaUy capable ot aidptlq COiltamlulioa 11 the site aad rnectillamp tM Sill re~ponat objecti- are MatiW il SICtiol 40 A brief deleriptioll of cadl ~ udlM statbull atw ~iS abO provided iD SKtioa 40 SectiOa SO dlsnlla and evahata tbe EC Jordu ampNaampability 1llt prosram wllkll aaaiMd till appUcabWIY of cartlia ICCbDOIOI tO 1M tfyuD sUamp lltd_ hi Sealoa 50 is a dilaalampioa of tilt ~ cxpatJMtllll dalip aDd procedura u4 dati evaamp-lioL cod~ troe tcdlDOloampY tbulltiaamp _ idaaUIIkatioa of 1lttMr ampe~lilll opttolll Is

-iaSoctloo60

10 QYiRytEW Of J5lMRONMfNIAL CONTAMINADQN

The Nyaua cMekal site is loclted off of Mtpako RCI u4 ~CM~tll ot M SwlbUY NN aM _ Streit ta AMIUd MIIUdiiiMta 11 _ oa Rprc 1middot1 A ore dtlliS view or tbe site is shawl Oil

r Aaure 1middot1 Tbe she wu thl locatiobull of dlalkal _~De~ lldlltilllor 61 )1111 ud il cunudy occvp5ed bJ

- - - DouioiiM 6l portoO - ol- -- shydilpoMd ot oa the Pte indltdina peniltty-trutl4 Pf011 cM~t~kalll_p frCHft tM wu~ewata trtlllftUI ~ IOU4 fKO ta dnabull (tor cMiakal predpltata ucl filter caka) ancl orf-speciftcadol pro4uas PTOCI cMaicU tUt coUd at be rtCI(Ied or rcIMII lnchadina pMDOlDiuob~UeM u4 IDifWrie sutfatc wac aro dilpOIIIl ol oa-litt 1c ampDOlt recent dye rnanldacturct

t1ya011 lac -plod tile sloe- 1965 10 1971 1MJ- shyA--oopdlai-----II 1M slto _be fouo41a llle lDIIampJ4~~=~-sm=~~=nrcoataaiaalt _ dlleded Ia ~~~~ tipdoM at NJUII ar _ ta hbM l-1 tporwat

_ coa~lll-~ Sourlta of Ofpaic udillorpak ooa~IbullUoa Mea 6ecected wltllia tM fonlU propttiJ ttovldampria COIItllliaalioa ol pouldwaltt Ul ocnrr4 Ia boO tbe bedrOCk ~ F1pNI lJ ulll 1 allOW lM attal ateat ol coatalliaatiol fix tc il sol aM Wrodt wdll ~middot heM limits ol CIOIIwaitioa OPical JAUIIJ tepNMAampalM of CMMI CIOIIlliniOCI II well

I I I I

[1 ~1 31 IJII [ r~middotmiddot~I

trlr ~i 1 (f~f l

I

I p UualyMI- oC-111lt ootJOI Millbllt IIIII ampy llllpoltl

UOioampJ-1 CoDtamiDIUid pouoctwawr bullPI to t11 alJrttial to a moor exteftt ta bull oonbettY dircdoa 10WUi M ~Ill) Jliyenel Ml Dow i1 priiMriiY lD U tut) 4irecdOft towani tMIUia put oftMTOWI of~ IM 4alamp aiiO IU mit COIIuaaat 411Uibvllol lD JfOUDdwaU ru be prtMDt II coDCUtnted iDClM4dl plllll llptrimposed 01 I __pl

-------N

OTICE If tfto flho hoage

II IIU clear t h

an

thll

NYANZA C

HE

MIC

AL

W

AST

E

DUHP

notice tt II due to

tht

AD

MIN

IST

RA

TIV

E

RE

CO

RD

qualttr of th

e docuMent

bolng fllbull o4middot

-agt

bull N

Cg

tshy2_1jttzbullbull5

2tti

iili~ ~

gJ

-sectlc

2o

bulltti

Oc

-1 cbull

Nc

~ z I

middot4f - rsS--~

(l

- -

middot

-+= )

-

)

)

---)

_Zl ~ co-bull_ c-o_Ru

~5110

Maxlmlm MCL01 foloof Mlnlmtntt

MCL1 ~ ~llllllol~llllllolQwlilll 39200

IIJQIIIIill 33050 29 (MW-109)0 4 (lloO 1400- 50 lOOO ll

Blri 01000

6 (MW-114 A 302) 33 -Beryllhua 14 (10114)l 302000 II (MW-IOl)

10 2230~middotmiddot

50 100 26 (Ul) 26lColdbullbull ll3~middotmiddot lJOO 90400cdlolt

1000 ~ l20300 l 2(MW-1048) 29 (Oil)roo 73600ldL )(1100 ~- 31050 02 (MW-201)32 (ll10)2 93

100 39l00 2 -N- 12

- 50 IJOOOO _ 1170middotmiddot - 10

l OOO

100000 9 (MW-301) - ll(ll)0 761l00~ 70 40 (36) 12000(MWmiddot98) l 9(MW) 100 l (MW-101) 36 (20)~ 70 23a- 7012middot__ 7 I7l l middot DklaoiOitla)MM 48l

0 3 (3) 600(MWJOlA)9 (MW-2038)

l ll (MWmiddot2048) 2000 2 9 (MW-2041) 2000Tol- 440 I 1JOO1000 l20 (MW-JOlA)Xylnll 2_

---_1-1(-dal GrovedMW CoosaaiDUl Freq ud CoeQIOlna Raa

NyUrampa-iltOI$110

ll(MW-1111) I 30 (MW-IISA) ~-tsladl- 10 (MW-107)l~ S6000 (MW-lllA)

tJamiddotJ)iaOrObeaiampM - bull 19 (MW-30S8)7SO 30 (3) SIOOOO (MW-113A)

14-p-- 41 (11)s 63 (MW-6A)600 610 16

tlo-~nc 3UlODOO(MW-lllA)100 (MW-1048)4-MampIgtyplloool IS SIOO(MW-11)IS (MW-30S8)NiuoliCIUIampM n SS100 (MW-113A)124-TricbiorobeftiCM - I3S (MW-10lt8)11 l30(MW-IISA) 170 (MW-611)

6N_ s 0 189 - 9 (MW-lll8) llmiddotDkhkKOitbaM 100 Ill100 l

111-TriCWofOitUIIamp 0 90 (MW-111) Vi ell- I 650 (MW-1048)ll(MW-117A)Mot~ 10 180 (MW-IIlA)96 (MW-96)1 a-NitMIOmiddotDimiddotbullmiddot 41000(MW-113A) s

ElMlt shyOil(lashy

ottbi eefJQ) 0001 (MW-118) iS (MW-108)

04 1 (37) 016 (MW-IOlA)Hololt I S4(MW-llll) 03S (MW-611)bullbullmiddot-ooT 3 OSS (MW-EAT-15)0011 (MW-IOS)- -IHC l 01 (MW-301)DelcamiddotIHC I 17(MW-9A)Dlol4rin ookgtfdabull Soutc~ Flftll WOfk Plla Jolyaaza 11 - orouactwater Sl14) Dcamber t917

Ortfl Prclilllinlty Suamary o( Site CbatKCriutioO NJUrampIIOIOO_St_ 191amp

1MO bull MM~d- Milia eoa-at tAYtl or EPA MO wtlkbcYCf is lllOfC ltriftstftL

1MCLO bull Mllfllbull eoaIIUMtt lAYtl 0oe1~ o( 63 ~ WIUI tS wdl polaU llllpkcent almbcn ia p~rcotMMS repraeat ~ampmpkl with

-ndoO _ MQ or MQO Wed_ aftM _ lioO ~ Ia - shy

I I

middot~ r

I

I I

) 0 WLIMINMY RfMEPIAl RpoundSPON$E OIJgcnyES

~po oOJoCiiOI for the Nyonu II middot Orobull- StY ~llf1 will be on the potential ror rokS to pbullblk ao4 the ca-roamltnL ~~~po objeCI not nnal and await completion of alltc-specilc tilt aiMU_L KoweYtr bUI4 01 CliltiOI dl~ wveral patbWI)l throuamph which humans

or tht eampMroruacll cou~ be tllpOie4 tO contamlnalll Ia pouactwatu bM been toeatlfiecl

o ttumaa cqu~~te tO coawainall pouactwaW wouP laiUoft Genna contaCt aR40r iobaiatloa if a water aupply aoune if dcwklfl at or bullr tbe 1Ue Ia tJre Mure

o cxpCIItiN 10 cootanUutell pou4WI W0MP 4Lrecl Qermal oonKl witb aDCl iobaltioD a( coowaiaUll lo eqMOYI or vapor lonD -piOI iato relideftdal ~~~ dodpdicnt rroca tbc lite

o u4 ~~tal apcllllfC 10 coocaalDUU froa poctwatcr once It ttiscUraeamp lato

wcda or tbe SuclbUIJ RiYef

Prtlhllinary ruS-1 rcspobull objecliwl tUt td4raamp tbelt poceatial apo~ure pathways inchiCampe

o Utaitilll pracatancl Murc riiD to humans cauMil b) apotUto to ooataminatc4 po~aactwatcr sltffacamp waterl aM -eau

o Ubullltilll deJfldltiol of tM Sltdb~try River aacl wetU41 liltamp to dischltp of coo~iaa- pouftdWiter and

o - appliltlgtbull ao4 rcplltlonl _ and ror PPY

MdltloNI- objeltIIWS may be 10pe4 on dall colleete4 In the Nyonull field intlplloa -middot aM 1M rilt performld bull ptn of tM RlFS

40 1QENDfJCampJON ANQ genNJNO OF DCtfNQIOOIE$

-- o( -middot-middot P- -torY o( tedlootol o(toldpdrll -inatiOn 11 1M Nytnaa _ EP teellnoloampY was evalolled on the - o( _ potclllal delnmiddotbullP -bull bull 11 MCU aod red- 1M potcntiol threat 10 poblllt

lbeuYitoii-L

Treat ~ pocealillly sllitab1 tor tM Nyaua liM wae ldPtifted Nled oa ~middot bull -n o( tM ~til oootaaiaatiol ull prcllnliIJ tctponsc objectiva The tcdtno~ - diYide4 iato ail calfIOI ucl catefMY rqwet~Rtilamp bull pp at re~pomamp actioU tblt covkl ___ -oOJoCiiOI

Sita eoauo1 COIItaillftlftl Treat_ ExtraciiOO

SlltdJIHiftthlll

)

lnncgtbulltll tedlooiOIa were identlllad rltgtntn4or JIIormampIIOD oa4 1ltc Superfloa4 ln_t TclthnOIOI)

Emiddotauadon Pro-= TtchnoloampY Proftlcs fJovember 1919 from tM EPA

42 TECHNOLOGY SCREENINO The laitlll scnertlol of~elthnolOampiOI wos - oa enampirinllelliblllry on4 oppllcobillry to tlto lOCidon or tlto NyortJA olte _ ntlytltotechnolOjlll wore-- oa agtnstroinu Imposelt by the rype or agtatomlnoau -middotc physkll agtn41tOns oltlto ute on4 _ or rettt~inlnl bull rault or tlto uurmenr p- croctcrlstlcl oltlto bullIre thll may or 11m1r tlto eKect_ o 1 tcchnOIOI) obtol - _ ltiptlOno Pbyskll propettY doll oltlto agtatominoau bullliCit olltllity bOiUal polaC -ry worc to oay lbolu Pttgte agtatominoau tbcmKIIIIY lmpaoe oabull ~todlaolOampYmiddot Wbullte ~- ldlatllod todelae - ltor ltlODII waste uatmcaL TiiM ~GftOIOIel wto1t a WM deatt) precluded by Wlll6 or site cUractcriitkl were elimltll rora--loa Tbc ults of this oltOill- _ rtsilmjp(Y Sqscoinl llfllms4i11TKbullIil (-May 1911~ TM ARCS te~a ldlatiGid odditlOnll toe~~aoOjielthll were

not coWdcred la ~ report Tobie 4middot1 Is 1 - o the remediatiOn tcchnoOjllltbat relftll after nln~ Tbc EbUltO-AilCS the )9techaoOjlllllstod oa Tobie 4-1 by-~ prodtKt lltCTIIUIC en4or inOrntltlOn pertonao doll -middot FSbull on4 bullhrobullJh dirlaquo agtnoultotiOO with n40ro A brie dOIltriptlOn of each

-~~-lnToblel-~

50 WASpound 1 ANQ u IRFAItBil m 1QT rsooRAM - Tbc tr0111hlliry _-1bull-to~ re-opodftlt -riOO reprdialthe perlormonlaquo

of--middot-ooiOilabullbull- shy ialtiol scneo~ POIIOtlll ftuncial rlsa on4 delaY lo - KtiOO oro _ with the --of 1 le(hnolOD lOr lmptementotlOn witbOIIt fl WfPOdaamp pcrfonMftCC data For tM uutabUity tCit PfOI-middot on-site bench-5CIIt telll wcro - oo troot-r -aoOjlll ooly II ipiOltoDI lt-1 lalOrmotiOO roprdinl the te(bldOI(i coM dketiyent- Of lrepkmotn~tbility cou4 M obtliaed at a rutOftlble eo~t P-I ud _U oltgte tlbiliry otudy ro-llad OltpDicl rrootmeftl pcctlvltly throop bettdt_ ~ lo ltloD _ relt~bull_ worc ideotltlcd durin the rroatobility otudy ud doll colieltrltd to_ the iDII_t_te otrubull u be to In evoiUitlnl

the applklbilicy o( MYCrtl ~~ tUt were aot btlldlmiddotbullbull From loorntltlOa ptherad ill - otudiOI dtamp woste dllrKterotlcl likely to lmplltt _-implemltDtobillry oadof-lalrroorrtechnolOIIOihbullbullicleifted

ThM -tlcs ladshyldiM rqeegliql middot A all llIIDbtr ol orpak alld iaorpllk contaminanu 1avt bctn ia 1t u- O~ ~~~ crronsmllkdJ to lavotw a ueaU1181 (a CCblalbull ol ubull- ) speorc proccu- oalpcd _ -----middot ()onlla _ shytlfiCdW fCIIiatlM CIOIIllaludoa

Ullf pracW middot Dtftdceciel Ia laflnlbulldol rcatilll 0 Ntk wttfl propen- sd pH oplaquotftlt Mry cooBOD TOC C DOl alii TM Rl ud ueaiblhlJ It~bull ld4rtU theM ~ ao4 flrthct We1Uify lmportut niMCtl li ely to illft lM trfectiveiIM o( UbullUMIIIII at~rNii-

10

--

I )

_ lloos-qSIolt __

Nua a-loll

ROlli tillXJl~

$11tOgtouol XFcaciaiiSP X X

loltihlioUl Coauoll ~- X5latfacc Waw Coluol

~ XCpplbulll XH)dnulkBarrilt Oroddw~MI lalaeeptor T~ftdl X

XFnaOIOIItiqo_ lajocdoll X

_ XtJmiddot

shyX

X =middot X

Wet Alr ()ddadoll1 X

~ XPNdplampl~lioiISediNalldol X -Locll w n~t FtdUa X XOI~WTNa-tFKIMtJ X -Potarilld ~ ()Ddaat ~o~J

DJiilll X sai-Fioill- XTllibull Fla EYapORlioas NltSiripplacc_-loa- X

-~ XMed6l FUusliol X ---X

X X

II

)

I

IJ r

-~ ~- Dnla - (_

lMIIWI IIPDES lllodWJO ~kMIIO Orouftdwltcr

shyDlll-CaUilloll ---middot lelt FUIIr FlloorPIW Onvlty1gtidtal01 v nmtiol

Rcta1M4 xa lfll

X X

X X X

X X

X X X X

1 tucwetM TtcUooD tbat il paR ot EPA Silamp OOMUIioll Proanbull middot turrcatty btiq rldd 1 1M Towll of AIJI)a ot M11 I p11bUdJ opaatcd _let UUIIMilt fidtlty

3 lllMMlM TdiiOkgtD

11

--

----

-I )

lllllo_Z ~ ot Orww Re8ldiadol T_

llyua QcUal Silo

FeocfAtSipl

llldaltioul ColiUOII

~loll Molltortq

Slllflcr Water Cotluol

ClppUit

tfJaiiUc Ianier

Groundwater lnjeaion

Reltrkt ~wt~ fuKll poll watIUill tlpl

11 lud or otMt NllricdoU to proltibh tbc use ol JfOIIIIChILtriiiMIMtilt

EYihaale mlpaliol ud dillriiMaUoll of eo~~~amp~~luaamps Oyener tiiDC ~a~ina 11orina 10 aapll lM CMIHnlal alliS bedroct aquller

ConUOI slllflct waw ru4 owr Ike 1114 lbuefore lallltrat6oa to poundwttar

Pmat iaftltraliiMI ot _doll iiiO coatlaiuted ZOIIII wiU a RCilA 111dtimiddotlayet cap or OlMr cappWc bullterilil

OMrt ltMItMUda pouctwaamper ftow aroud contlmintted zona willa limy Wlwat piliq

ampLiblillrl 1 bedroct ~ _ulictlly bullptradient of the site 10 tower JfOUMwalel dMidoll il coaaaaiuS

Pmut JfOUDdwalef _ tlarotaP COIItlflliMtcd IODa by poutiq Mdrock traura

laect wttrr Into the Jf0111Mh1W to bydnulkllly prevtnt the funhct miJfltioo ot COGtamiauq

ltiuod abulllriull ld 01J111 iiiiO liM JfOUMIWIIer aiGJ I uix of atiKI~ wdll lid redmd1Ui01 amnktues 10 stimulate

~middot- __ _ _ _ICampMIM _or~bull lltIHolopcal NeQOr

(ampJ I trictllq IUICf tOCatilt ~ CIOIIIKtOII)

I)

IIitr 1~

bullbull

) I ~

t~r~

Acrltioft

_ Otf-tlbull wT

FtciiiY

PolarU4 Mlt4iiJ()WolvOd QDdall 1M

()llidbe orpakl ill atJICUIIII pouadMIU willa I llal1tiOCO

applklt of ll~ upt aad a rona oQdilcr

Otatroy orpaic co~wafuall La aa aq~~M~Gtll IOiudOD by iDdMiaJ ollidadoll aiMI laydtolylil reeaiOM at lllP waperauuc aDd prt~Suramp Olyp at ekWUid _ cabaDC tbamp oddat~D of orpak

coapoddlto carbOa diolidamp bullbullmiddot

AI1111C tM lfOIadWatlt 10 ~ iaoJpClk itOft and mlfiMM andmiddot-middot- middot-eo-t dillotvd 10 aa tolubae font (lc metal sulftde W ~or boa aauta) padld tOiiclltiUOUIJI

ftoealladoa settle out IOl6dl ~ plilJmiddot

Dildlotl atroaed --to-- ()wOOdTNat_t WOJIII (POTWl for ubulltbullat Water mISt rr preutbullat llllldl141 bdofC diiCIW 10 tillamp fadlicy

adDente ubullbullbullbullbull _ (sl cartiOII) at aa ol-liw

Killty 1rllff coaUUMII CK (OIICIampIItrtlld wu~ to offmiddotslte (tctlity rot flnhcr ubulltmcnt

Olddizt orpnicS and c~rot)kll~ ftltcr ioM dint ionized OIYfll u4 aiuotta and llltflliokl IJbL

___ - --Ia aM it8ptn-~ Ofkl taps pUtt

coa-w toa bullrx pedwlta bJ liOUiaJ oft WI OOII(IIIItnlioM or VOC SVOO ill a cohama partedwilllt~enbulltlriiL w -doflfaucotbull bull-ait lxltl tllll _ bull plaquo dle - anMfw of VOOJSVOCI frola u oq_ _ shy

I )

~

~t-tiaed)

naiiiampUlliWIIIIilcu-_

loa-middot _ Me4il fltratioa

flltntioa

OfOIwhmpiaamp

Or~ialrucrotptor

llillllll Loodlll

NPOES OllcUrl

Rod---o1- 0lt _ orpako tJuobullP tdiOrpdoa oato paa ~Mwd cartMML Mey be ased u a poUsblaamp ~~ aMr uea~l tla 111 UVOIOUttoll or tir atrippinampW reiDOyenC

~allfdClld CQIIdta

Separate CODCCIUIwd Cl)lllaiUaU rro- mtiClld water ISinabull semimiddot

--- RcmcM bull sol fJOM tlrl WMteWllet iltum by fordbullamp

water nwP a aM tu~a or cartridbullmiddotYfC filter

ttclftOYamp sol aacl bullWI frOil wuaew~tcr auum 111in1 1 mcrnbraM _ fltract pvftdWttcf frOCft Cl Of lfiOfS cstrectiotl - tO CORtrol Of rcWM tM UlkrW CCMI _ Qf0111141w1 wouMI be uealld oa-Mat UUifONd 10 bullbull olaquo-tiw ~licy or diKNrJICllnto ~n lor

-J()IW Colkld JfOIIdwiiCt Ia ~pawl Drtin to allow treampUMIIt to

take pLaee

saare ue~-t rtiM~tamp ( _ thadae ipCil caWft) Ia aa oCImiddot

JtCilA rdliJmiddot OllcUtl P hlw tiM atona draiM ttWU MtfliiOfk or latO 1M ltMf hi tttal OIICraquorp OCitiOI wid M ___ -~u flooltftlotwiUIIoo

to ~toe tM rtetM

lei~ Utamptarou Net Wlwt the JfOIII sinamp OM or ~wtlll

II

)

lfu Use cutrtrpl torce 10 _ tM MdlJMllltioa rate of thtdJI

Dtwaters illldp by dfliUII giDlP lM ahadJC Nil aDd tv~poratioa frolltMwrc IOaitmiddot

()ewaterstl~IC by ~~Mill a coatLa- tuw belt tNt nbull over a drive aDd auide roUir 11uca llld Ukamp I (II)IIW70I MIL Shtdp is cootifliIOampSly diWiwed btCWMI lM IUW bella

otMten lllldfl _ ~ whll ~ Wlef 0 _ - _ - -Uto4-~ dcWitcritll IMlbOdl belli

Reduce tM IOiubull of 11-bull -cwal o( supetnltllll liquMt

Ocwatcn st~ae usiaa bull roampary cbullbullbull nuer

16

)

l l nCHNOLOOlES EVALUAreD l ao4llbelldl IAiiq wu 10 dcmOnsttalCthc cffcttln ol 1 tcthnoloJY In rc4ocinamp

poo-m coataonloanl that Clbt ao Nya to tbe MCUmiddot lie ronowlnamp oclttions daCribC bullbullbull UOIUDIGl ~eotalti~Md aDd lbC raOOoale lor cMIOIIDI ltlCII

lll EMIIJIIIIl l belldlmiddotIAiiq prcclpllltiooftOCltIIlaiiOalc4(tDCnlllioD and oa14atlonlflt40Cilon (-) ttquiR- 1llil wu tloDamp 10 delCrtniDC -1 and ooo41tiODI lor optimum rem o -_colloidal ao4 - - 1bC co11101lnatetl poutcr Hy4_ aetl 101idamp prodpilltiOtiWU -tlpte4 lo tbC PPM llludiiL ()aldatlottftetloctiDI rtqUitemCIII I

pK raaF for optimum metab reatQyenal wM abO bullgttilbOLIt~ IIUlytt preucat-14 be 10 _and rod 110bull conccnttatlons _ Ibull po ao Nyan belorlt othet lampdtoO _be _ Wit preucattneDI inorpnicllllll plbulll ca- _ IQlinl In alfoltripplol __ rod UV cftlclcncicS or ao nely lmpoct bioloPltl --bullbull perlortnl_ will abO tnellb loetli on polbullhlnamp proocUOI (I~ loa ()( rcverM 01100111) A _- o pacoot rlt-la i quoJilll _tiODI o( --lalioo (OrtMiloD led 10 IIIC -tillcatiOO o -F nnp (Or by4- polJIIIC (prodpllltiOO) ltyd-bull pcOildlt (-l icll_ ulllntbCCIeCI -o(lnoltPDicl D-pranpwerlt-olttbe p__ ill _ ll tina Table l middot l - tile tAl roo prod tbe boll r ulll

l ll Olll)llJIIlDurinamp ll lour etlditlonoltcchnololi boftdtmiddotICI oliOOIDI prcucattnCDI o arooICr 10 rc4uca- ampnorpnicl ThiiO lour_ were ioD altOinFo dlft bubble _oo ca____ ___L _ bull-bullbull- olt blllllll

-(LL bull 11rippln1 prior to actlvatc4 ca- Of ICiiVIte4 ca- ollor ___) _etiOI-1--Iol- loO_DF_ te41orinorpa1Crc-looly ea- _aott aoddiffuetl __ _ rororpolc -L BioloampICO__ tawd for botb i801pntt aD4 orpaic rcmovab lie PhiiC ll ideatlllcd tltc need to aetl lmplctneat ucattnCOI mcthOdl lor rc-1 o orpnicl For wmplc combibull bullbullabull 11rippin1 with acttvatc4 carbObull ucatmcat may be n_ary bullroomo cootantloaall arc dgtft~Cullto 11rip but -Uy 10 carbOn Altcrnatly c4 carbOn tniY be a pol~biDI 11cp ~ bioloalel ucatmcat bull cmplo)_ Tablel l-lto l -1 dcocribe Utbullt _ TIMamp 5-1 ilkoliftll tM water ctalily o( ttlamp r- Wllel priot ampa precipiudcm prcucaunenL

U 1Uf OBIECttvES _ o l ao4 ll beodt - 10 middot-- o - -o( ao4 -ubullilllbullbullbullbull pou-tallmpliiOOlshy11 1M tltyaua to beloW MOI TM bulltillamp- abO- 10 _1-middot-_---middot- piClypC o cacUaac - teiCOI ua- TbullriDI- oooductc4 to _ I rltllablt o IM tceJIOlOIYS abnity to _ contambullbullbull Ia the poutcr 11 the tlyaOJO 1111 TM olall col- - 001 iatcndc4 lor cftlclcY

I I I I

r~n hll

middot ll ~~l =~~Irrl l ~lil

f fl I

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 3: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

EPA WORK ASSIONMENf NUMBERo Q61Ll5 EPA COtmlACT NUMBER 61-WWJllt poundBASCO SERVICpound5 INCORpORATED

middotATAium mJDY EVALUATION NYANZA CHEMICAL sm

OPERAILI UNIT 11 ASHLAND MASSACHUSETTS

JUNE 1990

~~gt)_ FS~ S I ACOMbullItaacablt

)

NYANZA OIEMICAI SITE

ntEATABILITY SIJDY EVALUAnON

oPEAABLE UNIT II

ASHLAND MASSAOIUSETIS

JUNE 1990

) WORK ~tGNMENT NO 06-ILlS

NOnCE

------ tM UtS $UWI EPiroAIIWAlll PtoMCltlgta ~ (USIPA) -AilCS I ea- No61--IO--IK (EboOCO~

l TABU 01 co1lt111lt1S

UK

~1ST Of T-BUS bullbullbullbullbullbullbullbullbull bull bull bull bull bull bull bull bull bull bull bull bull bull II~OF FIOUIIES bull bull bull II

nmgtoDucnoN 1 10

OYEJIVIEW OF ENVIRONMENTAL CONTAMINATION bullbullbullbull 10

PREl-IMINARY 11poundMEDW RESPDNSE oaJECI1VES bullbullbullbull bull 30

IOpoundNTIFICATI0N AND SCREENINO OF TECgtINOLOOIES bull 40

41 Tetb~M)k)D 14catUkatioa 9 41Teclo__ 10

PIIASE lAND ll TREATAIIIUTY TEST PROORAM bull bull bull bull bull bull 10

50 Sl TecbaoOiiC EIIIUIIWIL 17 51 Tat ObjeetW bull 1 B Exptri~MDampII oip aDd Proccd1tiCI bull bull 11 54 Tbullt EvaltioM latcrprclltkMI 26

CONCLUSIONS 30 60

urf OF TAIIIJS

Orovodwater CoalaluDt frtllIUitf u4 eocntntiOn Rill 1

1-1 - SaeampDiq SUliWY for orouacr 1dMidialioa Tedutotoael ll _o__ Tpo ll

4-l PrectpicaliOa TreauiiY Daampa bullbull bullbullbull bullbullbullbullbullbull bullbullbullbull bullbull bull 19

H 20 Pbllamp II IUW Water Qarttteriltkl

S-l ll ldlliyen1 EfiiCtiveMI or PUle 11 TN~reDl T~

S-l 12 loa~ middot Tllbiliqt DILl

s ll Dithled ~- middot TbullUibilitJ Data bullbullbull

S-S cano~ - TrallbiliYOra bullbullbull 24

S-6

S-7 __ T -[)ola

= urr OF PIOUUS

l middotl Sloa_-~ middotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotbullmiddotmiddotmiddotmiddotmiddotmiddotmiddotbull middot middotmiddotmiddotmiddot--middot l l-1 - _ Map

l-l TCIIIo~ IOiiWIIII middot loueCoiiiOyen -- S

l_ TCIIIo o- - Wclll bull loUO CoiiiOII bullbullbullbullbullbull 6

middotI

) 10 JNIRODUCDON

Tbe Nyanza II bull Orouodwlttr Remedial ht~tlpdolllftuibiUty Study (RllfS) il the MCOnd of thtec operable uaiampS ldcaliaecl for he Nyaua site ne objeeliWI of tbe Nyua URlFS are to evahate the uturt aid diltrlb~ampdol ot poudniM coawaludol -- tM lilt ueodaled wilb tiUI coa~CiliDilkiD and coa~plete a CellibUcy atu4y or applicable remedJal allcmattvamp Tbe ftnt phaM ot remedial iallltiptloll lbr lM site bu beeA COfllpllted AddhioBII puadwatet IQW~~tlptiou (Ptwc It) aa4 uaociattd rillr aaMtill art cumatty lD _ IM remedial la_tlpUoa aaMllel were coDdICted 11adU he REM Ul coaUK The RIFS repoN will bt completed uDikr the ARCS coatrtCL

AJ put ol tile uuoilloa- 1M REM lll 10 ARCS__ tile ARCS-~~ otudy wllll EC Jordla eompuy penoDKI to obcala uatabWty ~ttdJ daca coDducted SU the REM 111 coatrKl iD support ot RllfS actMU 1il IICUkll meiiDCifUd~ampa il aa Cll~amp~Uol ot MK stiMS u weU 11 u cvalaltkla of DIW UOloi ideatiBell lfacl coaWO ot lM ueatabWIJ lilts

Sectioa 20 of Uil bullmoranclulll proW a summl) dilculltoa of tM coodltton of tbe site inclldiq kgtCltioa lnfcned CllampIU of cotnamludoa aacl type of coetaalaldoa Slttioo l O deCIMI preliminary rcbullbullllal fCI900M objective~ T~ powatiaUy capable ot aidptlq COiltamlulioa 11 the site aad rnectillamp tM Sill re~ponat objecti- are MatiW il SICtiol 40 A brief deleriptioll of cadl ~ udlM statbull atw ~iS abO provided iD SKtioa 40 SectiOa SO dlsnlla and evahata tbe EC Jordu ampNaampability 1llt prosram wllkll aaaiMd till appUcabWIY of cartlia ICCbDOIOI tO 1M tfyuD sUamp lltd_ hi Sealoa 50 is a dilaalampioa of tilt ~ cxpatJMtllll dalip aDd procedura u4 dati evaamp-lioL cod~ troe tcdlDOloampY tbulltiaamp _ idaaUIIkatioa of 1lttMr ampe~lilll opttolll Is

-iaSoctloo60

10 QYiRytEW Of J5lMRONMfNIAL CONTAMINADQN

The Nyaua cMekal site is loclted off of Mtpako RCI u4 ~CM~tll ot M SwlbUY NN aM _ Streit ta AMIUd MIIUdiiiMta 11 _ oa Rprc 1middot1 A ore dtlliS view or tbe site is shawl Oil

r Aaure 1middot1 Tbe she wu thl locatiobull of dlalkal _~De~ lldlltilllor 61 )1111 ud il cunudy occvp5ed bJ

- - - DouioiiM 6l portoO - ol- -- shydilpoMd ot oa the Pte indltdina peniltty-trutl4 Pf011 cM~t~kalll_p frCHft tM wu~ewata trtlllftUI ~ IOU4 fKO ta dnabull (tor cMiakal predpltata ucl filter caka) ancl orf-speciftcadol pro4uas PTOCI cMaicU tUt coUd at be rtCI(Ied or rcIMII lnchadina pMDOlDiuob~UeM u4 IDifWrie sutfatc wac aro dilpOIIIl ol oa-litt 1c ampDOlt recent dye rnanldacturct

t1ya011 lac -plod tile sloe- 1965 10 1971 1MJ- shyA--oopdlai-----II 1M slto _be fouo41a llle lDIIampJ4~~=~-sm=~~=nrcoataaiaalt _ dlleded Ia ~~~~ tipdoM at NJUII ar _ ta hbM l-1 tporwat

_ coa~lll-~ Sourlta of Ofpaic udillorpak ooa~IbullUoa Mea 6ecected wltllia tM fonlU propttiJ ttovldampria COIItllliaalioa ol pouldwaltt Ul ocnrr4 Ia boO tbe bedrOCk ~ F1pNI lJ ulll 1 allOW lM attal ateat ol coatalliaatiol fix tc il sol aM Wrodt wdll ~middot heM limits ol CIOIIwaitioa OPical JAUIIJ tepNMAampalM of CMMI CIOIIlliniOCI II well

I I I I

[1 ~1 31 IJII [ r~middotmiddot~I

trlr ~i 1 (f~f l

I

I p UualyMI- oC-111lt ootJOI Millbllt IIIII ampy llllpoltl

UOioampJ-1 CoDtamiDIUid pouoctwawr bullPI to t11 alJrttial to a moor exteftt ta bull oonbettY dircdoa 10WUi M ~Ill) Jliyenel Ml Dow i1 priiMriiY lD U tut) 4irecdOft towani tMIUia put oftMTOWI of~ IM 4alamp aiiO IU mit COIIuaaat 411Uibvllol lD JfOUDdwaU ru be prtMDt II coDCUtnted iDClM4dl plllll llptrimposed 01 I __pl

-------N

OTICE If tfto flho hoage

II IIU clear t h

an

thll

NYANZA C

HE

MIC

AL

W

AST

E

DUHP

notice tt II due to

tht

AD

MIN

IST

RA

TIV

E

RE

CO

RD

qualttr of th

e docuMent

bolng fllbull o4middot

-agt

bull N

Cg

tshy2_1jttzbullbull5

2tti

iili~ ~

gJ

-sectlc

2o

bulltti

Oc

-1 cbull

Nc

~ z I

middot4f - rsS--~

(l

- -

middot

-+= )

-

)

)

---)

_Zl ~ co-bull_ c-o_Ru

~5110

Maxlmlm MCL01 foloof Mlnlmtntt

MCL1 ~ ~llllllol~llllllolQwlilll 39200

IIJQIIIIill 33050 29 (MW-109)0 4 (lloO 1400- 50 lOOO ll

Blri 01000

6 (MW-114 A 302) 33 -Beryllhua 14 (10114)l 302000 II (MW-IOl)

10 2230~middotmiddot

50 100 26 (Ul) 26lColdbullbull ll3~middotmiddot lJOO 90400cdlolt

1000 ~ l20300 l 2(MW-1048) 29 (Oil)roo 73600ldL )(1100 ~- 31050 02 (MW-201)32 (ll10)2 93

100 39l00 2 -N- 12

- 50 IJOOOO _ 1170middotmiddot - 10

l OOO

100000 9 (MW-301) - ll(ll)0 761l00~ 70 40 (36) 12000(MWmiddot98) l 9(MW) 100 l (MW-101) 36 (20)~ 70 23a- 7012middot__ 7 I7l l middot DklaoiOitla)MM 48l

0 3 (3) 600(MWJOlA)9 (MW-2038)

l ll (MWmiddot2048) 2000 2 9 (MW-2041) 2000Tol- 440 I 1JOO1000 l20 (MW-JOlA)Xylnll 2_

---_1-1(-dal GrovedMW CoosaaiDUl Freq ud CoeQIOlna Raa

NyUrampa-iltOI$110

ll(MW-1111) I 30 (MW-IISA) ~-tsladl- 10 (MW-107)l~ S6000 (MW-lllA)

tJamiddotJ)iaOrObeaiampM - bull 19 (MW-30S8)7SO 30 (3) SIOOOO (MW-113A)

14-p-- 41 (11)s 63 (MW-6A)600 610 16

tlo-~nc 3UlODOO(MW-lllA)100 (MW-1048)4-MampIgtyplloool IS SIOO(MW-11)IS (MW-30S8)NiuoliCIUIampM n SS100 (MW-113A)124-TricbiorobeftiCM - I3S (MW-10lt8)11 l30(MW-IISA) 170 (MW-611)

6N_ s 0 189 - 9 (MW-lll8) llmiddotDkhkKOitbaM 100 Ill100 l

111-TriCWofOitUIIamp 0 90 (MW-111) Vi ell- I 650 (MW-1048)ll(MW-117A)Mot~ 10 180 (MW-IIlA)96 (MW-96)1 a-NitMIOmiddotDimiddotbullmiddot 41000(MW-113A) s

ElMlt shyOil(lashy

ottbi eefJQ) 0001 (MW-118) iS (MW-108)

04 1 (37) 016 (MW-IOlA)Hololt I S4(MW-llll) 03S (MW-611)bullbullmiddot-ooT 3 OSS (MW-EAT-15)0011 (MW-IOS)- -IHC l 01 (MW-301)DelcamiddotIHC I 17(MW-9A)Dlol4rin ookgtfdabull Soutc~ Flftll WOfk Plla Jolyaaza 11 - orouactwater Sl14) Dcamber t917

Ortfl Prclilllinlty Suamary o( Site CbatKCriutioO NJUrampIIOIOO_St_ 191amp

1MO bull MM~d- Milia eoa-at tAYtl or EPA MO wtlkbcYCf is lllOfC ltriftstftL

1MCLO bull Mllfllbull eoaIIUMtt lAYtl 0oe1~ o( 63 ~ WIUI tS wdl polaU llllpkcent almbcn ia p~rcotMMS repraeat ~ampmpkl with

-ndoO _ MQ or MQO Wed_ aftM _ lioO ~ Ia - shy

I I

middot~ r

I

I I

) 0 WLIMINMY RfMEPIAl RpoundSPON$E OIJgcnyES

~po oOJoCiiOI for the Nyonu II middot Orobull- StY ~llf1 will be on the potential ror rokS to pbullblk ao4 the ca-roamltnL ~~~po objeCI not nnal and await completion of alltc-specilc tilt aiMU_L KoweYtr bUI4 01 CliltiOI dl~ wveral patbWI)l throuamph which humans

or tht eampMroruacll cou~ be tllpOie4 tO contamlnalll Ia pouactwatu bM been toeatlfiecl

o ttumaa cqu~~te tO coawainall pouactwaW wouP laiUoft Genna contaCt aR40r iobaiatloa if a water aupply aoune if dcwklfl at or bullr tbe 1Ue Ia tJre Mure

o cxpCIItiN 10 cootanUutell pou4WI W0MP 4Lrecl Qermal oonKl witb aDCl iobaltioD a( coowaiaUll lo eqMOYI or vapor lonD -piOI iato relideftdal ~~~ dodpdicnt rroca tbc lite

o u4 ~~tal apcllllfC 10 coocaalDUU froa poctwatcr once It ttiscUraeamp lato

wcda or tbe SuclbUIJ RiYef

Prtlhllinary ruS-1 rcspobull objecliwl tUt td4raamp tbelt poceatial apo~ure pathways inchiCampe

o Utaitilll pracatancl Murc riiD to humans cauMil b) apotUto to ooataminatc4 po~aactwatcr sltffacamp waterl aM -eau

o Ubullltilll deJfldltiol of tM Sltdb~try River aacl wetU41 liltamp to dischltp of coo~iaa- pouftdWiter and

o - appliltlgtbull ao4 rcplltlonl _ and ror PPY

MdltloNI- objeltIIWS may be 10pe4 on dall colleete4 In the Nyonull field intlplloa -middot aM 1M rilt performld bull ptn of tM RlFS

40 1QENDfJCampJON ANQ genNJNO OF DCtfNQIOOIE$

-- o( -middot-middot P- -torY o( tedlootol o(toldpdrll -inatiOn 11 1M Nytnaa _ EP teellnoloampY was evalolled on the - o( _ potclllal delnmiddotbullP -bull bull 11 MCU aod red- 1M potcntiol threat 10 poblllt

lbeuYitoii-L

Treat ~ pocealillly sllitab1 tor tM Nyaua liM wae ldPtifted Nled oa ~middot bull -n o( tM ~til oootaaiaatiol ull prcllnliIJ tctponsc objectiva The tcdtno~ - diYide4 iato ail calfIOI ucl catefMY rqwet~Rtilamp bull pp at re~pomamp actioU tblt covkl ___ -oOJoCiiOI

Sita eoauo1 COIItaillftlftl Treat_ ExtraciiOO

SlltdJIHiftthlll

)

lnncgtbulltll tedlooiOIa were identlllad rltgtntn4or JIIormampIIOD oa4 1ltc Superfloa4 ln_t TclthnOIOI)

Emiddotauadon Pro-= TtchnoloampY Proftlcs fJovember 1919 from tM EPA

42 TECHNOLOGY SCREENINO The laitlll scnertlol of~elthnolOampiOI wos - oa enampirinllelliblllry on4 oppllcobillry to tlto lOCidon or tlto NyortJA olte _ ntlytltotechnolOjlll wore-- oa agtnstroinu Imposelt by the rype or agtatomlnoau -middotc physkll agtn41tOns oltlto ute on4 _ or rettt~inlnl bull rault or tlto uurmenr p- croctcrlstlcl oltlto bullIre thll may or 11m1r tlto eKect_ o 1 tcchnOIOI) obtol - _ ltiptlOno Pbyskll propettY doll oltlto agtatominoau bullliCit olltllity bOiUal polaC -ry worc to oay lbolu Pttgte agtatominoau tbcmKIIIIY lmpaoe oabull ~todlaolOampYmiddot Wbullte ~- ldlatllod todelae - ltor ltlODII waste uatmcaL TiiM ~GftOIOIel wto1t a WM deatt) precluded by Wlll6 or site cUractcriitkl were elimltll rora--loa Tbc ults of this oltOill- _ rtsilmjp(Y Sqscoinl llfllms4i11TKbullIil (-May 1911~ TM ARCS te~a ldlatiGid odditlOnll toe~~aoOjielthll were

not coWdcred la ~ report Tobie 4middot1 Is 1 - o the remediatiOn tcchnoOjllltbat relftll after nln~ Tbc EbUltO-AilCS the )9techaoOjlllllstod oa Tobie 4-1 by-~ prodtKt lltCTIIUIC en4or inOrntltlOn pertonao doll -middot FSbull on4 bullhrobullJh dirlaquo agtnoultotiOO with n40ro A brie dOIltriptlOn of each

-~~-lnToblel-~

50 WASpound 1 ANQ u IRFAItBil m 1QT rsooRAM - Tbc tr0111hlliry _-1bull-to~ re-opodftlt -riOO reprdialthe perlormonlaquo

of--middot-ooiOilabullbull- shy ialtiol scneo~ POIIOtlll ftuncial rlsa on4 delaY lo - KtiOO oro _ with the --of 1 le(hnolOD lOr lmptementotlOn witbOIIt fl WfPOdaamp pcrfonMftCC data For tM uutabUity tCit PfOI-middot on-site bench-5CIIt telll wcro - oo troot-r -aoOjlll ooly II ipiOltoDI lt-1 lalOrmotiOO roprdinl the te(bldOI(i coM dketiyent- Of lrepkmotn~tbility cou4 M obtliaed at a rutOftlble eo~t P-I ud _U oltgte tlbiliry otudy ro-llad OltpDicl rrootmeftl pcctlvltly throop bettdt_ ~ lo ltloD _ relt~bull_ worc ideotltlcd durin the rroatobility otudy ud doll colieltrltd to_ the iDII_t_te otrubull u be to In evoiUitlnl

the applklbilicy o( MYCrtl ~~ tUt were aot btlldlmiddotbullbull From loorntltlOa ptherad ill - otudiOI dtamp woste dllrKterotlcl likely to lmplltt _-implemltDtobillry oadof-lalrroorrtechnolOIIOihbullbullicleifted

ThM -tlcs ladshyldiM rqeegliql middot A all llIIDbtr ol orpak alld iaorpllk contaminanu 1avt bctn ia 1t u- O~ ~~~ crronsmllkdJ to lavotw a ueaU1181 (a CCblalbull ol ubull- ) speorc proccu- oalpcd _ -----middot ()onlla _ shytlfiCdW fCIIiatlM CIOIIllaludoa

Ullf pracW middot Dtftdceciel Ia laflnlbulldol rcatilll 0 Ntk wttfl propen- sd pH oplaquotftlt Mry cooBOD TOC C DOl alii TM Rl ud ueaiblhlJ It~bull ld4rtU theM ~ ao4 flrthct We1Uify lmportut niMCtl li ely to illft lM trfectiveiIM o( UbullUMIIIII at~rNii-

10

--

I )

_ lloos-qSIolt __

Nua a-loll

ROlli tillXJl~

$11tOgtouol XFcaciaiiSP X X

loltihlioUl Coauoll ~- X5latfacc Waw Coluol

~ XCpplbulll XH)dnulkBarrilt Oroddw~MI lalaeeptor T~ftdl X

XFnaOIOIItiqo_ lajocdoll X

_ XtJmiddot

shyX

X =middot X

Wet Alr ()ddadoll1 X

~ XPNdplampl~lioiISediNalldol X -Locll w n~t FtdUa X XOI~WTNa-tFKIMtJ X -Potarilld ~ ()Ddaat ~o~J

DJiilll X sai-Fioill- XTllibull Fla EYapORlioas NltSiripplacc_-loa- X

-~ XMed6l FUusliol X ---X

X X

II

)

I

IJ r

-~ ~- Dnla - (_

lMIIWI IIPDES lllodWJO ~kMIIO Orouftdwltcr

shyDlll-CaUilloll ---middot lelt FUIIr FlloorPIW Onvlty1gtidtal01 v nmtiol

Rcta1M4 xa lfll

X X

X X X

X X

X X X X

1 tucwetM TtcUooD tbat il paR ot EPA Silamp OOMUIioll Proanbull middot turrcatty btiq rldd 1 1M Towll of AIJI)a ot M11 I p11bUdJ opaatcd _let UUIIMilt fidtlty

3 lllMMlM TdiiOkgtD

11

--

----

-I )

lllllo_Z ~ ot Orww Re8ldiadol T_

llyua QcUal Silo

FeocfAtSipl

llldaltioul ColiUOII

~loll Molltortq

Slllflcr Water Cotluol

ClppUit

tfJaiiUc Ianier

Groundwater lnjeaion

Reltrkt ~wt~ fuKll poll watIUill tlpl

11 lud or otMt NllricdoU to proltibh tbc use ol JfOIIIIChILtriiiMIMtilt

EYihaale mlpaliol ud dillriiMaUoll of eo~~~amp~~luaamps Oyener tiiDC ~a~ina 11orina 10 aapll lM CMIHnlal alliS bedroct aquller

ConUOI slllflct waw ru4 owr Ike 1114 lbuefore lallltrat6oa to poundwttar

Pmat iaftltraliiMI ot _doll iiiO coatlaiuted ZOIIII wiU a RCilA 111dtimiddotlayet cap or OlMr cappWc bullterilil

OMrt ltMItMUda pouctwaamper ftow aroud contlmintted zona willa limy Wlwat piliq

ampLiblillrl 1 bedroct ~ _ulictlly bullptradient of the site 10 tower JfOUMwalel dMidoll il coaaaaiuS

Pmut JfOUDdwalef _ tlarotaP COIItlflliMtcd IODa by poutiq Mdrock traura

laect wttrr Into the Jf0111Mh1W to bydnulkllly prevtnt the funhct miJfltioo ot COGtamiauq

ltiuod abulllriull ld 01J111 iiiiO liM JfOUMIWIIer aiGJ I uix of atiKI~ wdll lid redmd1Ui01 amnktues 10 stimulate

~middot- __ _ _ _ICampMIM _or~bull lltIHolopcal NeQOr

(ampJ I trictllq IUICf tOCatilt ~ CIOIIIKtOII)

I)

IIitr 1~

bullbull

) I ~

t~r~

Acrltioft

_ Otf-tlbull wT

FtciiiY

PolarU4 Mlt4iiJ()WolvOd QDdall 1M

()llidbe orpakl ill atJICUIIII pouadMIU willa I llal1tiOCO

applklt of ll~ upt aad a rona oQdilcr

Otatroy orpaic co~wafuall La aa aq~~M~Gtll IOiudOD by iDdMiaJ ollidadoll aiMI laydtolylil reeaiOM at lllP waperauuc aDd prt~Suramp Olyp at ekWUid _ cabaDC tbamp oddat~D of orpak

coapoddlto carbOa diolidamp bullbullmiddot

AI1111C tM lfOIadWatlt 10 ~ iaoJpClk itOft and mlfiMM andmiddot-middot- middot-eo-t dillotvd 10 aa tolubae font (lc metal sulftde W ~or boa aauta) padld tOiiclltiUOUIJI

ftoealladoa settle out IOl6dl ~ plilJmiddot

Dildlotl atroaed --to-- ()wOOdTNat_t WOJIII (POTWl for ubulltbullat Water mISt rr preutbullat llllldl141 bdofC diiCIW 10 tillamp fadlicy

adDente ubullbullbullbullbull _ (sl cartiOII) at aa ol-liw

Killty 1rllff coaUUMII CK (OIICIampIItrtlld wu~ to offmiddotslte (tctlity rot flnhcr ubulltmcnt

Olddizt orpnicS and c~rot)kll~ ftltcr ioM dint ionized OIYfll u4 aiuotta and llltflliokl IJbL

___ - --Ia aM it8ptn-~ Ofkl taps pUtt

coa-w toa bullrx pedwlta bJ liOUiaJ oft WI OOII(IIIItnlioM or VOC SVOO ill a cohama partedwilllt~enbulltlriiL w -doflfaucotbull bull-ait lxltl tllll _ bull plaquo dle - anMfw of VOOJSVOCI frola u oq_ _ shy

I )

~

~t-tiaed)

naiiiampUlliWIIIIilcu-_

loa-middot _ Me4il fltratioa

flltntioa

OfOIwhmpiaamp

Or~ialrucrotptor

llillllll Loodlll

NPOES OllcUrl

Rod---o1- 0lt _ orpako tJuobullP tdiOrpdoa oato paa ~Mwd cartMML Mey be ased u a poUsblaamp ~~ aMr uea~l tla 111 UVOIOUttoll or tir atrippinampW reiDOyenC

~allfdClld CQIIdta

Separate CODCCIUIwd Cl)lllaiUaU rro- mtiClld water ISinabull semimiddot

--- RcmcM bull sol fJOM tlrl WMteWllet iltum by fordbullamp

water nwP a aM tu~a or cartridbullmiddotYfC filter

ttclftOYamp sol aacl bullWI frOil wuaew~tcr auum 111in1 1 mcrnbraM _ fltract pvftdWttcf frOCft Cl Of lfiOfS cstrectiotl - tO CORtrol Of rcWM tM UlkrW CCMI _ Qf0111141w1 wouMI be uealld oa-Mat UUifONd 10 bullbull olaquo-tiw ~licy or diKNrJICllnto ~n lor

-J()IW Colkld JfOIIdwiiCt Ia ~pawl Drtin to allow treampUMIIt to

take pLaee

saare ue~-t rtiM~tamp ( _ thadae ipCil caWft) Ia aa oCImiddot

JtCilA rdliJmiddot OllcUtl P hlw tiM atona draiM ttWU MtfliiOfk or latO 1M ltMf hi tttal OIICraquorp OCitiOI wid M ___ -~u flooltftlotwiUIIoo

to ~toe tM rtetM

lei~ Utamptarou Net Wlwt the JfOIII sinamp OM or ~wtlll

II

)

lfu Use cutrtrpl torce 10 _ tM MdlJMllltioa rate of thtdJI

Dtwaters illldp by dfliUII giDlP lM ahadJC Nil aDd tv~poratioa frolltMwrc IOaitmiddot

