Light Absorption in the Sea: Remote Sensing Retrievals Needed for Light Distribution with Depth, Affecting Heat, Water, and Carbon Budgets ByKendall L. CarderUniversity of South Florida

Semi-analytic ModelProvides Inherent Optical Properties (IOPs): a(); ag(); aw() summing to a() bbp(); bbw() or about 2% of bp()a() infers Chl_a, particulate organic carbon, and with light, primary productionag() infers dissolved organic carbon (e.g. river effluent)bbp() infers suspended particulate matterThese are needed to estimate the fractions of light with depth z converted to heat or carbon for the upper mixed layers for determination of carbon, heat and water budgets and heat andcarbon sequestration

Ocean ProductsTotal absorption consists of absorption by water (known), phytoplankton, and colored dissolved organic matter (CDOM)Separating and quantifying the last two semi-analytically provides quantities for the entire visible spectrum (Carder et al. 1999)Chl_a3 derives from phytoplankton absorption at 675 nmAbsorption by CDOM provides a means to estimate DOC (Walsh et al. 1992)

IPAR, ARP, FLInstantaneous photosynthetically available radiation (IPAR) provides the surface photon flux for calculation the light field with depth for times of MODIS overpassesTotal absorption for each visible band allows calculation of the light field with depth for use in heat and carbon budgets, and fluorescenceAbsorbed radiation by phytoplankton (ARP) provides the flux of photons absorbed/m2 for use in calculating fluorescence or photosynthesis Fluorescence efficiency is the ratio of photons fluoresced to photons absorbed by phytoplankton; since fluorescence is a competitive pathway to photosynthesis for ARP, its increase suggests a decrease in photosynthetic efficiency

ESE RelevanceBiology/Carbon Cycle: relevant toPOC, DOC, Primary Production & efficiencyTaxonomy from space: red tides, nitrogen-fixing trichodesmium, which requires >4X the iron of other phytoplankton groupsSaharan dust provides this to open ocean watersGlobal water and energy cyclesOcean heat budget: absorption and reflectance, depth of heat sequestrationOcean water and salt budgetsAffect atmospheric CO2, water vapor, heat energyHeat sequestration affects down-stream climate

Figure 1. Red tide (black) and Trichodesmium (aqua)29 September 2000 image using MODIS 470, 555, 645 nm, 500-m bands.

Figure 1. MAY SeaWiFS composite showing iron-rich Saharan dust reaching the Gulf of Mexico. Similar in June and July.

Product StatusAll products are being produced globally with reasonable agreement since November 2000 with similar SeaWiFS productsField uniformity continues to improve as MODIS calibration and atmospheric correction improvesClear-water Angstrom exponents for aerosols, derived from clear-water epsilons, are consistent with AERONET values from Holben et al. (JGR, 2001) for Hawaii, Cape Verde, & Brazil fire data

Product Status (contd)IPAR values consistent with Gregg and Carder (1990) model values for same locations and with Bahamas and MAB PAR measurements (within about 5%)Chl_a3 and FL both derive from semi-analytic model absorption coefficients:Chlorophylls are consistent with SeaWiFS except at high latitudes where SeaWiFS may under-estimate. Field accuracies of 25-30% (Carder et al.99) FL values range from 0.3% to 5%, consistent with Gordon (1979) and Carder and Steward (1985) and references cited (e.g. Kiefer 1973a, 1973b)FL derives from IPAR, ARP, and total spectral absorption coefficients, supporting their relative accuracy

Nitrate-Depletion TemperatureNDT: Temperatures above which nitrate is negligibleLarge, fast-growing cells (e.g. diatoms) found where T

Validation PlansData Sets:SeaBASS match-up values for chlorophyll and absorption coefficientsAERONET match-up values for clear-water epsilons and aerosol optical thickness for use with RADTRAN, a code within 5% of field IPAR dataField PAR data from CoBOP and HYCODE measurements off the Bahamas, WFS, N.J.