()ewaterstl~IC by ~~Mill a coatLa- tuw belt tNt nbull over a drive aDd auide roUir 11uca llld Ukamp I (II)IIW70I MIL Shtdp is cootifliIOampSly diWiwed btCWMI lM IUW bella

otMten lllldfl _ ~ whll ~ Wlef 0 _ - _ - -Uto4-~ dcWitcritll IMlbOdl belli

Reduce tM IOiubull of 11-bull -cwal o( supetnltllll liquMt

Ocwatcn st~ae usiaa bull roampary cbullbullbull nuer

16

)

l l nCHNOLOOlES EVALUAreD l ao4llbelldl IAiiq wu 10 dcmOnsttalCthc cffcttln ol 1 tcthnoloJY In rc4ocinamp

poo-m coataonloanl that Clbt ao Nya to tbe MCUmiddot lie ronowlnamp oclttions daCribC bullbullbull UOIUDIGl ~eotalti~Md aDd lbC raOOoale lor cMIOIIDI ltlCII

lll EMIIJIIIIl l belldlmiddotIAiiq prcclpllltiooftOCltIIlaiiOalc4(tDCnlllioD and oa14atlonlflt40Cilon (-) ttquiR- 1llil wu tloDamp 10 delCrtniDC -1 and ooo41tiODI lor optimum rem o -_colloidal ao4 - - 1bC co11101lnatetl poutcr Hy4_ aetl 101idamp prodpilltiOtiWU -tlpte4 lo tbC PPM llludiiL ()aldatlottftetloctiDI rtqUitemCIII I

pK raaF for optimum metab reatQyenal wM abO bullgttilbOLIt~ IIUlytt preucat-14 be 10 _and rod 110bull conccnttatlons _ Ibull po ao Nyan belorlt othet lampdtoO _be _ Wit preucattneDI inorpnicllllll plbulll ca- _ IQlinl In alfoltripplol __ rod UV cftlclcncicS or ao nely lmpoct bioloPltl --bullbull perlortnl_ will abO tnellb loetli on polbullhlnamp proocUOI (I~ loa ()( rcverM 01100111) A _- o pacoot rlt-la i quoJilll _tiODI o( --lalioo (OrtMiloD led 10 IIIC -tillcatiOO o -F nnp (Or by4- polJIIIC (prodpllltiOO) ltyd-bull pcOildlt (-l icll_ ulllntbCCIeCI -o(lnoltPDicl D-pranpwerlt-olttbe p__ ill _ ll tina Table l middot l - tile tAl roo prod tbe boll r ulll

l ll Olll)llJIIlDurinamp ll lour etlditlonoltcchnololi boftdtmiddotICI oliOOIDI prcucattnCDI o arooICr 10 rc4uca- ampnorpnicl ThiiO lour_ were ioD altOinFo dlft bubble _oo ca____ ___L _ bull-bullbull- olt blllllll

-(LL bull 11rippln1 prior to actlvatc4 ca- Of ICiiVIte4 ca- ollor ___) _etiOI-1--Iol- loO_DF_ te41orinorpa1Crc-looly ea- _aott aoddiffuetl __ _ rororpolc -L BioloampICO__ tawd for botb i801pntt aD4 orpaic rcmovab lie PhiiC ll ideatlllcd tltc need to aetl lmplctneat ucattnCOI mcthOdl lor rc-1 o orpnicl For wmplc combibull bullbullabull 11rippin1 with acttvatc4 carbObull ucatmcat may be n_ary bullroomo cootantloaall arc dgtft~Cullto 11rip but -Uy 10 carbOn Altcrnatly c4 carbOn tniY be a pol~biDI 11cp ~ bioloalel ucatmcat bull cmplo)_ Tablel l-lto l -1 dcocribe Utbullt _ TIMamp 5-1 ilkoliftll tM water ctalily o( ttlamp r- Wllel priot ampa precipiudcm prcucaunenL

U 1Uf OBIECttvES _ o l ao4 ll beodt - 10 middot-- o - -o( ao4 -ubullilllbullbullbullbull pou-tallmpliiOOlshy11 1M tltyaua to beloW MOI TM bulltillamp- abO- 10 _1-middot-_---middot- piClypC o cacUaac - teiCOI ua- TbullriDI- oooductc4 to _ I rltllablt o IM tceJIOlOIYS abnity to _ contambullbullbull Ia the poutcr 11 the tlyaOJO 1111 TM olall col- - 001 iatcndc4 lor cftlclcY

I I I I

r~n hll

middot ll ~~l =~~Irrl l ~lil

f fl I

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 4: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

)

NYANZA OIEMICAI SITE

ntEATABILITY SIJDY EVALUAnON

oPEAABLE UNIT II

ASHLAND MASSAOIUSETIS

JUNE 1990

) WORK ~tGNMENT NO 06-ILlS

NOnCE

------ tM UtS $UWI EPiroAIIWAlll PtoMCltlgta ~ (USIPA) -AilCS I ea- No61--IO--IK (EboOCO~

l TABU 01 co1lt111lt1S

UK

~1ST Of T-BUS bullbullbullbullbullbullbullbullbull bull bull bull bull bull bull bull bull bull bull bull bull bull II~OF FIOUIIES bull bull bull II

nmgtoDucnoN 1 10

OYEJIVIEW OF ENVIRONMENTAL CONTAMINATION bullbullbullbull 10

PREl-IMINARY 11poundMEDW RESPDNSE oaJECI1VES bullbullbullbull bull 30

IOpoundNTIFICATI0N AND SCREENINO OF TECgtINOLOOIES bull 40

41 Tetb~M)k)D 14catUkatioa 9 41Teclo__ 10

PIIASE lAND ll TREATAIIIUTY TEST PROORAM bull bull bull bull bull bull 10

50 Sl TecbaoOiiC EIIIUIIWIL 17 51 Tat ObjeetW bull 1 B Exptri~MDampII oip aDd Proccd1tiCI bull bull 11 54 Tbullt EvaltioM latcrprclltkMI 26

CONCLUSIONS 30 60

urf OF TAIIIJS

Orovodwater CoalaluDt frtllIUitf u4 eocntntiOn Rill 1

1-1 - SaeampDiq SUliWY for orouacr 1dMidialioa Tedutotoael ll _o__ Tpo ll

4-l PrectpicaliOa TreauiiY Daampa bullbull bullbullbull bullbullbullbullbullbull bullbullbullbull bullbull bull 19

H 20 Pbllamp II IUW Water Qarttteriltkl

S-l ll ldlliyen1 EfiiCtiveMI or PUle 11 TN~reDl T~

S-l 12 loa~ middot Tllbiliqt DILl

s ll Dithled ~- middot TbullUibilitJ Data bullbullbull

S-S cano~ - TrallbiliYOra bullbullbull 24

S-6

S-7 __ T -[)ola

= urr OF PIOUUS

l middotl Sloa_-~ middotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotbullmiddotmiddotmiddotmiddotmiddotmiddotmiddotbull middot middotmiddotmiddotmiddot--middot l l-1 - _ Map

l-l TCIIIo~ IOiiWIIII middot loueCoiiiOyen -- S

l_ TCIIIo o- - Wclll bull loUO CoiiiOII bullbullbullbullbullbull 6

middotI

) 10 JNIRODUCDON

Tbe Nyanza II bull Orouodwlttr Remedial ht~tlpdolllftuibiUty Study (RllfS) il the MCOnd of thtec operable uaiampS ldcaliaecl for he Nyaua site ne objeeliWI of tbe Nyua URlFS are to evahate the uturt aid diltrlb~ampdol ot poudniM coawaludol -- tM lilt ueodaled wilb tiUI coa~CiliDilkiD and coa~plete a CellibUcy atu4y or applicable remedJal allcmattvamp Tbe ftnt phaM ot remedial iallltiptloll lbr lM site bu beeA COfllpllted AddhioBII puadwatet IQW~~tlptiou (Ptwc It) aa4 uaociattd rillr aaMtill art cumatty lD _ IM remedial la_tlpUoa aaMllel were coDdICted 11adU he REM Ul coaUK The RIFS repoN will bt completed uDikr the ARCS coatrtCL

AJ put ol tile uuoilloa- 1M REM lll 10 ARCS__ tile ARCS-~~ otudy wllll EC Jordla eompuy penoDKI to obcala uatabWty ~ttdJ daca coDducted SU the REM 111 coatrKl iD support ot RllfS actMU 1il IICUkll meiiDCifUd~ampa il aa Cll~amp~Uol ot MK stiMS u weU 11 u cvalaltkla of DIW UOloi ideatiBell lfacl coaWO ot lM ueatabWIJ lilts

Sectioa 20 of Uil bullmoranclulll proW a summl) dilculltoa of tM coodltton of tbe site inclldiq kgtCltioa lnfcned CllampIU of cotnamludoa aacl type of coetaalaldoa Slttioo l O deCIMI preliminary rcbullbullllal fCI900M objective~ T~ powatiaUy capable ot aidptlq COiltamlulioa 11 the site aad rnectillamp tM Sill re~ponat objecti- are MatiW il SICtiol 40 A brief deleriptioll of cadl ~ udlM statbull atw ~iS abO provided iD SKtioa 40 SectiOa SO dlsnlla and evahata tbe EC Jordu ampNaampability 1llt prosram wllkll aaaiMd till appUcabWIY of cartlia ICCbDOIOI tO 1M tfyuD sUamp lltd_ hi Sealoa 50 is a dilaalampioa of tilt ~ cxpatJMtllll dalip aDd procedura u4 dati evaamp-lioL cod~ troe tcdlDOloampY tbulltiaamp _ idaaUIIkatioa of 1lttMr ampe~lilll opttolll Is

-iaSoctloo60

10 QYiRytEW Of J5lMRONMfNIAL CONTAMINADQN

The Nyaua cMekal site is loclted off of Mtpako RCI u4 ~CM~tll ot M SwlbUY NN aM _ Streit ta AMIUd MIIUdiiiMta 11 _ oa Rprc 1middot1 A ore dtlliS view or tbe site is shawl Oil

r Aaure 1middot1 Tbe she wu thl locatiobull of dlalkal _~De~ lldlltilllor 61 )1111 ud il cunudy occvp5ed bJ

- - - DouioiiM 6l portoO - ol- -- shydilpoMd ot oa the Pte indltdina peniltty-trutl4 Pf011 cM~t~kalll_p frCHft tM wu~ewata trtlllftUI ~ IOU4 fKO ta dnabull (tor cMiakal predpltata ucl filter caka) ancl orf-speciftcadol pro4uas PTOCI cMaicU tUt coUd at be rtCI(Ied or rcIMII lnchadina pMDOlDiuob~UeM u4 IDifWrie sutfatc wac aro dilpOIIIl ol oa-litt 1c ampDOlt recent dye rnanldacturct

t1ya011 lac -plod tile sloe- 1965 10 1971 1MJ- shyA--oopdlai-----II 1M slto _be fouo41a llle lDIIampJ4~~=~-sm=~~=nrcoataaiaalt _ dlleded Ia ~~~~ tipdoM at NJUII ar _ ta hbM l-1 tporwat

_ coa~lll-~ Sourlta of Ofpaic udillorpak ooa~IbullUoa Mea 6ecected wltllia tM fonlU propttiJ ttovldampria COIItllliaalioa ol pouldwaltt Ul ocnrr4 Ia boO tbe bedrOCk ~ F1pNI lJ ulll 1 allOW lM attal ateat ol coatalliaatiol fix tc il sol aM Wrodt wdll ~middot heM limits ol CIOIIwaitioa OPical JAUIIJ tepNMAampalM of CMMI CIOIIlliniOCI II well

I I I I

[1 ~1 31 IJII [ r~middotmiddot~I

trlr ~i 1 (f~f l

I

I p UualyMI- oC-111lt ootJOI Millbllt IIIII ampy llllpoltl

UOioampJ-1 CoDtamiDIUid pouoctwawr bullPI to t11 alJrttial to a moor exteftt ta bull oonbettY dircdoa 10WUi M ~Ill) Jliyenel Ml Dow i1 priiMriiY lD U tut) 4irecdOft towani tMIUia put oftMTOWI of~ IM 4alamp aiiO IU mit COIIuaaat 411Uibvllol lD JfOUDdwaU ru be prtMDt II coDCUtnted iDClM4dl plllll llptrimposed 01 I __pl

-------N

OTICE If tfto flho hoage

II IIU clear t h

an

thll

NYANZA C

HE

MIC

AL

W

AST

E

DUHP

notice tt II due to

tht

AD

MIN

IST

RA

TIV

E

RE

CO

RD

qualttr of th

e docuMent

bolng fllbull o4middot

-agt

bull N

Cg

tshy2_1jttzbullbull5

2tti

iili~ ~

gJ

-sectlc

2o

bulltti

Oc

-1 cbull

Nc

~ z I

middot4f - rsS--~

(l

- -

middot

-+= )

-

)

)

---)

_Zl ~ co-bull_ c-o_Ru

~5110

Maxlmlm MCL01 foloof Mlnlmtntt

MCL1 ~ ~llllllol~llllllolQwlilll 39200

IIJQIIIIill 33050 29 (MW-109)0 4 (lloO 1400- 50 lOOO ll

Blri 01000

6 (MW-114 A 302) 33 -Beryllhua 14 (10114)l 302000 II (MW-IOl)

10 2230~middotmiddot

50 100 26 (Ul) 26lColdbullbull ll3~middotmiddot lJOO 90400cdlolt

1000 ~ l20300 l 2(MW-1048) 29 (Oil)roo 73600ldL )(1100 ~- 31050 02 (MW-201)32 (ll10)2 93

100 39l00 2 -N- 12

- 50 IJOOOO _ 1170middotmiddot - 10

l OOO

100000 9 (MW-301) - ll(ll)0 761l00~ 70 40 (36) 12000(MWmiddot98) l 9(MW) 100 l (MW-101) 36 (20)~ 70 23a- 7012middot__ 7 I7l l middot DklaoiOitla)MM 48l

0 3 (3) 600(MWJOlA)9 (MW-2038)

l ll (MWmiddot2048) 2000 2 9 (MW-2041) 2000Tol- 440 I 1JOO1000 l20 (MW-JOlA)Xylnll 2_

---_1-1(-dal GrovedMW CoosaaiDUl Freq ud CoeQIOlna Raa

NyUrampa-iltOI$110

ll(MW-1111) I 30 (MW-IISA) ~-tsladl- 10 (MW-107)l~ S6000 (MW-lllA)

tJamiddotJ)iaOrObeaiampM - bull 19 (MW-30S8)7SO 30 (3) SIOOOO (MW-113A)

14-p-- 41 (11)s 63 (MW-6A)600 610 16

tlo-~nc 3UlODOO(MW-lllA)100 (MW-1048)4-MampIgtyplloool IS SIOO(MW-11)IS (MW-30S8)NiuoliCIUIampM n SS100 (MW-113A)124-TricbiorobeftiCM - I3S (MW-10lt8)11 l30(MW-IISA) 170 (MW-611)

6N_ s 0 189 - 9 (MW-lll8) llmiddotDkhkKOitbaM 100 Ill100 l

111-TriCWofOitUIIamp 0 90 (MW-111) Vi ell- I 650 (MW-1048)ll(MW-117A)Mot~ 10 180 (MW-IIlA)96 (MW-96)1 a-NitMIOmiddotDimiddotbullmiddot 41000(MW-113A) s

ElMlt shyOil(lashy

ottbi eefJQ) 0001 (MW-118) iS (MW-108)

04 1 (37) 016 (MW-IOlA)Hololt I S4(MW-llll) 03S (MW-611)bullbullmiddot-ooT 3 OSS (MW-EAT-15)0011 (MW-IOS)- -IHC l 01 (MW-301)DelcamiddotIHC I 17(MW-9A)Dlol4rin ookgtfdabull Soutc~ Flftll WOfk Plla Jolyaaza 11 - orouactwater Sl14) Dcamber t917

Ortfl Prclilllinlty Suamary o( Site CbatKCriutioO NJUrampIIOIOO_St_ 191amp

1MO bull MM~d- Milia eoa-at tAYtl or EPA MO wtlkbcYCf is lllOfC ltriftstftL

1MCLO bull Mllfllbull eoaIIUMtt lAYtl 0oe1~ o( 63 ~ WIUI tS wdl polaU llllpkcent almbcn ia p~rcotMMS repraeat ~ampmpkl with

-ndoO _ MQ or MQO Wed_ aftM _ lioO ~ Ia - shy

I I

middot~ r

I

I I

) 0 WLIMINMY RfMEPIAl RpoundSPON$E OIJgcnyES

~po oOJoCiiOI for the Nyonu II middot Orobull- StY ~llf1 will be on the potential ror rokS to pbullblk ao4 the ca-roamltnL ~~~po objeCI not nnal and await completion of alltc-specilc tilt aiMU_L KoweYtr bUI4 01 CliltiOI dl~ wveral patbWI)l throuamph which humans

or tht eampMroruacll cou~ be tllpOie4 tO contamlnalll Ia pouactwatu bM been toeatlfiecl

o ttumaa cqu~~te tO coawainall pouactwaW wouP laiUoft Genna contaCt aR40r iobaiatloa if a water aupply aoune if dcwklfl at or bullr tbe 1Ue Ia tJre Mure

o cxpCIItiN 10 cootanUutell pou4WI W0MP 4Lrecl Qermal oonKl witb aDCl iobaltioD a( coowaiaUll lo eqMOYI or vapor lonD -piOI iato relideftdal ~~~ dodpdicnt rroca tbc lite

o u4 ~~tal apcllllfC 10 coocaalDUU froa poctwatcr once It ttiscUraeamp lato

wcda or tbe SuclbUIJ RiYef

Prtlhllinary ruS-1 rcspobull objecliwl tUt td4raamp tbelt poceatial apo~ure pathways inchiCampe

o Utaitilll pracatancl Murc riiD to humans cauMil b) apotUto to ooataminatc4 po~aactwatcr sltffacamp waterl aM -eau

o Ubullltilll deJfldltiol of tM Sltdb~try River aacl wetU41 liltamp to dischltp of coo~iaa- pouftdWiter and

o - appliltlgtbull ao4 rcplltlonl _ and ror PPY

MdltloNI- objeltIIWS may be 10pe4 on dall colleete4 In the Nyonull field intlplloa -middot aM 1M rilt performld bull ptn of tM RlFS

40 1QENDfJCampJON ANQ genNJNO OF DCtfNQIOOIE$

-- o( -middot-middot P- -torY o( tedlootol o(toldpdrll -inatiOn 11 1M Nytnaa _ EP teellnoloampY was evalolled on the - o( _ potclllal delnmiddotbullP -bull bull 11 MCU aod red- 1M potcntiol threat 10 poblllt

lbeuYitoii-L

Treat ~ pocealillly sllitab1 tor tM Nyaua liM wae ldPtifted Nled oa ~middot bull -n o( tM ~til oootaaiaatiol ull prcllnliIJ tctponsc objectiva The tcdtno~ - diYide4 iato ail calfIOI ucl catefMY rqwet~Rtilamp bull pp at re~pomamp actioU tblt covkl ___ -oOJoCiiOI

Sita eoauo1 COIItaillftlftl Treat_ ExtraciiOO

SlltdJIHiftthlll

)

lnncgtbulltll tedlooiOIa were identlllad rltgtntn4or JIIormampIIOD oa4 1ltc Superfloa4 ln_t TclthnOIOI)

Emiddotauadon Pro-= TtchnoloampY Proftlcs fJovember 1919 from tM EPA

42 TECHNOLOGY SCREENINO The laitlll scnertlol of~elthnolOampiOI wos - oa enampirinllelliblllry on4 oppllcobillry to tlto lOCidon or tlto NyortJA olte _ ntlytltotechnolOjlll wore-- oa agtnstroinu Imposelt by the rype or agtatomlnoau -middotc physkll agtn41tOns oltlto ute on4 _ or rettt~inlnl bull rault or tlto uurmenr p- croctcrlstlcl oltlto bullIre thll may or 11m1r tlto eKect_ o 1 tcchnOIOI) obtol - _ ltiptlOno Pbyskll propettY doll oltlto agtatominoau bullliCit olltllity bOiUal polaC -ry worc to oay lbolu Pttgte agtatominoau tbcmKIIIIY lmpaoe oabull ~todlaolOampYmiddot Wbullte ~- ldlatllod todelae - ltor ltlODII waste uatmcaL TiiM ~GftOIOIel wto1t a WM deatt) precluded by Wlll6 or site cUractcriitkl were elimltll rora--loa Tbc ults of this oltOill- _ rtsilmjp(Y Sqscoinl llfllms4i11TKbullIil (-May 1911~ TM ARCS te~a ldlatiGid odditlOnll toe~~aoOjielthll were

not coWdcred la ~ report Tobie 4middot1 Is 1 - o the remediatiOn tcchnoOjllltbat relftll after nln~ Tbc EbUltO-AilCS the )9techaoOjlllllstod oa Tobie 4-1 by-~ prodtKt lltCTIIUIC en4or inOrntltlOn pertonao doll -middot FSbull on4 bullhrobullJh dirlaquo agtnoultotiOO with n40ro A brie dOIltriptlOn of each

-~~-lnToblel-~

50 WASpound 1 ANQ u IRFAItBil m 1QT rsooRAM - Tbc tr0111hlliry _-1bull-to~ re-opodftlt -riOO reprdialthe perlormonlaquo

of--middot-ooiOilabullbull- shy ialtiol scneo~ POIIOtlll ftuncial rlsa on4 delaY lo - KtiOO oro _ with the --of 1 le(hnolOD lOr lmptementotlOn witbOIIt fl WfPOdaamp pcrfonMftCC data For tM uutabUity tCit PfOI-middot on-site bench-5CIIt telll wcro - oo troot-r -aoOjlll ooly II ipiOltoDI lt-1 lalOrmotiOO roprdinl the te(bldOI(i coM dketiyent- Of lrepkmotn~tbility cou4 M obtliaed at a rutOftlble eo~t P-I ud _U oltgte tlbiliry otudy ro-llad OltpDicl rrootmeftl pcctlvltly throop bettdt_ ~ lo ltloD _ relt~bull_ worc ideotltlcd durin the rroatobility otudy ud doll colieltrltd to_ the iDII_t_te otrubull u be to In evoiUitlnl

the applklbilicy o( MYCrtl ~~ tUt were aot btlldlmiddotbullbull From loorntltlOa ptherad ill - otudiOI dtamp woste dllrKterotlcl likely to lmplltt _-implemltDtobillry oadof-lalrroorrtechnolOIIOihbullbullicleifted

ThM -tlcs ladshyldiM rqeegliql middot A all llIIDbtr ol orpak alld iaorpllk contaminanu 1avt bctn ia 1t u- O~ ~~~ crronsmllkdJ to lavotw a ueaU1181 (a CCblalbull ol ubull- ) speorc proccu- oalpcd _ -----middot ()onlla _ shytlfiCdW fCIIiatlM CIOIIllaludoa

Ullf pracW middot Dtftdceciel Ia laflnlbulldol rcatilll 0 Ntk wttfl propen- sd pH oplaquotftlt Mry cooBOD TOC C DOl alii TM Rl ud ueaiblhlJ It~bull ld4rtU theM ~ ao4 flrthct We1Uify lmportut niMCtl li ely to illft lM trfectiveiIM o( UbullUMIIIII at~rNii-

10

--

I )

_ lloos-qSIolt __

Nua a-loll

ROlli tillXJl~

$11tOgtouol XFcaciaiiSP X X

loltihlioUl Coauoll ~- X5latfacc Waw Coluol

~ XCpplbulll XH)dnulkBarrilt Oroddw~MI lalaeeptor T~ftdl X

XFnaOIOIItiqo_ lajocdoll X

_ XtJmiddot

shyX

X =middot X

Wet Alr ()ddadoll1 X

~ XPNdplampl~lioiISediNalldol X -Locll w n~t FtdUa X XOI~WTNa-tFKIMtJ X -Potarilld ~ ()Ddaat ~o~J

DJiilll X sai-Fioill- XTllibull Fla EYapORlioas NltSiripplacc_-loa- X

-~ XMed6l FUusliol X ---X

X X

II

)

I

IJ r

-~ ~- Dnla - (_

lMIIWI IIPDES lllodWJO ~kMIIO Orouftdwltcr

shyDlll-CaUilloll ---middot lelt FUIIr FlloorPIW Onvlty1gtidtal01 v nmtiol

Rcta1M4 xa lfll

X X

X X X

X X

X X X X

1 tucwetM TtcUooD tbat il paR ot EPA Silamp OOMUIioll Proanbull middot turrcatty btiq rldd 1 1M Towll of AIJI)a ot M11 I p11bUdJ opaatcd _let UUIIMilt fidtlty

3 lllMMlM TdiiOkgtD

11

--

----

-I )

lllllo_Z ~ ot Orww Re8ldiadol T_

llyua QcUal Silo

FeocfAtSipl

llldaltioul ColiUOII

~loll Molltortq

Slllflcr Water Cotluol

ClppUit

tfJaiiUc Ianier

Groundwater lnjeaion

Reltrkt ~wt~ fuKll poll watIUill tlpl

11 lud or otMt NllricdoU to proltibh tbc use ol JfOIIIIChILtriiiMIMtilt

EYihaale mlpaliol ud dillriiMaUoll of eo~~~amp~~luaamps Oyener tiiDC ~a~ina 11orina 10 aapll lM CMIHnlal alliS bedroct aquller

ConUOI slllflct waw ru4 owr Ike 1114 lbuefore lallltrat6oa to poundwttar

Pmat iaftltraliiMI ot _doll iiiO coatlaiuted ZOIIII wiU a RCilA 111dtimiddotlayet cap or OlMr cappWc bullterilil

OMrt ltMItMUda pouctwaamper ftow aroud contlmintted zona willa limy Wlwat piliq

ampLiblillrl 1 bedroct ~ _ulictlly bullptradient of the site 10 tower JfOUMwalel dMidoll il coaaaaiuS

Pmut JfOUDdwalef _ tlarotaP COIItlflliMtcd IODa by poutiq Mdrock traura

laect wttrr Into the Jf0111Mh1W to bydnulkllly prevtnt the funhct miJfltioo ot COGtamiauq

ltiuod abulllriull ld 01J111 iiiiO liM JfOUMIWIIer aiGJ I uix of atiKI~ wdll lid redmd1Ui01 amnktues 10 stimulate

~middot- __ _ _ _ICampMIM _or~bull lltIHolopcal NeQOr

(ampJ I trictllq IUICf tOCatilt ~ CIOIIIKtOII)

I)

IIitr 1~

bullbull

) I ~

t~r~

Acrltioft

_ Otf-tlbull wT

FtciiiY

PolarU4 Mlt4iiJ()WolvOd QDdall 1M

()llidbe orpakl ill atJICUIIII pouadMIU willa I llal1tiOCO

applklt of ll~ upt aad a rona oQdilcr

Otatroy orpaic co~wafuall La aa aq~~M~Gtll IOiudOD by iDdMiaJ ollidadoll aiMI laydtolylil reeaiOM at lllP waperauuc aDd prt~Suramp Olyp at ekWUid _ cabaDC tbamp oddat~D of orpak

coapoddlto carbOa diolidamp bullbullmiddot

AI1111C tM lfOIadWatlt 10 ~ iaoJpClk itOft and mlfiMM andmiddot-middot- middot-eo-t dillotvd 10 aa tolubae font (lc metal sulftde W ~or boa aauta) padld tOiiclltiUOUIJI

ftoealladoa settle out IOl6dl ~ plilJmiddot

Dildlotl atroaed --to-- ()wOOdTNat_t WOJIII (POTWl for ubulltbullat Water mISt rr preutbullat llllldl141 bdofC diiCIW 10 tillamp fadlicy

adDente ubullbullbullbullbull _ (sl cartiOII) at aa ol-liw

Killty 1rllff coaUUMII CK (OIICIampIItrtlld wu~ to offmiddotslte (tctlity rot flnhcr ubulltmcnt

Olddizt orpnicS and c~rot)kll~ ftltcr ioM dint ionized OIYfll u4 aiuotta and llltflliokl IJbL

___ - --Ia aM it8ptn-~ Ofkl taps pUtt

coa-w toa bullrx pedwlta bJ liOUiaJ oft WI OOII(IIIItnlioM or VOC SVOO ill a cohama partedwilllt~enbulltlriiL w -doflfaucotbull bull-ait lxltl tllll _ bull plaquo dle - anMfw of VOOJSVOCI frola u oq_ _ shy

I )

~

~t-tiaed)

naiiiampUlliWIIIIilcu-_

loa-middot _ Me4il fltratioa

flltntioa

OfOIwhmpiaamp

Or~ialrucrotptor

llillllll Loodlll

NPOES OllcUrl

Rod---o1- 0lt _ orpako tJuobullP tdiOrpdoa oato paa ~Mwd cartMML Mey be ased u a poUsblaamp ~~ aMr uea~l tla 111 UVOIOUttoll or tir atrippinampW reiDOyenC

~allfdClld CQIIdta

Separate CODCCIUIwd Cl)lllaiUaU rro- mtiClld water ISinabull semimiddot

--- RcmcM bull sol fJOM tlrl WMteWllet iltum by fordbullamp

water nwP a aM tu~a or cartridbullmiddotYfC filter

ttclftOYamp sol aacl bullWI frOil wuaew~tcr auum 111in1 1 mcrnbraM _ fltract pvftdWttcf frOCft Cl Of lfiOfS cstrectiotl - tO CORtrol Of rcWM tM UlkrW CCMI _ Qf0111141w1 wouMI be uealld oa-Mat UUifONd 10 bullbull olaquo-tiw ~licy or diKNrJICllnto ~n lor

-J()IW Colkld JfOIIdwiiCt Ia ~pawl Drtin to allow treampUMIIt to

take pLaee

saare ue~-t rtiM~tamp ( _ thadae ipCil caWft) Ia aa oCImiddot

JtCilA rdliJmiddot OllcUtl P hlw tiM atona draiM ttWU MtfliiOfk or latO 1M ltMf hi tttal OIICraquorp OCitiOI wid M ___ -~u flooltftlotwiUIIoo

to ~toe tM rtetM

lei~ Utamptarou Net Wlwt the JfOIII sinamp OM or ~wtlll

II

)

lfu Use cutrtrpl torce 10 _ tM MdlJMllltioa rate of thtdJI

Dtwaters illldp by dfliUII giDlP lM ahadJC Nil aDd tv~poratioa frolltMwrc IOaitmiddot

()ewaterstl~IC by ~~Mill a coatLa- tuw belt tNt nbull over a drive aDd auide roUir 11uca llld Ukamp I (II)IIW70I MIL Shtdp is cootifliIOampSly diWiwed btCWMI lM IUW bella

otMten lllldfl _ ~ whll ~ Wlef 0 _ - _ - -Uto4-~ dcWitcritll IMlbOdl belli

Reduce tM IOiubull of 11-bull -cwal o( supetnltllll liquMt

Ocwatcn st~ae usiaa bull roampary cbullbullbull nuer

16

)

l l nCHNOLOOlES EVALUAreD l ao4llbelldl IAiiq wu 10 dcmOnsttalCthc cffcttln ol 1 tcthnoloJY In rc4ocinamp

poo-m coataonloanl that Clbt ao Nya to tbe MCUmiddot lie ronowlnamp oclttions daCribC bullbullbull UOIUDIGl ~eotalti~Md aDd lbC raOOoale lor cMIOIIDI ltlCII

lll EMIIJIIIIl l belldlmiddotIAiiq prcclpllltiooftOCltIIlaiiOalc4(tDCnlllioD and oa14atlonlflt40Cilon (-) ttquiR- 1llil wu tloDamp 10 delCrtniDC -1 and ooo41tiODI lor optimum rem o -_colloidal ao4 - - 1bC co11101lnatetl poutcr Hy4_ aetl 101idamp prodpilltiOtiWU -tlpte4 lo tbC PPM llludiiL ()aldatlottftetloctiDI rtqUitemCIII I

pK raaF for optimum metab reatQyenal wM abO bullgttilbOLIt~ IIUlytt preucat-14 be 10 _and rod 110bull conccnttatlons _ Ibull po ao Nyan belorlt othet lampdtoO _be _ Wit preucattneDI inorpnicllllll plbulll ca- _ IQlinl In alfoltripplol __ rod UV cftlclcncicS or ao nely lmpoct bioloPltl --bullbull perlortnl_ will abO tnellb loetli on polbullhlnamp proocUOI (I~ loa ()( rcverM 01100111) A _- o pacoot rlt-la i quoJilll _tiODI o( --lalioo (OrtMiloD led 10 IIIC -tillcatiOO o -F nnp (Or by4- polJIIIC (prodpllltiOO) ltyd-bull pcOildlt (-l icll_ ulllntbCCIeCI -o(lnoltPDicl D-pranpwerlt-olttbe p__ ill _ ll tina Table l middot l - tile tAl roo prod tbe boll r ulll

l ll Olll)llJIIlDurinamp ll lour etlditlonoltcchnololi boftdtmiddotICI oliOOIDI prcucattnCDI o arooICr 10 rc4uca- ampnorpnicl ThiiO lour_ were ioD altOinFo dlft bubble _oo ca____ ___L _ bull-bullbull- olt blllllll

-(LL bull 11rippln1 prior to actlvatc4 ca- Of ICiiVIte4 ca- ollor ___) _etiOI-1--Iol- loO_DF_ te41orinorpa1Crc-looly ea- _aott aoddiffuetl __ _ rororpolc -L BioloampICO__ tawd for botb i801pntt aD4 orpaic rcmovab lie PhiiC ll ideatlllcd tltc need to aetl lmplctneat ucattnCOI mcthOdl lor rc-1 o orpnicl For wmplc combibull bullbullabull 11rippin1 with acttvatc4 carbObull ucatmcat may be n_ary bullroomo cootantloaall arc dgtft~Cullto 11rip but -Uy 10 carbOn Altcrnatly c4 carbOn tniY be a pol~biDI 11cp ~ bioloalel ucatmcat bull cmplo)_ Tablel l-lto l -1 dcocribe Utbullt _ TIMamp 5-1 ilkoliftll tM water ctalily o( ttlamp r- Wllel priot ampa precipiudcm prcucaunenL

U 1Uf OBIECttvES _ o l ao4 ll beodt - 10 middot-- o - -o( ao4 -ubullilllbullbullbullbull pou-tallmpliiOOlshy11 1M tltyaua to beloW MOI TM bulltillamp- abO- 10 _1-middot-_---middot- piClypC o cacUaac - teiCOI ua- TbullriDI- oooductc4 to _ I rltllablt o IM tceJIOlOIYS abnity to _ contambullbullbull Ia the poutcr 11 the tlyaOJO 1111 TM olall col- - 001 iatcndc4 lor cftlclcY

I I I I

r~n hll

middot ll ~~l =~~Irrl l ~lil

f fl I

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 5: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

l TABU 01 co1lt111lt1S

UK

~1ST Of T-BUS bullbullbullbullbullbullbullbullbull bull bull bull bull bull bull bull bull bull bull bull bull bull II~OF FIOUIIES bull bull bull II

nmgtoDucnoN 1 10

OYEJIVIEW OF ENVIRONMENTAL CONTAMINATION bullbullbullbull 10

PREl-IMINARY 11poundMEDW RESPDNSE oaJECI1VES bullbullbullbull bull 30

IOpoundNTIFICATI0N AND SCREENINO OF TECgtINOLOOIES bull 40

41 Tetb~M)k)D 14catUkatioa 9 41Teclo__ 10

PIIASE lAND ll TREATAIIIUTY TEST PROORAM bull bull bull bull bull bull 10

50 Sl TecbaoOiiC EIIIUIIWIL 17 51 Tat ObjeetW bull 1 B Exptri~MDampII oip aDd Proccd1tiCI bull bull 11 54 Tbullt EvaltioM latcrprclltkMI 26

CONCLUSIONS 30 60

urf OF TAIIIJS

Orovodwater CoalaluDt frtllIUitf u4 eocntntiOn Rill 1

1-1 - SaeampDiq SUliWY for orouacr 1dMidialioa Tedutotoael ll _o__ Tpo ll

4-l PrectpicaliOa TreauiiY Daampa bullbull bullbullbull bullbullbullbullbullbull bullbullbullbull bullbull bull 19

H 20 Pbllamp II IUW Water Qarttteriltkl

S-l ll ldlliyen1 EfiiCtiveMI or PUle 11 TN~reDl T~

S-l 12 loa~ middot Tllbiliqt DILl

s ll Dithled ~- middot TbullUibilitJ Data bullbullbull

S-S cano~ - TrallbiliYOra bullbullbull 24

S-6

S-7 __ T -[)ola

= urr OF PIOUUS

l middotl Sloa_-~ middotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotbullmiddotmiddotmiddotmiddotmiddotmiddotmiddotbull middot middotmiddotmiddotmiddot--middot l l-1 - _ Map

l-l TCIIIo~ IOiiWIIII middot loueCoiiiOyen -- S

l_ TCIIIo o- - Wclll bull loUO CoiiiOII bullbullbullbullbullbull 6

middotI

) 10 JNIRODUCDON

Tbe Nyanza II bull Orouodwlttr Remedial ht~tlpdolllftuibiUty Study (RllfS) il the MCOnd of thtec operable uaiampS ldcaliaecl for he Nyaua site ne objeeliWI of tbe Nyua URlFS are to evahate the uturt aid diltrlb~ampdol ot poudniM coawaludol -- tM lilt ueodaled wilb tiUI coa~CiliDilkiD and coa~plete a CellibUcy atu4y or applicable remedJal allcmattvamp Tbe ftnt phaM ot remedial iallltiptloll lbr lM site bu beeA COfllpllted AddhioBII puadwatet IQW~~tlptiou (Ptwc It) aa4 uaociattd rillr aaMtill art cumatty lD _ IM remedial la_tlpUoa aaMllel were coDdICted 11adU he REM Ul coaUK The RIFS repoN will bt completed uDikr the ARCS coatrtCL

AJ put ol tile uuoilloa- 1M REM lll 10 ARCS__ tile ARCS-~~ otudy wllll EC Jordla eompuy penoDKI to obcala uatabWty ~ttdJ daca coDducted SU the REM 111 coatrKl iD support ot RllfS actMU 1il IICUkll meiiDCifUd~ampa il aa Cll~amp~Uol ot MK stiMS u weU 11 u cvalaltkla of DIW UOloi ideatiBell lfacl coaWO ot lM ueatabWIJ lilts

Sectioa 20 of Uil bullmoranclulll proW a summl) dilculltoa of tM coodltton of tbe site inclldiq kgtCltioa lnfcned CllampIU of cotnamludoa aacl type of coetaalaldoa Slttioo l O deCIMI preliminary rcbullbullllal fCI900M objective~ T~ powatiaUy capable ot aidptlq COiltamlulioa 11 the site aad rnectillamp tM Sill re~ponat objecti- are MatiW il SICtiol 40 A brief deleriptioll of cadl ~ udlM statbull atw ~iS abO provided iD SKtioa 40 SectiOa SO dlsnlla and evahata tbe EC Jordu ampNaampability 1llt prosram wllkll aaaiMd till appUcabWIY of cartlia ICCbDOIOI tO 1M tfyuD sUamp lltd_ hi Sealoa 50 is a dilaalampioa of tilt ~ cxpatJMtllll dalip aDd procedura u4 dati evaamp-lioL cod~ troe tcdlDOloampY tbulltiaamp _ idaaUIIkatioa of 1lttMr ampe~lilll opttolll Is

-iaSoctloo60

10 QYiRytEW Of J5lMRONMfNIAL CONTAMINADQN

The Nyaua cMekal site is loclted off of Mtpako RCI u4 ~CM~tll ot M SwlbUY NN aM _ Streit ta AMIUd MIIUdiiiMta 11 _ oa Rprc 1middot1 A ore dtlliS view or tbe site is shawl Oil

r Aaure 1middot1 Tbe she wu thl locatiobull of dlalkal _~De~ lldlltilllor 61 )1111 ud il cunudy occvp5ed bJ

- - - DouioiiM 6l portoO - ol- -- shydilpoMd ot oa the Pte indltdina peniltty-trutl4 Pf011 cM~t~kalll_p frCHft tM wu~ewata trtlllftUI ~ IOU4 fKO ta dnabull (tor cMiakal predpltata ucl filter caka) ancl orf-speciftcadol pro4uas PTOCI cMaicU tUt coUd at be rtCI(Ied or rcIMII lnchadina pMDOlDiuob~UeM u4 IDifWrie sutfatc wac aro dilpOIIIl ol oa-litt 1c ampDOlt recent dye rnanldacturct

t1ya011 lac -plod tile sloe- 1965 10 1971 1MJ- shyA--oopdlai-----II 1M slto _be fouo41a llle lDIIampJ4~~=~-sm=~~=nrcoataaiaalt _ dlleded Ia ~~~~ tipdoM at NJUII ar _ ta hbM l-1 tporwat

_ coa~lll-~ Sourlta of Ofpaic udillorpak ooa~IbullUoa Mea 6ecected wltllia tM fonlU propttiJ ttovldampria COIItllliaalioa ol pouldwaltt Ul ocnrr4 Ia boO tbe bedrOCk ~ F1pNI lJ ulll 1 allOW lM attal ateat ol coatalliaatiol fix tc il sol aM Wrodt wdll ~middot heM limits ol CIOIIwaitioa OPical JAUIIJ tepNMAampalM of CMMI CIOIIlliniOCI II well

I I I I

[1 ~1 31 IJII [ r~middotmiddot~I

trlr ~i 1 (f~f l

I

I p UualyMI- oC-111lt ootJOI Millbllt IIIII ampy llllpoltl

UOioampJ-1 CoDtamiDIUid pouoctwawr bullPI to t11 alJrttial to a moor exteftt ta bull oonbettY dircdoa 10WUi M ~Ill) Jliyenel Ml Dow i1 priiMriiY lD U tut) 4irecdOft towani tMIUia put oftMTOWI of~ IM 4alamp aiiO IU mit COIIuaaat 411Uibvllol lD JfOUDdwaU ru be prtMDt II coDCUtnted iDClM4dl plllll llptrimposed 01 I __pl

-------N

OTICE If tfto flho hoage

II IIU clear t h

an

thll

NYANZA C

HE

MIC

AL

W

AST

E

DUHP

notice tt II due to

tht

AD

MIN

IST

RA

TIV

E

RE

CO

RD

qualttr of th

e docuMent

bolng fllbull o4middot

-agt

bull N

Cg

tshy2_1jttzbullbull5

2tti

iili~ ~

gJ

-sectlc

2o

bulltti

Oc

-1 cbull

Nc

~ z I

middot4f - rsS--~

(l

- -

middot

-+= )

-

)

)

---)

_Zl ~ co-bull_ c-o_Ru

~5110

Maxlmlm MCL01 foloof Mlnlmtntt

MCL1 ~ ~llllllol~llllllolQwlilll 39200

IIJQIIIIill 33050 29 (MW-109)0 4 (lloO 1400- 50 lOOO ll

Blri 01000

6 (MW-114 A 302) 33 -Beryllhua 14 (10114)l 302000 II (MW-IOl)

10 2230~middotmiddot

50 100 26 (Ul) 26lColdbullbull ll3~middotmiddot lJOO 90400cdlolt

1000 ~ l20300 l 2(MW-1048) 29 (Oil)roo 73600ldL )(1100 ~- 31050 02 (MW-201)32 (ll10)2 93

100 39l00 2 -N- 12

- 50 IJOOOO _ 1170middotmiddot - 10

l OOO

100000 9 (MW-301) - ll(ll)0 761l00~ 70 40 (36) 12000(MWmiddot98) l 9(MW) 100 l (MW-101) 36 (20)~ 70 23a- 7012middot__ 7 I7l l middot DklaoiOitla)MM 48l

0 3 (3) 600(MWJOlA)9 (MW-2038)

l ll (MWmiddot2048) 2000 2 9 (MW-2041) 2000Tol- 440 I 1JOO1000 l20 (MW-JOlA)Xylnll 2_

---_1-1(-dal GrovedMW CoosaaiDUl Freq ud CoeQIOlna Raa

NyUrampa-iltOI$110

ll(MW-1111) I 30 (MW-IISA) ~-tsladl- 10 (MW-107)l~ S6000 (MW-lllA)

tJamiddotJ)iaOrObeaiampM - bull 19 (MW-30S8)7SO 30 (3) SIOOOO (MW-113A)

14-p-- 41 (11)s 63 (MW-6A)600 610 16

tlo-~nc 3UlODOO(MW-lllA)100 (MW-1048)4-MampIgtyplloool IS SIOO(MW-11)IS (MW-30S8)NiuoliCIUIampM n SS100 (MW-113A)124-TricbiorobeftiCM - I3S (MW-10lt8)11 l30(MW-IISA) 170 (MW-611)

6N_ s 0 189 - 9 (MW-lll8) llmiddotDkhkKOitbaM 100 Ill100 l

111-TriCWofOitUIIamp 0 90 (MW-111) Vi ell- I 650 (MW-1048)ll(MW-117A)Mot~ 10 180 (MW-IIlA)96 (MW-96)1 a-NitMIOmiddotDimiddotbullmiddot 41000(MW-113A) s

ElMlt shyOil(lashy

ottbi eefJQ) 0001 (MW-118) iS (MW-108)

04 1 (37) 016 (MW-IOlA)Hololt I S4(MW-llll) 03S (MW-611)bullbullmiddot-ooT 3 OSS (MW-EAT-15)0011 (MW-IOS)- -IHC l 01 (MW-301)DelcamiddotIHC I 17(MW-9A)Dlol4rin ookgtfdabull Soutc~ Flftll WOfk Plla Jolyaaza 11 - orouactwater Sl14) Dcamber t917

Ortfl Prclilllinlty Suamary o( Site CbatKCriutioO NJUrampIIOIOO_St_ 191amp

1MO bull MM~d- Milia eoa-at tAYtl or EPA MO wtlkbcYCf is lllOfC ltriftstftL

1MCLO bull Mllfllbull eoaIIUMtt lAYtl 0oe1~ o( 63 ~ WIUI tS wdl polaU llllpkcent almbcn ia p~rcotMMS repraeat ~ampmpkl with

-ndoO _ MQ or MQO Wed_ aftM _ lioO ~ Ia - shy

I I

middot~ r

I

I I

) 0 WLIMINMY RfMEPIAl RpoundSPON$E OIJgcnyES

~po oOJoCiiOI for the Nyonu II middot Orobull- StY ~llf1 will be on the potential ror rokS to pbullblk ao4 the ca-roamltnL ~~~po objeCI not nnal and await completion of alltc-specilc tilt aiMU_L KoweYtr bUI4 01 CliltiOI dl~ wveral patbWI)l throuamph which humans

or tht eampMroruacll cou~ be tllpOie4 tO contamlnalll Ia pouactwatu bM been toeatlfiecl

o ttumaa cqu~~te tO coawainall pouactwaW wouP laiUoft Genna contaCt aR40r iobaiatloa if a water aupply aoune if dcwklfl at or bullr tbe 1Ue Ia tJre Mure

o cxpCIItiN 10 cootanUutell pou4WI W0MP 4Lrecl Qermal oonKl witb aDCl iobaltioD a( coowaiaUll lo eqMOYI or vapor lonD -piOI iato relideftdal ~~~ dodpdicnt rroca tbc lite

o u4 ~~tal apcllllfC 10 coocaalDUU froa poctwatcr once It ttiscUraeamp lato

wcda or tbe SuclbUIJ RiYef

Prtlhllinary ruS-1 rcspobull objecliwl tUt td4raamp tbelt poceatial apo~ure pathways inchiCampe

o Utaitilll pracatancl Murc riiD to humans cauMil b) apotUto to ooataminatc4 po~aactwatcr sltffacamp waterl aM -eau

o Ubullltilll deJfldltiol of tM Sltdb~try River aacl wetU41 liltamp to dischltp of coo~iaa- pouftdWiter and

o - appliltlgtbull ao4 rcplltlonl _ and ror PPY

MdltloNI- objeltIIWS may be 10pe4 on dall colleete4 In the Nyonull field intlplloa -middot aM 1M rilt performld bull ptn of tM RlFS

40 1QENDfJCampJON ANQ genNJNO OF DCtfNQIOOIE$

-- o( -middot-middot P- -torY o( tedlootol o(toldpdrll -inatiOn 11 1M Nytnaa _ EP teellnoloampY was evalolled on the - o( _ potclllal delnmiddotbullP -bull bull 11 MCU aod red- 1M potcntiol threat 10 poblllt

lbeuYitoii-L

Treat ~ pocealillly sllitab1 tor tM Nyaua liM wae ldPtifted Nled oa ~middot bull -n o( tM ~til oootaaiaatiol ull prcllnliIJ tctponsc objectiva The tcdtno~ - diYide4 iato ail calfIOI ucl catefMY rqwet~Rtilamp bull pp at re~pomamp actioU tblt covkl ___ -oOJoCiiOI

Sita eoauo1 COIItaillftlftl Treat_ ExtraciiOO

SlltdJIHiftthlll

)

lnncgtbulltll tedlooiOIa were identlllad rltgtntn4or JIIormampIIOD oa4 1ltc Superfloa4 ln_t TclthnOIOI)

Emiddotauadon Pro-= TtchnoloampY Proftlcs fJovember 1919 from tM EPA

42 TECHNOLOGY SCREENINO The laitlll scnertlol of~elthnolOampiOI wos - oa enampirinllelliblllry on4 oppllcobillry to tlto lOCidon or tlto NyortJA olte _ ntlytltotechnolOjlll wore-- oa agtnstroinu Imposelt by the rype or agtatomlnoau -middotc physkll agtn41tOns oltlto ute on4 _ or rettt~inlnl bull rault or tlto uurmenr p- croctcrlstlcl oltlto bullIre thll may or 11m1r tlto eKect_ o 1 tcchnOIOI) obtol - _ ltiptlOno Pbyskll propettY doll oltlto agtatominoau bullliCit olltllity bOiUal polaC -ry worc to oay lbolu Pttgte agtatominoau tbcmKIIIIY lmpaoe oabull ~todlaolOampYmiddot Wbullte ~- ldlatllod todelae - ltor ltlODII waste uatmcaL TiiM ~GftOIOIel wto1t a WM deatt) precluded by Wlll6 or site cUractcriitkl were elimltll rora--loa Tbc ults of this oltOill- _ rtsilmjp(Y Sqscoinl llfllms4i11TKbullIil (-May 1911~ TM ARCS te~a ldlatiGid odditlOnll toe~~aoOjielthll were

not coWdcred la ~ report Tobie 4middot1 Is 1 - o the remediatiOn tcchnoOjllltbat relftll after nln~ Tbc EbUltO-AilCS the )9techaoOjlllllstod oa Tobie 4-1 by-~ prodtKt lltCTIIUIC en4or inOrntltlOn pertonao doll -middot FSbull on4 bullhrobullJh dirlaquo agtnoultotiOO with n40ro A brie dOIltriptlOn of each

-~~-lnToblel-~

50 WASpound 1 ANQ u IRFAItBil m 1QT rsooRAM - Tbc tr0111hlliry _-1bull-to~ re-opodftlt -riOO reprdialthe perlormonlaquo

of--middot-ooiOilabullbull- shy ialtiol scneo~ POIIOtlll ftuncial rlsa on4 delaY lo - KtiOO oro _ with the --of 1 le(hnolOD lOr lmptementotlOn witbOIIt fl WfPOdaamp pcrfonMftCC data For tM uutabUity tCit PfOI-middot on-site bench-5CIIt telll wcro - oo troot-r -aoOjlll ooly II ipiOltoDI lt-1 lalOrmotiOO roprdinl the te(bldOI(i coM dketiyent- Of lrepkmotn~tbility cou4 M obtliaed at a rutOftlble eo~t P-I ud _U oltgte tlbiliry otudy ro-llad OltpDicl rrootmeftl pcctlvltly throop bettdt_ ~ lo ltloD _ relt~bull_ worc ideotltlcd durin the rroatobility otudy ud doll colieltrltd to_ the iDII_t_te otrubull u be to In evoiUitlnl

the applklbilicy o( MYCrtl ~~ tUt were aot btlldlmiddotbullbull From loorntltlOa ptherad ill - otudiOI dtamp woste dllrKterotlcl likely to lmplltt _-implemltDtobillry oadof-lalrroorrtechnolOIIOihbullbullicleifted

ThM -tlcs ladshyldiM rqeegliql middot A all llIIDbtr ol orpak alld iaorpllk contaminanu 1avt bctn ia 1t u- O~ ~~~ crronsmllkdJ to lavotw a ueaU1181 (a CCblalbull ol ubull- ) speorc proccu- oalpcd _ -----middot ()onlla _ shytlfiCdW fCIIiatlM CIOIIllaludoa

Ullf pracW middot Dtftdceciel Ia laflnlbulldol rcatilll 0 Ntk wttfl propen- sd pH oplaquotftlt Mry cooBOD TOC C DOl alii TM Rl ud ueaiblhlJ It~bull ld4rtU theM ~ ao4 flrthct We1Uify lmportut niMCtl li ely to illft lM trfectiveiIM o( UbullUMIIIII at~rNii-

10

--

I )

_ lloos-qSIolt __

Nua a-loll

ROlli tillXJl~

$11tOgtouol XFcaciaiiSP X X

loltihlioUl Coauoll ~- X5latfacc Waw Coluol

~ XCpplbulll XH)dnulkBarrilt Oroddw~MI lalaeeptor T~ftdl X

XFnaOIOIItiqo_ lajocdoll X

_ XtJmiddot

shyX

X =middot X

Wet Alr ()ddadoll1 X

~ XPNdplampl~lioiISediNalldol X -Locll w n~t FtdUa X XOI~WTNa-tFKIMtJ X -Potarilld ~ ()Ddaat ~o~J

DJiilll X sai-Fioill- XTllibull Fla EYapORlioas NltSiripplacc_-loa- X

-~ XMed6l FUusliol X ---X

X X

II

)

I

IJ r

-~ ~- Dnla - (_

lMIIWI IIPDES lllodWJO ~kMIIO Orouftdwltcr

shyDlll-CaUilloll ---middot lelt FUIIr FlloorPIW Onvlty1gtidtal01 v nmtiol

Rcta1M4 xa lfll

X X

X X X

X X

X X X X

1 tucwetM TtcUooD tbat il paR ot EPA Silamp OOMUIioll Proanbull middot turrcatty btiq rldd 1 1M Towll of AIJI)a ot M11 I p11bUdJ opaatcd _let UUIIMilt fidtlty

3 lllMMlM TdiiOkgtD

11

--

----

-I )

lllllo_Z ~ ot Orww Re8ldiadol T_

llyua QcUal Silo

FeocfAtSipl

llldaltioul ColiUOII

~loll Molltortq

Slllflcr Water Cotluol

ClppUit

tfJaiiUc Ianier

Groundwater lnjeaion

Reltrkt ~wt~ fuKll poll watIUill tlpl

11 lud or otMt NllricdoU to proltibh tbc use ol JfOIIIIChILtriiiMIMtilt

EYihaale mlpaliol ud dillriiMaUoll of eo~~~amp~~luaamps Oyener tiiDC ~a~ina 11orina 10 aapll lM CMIHnlal alliS bedroct aquller

ConUOI slllflct waw ru4 owr Ike 1114 lbuefore lallltrat6oa to poundwttar

Pmat iaftltraliiMI ot _doll iiiO coatlaiuted ZOIIII wiU a RCilA 111dtimiddotlayet cap or OlMr cappWc bullterilil

OMrt ltMItMUda pouctwaamper ftow aroud contlmintted zona willa limy Wlwat piliq

ampLiblillrl 1 bedroct ~ _ulictlly bullptradient of the site 10 tower JfOUMwalel dMidoll il coaaaaiuS

Pmut JfOUDdwalef _ tlarotaP COIItlflliMtcd IODa by poutiq Mdrock traura

laect wttrr Into the Jf0111Mh1W to bydnulkllly prevtnt the funhct miJfltioo ot COGtamiauq

ltiuod abulllriull ld 01J111 iiiiO liM JfOUMIWIIer aiGJ I uix of atiKI~ wdll lid redmd1Ui01 amnktues 10 stimulate

~middot- __ _ _ _ICampMIM _or~bull lltIHolopcal NeQOr

(ampJ I trictllq IUICf tOCatilt ~ CIOIIIKtOII)

I)

IIitr 1~

bullbull

) I ~

t~r~

Acrltioft

_ Otf-tlbull wT

FtciiiY

PolarU4 Mlt4iiJ()WolvOd QDdall 1M

()llidbe orpakl ill atJICUIIII pouadMIU willa I llal1tiOCO

applklt of ll~ upt aad a rona oQdilcr

Otatroy orpaic co~wafuall La aa aq~~M~Gtll IOiudOD by iDdMiaJ ollidadoll aiMI laydtolylil reeaiOM at lllP waperauuc aDd prt~Suramp Olyp at ekWUid _ cabaDC tbamp oddat~D of orpak

coapoddlto carbOa diolidamp bullbullmiddot

AI1111C tM lfOIadWatlt 10 ~ iaoJpClk itOft and mlfiMM andmiddot-middot- middot-eo-t dillotvd 10 aa tolubae font (lc metal sulftde W ~or boa aauta) padld tOiiclltiUOUIJI

ftoealladoa settle out IOl6dl ~ plilJmiddot

Dildlotl atroaed --to-- ()wOOdTNat_t WOJIII (POTWl for ubulltbullat Water mISt rr preutbullat llllldl141 bdofC diiCIW 10 tillamp fadlicy

adDente ubullbullbullbullbull _ (sl cartiOII) at aa ol-liw

Killty 1rllff coaUUMII CK (OIICIampIItrtlld wu~ to offmiddotslte (tctlity rot flnhcr ubulltmcnt

Olddizt orpnicS and c~rot)kll~ ftltcr ioM dint ionized OIYfll u4 aiuotta and llltflliokl IJbL

___ - --Ia aM it8ptn-~ Ofkl taps pUtt

coa-w toa bullrx pedwlta bJ liOUiaJ oft WI OOII(IIIItnlioM or VOC SVOO ill a cohama partedwilllt~enbulltlriiL w -doflfaucotbull bull-ait lxltl tllll _ bull plaquo dle - anMfw of VOOJSVOCI frola u oq_ _ shy

I )

~

~t-tiaed)

naiiiampUlliWIIIIilcu-_

loa-middot _ Me4il fltratioa

flltntioa

OfOIwhmpiaamp

Or~ialrucrotptor

llillllll Loodlll

NPOES OllcUrl

Rod---o1- 0lt _ orpako tJuobullP tdiOrpdoa oato paa ~Mwd cartMML Mey be ased u a poUsblaamp ~~ aMr uea~l tla 111 UVOIOUttoll or tir atrippinampW reiDOyenC

~allfdClld CQIIdta

Separate CODCCIUIwd Cl)lllaiUaU rro- mtiClld water ISinabull semimiddot

--- RcmcM bull sol fJOM tlrl WMteWllet iltum by fordbullamp

water nwP a aM tu~a or cartridbullmiddotYfC filter

ttclftOYamp sol aacl bullWI frOil wuaew~tcr auum 111in1 1 mcrnbraM _ fltract pvftdWttcf frOCft Cl Of lfiOfS cstrectiotl - tO CORtrol Of rcWM tM UlkrW CCMI _ Qf0111141w1 wouMI be uealld oa-Mat UUifONd 10 bullbull olaquo-tiw ~licy or diKNrJICllnto ~n lor

-J()IW Colkld JfOIIdwiiCt Ia ~pawl Drtin to allow treampUMIIt to

take pLaee

saare ue~-t rtiM~tamp ( _ thadae ipCil caWft) Ia aa oCImiddot

JtCilA rdliJmiddot OllcUtl P hlw tiM atona draiM ttWU MtfliiOfk or latO 1M ltMf hi tttal OIICraquorp OCitiOI wid M ___ -~u flooltftlotwiUIIoo

to ~toe tM rtetM

lei~ Utamptarou Net Wlwt the JfOIII sinamp OM or ~wtlll

II

)

lfu Use cutrtrpl torce 10 _ tM MdlJMllltioa rate of thtdJI

Dtwaters illldp by dfliUII giDlP lM ahadJC Nil aDd tv~poratioa frolltMwrc IOaitmiddot

()ewaterstl~IC by ~~Mill a coatLa- tuw belt tNt nbull over a drive aDd auide roUir 11uca llld Ukamp I (II)IIW70I MIL Shtdp is cootifliIOampSly diWiwed btCWMI lM IUW bella

otMten lllldfl _ ~ whll ~ Wlef 0 _ - _ - -Uto4-~ dcWitcritll IMlbOdl belli

Reduce tM IOiubull of 11-bull -cwal o( supetnltllll liquMt

Ocwatcn st~ae usiaa bull roampary cbullbullbull nuer

16

)

l l nCHNOLOOlES EVALUAreD l ao4llbelldl IAiiq wu 10 dcmOnsttalCthc cffcttln ol 1 tcthnoloJY In rc4ocinamp

poo-m coataonloanl that Clbt ao Nya to tbe MCUmiddot lie ronowlnamp oclttions daCribC bullbullbull UOIUDIGl ~eotalti~Md aDd lbC raOOoale lor cMIOIIDI ltlCII

lll EMIIJIIIIl l belldlmiddotIAiiq prcclpllltiooftOCltIIlaiiOalc4(tDCnlllioD and oa14atlonlflt40Cilon (-) ttquiR- 1llil wu tloDamp 10 delCrtniDC -1 and ooo41tiODI lor optimum rem o -_colloidal ao4 - - 1bC co11101lnatetl poutcr Hy4_ aetl 101idamp prodpilltiOtiWU -tlpte4 lo tbC PPM llludiiL ()aldatlottftetloctiDI rtqUitemCIII I

pK raaF for optimum metab reatQyenal wM abO bullgttilbOLIt~ IIUlytt preucat-14 be 10 _and rod 110bull conccnttatlons _ Ibull po ao Nyan belorlt othet lampdtoO _be _ Wit preucattneDI inorpnicllllll plbulll ca- _ IQlinl In alfoltripplol __ rod UV cftlclcncicS or ao nely lmpoct bioloPltl --bullbull perlortnl_ will abO tnellb loetli on polbullhlnamp proocUOI (I~ loa ()( rcverM 01100111) A _- o pacoot rlt-la i quoJilll _tiODI o( --lalioo (OrtMiloD led 10 IIIC -tillcatiOO o -F nnp (Or by4- polJIIIC (prodpllltiOO) ltyd-bull pcOildlt (-l icll_ ulllntbCCIeCI -o(lnoltPDicl D-pranpwerlt-olttbe p__ ill _ ll tina Table l middot l - tile tAl roo prod tbe boll r ulll

l ll Olll)llJIIlDurinamp ll lour etlditlonoltcchnololi boftdtmiddotICI oliOOIDI prcucattnCDI o arooICr 10 rc4uca- ampnorpnicl ThiiO lour_ were ioD altOinFo dlft bubble _oo ca____ ___L _ bull-bullbull- olt blllllll

-(LL bull 11rippln1 prior to actlvatc4 ca- Of ICiiVIte4 ca- ollor ___) _etiOI-1--Iol- loO_DF_ te41orinorpa1Crc-looly ea- _aott aoddiffuetl __ _ rororpolc -L BioloampICO__ tawd for botb i801pntt aD4 orpaic rcmovab lie PhiiC ll ideatlllcd tltc need to aetl lmplctneat ucattnCOI mcthOdl lor rc-1 o orpnicl For wmplc combibull bullbullabull 11rippin1 with acttvatc4 carbObull ucatmcat may be n_ary bullroomo cootantloaall arc dgtft~Cullto 11rip but -Uy 10 carbOn Altcrnatly c4 carbOn tniY be a pol~biDI 11cp ~ bioloalel ucatmcat bull cmplo)_ Tablel l-lto l -1 dcocribe Utbullt _ TIMamp 5-1 ilkoliftll tM water ctalily o( ttlamp r- Wllel priot ampa precipiudcm prcucaunenL

U 1Uf OBIECttvES _ o l ao4 ll beodt - 10 middot-- o - -o( ao4 -ubullilllbullbullbullbull pou-tallmpliiOOlshy11 1M tltyaua to beloW MOI TM bulltillamp- abO- 10 _1-middot-_---middot- piClypC o cacUaac - teiCOI ua- TbullriDI- oooductc4 to _ I rltllablt o IM tceJIOlOIYS abnity to _ contambullbullbull Ia the poutcr 11 the tlyaOJO 1111 TM olall col- - 001 iatcndc4 lor cftlclcY

I I I I

r~n hll

middot ll ~~l =~~Irrl l ~lil

f fl I

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 6: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

urf OF TAIIIJS

Orovodwater CoalaluDt frtllIUitf u4 eocntntiOn Rill 1

1-1 - SaeampDiq SUliWY for orouacr 1dMidialioa Tedutotoael ll _o__ Tpo ll

4-l PrectpicaliOa TreauiiY Daampa bullbull bullbullbull bullbullbullbullbullbull bullbullbullbull bullbull bull 19

H 20 Pbllamp II IUW Water Qarttteriltkl

S-l ll ldlliyen1 EfiiCtiveMI or PUle 11 TN~reDl T~

S-l 12 loa~ middot Tllbiliqt DILl

s ll Dithled ~- middot TbullUibilitJ Data bullbullbull

S-S cano~ - TrallbiliYOra bullbullbull 24

S-6

S-7 __ T -[)ola

= urr OF PIOUUS

l middotl Sloa_-~ middotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotmiddotbullmiddotmiddotmiddotmiddotmiddotmiddotmiddotbull middot middotmiddotmiddotmiddot--middot l l-1 - _ Map

l-l TCIIIo~ IOiiWIIII middot loueCoiiiOyen -- S

l_ TCIIIo o- - Wclll bull loUO CoiiiOII bullbullbullbullbullbull 6

middotI

) 10 JNIRODUCDON

Tbe Nyanza II bull Orouodwlttr Remedial ht~tlpdolllftuibiUty Study (RllfS) il the MCOnd of thtec operable uaiampS ldcaliaecl for he Nyaua site ne objeeliWI of tbe Nyua URlFS are to evahate the uturt aid diltrlb~ampdol ot poudniM coawaludol -- tM lilt ueodaled wilb tiUI coa~CiliDilkiD and coa~plete a CellibUcy atu4y or applicable remedJal allcmattvamp Tbe ftnt phaM ot remedial iallltiptloll lbr lM site bu beeA COfllpllted AddhioBII puadwatet IQW~~tlptiou (Ptwc It) aa4 uaociattd rillr aaMtill art cumatty lD _ IM remedial la_tlpUoa aaMllel were coDdICted 11adU he REM Ul coaUK The RIFS repoN will bt completed uDikr the ARCS coatrtCL

AJ put ol tile uuoilloa- 1M REM lll 10 ARCS__ tile ARCS-~~ otudy wllll EC Jordla eompuy penoDKI to obcala uatabWty ~ttdJ daca coDducted SU the REM 111 coatrKl iD support ot RllfS actMU 1il IICUkll meiiDCifUd~ampa il aa Cll~amp~Uol ot MK stiMS u weU 11 u cvalaltkla of DIW UOloi ideatiBell lfacl coaWO ot lM ueatabWIJ lilts

Sectioa 20 of Uil bullmoranclulll proW a summl) dilculltoa of tM coodltton of tbe site inclldiq kgtCltioa lnfcned CllampIU of cotnamludoa aacl type of coetaalaldoa Slttioo l O deCIMI preliminary rcbullbullllal fCI900M objective~ T~ powatiaUy capable ot aidptlq COiltamlulioa 11 the site aad rnectillamp tM Sill re~ponat objecti- are MatiW il SICtiol 40 A brief deleriptioll of cadl ~ udlM statbull atw ~iS abO provided iD SKtioa 40 SectiOa SO dlsnlla and evahata tbe EC Jordu ampNaampability 1llt prosram wllkll aaaiMd till appUcabWIY of cartlia ICCbDOIOI tO 1M tfyuD sUamp lltd_ hi Sealoa 50 is a dilaalampioa of tilt ~ cxpatJMtllll dalip aDd procedura u4 dati evaamp-lioL cod~ troe tcdlDOloampY tbulltiaamp _ idaaUIIkatioa of 1lttMr ampe~lilll opttolll Is

-iaSoctloo60

10 QYiRytEW Of J5lMRONMfNIAL CONTAMINADQN

The Nyaua cMekal site is loclted off of Mtpako RCI u4 ~CM~tll ot M SwlbUY NN aM _ Streit ta AMIUd MIIUdiiiMta 11 _ oa Rprc 1middot1 A ore dtlliS view or tbe site is shawl Oil

r Aaure 1middot1 Tbe she wu thl locatiobull of dlalkal _~De~ lldlltilllor 61 )1111 ud il cunudy occvp5ed bJ

- - - DouioiiM 6l portoO - ol- -- shydilpoMd ot oa the Pte indltdina peniltty-trutl4 Pf011 cM~t~kalll_p frCHft tM wu~ewata trtlllftUI ~ IOU4 fKO ta dnabull (tor cMiakal predpltata ucl filter caka) ancl orf-speciftcadol pro4uas PTOCI cMaicU tUt coUd at be rtCI(Ied or rcIMII lnchadina pMDOlDiuob~UeM u4 IDifWrie sutfatc wac aro dilpOIIIl ol oa-litt 1c ampDOlt recent dye rnanldacturct

t1ya011 lac -plod tile sloe- 1965 10 1971 1MJ- shyA--oopdlai-----II 1M slto _be fouo41a llle lDIIampJ4~~=~-sm=~~=nrcoataaiaalt _ dlleded Ia ~~~~ tipdoM at NJUII ar _ ta hbM l-1 tporwat

_ coa~lll-~ Sourlta of Ofpaic udillorpak ooa~IbullUoa Mea 6ecected wltllia tM fonlU propttiJ ttovldampria COIItllliaalioa ol pouldwaltt Ul ocnrr4 Ia boO tbe bedrOCk ~ F1pNI lJ ulll 1 allOW lM attal ateat ol coatalliaatiol fix tc il sol aM Wrodt wdll ~middot heM limits ol CIOIIwaitioa OPical JAUIIJ tepNMAampalM of CMMI CIOIIlliniOCI II well

I I I I

[1 ~1 31 IJII [ r~middotmiddot~I

trlr ~i 1 (f~f l

I

I p UualyMI- oC-111lt ootJOI Millbllt IIIII ampy llllpoltl

UOioampJ-1 CoDtamiDIUid pouoctwawr bullPI to t11 alJrttial to a moor exteftt ta bull oonbettY dircdoa 10WUi M ~Ill) Jliyenel Ml Dow i1 priiMriiY lD U tut) 4irecdOft towani tMIUia put oftMTOWI of~ IM 4alamp aiiO IU mit COIIuaaat 411Uibvllol lD JfOUDdwaU ru be prtMDt II coDCUtnted iDClM4dl plllll llptrimposed 01 I __pl

-------N

OTICE If tfto flho hoage

II IIU clear t h

an

thll

NYANZA C

HE

MIC

AL

W

AST

E

DUHP

notice tt II due to

tht

AD

MIN

IST

RA

TIV

E

RE

CO

RD

qualttr of th

e docuMent

bolng fllbull o4middot

-agt

bull N

Cg

tshy2_1jttzbullbull5

2tti

iili~ ~

gJ

-sectlc

2o

bulltti

Oc

-1 cbull

Nc

~ z I

middot4f - rsS--~

(l

- -

middot

-+= )

-

)

)

---)

_Zl ~ co-bull_ c-o_Ru

~5110

Maxlmlm MCL01 foloof Mlnlmtntt

MCL1 ~ ~llllllol~llllllolQwlilll 39200

IIJQIIIIill 33050 29 (MW-109)0 4 (lloO 1400- 50 lOOO ll

Blri 01000

6 (MW-114 A 302) 33 -Beryllhua 14 (10114)l 302000 II (MW-IOl)

10 2230~middotmiddot

50 100 26 (Ul) 26lColdbullbull ll3~middotmiddot lJOO 90400cdlolt

1000 ~ l20300 l 2(MW-1048) 29 (Oil)roo 73600ldL )(1100 ~- 31050 02 (MW-201)32 (ll10)2 93

100 39l00 2 -N- 12

- 50 IJOOOO _ 1170middotmiddot - 10

l OOO

100000 9 (MW-301) - ll(ll)0 761l00~ 70 40 (36) 12000(MWmiddot98) l 9(MW) 100 l (MW-101) 36 (20)~ 70 23a- 7012middot__ 7 I7l l middot DklaoiOitla)MM 48l

0 3 (3) 600(MWJOlA)9 (MW-2038)

l ll (MWmiddot2048) 2000 2 9 (MW-2041) 2000Tol- 440 I 1JOO1000 l20 (MW-JOlA)Xylnll 2_

---_1-1(-dal GrovedMW CoosaaiDUl Freq ud CoeQIOlna Raa

NyUrampa-iltOI$110

ll(MW-1111) I 30 (MW-IISA) ~-tsladl- 10 (MW-107)l~ S6000 (MW-lllA)

tJamiddotJ)iaOrObeaiampM - bull 19 (MW-30S8)7SO 30 (3) SIOOOO (MW-113A)

14-p-- 41 (11)s 63 (MW-6A)600 610 16

tlo-~nc 3UlODOO(MW-lllA)100 (MW-1048)4-MampIgtyplloool IS SIOO(MW-11)IS (MW-30S8)NiuoliCIUIampM n SS100 (MW-113A)124-TricbiorobeftiCM - I3S (MW-10lt8)11 l30(MW-IISA) 170 (MW-611)

6N_ s 0 189 - 9 (MW-lll8) llmiddotDkhkKOitbaM 100 Ill100 l

111-TriCWofOitUIIamp 0 90 (MW-111) Vi ell- I 650 (MW-1048)ll(MW-117A)Mot~ 10 180 (MW-IIlA)96 (MW-96)1 a-NitMIOmiddotDimiddotbullmiddot 41000(MW-113A) s

ElMlt shyOil(lashy

ottbi eefJQ) 0001 (MW-118) iS (MW-108)

04 1 (37) 016 (MW-IOlA)Hololt I S4(MW-llll) 03S (MW-611)bullbullmiddot-ooT 3 OSS (MW-EAT-15)0011 (MW-IOS)- -IHC l 01 (MW-301)DelcamiddotIHC I 17(MW-9A)Dlol4rin ookgtfdabull Soutc~ Flftll WOfk Plla Jolyaaza 11 - orouactwater Sl14) Dcamber t917

Ortfl Prclilllinlty Suamary o( Site CbatKCriutioO NJUrampIIOIOO_St_ 191amp

1MO bull MM~d- Milia eoa-at tAYtl or EPA MO wtlkbcYCf is lllOfC ltriftstftL

1MCLO bull Mllfllbull eoaIIUMtt lAYtl 0oe1~ o( 63 ~ WIUI tS wdl polaU llllpkcent almbcn ia p~rcotMMS repraeat ~ampmpkl with

-ndoO _ MQ or MQO Wed_ aftM _ lioO ~ Ia - shy

I I

middot~ r

I

I I

) 0 WLIMINMY RfMEPIAl RpoundSPON$E OIJgcnyES

~po oOJoCiiOI for the Nyonu II middot Orobull- StY ~llf1 will be on the potential ror rokS to pbullblk ao4 the ca-roamltnL ~~~po objeCI not nnal and await completion of alltc-specilc tilt aiMU_L KoweYtr bUI4 01 CliltiOI dl~ wveral patbWI)l throuamph which humans

or tht eampMroruacll cou~ be tllpOie4 tO contamlnalll Ia pouactwatu bM been toeatlfiecl

o ttumaa cqu~~te tO coawainall pouactwaW wouP laiUoft Genna contaCt aR40r iobaiatloa if a water aupply aoune if dcwklfl at or bullr tbe 1Ue Ia tJre Mure

o cxpCIItiN 10 cootanUutell pou4WI W0MP 4Lrecl Qermal oonKl witb aDCl iobaltioD a( coowaiaUll lo eqMOYI or vapor lonD -piOI iato relideftdal ~~~ dodpdicnt rroca tbc lite

o u4 ~~tal apcllllfC 10 coocaalDUU froa poctwatcr once It ttiscUraeamp lato

wcda or tbe SuclbUIJ RiYef

Prtlhllinary ruS-1 rcspobull objecliwl tUt td4raamp tbelt poceatial apo~ure pathways inchiCampe

o Utaitilll pracatancl Murc riiD to humans cauMil b) apotUto to ooataminatc4 po~aactwatcr sltffacamp waterl aM -eau

o Ubullltilll deJfldltiol of tM Sltdb~try River aacl wetU41 liltamp to dischltp of coo~iaa- pouftdWiter and

o - appliltlgtbull ao4 rcplltlonl _ and ror PPY

MdltloNI- objeltIIWS may be 10pe4 on dall colleete4 In the Nyonull field intlplloa -middot aM 1M rilt performld bull ptn of tM RlFS

40 1QENDfJCampJON ANQ genNJNO OF DCtfNQIOOIE$

-- o( -middot-middot P- -torY o( tedlootol o(toldpdrll -inatiOn 11 1M Nytnaa _ EP teellnoloampY was evalolled on the - o( _ potclllal delnmiddotbullP -bull bull 11 MCU aod red- 1M potcntiol threat 10 poblllt

lbeuYitoii-L

Treat ~ pocealillly sllitab1 tor tM Nyaua liM wae ldPtifted Nled oa ~middot bull -n o( tM ~til oootaaiaatiol ull prcllnliIJ tctponsc objectiva The tcdtno~ - diYide4 iato ail calfIOI ucl catefMY rqwet~Rtilamp bull pp at re~pomamp actioU tblt covkl ___ -oOJoCiiOI

Sita eoauo1 COIItaillftlftl Treat_ ExtraciiOO

SlltdJIHiftthlll

)

lnncgtbulltll tedlooiOIa were identlllad rltgtntn4or JIIormampIIOD oa4 1ltc Superfloa4 ln_t TclthnOIOI)

Emiddotauadon Pro-= TtchnoloampY Proftlcs fJovember 1919 from tM EPA

42 TECHNOLOGY SCREENINO The laitlll scnertlol of~elthnolOampiOI wos - oa enampirinllelliblllry on4 oppllcobillry to tlto lOCidon or tlto NyortJA olte _ ntlytltotechnolOjlll wore-- oa agtnstroinu Imposelt by the rype or agtatomlnoau -middotc physkll agtn41tOns oltlto ute on4 _ or rettt~inlnl bull rault or tlto uurmenr p- croctcrlstlcl oltlto bullIre thll may or 11m1r tlto eKect_ o 1 tcchnOIOI) obtol - _ ltiptlOno Pbyskll propettY doll oltlto agtatominoau bullliCit olltllity bOiUal polaC -ry worc to oay lbolu Pttgte agtatominoau tbcmKIIIIY lmpaoe oabull ~todlaolOampYmiddot Wbullte ~- ldlatllod todelae - ltor ltlODII waste uatmcaL TiiM ~GftOIOIel wto1t a WM deatt) precluded by Wlll6 or site cUractcriitkl were elimltll rora--loa Tbc ults of this oltOill- _ rtsilmjp(Y Sqscoinl llfllms4i11TKbullIil (-May 1911~ TM ARCS te~a ldlatiGid odditlOnll toe~~aoOjielthll were

not coWdcred la ~ report Tobie 4middot1 Is 1 - o the remediatiOn tcchnoOjllltbat relftll after nln~ Tbc EbUltO-AilCS the )9techaoOjlllllstod oa Tobie 4-1 by-~ prodtKt lltCTIIUIC en4or inOrntltlOn pertonao doll -middot FSbull on4 bullhrobullJh dirlaquo agtnoultotiOO with n40ro A brie dOIltriptlOn of each

-~~-lnToblel-~

50 WASpound 1 ANQ u IRFAItBil m 1QT rsooRAM - Tbc tr0111hlliry _-1bull-to~ re-opodftlt -riOO reprdialthe perlormonlaquo

of--middot-ooiOilabullbull- shy ialtiol scneo~ POIIOtlll ftuncial rlsa on4 delaY lo - KtiOO oro _ with the --of 1 le(hnolOD lOr lmptementotlOn witbOIIt fl WfPOdaamp pcrfonMftCC data For tM uutabUity tCit PfOI-middot on-site bench-5CIIt telll wcro - oo troot-r -aoOjlll ooly II ipiOltoDI lt-1 lalOrmotiOO roprdinl the te(bldOI(i coM dketiyent- Of lrepkmotn~tbility cou4 M obtliaed at a rutOftlble eo~t P-I ud _U oltgte tlbiliry otudy ro-llad OltpDicl rrootmeftl pcctlvltly throop bettdt_ ~ lo ltloD _ relt~bull_ worc ideotltlcd durin the rroatobility otudy ud doll colieltrltd to_ the iDII_t_te otrubull u be to In evoiUitlnl

the applklbilicy o( MYCrtl ~~ tUt were aot btlldlmiddotbullbull From loorntltlOa ptherad ill - otudiOI dtamp woste dllrKterotlcl likely to lmplltt _-implemltDtobillry oadof-lalrroorrtechnolOIIOihbullbullicleifted

ThM -tlcs ladshyldiM rqeegliql middot A all llIIDbtr ol orpak alld iaorpllk contaminanu 1avt bctn ia 1t u- O~ ~~~ crronsmllkdJ to lavotw a ueaU1181 (a CCblalbull ol ubull- ) speorc proccu- oalpcd _ -----middot ()onlla _ shytlfiCdW fCIIiatlM CIOIIllaludoa

Ullf pracW middot Dtftdceciel Ia laflnlbulldol rcatilll 0 Ntk wttfl propen- sd pH oplaquotftlt Mry cooBOD TOC C DOl alii TM Rl ud ueaiblhlJ It~bull ld4rtU theM ~ ao4 flrthct We1Uify lmportut niMCtl li ely to illft lM trfectiveiIM o( UbullUMIIIII at~rNii-

10

--

I )

_ lloos-qSIolt __

Nua a-loll

ROlli tillXJl~

$11tOgtouol XFcaciaiiSP X X

loltihlioUl Coauoll ~- X5latfacc Waw Coluol

~ XCpplbulll XH)dnulkBarrilt Oroddw~MI lalaeeptor T~ftdl X

XFnaOIOIItiqo_ lajocdoll X

_ XtJmiddot

shyX

X =middot X

Wet Alr ()ddadoll1 X

~ XPNdplampl~lioiISediNalldol X -Locll w n~t FtdUa X XOI~WTNa-tFKIMtJ X -Potarilld ~ ()Ddaat ~o~J

DJiilll X sai-Fioill- XTllibull Fla EYapORlioas NltSiripplacc_-loa- X

-~ XMed6l FUusliol X ---X

X X

II

)

I

IJ r

-~ ~- Dnla - (_

lMIIWI IIPDES lllodWJO ~kMIIO Orouftdwltcr

shyDlll-CaUilloll ---middot lelt FUIIr FlloorPIW Onvlty1gtidtal01 v nmtiol

Rcta1M4 xa lfll

X X

X X X

X X

X X X X

1 tucwetM TtcUooD tbat il paR ot EPA Silamp OOMUIioll Proanbull middot turrcatty btiq rldd 1 1M Towll of AIJI)a ot M11 I p11bUdJ opaatcd _let UUIIMilt fidtlty

3 lllMMlM TdiiOkgtD

11

--

----

-I )

lllllo_Z ~ ot Orww Re8ldiadol T_

llyua QcUal Silo

FeocfAtSipl

llldaltioul ColiUOII

~loll Molltortq

Slllflcr Water Cotluol

ClppUit

tfJaiiUc Ianier

Groundwater lnjeaion

Reltrkt ~wt~ fuKll poll watIUill tlpl

11 lud or otMt NllricdoU to proltibh tbc use ol JfOIIIIChILtriiiMIMtilt

EYihaale mlpaliol ud dillriiMaUoll of eo~~~amp~~luaamps Oyener tiiDC ~a~ina 11orina 10 aapll lM CMIHnlal alliS bedroct aquller

ConUOI slllflct waw ru4 owr Ike 1114 lbuefore lallltrat6oa to poundwttar

Pmat iaftltraliiMI ot _doll iiiO coatlaiuted ZOIIII wiU a RCilA 111dtimiddotlayet cap or OlMr cappWc bullterilil

OMrt ltMItMUda pouctwaamper ftow aroud contlmintted zona willa limy Wlwat piliq

ampLiblillrl 1 bedroct ~ _ulictlly bullptradient of the site 10 tower JfOUMwalel dMidoll il coaaaaiuS

Pmut JfOUDdwalef _ tlarotaP COIItlflliMtcd IODa by poutiq Mdrock traura

laect wttrr Into the Jf0111Mh1W to bydnulkllly prevtnt the funhct miJfltioo ot COGtamiauq

ltiuod abulllriull ld 01J111 iiiiO liM JfOUMIWIIer aiGJ I uix of atiKI~ wdll lid redmd1Ui01 amnktues 10 stimulate

~middot- __ _ _ _ICampMIM _or~bull lltIHolopcal NeQOr

(ampJ I trictllq IUICf tOCatilt ~ CIOIIIKtOII)

I)

IIitr 1~

bullbull

) I ~

t~r~

Acrltioft

_ Otf-tlbull wT

FtciiiY

PolarU4 Mlt4iiJ()WolvOd QDdall 1M

()llidbe orpakl ill atJICUIIII pouadMIU willa I llal1tiOCO

applklt of ll~ upt aad a rona oQdilcr

Otatroy orpaic co~wafuall La aa aq~~M~Gtll IOiudOD by iDdMiaJ ollidadoll aiMI laydtolylil reeaiOM at lllP waperauuc aDd prt~Suramp Olyp at ekWUid _ cabaDC tbamp oddat~D of orpak

coapoddlto carbOa diolidamp bullbullmiddot

AI1111C tM lfOIadWatlt 10 ~ iaoJpClk itOft and mlfiMM andmiddot-middot- middot-eo-t dillotvd 10 aa tolubae font (lc metal sulftde W ~or boa aauta) padld tOiiclltiUOUIJI

ftoealladoa settle out IOl6dl ~ plilJmiddot

Dildlotl atroaed --to-- ()wOOdTNat_t WOJIII (POTWl for ubulltbullat Water mISt rr preutbullat llllldl141 bdofC diiCIW 10 tillamp fadlicy

adDente ubullbullbullbullbull _ (sl cartiOII) at aa ol-liw

Killty 1rllff coaUUMII CK (OIICIampIItrtlld wu~ to offmiddotslte (tctlity rot flnhcr ubulltmcnt

Olddizt orpnicS and c~rot)kll~ ftltcr ioM dint ionized OIYfll u4 aiuotta and llltflliokl IJbL

___ - --Ia aM it8ptn-~ Ofkl taps pUtt

coa-w toa bullrx pedwlta bJ liOUiaJ oft WI OOII(IIIItnlioM or VOC SVOO ill a cohama partedwilllt~enbulltlriiL w -doflfaucotbull bull-ait lxltl tllll _ bull plaquo dle - anMfw of VOOJSVOCI frola u oq_ _ shy

I )

~

~t-tiaed)

naiiiampUlliWIIIIilcu-_

loa-middot _ Me4il fltratioa

flltntioa

OfOIwhmpiaamp

Or~ialrucrotptor

llillllll Loodlll

NPOES OllcUrl

Rod---o1- 0lt _ orpako tJuobullP tdiOrpdoa oato paa ~Mwd cartMML Mey be ased u a poUsblaamp ~~ aMr uea~l tla 111 UVOIOUttoll or tir atrippinampW reiDOyenC

~allfdClld CQIIdta

Separate CODCCIUIwd Cl)lllaiUaU rro- mtiClld water ISinabull semimiddot

--- RcmcM bull sol fJOM tlrl WMteWllet iltum by fordbullamp

water nwP a aM tu~a or cartridbullmiddotYfC filter

ttclftOYamp sol aacl bullWI frOil wuaew~tcr auum 111in1 1 mcrnbraM _ fltract pvftdWttcf frOCft Cl Of lfiOfS cstrectiotl - tO CORtrol Of rcWM tM UlkrW CCMI _ Qf0111141w1 wouMI be uealld oa-Mat UUifONd 10 bullbull olaquo-tiw ~licy or diKNrJICllnto ~n lor

-J()IW Colkld JfOIIdwiiCt Ia ~pawl Drtin to allow treampUMIIt to

take pLaee

saare ue~-t rtiM~tamp ( _ thadae ipCil caWft) Ia aa oCImiddot

JtCilA rdliJmiddot OllcUtl P hlw tiM atona draiM ttWU MtfliiOfk or latO 1M ltMf hi tttal OIICraquorp OCitiOI wid M ___ -~u flooltftlotwiUIIoo

to ~toe tM rtetM

lei~ Utamptarou Net Wlwt the JfOIII sinamp OM or ~wtlll

II

)

lfu Use cutrtrpl torce 10 _ tM MdlJMllltioa rate of thtdJI

Dtwaters illldp by dfliUII giDlP lM ahadJC Nil aDd tv~poratioa frolltMwrc IOaitmiddot

()ewaterstl~IC by ~~Mill a coatLa- tuw belt tNt nbull over a drive aDd auide roUir 11uca llld Ukamp I (II)IIW70I MIL Shtdp is cootifliIOampSly diWiwed btCWMI lM IUW bella

otMten lllldfl _ ~ whll ~ Wlef 0 _ - _ - -Uto4-~ dcWitcritll IMlbOdl belli

Reduce tM IOiubull of 11-bull -cwal o( supetnltllll liquMt

Ocwatcn st~ae usiaa bull roampary cbullbullbull nuer

16

)

l l nCHNOLOOlES EVALUAreD l ao4llbelldl IAiiq wu 10 dcmOnsttalCthc cffcttln ol 1 tcthnoloJY In rc4ocinamp

poo-m coataonloanl that Clbt ao Nya to tbe MCUmiddot lie ronowlnamp oclttions daCribC bullbullbull UOIUDIGl ~eotalti~Md aDd lbC raOOoale lor cMIOIIDI ltlCII

lll EMIIJIIIIl l belldlmiddotIAiiq prcclpllltiooftOCltIIlaiiOalc4(tDCnlllioD and oa14atlonlflt40Cilon (-) ttquiR- 1llil wu tloDamp 10 delCrtniDC -1 and ooo41tiODI lor optimum rem o -_colloidal ao4 - - 1bC co11101lnatetl poutcr Hy4_ aetl 101idamp prodpilltiOtiWU -tlpte4 lo tbC PPM llludiiL ()aldatlottftetloctiDI rtqUitemCIII I

pK raaF for optimum metab reatQyenal wM abO bullgttilbOLIt~ IIUlytt preucat-14 be 10 _and rod 110bull conccnttatlons _ Ibull po ao Nyan belorlt othet lampdtoO _be _ Wit preucattneDI inorpnicllllll plbulll ca- _ IQlinl In alfoltripplol __ rod UV cftlclcncicS or ao nely lmpoct bioloPltl --bullbull perlortnl_ will abO tnellb loetli on polbullhlnamp proocUOI (I~ loa ()( rcverM 01100111) A _- o pacoot rlt-la i quoJilll _tiODI o( --lalioo (OrtMiloD led 10 IIIC -tillcatiOO o -F nnp (Or by4- polJIIIC (prodpllltiOO) ltyd-bull pcOildlt (-l icll_ ulllntbCCIeCI -o(lnoltPDicl D-pranpwerlt-olttbe p__ ill _ ll tina Table l middot l - tile tAl roo prod tbe boll r ulll

l ll Olll)llJIIlDurinamp ll lour etlditlonoltcchnololi boftdtmiddotICI oliOOIDI prcucattnCDI o arooICr 10 rc4uca- ampnorpnicl ThiiO lour_ were ioD altOinFo dlft bubble _oo ca____ ___L _ bull-bullbull- olt blllllll

-(LL bull 11rippln1 prior to actlvatc4 ca- Of ICiiVIte4 ca- ollor ___) _etiOI-1--Iol- loO_DF_ te41orinorpa1Crc-looly ea- _aott aoddiffuetl __ _ rororpolc -L BioloampICO__ tawd for botb i801pntt aD4 orpaic rcmovab lie PhiiC ll ideatlllcd tltc need to aetl lmplctneat ucattnCOI mcthOdl lor rc-1 o orpnicl For wmplc combibull bullbullabull 11rippin1 with acttvatc4 carbObull ucatmcat may be n_ary bullroomo cootantloaall arc dgtft~Cullto 11rip but -Uy 10 carbOn Altcrnatly c4 carbOn tniY be a pol~biDI 11cp ~ bioloalel ucatmcat bull cmplo)_ Tablel l-lto l -1 dcocribe Utbullt _ TIMamp 5-1 ilkoliftll tM water ctalily o( ttlamp r- Wllel priot ampa precipiudcm prcucaunenL

U 1Uf OBIECttvES _ o l ao4 ll beodt - 10 middot-- o - -o( ao4 -ubullilllbullbullbullbull pou-tallmpliiOOlshy11 1M tltyaua to beloW MOI TM bulltillamp- abO- 10 _1-middot-_---middot- piClypC o cacUaac - teiCOI ua- TbullriDI- oooductc4 to _ I rltllablt o IM tceJIOlOIYS abnity to _ contambullbullbull Ia the poutcr 11 the tlyaOJO 1111 TM olall col- - 001 iatcndc4 lor cftlclcY

I I I I

r~n hll

middot ll ~~l =~~Irrl l ~lil

f fl I

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 7: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

) 10 JNIRODUCDON

Tbe Nyanza II bull Orouodwlttr Remedial ht~tlpdolllftuibiUty Study (RllfS) il the MCOnd of thtec operable uaiampS ldcaliaecl for he Nyaua site ne objeeliWI of tbe Nyua URlFS are to evahate the uturt aid diltrlb~ampdol ot poudniM coawaludol -- tM lilt ueodaled wilb tiUI coa~CiliDilkiD and coa~plete a CellibUcy atu4y or applicable remedJal allcmattvamp Tbe ftnt phaM ot remedial iallltiptloll lbr lM site bu beeA COfllpllted AddhioBII puadwatet IQW~~tlptiou (Ptwc It) aa4 uaociattd rillr aaMtill art cumatty lD _ IM remedial la_tlpUoa aaMllel were coDdICted 11adU he REM Ul coaUK The RIFS repoN will bt completed uDikr the ARCS coatrtCL

AJ put ol tile uuoilloa- 1M REM lll 10 ARCS__ tile ARCS-~~ otudy wllll EC Jordla eompuy penoDKI to obcala uatabWty ~ttdJ daca coDducted SU the REM 111 coatrKl iD support ot RllfS actMU 1il IICUkll meiiDCifUd~ampa il aa Cll~amp~Uol ot MK stiMS u weU 11 u cvalaltkla of DIW UOloi ideatiBell lfacl coaWO ot lM ueatabWIJ lilts

Sectioa 20 of Uil bullmoranclulll proW a summl) dilculltoa of tM coodltton of tbe site inclldiq kgtCltioa lnfcned CllampIU of cotnamludoa aacl type of coetaalaldoa Slttioo l O deCIMI preliminary rcbullbullllal fCI900M objective~ T~ powatiaUy capable ot aidptlq COiltamlulioa 11 the site aad rnectillamp tM Sill re~ponat objecti- are MatiW il SICtiol 40 A brief deleriptioll of cadl ~ udlM statbull atw ~iS abO provided iD SKtioa 40 SectiOa SO dlsnlla and evahata tbe EC Jordu ampNaampability 1llt prosram wllkll aaaiMd till appUcabWIY of cartlia ICCbDOIOI tO 1M tfyuD sUamp lltd_ hi Sealoa 50 is a dilaalampioa of tilt ~ cxpatJMtllll dalip aDd procedura u4 dati evaamp-lioL cod~ troe tcdlDOloampY tbulltiaamp _ idaaUIIkatioa of 1lttMr ampe~lilll opttolll Is

-iaSoctloo60

10 QYiRytEW Of J5lMRONMfNIAL CONTAMINADQN

The Nyaua cMekal site is loclted off of Mtpako RCI u4 ~CM~tll ot M SwlbUY NN aM _ Streit ta AMIUd MIIUdiiiMta 11 _ oa Rprc 1middot1 A ore dtlliS view or tbe site is shawl Oil

r Aaure 1middot1 Tbe she wu thl locatiobull of dlalkal _~De~ lldlltilllor 61 )1111 ud il cunudy occvp5ed bJ

- - - DouioiiM 6l portoO - ol- -- shydilpoMd ot oa the Pte indltdina peniltty-trutl4 Pf011 cM~t~kalll_p frCHft tM wu~ewata trtlllftUI ~ IOU4 fKO ta dnabull (tor cMiakal predpltata ucl filter caka) ancl orf-speciftcadol pro4uas PTOCI cMaicU tUt coUd at be rtCI(Ied or rcIMII lnchadina pMDOlDiuob~UeM u4 IDifWrie sutfatc wac aro dilpOIIIl ol oa-litt 1c ampDOlt recent dye rnanldacturct

t1ya011 lac -plod tile sloe- 1965 10 1971 1MJ- shyA--oopdlai-----II 1M slto _be fouo41a llle lDIIampJ4~~=~-sm=~~=nrcoataaiaalt _ dlleded Ia ~~~~ tipdoM at NJUII ar _ ta hbM l-1 tporwat

_ coa~lll-~ Sourlta of Ofpaic udillorpak ooa~IbullUoa Mea 6ecected wltllia tM fonlU propttiJ ttovldampria COIItllliaalioa ol pouldwaltt Ul ocnrr4 Ia boO tbe bedrOCk ~ F1pNI lJ ulll 1 allOW lM attal ateat ol coatalliaatiol fix tc il sol aM Wrodt wdll ~middot heM limits ol CIOIIwaitioa OPical JAUIIJ tepNMAampalM of CMMI CIOIIlliniOCI II well

I I I I

[1 ~1 31 IJII [ r~middotmiddot~I

trlr ~i 1 (f~f l

I

I p UualyMI- oC-111lt ootJOI Millbllt IIIII ampy llllpoltl

UOioampJ-1 CoDtamiDIUid pouoctwawr bullPI to t11 alJrttial to a moor exteftt ta bull oonbettY dircdoa 10WUi M ~Ill) Jliyenel Ml Dow i1 priiMriiY lD U tut) 4irecdOft towani tMIUia put oftMTOWI of~ IM 4alamp aiiO IU mit COIIuaaat 411Uibvllol lD JfOUDdwaU ru be prtMDt II coDCUtnted iDClM4dl plllll llptrimposed 01 I __pl

-------N

OTICE If tfto flho hoage

II IIU clear t h

an

thll

NYANZA C

HE

MIC

AL

W

AST

E

DUHP

notice tt II due to

tht

AD

MIN

IST

RA

TIV

E

RE

CO

RD

qualttr of th

e docuMent

bolng fllbull o4middot

-agt

bull N

Cg

tshy2_1jttzbullbull5

2tti

iili~ ~

gJ

-sectlc

2o

bulltti

Oc

-1 cbull

Nc

~ z I

middot4f - rsS--~

(l

- -

middot

-+= )

-

)

)

---)

_Zl ~ co-bull_ c-o_Ru

~5110

Maxlmlm MCL01 foloof Mlnlmtntt

MCL1 ~ ~llllllol~llllllolQwlilll 39200

IIJQIIIIill 33050 29 (MW-109)0 4 (lloO 1400- 50 lOOO ll

Blri 01000

6 (MW-114 A 302) 33 -Beryllhua 14 (10114)l 302000 II (MW-IOl)

10 2230~middotmiddot

50 100 26 (Ul) 26lColdbullbull ll3~middotmiddot lJOO 90400cdlolt

1000 ~ l20300 l 2(MW-1048) 29 (Oil)roo 73600ldL )(1100 ~- 31050 02 (MW-201)32 (ll10)2 93

100 39l00 2 -N- 12

- 50 IJOOOO _ 1170middotmiddot - 10

l OOO

100000 9 (MW-301) - ll(ll)0 761l00~ 70 40 (36) 12000(MWmiddot98) l 9(MW) 100 l (MW-101) 36 (20)~ 70 23a- 7012middot__ 7 I7l l middot DklaoiOitla)MM 48l

0 3 (3) 600(MWJOlA)9 (MW-2038)

l ll (MWmiddot2048) 2000 2 9 (MW-2041) 2000Tol- 440 I 1JOO1000 l20 (MW-JOlA)Xylnll 2_

---_1-1(-dal GrovedMW CoosaaiDUl Freq ud CoeQIOlna Raa

NyUrampa-iltOI$110

ll(MW-1111) I 30 (MW-IISA) ~-tsladl- 10 (MW-107)l~ S6000 (MW-lllA)

tJamiddotJ)iaOrObeaiampM - bull 19 (MW-30S8)7SO 30 (3) SIOOOO (MW-113A)

14-p-- 41 (11)s 63 (MW-6A)600 610 16

tlo-~nc 3UlODOO(MW-lllA)100 (MW-1048)4-MampIgtyplloool IS SIOO(MW-11)IS (MW-30S8)NiuoliCIUIampM n SS100 (MW-113A)124-TricbiorobeftiCM - I3S (MW-10lt8)11 l30(MW-IISA) 170 (MW-611)

6N_ s 0 189 - 9 (MW-lll8) llmiddotDkhkKOitbaM 100 Ill100 l

111-TriCWofOitUIIamp 0 90 (MW-111) Vi ell- I 650 (MW-1048)ll(MW-117A)Mot~ 10 180 (MW-IIlA)96 (MW-96)1 a-NitMIOmiddotDimiddotbullmiddot 41000(MW-113A) s

ElMlt shyOil(lashy

ottbi eefJQ) 0001 (MW-118) iS (MW-108)

04 1 (37) 016 (MW-IOlA)Hololt I S4(MW-llll) 03S (MW-611)bullbullmiddot-ooT 3 OSS (MW-EAT-15)0011 (MW-IOS)- -IHC l 01 (MW-301)DelcamiddotIHC I 17(MW-9A)Dlol4rin ookgtfdabull Soutc~ Flftll WOfk Plla Jolyaaza 11 - orouactwater Sl14) Dcamber t917

Ortfl Prclilllinlty Suamary o( Site CbatKCriutioO NJUrampIIOIOO_St_ 191amp

1MO bull MM~d- Milia eoa-at tAYtl or EPA MO wtlkbcYCf is lllOfC ltriftstftL

1MCLO bull Mllfllbull eoaIIUMtt lAYtl 0oe1~ o( 63 ~ WIUI tS wdl polaU llllpkcent almbcn ia p~rcotMMS repraeat ~ampmpkl with

-ndoO _ MQ or MQO Wed_ aftM _ lioO ~ Ia - shy

I I

middot~ r

I

I I

) 0 WLIMINMY RfMEPIAl RpoundSPON$E OIJgcnyES

~po oOJoCiiOI for the Nyonu II middot Orobull- StY ~llf1 will be on the potential ror rokS to pbullblk ao4 the ca-roamltnL ~~~po objeCI not nnal and await completion of alltc-specilc tilt aiMU_L KoweYtr bUI4 01 CliltiOI dl~ wveral patbWI)l throuamph which humans

or tht eampMroruacll cou~ be tllpOie4 tO contamlnalll Ia pouactwatu bM been toeatlfiecl

o ttumaa cqu~~te tO coawainall pouactwaW wouP laiUoft Genna contaCt aR40r iobaiatloa if a water aupply aoune if dcwklfl at or bullr tbe 1Ue Ia tJre Mure

o cxpCIItiN 10 cootanUutell pou4WI W0MP 4Lrecl Qermal oonKl witb aDCl iobaltioD a( coowaiaUll lo eqMOYI or vapor lonD -piOI iato relideftdal ~~~ dodpdicnt rroca tbc lite

o u4 ~~tal apcllllfC 10 coocaalDUU froa poctwatcr once It ttiscUraeamp lato

wcda or tbe SuclbUIJ RiYef

Prtlhllinary ruS-1 rcspobull objecliwl tUt td4raamp tbelt poceatial apo~ure pathways inchiCampe

o Utaitilll pracatancl Murc riiD to humans cauMil b) apotUto to ooataminatc4 po~aactwatcr sltffacamp waterl aM -eau

o Ubullltilll deJfldltiol of tM Sltdb~try River aacl wetU41 liltamp to dischltp of coo~iaa- pouftdWiter and

o - appliltlgtbull ao4 rcplltlonl _ and ror PPY

MdltloNI- objeltIIWS may be 10pe4 on dall colleete4 In the Nyonull field intlplloa -middot aM 1M rilt performld bull ptn of tM RlFS

40 1QENDfJCampJON ANQ genNJNO OF DCtfNQIOOIE$

-- o( -middot-middot P- -torY o( tedlootol o(toldpdrll -inatiOn 11 1M Nytnaa _ EP teellnoloampY was evalolled on the - o( _ potclllal delnmiddotbullP -bull bull 11 MCU aod red- 1M potcntiol threat 10 poblllt

lbeuYitoii-L

Treat ~ pocealillly sllitab1 tor tM Nyaua liM wae ldPtifted Nled oa ~middot bull -n o( tM ~til oootaaiaatiol ull prcllnliIJ tctponsc objectiva The tcdtno~ - diYide4 iato ail calfIOI ucl catefMY rqwet~Rtilamp bull pp at re~pomamp actioU tblt covkl ___ -oOJoCiiOI

Sita eoauo1 COIItaillftlftl Treat_ ExtraciiOO

SlltdJIHiftthlll

)

lnncgtbulltll tedlooiOIa were identlllad rltgtntn4or JIIormampIIOD oa4 1ltc Superfloa4 ln_t TclthnOIOI)