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3.59535174.55191231.1677

3.70565374.58476731.8184

3.80656774.58711431.7559

3.88401274.69506831.6415

3.94972474.72557731.5938

3.98257974.55660531.5685

4.06002574.75608631.5685

4.1374774.78894232.1677

4.23838474.84057232.1677

4.28062774.91332431.7936

4.34868574.98372931.6232

4.42613175.042431.5701

4.48010875.06352231.5455

4.5458275.10811131.5455

4.56928875.17382332.0564

4.5904175.53523531.7835

4.5904175.53054232.1553

4.61387875.51411432.1852

4.62326575.53054231.664

4.63499975.56105131.6598

4.67958975.60329431.6369

4.67958975.62441531.5701

4.69132375.65492432.1696

4.71244575.65727131.2528

4.7898975.67839231.67

4.88845875.65961831.6756

4.96590375.67839231.66

5.03161575.6877831.66

5.07620475.76757231.1151

5.02222775.80277531.2834

4.94478275.7910431.4589

4.93304775.79573432.1143

4.93304775.81920331.6581

4.94478275.83328431.5949

4.94478275.83797731.5949

4.93304775.84971131.5559

4.93304775.85440531.5559

4.93304775.8356332.1511

4.93304775.82389631.1804

4.94478275.78165332.1752

5.01049375.74879731.6675

5.14426375.76522531.6663

5.18650675.76287831.6663

5.2428375.79808131.6681

5.35313175.79338731.6681

5.47516675.78634732.1151

5.50802275.81216232.2552

5.49628875.81920332.6807

5.50802275.81450931.6803

5.63944575.76757231.6803

5.78260275.75818531.6688

5.90463775.71359531.6688

5.99381775.69951431.6705

6.09238475.67369934.37

6.21441975.64084334.252

6.28951875.62441534.252

6.39043275.63145634.252

6.44440975.65257734.298

6.52185575.63614934.348

6.599375.57982534.391

6.71898975.59625334.203

6.84102475.58217234.252

6.95132675.52819534.252

6.93959175.50472734.252

6.89500275.52819534.298

6.8292975.53523534.353

6.69786775.55166334.394

6.599375.5915634.1

6.54297675.53523534.159

6.63215675.53758234.204

6.70960275.51411434.252

6.78704775.49768634.252

6.93020475.49768634.252

6.93020475.46248434.297

6.8738875.42493434.391

6.75419275.39911934.349

6.62042275.35922334.306

6.57583275.38503834.356

6.54297675.38034434.394

6.599375.38738534.091

6.53358975.3686134.16

6.47726575.34514234.204

6.44440975.34044834.251

6.32472175.33106134.251

6.23554175.31932734.299

6.15809575.34279534.348

6.02667375.36626334.391

5.91637175.38738534.39

5.89290375.42493434.345

5.92575975.43666834.297

5.91637175.46248434.204

5.97034975.50003334.156

5.97034975.53992934.083

5.88351675.56339734.093

5.78260275.57747834.158

5.7168975.52350134.204

5.67230175.46248434.252

5.67230175.42493434.252

5.77321475.45309634.252

5.74974675.52350134.3

5.69576975.55166334.348

5.58546875.49768634.348

5.48455475.46248434.094

5.43057675.42962834.159

5.40945575.42728134.204

5.37425275.43197534.252

5.29680775.48829934.252

5.20997475.50707334.252

5.12079475.5540134.298

5.05508375.58217234.35

4.97763775.58217234.391

4.90019275.59625334.1

4.88845875.63145634.166

4.86733675.62910934.205

4.94478275.59625334.255

4.8790775.54462334.255

4.75703575.50003334.255

4.70071175.43197534.298

4.64673475.37095734.348

4.5458275.413234.391

4.52469875.51646134.205

4.45898775.53992934.257

4.39092975.55166334.257

4.36980775.52584834.257

4.34868575.52584834.299

4.29236175.50707334.35

4.2712475.51176734.392

4.2266575.52584834.094

4.23838475.55166334.158

4.2712475.53523534.203

4.34868575.57278534.252

4.33695175.57513234.252

4.24777275.58921334.252

4.19379475.63145634.298

4.19379475.7323734.349

4.16093975.74410434.392

4.12573675.79808134.091

4.07175975.78434.158

4.04829175.76757234.204

3.98257975.76522534.252

3.88401275.78434.252

3.85115675.80277534.252

3.69626575.83328434.3

3.63994175.84971134.3

3.67279776.10786334.391

3.6188276.08908934.165

3.60708676.09378234.298

3.60708676.12194434.346

3.54137476.154835.2018

3.45219476.22520535.2018

3.35362776.28387635.2018

3.30903876.27918235.2018