Emiddotauadon Pro-= TtchnoloampY Proftlcs fJovember 1919 from tM EPA

42 TECHNOLOGY SCREENINO The laitlll scnertlol of~elthnolOampiOI wos - oa enampirinllelliblllry on4 oppllcobillry to tlto lOCidon or tlto NyortJA olte _ ntlytltotechnolOjlll wore-- oa agtnstroinu Imposelt by the rype or agtatomlnoau -middotc physkll agtn41tOns oltlto ute on4 _ or rettt~inlnl bull rault or tlto uurmenr p- croctcrlstlcl oltlto bullIre thll may or 11m1r tlto eKect_ o 1 tcchnOIOI) obtol - _ ltiptlOno Pbyskll propettY doll oltlto agtatominoau bullliCit olltllity bOiUal polaC -ry worc to oay lbolu Pttgte agtatominoau tbcmKIIIIY lmpaoe oabull ~todlaolOampYmiddot Wbullte ~- ldlatllod todelae - ltor ltlODII waste uatmcaL TiiM ~GftOIOIel wto1t a WM deatt) precluded by Wlll6 or site cUractcriitkl were elimltll rora--loa Tbc ults of this oltOill- _ rtsilmjp(Y Sqscoinl llfllms4i11TKbullIil (-May 1911~ TM ARCS te~a ldlatiGid odditlOnll toe~~aoOjielthll were

not coWdcred la ~ report Tobie 4middot1 Is 1 - o the remediatiOn tcchnoOjllltbat relftll after nln~ Tbc EbUltO-AilCS the )9techaoOjlllllstod oa Tobie 4-1 by-~ prodtKt lltCTIIUIC en4or inOrntltlOn pertonao doll -middot FSbull on4 bullhrobullJh dirlaquo agtnoultotiOO with n40ro A brie dOIltriptlOn of each

-~~-lnToblel-~

50 WASpound 1 ANQ u IRFAItBil m 1QT rsooRAM - Tbc tr0111hlliry _-1bull-to~ re-opodftlt -riOO reprdialthe perlormonlaquo

of--middot-ooiOilabullbull- shy ialtiol scneo~ POIIOtlll ftuncial rlsa on4 delaY lo - KtiOO oro _ with the --of 1 le(hnolOD lOr lmptementotlOn witbOIIt fl WfPOdaamp pcrfonMftCC data For tM uutabUity tCit PfOI-middot on-site bench-5CIIt telll wcro - oo troot-r -aoOjlll ooly II ipiOltoDI lt-1 lalOrmotiOO roprdinl the te(bldOI(i coM dketiyent- Of lrepkmotn~tbility cou4 M obtliaed at a rutOftlble eo~t P-I ud _U oltgte tlbiliry otudy ro-llad OltpDicl rrootmeftl pcctlvltly throop bettdt_ ~ lo ltloD _ relt~bull_ worc ideotltlcd durin the rroatobility otudy ud doll colieltrltd to_ the iDII_t_te otrubull u be to In evoiUitlnl

the applklbilicy o( MYCrtl ~~ tUt were aot btlldlmiddotbullbull From loorntltlOa ptherad ill - otudiOI dtamp woste dllrKterotlcl likely to lmplltt _-implemltDtobillry oadof-lalrroorrtechnolOIIOihbullbullicleifted

ThM -tlcs ladshyldiM rqeegliql middot A all llIIDbtr ol orpak alld iaorpllk contaminanu 1avt bctn ia 1t u- O~ ~~~ crronsmllkdJ to lavotw a ueaU1181 (a CCblalbull ol ubull- ) speorc proccu- oalpcd _ -----middot ()onlla _ shytlfiCdW fCIIiatlM CIOIIllaludoa

Ullf pracW middot Dtftdceciel Ia laflnlbulldol rcatilll 0 Ntk wttfl propen- sd pH oplaquotftlt Mry cooBOD TOC C DOl alii TM Rl ud ueaiblhlJ It~bull ld4rtU theM ~ ao4 flrthct We1Uify lmportut niMCtl li ely to illft lM trfectiveiIM o( UbullUMIIIII at~rNii-

10

--

I )

_ lloos-qSIolt __

Nua a-loll

ROlli tillXJl~

$11tOgtouol XFcaciaiiSP X X

loltihlioUl Coauoll ~- X5latfacc Waw Coluol

~ XCpplbulll XH)dnulkBarrilt Oroddw~MI lalaeeptor T~ftdl X

XFnaOIOIItiqo_ lajocdoll X

_ XtJmiddot

shyX

X =middot X

Wet Alr ()ddadoll1 X

~ XPNdplampl~lioiISediNalldol X -Locll w n~t FtdUa X XOI~WTNa-tFKIMtJ X -Potarilld ~ ()Ddaat ~o~J

DJiilll X sai-Fioill- XTllibull Fla EYapORlioas NltSiripplacc_-loa- X

-~ XMed6l FUusliol X ---X

X X

II

)

I

IJ r

-~ ~- Dnla - (_

lMIIWI IIPDES lllodWJO ~kMIIO Orouftdwltcr

shyDlll-CaUilloll ---middot lelt FUIIr FlloorPIW Onvlty1gtidtal01 v nmtiol

Rcta1M4 xa lfll

X X

X X X

X X

X X X X

1 tucwetM TtcUooD tbat il paR ot EPA Silamp OOMUIioll Proanbull middot turrcatty btiq rldd 1 1M Towll of AIJI)a ot M11 I p11bUdJ opaatcd _let UUIIMilt fidtlty

3 lllMMlM TdiiOkgtD

11

--

----

-I )

lllllo_Z ~ ot Orww Re8ldiadol T_

llyua QcUal Silo

FeocfAtSipl

llldaltioul ColiUOII

~loll Molltortq

Slllflcr Water Cotluol

ClppUit

tfJaiiUc Ianier

Groundwater lnjeaion

Reltrkt ~wt~ fuKll poll watIUill tlpl

11 lud or otMt NllricdoU to proltibh tbc use ol JfOIIIIChILtriiiMIMtilt

EYihaale mlpaliol ud dillriiMaUoll of eo~~~amp~~luaamps Oyener tiiDC ~a~ina 11orina 10 aapll lM CMIHnlal alliS bedroct aquller

ConUOI slllflct waw ru4 owr Ike 1114 lbuefore lallltrat6oa to poundwttar

Pmat iaftltraliiMI ot _doll iiiO coatlaiuted ZOIIII wiU a RCilA 111dtimiddotlayet cap or OlMr cappWc bullterilil

OMrt ltMItMUda pouctwaamper ftow aroud contlmintted zona willa limy Wlwat piliq

ampLiblillrl 1 bedroct ~ _ulictlly bullptradient of the site 10 tower JfOUMwalel dMidoll il coaaaaiuS

Pmut JfOUDdwalef _ tlarotaP COIItlflliMtcd IODa by poutiq Mdrock traura

laect wttrr Into the Jf0111Mh1W to bydnulkllly prevtnt the funhct miJfltioo ot COGtamiauq

ltiuod abulllriull ld 01J111 iiiiO liM JfOUMIWIIer aiGJ I uix of atiKI~ wdll lid redmd1Ui01 amnktues 10 stimulate

~middot- __ _ _ _ICampMIM _or~bull lltIHolopcal NeQOr

(ampJ I trictllq IUICf tOCatilt ~ CIOIIIKtOII)

I)

IIitr 1~

bullbull

) I ~

t~r~

Acrltioft

_ Otf-tlbull wT

FtciiiY

PolarU4 Mlt4iiJ()WolvOd QDdall 1M

()llidbe orpakl ill atJICUIIII pouadMIU willa I llal1tiOCO

applklt of ll~ upt aad a rona oQdilcr

Otatroy orpaic co~wafuall La aa aq~~M~Gtll IOiudOD by iDdMiaJ ollidadoll aiMI laydtolylil reeaiOM at lllP waperauuc aDd prt~Suramp Olyp at ekWUid _ cabaDC tbamp oddat~D of orpak

coapoddlto carbOa diolidamp bullbullmiddot

AI1111C tM lfOIadWatlt 10 ~ iaoJpClk itOft and mlfiMM andmiddot-middot- middot-eo-t dillotvd 10 aa tolubae font (lc metal sulftde W ~or boa aauta) padld tOiiclltiUOUIJI

ftoealladoa settle out IOl6dl ~ plilJmiddot

Dildlotl atroaed --to-- ()wOOdTNat_t WOJIII (POTWl for ubulltbullat Water mISt rr preutbullat llllldl141 bdofC diiCIW 10 tillamp fadlicy

adDente ubullbullbullbullbull _ (sl cartiOII) at aa ol-liw

Killty 1rllff coaUUMII CK (OIICIampIItrtlld wu~ to offmiddotslte (tctlity rot flnhcr ubulltmcnt

Olddizt orpnicS and c~rot)kll~ ftltcr ioM dint ionized OIYfll u4 aiuotta and llltflliokl IJbL

___ - --Ia aM it8ptn-~ Ofkl taps pUtt

coa-w toa bullrx pedwlta bJ liOUiaJ oft WI OOII(IIIItnlioM or VOC SVOO ill a cohama partedwilllt~enbulltlriiL w -doflfaucotbull bull-ait lxltl tllll _ bull plaquo dle - anMfw of VOOJSVOCI frola u oq_ _ shy

I )

~

~t-tiaed)

naiiiampUlliWIIIIilcu-_

loa-middot _ Me4il fltratioa

flltntioa

OfOIwhmpiaamp

Or~ialrucrotptor

llillllll Loodlll

NPOES OllcUrl

Rod---o1- 0lt _ orpako tJuobullP tdiOrpdoa oato paa ~Mwd cartMML Mey be ased u a poUsblaamp ~~ aMr uea~l tla 111 UVOIOUttoll or tir atrippinampW reiDOyenC

~allfdClld CQIIdta

Separate CODCCIUIwd Cl)lllaiUaU rro- mtiClld water ISinabull semimiddot

--- RcmcM bull sol fJOM tlrl WMteWllet iltum by fordbullamp

water nwP a aM tu~a or cartridbullmiddotYfC filter

ttclftOYamp sol aacl bullWI frOil wuaew~tcr auum 111in1 1 mcrnbraM _ fltract pvftdWttcf frOCft Cl Of lfiOfS cstrectiotl - tO CORtrol Of rcWM tM UlkrW CCMI _ Qf0111141w1 wouMI be uealld oa-Mat UUifONd 10 bullbull olaquo-tiw ~licy or diKNrJICllnto ~n lor

-J()IW Colkld JfOIIdwiiCt Ia ~pawl Drtin to allow treampUMIIt to

take pLaee

saare ue~-t rtiM~tamp ( _ thadae ipCil caWft) Ia aa oCImiddot

JtCilA rdliJmiddot OllcUtl P hlw tiM atona draiM ttWU MtfliiOfk or latO 1M ltMf hi tttal OIICraquorp OCitiOI wid M ___ -~u flooltftlotwiUIIoo

to ~toe tM rtetM

lei~ Utamptarou Net Wlwt the JfOIII sinamp OM or ~wtlll

II

)

lfu Use cutrtrpl torce 10 _ tM MdlJMllltioa rate of thtdJI

Dtwaters illldp by dfliUII giDlP lM ahadJC Nil aDd tv~poratioa frolltMwrc IOaitmiddot

()ewaterstl~IC by ~~Mill a coatLa- tuw belt tNt nbull over a drive aDd auide roUir 11uca llld Ukamp I (II)IIW70I MIL Shtdp is cootifliIOampSly diWiwed btCWMI lM IUW bella

otMten lllldfl _ ~ whll ~ Wlef 0 _ - _ - -Uto4-~ dcWitcritll IMlbOdl belli

Reduce tM IOiubull of 11-bull -cwal o( supetnltllll liquMt

Ocwatcn st~ae usiaa bull roampary cbullbullbull nuer

16

)

l l nCHNOLOOlES EVALUAreD l ao4llbelldl IAiiq wu 10 dcmOnsttalCthc cffcttln ol 1 tcthnoloJY In rc4ocinamp

poo-m coataonloanl that Clbt ao Nya to tbe MCUmiddot lie ronowlnamp oclttions daCribC bullbullbull UOIUDIGl ~eotalti~Md aDd lbC raOOoale lor cMIOIIDI ltlCII

lll EMIIJIIIIl l belldlmiddotIAiiq prcclpllltiooftOCltIIlaiiOalc4(tDCnlllioD and oa14atlonlflt40Cilon (-) ttquiR- 1llil wu tloDamp 10 delCrtniDC -1 and ooo41tiODI lor optimum rem o -_colloidal ao4 - - 1bC co11101lnatetl poutcr Hy4_ aetl 101idamp prodpilltiOtiWU -tlpte4 lo tbC PPM llludiiL ()aldatlottftetloctiDI rtqUitemCIII I

pK raaF for optimum metab reatQyenal wM abO bullgttilbOLIt~ IIUlytt preucat-14 be 10 _and rod 110bull conccnttatlons _ Ibull po ao Nyan belorlt othet lampdtoO _be _ Wit preucattneDI inorpnicllllll plbulll ca- _ IQlinl In alfoltripplol __ rod UV cftlclcncicS or ao nely lmpoct bioloPltl --bullbull perlortnl_ will abO tnellb loetli on polbullhlnamp proocUOI (I~ loa ()( rcverM 01100111) A _- o pacoot rlt-la i quoJilll _tiODI o( --lalioo (OrtMiloD led 10 IIIC -tillcatiOO o -F nnp (Or by4- polJIIIC (prodpllltiOO) ltyd-bull pcOildlt (-l icll_ ulllntbCCIeCI -o(lnoltPDicl D-pranpwerlt-olttbe p__ ill _ ll tina Table l middot l - tile tAl roo prod tbe boll r ulll

l ll Olll)llJIIlDurinamp ll lour etlditlonoltcchnololi boftdtmiddotICI oliOOIDI prcucattnCDI o arooICr 10 rc4uca- ampnorpnicl ThiiO lour_ were ioD altOinFo dlft bubble _oo ca____ ___L _ bull-bullbull- olt blllllll

-(LL bull 11rippln1 prior to actlvatc4 ca- Of ICiiVIte4 ca- ollor ___) _etiOI-1--Iol- loO_DF_ te41orinorpa1Crc-looly ea- _aott aoddiffuetl __ _ rororpolc -L BioloampICO__ tawd for botb i801pntt aD4 orpaic rcmovab lie PhiiC ll ideatlllcd tltc need to aetl lmplctneat ucattnCOI mcthOdl lor rc-1 o orpnicl For wmplc combibull bullbullabull 11rippin1 with acttvatc4 carbObull ucatmcat may be n_ary bullroomo cootantloaall arc dgtft~Cullto 11rip but -Uy 10 carbOn Altcrnatly c4 carbOn tniY be a pol~biDI 11cp ~ bioloalel ucatmcat bull cmplo)_ Tablel l-lto l -1 dcocribe Utbullt _ TIMamp 5-1 ilkoliftll tM water ctalily o( ttlamp r- Wllel priot ampa precipiudcm prcucaunenL

U 1Uf OBIECttvES _ o l ao4 ll beodt - 10 middot-- o - -o( ao4 -ubullilllbullbullbullbull pou-tallmpliiOOlshy11 1M tltyaua to beloW MOI TM bulltillamp- abO- 10 _1-middot-_---middot- piClypC o cacUaac - teiCOI ua- TbullriDI- oooductc4 to _ I rltllablt o IM tceJIOlOIYS abnity to _ contambullbullbull Ia the poutcr 11 the tlyaOJO 1111 TM olall col- - 001 iatcndc4 lor cftlclcY

I I I I

r~n hll

middot ll ~~l =~~Irrl l ~lil

f fl I

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 8: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

I p UualyMI- oC-111lt ootJOI Millbllt IIIII ampy llllpoltl

UOioampJ-1 CoDtamiDIUid pouoctwawr bullPI to t11 alJrttial to a moor exteftt ta bull oonbettY dircdoa 10WUi M ~Ill) Jliyenel Ml Dow i1 priiMriiY lD U tut) 4irecdOft towani tMIUia put oftMTOWI of~ IM 4alamp aiiO IU mit COIIuaaat 411Uibvllol lD JfOUDdwaU ru be prtMDt II coDCUtnted iDClM4dl plllll llptrimposed 01 I __pl

-------N

OTICE If tfto flho hoage

II IIU clear t h

an

thll

NYANZA C

HE

MIC

AL

W

AST

E

DUHP

notice tt II due to

tht

AD

MIN

IST

RA

TIV

E

RE

CO

RD

qualttr of th

e docuMent

bolng fllbull o4middot

-agt

bull N

Cg

tshy2_1jttzbullbull5

2tti

iili~ ~

gJ

-sectlc

2o

bulltti

Oc

-1 cbull

Nc

~ z I

middot4f - rsS--~

(l

- -

middot

-+= )

-

)

)

---)

_Zl ~ co-bull_ c-o_Ru

~5110

Maxlmlm MCL01 foloof Mlnlmtntt

MCL1 ~ ~llllllol~llllllolQwlilll 39200

IIJQIIIIill 33050 29 (MW-109)0 4 (lloO 1400- 50 lOOO ll

Blri 01000

6 (MW-114 A 302) 33 -Beryllhua 14 (10114)l 302000 II (MW-IOl)

10 2230~middotmiddot

50 100 26 (Ul) 26lColdbullbull ll3~middotmiddot lJOO 90400cdlolt

1000 ~ l20300 l 2(MW-1048) 29 (Oil)roo 73600ldL )(1100 ~- 31050 02 (MW-201)32 (ll10)2 93

100 39l00 2 -N- 12

- 50 IJOOOO _ 1170middotmiddot - 10

l OOO

100000 9 (MW-301) - ll(ll)0 761l00~ 70 40 (36) 12000(MWmiddot98) l 9(MW) 100 l (MW-101) 36 (20)~ 70 23a- 7012middot__ 7 I7l l middot DklaoiOitla)MM 48l

0 3 (3) 600(MWJOlA)9 (MW-2038)

l ll (MWmiddot2048) 2000 2 9 (MW-2041) 2000Tol- 440 I 1JOO1000 l20 (MW-JOlA)Xylnll 2_

---_1-1(-dal GrovedMW CoosaaiDUl Freq ud CoeQIOlna Raa

NyUrampa-iltOI$110

ll(MW-1111) I 30 (MW-IISA) ~-tsladl- 10 (MW-107)l~ S6000 (MW-lllA)

tJamiddotJ)iaOrObeaiampM - bull 19 (MW-30S8)7SO 30 (3) SIOOOO (MW-113A)

14-p-- 41 (11)s 63 (MW-6A)600 610 16

tlo-~nc 3UlODOO(MW-lllA)100 (MW-1048)4-MampIgtyplloool IS SIOO(MW-11)IS (MW-30S8)NiuoliCIUIampM n SS100 (MW-113A)124-TricbiorobeftiCM - I3S (MW-10lt8)11 l30(MW-IISA) 170 (MW-611)

6N_ s 0 189 - 9 (MW-lll8) llmiddotDkhkKOitbaM 100 Ill100 l

111-TriCWofOitUIIamp 0 90 (MW-111) Vi ell- I 650 (MW-1048)ll(MW-117A)Mot~ 10 180 (MW-IIlA)96 (MW-96)1 a-NitMIOmiddotDimiddotbullmiddot 41000(MW-113A) s

ElMlt shyOil(lashy

ottbi eefJQ) 0001 (MW-118) iS (MW-108)

04 1 (37) 016 (MW-IOlA)Hololt I S4(MW-llll) 03S (MW-611)bullbullmiddot-ooT 3 OSS (MW-EAT-15)0011 (MW-IOS)- -IHC l 01 (MW-301)DelcamiddotIHC I 17(MW-9A)Dlol4rin ookgtfdabull Soutc~ Flftll WOfk Plla Jolyaaza 11 - orouactwater Sl14) Dcamber t917

Ortfl Prclilllinlty Suamary o( Site CbatKCriutioO NJUrampIIOIOO_St_ 191amp

1MO bull MM~d- Milia eoa-at tAYtl or EPA MO wtlkbcYCf is lllOfC ltriftstftL

1MCLO bull Mllfllbull eoaIIUMtt lAYtl 0oe1~ o( 63 ~ WIUI tS wdl polaU llllpkcent almbcn ia p~rcotMMS repraeat ~ampmpkl with

-ndoO _ MQ or MQO Wed_ aftM _ lioO ~ Ia - shy

I I

middot~ r

I

I I

) 0 WLIMINMY RfMEPIAl RpoundSPON$E OIJgcnyES

~po oOJoCiiOI for the Nyonu II middot Orobull- StY ~llf1 will be on the potential ror rokS to pbullblk ao4 the ca-roamltnL ~~~po objeCI not nnal and await completion of alltc-specilc tilt aiMU_L KoweYtr bUI4 01 CliltiOI dl~ wveral patbWI)l throuamph which humans

or tht eampMroruacll cou~ be tllpOie4 tO contamlnalll Ia pouactwatu bM been toeatlfiecl

o ttumaa cqu~~te tO coawainall pouactwaW wouP laiUoft Genna contaCt aR40r iobaiatloa if a water aupply aoune if dcwklfl at or bullr tbe 1Ue Ia tJre Mure

o cxpCIItiN 10 cootanUutell pou4WI W0MP 4Lrecl Qermal oonKl witb aDCl iobaltioD a( coowaiaUll lo eqMOYI or vapor lonD -piOI iato relideftdal ~~~ dodpdicnt rroca tbc lite

o u4 ~~tal apcllllfC 10 coocaalDUU froa poctwatcr once It ttiscUraeamp lato

wcda or tbe SuclbUIJ RiYef

Prtlhllinary ruS-1 rcspobull objecliwl tUt td4raamp tbelt poceatial apo~ure pathways inchiCampe

o Utaitilll pracatancl Murc riiD to humans cauMil b) apotUto to ooataminatc4 po~aactwatcr sltffacamp waterl aM -eau

o Ubullltilll deJfldltiol of tM Sltdb~try River aacl wetU41 liltamp to dischltp of coo~iaa- pouftdWiter and

o - appliltlgtbull ao4 rcplltlonl _ and ror PPY

MdltloNI- objeltIIWS may be 10pe4 on dall colleete4 In the Nyonull field intlplloa -middot aM 1M rilt performld bull ptn of tM RlFS

40 1QENDfJCampJON ANQ genNJNO OF DCtfNQIOOIE$

-- o( -middot-middot P- -torY o( tedlootol o(toldpdrll -inatiOn 11 1M Nytnaa _ EP teellnoloampY was evalolled on the - o( _ potclllal delnmiddotbullP -bull bull 11 MCU aod red- 1M potcntiol threat 10 poblllt

lbeuYitoii-L

Treat ~ pocealillly sllitab1 tor tM Nyaua liM wae ldPtifted Nled oa ~middot bull -n o( tM ~til oootaaiaatiol ull prcllnliIJ tctponsc objectiva The tcdtno~ - diYide4 iato ail calfIOI ucl catefMY rqwet~Rtilamp bull pp at re~pomamp actioU tblt covkl ___ -oOJoCiiOI

Sita eoauo1 COIItaillftlftl Treat_ ExtraciiOO

SlltdJIHiftthlll

)

lnncgtbulltll tedlooiOIa were identlllad rltgtntn4or JIIormampIIOD oa4 1ltc Superfloa4 ln_t TclthnOIOI)

Emiddotauadon Pro-= TtchnoloampY Proftlcs fJovember 1919 from tM EPA

42 TECHNOLOGY SCREENINO The laitlll scnertlol of~elthnolOampiOI wos - oa enampirinllelliblllry on4 oppllcobillry to tlto lOCidon or tlto NyortJA olte _ ntlytltotechnolOjlll wore-- oa agtnstroinu Imposelt by the rype or agtatomlnoau -middotc physkll agtn41tOns oltlto ute on4 _ or rettt~inlnl bull rault or tlto uurmenr p- croctcrlstlcl oltlto bullIre thll may or 11m1r tlto eKect_ o 1 tcchnOIOI) obtol - _ ltiptlOno Pbyskll propettY doll oltlto agtatominoau bullliCit olltllity bOiUal polaC -ry worc to oay lbolu Pttgte agtatominoau tbcmKIIIIY lmpaoe oabull ~todlaolOampYmiddot Wbullte ~- ldlatllod todelae - ltor ltlODII waste uatmcaL TiiM ~GftOIOIel wto1t a WM deatt) precluded by Wlll6 or site cUractcriitkl were elimltll rora--loa Tbc ults of this oltOill- _ rtsilmjp(Y Sqscoinl llfllms4i11TKbullIil (-May 1911~ TM ARCS te~a ldlatiGid odditlOnll toe~~aoOjielthll were

not coWdcred la ~ report Tobie 4middot1 Is 1 - o the remediatiOn tcchnoOjllltbat relftll after nln~ Tbc EbUltO-AilCS the )9techaoOjlllllstod oa Tobie 4-1 by-~ prodtKt lltCTIIUIC en4or inOrntltlOn pertonao doll -middot FSbull on4 bullhrobullJh dirlaquo agtnoultotiOO with n40ro A brie dOIltriptlOn of each

-~~-lnToblel-~

50 WASpound 1 ANQ u IRFAItBil m 1QT rsooRAM - Tbc tr0111hlliry _-1bull-to~ re-opodftlt -riOO reprdialthe perlormonlaquo

of--middot-ooiOilabullbull- shy ialtiol scneo~ POIIOtlll ftuncial rlsa on4 delaY lo - KtiOO oro _ with the --of 1 le(hnolOD lOr lmptementotlOn witbOIIt fl WfPOdaamp pcrfonMftCC data For tM uutabUity tCit PfOI-middot on-site bench-5CIIt telll wcro - oo troot-r -aoOjlll ooly II ipiOltoDI lt-1 lalOrmotiOO roprdinl the te(bldOI(i coM dketiyent- Of lrepkmotn~tbility cou4 M obtliaed at a rutOftlble eo~t P-I ud _U oltgte tlbiliry otudy ro-llad OltpDicl rrootmeftl pcctlvltly throop bettdt_ ~ lo ltloD _ relt~bull_ worc ideotltlcd durin the rroatobility otudy ud doll colieltrltd to_ the iDII_t_te otrubull u be to In evoiUitlnl

the applklbilicy o( MYCrtl ~~ tUt were aot btlldlmiddotbullbull From loorntltlOa ptherad ill - otudiOI dtamp woste dllrKterotlcl likely to lmplltt _-implemltDtobillry oadof-lalrroorrtechnolOIIOihbullbullicleifted

ThM -tlcs ladshyldiM rqeegliql middot A all llIIDbtr ol orpak alld iaorpllk contaminanu 1avt bctn ia 1t u- O~ ~~~ crronsmllkdJ to lavotw a ueaU1181 (a CCblalbull ol ubull- ) speorc proccu- oalpcd _ -----middot ()onlla _ shytlfiCdW fCIIiatlM CIOIIllaludoa

Ullf pracW middot Dtftdceciel Ia laflnlbulldol rcatilll 0 Ntk wttfl propen- sd pH oplaquotftlt Mry cooBOD TOC C DOl alii TM Rl ud ueaiblhlJ It~bull ld4rtU theM ~ ao4 flrthct We1Uify lmportut niMCtl li ely to illft lM trfectiveiIM o( UbullUMIIIII at~rNii-

10

--

I )

_ lloos-qSIolt __

Nua a-loll

ROlli tillXJl~

$11tOgtouol XFcaciaiiSP X X

loltihlioUl Coauoll ~- X5latfacc Waw Coluol

~ XCpplbulll XH)dnulkBarrilt Oroddw~MI lalaeeptor T~ftdl X

XFnaOIOIItiqo_ lajocdoll X

_ XtJmiddot

shyX

X =middot X

Wet Alr ()ddadoll1 X

~ XPNdplampl~lioiISediNalldol X -Locll w n~t FtdUa X XOI~WTNa-tFKIMtJ X -Potarilld ~ ()Ddaat ~o~J

DJiilll X sai-Fioill- XTllibull Fla EYapORlioas NltSiripplacc_-loa- X

-~ XMed6l FUusliol X ---X

X X

II

)

I

IJ r

-~ ~- Dnla - (_

lMIIWI IIPDES lllodWJO ~kMIIO Orouftdwltcr

shyDlll-CaUilloll ---middot lelt FUIIr FlloorPIW Onvlty1gtidtal01 v nmtiol

Rcta1M4 xa lfll

X X

X X X

X X

X X X X

1 tucwetM TtcUooD tbat il paR ot EPA Silamp OOMUIioll Proanbull middot turrcatty btiq rldd 1 1M Towll of AIJI)a ot M11 I p11bUdJ opaatcd _let UUIIMilt fidtlty

3 lllMMlM TdiiOkgtD

11

--

----

-I )

lllllo_Z ~ ot Orww Re8ldiadol T_

llyua QcUal Silo

FeocfAtSipl

llldaltioul ColiUOII

~loll Molltortq

Slllflcr Water Cotluol

ClppUit

tfJaiiUc Ianier

Groundwater lnjeaion

Reltrkt ~wt~ fuKll poll watIUill tlpl

11 lud or otMt NllricdoU to proltibh tbc use ol JfOIIIIChILtriiiMIMtilt

EYihaale mlpaliol ud dillriiMaUoll of eo~~~amp~~luaamps Oyener tiiDC ~a~ina 11orina 10 aapll lM CMIHnlal alliS bedroct aquller

ConUOI slllflct waw ru4 owr Ike 1114 lbuefore lallltrat6oa to poundwttar

Pmat iaftltraliiMI ot _doll iiiO coatlaiuted ZOIIII wiU a RCilA 111dtimiddotlayet cap or OlMr cappWc bullterilil

OMrt ltMItMUda pouctwaamper ftow aroud contlmintted zona willa limy Wlwat piliq

ampLiblillrl 1 bedroct ~ _ulictlly bullptradient of the site 10 tower JfOUMwalel dMidoll il coaaaaiuS

Pmut JfOUDdwalef _ tlarotaP COIItlflliMtcd IODa by poutiq Mdrock traura

laect wttrr Into the Jf0111Mh1W to bydnulkllly prevtnt the funhct miJfltioo ot COGtamiauq

ltiuod abulllriull ld 01J111 iiiiO liM JfOUMIWIIer aiGJ I uix of atiKI~ wdll lid redmd1Ui01 amnktues 10 stimulate

~middot- __ _ _ _ICampMIM _or~bull lltIHolopcal NeQOr

(ampJ I trictllq IUICf tOCatilt ~ CIOIIIKtOII)

I)

IIitr 1~

bullbull

) I ~

t~r~

Acrltioft

_ Otf-tlbull wT

FtciiiY

PolarU4 Mlt4iiJ()WolvOd QDdall 1M

()llidbe orpakl ill atJICUIIII pouadMIU willa I llal1tiOCO

applklt of ll~ upt aad a rona oQdilcr

Otatroy orpaic co~wafuall La aa aq~~M~Gtll IOiudOD by iDdMiaJ ollidadoll aiMI laydtolylil reeaiOM at lllP waperauuc aDd prt~Suramp Olyp at ekWUid _ cabaDC tbamp oddat~D of orpak

coapoddlto carbOa diolidamp bullbullmiddot

AI1111C tM lfOIadWatlt 10 ~ iaoJpClk itOft and mlfiMM andmiddot-middot- middot-eo-t dillotvd 10 aa tolubae font (lc metal sulftde W ~or boa aauta) padld tOiiclltiUOUIJI

ftoealladoa settle out IOl6dl ~ plilJmiddot

Dildlotl atroaed --to-- ()wOOdTNat_t WOJIII (POTWl for ubulltbullat Water mISt rr preutbullat llllldl141 bdofC diiCIW 10 tillamp fadlicy

adDente ubullbullbullbullbull _ (sl cartiOII) at aa ol-liw

Killty 1rllff coaUUMII CK (OIICIampIItrtlld wu~ to offmiddotslte (tctlity rot flnhcr ubulltmcnt

Olddizt orpnicS and c~rot)kll~ ftltcr ioM dint ionized OIYfll u4 aiuotta and llltflliokl IJbL

___ - --Ia aM it8ptn-~ Ofkl taps pUtt

coa-w toa bullrx pedwlta bJ liOUiaJ oft WI OOII(IIIItnlioM or VOC SVOO ill a cohama partedwilllt~enbulltlriiL w -doflfaucotbull bull-ait lxltl tllll _ bull plaquo dle - anMfw of VOOJSVOCI frola u oq_ _ shy

I )

~

~t-tiaed)

naiiiampUlliWIIIIilcu-_

loa-middot _ Me4il fltratioa

flltntioa

OfOIwhmpiaamp

Or~ialrucrotptor

llillllll Loodlll

NPOES OllcUrl

Rod---o1- 0lt _ orpako tJuobullP tdiOrpdoa oato paa ~Mwd cartMML Mey be ased u a poUsblaamp ~~ aMr uea~l tla 111 UVOIOUttoll or tir atrippinampW reiDOyenC

~allfdClld CQIIdta

Separate CODCCIUIwd Cl)lllaiUaU rro- mtiClld water ISinabull semimiddot

--- RcmcM bull sol fJOM tlrl WMteWllet iltum by fordbullamp

water nwP a aM tu~a or cartridbullmiddotYfC filter

ttclftOYamp sol aacl bullWI frOil wuaew~tcr auum 111in1 1 mcrnbraM _ fltract pvftdWttcf frOCft Cl Of lfiOfS cstrectiotl - tO CORtrol Of rcWM tM UlkrW CCMI _ Qf0111141w1 wouMI be uealld oa-Mat UUifONd 10 bullbull olaquo-tiw ~licy or diKNrJICllnto ~n lor

-J()IW Colkld JfOIIdwiiCt Ia ~pawl Drtin to allow treampUMIIt to

take pLaee

saare ue~-t rtiM~tamp ( _ thadae ipCil caWft) Ia aa oCImiddot

JtCilA rdliJmiddot OllcUtl P hlw tiM atona draiM ttWU MtfliiOfk or latO 1M ltMf hi tttal OIICraquorp OCitiOI wid M ___ -~u flooltftlotwiUIIoo

to ~toe tM rtetM

lei~ Utamptarou Net Wlwt the JfOIII sinamp OM or ~wtlll

II

)

lfu Use cutrtrpl torce 10 _ tM MdlJMllltioa rate of thtdJI

Dtwaters illldp by dfliUII giDlP lM ahadJC Nil aDd tv~poratioa frolltMwrc IOaitmiddot

()ewaterstl~IC by ~~Mill a coatLa- tuw belt tNt nbull over a drive aDd auide roUir 11uca llld Ukamp I (II)IIW70I MIL Shtdp is cootifliIOampSly diWiwed btCWMI lM IUW bella

otMten lllldfl _ ~ whll ~ Wlef 0 _ - _ - -Uto4-~ dcWitcritll IMlbOdl belli

Reduce tM IOiubull of 11-bull -cwal o( supetnltllll liquMt

Ocwatcn st~ae usiaa bull roampary cbullbullbull nuer

16

)

l l nCHNOLOOlES EVALUAreD l ao4llbelldl IAiiq wu 10 dcmOnsttalCthc cffcttln ol 1 tcthnoloJY In rc4ocinamp

poo-m coataonloanl that Clbt ao Nya to tbe MCUmiddot lie ronowlnamp oclttions daCribC bullbullbull UOIUDIGl ~eotalti~Md aDd lbC raOOoale lor cMIOIIDI ltlCII

lll EMIIJIIIIl l belldlmiddotIAiiq prcclpllltiooftOCltIIlaiiOalc4(tDCnlllioD and oa14atlonlflt40Cilon (-) ttquiR- 1llil wu tloDamp 10 delCrtniDC -1 and ooo41tiODI lor optimum rem o -_colloidal ao4 - - 1bC co11101lnatetl poutcr Hy4_ aetl 101idamp prodpilltiOtiWU -tlpte4 lo tbC PPM llludiiL ()aldatlottftetloctiDI rtqUitemCIII I

pK raaF for optimum metab reatQyenal wM abO bullgttilbOLIt~ IIUlytt preucat-14 be 10 _and rod 110bull conccnttatlons _ Ibull po ao Nyan belorlt othet lampdtoO _be _ Wit preucattneDI inorpnicllllll plbulll ca- _ IQlinl In alfoltripplol __ rod UV cftlclcncicS or ao nely lmpoct bioloPltl --bullbull perlortnl_ will abO tnellb loetli on polbullhlnamp proocUOI (I~ loa ()( rcverM 01100111) A _- o pacoot rlt-la i quoJilll _tiODI o( --lalioo (OrtMiloD led 10 IIIC -tillcatiOO o -F nnp (Or by4- polJIIIC (prodpllltiOO) ltyd-bull pcOildlt (-l icll_ ulllntbCCIeCI -o(lnoltPDicl D-pranpwerlt-olttbe p__ ill _ ll tina Table l middot l - tile tAl roo prod tbe boll r ulll

l ll Olll)llJIIlDurinamp ll lour etlditlonoltcchnololi boftdtmiddotICI oliOOIDI prcucattnCDI o arooICr 10 rc4uca- ampnorpnicl ThiiO lour_ were ioD altOinFo dlft bubble _oo ca____ ___L _ bull-bullbull- olt blllllll

-(LL bull 11rippln1 prior to actlvatc4 ca- Of ICiiVIte4 ca- ollor ___) _etiOI-1--Iol- loO_DF_ te41orinorpa1Crc-looly ea- _aott aoddiffuetl __ _ rororpolc -L BioloampICO__ tawd for botb i801pntt aD4 orpaic rcmovab lie PhiiC ll ideatlllcd tltc need to aetl lmplctneat ucattnCOI mcthOdl lor rc-1 o orpnicl For wmplc combibull bullbullabull 11rippin1 with acttvatc4 carbObull ucatmcat may be n_ary bullroomo cootantloaall arc dgtft~Cullto 11rip but -Uy 10 carbOn Altcrnatly c4 carbOn tniY be a pol~biDI 11cp ~ bioloalel ucatmcat bull cmplo)_ Tablel l-lto l -1 dcocribe Utbullt _ TIMamp 5-1 ilkoliftll tM water ctalily o( ttlamp r- Wllel priot ampa precipiudcm prcucaunenL

U 1Uf OBIECttvES _ o l ao4 ll beodt - 10 middot-- o - -o( ao4 -ubullilllbullbullbullbull pou-tallmpliiOOlshy11 1M tltyaua to beloW MOI TM bulltillamp- abO- 10 _1-middot-_---middot- piClypC o cacUaac - teiCOI ua- TbullriDI- oooductc4 to _ I rltllablt o IM tceJIOlOIYS abnity to _ contambullbullbull Ia the poutcr 11 the tlyaOJO 1111 TM olall col- - 001 iatcndc4 lor cftlclcY

I I I I

r~n hll

middot ll ~~l =~~Irrl l ~lil

f fl I

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 9: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

-------N

OTICE If tfto flho hoage

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an

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tht

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RE

CO

RD

qualttr of th

e docuMent

bolng fllbull o4middot

-agt

bull N

Cg

tshy2_1jttzbullbull5

2tti

iili~ ~

gJ

-sectlc

2o

bulltti

Oc

-1 cbull

Nc

~ z I

middot4f - rsS--~

(l

- -

middot

-+= )

-

)

)

---)

_Zl ~ co-bull_ c-o_Ru

~5110

Maxlmlm MCL01 foloof Mlnlmtntt

MCL1 ~ ~llllllol~llllllolQwlilll 39200

IIJQIIIIill 33050 29 (MW-109)0 4 (lloO 1400- 50 lOOO ll

Blri 01000

6 (MW-114 A 302) 33 -Beryllhua 14 (10114)l 302000 II (MW-IOl)

10 2230~middotmiddot

50 100 26 (Ul) 26lColdbullbull ll3~middotmiddot lJOO 90400cdlolt

1000 ~ l20300 l 2(MW-1048) 29 (Oil)roo 73600ldL )(1100 ~- 31050 02 (MW-201)32 (ll10)2 93

100 39l00 2 -N- 12

- 50 IJOOOO _ 1170middotmiddot - 10

l OOO

100000 9 (MW-301) - ll(ll)0 761l00~ 70 40 (36) 12000(MWmiddot98) l 9(MW) 100 l (MW-101) 36 (20)~ 70 23a- 7012middot__ 7 I7l l middot DklaoiOitla)MM 48l

0 3 (3) 600(MWJOlA)9 (MW-2038)

l ll (MWmiddot2048) 2000 2 9 (MW-2041) 2000Tol- 440 I 1JOO1000 l20 (MW-JOlA)Xylnll 2_

---_1-1(-dal GrovedMW CoosaaiDUl Freq ud CoeQIOlna Raa

NyUrampa-iltOI$110

ll(MW-1111) I 30 (MW-IISA) ~-tsladl- 10 (MW-107)l~ S6000 (MW-lllA)

tJamiddotJ)iaOrObeaiampM - bull 19 (MW-30S8)7SO 30 (3) SIOOOO (MW-113A)

14-p-- 41 (11)s 63 (MW-6A)600 610 16

tlo-~nc 3UlODOO(MW-lllA)100 (MW-1048)4-MampIgtyplloool IS SIOO(MW-11)IS (MW-30S8)NiuoliCIUIampM n SS100 (MW-113A)124-TricbiorobeftiCM - I3S (MW-10lt8)11 l30(MW-IISA) 170 (MW-611)

6N_ s 0 189 - 9 (MW-lll8) llmiddotDkhkKOitbaM 100 Ill100 l

111-TriCWofOitUIIamp 0 90 (MW-111) Vi ell- I 650 (MW-1048)ll(MW-117A)Mot~ 10 180 (MW-IIlA)96 (MW-96)1 a-NitMIOmiddotDimiddotbullmiddot 41000(MW-113A) s

ElMlt shyOil(lashy

ottbi eefJQ) 0001 (MW-118) iS (MW-108)

04 1 (37) 016 (MW-IOlA)Hololt I S4(MW-llll) 03S (MW-611)bullbullmiddot-ooT 3 OSS (MW-EAT-15)0011 (MW-IOS)- -IHC l 01 (MW-301)DelcamiddotIHC I 17(MW-9A)Dlol4rin ookgtfdabull Soutc~ Flftll WOfk Plla Jolyaaza 11 - orouactwater Sl14) Dcamber t917

Ortfl Prclilllinlty Suamary o( Site CbatKCriutioO NJUrampIIOIOO_St_ 191amp

1MO bull MM~d- Milia eoa-at tAYtl or EPA MO wtlkbcYCf is lllOfC ltriftstftL

1MCLO bull Mllfllbull eoaIIUMtt lAYtl 0oe1~ o( 63 ~ WIUI tS wdl polaU llllpkcent almbcn ia p~rcotMMS repraeat ~ampmpkl with

-ndoO _ MQ or MQO Wed_ aftM _ lioO ~ Ia - shy

I I

middot~ r

I

I I

) 0 WLIMINMY RfMEPIAl RpoundSPON$E OIJgcnyES

~po oOJoCiiOI for the Nyonu II middot Orobull- StY ~llf1 will be on the potential ror rokS to pbullblk ao4 the ca-roamltnL ~~~po objeCI not nnal and await completion of alltc-specilc tilt aiMU_L KoweYtr bUI4 01 CliltiOI dl~ wveral patbWI)l throuamph which humans

or tht eampMroruacll cou~ be tllpOie4 tO contamlnalll Ia pouactwatu bM been toeatlfiecl

o ttumaa cqu~~te tO coawainall pouactwaW wouP laiUoft Genna contaCt aR40r iobaiatloa if a water aupply aoune if dcwklfl at or bullr tbe 1Ue Ia tJre Mure

o cxpCIItiN 10 cootanUutell pou4WI W0MP 4Lrecl Qermal oonKl witb aDCl iobaltioD a( coowaiaUll lo eqMOYI or vapor lonD -piOI iato relideftdal ~~~ dodpdicnt rroca tbc lite

o u4 ~~tal apcllllfC 10 coocaalDUU froa poctwatcr once It ttiscUraeamp lato

wcda or tbe SuclbUIJ RiYef

Prtlhllinary ruS-1 rcspobull objecliwl tUt td4raamp tbelt poceatial apo~ure pathways inchiCampe

o Utaitilll pracatancl Murc riiD to humans cauMil b) apotUto to ooataminatc4 po~aactwatcr sltffacamp waterl aM -eau

o Ubullltilll deJfldltiol of tM Sltdb~try River aacl wetU41 liltamp to dischltp of coo~iaa- pouftdWiter and

o - appliltlgtbull ao4 rcplltlonl _ and ror PPY

MdltloNI- objeltIIWS may be 10pe4 on dall colleete4 In the Nyonull field intlplloa -middot aM 1M rilt performld bull ptn of tM RlFS

40 1QENDfJCampJON ANQ genNJNO OF DCtfNQIOOIE$

-- o( -middot-middot P- -torY o( tedlootol o(toldpdrll -inatiOn 11 1M Nytnaa _ EP teellnoloampY was evalolled on the - o( _ potclllal delnmiddotbullP -bull bull 11 MCU aod red- 1M potcntiol threat 10 poblllt

lbeuYitoii-L

Treat ~ pocealillly sllitab1 tor tM Nyaua liM wae ldPtifted Nled oa ~middot bull -n o( tM ~til oootaaiaatiol ull prcllnliIJ tctponsc objectiva The tcdtno~ - diYide4 iato ail calfIOI ucl catefMY rqwet~Rtilamp bull pp at re~pomamp actioU tblt covkl ___ -oOJoCiiOI

Sita eoauo1 COIItaillftlftl Treat_ ExtraciiOO

SlltdJIHiftthlll

)

lnncgtbulltll tedlooiOIa were identlllad rltgtntn4or JIIormampIIOD oa4 1ltc Superfloa4 ln_t TclthnOIOI)

Emiddotauadon Pro-= TtchnoloampY Proftlcs fJovember 1919 from tM EPA

42 TECHNOLOGY SCREENINO The laitlll scnertlol of~elthnolOampiOI wos - oa enampirinllelliblllry on4 oppllcobillry to tlto lOCidon or tlto NyortJA olte _ ntlytltotechnolOjlll wore-- oa agtnstroinu Imposelt by the rype or agtatomlnoau -middotc physkll agtn41tOns oltlto ute on4 _ or rettt~inlnl bull rault or tlto uurmenr p- croctcrlstlcl oltlto bullIre thll may or 11m1r tlto eKect_ o 1 tcchnOIOI) obtol - _ ltiptlOno Pbyskll propettY doll oltlto agtatominoau bullliCit olltllity bOiUal polaC -ry worc to oay lbolu Pttgte agtatominoau tbcmKIIIIY lmpaoe oabull ~todlaolOampYmiddot Wbullte ~- ldlatllod todelae - ltor ltlODII waste uatmcaL TiiM ~GftOIOIel wto1t a WM deatt) precluded by Wlll6 or site cUractcriitkl were elimltll rora--loa Tbc ults of this oltOill- _ rtsilmjp(Y Sqscoinl llfllms4i11TKbullIil (-May 1911~ TM ARCS te~a ldlatiGid odditlOnll toe~~aoOjielthll were

not coWdcred la ~ report Tobie 4middot1 Is 1 - o the remediatiOn tcchnoOjllltbat relftll after nln~ Tbc EbUltO-AilCS the )9techaoOjlllllstod oa Tobie 4-1 by-~ prodtKt lltCTIIUIC en4or inOrntltlOn pertonao doll -middot FSbull on4 bullhrobullJh dirlaquo agtnoultotiOO with n40ro A brie dOIltriptlOn of each

-~~-lnToblel-~

50 WASpound 1 ANQ u IRFAItBil m 1QT rsooRAM - Tbc tr0111hlliry _-1bull-to~ re-opodftlt -riOO reprdialthe perlormonlaquo

of--middot-ooiOilabullbull- shy ialtiol scneo~ POIIOtlll ftuncial rlsa on4 delaY lo - KtiOO oro _ with the --of 1 le(hnolOD lOr lmptementotlOn witbOIIt fl WfPOdaamp pcrfonMftCC data For tM uutabUity tCit PfOI-middot on-site bench-5CIIt telll wcro - oo troot-r -aoOjlll ooly II ipiOltoDI lt-1 lalOrmotiOO roprdinl the te(bldOI(i coM dketiyent- Of lrepkmotn~tbility cou4 M obtliaed at a rutOftlble eo~t P-I ud _U oltgte tlbiliry otudy ro-llad OltpDicl rrootmeftl pcctlvltly throop bettdt_ ~ lo ltloD _ relt~bull_ worc ideotltlcd durin the rroatobility otudy ud doll colieltrltd to_ the iDII_t_te otrubull u be to In evoiUitlnl

the applklbilicy o( MYCrtl ~~ tUt were aot btlldlmiddotbullbull From loorntltlOa ptherad ill - otudiOI dtamp woste dllrKterotlcl likely to lmplltt _-implemltDtobillry oadof-lalrroorrtechnolOIIOihbullbullicleifted

ThM -tlcs ladshyldiM rqeegliql middot A all llIIDbtr ol orpak alld iaorpllk contaminanu 1avt bctn ia 1t u- O~ ~~~ crronsmllkdJ to lavotw a ueaU1181 (a CCblalbull ol ubull- ) speorc proccu- oalpcd _ -----middot ()onlla _ shytlfiCdW fCIIiatlM CIOIIllaludoa

Ullf pracW middot Dtftdceciel Ia laflnlbulldol rcatilll 0 Ntk wttfl propen- sd pH oplaquotftlt Mry cooBOD TOC C DOl alii TM Rl ud ueaiblhlJ It~bull ld4rtU theM ~ ao4 flrthct We1Uify lmportut niMCtl li ely to illft lM trfectiveiIM o( UbullUMIIIII at~rNii-

10

--

I )

_ lloos-qSIolt __

Nua a-loll

ROlli tillXJl~

$11tOgtouol XFcaciaiiSP X X

loltihlioUl Coauoll ~- X5latfacc Waw Coluol

~ XCpplbulll XH)dnulkBarrilt Oroddw~MI lalaeeptor T~ftdl X

XFnaOIOIItiqo_ lajocdoll X

_ XtJmiddot

shyX

X =middot X

Wet Alr ()ddadoll1 X

~ XPNdplampl~lioiISediNalldol X -Locll w n~t FtdUa X XOI~WTNa-tFKIMtJ X -Potarilld ~ ()Ddaat ~o~J

DJiilll X sai-Fioill- XTllibull Fla EYapORlioas NltSiripplacc_-loa- X

-~ XMed6l FUusliol X ---X

X X

II

)

I

IJ r

-~ ~- Dnla - (_

lMIIWI IIPDES lllodWJO ~kMIIO Orouftdwltcr

shyDlll-CaUilloll ---middot lelt FUIIr FlloorPIW Onvlty1gtidtal01 v nmtiol

Rcta1M4 xa lfll

X X

X X X

X X

X X X X

1 tucwetM TtcUooD tbat il paR ot EPA Silamp OOMUIioll Proanbull middot turrcatty btiq rldd 1 1M Towll of AIJI)a ot M11 I p11bUdJ opaatcd _let UUIIMilt fidtlty

3 lllMMlM TdiiOkgtD

11

--

----

-I )

lllllo_Z ~ ot Orww Re8ldiadol T_

llyua QcUal Silo

FeocfAtSipl

llldaltioul ColiUOII

~loll Molltortq

Slllflcr Water Cotluol

ClppUit

tfJaiiUc Ianier

Groundwater lnjeaion

Reltrkt ~wt~ fuKll poll watIUill tlpl

11 lud or otMt NllricdoU to proltibh tbc use ol JfOIIIIChILtriiiMIMtilt

EYihaale mlpaliol ud dillriiMaUoll of eo~~~amp~~luaamps Oyener tiiDC ~a~ina 11orina 10 aapll lM CMIHnlal alliS bedroct aquller

ConUOI slllflct waw ru4 owr Ike 1114 lbuefore lallltrat6oa to poundwttar

Pmat iaftltraliiMI ot _doll iiiO coatlaiuted ZOIIII wiU a RCilA 111dtimiddotlayet cap or OlMr cappWc bullterilil

OMrt ltMItMUda pouctwaamper ftow aroud contlmintted zona willa limy Wlwat piliq

ampLiblillrl 1 bedroct ~ _ulictlly bullptradient of the site 10 tower JfOUMwalel dMidoll il coaaaaiuS

Pmut JfOUDdwalef _ tlarotaP COIItlflliMtcd IODa by poutiq Mdrock traura

laect wttrr Into the Jf0111Mh1W to bydnulkllly prevtnt the funhct miJfltioo ot COGtamiauq

ltiuod abulllriull ld 01J111 iiiiO liM JfOUMIWIIer aiGJ I uix of atiKI~ wdll lid redmd1Ui01 amnktues 10 stimulate

~middot- __ _ _ _ICampMIM _or~bull lltIHolopcal NeQOr

(ampJ I trictllq IUICf tOCatilt ~ CIOIIIKtOII)

I)

IIitr 1~

bullbull

) I ~

t~r~

Acrltioft

_ Otf-tlbull wT

FtciiiY

PolarU4 Mlt4iiJ()WolvOd QDdall 1M

()llidbe orpakl ill atJICUIIII pouadMIU willa I llal1tiOCO

applklt of ll~ upt aad a rona oQdilcr

Otatroy orpaic co~wafuall La aa aq~~M~Gtll IOiudOD by iDdMiaJ ollidadoll aiMI laydtolylil reeaiOM at lllP waperauuc aDd prt~Suramp Olyp at ekWUid _ cabaDC tbamp oddat~D of orpak

coapoddlto carbOa diolidamp bullbullmiddot

AI1111C tM lfOIadWatlt 10 ~ iaoJpClk itOft and mlfiMM andmiddot-middot- middot-eo-t dillotvd 10 aa tolubae font (lc metal sulftde W ~or boa aauta) padld tOiiclltiUOUIJI

ftoealladoa settle out IOl6dl ~ plilJmiddot

Dildlotl atroaed --to-- ()wOOdTNat_t WOJIII (POTWl for ubulltbullat Water mISt rr preutbullat llllldl141 bdofC diiCIW 10 tillamp fadlicy

adDente ubullbullbullbullbull _ (sl cartiOII) at aa ol-liw

Killty 1rllff coaUUMII CK (OIICIampIItrtlld wu~ to offmiddotslte (tctlity rot flnhcr ubulltmcnt

Olddizt orpnicS and c~rot)kll~ ftltcr ioM dint ionized OIYfll u4 aiuotta and llltflliokl IJbL

___ - --Ia aM it8ptn-~ Ofkl taps pUtt

coa-w toa bullrx pedwlta bJ liOUiaJ oft WI OOII(IIIItnlioM or VOC SVOO ill a cohama partedwilllt~enbulltlriiL w -doflfaucotbull bull-ait lxltl tllll _ bull plaquo dle - anMfw of VOOJSVOCI frola u oq_ _ shy

I )

~

~t-tiaed)

naiiiampUlliWIIIIilcu-_

loa-middot _ Me4il fltratioa

flltntioa

OfOIwhmpiaamp

Or~ialrucrotptor

llillllll Loodlll

NPOES OllcUrl

Rod---o1- 0lt _ orpako tJuobullP tdiOrpdoa oato paa ~Mwd cartMML Mey be ased u a poUsblaamp ~~ aMr uea~l tla 111 UVOIOUttoll or tir atrippinampW reiDOyenC

~allfdClld CQIIdta

Separate CODCCIUIwd Cl)lllaiUaU rro- mtiClld water ISinabull semimiddot

--- RcmcM bull sol fJOM tlrl WMteWllet iltum by fordbullamp

water nwP a aM tu~a or cartridbullmiddotYfC filter

ttclftOYamp sol aacl bullWI frOil wuaew~tcr auum 111in1 1 mcrnbraM _ fltract pvftdWttcf frOCft Cl Of lfiOfS cstrectiotl - tO CORtrol Of rcWM tM UlkrW CCMI _ Qf0111141w1 wouMI be uealld oa-Mat UUifONd 10 bullbull olaquo-tiw ~licy or diKNrJICllnto ~n lor

-J()IW Colkld JfOIIdwiiCt Ia ~pawl Drtin to allow treampUMIIt to

take pLaee

saare ue~-t rtiM~tamp ( _ thadae ipCil caWft) Ia aa oCImiddot

JtCilA rdliJmiddot OllcUtl P hlw tiM atona draiM ttWU MtfliiOfk or latO 1M ltMf hi tttal OIICraquorp OCitiOI wid M ___ -~u flooltftlotwiUIIoo

to ~toe tM rtetM

lei~ Utamptarou Net Wlwt the JfOIII sinamp OM or ~wtlll

II

)

lfu Use cutrtrpl torce 10 _ tM MdlJMllltioa rate of thtdJI

Dtwaters illldp by dfliUII giDlP lM ahadJC Nil aDd tv~poratioa frolltMwrc IOaitmiddot

()ewaterstl~IC by ~~Mill a coatLa- tuw belt tNt nbull over a drive aDd auide roUir 11uca llld Ukamp I (II)IIW70I MIL Shtdp is cootifliIOampSly diWiwed btCWMI lM IUW bella

otMten lllldfl _ ~ whll ~ Wlef 0 _ - _ - -Uto4-~ dcWitcritll IMlbOdl belli

Reduce tM IOiubull of 11-bull -cwal o( supetnltllll liquMt

Ocwatcn st~ae usiaa bull roampary cbullbullbull nuer

16

)

l l nCHNOLOOlES EVALUAreD l ao4llbelldl IAiiq wu 10 dcmOnsttalCthc cffcttln ol 1 tcthnoloJY In rc4ocinamp

poo-m coataonloanl that Clbt ao Nya to tbe MCUmiddot lie ronowlnamp oclttions daCribC bullbullbull UOIUDIGl ~eotalti~Md aDd lbC raOOoale lor cMIOIIDI ltlCII

lll EMIIJIIIIl l belldlmiddotIAiiq prcclpllltiooftOCltIIlaiiOalc4(tDCnlllioD and oa14atlonlflt40Cilon (-) ttquiR- 1llil wu tloDamp 10 delCrtniDC -1 and ooo41tiODI lor optimum rem o -_colloidal ao4 - - 1bC co11101lnatetl poutcr Hy4_ aetl 101idamp prodpilltiOtiWU -tlpte4 lo tbC PPM llludiiL ()aldatlottftetloctiDI rtqUitemCIII I

pK raaF for optimum metab reatQyenal wM abO bullgttilbOLIt~ IIUlytt preucat-14 be 10 _and rod 110bull conccnttatlons _ Ibull po ao Nyan belorlt othet lampdtoO _be _ Wit preucattneDI inorpnicllllll plbulll ca- _ IQlinl In alfoltripplol __ rod UV cftlclcncicS or ao nely lmpoct bioloPltl --bullbull perlortnl_ will abO tnellb loetli on polbullhlnamp proocUOI (I~ loa ()( rcverM 01100111) A _- o pacoot rlt-la i quoJilll _tiODI o( --lalioo (OrtMiloD led 10 IIIC -tillcatiOO o -F nnp (Or by4- polJIIIC (prodpllltiOO) ltyd-bull pcOildlt (-l icll_ ulllntbCCIeCI -o(lnoltPDicl D-pranpwerlt-olttbe p__ ill _ ll tina Table l middot l - tile tAl roo prod tbe boll r ulll

l ll Olll)llJIIlDurinamp ll lour etlditlonoltcchnololi boftdtmiddotICI oliOOIDI prcucattnCDI o arooICr 10 rc4uca- ampnorpnicl ThiiO lour_ were ioD altOinFo dlft bubble _oo ca____ ___L _ bull-bullbull- olt blllllll

-(LL bull 11rippln1 prior to actlvatc4 ca- Of ICiiVIte4 ca- ollor ___) _etiOI-1--Iol- loO_DF_ te41orinorpa1Crc-looly ea- _aott aoddiffuetl __ _ rororpolc -L BioloampICO__ tawd for botb i801pntt aD4 orpaic rcmovab lie PhiiC ll ideatlllcd tltc need to aetl lmplctneat ucattnCOI mcthOdl lor rc-1 o orpnicl For wmplc combibull bullbullabull 11rippin1 with acttvatc4 carbObull ucatmcat may be n_ary bullroomo cootantloaall arc dgtft~Cullto 11rip but -Uy 10 carbOn Altcrnatly c4 carbOn tniY be a pol~biDI 11cp ~ bioloalel ucatmcat bull cmplo)_ Tablel l-lto l -1 dcocribe Utbullt _ TIMamp 5-1 ilkoliftll tM water ctalily o( ttlamp r- Wllel priot ampa precipiudcm prcucaunenL

U 1Uf OBIECttvES _ o l ao4 ll beodt - 10 middot-- o - -o( ao4 -ubullilllbullbullbullbull pou-tallmpliiOOlshy11 1M tltyaua to beloW MOI TM bulltillamp- abO- 10 _1-middot-_---middot- piClypC o cacUaac - teiCOI ua- TbullriDI- oooductc4 to _ I rltllablt o IM tceJIOlOIYS abnity to _ contambullbullbull Ia the poutcr 11 the tlyaOJO 1111 TM olall col- - 001 iatcndc4 lor cftlclcY

I I I I

r~n hll

middot ll ~~l =~~Irrl l ~lil

f fl I

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 10: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

)

)

---)

_Zl ~ co-bull_ c-o_Ru

~5110

Maxlmlm MCL01 foloof Mlnlmtntt

MCL1 ~ ~llllllol~llllllolQwlilll 39200

IIJQIIIIill 33050 29 (MW-109)0 4 (lloO 1400- 50 lOOO ll

Blri 01000

6 (MW-114 A 302) 33 -Beryllhua 14 (10114)l 302000 II (MW-IOl)

10 2230~middotmiddot

50 100 26 (Ul) 26lColdbullbull ll3~middotmiddot lJOO 90400cdlolt

1000 ~ l20300 l 2(MW-1048) 29 (Oil)roo 73600ldL )(1100 ~- 31050 02 (MW-201)32 (ll10)2 93

100 39l00 2 -N- 12

- 50 IJOOOO _ 1170middotmiddot - 10

l OOO

100000 9 (MW-301) - ll(ll)0 761l00~ 70 40 (36) 12000(MWmiddot98) l 9(MW) 100 l (MW-101) 36 (20)~ 70 23a- 7012middot__ 7 I7l l middot DklaoiOitla)MM 48l

0 3 (3) 600(MWJOlA)9 (MW-2038)

l ll (MWmiddot2048) 2000 2 9 (MW-2041) 2000Tol- 440 I 1JOO1000 l20 (MW-JOlA)Xylnll 2_

---_1-1(-dal GrovedMW CoosaaiDUl Freq ud CoeQIOlna Raa

NyUrampa-iltOI$110

ll(MW-1111) I 30 (MW-IISA) ~-tsladl- 10 (MW-107)l~ S6000 (MW-lllA)

tJamiddotJ)iaOrObeaiampM - bull 19 (MW-30S8)7SO 30 (3) SIOOOO (MW-113A)

14-p-- 41 (11)s 63 (MW-6A)600 610 16

tlo-~nc 3UlODOO(MW-lllA)100 (MW-1048)4-MampIgtyplloool IS SIOO(MW-11)IS (MW-30S8)NiuoliCIUIampM n SS100 (MW-113A)124-TricbiorobeftiCM - I3S (MW-10lt8)11 l30(MW-IISA) 170 (MW-611)

6N_ s 0 189 - 9 (MW-lll8) llmiddotDkhkKOitbaM 100 Ill100 l

111-TriCWofOitUIIamp 0 90 (MW-111) Vi ell- I 650 (MW-1048)ll(MW-117A)Mot~ 10 180 (MW-IIlA)96 (MW-96)1 a-NitMIOmiddotDimiddotbullmiddot 41000(MW-113A) s

ElMlt shyOil(lashy

ottbi eefJQ) 0001 (MW-118) iS (MW-108)

04 1 (37) 016 (MW-IOlA)Hololt I S4(MW-llll) 03S (MW-611)bullbullmiddot-ooT 3 OSS (MW-EAT-15)0011 (MW-IOS)- -IHC l 01 (MW-301)DelcamiddotIHC I 17(MW-9A)Dlol4rin ookgtfdabull Soutc~ Flftll WOfk Plla Jolyaaza 11 - orouactwater Sl14) Dcamber t917

Ortfl Prclilllinlty Suamary o( Site CbatKCriutioO NJUrampIIOIOO_St_ 191amp

1MO bull MM~d- Milia eoa-at tAYtl or EPA MO wtlkbcYCf is lllOfC ltriftstftL

1MCLO bull Mllfllbull eoaIIUMtt lAYtl 0oe1~ o( 63 ~ WIUI tS wdl polaU llllpkcent almbcn ia p~rcotMMS repraeat ~ampmpkl with

-ndoO _ MQ or MQO Wed_ aftM _ lioO ~ Ia - shy

I I

middot~ r

I

I I

) 0 WLIMINMY RfMEPIAl RpoundSPON$E OIJgcnyES

~po oOJoCiiOI for the Nyonu II middot Orobull- StY ~llf1 will be on the potential ror rokS to pbullblk ao4 the ca-roamltnL ~~~po objeCI not nnal and await completion of alltc-specilc tilt aiMU_L KoweYtr bUI4 01 CliltiOI dl~ wveral patbWI)l throuamph which humans

or tht eampMroruacll cou~ be tllpOie4 tO contamlnalll Ia pouactwatu bM been toeatlfiecl

o ttumaa cqu~~te tO coawainall pouactwaW wouP laiUoft Genna contaCt aR40r iobaiatloa if a water aupply aoune if dcwklfl at or bullr tbe 1Ue Ia tJre Mure

o cxpCIItiN 10 cootanUutell pou4WI W0MP 4Lrecl Qermal oonKl witb aDCl iobaltioD a( coowaiaUll lo eqMOYI or vapor lonD -piOI iato relideftdal ~~~ dodpdicnt rroca tbc lite

o u4 ~~tal apcllllfC 10 coocaalDUU froa poctwatcr once It ttiscUraeamp lato

wcda or tbe SuclbUIJ RiYef

Prtlhllinary ruS-1 rcspobull objecliwl tUt td4raamp tbelt poceatial apo~ure pathways inchiCampe

o Utaitilll pracatancl Murc riiD to humans cauMil b) apotUto to ooataminatc4 po~aactwatcr sltffacamp waterl aM -eau

o Ubullltilll deJfldltiol of tM Sltdb~try River aacl wetU41 liltamp to dischltp of coo~iaa- pouftdWiter and

o - appliltlgtbull ao4 rcplltlonl _ and ror PPY

MdltloNI- objeltIIWS may be 10pe4 on dall colleete4 In the Nyonull field intlplloa -middot aM 1M rilt performld bull ptn of tM RlFS

40 1QENDfJCampJON ANQ genNJNO OF DCtfNQIOOIE$

-- o( -middot-middot P- -torY o( tedlootol o(toldpdrll -inatiOn 11 1M Nytnaa _ EP teellnoloampY was evalolled on the - o( _ potclllal delnmiddotbullP -bull bull 11 MCU aod red- 1M potcntiol threat 10 poblllt

lbeuYitoii-L

Treat ~ pocealillly sllitab1 tor tM Nyaua liM wae ldPtifted Nled oa ~middot bull -n o( tM ~til oootaaiaatiol ull prcllnliIJ tctponsc objectiva The tcdtno~ - diYide4 iato ail calfIOI ucl catefMY rqwet~Rtilamp bull pp at re~pomamp actioU tblt covkl ___ -oOJoCiiOI

Sita eoauo1 COIItaillftlftl Treat_ ExtraciiOO

SlltdJIHiftthlll

)

lnncgtbulltll tedlooiOIa were identlllad rltgtntn4or JIIormampIIOD oa4 1ltc Superfloa4 ln_t TclthnOIOI)

Emiddotauadon Pro-= TtchnoloampY Proftlcs fJovember 1919 from tM EPA

42 TECHNOLOGY SCREENINO The laitlll scnertlol of~elthnolOampiOI wos - oa enampirinllelliblllry on4 oppllcobillry to tlto lOCidon or tlto NyortJA olte _ ntlytltotechnolOjlll wore-- oa agtnstroinu Imposelt by the rype or agtatomlnoau -middotc physkll agtn41tOns oltlto ute on4 _ or rettt~inlnl bull rault or tlto uurmenr p- croctcrlstlcl oltlto bullIre thll may or 11m1r tlto eKect_ o 1 tcchnOIOI) obtol - _ ltiptlOno Pbyskll propettY doll oltlto agtatominoau bullliCit olltllity bOiUal polaC -ry worc to oay lbolu Pttgte agtatominoau tbcmKIIIIY lmpaoe oabull ~todlaolOampYmiddot Wbullte ~- ldlatllod todelae - ltor ltlODII waste uatmcaL TiiM ~GftOIOIel wto1t a WM deatt) precluded by Wlll6 or site cUractcriitkl were elimltll rora--loa Tbc ults of this oltOill- _ rtsilmjp(Y Sqscoinl llfllms4i11TKbullIil (-May 1911~ TM ARCS te~a ldlatiGid odditlOnll toe~~aoOjielthll were

not coWdcred la ~ report Tobie 4middot1 Is 1 - o the remediatiOn tcchnoOjllltbat relftll after nln~ Tbc EbUltO-AilCS the )9techaoOjlllllstod oa Tobie 4-1 by-~ prodtKt lltCTIIUIC en4or inOrntltlOn pertonao doll -middot FSbull on4 bullhrobullJh dirlaquo agtnoultotiOO with n40ro A brie dOIltriptlOn of each

-~~-lnToblel-~

50 WASpound 1 ANQ u IRFAItBil m 1QT rsooRAM - Tbc tr0111hlliry _-1bull-to~ re-opodftlt -riOO reprdialthe perlormonlaquo

of--middot-ooiOilabullbull- shy ialtiol scneo~ POIIOtlll ftuncial rlsa on4 delaY lo - KtiOO oro _ with the --of 1 le(hnolOD lOr lmptementotlOn witbOIIt fl WfPOdaamp pcrfonMftCC data For tM uutabUity tCit PfOI-middot on-site bench-5CIIt telll wcro - oo troot-r -aoOjlll ooly II ipiOltoDI lt-1 lalOrmotiOO roprdinl the te(bldOI(i coM dketiyent- Of lrepkmotn~tbility cou4 M obtliaed at a rutOftlble eo~t P-I ud _U oltgte tlbiliry otudy ro-llad OltpDicl rrootmeftl pcctlvltly throop bettdt_ ~ lo ltloD _ relt~bull_ worc ideotltlcd durin the rroatobility otudy ud doll colieltrltd to_ the iDII_t_te otrubull u be to In evoiUitlnl

the applklbilicy o( MYCrtl ~~ tUt were aot btlldlmiddotbullbull From loorntltlOa ptherad ill - otudiOI dtamp woste dllrKterotlcl likely to lmplltt _-implemltDtobillry oadof-lalrroorrtechnolOIIOihbullbullicleifted

ThM -tlcs ladshyldiM rqeegliql middot A all llIIDbtr ol orpak alld iaorpllk contaminanu 1avt bctn ia 1t u- O~ ~~~ crronsmllkdJ to lavotw a ueaU1181 (a CCblalbull ol ubull- ) speorc proccu- oalpcd _ -----middot ()onlla _ shytlfiCdW fCIIiatlM CIOIIllaludoa

Ullf pracW middot Dtftdceciel Ia laflnlbulldol rcatilll 0 Ntk wttfl propen- sd pH oplaquotftlt Mry cooBOD TOC C DOl alii TM Rl ud ueaiblhlJ It~bull ld4rtU theM ~ ao4 flrthct We1Uify lmportut niMCtl li ely to illft lM trfectiveiIM o( UbullUMIIIII at~rNii-

10

--

I )

_ lloos-qSIolt __

Nua a-loll

ROlli tillXJl~

$11tOgtouol XFcaciaiiSP X X

loltihlioUl Coauoll ~- X5latfacc Waw Coluol

~ XCpplbulll XH)dnulkBarrilt Oroddw~MI lalaeeptor T~ftdl X

XFnaOIOIItiqo_ lajocdoll X

_ XtJmiddot

shyX

X =middot X

Wet Alr ()ddadoll1 X

~ XPNdplampl~lioiISediNalldol X -Locll w n~t FtdUa X XOI~WTNa-tFKIMtJ X -Potarilld ~ ()Ddaat ~o~J

DJiilll X sai-Fioill- XTllibull Fla EYapORlioas NltSiripplacc_-loa- X

-~ XMed6l FUusliol X ---X

X X

II

)

I

IJ r

-~ ~- Dnla - (_

lMIIWI IIPDES lllodWJO ~kMIIO Orouftdwltcr

shyDlll-CaUilloll ---middot lelt FUIIr FlloorPIW Onvlty1gtidtal01 v nmtiol

Rcta1M4 xa lfll

X X

X X X

X X

X X X X

1 tucwetM TtcUooD tbat il paR ot EPA Silamp OOMUIioll Proanbull middot turrcatty btiq rldd 1 1M Towll of AIJI)a ot M11 I p11bUdJ opaatcd _let UUIIMilt fidtlty

3 lllMMlM TdiiOkgtD

11

--

----

-I )

lllllo_Z ~ ot Orww Re8ldiadol T_

llyua QcUal Silo

FeocfAtSipl

llldaltioul ColiUOII

~loll Molltortq

Slllflcr Water Cotluol

ClppUit

tfJaiiUc Ianier

Groundwater lnjeaion

Reltrkt ~wt~ fuKll poll watIUill tlpl

11 lud or otMt NllricdoU to proltibh tbc use ol JfOIIIIChILtriiiMIMtilt

EYihaale mlpaliol ud dillriiMaUoll of eo~~~amp~~luaamps Oyener tiiDC ~a~ina 11orina 10 aapll lM CMIHnlal alliS bedroct aquller

ConUOI slllflct waw ru4 owr Ike 1114 lbuefore lallltrat6oa to poundwttar

Pmat iaftltraliiMI ot _doll iiiO coatlaiuted ZOIIII wiU a RCilA 111dtimiddotlayet cap or OlMr cappWc bullterilil

OMrt ltMItMUda pouctwaamper ftow aroud contlmintted zona willa limy Wlwat piliq

ampLiblillrl 1 bedroct ~ _ulictlly bullptradient of the site 10 tower JfOUMwalel dMidoll il coaaaaiuS

Pmut JfOUDdwalef _ tlarotaP COIItlflliMtcd IODa by poutiq Mdrock traura

laect wttrr Into the Jf0111Mh1W to bydnulkllly prevtnt the funhct miJfltioo ot COGtamiauq

ltiuod abulllriull ld 01J111 iiiiO liM JfOUMIWIIer aiGJ I uix of atiKI~ wdll lid redmd1Ui01 amnktues 10 stimulate

~middot- __ _ _ _ICampMIM _or~bull lltIHolopcal NeQOr

(ampJ I trictllq IUICf tOCatilt ~ CIOIIIKtOII)

I)

IIitr 1~

bullbull

) I ~

t~r~

Acrltioft

_ Otf-tlbull wT

FtciiiY

PolarU4 Mlt4iiJ()WolvOd QDdall 1M

()llidbe orpakl ill atJICUIIII pouadMIU willa I llal1tiOCO

applklt of ll~ upt aad a rona oQdilcr

Otatroy orpaic co~wafuall La aa aq~~M~Gtll IOiudOD by iDdMiaJ ollidadoll aiMI laydtolylil reeaiOM at lllP waperauuc aDd prt~Suramp Olyp at ekWUid _ cabaDC tbamp oddat~D of orpak

coapoddlto carbOa diolidamp bullbullmiddot

AI1111C tM lfOIadWatlt 10 ~ iaoJpClk itOft and mlfiMM andmiddot-middot- middot-eo-t dillotvd 10 aa tolubae font (lc metal sulftde W ~or boa aauta) padld tOiiclltiUOUIJI

ftoealladoa settle out IOl6dl ~ plilJmiddot

Dildlotl atroaed --to-- ()wOOdTNat_t WOJIII (POTWl for ubulltbullat Water mISt rr preutbullat llllldl141 bdofC diiCIW 10 tillamp fadlicy

adDente ubullbullbullbullbull _ (sl cartiOII) at aa ol-liw

Killty 1rllff coaUUMII CK (OIICIampIItrtlld wu~ to offmiddotslte (tctlity rot flnhcr ubulltmcnt

Olddizt orpnicS and c~rot)kll~ ftltcr ioM dint ionized OIYfll u4 aiuotta and llltflliokl IJbL

___ - --Ia aM it8ptn-~ Ofkl taps pUtt

coa-w toa bullrx pedwlta bJ liOUiaJ oft WI OOII(IIIItnlioM or VOC SVOO ill a cohama partedwilllt~enbulltlriiL w -doflfaucotbull bull-ait lxltl tllll _ bull plaquo dle - anMfw of VOOJSVOCI frola u oq_ _ shy

I )

~

~t-tiaed)

naiiiampUlliWIIIIilcu-_

loa-middot _ Me4il fltratioa

flltntioa

OfOIwhmpiaamp

Or~ialrucrotptor

llillllll Loodlll

NPOES OllcUrl

Rod---o1- 0lt _ orpako tJuobullP tdiOrpdoa oato paa ~Mwd cartMML Mey be ased u a poUsblaamp ~~ aMr uea~l tla 111 UVOIOUttoll or tir atrippinampW reiDOyenC

~allfdClld CQIIdta

Separate CODCCIUIwd Cl)lllaiUaU rro- mtiClld water ISinabull semimiddot

--- RcmcM bull sol fJOM tlrl WMteWllet iltum by fordbullamp

water nwP a aM tu~a or cartridbullmiddotYfC filter

ttclftOYamp sol aacl bullWI frOil wuaew~tcr auum 111in1 1 mcrnbraM _ fltract pvftdWttcf frOCft Cl Of lfiOfS cstrectiotl - tO CORtrol Of rcWM tM UlkrW CCMI _ Qf0111141w1 wouMI be uealld oa-Mat UUifONd 10 bullbull olaquo-tiw ~licy or diKNrJICllnto ~n lor

-J()IW Colkld JfOIIdwiiCt Ia ~pawl Drtin to allow treampUMIIt to

take pLaee

saare ue~-t rtiM~tamp ( _ thadae ipCil caWft) Ia aa oCImiddot

JtCilA rdliJmiddot OllcUtl P hlw tiM atona draiM ttWU MtfliiOfk or latO 1M ltMf hi tttal OIICraquorp OCitiOI wid M ___ -~u flooltftlotwiUIIoo

to ~toe tM rtetM

lei~ Utamptarou Net Wlwt the JfOIII sinamp OM or ~wtlll

II

)

lfu Use cutrtrpl torce 10 _ tM MdlJMllltioa rate of thtdJI

Dtwaters illldp by dfliUII giDlP lM ahadJC Nil aDd tv~poratioa frolltMwrc IOaitmiddot

()ewaterstl~IC by ~~Mill a coatLa- tuw belt tNt nbull over a drive aDd auide roUir 11uca llld Ukamp I (II)IIW70I MIL Shtdp is cootifliIOampSly diWiwed btCWMI lM IUW bella

otMten lllldfl _ ~ whll ~ Wlef 0 _ - _ - -Uto4-~ dcWitcritll IMlbOdl belli

Reduce tM IOiubull of 11-bull -cwal o( supetnltllll liquMt

Ocwatcn st~ae usiaa bull roampary cbullbullbull nuer

16

)

l l nCHNOLOOlES EVALUAreD l ao4llbelldl IAiiq wu 10 dcmOnsttalCthc cffcttln ol 1 tcthnoloJY In rc4ocinamp

poo-m coataonloanl that Clbt ao Nya to tbe MCUmiddot lie ronowlnamp oclttions daCribC bullbullbull UOIUDIGl ~eotalti~Md aDd lbC raOOoale lor cMIOIIDI ltlCII

lll EMIIJIIIIl l belldlmiddotIAiiq prcclpllltiooftOCltIIlaiiOalc4(tDCnlllioD and oa14atlonlflt40Cilon (-) ttquiR- 1llil wu tloDamp 10 delCrtniDC -1 and ooo41tiODI lor optimum rem o -_colloidal ao4 - - 1bC co11101lnatetl poutcr Hy4_ aetl 101idamp prodpilltiOtiWU -tlpte4 lo tbC PPM llludiiL ()aldatlottftetloctiDI rtqUitemCIII I

pK raaF for optimum metab reatQyenal wM abO bullgttilbOLIt~ IIUlytt preucat-14 be 10 _and rod 110bull conccnttatlons _ Ibull po ao Nyan belorlt othet lampdtoO _be _ Wit preucattneDI inorpnicllllll plbulll ca- _ IQlinl In alfoltripplol __ rod UV cftlclcncicS or ao nely lmpoct bioloPltl --bullbull perlortnl_ will abO tnellb loetli on polbullhlnamp proocUOI (I~ loa ()( rcverM 01100111) A _- o pacoot rlt-la i quoJilll _tiODI o( --lalioo (OrtMiloD led 10 IIIC -tillcatiOO o -F nnp (Or by4- polJIIIC (prodpllltiOO) ltyd-bull pcOildlt (-l icll_ ulllntbCCIeCI -o(lnoltPDicl D-pranpwerlt-olttbe p__ ill _ ll tina Table l middot l - tile tAl roo prod tbe boll r ulll

l ll Olll)llJIIlDurinamp ll lour etlditlonoltcchnololi boftdtmiddotICI oliOOIDI prcucattnCDI o arooICr 10 rc4uca- ampnorpnicl ThiiO lour_ were ioD altOinFo dlft bubble _oo ca____ ___L _ bull-bullbull- olt blllllll

-(LL bull 11rippln1 prior to actlvatc4 ca- Of ICiiVIte4 ca- ollor ___) _etiOI-1--Iol- loO_DF_ te41orinorpa1Crc-looly ea- _aott aoddiffuetl __ _ rororpolc -L BioloampICO__ tawd for botb i801pntt aD4 orpaic rcmovab lie PhiiC ll ideatlllcd tltc need to aetl lmplctneat ucattnCOI mcthOdl lor rc-1 o orpnicl For wmplc combibull bullbullabull 11rippin1 with acttvatc4 carbObull ucatmcat may be n_ary bullroomo cootantloaall arc dgtft~Cullto 11rip but -Uy 10 carbOn Altcrnatly c4 carbOn tniY be a pol~biDI 11cp ~ bioloalel ucatmcat bull cmplo)_ Tablel l-lto l -1 dcocribe Utbullt _ TIMamp 5-1 ilkoliftll tM water ctalily o( ttlamp r- Wllel priot ampa precipiudcm prcucaunenL

U 1Uf OBIECttvES _ o l ao4 ll beodt - 10 middot-- o - -o( ao4 -ubullilllbullbullbullbull pou-tallmpliiOOlshy11 1M tltyaua to beloW MOI TM bulltillamp- abO- 10 _1-middot-_---middot- piClypC o cacUaac - teiCOI ua- TbullriDI- oooductc4 to _ I rltllablt o IM tceJIOlOIYS abnity to _ contambullbullbull Ia the poutcr 11 the tlyaOJO 1111 TM olall col- - 001 iatcndc4 lor cftlclcY

I I I I

r~n hll

middot ll ~~l =~~Irrl l ~lil

f fl I

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 11: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

)

---)

_Zl ~ co-bull_ c-o_Ru

~5110

Maxlmlm MCL01 foloof Mlnlmtntt

MCL1 ~ ~llllllol~llllllolQwlilll 39200

IIJQIIIIill 33050 29 (MW-109)0 4 (lloO 1400- 50 lOOO ll

Blri 01000

6 (MW-114 A 302) 33 -Beryllhua 14 (10114)l 302000 II (MW-IOl)

10 2230~middotmiddot

50 100 26 (Ul) 26lColdbullbull ll3~middotmiddot lJOO 90400cdlolt

1000 ~ l20300 l 2(MW-1048) 29 (Oil)roo 73600ldL )(1100 ~- 31050 02 (MW-201)32 (ll10)2 93

100 39l00 2 -N- 12

- 50 IJOOOO _ 1170middotmiddot - 10

l OOO

100000 9 (MW-301) - ll(ll)0 761l00~ 70 40 (36) 12000(MWmiddot98) l 9(MW) 100 l (MW-101) 36 (20)~ 70 23a- 7012middot__ 7 I7l l middot DklaoiOitla)MM 48l

0 3 (3) 600(MWJOlA)9 (MW-2038)

l ll (MWmiddot2048) 2000 2 9 (MW-2041) 2000Tol- 440 I 1JOO1000 l20 (MW-JOlA)Xylnll 2_

---_1-1(-dal GrovedMW CoosaaiDUl Freq ud CoeQIOlna Raa

NyUrampa-iltOI$110

ll(MW-1111) I 30 (MW-IISA) ~-tsladl- 10 (MW-107)l~ S6000 (MW-lllA)

tJamiddotJ)iaOrObeaiampM - bull 19 (MW-30S8)7SO 30 (3) SIOOOO (MW-113A)

14-p-- 41 (11)s 63 (MW-6A)600 610 16

tlo-~nc 3UlODOO(MW-lllA)100 (MW-1048)4-MampIgtyplloool IS SIOO(MW-11)IS (MW-30S8)NiuoliCIUIampM n SS100 (MW-113A)124-TricbiorobeftiCM - I3S (MW-10lt8)11 l30(MW-IISA) 170 (MW-611)

6N_ s 0 189 - 9 (MW-lll8) llmiddotDkhkKOitbaM 100 Ill100 l

111-TriCWofOitUIIamp 0 90 (MW-111) Vi ell- I 650 (MW-1048)ll(MW-117A)Mot~ 10 180 (MW-IIlA)96 (MW-96)1 a-NitMIOmiddotDimiddotbullmiddot 41000(MW-113A) s

ElMlt shyOil(lashy

ottbi eefJQ) 0001 (MW-118) iS (MW-108)

04 1 (37) 016 (MW-IOlA)Hololt I S4(MW-llll) 03S (MW-611)bullbullmiddot-ooT 3 OSS (MW-EAT-15)0011 (MW-IOS)- -IHC l 01 (MW-301)DelcamiddotIHC I 17(MW-9A)Dlol4rin ookgtfdabull Soutc~ Flftll WOfk Plla Jolyaaza 11 - orouactwater Sl14) Dcamber t917

Ortfl Prclilllinlty Suamary o( Site CbatKCriutioO NJUrampIIOIOO_St_ 191amp

1MO bull MM~d- Milia eoa-at tAYtl or EPA MO wtlkbcYCf is lllOfC ltriftstftL

1MCLO bull Mllfllbull eoaIIUMtt lAYtl 0oe1~ o( 63 ~ WIUI tS wdl polaU llllpkcent almbcn ia p~rcotMMS repraeat ~ampmpkl with

-ndoO _ MQ or MQO Wed_ aftM _ lioO ~ Ia - shy

I I

middot~ r

I

I I

) 0 WLIMINMY RfMEPIAl RpoundSPON$E OIJgcnyES

~po oOJoCiiOI for the Nyonu II middot Orobull- StY ~llf1 will be on the potential ror rokS to pbullblk ao4 the ca-roamltnL ~~~po objeCI not nnal and await completion of alltc-specilc tilt aiMU_L KoweYtr bUI4 01 CliltiOI dl~ wveral patbWI)l throuamph which humans

or tht eampMroruacll cou~ be tllpOie4 tO contamlnalll Ia pouactwatu bM been toeatlfiecl

o ttumaa cqu~~te tO coawainall pouactwaW wouP laiUoft Genna contaCt aR40r iobaiatloa if a water aupply aoune if dcwklfl at or bullr tbe 1Ue Ia tJre Mure

o cxpCIItiN 10 cootanUutell pou4WI W0MP 4Lrecl Qermal oonKl witb aDCl iobaltioD a( coowaiaUll lo eqMOYI or vapor lonD -piOI iato relideftdal ~~~ dodpdicnt rroca tbc lite

o u4 ~~tal apcllllfC 10 coocaalDUU froa poctwatcr once It ttiscUraeamp lato

wcda or tbe SuclbUIJ RiYef

Prtlhllinary ruS-1 rcspobull objecliwl tUt td4raamp tbelt poceatial apo~ure pathways inchiCampe

o Utaitilll pracatancl Murc riiD to humans cauMil b) apotUto to ooataminatc4 po~aactwatcr sltffacamp waterl aM -eau

o Ubullltilll deJfldltiol of tM Sltdb~try River aacl wetU41 liltamp to dischltp of coo~iaa- pouftdWiter and

o - appliltlgtbull ao4 rcplltlonl _ and ror PPY

MdltloNI- objeltIIWS may be 10pe4 on dall colleete4 In the Nyonull field intlplloa -middot aM 1M rilt performld bull ptn of tM RlFS

40 1QENDfJCampJON ANQ genNJNO OF DCtfNQIOOIE$

-- o( -middot-middot P- -torY o( tedlootol o(toldpdrll -inatiOn 11 1M Nytnaa _ EP teellnoloampY was evalolled on the - o( _ potclllal delnmiddotbullP -bull bull 11 MCU aod red- 1M potcntiol threat 10 poblllt

lbeuYitoii-L

Treat ~ pocealillly sllitab1 tor tM Nyaua liM wae ldPtifted Nled oa ~middot bull -n o( tM ~til oootaaiaatiol ull prcllnliIJ tctponsc objectiva The tcdtno~ - diYide4 iato ail calfIOI ucl catefMY rqwet~Rtilamp bull pp at re~pomamp actioU tblt covkl ___ -oOJoCiiOI

Sita eoauo1 COIItaillftlftl Treat_ ExtraciiOO

SlltdJIHiftthlll

)

lnncgtbulltll tedlooiOIa were identlllad rltgtntn4or JIIormampIIOD oa4 1ltc Superfloa4 ln_t TclthnOIOI)

Emiddotauadon Pro-= TtchnoloampY Proftlcs fJovember 1919 from tM EPA

42 TECHNOLOGY SCREENINO The laitlll scnertlol of~elthnolOampiOI wos - oa enampirinllelliblllry on4 oppllcobillry to tlto lOCidon or tlto NyortJA olte _ ntlytltotechnolOjlll wore-- oa agtnstroinu Imposelt by the rype or agtatomlnoau -middotc physkll agtn41tOns oltlto ute on4 _ or rettt~inlnl bull rault or tlto uurmenr p- croctcrlstlcl oltlto bullIre thll may or 11m1r tlto eKect_ o 1 tcchnOIOI) obtol - _ ltiptlOno Pbyskll propettY doll oltlto agtatominoau bullliCit olltllity bOiUal polaC -ry worc to oay lbolu Pttgte agtatominoau tbcmKIIIIY lmpaoe oabull ~todlaolOampYmiddot Wbullte ~- ldlatllod todelae - ltor ltlODII waste uatmcaL TiiM ~GftOIOIel wto1t a WM deatt) precluded by Wlll6 or site cUractcriitkl were elimltll rora--loa Tbc ults of this oltOill- _ rtsilmjp(Y Sqscoinl llfllms4i11TKbullIil (-May 1911~ TM ARCS te~a ldlatiGid odditlOnll toe~~aoOjielthll were

not coWdcred la ~ report Tobie 4middot1 Is 1 - o the remediatiOn tcchnoOjllltbat relftll after nln~ Tbc EbUltO-AilCS the )9techaoOjlllllstod oa Tobie 4-1 by-~ prodtKt lltCTIIUIC en4or inOrntltlOn pertonao doll -middot FSbull on4 bullhrobullJh dirlaquo agtnoultotiOO with n40ro A brie dOIltriptlOn of each

-~~-lnToblel-~

50 WASpound 1 ANQ u IRFAItBil m 1QT rsooRAM - Tbc tr0111hlliry _-1bull-to~ re-opodftlt -riOO reprdialthe perlormonlaquo

of--middot-ooiOilabullbull- shy ialtiol scneo~ POIIOtlll ftuncial rlsa on4 delaY lo - KtiOO oro _ with the --of 1 le(hnolOD lOr lmptementotlOn witbOIIt fl WfPOdaamp pcrfonMftCC data For tM uutabUity tCit PfOI-middot on-site bench-5CIIt telll wcro - oo troot-r -aoOjlll ooly II ipiOltoDI lt-1 lalOrmotiOO roprdinl the te(bldOI(i coM dketiyent- Of lrepkmotn~tbility cou4 M obtliaed at a rutOftlble eo~t P-I ud _U oltgte tlbiliry otudy ro-llad OltpDicl rrootmeftl pcctlvltly throop bettdt_ ~ lo ltloD _ relt~bull_ worc ideotltlcd durin the rroatobility otudy ud doll colieltrltd to_ the iDII_t_te otrubull u be to In evoiUitlnl

the applklbilicy o( MYCrtl ~~ tUt were aot btlldlmiddotbullbull From loorntltlOa ptherad ill - otudiOI dtamp woste dllrKterotlcl likely to lmplltt _-implemltDtobillry oadof-lalrroorrtechnolOIIOihbullbullicleifted

ThM -tlcs ladshyldiM rqeegliql middot A all llIIDbtr ol orpak alld iaorpllk contaminanu 1avt bctn ia 1t u- O~ ~~~ crronsmllkdJ to lavotw a ueaU1181 (a CCblalbull ol ubull- ) speorc proccu- oalpcd _ -----middot ()onlla _ shytlfiCdW fCIIiatlM CIOIIllaludoa

Ullf pracW middot Dtftdceciel Ia laflnlbulldol rcatilll 0 Ntk wttfl propen- sd pH oplaquotftlt Mry cooBOD TOC C DOl alii TM Rl ud ueaiblhlJ It~bull ld4rtU theM ~ ao4 flrthct We1Uify lmportut niMCtl li ely to illft lM trfectiveiIM o( UbullUMIIIII at~rNii-

10

--

I )

_ lloos-qSIolt __

Nua a-loll

ROlli tillXJl~

$11tOgtouol XFcaciaiiSP X X

loltihlioUl Coauoll ~- X5latfacc Waw Coluol

~ XCpplbulll XH)dnulkBarrilt Oroddw~MI lalaeeptor T~ftdl X

XFnaOIOIItiqo_ lajocdoll X

_ XtJmiddot

shyX

X =middot X

Wet Alr ()ddadoll1 X

~ XPNdplampl~lioiISediNalldol X -Locll w n~t FtdUa X XOI~WTNa-tFKIMtJ X -Potarilld ~ ()Ddaat ~o~J

DJiilll X sai-Fioill- XTllibull Fla EYapORlioas NltSiripplacc_-loa- X

-~ XMed6l FUusliol X ---X

X X

II

)

I

IJ r

-~ ~- Dnla - (_

lMIIWI IIPDES lllodWJO ~kMIIO Orouftdwltcr

shyDlll-CaUilloll ---middot lelt FUIIr FlloorPIW Onvlty1gtidtal01 v nmtiol

Rcta1M4 xa lfll

X X

X X X

X X

X X X X

1 tucwetM TtcUooD tbat il paR ot EPA Silamp OOMUIioll Proanbull middot turrcatty btiq rldd 1 1M Towll of AIJI)a ot M11 I p11bUdJ opaatcd _let UUIIMilt fidtlty

3 lllMMlM TdiiOkgtD

11

--

----

-I )

lllllo_Z ~ ot Orww Re8ldiadol T_

llyua QcUal Silo

FeocfAtSipl

llldaltioul ColiUOII

~loll Molltortq

Slllflcr Water Cotluol

ClppUit

tfJaiiUc Ianier

Groundwater lnjeaion

Reltrkt ~wt~ fuKll poll watIUill tlpl

11 lud or otMt NllricdoU to proltibh tbc use ol JfOIIIIChILtriiiMIMtilt

EYihaale mlpaliol ud dillriiMaUoll of eo~~~amp~~luaamps Oyener tiiDC ~a~ina 11orina 10 aapll lM CMIHnlal alliS bedroct aquller

ConUOI slllflct waw ru4 owr Ike 1114 lbuefore lallltrat6oa to poundwttar

Pmat iaftltraliiMI ot _doll iiiO coatlaiuted ZOIIII wiU a RCilA 111dtimiddotlayet cap or OlMr cappWc bullterilil

OMrt ltMItMUda pouctwaamper ftow aroud contlmintted zona willa limy Wlwat piliq

ampLiblillrl 1 bedroct ~ _ulictlly bullptradient of the site 10 tower JfOUMwalel dMidoll il coaaaaiuS

Pmut JfOUDdwalef _ tlarotaP COIItlflliMtcd IODa by poutiq Mdrock traura

laect wttrr Into the Jf0111Mh1W to bydnulkllly prevtnt the funhct miJfltioo ot COGtamiauq

ltiuod abulllriull ld 01J111 iiiiO liM JfOUMIWIIer aiGJ I uix of atiKI~ wdll lid redmd1Ui01 amnktues 10 stimulate

~middot- __ _ _ _ICampMIM _or~bull lltIHolopcal NeQOr

(ampJ I trictllq IUICf tOCatilt ~ CIOIIIKtOII)

I)

IIitr 1~

bullbull

) I ~

t~r~

Acrltioft

_ Otf-tlbull wT

FtciiiY

PolarU4 Mlt4iiJ()WolvOd QDdall 1M

()llidbe orpakl ill atJICUIIII pouadMIU willa I llal1tiOCO

applklt of ll~ upt aad a rona oQdilcr

Otatroy orpaic co~wafuall La aa aq~~M~Gtll IOiudOD by iDdMiaJ ollidadoll aiMI laydtolylil reeaiOM at lllP waperauuc aDd prt~Suramp Olyp at ekWUid _ cabaDC tbamp oddat~D of orpak

coapoddlto carbOa diolidamp bullbullmiddot

AI1111C tM lfOIadWatlt 10 ~ iaoJpClk itOft and mlfiMM andmiddot-middot- middot-eo-t dillotvd 10 aa tolubae font (lc metal sulftde W ~or boa aauta) padld tOiiclltiUOUIJI

ftoealladoa settle out IOl6dl ~ plilJmiddot

Dildlotl atroaed --to-- ()wOOdTNat_t WOJIII (POTWl for ubulltbullat Water mISt rr preutbullat llllldl141 bdofC diiCIW 10 tillamp fadlicy

adDente ubullbullbullbullbull _ (sl cartiOII) at aa ol-liw

Killty 1rllff coaUUMII CK (OIICIampIItrtlld wu~ to offmiddotslte (tctlity rot flnhcr ubulltmcnt

Olddizt orpnicS and c~rot)kll~ ftltcr ioM dint ionized OIYfll u4 aiuotta and llltflliokl IJbL

___ - --Ia aM it8ptn-~ Ofkl taps pUtt

coa-w toa bullrx pedwlta bJ liOUiaJ oft WI OOII(IIIItnlioM or VOC SVOO ill a cohama partedwilllt~enbulltlriiL w -doflfaucotbull bull-ait lxltl tllll _ bull plaquo dle - anMfw of VOOJSVOCI frola u oq_ _ shy

I )

~

~t-tiaed)

naiiiampUlliWIIIIilcu-_

loa-middot _ Me4il fltratioa

flltntioa

OfOIwhmpiaamp

Or~ialrucrotptor

llillllll Loodlll

NPOES OllcUrl

Rod---o1- 0lt _ orpako tJuobullP tdiOrpdoa oato paa ~Mwd cartMML Mey be ased u a poUsblaamp ~~ aMr uea~l tla 111 UVOIOUttoll or tir atrippinampW reiDOyenC

~allfdClld CQIIdta

Separate CODCCIUIwd Cl)lllaiUaU rro- mtiClld water ISinabull semimiddot

--- RcmcM bull sol fJOM tlrl WMteWllet iltum by fordbullamp

water nwP a aM tu~a or cartridbullmiddotYfC filter

ttclftOYamp sol aacl bullWI frOil wuaew~tcr auum 111in1 1 mcrnbraM _ fltract pvftdWttcf frOCft Cl Of lfiOfS cstrectiotl - tO CORtrol Of rcWM tM UlkrW CCMI _ Qf0111141w1 wouMI be uealld oa-Mat UUifONd 10 bullbull olaquo-tiw ~licy or diKNrJICllnto ~n lor

-J()IW Colkld JfOIIdwiiCt Ia ~pawl Drtin to allow treampUMIIt to

take pLaee

saare ue~-t rtiM~tamp ( _ thadae ipCil caWft) Ia aa oCImiddot

JtCilA rdliJmiddot OllcUtl P hlw tiM atona draiM ttWU MtfliiOfk or latO 1M ltMf hi tttal OIICraquorp OCitiOI wid M ___ -~u flooltftlotwiUIIoo

to ~toe tM rtetM

lei~ Utamptarou Net Wlwt the JfOIII sinamp OM or ~wtlll

II

)

lfu Use cutrtrpl torce 10 _ tM MdlJMllltioa rate of thtdJI

Dtwaters illldp by dfliUII giDlP lM ahadJC Nil aDd tv~poratioa frolltMwrc IOaitmiddot

()ewaterstl~IC by ~~Mill a coatLa- tuw belt tNt nbull over a drive aDd auide roUir 11uca llld Ukamp I (II)IIW70I MIL Shtdp is cootifliIOampSly diWiwed btCWMI lM IUW bella

otMten lllldfl _ ~ whll ~ Wlef 0 _ - _ - -Uto4-~ dcWitcritll IMlbOdl belli

Reduce tM IOiubull of 11-bull -cwal o( supetnltllll liquMt

Ocwatcn st~ae usiaa bull roampary cbullbullbull nuer

16

)

l l nCHNOLOOlES EVALUAreD l ao4llbelldl IAiiq wu 10 dcmOnsttalCthc cffcttln ol 1 tcthnoloJY In rc4ocinamp

poo-m coataonloanl that Clbt ao Nya to tbe MCUmiddot lie ronowlnamp oclttions daCribC bullbullbull UOIUDIGl ~eotalti~Md aDd lbC raOOoale lor cMIOIIDI ltlCII

lll EMIIJIIIIl l belldlmiddotIAiiq prcclpllltiooftOCltIIlaiiOalc4(tDCnlllioD and oa14atlonlflt40Cilon (-) ttquiR- 1llil wu tloDamp 10 delCrtniDC -1 and ooo41tiODI lor optimum rem o -_colloidal ao4 - - 1bC co11101lnatetl poutcr Hy4_ aetl 101idamp prodpilltiOtiWU -tlpte4 lo tbC PPM llludiiL ()aldatlottftetloctiDI rtqUitemCIII I

pK raaF for optimum metab reatQyenal wM abO bullgttilbOLIt~ IIUlytt preucat-14 be 10 _and rod 110bull conccnttatlons _ Ibull po ao Nyan belorlt othet lampdtoO _be _ Wit preucattneDI inorpnicllllll plbulll ca- _ IQlinl In alfoltripplol __ rod UV cftlclcncicS or ao nely lmpoct bioloPltl --bullbull perlortnl_ will abO tnellb loetli on polbullhlnamp proocUOI (I~ loa ()( rcverM 01100111) A _- o pacoot rlt-la i quoJilll _tiODI o( --lalioo (OrtMiloD led 10 IIIC -tillcatiOO o -F nnp (Or by4- polJIIIC (prodpllltiOO) ltyd-bull pcOildlt (-l icll_ ulllntbCCIeCI -o(lnoltPDicl D-pranpwerlt-olttbe p__ ill _ ll tina Table l middot l - tile tAl roo prod tbe boll r ulll

l ll Olll)llJIIlDurinamp ll lour etlditlonoltcchnololi boftdtmiddotICI oliOOIDI prcucattnCDI o arooICr 10 rc4uca- ampnorpnicl ThiiO lour_ were ioD altOinFo dlft bubble _oo ca____ ___L _ bull-bullbull- olt blllllll

-(LL bull 11rippln1 prior to actlvatc4 ca- Of ICiiVIte4 ca- ollor ___) _etiOI-1--Iol- loO_DF_ te41orinorpa1Crc-looly ea- _aott aoddiffuetl __ _ rororpolc -L BioloampICO__ tawd for botb i801pntt aD4 orpaic rcmovab lie PhiiC ll ideatlllcd tltc need to aetl lmplctneat ucattnCOI mcthOdl lor rc-1 o orpnicl For wmplc combibull bullbullabull 11rippin1 with acttvatc4 carbObull ucatmcat may be n_ary bullroomo cootantloaall arc dgtft~Cullto 11rip but -Uy 10 carbOn Altcrnatly c4 carbOn tniY be a pol~biDI 11cp ~ bioloalel ucatmcat bull cmplo)_ Tablel l-lto l -1 dcocribe Utbullt _ TIMamp 5-1 ilkoliftll tM water ctalily o( ttlamp r- Wllel priot ampa precipiudcm prcucaunenL

U 1Uf OBIECttvES _ o l ao4 ll beodt - 10 middot-- o - -o( ao4 -ubullilllbullbullbullbull pou-tallmpliiOOlshy11 1M tltyaua to beloW MOI TM bulltillamp- abO- 10 _1-middot-_---middot- piClypC o cacUaac - teiCOI ua- TbullriDI- oooductc4 to _ I rltllablt o IM tceJIOlOIYS abnity to _ contambullbullbull Ia the poutcr 11 the tlyaOJO 1111 TM olall col- - 001 iatcndc4 lor cftlclcY

I I I I

r~n hll

middot ll ~~l =~~Irrl l ~lil

f fl I

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 12: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

---)

_Zl ~ co-bull_ c-o_Ru

~5110

Maxlmlm MCL01 foloof Mlnlmtntt

MCL1 ~ ~llllllol~llllllolQwlilll 39200

IIJQIIIIill 33050 29 (MW-109)0 4 (lloO 1400- 50 lOOO ll

Blri 01000

6 (MW-114 A 302) 33 -Beryllhua 14 (10114)l 302000 II (MW-IOl)

10 2230~middotmiddot

50 100 26 (Ul) 26lColdbullbull ll3~middotmiddot lJOO 90400cdlolt

1000 ~ l20300 l 2(MW-1048) 29 (Oil)roo 73600ldL )(1100 ~- 31050 02 (MW-201)32 (ll10)2 93

100 39l00 2 -N- 12

- 50 IJOOOO _ 1170middotmiddot - 10

l OOO

100000 9 (MW-301) - ll(ll)0 761l00~ 70 40 (36) 12000(MWmiddot98) l 9(MW) 100 l (MW-101) 36 (20)~ 70 23a- 7012middot__ 7 I7l l middot DklaoiOitla)MM 48l