3.24097976.26744835.2018

3.18700276.27214235.2018

3.10955776.28152935.2018

3.02037776.28387635.2018

2.91946375.02831935.2018

2.7880475.01423835.2018

2.63314974.98842335.2018

2.41254774.96260835.2018

2.27877774.96964835.2018

2.18959774.93913935.2018

2.11215274.93209935.2018

2.06756274.88985635.2018

1.99011674.85230635.2018

1.89154974.80771735.2018

1.74604574.81710435.2018

1.59115469.96854335.2018

1.42452970.00139835.2018

1.25790469.96854335.2018

1.10301370.00843935.2018

0.99271170.03894835.2018

0.90353270.08823135.2018

0.84955470.11169935.2018

0.8378270.02721335.2018

0.82608669.98027735.2018

0.87067670.04833535.2018

0.89414470.03660135.2018

1.01383370.02721335.2018

1.07015769.97088935.2018

0.98097770.01782635.2018

0.8378270.1257835.2018

0.7932370.25720335.2018

0.70405170.4379135.2018

0.52803870.30883435.2018

0.370870.27363135.2018

0.21590970.3111835.2018

0.00704170.30179335.2018

10.00925270.26659135.2018

9.9435470.3111835.2018

9.85670870.32760835.2018

9.59386270.40505435.2018

9.36387270.46372535.2018

9.21132870.6233135.2018

9.03766270.78758835.2018

8.80767270.88146135.2018

8.67624970.98941635.2018

8.64339471.05043435.2018

8.51197171.02227235.2018

8.41105771.01523135.2018

8.43452570.95421335.2018

8.66451570.90023635.2018

8.89450570.90727735.2018

9.02592870.9565635.2018

9.22306270.97768235.2018

9.24418471.03165935.2018

9.42019671.13257335.2018

9.60559671.21705935.2018

9.84497371.2381835.2018

4.98937171.24287435.2018

5.03161571.28511735.2018

5.13252871.30858535.2018

5.18650671.65122335.2018

5.09967371.76152535.2018

5.04334972.05487935.2018

4.98937172.12997835.2018

-0.04928472.16752735.2018

0.15019772.16987435.2018

0.26049972.36700835.2018

0.47171472.43741335.2018

1.43626372.5805735.2018

1.52544372.60638535.2018

1.52544372.6697535.2018

1.52544372.74719535.2018

1.54656472.74719535.2018

1.54656472.78005135.2018

1.54656472.92320835.2018

1.55829972.96779835.2018

1.55829973.0475935.2018

1.50197473.12034235.2018

1.37055273.1813635.2018

1.33534973.20717535.2018

1.32596273.25411235.2018

1.35881873.29870235.2018

1.43626373.42543135.2018

6.44440973.51226435.2018

6.67674673.6037935.2018

6.19095173.66480835.2018

6.20268573.71643835.2018

6.05952873.76102835.2018

5.92575973.81031235.2018

5.83892673.81500535.2018

5.73801273.81031235.2018

5.61832373.79153735.2018

5.40945573.78449635.2018

5.18650673.79153735.2018

4.97763773.7821535.2018

4.74530173.73521335.2018

4.41439773.73521335.2018

4.19379473.71409135.2018

3.97084573.69531735.2018

3.68453173.62491235.2018

3.49678473.54277235.2018

3.23159273.47940835.2018

2.88660773.37145335.2018

2.79977473.29166135.2018

2.65427173.17666635.2018

2.40081273.01238835.2018

2.05582872.88565935.2018

1.86808172.78239835.2018

1.5794272.61342635.2018

1.44799772.48669735.2018

1.51370972.36231435.2018

1.5794272.19099535.2018

1.64747872.03141135.2018

1.5794271.87886635.2018

1.46911971.75213735.2018

1.40340771.68173235.2018

1.43626371.56908435.2018

1.39167371.4681735.2018

1.39167371.44235535.2018

1.40340771.39072535.2018

1.48085371.31327935.2018

1.50197471.26634235.2018

1.45738571.28511735.2018

1.65686671.25226135.2018

1.80236971.21705935.2018

1.87981571.20063135.2018

2.0910371.1865535.2018

2.18959771.10441135.2018

2.32336771.02461835.2018

2.52284871.0011535.2018

2.73171670.98472235.2018

2.91007671.03635335.2018

3.14241271.08563635.2018

3.37474971.12787935.2018

3.56249671.14900135.2018

3.81830171.1419635.2018

4.00604871.13961335.2018

4.1374771.16073535.2018

4.33695171.12787935.2018

4.60214471.07155535.2018

4.82274670.96360135.2018

4.93304770.92605135.2018

5.12079471.05043435.2018

5.41884271.16308235.2018

5.70515671.24522135.2018

5.94922771.34144135.2018

6.26839771.38603135.2018

6.43267571.41888735.2018