0 3 (3) 600(MWJOlA)9 (MW-2038)

l ll (MWmiddot2048) 2000 2 9 (MW-2041) 2000Tol- 440 I 1JOO1000 l20 (MW-JOlA)Xylnll 2_

---_1-1(-dal GrovedMW CoosaaiDUl Freq ud CoeQIOlna Raa

NyUrampa-iltOI$110

ll(MW-1111) I 30 (MW-IISA) ~-tsladl- 10 (MW-107)l~ S6000 (MW-lllA)

tJamiddotJ)iaOrObeaiampM - bull 19 (MW-30S8)7SO 30 (3) SIOOOO (MW-113A)

14-p-- 41 (11)s 63 (MW-6A)600 610 16

tlo-~nc 3UlODOO(MW-lllA)100 (MW-1048)4-MampIgtyplloool IS SIOO(MW-11)IS (MW-30S8)NiuoliCIUIampM n SS100 (MW-113A)124-TricbiorobeftiCM - I3S (MW-10lt8)11 l30(MW-IISA) 170 (MW-611)

6N_ s 0 189 - 9 (MW-lll8) llmiddotDkhkKOitbaM 100 Ill100 l

111-TriCWofOitUIIamp 0 90 (MW-111) Vi ell- I 650 (MW-1048)ll(MW-117A)Mot~ 10 180 (MW-IIlA)96 (MW-96)1 a-NitMIOmiddotDimiddotbullmiddot 41000(MW-113A) s

ElMlt shyOil(lashy

ottbi eefJQ) 0001 (MW-118) iS (MW-108)

04 1 (37) 016 (MW-IOlA)Hololt I S4(MW-llll) 03S (MW-611)bullbullmiddot-ooT 3 OSS (MW-EAT-15)0011 (MW-IOS)- -IHC l 01 (MW-301)DelcamiddotIHC I 17(MW-9A)Dlol4rin ookgtfdabull Soutc~ Flftll WOfk Plla Jolyaaza 11 - orouactwater Sl14) Dcamber t917

Ortfl Prclilllinlty Suamary o( Site CbatKCriutioO NJUrampIIOIOO_St_ 191amp

1MO bull MM~d- Milia eoa-at tAYtl or EPA MO wtlkbcYCf is lllOfC ltriftstftL

1MCLO bull Mllfllbull eoaIIUMtt lAYtl 0oe1~ o( 63 ~ WIUI tS wdl polaU llllpkcent almbcn ia p~rcotMMS repraeat ~ampmpkl with

-ndoO _ MQ or MQO Wed_ aftM _ lioO ~ Ia - shy

I I

middot~ r

I

I I

) 0 WLIMINMY RfMEPIAl RpoundSPON$E OIJgcnyES

~po oOJoCiiOI for the Nyonu II middot Orobull- StY ~llf1 will be on the potential ror rokS to pbullblk ao4 the ca-roamltnL ~~~po objeCI not nnal and await completion of alltc-specilc tilt aiMU_L KoweYtr bUI4 01 CliltiOI dl~ wveral patbWI)l throuamph which humans

or tht eampMroruacll cou~ be tllpOie4 tO contamlnalll Ia pouactwatu bM been toeatlfiecl

o ttumaa cqu~~te tO coawainall pouactwaW wouP laiUoft Genna contaCt aR40r iobaiatloa if a water aupply aoune if dcwklfl at or bullr tbe 1Ue Ia tJre Mure

o cxpCIItiN 10 cootanUutell pou4WI W0MP 4Lrecl Qermal oonKl witb aDCl iobaltioD a( coowaiaUll lo eqMOYI or vapor lonD -piOI iato relideftdal ~~~ dodpdicnt rroca tbc lite

o u4 ~~tal apcllllfC 10 coocaalDUU froa poctwatcr once It ttiscUraeamp lato

wcda or tbe SuclbUIJ RiYef

Prtlhllinary ruS-1 rcspobull objecliwl tUt td4raamp tbelt poceatial apo~ure pathways inchiCampe

o Utaitilll pracatancl Murc riiD to humans cauMil b) apotUto to ooataminatc4 po~aactwatcr sltffacamp waterl aM -eau

o Ubullltilll deJfldltiol of tM Sltdb~try River aacl wetU41 liltamp to dischltp of coo~iaa- pouftdWiter and

o - appliltlgtbull ao4 rcplltlonl _ and ror PPY

MdltloNI- objeltIIWS may be 10pe4 on dall colleete4 In the Nyonull field intlplloa -middot aM 1M rilt performld bull ptn of tM RlFS

40 1QENDfJCampJON ANQ genNJNO OF DCtfNQIOOIE$

-- o( -middot-middot P- -torY o( tedlootol o(toldpdrll -inatiOn 11 1M Nytnaa _ EP teellnoloampY was evalolled on the - o( _ potclllal delnmiddotbullP -bull bull 11 MCU aod red- 1M potcntiol threat 10 poblllt

lbeuYitoii-L

Treat ~ pocealillly sllitab1 tor tM Nyaua liM wae ldPtifted Nled oa ~middot bull -n o( tM ~til oootaaiaatiol ull prcllnliIJ tctponsc objectiva The tcdtno~ - diYide4 iato ail calfIOI ucl catefMY rqwet~Rtilamp bull pp at re~pomamp actioU tblt covkl ___ -oOJoCiiOI

Sita eoauo1 COIItaillftlftl Treat_ ExtraciiOO

SlltdJIHiftthlll

)

lnncgtbulltll tedlooiOIa were identlllad rltgtntn4or JIIormampIIOD oa4 1ltc Superfloa4 ln_t TclthnOIOI)

Emiddotauadon Pro-= TtchnoloampY Proftlcs fJovember 1919 from tM EPA

42 TECHNOLOGY SCREENINO The laitlll scnertlol of~elthnolOampiOI wos - oa enampirinllelliblllry on4 oppllcobillry to tlto lOCidon or tlto NyortJA olte _ ntlytltotechnolOjlll wore-- oa agtnstroinu Imposelt by the rype or agtatomlnoau -middotc physkll agtn41tOns oltlto ute on4 _ or rettt~inlnl bull rault or tlto uurmenr p- croctcrlstlcl oltlto bullIre thll may or 11m1r tlto eKect_ o 1 tcchnOIOI) obtol - _ ltiptlOno Pbyskll propettY doll oltlto agtatominoau bullliCit olltllity bOiUal polaC -ry worc to oay lbolu Pttgte agtatominoau tbcmKIIIIY lmpaoe oabull ~todlaolOampYmiddot Wbullte ~- ldlatllod todelae - ltor ltlODII waste uatmcaL TiiM ~GftOIOIel wto1t a WM deatt) precluded by Wlll6 or site cUractcriitkl were elimltll rora--loa Tbc ults of this oltOill- _ rtsilmjp(Y Sqscoinl llfllms4i11TKbullIil (-May 1911~ TM ARCS te~a ldlatiGid odditlOnll toe~~aoOjielthll were

not coWdcred la ~ report Tobie 4middot1 Is 1 - o the remediatiOn tcchnoOjllltbat relftll after nln~ Tbc EbUltO-AilCS the )9techaoOjlllllstod oa Tobie 4-1 by-~ prodtKt lltCTIIUIC en4or inOrntltlOn pertonao doll -middot FSbull on4 bullhrobullJh dirlaquo agtnoultotiOO with n40ro A brie dOIltriptlOn of each

-~~-lnToblel-~

50 WASpound 1 ANQ u IRFAItBil m 1QT rsooRAM - Tbc tr0111hlliry _-1bull-to~ re-opodftlt -riOO reprdialthe perlormonlaquo

of--middot-ooiOilabullbull- shy ialtiol scneo~ POIIOtlll ftuncial rlsa on4 delaY lo - KtiOO oro _ with the --of 1 le(hnolOD lOr lmptementotlOn witbOIIt fl WfPOdaamp pcrfonMftCC data For tM uutabUity tCit PfOI-middot on-site bench-5CIIt telll wcro - oo troot-r -aoOjlll ooly II ipiOltoDI lt-1 lalOrmotiOO roprdinl the te(bldOI(i coM dketiyent- Of lrepkmotn~tbility cou4 M obtliaed at a rutOftlble eo~t P-I ud _U oltgte tlbiliry otudy ro-llad OltpDicl rrootmeftl pcctlvltly throop bettdt_ ~ lo ltloD _ relt~bull_ worc ideotltlcd durin the rroatobility otudy ud doll colieltrltd to_ the iDII_t_te otrubull u be to In evoiUitlnl

the applklbilicy o( MYCrtl ~~ tUt were aot btlldlmiddotbullbull From loorntltlOa ptherad ill - otudiOI dtamp woste dllrKterotlcl likely to lmplltt _-implemltDtobillry oadof-lalrroorrtechnolOIIOihbullbullicleifted

ThM -tlcs ladshyldiM rqeegliql middot A all llIIDbtr ol orpak alld iaorpllk contaminanu 1avt bctn ia 1t u- O~ ~~~ crronsmllkdJ to lavotw a ueaU1181 (a CCblalbull ol ubull- ) speorc proccu- oalpcd _ -----middot ()onlla _ shytlfiCdW fCIIiatlM CIOIIllaludoa

Ullf pracW middot Dtftdceciel Ia laflnlbulldol rcatilll 0 Ntk wttfl propen- sd pH oplaquotftlt Mry cooBOD TOC C DOl alii TM Rl ud ueaiblhlJ It~bull ld4rtU theM ~ ao4 flrthct We1Uify lmportut niMCtl li ely to illft lM trfectiveiIM o( UbullUMIIIII at~rNii-

10

--

I )

_ lloos-qSIolt __

Nua a-loll

ROlli tillXJl~

$11tOgtouol XFcaciaiiSP X X

loltihlioUl Coauoll ~- X5latfacc Waw Coluol

~ XCpplbulll XH)dnulkBarrilt Oroddw~MI lalaeeptor T~ftdl X

XFnaOIOIItiqo_ lajocdoll X

_ XtJmiddot

shyX

X =middot X

Wet Alr ()ddadoll1 X

~ XPNdplampl~lioiISediNalldol X -Locll w n~t FtdUa X XOI~WTNa-tFKIMtJ X -Potarilld ~ ()Ddaat ~o~J

DJiilll X sai-Fioill- XTllibull Fla EYapORlioas NltSiripplacc_-loa- X

-~ XMed6l FUusliol X ---X

X X

II

)

I

IJ r

-~ ~- Dnla - (_

lMIIWI IIPDES lllodWJO ~kMIIO Orouftdwltcr

shyDlll-CaUilloll ---middot lelt FUIIr FlloorPIW Onvlty1gtidtal01 v nmtiol

Rcta1M4 xa lfll

X X

X X X

X X

X X X X

1 tucwetM TtcUooD tbat il paR ot EPA Silamp OOMUIioll Proanbull middot turrcatty btiq rldd 1 1M Towll of AIJI)a ot M11 I p11bUdJ opaatcd _let UUIIMilt fidtlty

3 lllMMlM TdiiOkgtD

11

--

----

-I )

lllllo_Z ~ ot Orww Re8ldiadol T_

llyua QcUal Silo

FeocfAtSipl

llldaltioul ColiUOII

~loll Molltortq

Slllflcr Water Cotluol

ClppUit

tfJaiiUc Ianier

Groundwater lnjeaion

Reltrkt ~wt~ fuKll poll watIUill tlpl

11 lud or otMt NllricdoU to proltibh tbc use ol JfOIIIIChILtriiiMIMtilt

EYihaale mlpaliol ud dillriiMaUoll of eo~~~amp~~luaamps Oyener tiiDC ~a~ina 11orina 10 aapll lM CMIHnlal alliS bedroct aquller

ConUOI slllflct waw ru4 owr Ike 1114 lbuefore lallltrat6oa to poundwttar

Pmat iaftltraliiMI ot _doll iiiO coatlaiuted ZOIIII wiU a RCilA 111dtimiddotlayet cap or OlMr cappWc bullterilil

OMrt ltMItMUda pouctwaamper ftow aroud contlmintted zona willa limy Wlwat piliq

ampLiblillrl 1 bedroct ~ _ulictlly bullptradient of the site 10 tower JfOUMwalel dMidoll il coaaaaiuS

Pmut JfOUDdwalef _ tlarotaP COIItlflliMtcd IODa by poutiq Mdrock traura

laect wttrr Into the Jf0111Mh1W to bydnulkllly prevtnt the funhct miJfltioo ot COGtamiauq

ltiuod abulllriull ld 01J111 iiiiO liM JfOUMIWIIer aiGJ I uix of atiKI~ wdll lid redmd1Ui01 amnktues 10 stimulate

~middot- __ _ _ _ICampMIM _or~bull lltIHolopcal NeQOr

(ampJ I trictllq IUICf tOCatilt ~ CIOIIIKtOII)

I)

IIitr 1~

bullbull

) I ~

t~r~

Acrltioft

_ Otf-tlbull wT

FtciiiY

PolarU4 Mlt4iiJ()WolvOd QDdall 1M

()llidbe orpakl ill atJICUIIII pouadMIU willa I llal1tiOCO

applklt of ll~ upt aad a rona oQdilcr

Otatroy orpaic co~wafuall La aa aq~~M~Gtll IOiudOD by iDdMiaJ ollidadoll aiMI laydtolylil reeaiOM at lllP waperauuc aDd prt~Suramp Olyp at ekWUid _ cabaDC tbamp oddat~D of orpak

coapoddlto carbOa diolidamp bullbullmiddot

AI1111C tM lfOIadWatlt 10 ~ iaoJpClk itOft and mlfiMM andmiddot-middot- middot-eo-t dillotvd 10 aa tolubae font (lc metal sulftde W ~or boa aauta) padld tOiiclltiUOUIJI

ftoealladoa settle out IOl6dl ~ plilJmiddot

Dildlotl atroaed --to-- ()wOOdTNat_t WOJIII (POTWl for ubulltbullat Water mISt rr preutbullat llllldl141 bdofC diiCIW 10 tillamp fadlicy

adDente ubullbullbullbullbull _ (sl cartiOII) at aa ol-liw

Killty 1rllff coaUUMII CK (OIICIampIItrtlld wu~ to offmiddotslte (tctlity rot flnhcr ubulltmcnt

Olddizt orpnicS and c~rot)kll~ ftltcr ioM dint ionized OIYfll u4 aiuotta and llltflliokl IJbL

___ - --Ia aM it8ptn-~ Ofkl taps pUtt

coa-w toa bullrx pedwlta bJ liOUiaJ oft WI OOII(IIIItnlioM or VOC SVOO ill a cohama partedwilllt~enbulltlriiL w -doflfaucotbull bull-ait lxltl tllll _ bull plaquo dle - anMfw of VOOJSVOCI frola u oq_ _ shy

I )

~

~t-tiaed)

naiiiampUlliWIIIIilcu-_

loa-middot _ Me4il fltratioa

flltntioa

OfOIwhmpiaamp

Or~ialrucrotptor

llillllll Loodlll

NPOES OllcUrl

Rod---o1- 0lt _ orpako tJuobullP tdiOrpdoa oato paa ~Mwd cartMML Mey be ased u a poUsblaamp ~~ aMr uea~l tla 111 UVOIOUttoll or tir atrippinampW reiDOyenC

~allfdClld CQIIdta

Separate CODCCIUIwd Cl)lllaiUaU rro- mtiClld water ISinabull semimiddot

--- RcmcM bull sol fJOM tlrl WMteWllet iltum by fordbullamp

water nwP a aM tu~a or cartridbullmiddotYfC filter

ttclftOYamp sol aacl bullWI frOil wuaew~tcr auum 111in1 1 mcrnbraM _ fltract pvftdWttcf frOCft Cl Of lfiOfS cstrectiotl - tO CORtrol Of rcWM tM UlkrW CCMI _ Qf0111141w1 wouMI be uealld oa-Mat UUifONd 10 bullbull olaquo-tiw ~licy or diKNrJICllnto ~n lor

-J()IW Colkld JfOIIdwiiCt Ia ~pawl Drtin to allow treampUMIIt to

take pLaee

saare ue~-t rtiM~tamp ( _ thadae ipCil caWft) Ia aa oCImiddot

JtCilA rdliJmiddot OllcUtl P hlw tiM atona draiM ttWU MtfliiOfk or latO 1M ltMf hi tttal OIICraquorp OCitiOI wid M ___ -~u flooltftlotwiUIIoo

to ~toe tM rtetM

lei~ Utamptarou Net Wlwt the JfOIII sinamp OM or ~wtlll

II

)

lfu Use cutrtrpl torce 10 _ tM MdlJMllltioa rate of thtdJI

Dtwaters illldp by dfliUII giDlP lM ahadJC Nil aDd tv~poratioa frolltMwrc IOaitmiddot

()ewaterstl~IC by ~~Mill a coatLa- tuw belt tNt nbull over a drive aDd auide roUir 11uca llld Ukamp I (II)IIW70I MIL Shtdp is cootifliIOampSly diWiwed btCWMI lM IUW bella

otMten lllldfl _ ~ whll ~ Wlef 0 _ - _ - -Uto4-~ dcWitcritll IMlbOdl belli

Reduce tM IOiubull of 11-bull -cwal o( supetnltllll liquMt

Ocwatcn st~ae usiaa bull roampary cbullbullbull nuer

16

)

l l nCHNOLOOlES EVALUAreD l ao4llbelldl IAiiq wu 10 dcmOnsttalCthc cffcttln ol 1 tcthnoloJY In rc4ocinamp

poo-m coataonloanl that Clbt ao Nya to tbe MCUmiddot lie ronowlnamp oclttions daCribC bullbullbull UOIUDIGl ~eotalti~Md aDd lbC raOOoale lor cMIOIIDI ltlCII

lll EMIIJIIIIl l belldlmiddotIAiiq prcclpllltiooftOCltIIlaiiOalc4(tDCnlllioD and oa14atlonlflt40Cilon (-) ttquiR- 1llil wu tloDamp 10 delCrtniDC -1 and ooo41tiODI lor optimum rem o -_colloidal ao4 - - 1bC co11101lnatetl poutcr Hy4_ aetl 101idamp prodpilltiOtiWU -tlpte4 lo tbC PPM llludiiL ()aldatlottftetloctiDI rtqUitemCIII I

pK raaF for optimum metab reatQyenal wM abO bullgttilbOLIt~ IIUlytt preucat-14 be 10 _and rod 110bull conccnttatlons _ Ibull po ao Nyan belorlt othet lampdtoO _be _ Wit preucattneDI inorpnicllllll plbulll ca- _ IQlinl In alfoltripplol __ rod UV cftlclcncicS or ao nely lmpoct bioloPltl --bullbull perlortnl_ will abO tnellb loetli on polbullhlnamp proocUOI (I~ loa ()( rcverM 01100111) A _- o pacoot rlt-la i quoJilll _tiODI o( --lalioo (OrtMiloD led 10 IIIC -tillcatiOO o -F nnp (Or by4- polJIIIC (prodpllltiOO) ltyd-bull pcOildlt (-l icll_ ulllntbCCIeCI -o(lnoltPDicl D-pranpwerlt-olttbe p__ ill _ ll tina Table l middot l - tile tAl roo prod tbe boll r ulll

l ll Olll)llJIIlDurinamp ll lour etlditlonoltcchnololi boftdtmiddotICI oliOOIDI prcucattnCDI o arooICr 10 rc4uca- ampnorpnicl ThiiO lour_ were ioD altOinFo dlft bubble _oo ca____ ___L _ bull-bullbull- olt blllllll

-(LL bull 11rippln1 prior to actlvatc4 ca- Of ICiiVIte4 ca- ollor ___) _etiOI-1--Iol- loO_DF_ te41orinorpa1Crc-looly ea- _aott aoddiffuetl __ _ rororpolc -L BioloampICO__ tawd for botb i801pntt aD4 orpaic rcmovab lie PhiiC ll ideatlllcd tltc need to aetl lmplctneat ucattnCOI mcthOdl lor rc-1 o orpnicl For wmplc combibull bullbullabull 11rippin1 with acttvatc4 carbObull ucatmcat may be n_ary bullroomo cootantloaall arc dgtft~Cullto 11rip but -Uy 10 carbOn Altcrnatly c4 carbOn tniY be a pol~biDI 11cp ~ bioloalel ucatmcat bull cmplo)_ Tablel l-lto l -1 dcocribe Utbullt _ TIMamp 5-1 ilkoliftll tM water ctalily o( ttlamp r- Wllel priot ampa precipiudcm prcucaunenL

U 1Uf OBIECttvES _ o l ao4 ll beodt - 10 middot-- o - -o( ao4 -ubullilllbullbullbullbull pou-tallmpliiOOlshy11 1M tltyaua to beloW MOI TM bulltillamp- abO- 10 _1-middot-_---middot- piClypC o cacUaac - teiCOI ua- TbullriDI- oooductc4 to _ I rltllablt o IM tceJIOlOIYS abnity to _ contambullbullbull Ia the poutcr 11 the tlyaOJO 1111 TM olall col- - 001 iatcndc4 lor cftlclcY

I I I I

r~n hll

middot ll ~~l =~~Irrl l ~lil

f fl I

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 13: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

---_1-1(-dal GrovedMW CoosaaiDUl Freq ud CoeQIOlna Raa

NyUrampa-iltOI$110

ll(MW-1111) I 30 (MW-IISA) ~-tsladl- 10 (MW-107)l~ S6000 (MW-lllA)

tJamiddotJ)iaOrObeaiampM - bull 19 (MW-30S8)7SO 30 (3) SIOOOO (MW-113A)

14-p-- 41 (11)s 63 (MW-6A)600 610 16

tlo-~nc 3UlODOO(MW-lllA)100 (MW-1048)4-MampIgtyplloool IS SIOO(MW-11)IS (MW-30S8)NiuoliCIUIampM n SS100 (MW-113A)124-TricbiorobeftiCM - I3S (MW-10lt8)11 l30(MW-IISA) 170 (MW-611)

6N_ s 0 189 - 9 (MW-lll8) llmiddotDkhkKOitbaM 100 Ill100 l

111-TriCWofOitUIIamp 0 90 (MW-111) Vi ell- I 650 (MW-1048)ll(MW-117A)Mot~ 10 180 (MW-IIlA)96 (MW-96)1 a-NitMIOmiddotDimiddotbullmiddot 41000(MW-113A) s

ElMlt shyOil(lashy

ottbi eefJQ) 0001 (MW-118) iS (MW-108)

04 1 (37) 016 (MW-IOlA)Hololt I S4(MW-llll) 03S (MW-611)bullbullmiddot-ooT 3 OSS (MW-EAT-15)0011 (MW-IOS)- -IHC l 01 (MW-301)DelcamiddotIHC I 17(MW-9A)Dlol4rin ookgtfdabull Soutc~ Flftll WOfk Plla Jolyaaza 11 - orouactwater Sl14) Dcamber t917

Ortfl Prclilllinlty Suamary o( Site CbatKCriutioO NJUrampIIOIOO_St_ 191amp

1MO bull MM~d- Milia eoa-at tAYtl or EPA MO wtlkbcYCf is lllOfC ltriftstftL

1MCLO bull Mllfllbull eoaIIUMtt lAYtl 0oe1~ o( 63 ~ WIUI tS wdl polaU llllpkcent almbcn ia p~rcotMMS repraeat ~ampmpkl with

-ndoO _ MQ or MQO Wed_ aftM _ lioO ~ Ia - shy

I I

middot~ r

I

I I

) 0 WLIMINMY RfMEPIAl RpoundSPON$E OIJgcnyES

~po oOJoCiiOI for the Nyonu II middot Orobull- StY ~llf1 will be on the potential ror rokS to pbullblk ao4 the ca-roamltnL ~~~po objeCI not nnal and await completion of alltc-specilc tilt aiMU_L KoweYtr bUI4 01 CliltiOI dl~ wveral patbWI)l throuamph which humans

or tht eampMroruacll cou~ be tllpOie4 tO contamlnalll Ia pouactwatu bM been toeatlfiecl

o ttumaa cqu~~te tO coawainall pouactwaW wouP laiUoft Genna contaCt aR40r iobaiatloa if a water aupply aoune if dcwklfl at or bullr tbe 1Ue Ia tJre Mure

o cxpCIItiN 10 cootanUutell pou4WI W0MP 4Lrecl Qermal oonKl witb aDCl iobaltioD a( coowaiaUll lo eqMOYI or vapor lonD -piOI iato relideftdal ~~~ dodpdicnt rroca tbc lite

o u4 ~~tal apcllllfC 10 coocaalDUU froa poctwatcr once It ttiscUraeamp lato

wcda or tbe SuclbUIJ RiYef

Prtlhllinary ruS-1 rcspobull objecliwl tUt td4raamp tbelt poceatial apo~ure pathways inchiCampe

o Utaitilll pracatancl Murc riiD to humans cauMil b) apotUto to ooataminatc4 po~aactwatcr sltffacamp waterl aM -eau

o Ubullltilll deJfldltiol of tM Sltdb~try River aacl wetU41 liltamp to dischltp of coo~iaa- pouftdWiter and

o - appliltlgtbull ao4 rcplltlonl _ and ror PPY

MdltloNI- objeltIIWS may be 10pe4 on dall colleete4 In the Nyonull field intlplloa -middot aM 1M rilt performld bull ptn of tM RlFS

40 1QENDfJCampJON ANQ genNJNO OF DCtfNQIOOIE$

-- o( -middot-middot P- -torY o( tedlootol o(toldpdrll -inatiOn 11 1M Nytnaa _ EP teellnoloampY was evalolled on the - o( _ potclllal delnmiddotbullP -bull bull 11 MCU aod red- 1M potcntiol threat 10 poblllt

lbeuYitoii-L

Treat ~ pocealillly sllitab1 tor tM Nyaua liM wae ldPtifted Nled oa ~middot bull -n o( tM ~til oootaaiaatiol ull prcllnliIJ tctponsc objectiva The tcdtno~ - diYide4 iato ail calfIOI ucl catefMY rqwet~Rtilamp bull pp at re~pomamp actioU tblt covkl ___ -oOJoCiiOI

Sita eoauo1 COIItaillftlftl Treat_ ExtraciiOO

SlltdJIHiftthlll

)

lnncgtbulltll tedlooiOIa were identlllad rltgtntn4or JIIormampIIOD oa4 1ltc Superfloa4 ln_t TclthnOIOI)

Emiddotauadon Pro-= TtchnoloampY Proftlcs fJovember 1919 from tM EPA

42 TECHNOLOGY SCREENINO The laitlll scnertlol of~elthnolOampiOI wos - oa enampirinllelliblllry on4 oppllcobillry to tlto lOCidon or tlto NyortJA olte _ ntlytltotechnolOjlll wore-- oa agtnstroinu Imposelt by the rype or agtatomlnoau -middotc physkll agtn41tOns oltlto ute on4 _ or rettt~inlnl bull rault or tlto uurmenr p- croctcrlstlcl oltlto bullIre thll may or 11m1r tlto eKect_ o 1 tcchnOIOI) obtol - _ ltiptlOno Pbyskll propettY doll oltlto agtatominoau bullliCit olltllity bOiUal polaC -ry worc to oay lbolu Pttgte agtatominoau tbcmKIIIIY lmpaoe oabull ~todlaolOampYmiddot Wbullte ~- ldlatllod todelae - ltor ltlODII waste uatmcaL TiiM ~GftOIOIel wto1t a WM deatt) precluded by Wlll6 or site cUractcriitkl were elimltll rora--loa Tbc ults of this oltOill- _ rtsilmjp(Y Sqscoinl llfllms4i11TKbullIil (-May 1911~ TM ARCS te~a ldlatiGid odditlOnll toe~~aoOjielthll were

not coWdcred la ~ report Tobie 4middot1 Is 1 - o the remediatiOn tcchnoOjllltbat relftll after nln~ Tbc EbUltO-AilCS the )9techaoOjlllllstod oa Tobie 4-1 by-~ prodtKt lltCTIIUIC en4or inOrntltlOn pertonao doll -middot FSbull on4 bullhrobullJh dirlaquo agtnoultotiOO with n40ro A brie dOIltriptlOn of each

-~~-lnToblel-~

50 WASpound 1 ANQ u IRFAItBil m 1QT rsooRAM - Tbc tr0111hlliry _-1bull-to~ re-opodftlt -riOO reprdialthe perlormonlaquo

of--middot-ooiOilabullbull- shy ialtiol scneo~ POIIOtlll ftuncial rlsa on4 delaY lo - KtiOO oro _ with the --of 1 le(hnolOD lOr lmptementotlOn witbOIIt fl WfPOdaamp pcrfonMftCC data For tM uutabUity tCit PfOI-middot on-site bench-5CIIt telll wcro - oo troot-r -aoOjlll ooly II ipiOltoDI lt-1 lalOrmotiOO roprdinl the te(bldOI(i coM dketiyent- Of lrepkmotn~tbility cou4 M obtliaed at a rutOftlble eo~t P-I ud _U oltgte tlbiliry otudy ro-llad OltpDicl rrootmeftl pcctlvltly throop bettdt_ ~ lo ltloD _ relt~bull_ worc ideotltlcd durin the rroatobility otudy ud doll colieltrltd to_ the iDII_t_te otrubull u be to In evoiUitlnl

the applklbilicy o( MYCrtl ~~ tUt were aot btlldlmiddotbullbull From loorntltlOa ptherad ill - otudiOI dtamp woste dllrKterotlcl likely to lmplltt _-implemltDtobillry oadof-lalrroorrtechnolOIIOihbullbullicleifted

ThM -tlcs ladshyldiM rqeegliql middot A all llIIDbtr ol orpak alld iaorpllk contaminanu 1avt bctn ia 1t u- O~ ~~~ crronsmllkdJ to lavotw a ueaU1181 (a CCblalbull ol ubull- ) speorc proccu- oalpcd _ -----middot ()onlla _ shytlfiCdW fCIIiatlM CIOIIllaludoa

Ullf pracW middot Dtftdceciel Ia laflnlbulldol rcatilll 0 Ntk wttfl propen- sd pH oplaquotftlt Mry cooBOD TOC C DOl alii TM Rl ud ueaiblhlJ It~bull ld4rtU theM ~ ao4 flrthct We1Uify lmportut niMCtl li ely to illft lM trfectiveiIM o( UbullUMIIIII at~rNii-

10

--

I )

_ lloos-qSIolt __

Nua a-loll

ROlli tillXJl~

$11tOgtouol XFcaciaiiSP X X

loltihlioUl Coauoll ~- X5latfacc Waw Coluol

~ XCpplbulll XH)dnulkBarrilt Oroddw~MI lalaeeptor T~ftdl X

XFnaOIOIItiqo_ lajocdoll X

_ XtJmiddot

shyX

X =middot X

Wet Alr ()ddadoll1 X

~ XPNdplampl~lioiISediNalldol X -Locll w n~t FtdUa X XOI~WTNa-tFKIMtJ X -Potarilld ~ ()Ddaat ~o~J

DJiilll X sai-Fioill- XTllibull Fla EYapORlioas NltSiripplacc_-loa- X

-~ XMed6l FUusliol X ---X

X X

II

)

I

IJ r

-~ ~- Dnla - (_

lMIIWI IIPDES lllodWJO ~kMIIO Orouftdwltcr

shyDlll-CaUilloll ---middot lelt FUIIr FlloorPIW Onvlty1gtidtal01 v nmtiol

Rcta1M4 xa lfll

X X

X X X

X X

X X X X

1 tucwetM TtcUooD tbat il paR ot EPA Silamp OOMUIioll Proanbull middot turrcatty btiq rldd 1 1M Towll of AIJI)a ot M11 I p11bUdJ opaatcd _let UUIIMilt fidtlty

3 lllMMlM TdiiOkgtD

11

--

----

-I )

lllllo_Z ~ ot Orww Re8ldiadol T_

llyua QcUal Silo

FeocfAtSipl

llldaltioul ColiUOII

~loll Molltortq

Slllflcr Water Cotluol

ClppUit

tfJaiiUc Ianier

Groundwater lnjeaion

Reltrkt ~wt~ fuKll poll watIUill tlpl

11 lud or otMt NllricdoU to proltibh tbc use ol JfOIIIIChILtriiiMIMtilt

EYihaale mlpaliol ud dillriiMaUoll of eo~~~amp~~luaamps Oyener tiiDC ~a~ina 11orina 10 aapll lM CMIHnlal alliS bedroct aquller

ConUOI slllflct waw ru4 owr Ike 1114 lbuefore lallltrat6oa to poundwttar

Pmat iaftltraliiMI ot _doll iiiO coatlaiuted ZOIIII wiU a RCilA 111dtimiddotlayet cap or OlMr cappWc bullterilil

OMrt ltMItMUda pouctwaamper ftow aroud contlmintted zona willa limy Wlwat piliq

ampLiblillrl 1 bedroct ~ _ulictlly bullptradient of the site 10 tower JfOUMwalel dMidoll il coaaaaiuS

Pmut JfOUDdwalef _ tlarotaP COIItlflliMtcd IODa by poutiq Mdrock traura

laect wttrr Into the Jf0111Mh1W to bydnulkllly prevtnt the funhct miJfltioo ot COGtamiauq

ltiuod abulllriull ld 01J111 iiiiO liM JfOUMIWIIer aiGJ I uix of atiKI~ wdll lid redmd1Ui01 amnktues 10 stimulate

~middot- __ _ _ _ICampMIM _or~bull lltIHolopcal NeQOr

(ampJ I trictllq IUICf tOCatilt ~ CIOIIIKtOII)

I)

IIitr 1~

bullbull

) I ~

t~r~

Acrltioft

_ Otf-tlbull wT

FtciiiY

PolarU4 Mlt4iiJ()WolvOd QDdall 1M

()llidbe orpakl ill atJICUIIII pouadMIU willa I llal1tiOCO

applklt of ll~ upt aad a rona oQdilcr

Otatroy orpaic co~wafuall La aa aq~~M~Gtll IOiudOD by iDdMiaJ ollidadoll aiMI laydtolylil reeaiOM at lllP waperauuc aDd prt~Suramp Olyp at ekWUid _ cabaDC tbamp oddat~D of orpak

coapoddlto carbOa diolidamp bullbullmiddot

AI1111C tM lfOIadWatlt 10 ~ iaoJpClk itOft and mlfiMM andmiddot-middot- middot-eo-t dillotvd 10 aa tolubae font (lc metal sulftde W ~or boa aauta) padld tOiiclltiUOUIJI

ftoealladoa settle out IOl6dl ~ plilJmiddot

Dildlotl atroaed --to-- ()wOOdTNat_t WOJIII (POTWl for ubulltbullat Water mISt rr preutbullat llllldl141 bdofC diiCIW 10 tillamp fadlicy

adDente ubullbullbullbullbull _ (sl cartiOII) at aa ol-liw

Killty 1rllff coaUUMII CK (OIICIampIItrtlld wu~ to offmiddotslte (tctlity rot flnhcr ubulltmcnt

Olddizt orpnicS and c~rot)kll~ ftltcr ioM dint ionized OIYfll u4 aiuotta and llltflliokl IJbL

___ - --Ia aM it8ptn-~ Ofkl taps pUtt

coa-w toa bullrx pedwlta bJ liOUiaJ oft WI OOII(IIIItnlioM or VOC SVOO ill a cohama partedwilllt~enbulltlriiL w -doflfaucotbull bull-ait lxltl tllll _ bull plaquo dle - anMfw of VOOJSVOCI frola u oq_ _ shy

I )

~

~t-tiaed)

naiiiampUlliWIIIIilcu-_

loa-middot _ Me4il fltratioa

flltntioa

OfOIwhmpiaamp

Or~ialrucrotptor

llillllll Loodlll

NPOES OllcUrl

Rod---o1- 0lt _ orpako tJuobullP tdiOrpdoa oato paa ~Mwd cartMML Mey be ased u a poUsblaamp ~~ aMr uea~l tla 111 UVOIOUttoll or tir atrippinampW reiDOyenC

~allfdClld CQIIdta

Separate CODCCIUIwd Cl)lllaiUaU rro- mtiClld water ISinabull semimiddot

--- RcmcM bull sol fJOM tlrl WMteWllet iltum by fordbullamp

water nwP a aM tu~a or cartridbullmiddotYfC filter

ttclftOYamp sol aacl bullWI frOil wuaew~tcr auum 111in1 1 mcrnbraM _ fltract pvftdWttcf frOCft Cl Of lfiOfS cstrectiotl - tO CORtrol Of rcWM tM UlkrW CCMI _ Qf0111141w1 wouMI be uealld oa-Mat UUifONd 10 bullbull olaquo-tiw ~licy or diKNrJICllnto ~n lor

-J()IW Colkld JfOIIdwiiCt Ia ~pawl Drtin to allow treampUMIIt to

take pLaee

saare ue~-t rtiM~tamp ( _ thadae ipCil caWft) Ia aa oCImiddot

JtCilA rdliJmiddot OllcUtl P hlw tiM atona draiM ttWU MtfliiOfk or latO 1M ltMf hi tttal OIICraquorp OCitiOI wid M ___ -~u flooltftlotwiUIIoo

to ~toe tM rtetM

lei~ Utamptarou Net Wlwt the JfOIII sinamp OM or ~wtlll

II

)

lfu Use cutrtrpl torce 10 _ tM MdlJMllltioa rate of thtdJI

Dtwaters illldp by dfliUII giDlP lM ahadJC Nil aDd tv~poratioa frolltMwrc IOaitmiddot

()ewaterstl~IC by ~~Mill a coatLa- tuw belt tNt nbull over a drive aDd auide roUir 11uca llld Ukamp I (II)IIW70I MIL Shtdp is cootifliIOampSly diWiwed btCWMI lM IUW bella

otMten lllldfl _ ~ whll ~ Wlef 0 _ - _ - -Uto4-~ dcWitcritll IMlbOdl belli

Reduce tM IOiubull of 11-bull -cwal o( supetnltllll liquMt

Ocwatcn st~ae usiaa bull roampary cbullbullbull nuer

16

)

l l nCHNOLOOlES EVALUAreD l ao4llbelldl IAiiq wu 10 dcmOnsttalCthc cffcttln ol 1 tcthnoloJY In rc4ocinamp

poo-m coataonloanl that Clbt ao Nya to tbe MCUmiddot lie ronowlnamp oclttions daCribC bullbullbull UOIUDIGl ~eotalti~Md aDd lbC raOOoale lor cMIOIIDI ltlCII

lll EMIIJIIIIl l belldlmiddotIAiiq prcclpllltiooftOCltIIlaiiOalc4(tDCnlllioD and oa14atlonlflt40Cilon (-) ttquiR- 1llil wu tloDamp 10 delCrtniDC -1 and ooo41tiODI lor optimum rem o -_colloidal ao4 - - 1bC co11101lnatetl poutcr Hy4_ aetl 101idamp prodpilltiOtiWU -tlpte4 lo tbC PPM llludiiL ()aldatlottftetloctiDI rtqUitemCIII I

pK raaF for optimum metab reatQyenal wM abO bullgttilbOLIt~ IIUlytt preucat-14 be 10 _and rod 110bull conccnttatlons _ Ibull po ao Nyan belorlt othet lampdtoO _be _ Wit preucattneDI inorpnicllllll plbulll ca- _ IQlinl In alfoltripplol __ rod UV cftlclcncicS or ao nely lmpoct bioloPltl --bullbull perlortnl_ will abO tnellb loetli on polbullhlnamp proocUOI (I~ loa ()( rcverM 01100111) A _- o pacoot rlt-la i quoJilll _tiODI o( --lalioo (OrtMiloD led 10 IIIC -tillcatiOO o -F nnp (Or by4- polJIIIC (prodpllltiOO) ltyd-bull pcOildlt (-l icll_ ulllntbCCIeCI -o(lnoltPDicl D-pranpwerlt-olttbe p__ ill _ ll tina Table l middot l - tile tAl roo prod tbe boll r ulll

l ll Olll)llJIIlDurinamp ll lour etlditlonoltcchnololi boftdtmiddotICI oliOOIDI prcucattnCDI o arooICr 10 rc4uca- ampnorpnicl ThiiO lour_ were ioD altOinFo dlft bubble _oo ca____ ___L _ bull-bullbull- olt blllllll

-(LL bull 11rippln1 prior to actlvatc4 ca- Of ICiiVIte4 ca- ollor ___) _etiOI-1--Iol- loO_DF_ te41orinorpa1Crc-looly ea- _aott aoddiffuetl __ _ rororpolc -L BioloampICO__ tawd for botb i801pntt aD4 orpaic rcmovab lie PhiiC ll ideatlllcd tltc need to aetl lmplctneat ucattnCOI mcthOdl lor rc-1 o orpnicl For wmplc combibull bullbullabull 11rippin1 with acttvatc4 carbObull ucatmcat may be n_ary bullroomo cootantloaall arc dgtft~Cullto 11rip but -Uy 10 carbOn Altcrnatly c4 carbOn tniY be a pol~biDI 11cp ~ bioloalel ucatmcat bull cmplo)_ Tablel l-lto l -1 dcocribe Utbullt _ TIMamp 5-1 ilkoliftll tM water ctalily o( ttlamp r- Wllel priot ampa precipiudcm prcucaunenL

U 1Uf OBIECttvES _ o l ao4 ll beodt - 10 middot-- o - -o( ao4 -ubullilllbullbullbullbull pou-tallmpliiOOlshy11 1M tltyaua to beloW MOI TM bulltillamp- abO- 10 _1-middot-_---middot- piClypC o cacUaac - teiCOI ua- TbullriDI- oooductc4 to _ I rltllablt o IM tceJIOlOIYS abnity to _ contambullbullbull Ia the poutcr 11 the tlyaOJO 1111 TM olall col- - 001 iatcndc4 lor cftlclcY

I I I I

r~n hll

middot ll ~~l =~~Irrl l ~lil

f fl I

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 14: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

I I

) 0 WLIMINMY RfMEPIAl RpoundSPON$E OIJgcnyES

~po oOJoCiiOI for the Nyonu II middot Orobull- StY ~llf1 will be on the potential ror rokS to pbullblk ao4 the ca-roamltnL ~~~po objeCI not nnal and await completion of alltc-specilc tilt aiMU_L KoweYtr bUI4 01 CliltiOI dl~ wveral patbWI)l throuamph which humans

or tht eampMroruacll cou~ be tllpOie4 tO contamlnalll Ia pouactwatu bM been toeatlfiecl

o ttumaa cqu~~te tO coawainall pouactwaW wouP laiUoft Genna contaCt aR40r iobaiatloa if a water aupply aoune if dcwklfl at or bullr tbe 1Ue Ia tJre Mure

o cxpCIItiN 10 cootanUutell pou4WI W0MP 4Lrecl Qermal oonKl witb aDCl iobaltioD a( coowaiaUll lo eqMOYI or vapor lonD -piOI iato relideftdal ~~~ dodpdicnt rroca tbc lite

o u4 ~~tal apcllllfC 10 coocaalDUU froa poctwatcr once It ttiscUraeamp lato

wcda or tbe SuclbUIJ RiYef

Prtlhllinary ruS-1 rcspobull objecliwl tUt td4raamp tbelt poceatial apo~ure pathways inchiCampe

o Utaitilll pracatancl Murc riiD to humans cauMil b) apotUto to ooataminatc4 po~aactwatcr sltffacamp waterl aM -eau

o Ubullltilll deJfldltiol of tM Sltdb~try River aacl wetU41 liltamp to dischltp of coo~iaa- pouftdWiter and

o - appliltlgtbull ao4 rcplltlonl _ and ror PPY

MdltloNI- objeltIIWS may be 10pe4 on dall colleete4 In the Nyonull field intlplloa -middot aM 1M rilt performld bull ptn of tM RlFS

40 1QENDfJCampJON ANQ genNJNO OF DCtfNQIOOIE$

-- o( -middot-middot P- -torY o( tedlootol o(toldpdrll -inatiOn 11 1M Nytnaa _ EP teellnoloampY was evalolled on the - o( _ potclllal delnmiddotbullP -bull bull 11 MCU aod red- 1M potcntiol threat 10 poblllt

lbeuYitoii-L

Treat ~ pocealillly sllitab1 tor tM Nyaua liM wae ldPtifted Nled oa ~middot bull -n o( tM ~til oootaaiaatiol ull prcllnliIJ tctponsc objectiva The tcdtno~ - diYide4 iato ail calfIOI ucl catefMY rqwet~Rtilamp bull pp at re~pomamp actioU tblt covkl ___ -oOJoCiiOI

Sita eoauo1 COIItaillftlftl Treat_ ExtraciiOO

SlltdJIHiftthlll

)

lnncgtbulltll tedlooiOIa were identlllad rltgtntn4or JIIormampIIOD oa4 1ltc Superfloa4 ln_t TclthnOIOI)

Emiddotauadon Pro-= TtchnoloampY Proftlcs fJovember 1919 from tM EPA

42 TECHNOLOGY SCREENINO The laitlll scnertlol of~elthnolOampiOI wos - oa enampirinllelliblllry on4 oppllcobillry to tlto lOCidon or tlto NyortJA olte _ ntlytltotechnolOjlll wore-- oa agtnstroinu Imposelt by the rype or agtatomlnoau -middotc physkll agtn41tOns oltlto ute on4 _ or rettt~inlnl bull rault or tlto uurmenr p- croctcrlstlcl oltlto bullIre thll may or 11m1r tlto eKect_ o 1 tcchnOIOI) obtol - _ ltiptlOno Pbyskll propettY doll oltlto agtatominoau bullliCit olltllity bOiUal polaC -ry worc to oay lbolu Pttgte agtatominoau tbcmKIIIIY lmpaoe oabull ~todlaolOampYmiddot Wbullte ~- ldlatllod todelae - ltor ltlODII waste uatmcaL TiiM ~GftOIOIel wto1t a WM deatt) precluded by Wlll6 or site cUractcriitkl were elimltll rora--loa Tbc ults of this oltOill- _ rtsilmjp(Y Sqscoinl llfllms4i11TKbullIil (-May 1911~ TM ARCS te~a ldlatiGid odditlOnll toe~~aoOjielthll were

not coWdcred la ~ report Tobie 4middot1 Is 1 - o the remediatiOn tcchnoOjllltbat relftll after nln~ Tbc EbUltO-AilCS the )9techaoOjlllllstod oa Tobie 4-1 by-~ prodtKt lltCTIIUIC en4or inOrntltlOn pertonao doll -middot FSbull on4 bullhrobullJh dirlaquo agtnoultotiOO with n40ro A brie dOIltriptlOn of each

-~~-lnToblel-~

50 WASpound 1 ANQ u IRFAItBil m 1QT rsooRAM - Tbc tr0111hlliry _-1bull-to~ re-opodftlt -riOO reprdialthe perlormonlaquo

of--middot-ooiOilabullbull- shy ialtiol scneo~ POIIOtlll ftuncial rlsa on4 delaY lo - KtiOO oro _ with the --of 1 le(hnolOD lOr lmptementotlOn witbOIIt fl WfPOdaamp pcrfonMftCC data For tM uutabUity tCit PfOI-middot on-site bench-5CIIt telll wcro - oo troot-r -aoOjlll ooly II ipiOltoDI lt-1 lalOrmotiOO roprdinl the te(bldOI(i coM dketiyent- Of lrepkmotn~tbility cou4 M obtliaed at a rutOftlble eo~t P-I ud _U oltgte tlbiliry otudy ro-llad OltpDicl rrootmeftl pcctlvltly throop bettdt_ ~ lo ltloD _ relt~bull_ worc ideotltlcd durin the rroatobility otudy ud doll colieltrltd to_ the iDII_t_te otrubull u be to In evoiUitlnl

the applklbilicy o( MYCrtl ~~ tUt were aot btlldlmiddotbullbull From loorntltlOa ptherad ill - otudiOI dtamp woste dllrKterotlcl likely to lmplltt _-implemltDtobillry oadof-lalrroorrtechnolOIIOihbullbullicleifted

ThM -tlcs ladshyldiM rqeegliql middot A all llIIDbtr ol orpak alld iaorpllk contaminanu 1avt bctn ia 1t u- O~ ~~~ crronsmllkdJ to lavotw a ueaU1181 (a CCblalbull ol ubull- ) speorc proccu- oalpcd _ -----middot ()onlla _ shytlfiCdW fCIIiatlM CIOIIllaludoa

Ullf pracW middot Dtftdceciel Ia laflnlbulldol rcatilll 0 Ntk wttfl propen- sd pH oplaquotftlt Mry cooBOD TOC C DOl alii TM Rl ud ueaiblhlJ It~bull ld4rtU theM ~ ao4 flrthct We1Uify lmportut niMCtl li ely to illft lM trfectiveiIM o( UbullUMIIIII at~rNii-

10

--

I )

_ lloos-qSIolt __

Nua a-loll

ROlli tillXJl~

$11tOgtouol XFcaciaiiSP X X

loltihlioUl Coauoll ~- X5latfacc Waw Coluol

~ XCpplbulll XH)dnulkBarrilt Oroddw~MI lalaeeptor T~ftdl X

XFnaOIOIItiqo_ lajocdoll X

_ XtJmiddot

shyX

X =middot X

Wet Alr ()ddadoll1 X

~ XPNdplampl~lioiISediNalldol X -Locll w n~t FtdUa X XOI~WTNa-tFKIMtJ X -Potarilld ~ ()Ddaat ~o~J

DJiilll X sai-Fioill- XTllibull Fla EYapORlioas NltSiripplacc_-loa- X

-~ XMed6l FUusliol X ---X

X X

II

)

I

IJ r

-~ ~- Dnla - (_

lMIIWI IIPDES lllodWJO ~kMIIO Orouftdwltcr

shyDlll-CaUilloll ---middot lelt FUIIr FlloorPIW Onvlty1gtidtal01 v nmtiol

Rcta1M4 xa lfll

X X

X X X

X X

X X X X

1 tucwetM TtcUooD tbat il paR ot EPA Silamp OOMUIioll Proanbull middot turrcatty btiq rldd 1 1M Towll of AIJI)a ot M11 I p11bUdJ opaatcd _let UUIIMilt fidtlty

3 lllMMlM TdiiOkgtD

11

--

----

-I )

lllllo_Z ~ ot Orww Re8ldiadol T_

llyua QcUal Silo

FeocfAtSipl

llldaltioul ColiUOII

~loll Molltortq

Slllflcr Water Cotluol

ClppUit

tfJaiiUc Ianier

Groundwater lnjeaion

Reltrkt ~wt~ fuKll poll watIUill tlpl

11 lud or otMt NllricdoU to proltibh tbc use ol JfOIIIIChILtriiiMIMtilt

EYihaale mlpaliol ud dillriiMaUoll of eo~~~amp~~luaamps Oyener tiiDC ~a~ina 11orina 10 aapll lM CMIHnlal alliS bedroct aquller

ConUOI slllflct waw ru4 owr Ike 1114 lbuefore lallltrat6oa to poundwttar

Pmat iaftltraliiMI ot _doll iiiO coatlaiuted ZOIIII wiU a RCilA 111dtimiddotlayet cap or OlMr cappWc bullterilil

OMrt ltMItMUda pouctwaamper ftow aroud contlmintted zona willa limy Wlwat piliq

ampLiblillrl 1 bedroct ~ _ulictlly bullptradient of the site 10 tower JfOUMwalel dMidoll il coaaaaiuS

Pmut JfOUDdwalef _ tlarotaP COIItlflliMtcd IODa by poutiq Mdrock traura

laect wttrr Into the Jf0111Mh1W to bydnulkllly prevtnt the funhct miJfltioo ot COGtamiauq

ltiuod abulllriull ld 01J111 iiiiO liM JfOUMIWIIer aiGJ I uix of atiKI~ wdll lid redmd1Ui01 amnktues 10 stimulate

~middot- __ _ _ _ICampMIM _or~bull lltIHolopcal NeQOr

(ampJ I trictllq IUICf tOCatilt ~ CIOIIIKtOII)

I)

IIitr 1~

bullbull

) I ~

t~r~

Acrltioft

_ Otf-tlbull wT

FtciiiY

PolarU4 Mlt4iiJ()WolvOd QDdall 1M

()llidbe orpakl ill atJICUIIII pouadMIU willa I llal1tiOCO

applklt of ll~ upt aad a rona oQdilcr

Otatroy orpaic co~wafuall La aa aq~~M~Gtll IOiudOD by iDdMiaJ ollidadoll aiMI laydtolylil reeaiOM at lllP waperauuc aDd prt~Suramp Olyp at ekWUid _ cabaDC tbamp oddat~D of orpak

coapoddlto carbOa diolidamp bullbullmiddot

AI1111C tM lfOIadWatlt 10 ~ iaoJpClk itOft and mlfiMM andmiddot-middot- middot-eo-t dillotvd 10 aa tolubae font (lc metal sulftde W ~or boa aauta) padld tOiiclltiUOUIJI

ftoealladoa settle out IOl6dl ~ plilJmiddot

Dildlotl atroaed --to-- ()wOOdTNat_t WOJIII (POTWl for ubulltbullat Water mISt rr preutbullat llllldl141 bdofC diiCIW 10 tillamp fadlicy

adDente ubullbullbullbullbull _ (sl cartiOII) at aa ol-liw

Killty 1rllff coaUUMII CK (OIICIampIItrtlld wu~ to offmiddotslte (tctlity rot flnhcr ubulltmcnt

Olddizt orpnicS and c~rot)kll~ ftltcr ioM dint ionized OIYfll u4 aiuotta and llltflliokl IJbL

___ - --Ia aM it8ptn-~ Ofkl taps pUtt

coa-w toa bullrx pedwlta bJ liOUiaJ oft WI OOII(IIIItnlioM or VOC SVOO ill a cohama partedwilllt~enbulltlriiL w -doflfaucotbull bull-ait lxltl tllll _ bull plaquo dle - anMfw of VOOJSVOCI frola u oq_ _ shy

I )

~

~t-tiaed)

naiiiampUlliWIIIIilcu-_

loa-middot _ Me4il fltratioa

flltntioa

OfOIwhmpiaamp

Or~ialrucrotptor

llillllll Loodlll

NPOES OllcUrl

Rod---o1- 0lt _ orpako tJuobullP tdiOrpdoa oato paa ~Mwd cartMML Mey be ased u a poUsblaamp ~~ aMr uea~l tla 111 UVOIOUttoll or tir atrippinampW reiDOyenC

~allfdClld CQIIdta

Separate CODCCIUIwd Cl)lllaiUaU rro- mtiClld water ISinabull semimiddot

--- RcmcM bull sol fJOM tlrl WMteWllet iltum by fordbullamp

water nwP a aM tu~a or cartridbullmiddotYfC filter

ttclftOYamp sol aacl bullWI frOil wuaew~tcr auum 111in1 1 mcrnbraM _ fltract pvftdWttcf frOCft Cl Of lfiOfS cstrectiotl - tO CORtrol Of rcWM tM UlkrW CCMI _ Qf0111141w1 wouMI be uealld oa-Mat UUifONd 10 bullbull olaquo-tiw ~licy or diKNrJICllnto ~n lor

-J()IW Colkld JfOIIdwiiCt Ia ~pawl Drtin to allow treampUMIIt to

take pLaee

saare ue~-t rtiM~tamp ( _ thadae ipCil caWft) Ia aa oCImiddot

JtCilA rdliJmiddot OllcUtl P hlw tiM atona draiM ttWU MtfliiOfk or latO 1M ltMf hi tttal OIICraquorp OCitiOI wid M ___ -~u flooltftlotwiUIIoo

to ~toe tM rtetM

lei~ Utamptarou Net Wlwt the JfOIII sinamp OM or ~wtlll

II

)

lfu Use cutrtrpl torce 10 _ tM MdlJMllltioa rate of thtdJI

Dtwaters illldp by dfliUII giDlP lM ahadJC Nil aDd tv~poratioa frolltMwrc IOaitmiddot

()ewaterstl~IC by ~~Mill a coatLa- tuw belt tNt nbull over a drive aDd auide roUir 11uca llld Ukamp I (II)IIW70I MIL Shtdp is cootifliIOampSly diWiwed btCWMI lM IUW bella

otMten lllldfl _ ~ whll ~ Wlef 0 _ - _ - -Uto4-~ dcWitcritll IMlbOdl belli

Reduce tM IOiubull of 11-bull -cwal o( supetnltllll liquMt

Ocwatcn st~ae usiaa bull roampary cbullbullbull nuer

16

)

l l nCHNOLOOlES EVALUAreD l ao4llbelldl IAiiq wu 10 dcmOnsttalCthc cffcttln ol 1 tcthnoloJY In rc4ocinamp

poo-m coataonloanl that Clbt ao Nya to tbe MCUmiddot lie ronowlnamp oclttions daCribC bullbullbull UOIUDIGl ~eotalti~Md aDd lbC raOOoale lor cMIOIIDI ltlCII

lll EMIIJIIIIl l belldlmiddotIAiiq prcclpllltiooftOCltIIlaiiOalc4(tDCnlllioD and oa14atlonlflt40Cilon (-) ttquiR- 1llil wu tloDamp 10 delCrtniDC -1 and ooo41tiODI lor optimum rem o -_colloidal ao4 - - 1bC co11101lnatetl poutcr Hy4_ aetl 101idamp prodpilltiOtiWU -tlpte4 lo tbC PPM llludiiL ()aldatlottftetloctiDI rtqUitemCIII I

pK raaF for optimum metab reatQyenal wM abO bullgttilbOLIt~ IIUlytt preucat-14 be 10 _and rod 110bull conccnttatlons _ Ibull po ao Nyan belorlt othet lampdtoO _be _ Wit preucattneDI inorpnicllllll plbulll ca- _ IQlinl In alfoltripplol __ rod UV cftlclcncicS or ao nely lmpoct bioloPltl --bullbull perlortnl_ will abO tnellb loetli on polbullhlnamp proocUOI (I~ loa ()( rcverM 01100111) A _- o pacoot rlt-la i quoJilll _tiODI o( --lalioo (OrtMiloD led 10 IIIC -tillcatiOO o -F nnp (Or by4- polJIIIC (prodpllltiOO) ltyd-bull pcOildlt (-l icll_ ulllntbCCIeCI -o(lnoltPDicl D-pranpwerlt-olttbe p__ ill _ ll tina Table l middot l - tile tAl roo prod tbe boll r ulll

l ll Olll)llJIIlDurinamp ll lour etlditlonoltcchnololi boftdtmiddotICI oliOOIDI prcucattnCDI o arooICr 10 rc4uca- ampnorpnicl ThiiO lour_ were ioD altOinFo dlft bubble _oo ca____ ___L _ bull-bullbull- olt blllllll

-(LL bull 11rippln1 prior to actlvatc4 ca- Of ICiiVIte4 ca- ollor ___) _etiOI-1--Iol- loO_DF_ te41orinorpa1Crc-looly ea- _aott aoddiffuetl __ _ rororpolc -L BioloampICO__ tawd for botb i801pntt aD4 orpaic rcmovab lie PhiiC ll ideatlllcd tltc need to aetl lmplctneat ucattnCOI mcthOdl lor rc-1 o orpnicl For wmplc combibull bullbullabull 11rippin1 with acttvatc4 carbObull ucatmcat may be n_ary bullroomo cootantloaall arc dgtft~Cullto 11rip but -Uy 10 carbOn Altcrnatly c4 carbOn tniY be a pol~biDI 11cp ~ bioloalel ucatmcat bull cmplo)_ Tablel l-lto l -1 dcocribe Utbullt _ TIMamp 5-1 ilkoliftll tM water ctalily o( ttlamp r- Wllel priot ampa precipiudcm prcucaunenL

U 1Uf OBIECttvES _ o l ao4 ll beodt - 10 middot-- o - -o( ao4 -ubullilllbullbullbullbull pou-tallmpliiOOlshy11 1M tltyaua to beloW MOI TM bulltillamp- abO- 10 _1-middot-_---middot- piClypC o cacUaac - teiCOI ua- TbullriDI- oooductc4 to _ I rltllablt o IM tceJIOlOIYS abnity to _ contambullbullbull Ia the poutcr 11 the tlyaOJO 1111 TM olall col- - 001 iatcndc4 lor cftlclcY

I I I I

r~n hll

middot ll ~~l =~~Irrl l ~lil

f fl I

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 15: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

)

lnncgtbulltll tedlooiOIa were identlllad rltgtntn4or JIIormampIIOD oa4 1ltc Superfloa4 ln_t TclthnOIOI)

Emiddotauadon Pro-= TtchnoloampY Proftlcs fJovember 1919 from tM EPA

42 TECHNOLOGY SCREENINO The laitlll scnertlol of~elthnolOampiOI wos - oa enampirinllelliblllry on4 oppllcobillry to tlto lOCidon or tlto NyortJA olte _ ntlytltotechnolOjlll wore-- oa agtnstroinu Imposelt by the rype or agtatomlnoau -middotc physkll agtn41tOns oltlto ute on4 _ or rettt~inlnl bull rault or tlto uurmenr p- croctcrlstlcl oltlto bullIre thll may or 11m1r tlto eKect_ o 1 tcchnOIOI) obtol - _ ltiptlOno Pbyskll propettY doll oltlto agtatominoau bullliCit olltllity bOiUal polaC -ry worc to oay lbolu Pttgte agtatominoau tbcmKIIIIY lmpaoe oabull ~todlaolOampYmiddot Wbullte ~- ldlatllod todelae - ltor ltlODII waste uatmcaL TiiM ~GftOIOIel wto1t a WM deatt) precluded by Wlll6 or site cUractcriitkl were elimltll rora--loa Tbc ults of this oltOill- _ rtsilmjp(Y Sqscoinl llfllms4i11TKbullIil (-May 1911~ TM ARCS te~a ldlatiGid odditlOnll toe~~aoOjielthll were

not coWdcred la ~ report Tobie 4middot1 Is 1 - o the remediatiOn tcchnoOjllltbat relftll after nln~ Tbc EbUltO-AilCS the )9techaoOjlllllstod oa Tobie 4-1 by-~ prodtKt lltCTIIUIC en4or inOrntltlOn pertonao doll -middot FSbull on4 bullhrobullJh dirlaquo agtnoultotiOO with n40ro A brie dOIltriptlOn of each

-~~-lnToblel-~

50 WASpound 1 ANQ u IRFAItBil m 1QT rsooRAM - Tbc tr0111hlliry _-1bull-to~ re-opodftlt -riOO reprdialthe perlormonlaquo

of--middot-ooiOilabullbull- shy ialtiol scneo~ POIIOtlll ftuncial rlsa on4 delaY lo - KtiOO oro _ with the --of 1 le(hnolOD lOr lmptementotlOn witbOIIt fl WfPOdaamp pcrfonMftCC data For tM uutabUity tCit PfOI-middot on-site bench-5CIIt telll wcro - oo troot-r -aoOjlll ooly II ipiOltoDI lt-1 lalOrmotiOO roprdinl the te(bldOI(i coM dketiyent- Of lrepkmotn~tbility cou4 M obtliaed at a rutOftlble eo~t P-I ud _U oltgte tlbiliry otudy ro-llad OltpDicl rrootmeftl pcctlvltly throop bettdt_ ~ lo ltloD _ relt~bull_ worc ideotltlcd durin the rroatobility otudy ud doll colieltrltd to_ the iDII_t_te otrubull u be to In evoiUitlnl

the applklbilicy o( MYCrtl ~~ tUt were aot btlldlmiddotbullbull From loorntltlOa ptherad ill - otudiOI dtamp woste dllrKterotlcl likely to lmplltt _-implemltDtobillry oadof-lalrroorrtechnolOIIOihbullbullicleifted

ThM -tlcs ladshyldiM rqeegliql middot A all llIIDbtr ol orpak alld iaorpllk contaminanu 1avt bctn ia 1t u- O~ ~~~ crronsmllkdJ to lavotw a ueaU1181 (a CCblalbull ol ubull- ) speorc proccu- oalpcd _ -----middot ()onlla _ shytlfiCdW fCIIiatlM CIOIIllaludoa

Ullf pracW middot Dtftdceciel Ia laflnlbulldol rcatilll 0 Ntk wttfl propen- sd pH oplaquotftlt Mry cooBOD TOC C DOl alii TM Rl ud ueaiblhlJ It~bull ld4rtU theM ~ ao4 flrthct We1Uify lmportut niMCtl li ely to illft lM trfectiveiIM o( UbullUMIIIII at~rNii-

10

--

I )

_ lloos-qSIolt __

Nua a-loll

ROlli tillXJl~

$11tOgtouol XFcaciaiiSP X X

loltihlioUl Coauoll ~- X5latfacc Waw Coluol

~ XCpplbulll XH)dnulkBarrilt Oroddw~MI lalaeeptor T~ftdl X

XFnaOIOIItiqo_ lajocdoll X

_ XtJmiddot

shyX

X =middot X

Wet Alr ()ddadoll1 X

~ XPNdplampl~lioiISediNalldol X -Locll w n~t FtdUa X XOI~WTNa-tFKIMtJ X -Potarilld ~ ()Ddaat ~o~J

DJiilll X sai-Fioill- XTllibull Fla EYapORlioas NltSiripplacc_-loa- X

-~ XMed6l FUusliol X ---X

X X

II

)

I

IJ r

-~ ~- Dnla - (_

lMIIWI IIPDES lllodWJO ~kMIIO Orouftdwltcr

shyDlll-CaUilloll ---middot lelt FUIIr FlloorPIW Onvlty1gtidtal01 v nmtiol

Rcta1M4 xa lfll

X X

X X X

X X

X X X X

1 tucwetM TtcUooD tbat il paR ot EPA Silamp OOMUIioll Proanbull middot turrcatty btiq rldd 1 1M Towll of AIJI)a ot M11 I p11bUdJ opaatcd _let UUIIMilt fidtlty

3 lllMMlM TdiiOkgtD

11

--

----

-I )

lllllo_Z ~ ot Orww Re8ldiadol T_

llyua QcUal Silo

FeocfAtSipl

llldaltioul ColiUOII

~loll Molltortq

Slllflcr Water Cotluol

ClppUit

tfJaiiUc Ianier

Groundwater lnjeaion

Reltrkt ~wt~ fuKll poll watIUill tlpl

11 lud or otMt NllricdoU to proltibh tbc use ol JfOIIIIChILtriiiMIMtilt

EYihaale mlpaliol ud dillriiMaUoll of eo~~~amp~~luaamps Oyener tiiDC ~a~ina 11orina 10 aapll lM CMIHnlal alliS bedroct aquller

ConUOI slllflct waw ru4 owr Ike 1114 lbuefore lallltrat6oa to poundwttar

Pmat iaftltraliiMI ot _doll iiiO coatlaiuted ZOIIII wiU a RCilA 111dtimiddotlayet cap or OlMr cappWc bullterilil

OMrt ltMItMUda pouctwaamper ftow aroud contlmintted zona willa limy Wlwat piliq

ampLiblillrl 1 bedroct ~ _ulictlly bullptradient of the site 10 tower JfOUMwalel dMidoll il coaaaaiuS

Pmut JfOUDdwalef _ tlarotaP COIItlflliMtcd IODa by poutiq Mdrock traura

laect wttrr Into the Jf0111Mh1W to bydnulkllly prevtnt the funhct miJfltioo ot COGtamiauq

ltiuod abulllriull ld 01J111 iiiiO liM JfOUMIWIIer aiGJ I uix of atiKI~ wdll lid redmd1Ui01 amnktues 10 stimulate

~middot- __ _ _ _ICampMIM _or~bull lltIHolopcal NeQOr

(ampJ I trictllq IUICf tOCatilt ~ CIOIIIKtOII)

I)

IIitr 1~

bullbull

) I ~

t~r~

Acrltioft

_ Otf-tlbull wT

FtciiiY

PolarU4 Mlt4iiJ()WolvOd QDdall 1M

()llidbe orpakl ill atJICUIIII pouadMIU willa I llal1tiOCO

applklt of ll~ upt aad a rona oQdilcr

Otatroy orpaic co~wafuall La aa aq~~M~Gtll IOiudOD by iDdMiaJ ollidadoll aiMI laydtolylil reeaiOM at lllP waperauuc aDd prt~Suramp Olyp at ekWUid _ cabaDC tbamp oddat~D of orpak

coapoddlto carbOa diolidamp bullbullmiddot

AI1111C tM lfOIadWatlt 10 ~ iaoJpClk itOft and mlfiMM andmiddot-middot- middot-eo-t dillotvd 10 aa tolubae font (lc metal sulftde W ~or boa aauta) padld tOiiclltiUOUIJI

ftoealladoa settle out IOl6dl ~ plilJmiddot

Dildlotl atroaed --to-- ()wOOdTNat_t WOJIII (POTWl for ubulltbullat Water mISt rr preutbullat llllldl141 bdofC diiCIW 10 tillamp fadlicy

adDente ubullbullbullbullbull _ (sl cartiOII) at aa ol-liw

Killty 1rllff coaUUMII CK (OIICIampIItrtlld wu~ to offmiddotslte (tctlity rot flnhcr ubulltmcnt

Olddizt orpnicS and c~rot)kll~ ftltcr ioM dint ionized OIYfll u4 aiuotta and llltflliokl IJbL

___ - --Ia aM it8ptn-~ Ofkl taps pUtt

coa-w toa bullrx pedwlta bJ liOUiaJ oft WI OOII(IIIItnlioM or VOC SVOO ill a cohama partedwilllt~enbulltlriiL w -doflfaucotbull bull-ait lxltl tllll _ bull plaquo dle - anMfw of VOOJSVOCI frola u oq_ _ shy

I )

~

~t-tiaed)

naiiiampUlliWIIIIilcu-_

loa-middot _ Me4il fltratioa

flltntioa

OfOIwhmpiaamp

Or~ialrucrotptor

llillllll Loodlll

NPOES OllcUrl

Rod---o1- 0lt _ orpako tJuobullP tdiOrpdoa oato paa ~Mwd cartMML Mey be ased u a poUsblaamp ~~ aMr uea~l tla 111 UVOIOUttoll or tir atrippinampW reiDOyenC

~allfdClld CQIIdta

Separate CODCCIUIwd Cl)lllaiUaU rro- mtiClld water ISinabull semimiddot

--- RcmcM bull sol fJOM tlrl WMteWllet iltum by fordbullamp

water nwP a aM tu~a or cartridbullmiddotYfC filter

ttclftOYamp sol aacl bullWI frOil wuaew~tcr auum 111in1 1 mcrnbraM _ fltract pvftdWttcf frOCft Cl Of lfiOfS cstrectiotl - tO CORtrol Of rcWM tM UlkrW CCMI _ Qf0111141w1 wouMI be uealld oa-Mat UUifONd 10 bullbull olaquo-tiw ~licy or diKNrJICllnto ~n lor

-J()IW Colkld JfOIIdwiiCt Ia ~pawl Drtin to allow treampUMIIt to

take pLaee

saare ue~-t rtiM~tamp ( _ thadae ipCil caWft) Ia aa oCImiddot

JtCilA rdliJmiddot OllcUtl P hlw tiM atona draiM ttWU MtfliiOfk or latO 1M ltMf hi tttal OIICraquorp OCitiOI wid M ___ -~u flooltftlotwiUIIoo

to ~toe tM rtetM

lei~ Utamptarou Net Wlwt the JfOIII sinamp OM or ~wtlll

II

)

lfu Use cutrtrpl torce 10 _ tM MdlJMllltioa rate of thtdJI

Dtwaters illldp by dfliUII giDlP lM ahadJC Nil aDd tv~poratioa frolltMwrc IOaitmiddot

()ewaterstl~IC by ~~Mill a coatLa- tuw belt tNt nbull over a drive aDd auide roUir 11uca llld Ukamp I (II)IIW70I MIL Shtdp is cootifliIOampSly diWiwed btCWMI lM IUW bella

otMten lllldfl _ ~ whll ~ Wlef 0 _ - _ - -Uto4-~ dcWitcritll IMlbOdl belli

Reduce tM IOiubull of 11-bull -cwal o( supetnltllll liquMt

Ocwatcn st~ae usiaa bull roampary cbullbullbull nuer

16

)

l l nCHNOLOOlES EVALUAreD l ao4llbelldl IAiiq wu 10 dcmOnsttalCthc cffcttln ol 1 tcthnoloJY In rc4ocinamp

poo-m coataonloanl that Clbt ao Nya to tbe MCUmiddot lie ronowlnamp oclttions daCribC bullbullbull UOIUDIGl ~eotalti~Md aDd lbC raOOoale lor cMIOIIDI ltlCII

lll EMIIJIIIIl l belldlmiddotIAiiq prcclpllltiooftOCltIIlaiiOalc4(tDCnlllioD and oa14atlonlflt40Cilon (-) ttquiR- 1llil wu tloDamp 10 delCrtniDC -1 and ooo41tiODI lor optimum rem o -_colloidal ao4 - - 1bC co11101lnatetl poutcr Hy4_ aetl 101idamp prodpilltiOtiWU -tlpte4 lo tbC PPM llludiiL ()aldatlottftetloctiDI rtqUitemCIII I

pK raaF for optimum metab reatQyenal wM abO bullgttilbOLIt~ IIUlytt preucat-14 be 10 _and rod 110bull conccnttatlons _ Ibull po ao Nyan belorlt othet lampdtoO _be _ Wit preucattneDI inorpnicllllll plbulll ca- _ IQlinl In alfoltripplol __ rod UV cftlclcncicS or ao nely lmpoct bioloPltl --bullbull perlortnl_ will abO tnellb loetli on polbullhlnamp proocUOI (I~ loa ()( rcverM 01100111) A _- o pacoot rlt-la i quoJilll _tiODI o( --lalioo (OrtMiloD led 10 IIIC -tillcatiOO o -F nnp (Or by4- polJIIIC (prodpllltiOO) ltyd-bull pcOildlt (-l icll_ ulllntbCCIeCI -o(lnoltPDicl D-pranpwerlt-olttbe p__ ill _ ll tina Table l middot l - tile tAl roo prod tbe boll r ulll

l ll Olll)llJIIlDurinamp ll lour etlditlonoltcchnololi boftdtmiddotICI oliOOIDI prcucattnCDI o arooICr 10 rc4uca- ampnorpnicl ThiiO lour_ were ioD altOinFo dlft bubble _oo ca____ ___L _ bull-bullbull- olt blllllll

-(LL bull 11rippln1 prior to actlvatc4 ca- Of ICiiVIte4 ca- ollor ___) _etiOI-1--Iol- loO_DF_ te41orinorpa1Crc-looly ea- _aott aoddiffuetl __ _ rororpolc -L BioloampICO__ tawd for botb i801pntt aD4 orpaic rcmovab lie PhiiC ll ideatlllcd tltc need to aetl lmplctneat ucattnCOI mcthOdl lor rc-1 o orpnicl For wmplc combibull bullbullabull 11rippin1 with acttvatc4 carbObull ucatmcat may be n_ary bullroomo cootantloaall arc dgtft~Cullto 11rip but -Uy 10 carbOn Altcrnatly c4 carbOn tniY be a pol~biDI 11cp ~ bioloalel ucatmcat bull cmplo)_ Tablel l-lto l -1 dcocribe Utbullt _ TIMamp 5-1 ilkoliftll tM water ctalily o( ttlamp r- Wllel priot ampa precipiudcm prcucaunenL

U 1Uf OBIECttvES _ o l ao4 ll beodt - 10 middot-- o - -o( ao4 -ubullilllbullbullbullbull pou-tallmpliiOOlshy11 1M tltyaua to beloW MOI TM bulltillamp- abO- 10 _1-middot-_---middot- piClypC o cacUaac - teiCOI ua- TbullriDI- oooductc4 to _ I rltllablt o IM tceJIOlOIYS abnity to _ contambullbullbull Ia the poutcr 11 the tlyaOJO 1111 TM olall col- - 001 iatcndc4 lor cftlclcY

I I I I

r~n hll

middot ll ~~l =~~Irrl l ~lil

f fl I

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 16: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

--

I )

_ lloos-qSIolt __

Nua a-loll

ROlli tillXJl~

$11tOgtouol XFcaciaiiSP X X

loltihlioUl Coauoll ~- X5latfacc Waw Coluol

~ XCpplbulll XH)dnulkBarrilt Oroddw~MI lalaeeptor T~ftdl X

XFnaOIOIItiqo_ lajocdoll X

_ XtJmiddot

shyX

X =middot X

Wet Alr ()ddadoll1 X

~ XPNdplampl~lioiISediNalldol X -Locll w n~t FtdUa X XOI~WTNa-tFKIMtJ X -Potarilld ~ ()Ddaat ~o~J

DJiilll X sai-Fioill- XTllibull Fla EYapORlioas NltSiripplacc_-loa- X

-~ XMed6l FUusliol X ---X

X X

II

)

I

IJ r

-~ ~- Dnla - (_

lMIIWI IIPDES lllodWJO ~kMIIO Orouftdwltcr

shyDlll-CaUilloll ---middot lelt FUIIr FlloorPIW Onvlty1gtidtal01 v nmtiol

Rcta1M4 xa lfll

X X

X X X

X X

X X X X

1 tucwetM TtcUooD tbat il paR ot EPA Silamp OOMUIioll Proanbull middot turrcatty btiq rldd 1 1M Towll of AIJI)a ot M11 I p11bUdJ opaatcd _let UUIIMilt fidtlty

3 lllMMlM TdiiOkgtD

11

--

----

-I )

lllllo_Z ~ ot Orww Re8ldiadol T_

llyua QcUal Silo

FeocfAtSipl

llldaltioul ColiUOII

~loll Molltortq

Slllflcr Water Cotluol

ClppUit

tfJaiiUc Ianier

Groundwater lnjeaion

Reltrkt ~wt~ fuKll poll watIUill tlpl

11 lud or otMt NllricdoU to proltibh tbc use ol JfOIIIIChILtriiiMIMtilt

EYihaale mlpaliol ud dillriiMaUoll of eo~~~amp~~luaamps Oyener tiiDC ~a~ina 11orina 10 aapll lM CMIHnlal alliS bedroct aquller

ConUOI slllflct waw ru4 owr Ike 1114 lbuefore lallltrat6oa to poundwttar

Pmat iaftltraliiMI ot _doll iiiO coatlaiuted ZOIIII wiU a RCilA 111dtimiddotlayet cap or OlMr cappWc bullterilil

OMrt ltMItMUda pouctwaamper ftow aroud contlmintted zona willa limy Wlwat piliq

ampLiblillrl 1 bedroct ~ _ulictlly bullptradient of the site 10 tower JfOUMwalel dMidoll il coaaaaiuS

Pmut JfOUDdwalef _ tlarotaP COIItlflliMtcd IODa by poutiq Mdrock traura

laect wttrr Into the Jf0111Mh1W to bydnulkllly prevtnt the funhct miJfltioo ot COGtamiauq

ltiuod abulllriull ld 01J111 iiiiO liM JfOUMIWIIer aiGJ I uix of atiKI~ wdll lid redmd1Ui01 amnktues 10 stimulate

~middot- __ _ _ _ICampMIM _or~bull lltIHolopcal NeQOr

(ampJ I trictllq IUICf tOCatilt ~ CIOIIIKtOII)

I)

IIitr 1~

bullbull

) I ~

t~r~

Acrltioft

_ Otf-tlbull wT

FtciiiY

PolarU4 Mlt4iiJ()WolvOd QDdall 1M

()llidbe orpakl ill atJICUIIII pouadMIU willa I llal1tiOCO

applklt of ll~ upt aad a rona oQdilcr

Otatroy orpaic co~wafuall La aa aq~~M~Gtll IOiudOD by iDdMiaJ ollidadoll aiMI laydtolylil reeaiOM at lllP waperauuc aDd prt~Suramp Olyp at ekWUid _ cabaDC tbamp oddat~D of orpak

coapoddlto carbOa diolidamp bullbullmiddot

AI1111C tM lfOIadWatlt 10 ~ iaoJpClk itOft and mlfiMM andmiddot-middot- middot-eo-t dillotvd 10 aa tolubae font (lc metal sulftde W ~or boa aauta) padld tOiiclltiUOUIJI

ftoealladoa settle out IOl6dl ~ plilJmiddot

Dildlotl atroaed --to-- ()wOOdTNat_t WOJIII (POTWl for ubulltbullat Water mISt rr preutbullat llllldl141 bdofC diiCIW 10 tillamp fadlicy

adDente ubullbullbullbullbull _ (sl cartiOII) at aa ol-liw

Killty 1rllff coaUUMII CK (OIICIampIItrtlld wu~ to offmiddotslte (tctlity rot flnhcr ubulltmcnt

Olddizt orpnicS and c~rot)kll~ ftltcr ioM dint ionized OIYfll u4 aiuotta and llltflliokl IJbL

___ - --Ia aM it8ptn-~ Ofkl taps pUtt

coa-w toa bullrx pedwlta bJ liOUiaJ oft WI OOII(IIIItnlioM or VOC SVOO ill a cohama partedwilllt~enbulltlriiL w -doflfaucotbull bull-ait lxltl tllll _ bull plaquo dle - anMfw of VOOJSVOCI frola u oq_ _ shy

I )

~

~t-tiaed)

naiiiampUlliWIIIIilcu-_

loa-middot _ Me4il fltratioa

flltntioa

OfOIwhmpiaamp

Or~ialrucrotptor

llillllll Loodlll

NPOES OllcUrl

Rod---o1- 0lt _ orpako tJuobullP tdiOrpdoa oato paa ~Mwd cartMML Mey be ased u a poUsblaamp ~~ aMr uea~l tla 111 UVOIOUttoll or tir atrippinampW reiDOyenC

~allfdClld CQIIdta

Separate CODCCIUIwd Cl)lllaiUaU rro- mtiClld water ISinabull semimiddot

--- RcmcM bull sol fJOM tlrl WMteWllet iltum by fordbullamp

water nwP a aM tu~a or cartridbullmiddotYfC filter

ttclftOYamp sol aacl bullWI frOil wuaew~tcr auum 111in1 1 mcrnbraM _ fltract pvftdWttcf frOCft Cl Of lfiOfS cstrectiotl - tO CORtrol Of rcWM tM UlkrW CCMI _ Qf0111141w1 wouMI be uealld oa-Mat UUifONd 10 bullbull olaquo-tiw ~licy or diKNrJICllnto ~n lor

-J()IW Colkld JfOIIdwiiCt Ia ~pawl Drtin to allow treampUMIIt to

take pLaee

saare ue~-t rtiM~tamp ( _ thadae ipCil caWft) Ia aa oCImiddot

JtCilA rdliJmiddot OllcUtl P hlw tiM atona draiM ttWU MtfliiOfk or latO 1M ltMf hi tttal OIICraquorp OCitiOI wid M ___ -~u flooltftlotwiUIIoo

to ~toe tM rtetM

lei~ Utamptarou Net Wlwt the JfOIII sinamp OM or ~wtlll

II

)

lfu Use cutrtrpl torce 10 _ tM MdlJMllltioa rate of thtdJI

Dtwaters illldp by dfliUII giDlP lM ahadJC Nil aDd tv~poratioa frolltMwrc IOaitmiddot

()ewaterstl~IC by ~~Mill a coatLa- tuw belt tNt nbull over a drive aDd auide roUir 11uca llld Ukamp I (II)IIW70I MIL Shtdp is cootifliIOampSly diWiwed btCWMI lM IUW bella

otMten lllldfl _ ~ whll ~ Wlef 0 _ - _ - -Uto4-~ dcWitcritll IMlbOdl belli

Reduce tM IOiubull of 11-bull -cwal o( supetnltllll liquMt

Ocwatcn st~ae usiaa bull roampary cbullbullbull nuer

16

)

l l nCHNOLOOlES EVALUAreD l ao4llbelldl IAiiq wu 10 dcmOnsttalCthc cffcttln ol 1 tcthnoloJY In rc4ocinamp

poo-m coataonloanl that Clbt ao Nya to tbe MCUmiddot lie ronowlnamp oclttions daCribC bullbullbull UOIUDIGl ~eotalti~Md aDd lbC raOOoale lor cMIOIIDI ltlCII

lll EMIIJIIIIl l belldlmiddotIAiiq prcclpllltiooftOCltIIlaiiOalc4(tDCnlllioD and oa14atlonlflt40Cilon (-) ttquiR- 1llil wu tloDamp 10 delCrtniDC -1 and ooo41tiODI lor optimum rem o -_colloidal ao4 - - 1bC co11101lnatetl poutcr Hy4_ aetl 101idamp prodpilltiOtiWU -tlpte4 lo tbC PPM llludiiL ()aldatlottftetloctiDI rtqUitemCIII I

pK raaF for optimum metab reatQyenal wM abO bullgttilbOLIt~ IIUlytt preucat-14 be 10 _and rod 110bull conccnttatlons _ Ibull po ao Nyan belorlt othet lampdtoO _be _ Wit preucattneDI inorpnicllllll plbulll ca- _ IQlinl In alfoltripplol __ rod UV cftlclcncicS or ao nely lmpoct bioloPltl --bullbull perlortnl_ will abO tnellb loetli on polbullhlnamp proocUOI (I~ loa ()( rcverM 01100111) A _- o pacoot rlt-la i quoJilll _tiODI o( --lalioo (OrtMiloD led 10 IIIC -tillcatiOO o -F nnp (Or by4- polJIIIC (prodpllltiOO) ltyd-bull pcOildlt (-l icll_ ulllntbCCIeCI -o(lnoltPDicl D-pranpwerlt-olttbe p__ ill _ ll tina Table l middot l - tile tAl roo prod tbe boll r ulll

l ll Olll)llJIIlDurinamp ll lour etlditlonoltcchnololi boftdtmiddotICI oliOOIDI prcucattnCDI o arooICr 10 rc4uca- ampnorpnicl ThiiO lour_ were ioD altOinFo dlft bubble _oo ca____ ___L _ bull-bullbull- olt blllllll

-(LL bull 11rippln1 prior to actlvatc4 ca- Of ICiiVIte4 ca- ollor ___) _etiOI-1--Iol- loO_DF_ te41orinorpa1Crc-looly ea- _aott aoddiffuetl __ _ rororpolc -L BioloampICO__ tawd for botb i801pntt aD4 orpaic rcmovab lie PhiiC ll ideatlllcd tltc need to aetl lmplctneat ucattnCOI mcthOdl lor rc-1 o orpnicl For wmplc combibull bullbullabull 11rippin1 with acttvatc4 carbObull ucatmcat may be n_ary bullroomo cootantloaall arc dgtft~Cullto 11rip but -Uy 10 carbOn Altcrnatly c4 carbOn tniY be a pol~biDI 11cp ~ bioloalel ucatmcat bull cmplo)_ Tablel l-lto l -1 dcocribe Utbullt _ TIMamp 5-1 ilkoliftll tM water ctalily o( ttlamp r- Wllel priot ampa precipiudcm prcucaunenL

U 1Uf OBIECttvES _ o l ao4 ll beodt - 10 middot-- o - -o( ao4 -ubullilllbullbullbullbull pou-tallmpliiOOlshy11 1M tltyaua to beloW MOI TM bulltillamp- abO- 10 _1-middot-_---middot- piClypC o cacUaac - teiCOI ua- TbullriDI- oooductc4 to _ I rltllablt o IM tceJIOlOIYS abnity to _ contambullbullbull Ia the poutcr 11 the tlyaOJO 1111 TM olall col- - 001 iatcndc4 lor cftlclcY

I I I I

r~n hll

middot ll ~~l =~~Irrl l ~lil

f fl I

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 17: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

)

I

IJ r

-~ ~- Dnla - (_

lMIIWI IIPDES lllodWJO ~kMIIO Orouftdwltcr

shyDlll-CaUilloll ---middot lelt FUIIr FlloorPIW Onvlty1gtidtal01 v nmtiol

Rcta1M4 xa lfll

X X

X X X

X X

X X X X

1 tucwetM TtcUooD tbat il paR ot EPA Silamp OOMUIioll Proanbull middot turrcatty btiq rldd 1 1M Towll of AIJI)a ot M11 I p11bUdJ opaatcd _let UUIIMilt fidtlty

3 lllMMlM TdiiOkgtD

11

--

----

-I )

lllllo_Z ~ ot Orww Re8ldiadol T_

llyua QcUal Silo

FeocfAtSipl

llldaltioul ColiUOII

~loll Molltortq

Slllflcr Water Cotluol

ClppUit

tfJaiiUc Ianier

Groundwater lnjeaion

Reltrkt ~wt~ fuKll poll watIUill tlpl

11 lud or otMt NllricdoU to proltibh tbc use ol JfOIIIIChILtriiiMIMtilt

EYihaale mlpaliol ud dillriiMaUoll of eo~~~amp~~luaamps Oyener tiiDC ~a~ina 11orina 10 aapll lM CMIHnlal alliS bedroct aquller

ConUOI slllflct waw ru4 owr Ike 1114 lbuefore lallltrat6oa to poundwttar

Pmat iaftltraliiMI ot _doll iiiO coatlaiuted ZOIIII wiU a RCilA 111dtimiddotlayet cap or OlMr cappWc bullterilil

OMrt ltMItMUda pouctwaamper ftow aroud contlmintted zona willa limy Wlwat piliq

ampLiblillrl 1 bedroct ~ _ulictlly bullptradient of the site 10 tower JfOUMwalel dMidoll il coaaaaiuS

Pmut JfOUDdwalef _ tlarotaP COIItlflliMtcd IODa by poutiq Mdrock traura

laect wttrr Into the Jf0111Mh1W to bydnulkllly prevtnt the funhct miJfltioo ot COGtamiauq

ltiuod abulllriull ld 01J111 iiiiO liM JfOUMIWIIer aiGJ I uix of atiKI~ wdll lid redmd1Ui01 amnktues 10 stimulate

~middot- __ _ _ _ICampMIM _or~bull lltIHolopcal NeQOr

(ampJ I trictllq IUICf tOCatilt ~ CIOIIIKtOII)

I)

IIitr 1~

bullbull

) I ~

t~r~

Acrltioft

_ Otf-tlbull wT

FtciiiY

PolarU4 Mlt4iiJ()WolvOd QDdall 1M

()llidbe orpakl ill atJICUIIII pouadMIU willa I llal1tiOCO

applklt of ll~ upt aad a rona oQdilcr

Otatroy orpaic co~wafuall La aa aq~~M~Gtll IOiudOD by iDdMiaJ ollidadoll aiMI laydtolylil reeaiOM at lllP waperauuc aDd prt~Suramp Olyp at ekWUid _ cabaDC tbamp oddat~D of orpak

coapoddlto carbOa diolidamp bullbullmiddot

AI1111C tM lfOIadWatlt 10 ~ iaoJpClk itOft and mlfiMM andmiddot-middot- middot-eo-t dillotvd 10 aa tolubae font (lc metal sulftde W ~or boa aauta) padld tOiiclltiUOUIJI

ftoealladoa settle out IOl6dl ~ plilJmiddot

Dildlotl atroaed --to-- ()wOOdTNat_t WOJIII (POTWl for ubulltbullat Water mISt rr preutbullat llllldl141 bdofC diiCIW 10 tillamp fadlicy

adDente ubullbullbullbullbull _ (sl cartiOII) at aa ol-liw

Killty 1rllff coaUUMII CK (OIICIampIItrtlld wu~ to offmiddotslte (tctlity rot flnhcr ubulltmcnt

Olddizt orpnicS and c~rot)kll~ ftltcr ioM dint ionized OIYfll u4 aiuotta and llltflliokl IJbL

___ - --Ia aM it8ptn-~ Ofkl taps pUtt

coa-w toa bullrx pedwlta bJ liOUiaJ oft WI OOII(IIIItnlioM or VOC SVOO ill a cohama partedwilllt~enbulltlriiL w -doflfaucotbull bull-ait lxltl tllll _ bull plaquo dle - anMfw of VOOJSVOCI frola u oq_ _ shy

I )

~

~t-tiaed)

naiiiampUlliWIIIIilcu-_

loa-middot _ Me4il fltratioa

flltntioa

OfOIwhmpiaamp

Or~ialrucrotptor

llillllll Loodlll

NPOES OllcUrl

Rod---o1- 0lt _ orpako tJuobullP tdiOrpdoa oato paa ~Mwd cartMML Mey be ased u a poUsblaamp ~~ aMr uea~l tla 111 UVOIOUttoll or tir atrippinampW reiDOyenC

~allfdClld CQIIdta

Separate CODCCIUIwd Cl)lllaiUaU rro- mtiClld water ISinabull semimiddot

--- RcmcM bull sol fJOM tlrl WMteWllet iltum by fordbullamp

water nwP a aM tu~a or cartridbullmiddotYfC filter

ttclftOYamp sol aacl bullWI frOil wuaew~tcr auum 111in1 1 mcrnbraM _ fltract pvftdWttcf frOCft Cl Of lfiOfS cstrectiotl - tO CORtrol Of rcWM tM UlkrW CCMI _ Qf0111141w1 wouMI be uealld oa-Mat UUifONd 10 bullbull olaquo-tiw ~licy or diKNrJICllnto ~n lor

-J()IW Colkld JfOIIdwiiCt Ia ~pawl Drtin to allow treampUMIIt to

take pLaee

saare ue~-t rtiM~tamp ( _ thadae ipCil caWft) Ia aa oCImiddot

JtCilA rdliJmiddot OllcUtl P hlw tiM atona draiM ttWU MtfliiOfk or latO 1M ltMf hi tttal OIICraquorp OCitiOI wid M ___ -~u flooltftlotwiUIIoo

to ~toe tM rtetM

lei~ Utamptarou Net Wlwt the JfOIII sinamp OM or ~wtlll

II

)

lfu Use cutrtrpl torce 10 _ tM MdlJMllltioa rate of thtdJI

Dtwaters illldp by dfliUII giDlP lM ahadJC Nil aDd tv~poratioa frolltMwrc IOaitmiddot

()ewaterstl~IC by ~~Mill a coatLa- tuw belt tNt nbull over a drive aDd auide roUir 11uca llld Ukamp I (II)IIW70I MIL Shtdp is cootifliIOampSly diWiwed btCWMI lM IUW bella

otMten lllldfl _ ~ whll ~ Wlef 0 _ - _ - -Uto4-~ dcWitcritll IMlbOdl belli

Reduce tM IOiubull of 11-bull -cwal o( supetnltllll liquMt

Ocwatcn st~ae usiaa bull roampary cbullbullbull nuer

16

)

l l nCHNOLOOlES EVALUAreD l ao4llbelldl IAiiq wu 10 dcmOnsttalCthc cffcttln ol 1 tcthnoloJY In rc4ocinamp

poo-m coataonloanl that Clbt ao Nya to tbe MCUmiddot lie ronowlnamp oclttions daCribC bullbullbull UOIUDIGl ~eotalti~Md aDd lbC raOOoale lor cMIOIIDI ltlCII

lll EMIIJIIIIl l belldlmiddotIAiiq prcclpllltiooftOCltIIlaiiOalc4(tDCnlllioD and oa14atlonlflt40Cilon (-) ttquiR- 1llil wu tloDamp 10 delCrtniDC -1 and ooo41tiODI lor optimum rem o -_colloidal ao4 - - 1bC co11101lnatetl poutcr Hy4_ aetl 101idamp prodpilltiOtiWU -tlpte4 lo tbC PPM llludiiL ()aldatlottftetloctiDI rtqUitemCIII I

pK raaF for optimum metab reatQyenal wM abO bullgttilbOLIt~ IIUlytt preucat-14 be 10 _and rod 110bull conccnttatlons _ Ibull po ao Nyan belorlt othet lampdtoO _be _ Wit preucattneDI inorpnicllllll plbulll ca- _ IQlinl In alfoltripplol __ rod UV cftlclcncicS or ao nely lmpoct bioloPltl --bullbull perlortnl_ will abO tnellb loetli on polbullhlnamp proocUOI (I~ loa ()( rcverM 01100111) A _- o pacoot rlt-la i quoJilll _tiODI o( --lalioo (OrtMiloD led 10 IIIC -tillcatiOO o -F nnp (Or by4- polJIIIC (prodpllltiOO) ltyd-bull pcOildlt (-l icll_ ulllntbCCIeCI -o(lnoltPDicl D-pranpwerlt-olttbe p__ ill _ ll tina Table l middot l - tile tAl roo prod tbe boll r ulll

l ll Olll)llJIIlDurinamp ll lour etlditlonoltcchnololi boftdtmiddotICI oliOOIDI prcucattnCDI o arooICr 10 rc4uca- ampnorpnicl ThiiO lour_ were ioD altOinFo dlft bubble _oo ca____ ___L _ bull-bullbull- olt blllllll

-(LL bull 11rippln1 prior to actlvatc4 ca- Of ICiiVIte4 ca- ollor ___) _etiOI-1--Iol- loO_DF_ te41orinorpa1Crc-looly ea- _aott aoddiffuetl __ _ rororpolc -L BioloampICO__ tawd for botb i801pntt aD4 orpaic rcmovab lie PhiiC ll ideatlllcd tltc need to aetl lmplctneat ucattnCOI mcthOdl lor rc-1 o orpnicl For wmplc combibull bullbullabull 11rippin1 with acttvatc4 carbObull ucatmcat may be n_ary bullroomo cootantloaall arc dgtft~Cullto 11rip but -Uy 10 carbOn Altcrnatly c4 carbOn tniY be a pol~biDI 11cp ~ bioloalel ucatmcat bull cmplo)_ Tablel l-lto l -1 dcocribe Utbullt _ TIMamp 5-1 ilkoliftll tM water ctalily o( ttlamp r- Wllel priot ampa precipiudcm prcucaunenL

U 1Uf OBIECttvES _ o l ao4 ll beodt - 10 middot-- o - -o( ao4 -ubullilllbullbullbullbull pou-tallmpliiOOlshy11 1M tltyaua to beloW MOI TM bulltillamp- abO- 10 _1-middot-_---middot- piClypC o cacUaac - teiCOI ua- TbullriDI- oooductc4 to _ I rltllablt o IM tceJIOlOIYS abnity to _ contambullbullbull Ia the poutcr 11 the tlyaOJO 1111 TM olall col- - 001 iatcndc4 lor cftlclcY

I I I I

r~n hll

middot ll ~~l =~~Irrl l ~lil

f fl I

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 18: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

--

----

-I )

lllllo_Z ~ ot Orww Re8ldiadol T_

llyua QcUal Silo

FeocfAtSipl

llldaltioul ColiUOII

~loll Molltortq

Slllflcr Water Cotluol

ClppUit

tfJaiiUc Ianier

Groundwater lnjeaion

Reltrkt ~wt~ fuKll poll watIUill tlpl

11 lud or otMt NllricdoU to proltibh tbc use ol JfOIIIIChILtriiiMIMtilt

EYihaale mlpaliol ud dillriiMaUoll of eo~~~amp~~luaamps Oyener tiiDC ~a~ina 11orina 10 aapll lM CMIHnlal alliS bedroct aquller

ConUOI slllflct waw ru4 owr Ike 1114 lbuefore lallltrat6oa to poundwttar

Pmat iaftltraliiMI ot _doll iiiO coatlaiuted ZOIIII wiU a RCilA 111dtimiddotlayet cap or OlMr cappWc bullterilil

OMrt ltMItMUda pouctwaamper ftow aroud contlmintted zona willa limy Wlwat piliq

ampLiblillrl 1 bedroct ~ _ulictlly bullptradient of the site 10 tower JfOUMwalel dMidoll il coaaaaiuS

Pmut JfOUDdwalef _ tlarotaP COIItlflliMtcd IODa by poutiq Mdrock traura

laect wttrr Into the Jf0111Mh1W to bydnulkllly prevtnt the funhct miJfltioo ot COGtamiauq

ltiuod abulllriull ld 01J111 iiiiO liM JfOUMIWIIer aiGJ I uix of atiKI~ wdll lid redmd1Ui01 amnktues 10 stimulate

~middot- __ _ _ _ICampMIM _or~bull lltIHolopcal NeQOr

(ampJ I trictllq IUICf tOCatilt ~ CIOIIIKtOII)

I)

IIitr 1~

bullbull

) I ~

t~r~

Acrltioft

_ Otf-tlbull wT

FtciiiY

PolarU4 Mlt4iiJ()WolvOd QDdall 1M

()llidbe orpakl ill atJICUIIII pouadMIU willa I llal1tiOCO

applklt of ll~ upt aad a rona oQdilcr

Otatroy orpaic co~wafuall La aa aq~~M~Gtll IOiudOD by iDdMiaJ ollidadoll aiMI laydtolylil reeaiOM at lllP waperauuc aDd prt~Suramp Olyp at ekWUid _ cabaDC tbamp oddat~D of orpak

coapoddlto carbOa diolidamp bullbullmiddot

AI1111C tM lfOIadWatlt 10 ~ iaoJpClk itOft and mlfiMM andmiddot-middot- middot-eo-t dillotvd 10 aa tolubae font (lc metal sulftde W ~or boa aauta) padld tOiiclltiUOUIJI

ftoealladoa settle out IOl6dl ~ plilJmiddot

Dildlotl atroaed --to-- ()wOOdTNat_t WOJIII (POTWl for ubulltbullat Water mISt rr preutbullat llllldl141 bdofC diiCIW 10 tillamp fadlicy

adDente ubullbullbullbullbull _ (sl cartiOII) at aa ol-liw

Killty 1rllff coaUUMII CK (OIICIampIItrtlld wu~ to offmiddotslte (tctlity rot flnhcr ubulltmcnt

Olddizt orpnicS and c~rot)kll~ ftltcr ioM dint ionized OIYfll u4 aiuotta and llltflliokl IJbL

___ - --Ia aM it8ptn-~ Ofkl taps pUtt

coa-w toa bullrx pedwlta bJ liOUiaJ oft WI OOII(IIIItnlioM or VOC SVOO ill a cohama partedwilllt~enbulltlriiL w -doflfaucotbull bull-ait lxltl tllll _ bull plaquo dle - anMfw of VOOJSVOCI frola u oq_ _ shy

I )

~

~t-tiaed)

naiiiampUlliWIIIIilcu-_

loa-middot _ Me4il fltratioa

flltntioa

OfOIwhmpiaamp

Or~ialrucrotptor

llillllll Loodlll

NPOES OllcUrl

Rod---o1- 0lt _ orpako tJuobullP tdiOrpdoa oato paa ~Mwd cartMML Mey be ased u a poUsblaamp ~~ aMr uea~l tla 111 UVOIOUttoll or tir atrippinampW reiDOyenC

~allfdClld CQIIdta

Separate CODCCIUIwd Cl)lllaiUaU rro- mtiClld water ISinabull semimiddot

--- RcmcM bull sol fJOM tlrl WMteWllet iltum by fordbullamp

water nwP a aM tu~a or cartridbullmiddotYfC filter

ttclftOYamp sol aacl bullWI frOil wuaew~tcr auum 111in1 1 mcrnbraM _ fltract pvftdWttcf frOCft Cl Of lfiOfS cstrectiotl - tO CORtrol Of rcWM tM UlkrW CCMI _ Qf0111141w1 wouMI be uealld oa-Mat UUifONd 10 bullbull olaquo-tiw ~licy or diKNrJICllnto ~n lor

-J()IW Colkld JfOIIdwiiCt Ia ~pawl Drtin to allow treampUMIIt to

take pLaee

saare ue~-t rtiM~tamp ( _ thadae ipCil caWft) Ia aa oCImiddot

JtCilA rdliJmiddot OllcUtl P hlw tiM atona draiM ttWU MtfliiOfk or latO 1M ltMf hi tttal OIICraquorp OCitiOI wid M ___ -~u flooltftlotwiUIIoo

to ~toe tM rtetM

lei~ Utamptarou Net Wlwt the JfOIII sinamp OM or ~wtlll

II

)

lfu Use cutrtrpl torce 10 _ tM MdlJMllltioa rate of thtdJI

Dtwaters illldp by dfliUII giDlP lM ahadJC Nil aDd tv~poratioa frolltMwrc IOaitmiddot

()ewaterstl~IC by ~~Mill a coatLa- tuw belt tNt nbull over a drive aDd auide roUir 11uca llld Ukamp I (II)IIW70I MIL Shtdp is cootifliIOampSly diWiwed btCWMI lM IUW bella

otMten lllldfl _ ~ whll ~ Wlef 0 _ - _ - -Uto4-~ dcWitcritll IMlbOdl belli

Reduce tM IOiubull of 11-bull -cwal o( supetnltllll liquMt

Ocwatcn st~ae usiaa bull roampary cbullbullbull nuer

16

)

l l nCHNOLOOlES EVALUAreD l ao4llbelldl IAiiq wu 10 dcmOnsttalCthc cffcttln ol 1 tcthnoloJY In rc4ocinamp

poo-m coataonloanl that Clbt ao Nya to tbe MCUmiddot lie ronowlnamp oclttions daCribC bullbullbull UOIUDIGl ~eotalti~Md aDd lbC raOOoale lor cMIOIIDI ltlCII

lll EMIIJIIIIl l belldlmiddotIAiiq prcclpllltiooftOCltIIlaiiOalc4(tDCnlllioD and oa14atlonlflt40Cilon (-) ttquiR- 1llil wu tloDamp 10 delCrtniDC -1 and ooo41tiODI lor optimum rem o -_colloidal ao4 - - 1bC co11101lnatetl poutcr Hy4_ aetl 101idamp prodpilltiOtiWU -tlpte4 lo tbC PPM llludiiL ()aldatlottftetloctiDI rtqUitemCIII I

pK raaF for optimum metab reatQyenal wM abO bullgttilbOLIt~ IIUlytt preucat-14 be 10 _and rod 110bull conccnttatlons _ Ibull po ao Nyan belorlt othet lampdtoO _be _ Wit preucattneDI inorpnicllllll plbulll ca- _ IQlinl In alfoltripplol __ rod UV cftlclcncicS or ao nely lmpoct bioloPltl --bullbull perlortnl_ will abO tnellb loetli on polbullhlnamp proocUOI (I~ loa ()( rcverM 01100111) A _- o pacoot rlt-la i quoJilll _tiODI o( --lalioo (OrtMiloD led 10 IIIC -tillcatiOO o -F nnp (Or by4- polJIIIC (prodpllltiOO) ltyd-bull pcOildlt (-l icll_ ulllntbCCIeCI -o(lnoltPDicl D-pranpwerlt-olttbe p__ ill _ ll tina Table l middot l - tile tAl roo prod tbe boll r ulll

l ll Olll)llJIIlDurinamp ll lour etlditlonoltcchnololi boftdtmiddotICI oliOOIDI prcucattnCDI o arooICr 10 rc4uca- ampnorpnicl ThiiO lour_ were ioD altOinFo dlft bubble _oo ca____ ___L _ bull-bullbull- olt blllllll

-(LL bull 11rippln1 prior to actlvatc4 ca- Of ICiiVIte4 ca- ollor ___) _etiOI-1--Iol- loO_DF_ te41orinorpa1Crc-looly ea- _aott aoddiffuetl __ _ rororpolc -L BioloampICO__ tawd for botb i801pntt aD4 orpaic rcmovab lie PhiiC ll ideatlllcd tltc need to aetl lmplctneat ucattnCOI mcthOdl lor rc-1 o orpnicl For wmplc combibull bullbullabull 11rippin1 with acttvatc4 carbObull ucatmcat may be n_ary bullroomo cootantloaall arc dgtft~Cullto 11rip but -Uy 10 carbOn Altcrnatly c4 carbOn tniY be a pol~biDI 11cp ~ bioloalel ucatmcat bull cmplo)_ Tablel l-lto l -1 dcocribe Utbullt _ TIMamp 5-1 ilkoliftll tM water ctalily o( ttlamp r- Wllel priot ampa precipiudcm prcucaunenL

U 1Uf OBIECttvES _ o l ao4 ll beodt - 10 middot-- o - -o( ao4 -ubullilllbullbullbullbull pou-tallmpliiOOlshy11 1M tltyaua to beloW MOI TM bulltillamp- abO- 10 _1-middot-_---middot- piClypC o cacUaac - teiCOI ua- TbullriDI- oooductc4 to _ I rltllablt o IM tceJIOlOIYS abnity to _ contambullbullbull Ia the poutcr 11 the tlyaOJO 1111 TM olall col- - 001 iatcndc4 lor cftlclcY

I I I I

r~n hll

middot ll ~~l =~~Irrl l ~lil

f fl I

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 19: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

bullbull

) I ~

t~r~

Acrltioft

_ Otf-tlbull wT

FtciiiY

PolarU4 Mlt4iiJ()WolvOd QDdall 1M

()llidbe orpakl ill atJICUIIII pouadMIU willa I llal1tiOCO

applklt of ll~ upt aad a rona oQdilcr

Otatroy orpaic co~wafuall La aa aq~~M~Gtll IOiudOD by iDdMiaJ ollidadoll aiMI laydtolylil reeaiOM at lllP waperauuc aDd prt~Suramp Olyp at ekWUid _ cabaDC tbamp oddat~D of orpak

coapoddlto carbOa diolidamp bullbullmiddot

AI1111C tM lfOIadWatlt 10 ~ iaoJpClk itOft and mlfiMM andmiddot-middot- middot-eo-t dillotvd 10 aa tolubae font (lc metal sulftde W ~or boa aauta) padld tOiiclltiUOUIJI

ftoealladoa settle out IOl6dl ~ plilJmiddot

Dildlotl atroaed --to-- ()wOOdTNat_t WOJIII (POTWl for ubulltbullat Water mISt rr preutbullat llllldl141 bdofC diiCIW 10 tillamp fadlicy

adDente ubullbullbullbullbull _ (sl cartiOII) at aa ol-liw

Killty 1rllff coaUUMII CK (OIICIampIItrtlld wu~ to offmiddotslte (tctlity rot flnhcr ubulltmcnt

Olddizt orpnicS and c~rot)kll~ ftltcr ioM dint ionized OIYfll u4 aiuotta and llltflliokl IJbL

___ - --Ia aM it8ptn-~ Ofkl taps pUtt

coa-w toa bullrx pedwlta bJ liOUiaJ oft WI OOII(IIIItnlioM or VOC SVOO ill a cohama partedwilllt~enbulltlriiL w -doflfaucotbull bull-ait lxltl tllll _ bull plaquo dle - anMfw of VOOJSVOCI frola u oq_ _ shy

I )

~

~t-tiaed)

naiiiampUlliWIIIIilcu-_

loa-middot _ Me4il fltratioa

flltntioa

OfOIwhmpiaamp

Or~ialrucrotptor

llillllll Loodlll

NPOES OllcUrl

Rod---o1- 0lt _ orpako tJuobullP tdiOrpdoa oato paa ~Mwd cartMML Mey be ased u a poUsblaamp ~~ aMr uea~l tla 111 UVOIOUttoll or tir atrippinampW reiDOyenC

~allfdClld CQIIdta

Separate CODCCIUIwd Cl)lllaiUaU rro- mtiClld water ISinabull semimiddot

--- RcmcM bull sol fJOM tlrl WMteWllet iltum by fordbullamp

water nwP a aM tu~a or cartridbullmiddotYfC filter

ttclftOYamp sol aacl bullWI frOil wuaew~tcr auum 111in1 1 mcrnbraM _ fltract pvftdWttcf frOCft Cl Of lfiOfS cstrectiotl - tO CORtrol Of rcWM tM UlkrW CCMI _ Qf0111141w1 wouMI be uealld oa-Mat UUifONd 10 bullbull olaquo-tiw ~licy or diKNrJICllnto ~n lor

-J()IW Colkld JfOIIdwiiCt Ia ~pawl Drtin to allow treampUMIIt to

take pLaee

saare ue~-t rtiM~tamp ( _ thadae ipCil caWft) Ia aa oCImiddot

JtCilA rdliJmiddot OllcUtl P hlw tiM atona draiM ttWU MtfliiOfk or latO 1M ltMf hi tttal OIICraquorp OCitiOI wid M ___ -~u flooltftlotwiUIIoo

to ~toe tM rtetM

lei~ Utamptarou Net Wlwt the JfOIII sinamp OM or ~wtlll

II

)

lfu Use cutrtrpl torce 10 _ tM MdlJMllltioa rate of thtdJI

Dtwaters illldp by dfliUII giDlP lM ahadJC Nil aDd tv~poratioa frolltMwrc IOaitmiddot

()ewaterstl~IC by ~~Mill a coatLa- tuw belt tNt nbull over a drive aDd auide roUir 11uca llld Ukamp I (II)IIW70I MIL Shtdp is cootifliIOampSly diWiwed btCWMI lM IUW bella

otMten lllldfl _ ~ whll ~ Wlef 0 _ - _ - -Uto4-~ dcWitcritll IMlbOdl belli

Reduce tM IOiubull of 11-bull -cwal o( supetnltllll liquMt

Ocwatcn st~ae usiaa bull roampary cbullbullbull nuer

16

)

l l nCHNOLOOlES EVALUAreD l ao4llbelldl IAiiq wu 10 dcmOnsttalCthc cffcttln ol 1 tcthnoloJY In rc4ocinamp

poo-m coataonloanl that Clbt ao Nya to tbe MCUmiddot lie ronowlnamp oclttions daCribC bullbullbull UOIUDIGl ~eotalti~Md aDd lbC raOOoale lor cMIOIIDI ltlCII

lll EMIIJIIIIl l belldlmiddotIAiiq prcclpllltiooftOCltIIlaiiOalc4(tDCnlllioD and oa14atlonlflt40Cilon (-) ttquiR- 1llil wu tloDamp 10 delCrtniDC -1 and ooo41tiODI lor optimum rem o -_colloidal ao4 - - 1bC co11101lnatetl poutcr Hy4_ aetl 101idamp prodpilltiOtiWU -tlpte4 lo tbC PPM llludiiL ()aldatlottftetloctiDI rtqUitemCIII I

pK raaF for optimum metab reatQyenal wM abO bullgttilbOLIt~ IIUlytt preucat-14 be 10 _and rod 110bull conccnttatlons _ Ibull po ao Nyan belorlt othet lampdtoO _be _ Wit preucattneDI inorpnicllllll plbulll ca- _ IQlinl In alfoltripplol __ rod UV cftlclcncicS or ao nely lmpoct bioloPltl --bullbull perlortnl_ will abO tnellb loetli on polbullhlnamp proocUOI (I~ loa ()( rcverM 01100111) A _- o pacoot rlt-la i quoJilll _tiODI o( --lalioo (OrtMiloD led 10 IIIC -tillcatiOO o -F nnp (Or by4- polJIIIC (prodpllltiOO) ltyd-bull pcOildlt (-l icll_ ulllntbCCIeCI -o(lnoltPDicl D-pranpwerlt-olttbe p__ ill _ ll tina Table l middot l - tile tAl roo prod tbe boll r ulll

l ll Olll)llJIIlDurinamp ll lour etlditlonoltcchnololi boftdtmiddotICI oliOOIDI prcucattnCDI o arooICr 10 rc4uca- ampnorpnicl ThiiO lour_ were ioD altOinFo dlft bubble _oo ca____ ___L _ bull-bullbull- olt blllllll

-(LL bull 11rippln1 prior to actlvatc4 ca- Of ICiiVIte4 ca- ollor ___) _etiOI-1--Iol- loO_DF_ te41orinorpa1Crc-looly ea- _aott aoddiffuetl __ _ rororpolc -L BioloampICO__ tawd for botb i801pntt aD4 orpaic rcmovab lie PhiiC ll ideatlllcd tltc need to aetl lmplctneat ucattnCOI mcthOdl lor rc-1 o orpnicl For wmplc combibull bullbullabull 11rippin1 with acttvatc4 carbObull ucatmcat may be n_ary bullroomo cootantloaall arc dgtft~Cullto 11rip but -Uy 10 carbOn Altcrnatly c4 carbOn tniY be a pol~biDI 11cp ~ bioloalel ucatmcat bull cmplo)_ Tablel l-lto l -1 dcocribe Utbullt _ TIMamp 5-1 ilkoliftll tM water ctalily o( ttlamp r- Wllel priot ampa precipiudcm prcucaunenL

U 1Uf OBIECttvES _ o l ao4 ll beodt - 10 middot-- o - -o( ao4 -ubullilllbullbullbullbull pou-tallmpliiOOlshy11 1M tltyaua to beloW MOI TM bulltillamp- abO- 10 _1-middot-_---middot- piClypC o cacUaac - teiCOI ua- TbullriDI- oooductc4 to _ I rltllablt o IM tceJIOlOIYS abnity to _ contambullbullbull Ia the poutcr 11 the tlyaOJO 1111 TM olall col- - 001 iatcndc4 lor cftlclcY

I I I I

r~n hll

middot ll ~~l =~~Irrl l ~lil

f fl I

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 20: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

I )

~

~t-tiaed)

naiiiampUlliWIIIIilcu-_

loa-middot _ Me4il fltratioa

flltntioa

OfOIwhmpiaamp

Or~ialrucrotptor

llillllll Loodlll

NPOES OllcUrl

Rod---o1- 0lt _ orpako tJuobullP tdiOrpdoa oato paa ~Mwd cartMML Mey be ased u a poUsblaamp ~~ aMr uea~l tla 111 UVOIOUttoll or tir atrippinampW reiDOyenC

~allfdClld CQIIdta

Separate CODCCIUIwd Cl)lllaiUaU rro- mtiClld water ISinabull semimiddot

--- RcmcM bull sol fJOM tlrl WMteWllet iltum by fordbullamp

water nwP a aM tu~a or cartridbullmiddotYfC filter

ttclftOYamp sol aacl bullWI frOil wuaew~tcr auum 111in1 1 mcrnbraM _ fltract pvftdWttcf frOCft Cl Of lfiOfS cstrectiotl - tO CORtrol Of rcWM tM UlkrW CCMI _ Qf0111141w1 wouMI be uealld oa-Mat UUifONd 10 bullbull olaquo-tiw ~licy or diKNrJICllnto ~n lor

-J()IW Colkld JfOIIdwiiCt Ia ~pawl Drtin to allow treampUMIIt to

take pLaee

saare ue~-t rtiM~tamp ( _ thadae ipCil caWft) Ia aa oCImiddot

JtCilA rdliJmiddot OllcUtl P hlw tiM atona draiM ttWU MtfliiOfk or latO 1M ltMf hi tttal OIICraquorp OCitiOI wid M ___ -~u flooltftlotwiUIIoo

to ~toe tM rtetM

lei~ Utamptarou Net Wlwt the JfOIII sinamp OM or ~wtlll

II

)

lfu Use cutrtrpl torce 10 _ tM MdlJMllltioa rate of thtdJI

Dtwaters illldp by dfliUII giDlP lM ahadJC Nil aDd tv~poratioa frolltMwrc IOaitmiddot

()ewaterstl~IC by ~~Mill a coatLa- tuw belt tNt nbull over a drive aDd auide roUir 11uca llld Ukamp I (II)IIW70I MIL Shtdp is cootifliIOampSly diWiwed btCWMI lM IUW bella

otMten lllldfl _ ~ whll ~ Wlef 0 _ - _ - -Uto4-~ dcWitcritll IMlbOdl belli

Reduce tM IOiubull of 11-bull -cwal o( supetnltllll liquMt

Ocwatcn st~ae usiaa bull roampary cbullbullbull nuer

16

)

l l nCHNOLOOlES EVALUAreD l ao4llbelldl IAiiq wu 10 dcmOnsttalCthc cffcttln ol 1 tcthnoloJY In rc4ocinamp

poo-m coataonloanl that Clbt ao Nya to tbe MCUmiddot lie ronowlnamp oclttions daCribC bullbullbull UOIUDIGl ~eotalti~Md aDd lbC raOOoale lor cMIOIIDI ltlCII

lll EMIIJIIIIl l belldlmiddotIAiiq prcclpllltiooftOCltIIlaiiOalc4(tDCnlllioD and oa14atlonlflt40Cilon (-) ttquiR- 1llil wu tloDamp 10 delCrtniDC -1 and ooo41tiODI lor optimum rem o -_colloidal ao4 - - 1bC co11101lnatetl poutcr Hy4_ aetl 101idamp prodpilltiOtiWU -tlpte4 lo tbC PPM llludiiL ()aldatlottftetloctiDI rtqUitemCIII I

pK raaF for optimum metab reatQyenal wM abO bullgttilbOLIt~ IIUlytt preucat-14 be 10 _and rod 110bull conccnttatlons _ Ibull po ao Nyan belorlt othet lampdtoO _be _ Wit preucattneDI inorpnicllllll plbulll ca- _ IQlinl In alfoltripplol __ rod UV cftlclcncicS or ao nely lmpoct bioloPltl --bullbull perlortnl_ will abO tnellb loetli on polbullhlnamp proocUOI (I~ loa ()( rcverM 01100111) A _- o pacoot rlt-la i quoJilll _tiODI o( --lalioo (OrtMiloD led 10 IIIC -tillcatiOO o -F nnp (Or by4- polJIIIC (prodpllltiOO) ltyd-bull pcOildlt (-l icll_ ulllntbCCIeCI -o(lnoltPDicl D-pranpwerlt-olttbe p__ ill _ ll tina Table l middot l - tile tAl roo prod tbe boll r ulll

l ll Olll)llJIIlDurinamp ll lour etlditlonoltcchnololi boftdtmiddotICI oliOOIDI prcucattnCDI o arooICr 10 rc4uca- ampnorpnicl ThiiO lour_ were ioD altOinFo dlft bubble _oo ca____ ___L _ bull-bullbull- olt blllllll

-(LL bull 11rippln1 prior to actlvatc4 ca- Of ICiiVIte4 ca- ollor ___) _etiOI-1--Iol- loO_DF_ te41orinorpa1Crc-looly ea- _aott aoddiffuetl __ _ rororpolc -L BioloampICO__ tawd for botb i801pntt aD4 orpaic rcmovab lie PhiiC ll ideatlllcd tltc need to aetl lmplctneat ucattnCOI mcthOdl lor rc-1 o orpnicl For wmplc combibull bullbullabull 11rippin1 with acttvatc4 carbObull ucatmcat may be n_ary bullroomo cootantloaall arc dgtft~Cullto 11rip but -Uy 10 carbOn Altcrnatly c4 carbOn tniY be a pol~biDI 11cp ~ bioloalel ucatmcat bull cmplo)_ Tablel l-lto l -1 dcocribe Utbullt _ TIMamp 5-1 ilkoliftll tM water ctalily o( ttlamp r- Wllel priot ampa precipiudcm prcucaunenL

U 1Uf OBIECttvES _ o l ao4 ll beodt - 10 middot-- o - -o( ao4 -ubullilllbullbullbullbull pou-tallmpliiOOlshy11 1M tltyaua to beloW MOI TM bulltillamp- abO- 10 _1-middot-_---middot- piClypC o cacUaac - teiCOI ua- TbullriDI- oooductc4 to _ I rltllablt o IM tceJIOlOIYS abnity to _ contambullbullbull Ia the poutcr 11 the tlyaOJO 1111 TM olall col- - 001 iatcndc4 lor cftlclcY

I I I I

r~n hll

middot ll ~~l =~~Irrl l ~lil

f fl I

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 21: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

)

lfu Use cutrtrpl torce 10 _ tM MdlJMllltioa rate of thtdJI

Dtwaters illldp by dfliUII giDlP lM ahadJC Nil aDd tv~poratioa frolltMwrc IOaitmiddot

()ewaterstl~IC by ~~Mill a coatLa- tuw belt tNt nbull over a drive aDd auide roUir 11uca llld Ukamp I (II)IIW70I MIL Shtdp is cootifliIOampSly diWiwed btCWMI lM IUW bella

otMten lllldfl _ ~ whll ~ Wlef 0 _ - _ - -Uto4-~ dcWitcritll IMlbOdl belli

Reduce tM IOiubull of 11-bull -cwal o( supetnltllll liquMt

Ocwatcn st~ae usiaa bull roampary cbullbullbull nuer

16

)

l l nCHNOLOOlES EVALUAreD l ao4llbelldl IAiiq wu 10 dcmOnsttalCthc cffcttln ol 1 tcthnoloJY In rc4ocinamp

poo-m coataonloanl that Clbt ao Nya to tbe MCUmiddot lie ronowlnamp oclttions daCribC bullbullbull UOIUDIGl ~eotalti~Md aDd lbC raOOoale lor cMIOIIDI ltlCII

lll EMIIJIIIIl l belldlmiddotIAiiq prcclpllltiooftOCltIIlaiiOalc4(tDCnlllioD and oa14atlonlflt40Cilon (-) ttquiR- 1llil wu tloDamp 10 delCrtniDC -1 and ooo41tiODI lor optimum rem o -_colloidal ao4 - - 1bC co11101lnatetl poutcr Hy4_ aetl 101idamp prodpilltiOtiWU -tlpte4 lo tbC PPM llludiiL ()aldatlottftetloctiDI rtqUitemCIII I

pK raaF for optimum metab reatQyenal wM abO bullgttilbOLIt~ IIUlytt preucat-14 be 10 _and rod 110bull conccnttatlons _ Ibull po ao Nyan belorlt othet lampdtoO _be _ Wit preucattneDI inorpnicllllll plbulll ca- _ IQlinl In alfoltripplol __ rod UV cftlclcncicS or ao nely lmpoct bioloPltl --bullbull perlortnl_ will abO tnellb loetli on polbullhlnamp proocUOI (I~ loa ()( rcverM 01100111) A _- o pacoot rlt-la i quoJilll _tiODI o( --lalioo (OrtMiloD led 10 IIIC -tillcatiOO o -F nnp (Or by4- polJIIIC (prodpllltiOO) ltyd-bull pcOildlt (-l icll_ ulllntbCCIeCI -o(lnoltPDicl D-pranpwerlt-olttbe p__ ill _ ll tina Table l middot l - tile tAl roo prod tbe boll r ulll

l ll Olll)llJIIlDurinamp ll lour etlditlonoltcchnololi boftdtmiddotICI oliOOIDI prcucattnCDI o arooICr 10 rc4uca- ampnorpnicl ThiiO lour_ were ioD altOinFo dlft bubble _oo ca____ ___L _ bull-bullbull- olt blllllll

-(LL bull 11rippln1 prior to actlvatc4 ca- Of ICiiVIte4 ca- ollor ___) _etiOI-1--Iol- loO_DF_ te41orinorpa1Crc-looly ea- _aott aoddiffuetl __ _ rororpolc -L BioloampICO__ tawd for botb i801pntt aD4 orpaic rcmovab lie PhiiC ll ideatlllcd tltc need to aetl lmplctneat ucattnCOI mcthOdl lor rc-1 o orpnicl For wmplc combibull bullbullabull 11rippin1 with acttvatc4 carbObull ucatmcat may be n_ary bullroomo cootantloaall arc dgtft~Cullto 11rip but -Uy 10 carbOn Altcrnatly c4 carbOn tniY be a pol~biDI 11cp ~ bioloalel ucatmcat bull cmplo)_ Tablel l-lto l -1 dcocribe Utbullt _ TIMamp 5-1 ilkoliftll tM water ctalily o( ttlamp r- Wllel priot ampa precipiudcm prcucaunenL

U 1Uf OBIECttvES _ o l ao4 ll beodt - 10 middot-- o - -o( ao4 -ubullilllbullbullbullbull pou-tallmpliiOOlshy11 1M tltyaua to beloW MOI TM bulltillamp- abO- 10 _1-middot-_---middot- piClypC o cacUaac - teiCOI ua- TbullriDI- oooductc4 to _ I rltllablt o IM tceJIOlOIYS abnity to _ contambullbullbull Ia the poutcr 11 the tlyaOJO 1111 TM olall col- - 001 iatcndc4 lor cftlclcY

I I I I

r~n hll

middot ll ~~l =~~Irrl l ~lil

f fl I

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 22: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

)

l l nCHNOLOOlES EVALUAreD l ao4llbelldl IAiiq wu 10 dcmOnsttalCthc cffcttln ol 1 tcthnoloJY In rc4ocinamp

poo-m coataonloanl that Clbt ao Nya to tbe MCUmiddot lie ronowlnamp oclttions daCribC bullbullbull UOIUDIGl ~eotalti~Md aDd lbC raOOoale lor cMIOIIDI ltlCII

lll EMIIJIIIIl l belldlmiddotIAiiq prcclpllltiooftOCltIIlaiiOalc4(tDCnlllioD and oa14atlonlflt40Cilon (-) ttquiR- 1llil wu tloDamp 10 delCrtniDC -1 and ooo41tiODI lor optimum rem o -_colloidal ao4 - - 1bC co11101lnatetl poutcr Hy4_ aetl 101idamp prodpilltiOtiWU -tlpte4 lo tbC PPM llludiiL ()aldatlottftetloctiDI rtqUitemCIII I

pK raaF for optimum metab reatQyenal wM abO bullgttilbOLIt~ IIUlytt preucat-14 be 10 _and rod 110bull conccnttatlons _ Ibull po ao Nyan belorlt othet lampdtoO _be _ Wit preucattneDI inorpnicllllll plbulll ca- _ IQlinl In alfoltripplol __ rod UV cftlclcncicS or ao nely lmpoct bioloPltl --bullbull perlortnl_ will abO tnellb loetli on polbullhlnamp proocUOI (I~ loa ()( rcverM 01100111) A _- o pacoot rlt-la i quoJilll _tiODI o( --lalioo (OrtMiloD led 10 IIIC -tillcatiOO o -F nnp (Or by4- polJIIIC (prodpllltiOO) ltyd-bull pcOildlt (-l icll_ ulllntbCCIeCI -o(lnoltPDicl D-pranpwerlt-olttbe p__ ill _ ll tina Table l middot l - tile tAl roo prod tbe boll r ulll

l ll Olll)llJIIlDurinamp ll lour etlditlonoltcchnololi boftdtmiddotICI oliOOIDI prcucattnCDI o arooICr 10 rc4uca- ampnorpnicl ThiiO lour_ were ioD altOinFo dlft bubble _oo ca____ ___L _ bull-bullbull- olt blllllll

-(LL bull 11rippln1 prior to actlvatc4 ca- Of ICiiVIte4 ca- ollor ___) _etiOI-1--Iol- loO_DF_ te41orinorpa1Crc-looly ea- _aott aoddiffuetl __ _ rororpolc -L BioloampICO__ tawd for botb i801pntt aD4 orpaic rcmovab lie PhiiC ll ideatlllcd tltc need to aetl lmplctneat ucattnCOI mcthOdl lor rc-1 o orpnicl For wmplc combibull bullbullabull 11rippin1 with acttvatc4 carbObull ucatmcat may be n_ary bullroomo cootantloaall arc dgtft~Cullto 11rip but -Uy 10 carbOn Altcrnatly c4 carbOn tniY be a pol~biDI 11cp ~ bioloalel ucatmcat bull cmplo)_ Tablel l-lto l -1 dcocribe Utbullt _ TIMamp 5-1 ilkoliftll tM water ctalily o( ttlamp r- Wllel priot ampa precipiudcm prcucaunenL

U 1Uf OBIECttvES _ o l ao4 ll beodt - 10 middot-- o - -o( ao4 -ubullilllbullbullbullbull pou-tallmpliiOOlshy11 1M tltyaua to beloW MOI TM bulltillamp- abO- 10 _1-middot-_---middot- piClypC o cacUaac - teiCOI ua- TbullriDI- oooductc4 to _ I rltllablt o IM tceJIOlOIYS abnity to _ contambullbullbull Ia the poutcr 11 the tlyaOJO 1111 TM olall col- - 001 iatcndc4 lor cftlclcY

I I I I

r~n hll

middot ll ~~l =~~Irrl l ~lil

f fl I

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 23: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

) cakUatiOU OC lot cialp purposa The dill wiU be ISCICliO bclp Mtlblilb tiable UCIIUMftt trains for the voundwtter at tbe Nyanza tlte tO cktcrmlne the Deed for a4ditioRII technooJ) tettlnJ and to evaluate

technoioamp ud altcrnaUW durinamp the FS procaa

S3 EXPIJliMEiffAI DESION AND PROCEDURES

5)1 BampW WeS[ $tmpLf Dill

RIW water ampamp were cotletlcd from fow OQolite lft(NliiOrilll welll aM 1M Ia the bench -$CIIc tes1l A diiJIreDt cobullpoatw sample from rwo CK wee weUI was lied for elda tbullL lbo sourca of tle composite

- --Willmiddot aawwwSgwSM MWSCud68

MW 8 SC aad 68

MW Sl SCall468

MW SISC ud 6C

TM ~ of tMIamp wclll are tltOWft Oft flaure l-3 TM a--bull tUt were chQMn to be tested Ia tM nw - arc it4icatiyenamp of tbOM tlllt IMY be pnwat at tM $111 COMiderina tbe lllistory aS utbullrt of tM _ iDdumy at tM tilt TM latl~t CIOMltatralioal of lorJIDicS al4 orpnks lilted lot ~ welll aS boW tbllamp laft~atnt concuuatbull coeptre 10 tbe maximum contamiftlnt tevtb

lahiSmiddotl

TM tot~bulll are bl1d dllerlpdoa of beDCi4CampM tllliftl KlMtill fof anc teduo~ as condlltttlll uamp tr BC JofdU cora n nw bull IIIII lN (bull ar-r ubullUMII) _ IW I -riMyoiCOU TMCIOII~ tUt lllalclaea 10 be au~J dlolrt tMt llllklpltecl to be tbe pardcbullr tedaoloD bela~ lilted Not all COftttmlnanampl aulyled for ~ technokgtfY benctamp-scale bullbullted DQO tcwl Ill wu IIHd to evbullluate PNM t tatlnl

effectiW_ aDd lcYCI tV wu uted for PhiM IL

5)1l ~ I PrcdpitatiOG PUle 1 MMit uaamp of precipitalioa bulldllodl COIMfuae4 011 rtw pouadWitU 11mpta to cktermiM tM ~ iA rtll0yeni _ (-llldial~ MCCdYmiddot NapMM chromium 1nd Mad) TM ~ ot prtcipitatioa Ia re41d orpaks Ml abO latiptcd

1- _ 011 l -tha umpMI la ~ wit ASTM 02035 Stbullndard PtKICC bopi~dcJI~toaJr_otwater TM _otliiJOIIidtuUdJI f1tdpltat_u4 tM for ttlllctif)l Of tioa llampfiWIN CftluteiL Fiola diM tiiCI toyenP dollaamp IR MN -~ b bull ia PMM 11 Mid u OM nw water ubullplt and uuted water Nmptll wert _ for ltiOtpbullks orpa KidS aiMI lDOfplic td bull atniiIOftia BOD COO ___ _

II

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 24: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

- -

l )

tAIUSmiddotl _tiPITAliOII 1UA1MILilf DATIbull tloiiL)

bull Of tlllll middot- tVQ tH COIIC middot

-lt - muur IICLilltUOIJC1

COICIITUfiCII zC(IIICIITPTIOII middotshy

tdiMICI

AUIIIIUI

ubullII_bullbull

eM_CUll _ -middot -WI -bull --~~-_ -bullmiddotshy- -middot - -shy

1101ll111t -middot

tltCIUfllll shy

[111shytmiddotltlta_bullbull -CIILGIOfshy middotmiddot- middotshy-T middotmiddot -Jtl~ middot- middot- shylltl-- middot-middot- - 114bulltltcampIIDIIIM middot-M ill shy

~

oz lN u o ~zII ~n0

~~ n

n shy ttoltiiCIIAII OJlt -tOmiddot~ ~~ 241 tiiCIIAII d- middot bull110

obull

bull -

1101 Ul18 0

middot 0 10 0 10 0

bull - shy fllllt-

0-t

~

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 25: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

- - ----

I )

) tA1115bullZI PIIAII 11 UW IMTll tlWAttlllSTICI

lll~lamplf CCIII(IIUAliOIII(ua1)(1)

eOftlllll AVO Iff COliCOlfiUIIO AIII MTICTIO IIOL IICLIO UttiOSIClAIUtiCII t(IICilltUtiOII

-middot IIOt ttlf10 -_cs 0

to middot- shy

nllll __ IS - UIUJ

ISOO

00 IIJJS -middot

-middot-_ -

- znn

) - middot-middot bull

100 -middot -- middotshy - -- - shymiddotshy_ lllnllstbull bull TIICW-~ middotoo

HOICIIl-tlllbull- -

middot--

- bull bull - - shy- ImiddotCII -1111~ ~

bullbull bullbull nu bull 1 111~ II IS- middot- 114bullftlta-middot- middot-- middot-- - middot-

IIIIIU n

1 c-11bull t a ~hbull_ tcllfllll61 J Ctllflllllte tet tIIYJIK 4 ~tle t tc1MK

lO

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 26: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

-------

I )

tAIIIbullJ MUfi~UrtCTtIIIIIIIOfPIIAIIIITWTMitttt)IIIOIOGilll14l)

AyenPMI PUCIIT IWINAL

AYIOUittiO OlffUIIO llfllalf lt~OGICAL AOICIIITIOII - MU11011

I(IICIITUTUII -

JJir=t (~middot

cs _ 1111111 lllfLUII

-middotIllCJUIIII-middotIll-middot- _ middot-shy -middot-

-middotIll_ ~~

Htt~T------Ill shymiddotmiddotshy1111-shymiddot-middotmiddot-shy--shytl4middotti iCIILshy

bullnbullbull 1 bullbullbull dill bull t

-

IIOttntbull IIOtttttbull

II til -middot IllIll 11

utm shy -middot-bull Ill til bull

middot- til

11(11bull -

IIOttlltll til til til til

n tilIll til til til a-tiiCIIAbull

tilIll n til middot-OSD til Ill

f1111 t ftl tM ectiWI tlbulllt

ll

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 27: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

i~

) TAillJmiddot4

ICII tJOWIII ttUTAIUtff DATA (14U

) t0f11

AIGifHUliT bullbulluut IUl~bullt 000 MClGCOIIC bull liCllOIIIClIIPINAL

CDICIITUfiCII C(ll(lltUTIIIIICG~HJ~~Dm

cs ALIIUIU 0

c middot- d MJgt_ - -

10

z

z

-middot

~~

MO

CALC_IIll - - ~iii 0

an M

-middot-_ - d -- - -- bull - middot--

bullII middot- shy ylnMfiiIICI L

) t n_ll bullt LYited

n

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 28: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

) TlolllSbullS

OlffUIIDMIA11CIIlllU1MiliT1DATA(II

I Of liMit

tIGlfflUlllt ICLGCOIICmiddotUctlDICllffltaIT CCIICIIITUTIIII

lllfUIT _ COICllltUfiCII -------middot ~(1)_

TttCMcMl- - HtlcacMilshy bull ---__

_ shy II --

1Jtl~ bullbull bull middot middot~

1100 11tl~ ~ - 114bull-ftl_ middot- shy bullmiddotbull middotshy--1 f1le II bullu~ Mfttlbull tftl tlllt enly h~l __

)

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 29: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

1-ISmiddott wbullMISCIIPf1011UA1tllll1fOA1A(IIIU

01111MS AVGIUUIIIt

llfUl IH~I1 aG COliCmiddot uausa middot- ~middotuubullCCIICIIu~(I)_

10100111CIILOICII1-

10 - 10

HttCIIIICII1 -- bull

0

0- bull - shy ltII -_ middotmiddot- - bullII

tabullbull- middot~middotmiddot-~~ ) llmiddottlll---- middotshyM1UI -n

~ 1 n _ 11 _ ~~- tt ew1111tbull In _t ~r~tr -

2A

z -lt

B IN ~~ z ~n

~iii ~~ -10

~~ d n~

~

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 30: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

)

TAIIlbull7 IICilOGIULTHAlAIIIIfYDAlA tloiiiiL)

middot- IOfliMll

nClffLUIIt_ lfFLIPf abullrtuur IICLGCOIIC PttlMJIICL

CGICUTUTICII CGICIITUliCII-

z -lt

~~ MJgt z

E~ JgtM -10

~~

cs M111shy

- bullnll11_ CALC liM_

-middot - -middot IICIIL - _ llltiiL__ 1bull1DIOIL_f_ shyshy-- JmiddotCil 1JIICilshy14t1Campshy11tiCamp--shyltfUIMshyshy114bullfIICIIshylollll UffiMl-

- - - bull --

- 1000 10- shy -middotshy 50 0 1000 50 41 D

m 070 I bull o _middotshy n o 01 0 -

0-100

100

middot

middot

middotshy- -middotshymiddotshybullII

bullII

100

- bull

-

u

di1 ~

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 31: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

) 5321 Phue II Precipitation

PbUC Jl preciplampadoa Is baled on data coueaod from Pbue L includina effective precipitation rcaacna dollna nn- u4 redox requlremcnu TbcM tau were puformod on rtw aroundwater to prodijU

~- for la bend telliDJlbe foUowiiiJ ~

5323 PUle 11 810otiQl TreatiiMII

amp5olopcal traUDUt utilized pretrutod water u4 coftlbted ala muimvnt of three lmiddotJIIIon multlpltmiddotbltdl ructOn ne raaon were naa ln panlld to cktermM tM man cell re~kknce time required to dear tile contatuau pracaL Blcterlal alltu~e~ were obWied rro llaMI) plaat wute aftd requlrlaquol u acdhaatioa period of twO weeki At lbc cad of tK Mit - were llba froM cadi ruaor tad analyzed for voes svoes and metall Tatlna foe tbeie panIDtten in4katcd the effect or mean cell ~ timamp oa rcampIIOIIl of the coatamlaaau preiCIIL

5314 Phase II Carboa Adsorption

CarOoa adlorptioG ae~tlq wu performed oft prflTUted water Ia a bltdri ractor Vtriolll amounu ot puu ecttvlled cartiOI (GAC) were _ 10 tJuel 1-Uter ubull- vftdampt bullampitatioa Pretra~t COMiltld of 500 m~ of lime 2 mLL of b)Clropn peroxide tad 2 bullIll ot CIJOn 2439 Contact dma ud of cutloa were baed on tyenailable dati u4 Yndor taloraltioamp A uatple we~ taUa from cadi 1111 alii aulpld for various orpaMI ucl bull1111middot F1011 aulyMI tiM oYCIIII cffec1iYCMM of

llGI of tblle COftliiDiftiRU b) GAC obWMcl

SllS Pbue II Oilfused Bubble Mrttioa

oured taltiOa taU weN pcrfoiMd 011 tlutc of pretrelled water PmraUMDI CODiilled or 45 1ftt1 olliM 1 vL of tydropn pcroxick and 17 bull _ of Clip 1439 The air-ao-water ratio wa van w

foe a Mit Altar ltatmut water -re aulpld for VOC aDd SVOC From 11MM aulysct tM _ ol diffuMd Mndot~ oa tM coatu~luaw pNIUI at tM lite were Clllhbullate4

5316 _ II loa Excbanp

loll adanp batctt tatinl wu performed 011 two santp ot prttrated water and three mpa ot ftOImiddot

ubullled water Pretreatment Cl)ftlisled or 1 IMIL of ll)dfOJCII perodfk U ml of $Odium hydroWC and 15 atiL 0( Clip 1439 Tbele ICIII iftCOfPOIle4 three dtflrertDt acbaltop rCSIM with I $CI dosiftl JIIC Dolial rttel were buecl on available dati an4 wDCSor illfonMtion Samples were analyu4 for metaiL 0111 troca tblae tellS idkatc the owraU perfomaacc ot thif tedlnoloiJ for rcmovinl uivaltnt and Muvaleat cluoiu- lroamp Mid aDd mcrauy aDd llllbliP rtilll type1 10 be used 4urina pikulna

S4 TEST EVALUATIONS AND NnllPitETAnOH

5U nwtepa gt tM Rslasfvt fStbsaW pi ttt lwlt Ieg eMI Irgtmsnt Oolll

TreaUMtbull Wlft COfft ill ~ ot IIWIIbull pcrcnt remG11 (Me Tab 5-)) aDd aM wtlh rapea to -tina or aceedillJ Muim11bull eou-t Levdl (MQ) for driWia water we TabMI 5-4 to S-f)

I I

I I

r11tr I rr~bullmiddot ( bull IJ bull bull

I

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 32: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

I I I I

) SU Jnorppk Rcmgytll

Ptwc 1 prcdpiampldoD aDd PUN 11 ioa acbaaae bullUDamp foaiMd oa tbe rcmcwa1 or inorpnic coauminaats Tablc6 Smiddot l ud li-4 delcribe tbe roenp rbullulu of tM teat ruu for eldl ~ Table 5middot1 delai lnorpDkl removal for a comblDed ~pilllioa aad biolopcal procaa to iAclklle the Impact bioioJkal

uauneftl may blve oa lM iDorplkl

lA aeaerat bolla~~ o~t iBOrpakl to Wow tM MCU JoaUap wu pnlly DOt bull elaquoettlYc OCI aqe lor iroa ud manp aapt ampMt fIIIO of 1M lbrM reaill were s~Ki~ihal Ia ttmcwiftamp iroa aDd maapMM to bek)w tbc Ma loa acUqc Wll ailo ab 10 rtdce ahunieura 10 belOW llloMQwllllllo- Seleclloooflllo-of_olloold_ldulhal-oflheM coatamiadll ICICODdlly MCLI wtlil3 cio DOl uw tbe ~ crilelil u tbe otbet priiDiry

MCU

-ro te1t n~bull taa kgtll uabull iacl1414 pnuatmampAt wtua predpiampltioL nil did DOt sipilkantly

-acyofloii-

Table S-7 IIUfbatbull twraJC raMMl dllciCDCill of ilorpakl for b~ tmeaL nil 41amp1 i5-ltd 10 iadkall bow tM 11M otecttvalflll studbull rro aootMr __ uuuneat rdllty for tbe baeteril aaltllNI could haptet eluan coaceatrattoJ swn1 iMMpakl __ lM MCL ud MYtt~l iiiOflllic CCJMe~~tnlk Klllllly iaeaMIL la 1 fWIICIIII Cldlil) 001raquo a bKIIrit pop11Litioll IIbullUbliiMd Ulbamp b~ ruaor aiMilM ICampMHIII _source il 4ilcolldaued ampWI ~ sboul4 subl_

Abo u ladklltd Ia Tabk S-7 a slpilkaat deCtC Ia ~ ~ Tlds ocnned consiltuUy ia a -t No CMW loorpllit W NpilcUt rcMOVampi durtq ~ UtiDampaL

lie _ 1 -tpiutioa lelts s~ ia Til S-1 retldMd frOil a dlalkll daNae of 05 mtl pcfOKHM 11114 750 mil lime The addition of liM accounts for the intreae Ia Cllcham wldcb b accampptabk UDCII cakiU il ot rqulaled Tbe iDCfalamp la blrium Ml lOt expectlll ud may be 1ft lntlyttcll ertor

Eadl p~dentGft~Uited elkaiyentMU in deaeaill tM of COIItaaiuaU II tMubullpM obWMd rro tM Nyull liiL Howtver a_ of raw Witlaquo wi~ tM lailtorical coatallllinut ran- rtponed ia Tlltltlmiddotl illlllcMIII WlrildoL bad dYOUia -y _ _ lftltdl lllipr Ia IM oa-tilt moniiOiiftl aa tUa IM _ b Tie t~~tlq coca-CIADOt verily tUt theM hiahcr ~ caa bel~ treated by oamp ~

RecoanJliftJ that mractiftl poundWiter OYer 1 lonl period ttl bullncnualt the lnftutnu conctntntions well bdow tM -u- tbiM rMb ay aot be sen 111 uuacnt rcillty Howeyena the facility may Initially require inorpnk trcatmeat ~ Ia acria or reclradatioa Redlculatkgtll coul4 Involve rctumiAJ tiM aow to tM -of 1M prOCI ot ~ lato llC po-w upandlcnt of the recovcry wd

AJ ~- 11 COli CICIIIUIdoM Ia IIUtiCMd pouctw~tcr dilcreMC tM cftlt eo~Ce~ltldoMlald___ _ lM MCL11 dtiMtlbltClll 1 lifc-cyde dellp l~114 aatidpatc bullbull lmprOotmeat_ ____poollllodollpUfoof

_- SU 9reakRWQflll

few orJiak ruM)yen1111 tru- -tlilodampWIN bulltilized -ipitatioll foUowed by illIMd Krllioamp prccipitatkgtlll lraquogtkIWM ~ UIIMIII- Cpitatioll ~ cutloe ldlorpdoa Predpitatioo Will

on1) to pnynt i~ttcrftrtnct frola tM iaofpaica COMltotntioM

11

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 33: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

)

Oiftllsed acradoa wu cftcctM over tbe teiiCd air-to-watampr ntio rup of 501 throuJh 1501 Trkhloroclbenc wu the oftly orpUc Wt slplficaaly acooded tic MCU A aumber or cotuamlnana were below dctectloa Umlu Ia tbe raw wtter Mott ot tbeM are doanneated lA the lilcnnarc to be hiJbly

11rippoigtIL

ne carboa adlorplioo tbullu IDdklled tblt orpllka MQI caa N obta(Hd BaNd on tbe lncllvlchaal tau Wll effectM except for tM wu bulltaa tM ~ catt1o1 dolafiL T1UI rtlllltll u cxpettecl slDce Ultllturt docviMits tbe ablllcy of tctMlld canoe to ~ orpakL SoiM COIIIpouDCII tbat do not IIIYC bull~abUsbed Maa sudl u chJorolonl u4 24ioropMDOl 4id uw rdltivtiJ poor rtiiOYIL Chlorotona _~__ - p~~eoo~ror-oopll aJoropllaOI ~ lypicolly -BJ- EC Jordu _ u- II 2~ oftu prcuuuacaamp whick may aplala aa lAwfaeoot Wt decnMtd tM Oyenlllll telnOoll of lbil coallllliiWIL

BiokJSical ~~ W11 1110 elflaM ia rtdU co~~UamplaUU 10 Wow MttL AltJaoup lM IVamprtJC trichkKOetMM lMI Wll aboYt tile MO 1M twO MIG wttl tM 1oq1r _liol t- 16 IKMtrl alltd 14 houn cUd tridakNOetKM to bdow 1M MCL 5rfenl conlltniUItl were betow de~tcdon llmhs Ia tM raw WIW aapll However UWit_ II ailabM tbat doaampMlll tMit bull beiRJ btodepMib Some do rejecamptd by EC JofGaa 10 laltiaamp protbull EC Jordaft reponed that Nctcril acdiNtioa tlbull may Uyent Mel IUillqUIamp CHI coauol n- witltOVt nuukats tO stlmtollate biopowt~ hip reMOYail llW KIUIMd nil bamp d1111 10 oval frobull tOYtillation and 101

tkrobullP dqndltioL FunMt Utlll WOttld N ltlllbullited 10 codnl tllil

OuriftJ boU1o tlrll bio~l 1t cWfwMd Mnlioa leiU tM Mal 0( 1-dlokKOp-oi 1-ahropheDOl 14shyclidlkKoplileol 11M1 4-ninopiiPOI _ nil Iii likely due to u cMmkll aiOftl betwen peroDdamp lddcd fof prabull~bull ud COfiWIIoiMU l1rMdy pNIUI iJ tbt pobullter For eampk ddorObeM rudily coMiMI widlo _ bydrotla peroxide 10 prod~Ke 1410ropbenol

8asecl 011 tiM ltlli e~Ch of tMM rroc-- COyentd be ctfectiw to remow orpaia In tbe raw wtter Simp oMalMt froa tlrll Nyull silL Allo _ oa a ooapert10a of tM ~ 4111 ill T- 1middot1 ud 1M dlta Ia Tlblc S-1 tM raw WIIU b _ II orpllkl remowl lftJ Nd li111olllr 1YJ ud

CIOIMll8- ot ooataaiua_

Ft0t11 the beach tt~tlnJ pcrforMd 10 dlampc k 1fP1U1 tUt ay ot 1M NWIII uutmcnt proceua couW be succeMflll In rcdlcinJ contamlunu to ICCtpLiblc ~b OYtr the tift~ dalp of the rcrneclittion

Ia ___ widlo EC Jot8l CoefuJ k Wll Ilk llllt tM ~ UUMat PfOI coukl be -lbullprcwM Ma Mdldoul _ Tie~ flld oiMailllll froa a IUCfJ liw wMre sialtar ill cUICfiilkl 10 1M WU Illamp It Iii lltlt tblt tM ICdiNtiotlo period fiiMd Ia thclamp letll WIS IIOt ~liM ~ 10- lilt Tie itt b6o6otiC11 CIOIIIampiMI _ lrldl ot torWC 1M orpaic anbulllaull IMa 1M raw Wlttr 11114 fof lhc oUrcr ~ Mea tM nw MW MamplIOUictM flo 411 _ klellioa II Iii aot Uowllo II t~lil dM if IIIII WpetCIOIIII _ CD4lM Myen1 _Mil dllirabll bullbullIll ia IIIII biolopcll

iliiPOplamp

bw b eac11 0( tM Iliad - a poal bullbull tro a _itoriliJ weltl oa lilt sitt lecavse rcat wclll tw - of tM uutiMilt IMftdl ltlll eKl of 1M

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 34: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

tttaUDUtl W cWfcrial rn water cobullwmlaalt kvelL ~ tM Ieveii ot ~coDitil~tampatl 11 tM bodl test samp were below tbe maximum Ieveli recorded on tbc site Oroundwater umpkll colleteed ac 1M Nyaua slle ladklle Wt coawaiaut kvcls lD tbe plume IDlY be btpcr tlwl lewis detected In the bench

tell raw WIIU UIDplel

SlllCC act111 rn wa1er dwtaeriltkl will vary fro tM Mit umplll Ute predllon or OKil tilt shouk1 M coutdercd eDUally accurate aDd wW DOt predict fuiimiddotKik dlkieDdll The bench testlnlllrely tchleved tbeLr pll HoweYU dl1 DOt s oa tM ~ ot ~ proceu oa all coatantiMnts Future teltiJamp Nollld include more oomprebelllilyent uw OtMr Wt can be lddrtiMd are stwsae whuMI OtMI oDdlnts iarpr airWitcr ratioamp ud kMlfU carboa cot1t1Cl liJML Abo If additive~ were UMd anal)MIIcl be oompkted 10 dctermlM It tMy coatriiMttaiO coatamiutc lcYdlla M dflucaL

SludF volume and proclucdon data for the ~ te1teel were DOl collected durinl the beDCb tcltl SlllCC stud Ukdy to coattla twarcknas levda ol e11amp bulltibullMI of the wtumc JCMflted woulcl bclp

tM ldecdOA of dlwattriae aDd Wiliaate clilpOIIl altenativamp

60 CONQUSIONS

TrbulltabiiiJ lllliaa of predfHtat loa loa achaap auadoa aDd cartoa adlorplion lodicated tblt thllt ~ are ful6llk tor rtmoriftlthe N)lllll coatabulllnnts frola poultdwlter tad that MYCtal pote1uial ubull~t uaia cocabialtioas ailt tbat could rediMll CIOitaaiftllioa tcwll to below MCLS n t~~dDI WM DOl hlldeat 10 drdop dclliled dlilp criteria blt tbis lcyenel of teltiq ca1 be accomplished duriq UCu_ TM EPA uaual Ouidlnce for Conductill ReiMidial ~~- ud Fulibilil) Studt uftdu CERCLA Jaaen Flul October 1911 dlleriba the oc- for dewmlbullilll tM - for teStiftl of tedlnotopel _ tilt FS ptocL IIi a if the tedlaoiog il wdl PfOU oa similar applications or If rtlatiYel) low -~ arc re~tuired tiDamp be apptopriaw durina 1he desiJn ptwc

A of uusat ~ tUt S 1M prcUaialty sataibulll were not tt~tecl 1MM tdDOkraquoi cal be tilted either durillJ 1M FS procw or duriq tM delip pMSe 1fter the ROD hill bell 161 dlcilicla may be inbcaced Dy the ftcldbiUIJ of ttrc 100 ror ueaunent tecbnotoe

tdletiol cDMWaatioM

ScYcral of the prooc~M~in T1ble 4-l art well proven baed on the eqcrtence ot the ARCS teant and dill hampmilbld b7 ~ lDcincration ucaUMbullt at aa olaquo-site wstcWtter treatment pltnt aeratkln GAC reYUM ONDOSis aDd media nitration arc tccboiolk tblt hM beelliiSed In 1 wide lcty of bullpplicaliofts OYCJ Nil) _ Sll(ftdeet daampa exists 10 evaluate tM tecbDOtoi to the lcYtl required for the FS

swnl _ _ ud ftl~ _a~ Tlampliftl duriJlamp lM fS _ be to verlfy if tM ~II appropriate lx QampMtallllunts bullM 10 tumisll beulaquo

llliallelolatiiiiiOCiateelwitlllMM~

PoCan-t _ il u iDDOIdve ~ lUI il 110t Umiddotpwa tfoweyentt 1 wDCior lndicDted a wiW to co ~e~tiq fOr 1M cotl of uct WOfiL Meebrlbull ftltratiiHI il MMkMI to 1M ooecacratioa of eo~~lllllauts and If h iiiCK ~ CMtt ill MMr ClllualioM 1U1J require ttatl 10

dewaiMifit ilyeniablamp

TniWCJ bulltill 0( eiCl of 1WO ~ cotd w_ 110 ri tht Hits of tedlnokgttil KttelllftJo be bullppropritte duri 1M fS or 11 tM aibulllbullubull prior to ftftll des of 1M tetllftOioPil if iniKMIM teeUokgtl s~ potarilllx IOIbulltbull ne NCP lndicatel

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288
Page 35: LETTER REGARDING DEVELOPMENT OF TREATMENT …daacription, and contaainant charactariaation of tha Nyan&a alta. Thb includaa a coapilation of Phaaa I qroun4vatar aa•plin9 data and

--thatUO-olol_bollllo_w _ollorstMI) poteatiampIIOC copuab or hperior treatment perfonuDCI or _tatkgtl wllh fewer or adyenerM dJettl tUa ocW ledlDoloamp or krMN COIampI fol uauar - of perfonuace

Sbad -llriqud b6olopa1 utatatut dlkieDCIIIIN woqly ilallced by the type o( waste 51Mtp YOIIUDI ~ida~ aN DOt Q) PredpiWioll )ar - bl loQowld by -UlUieiUI of ICJUdl

111-aate 4ilpolampl ot lOde IIIMI wW wIJ M a COli ot tM rebullcUatkHa amptiiUtbull of siMift vo~- wW be uefW 10 eYIIu ckwllaiq (cocetUillq) ud dilpll altuutr F1111Mr Mlliai J olio bo- W---wtU alto bo reqbulllred 0lt W ~ uttMII 110M il AlideaL

  1. barcode 579288
  2. barcodetext SDMS Doc ID 579288