6.44440971.54796335.2018

9.24418471.62775535.2018

9.05878471.62775535.2018

8.76308271.66999835.2018

8.50023771.76621835.2018

8.32422471.86243835.2018

8.14821271.92345635.2018

7.81965571.97743335.2018

7.51221972.0173335.2018

7.32447272.08538835.2018

7.31508572.15109935.2018

7.25876172.22854535.2018

6.98418172.22854535.2018

6.93020472.2097735.2018

6.89500272.26844135.2018

6.68613372.37170235.2018

6.43267572.39751735.2018

6.19095172.36700835.2018

10.08669772.36231435.2018

9.9881372.42802635.2018

10.00925272.51720535.2018

9.91068572.56883635.2018

9.72528572.7143435.2018

9.5727472.87627135.2018

9.63845272.92790235.2018

9.82385272.93259535.2018

9.9435472.8997435.2018

9.73701972.85749735.2018

9.56100672.81290735.2018

9.42958472.73780835.2018

9.37560672.74954235.2018

9.35448572.84810935.2018

9.28877372.89269935.2018

9.20194172.98422635.2018

9.03766273.00335.2018

8.78420473.04993735.2018

8.59880473.07105935.2018

8.5870773.05463135.2018

8.67624973.10156735.2018

8.75134873.06636535.2018

8.97195173.02412235.2018

9.19020673.00335.2018

9.39672872.98657335.2018

9.56100673.02412235.2018

9.69242973.08279335.2018

9.86844273.1438135.2018

3.13067873.22829735.2018

2.94293173.31747635.2018

2.75518473.34094535.2018

2.73171673.24003135.2018

2.6988673.20717535.2018

2.47825873.34094535.2018

2.32336773.40196235.2018

2.21306673.44655235.2018

2.13327373.40900335.2018

2.0910373.34329135.2018

2.16847673.28696735.2018

2.25530973.38788135.2018

2.25530973.47002135.2018

2.16847673.56624135.2018

2.01358573.63195235.2018

1.91267173.6483835.2018

1.82349173.69531735.2018

1.76951473.68592935.2018

1.73665873.7000135.2018

1.69206873.70470435.2018

1.65686673.70705135.2018

1.64747873.64603335.2018

1.61462373.57797535.2018

1.52544373.47471435.2018

1.49258773.38084135.2018

1.40340773.31278335.2018

1.32596273.26349935.2018

1.20392673.2259535.2018

1.15933773.188435.2018

1.29310673.12034235.2018

1.35881873.05463135.2018

1.31422872.98891935.2018

1.18045872.9513735.2018

1.08189172.8997435.2018

1.09362572.79647935.2018

1.10301372.75658335.2018

1.02556772.71199335.2018

0.9715972.60638535.2018

0.92772.4843535.2018

0.87067672.36700835.2018

0.80496472.28486935.2018

0.80496472.18395535.2018

0.68292972.15344635.2018

0.60548372.15579335.2018

0.60548372.09008135.2018

0.56089472.06191935.2018

0.43885872.08538835.2018

0.36141372.0243735.2018

0.30508971.96335235.2018

0.26049971.90233535.2018

0.23937771.97508735.2018

0.29335472.10416235.2018

0.34967872.20038335.2018

0.43885872.18630235.2018

0.49283572.31772435.2018

0.52803872.35762135.2018

0.47171476.99966135.2018

0.32855776.97619235.2018

0.17366676.97149935.2018

0.07275276.93864335.2018

1.79063576.92456235.2018

1.80236976.87997235.2018

1.80236976.82834235.2018

1.83522576.74150935.2018

1.85634776.69457235.2018

1.91267176.62886135.2018

1.96899576.5701935.2018

2.02297276.53498735.2018

2.06756276.50917235.2018

2.06756276.44580735.2018

2.11215276.39417735.2018

2.13327376.3847935.2018

2.07929676.45988835.2018

2.0464476.53498735.2018

1.94552676.45050135.2018

1.87981576.40825835.2018

1.82349176.51621335.2018

1.80236976.62886135.2018

1.79063576.72038735.2018

1.668676.76967135.2018

1.668676.69222535.2018

1.668676.60539235.2018

1.6240176.54906835.2018

1.63574476.44111435.2018

1.6240176.38244335.2018

1.61462376.37305635.2018

1.44799776.37070935.2018

1.37055276.32142535.2018

1.34708376.33315935.2018

1.39167376.3472435.2018

1.44799776.42703335.2018

1.48085376.51855935.2018

1.5348376.48335735.2018

1.61462376.4364235.2018

1.668676.38948335.2018

1.17107176.34489435.2018

1.11474776.32846635.2018

1.00444576.41060535.2018

0.89414476.45988835.2018

0.8824176.56784335.2018

0.99271176.51855935.2018

1.07015776.44815435.2018

1.07015776.36366835.2018

1.18045876.33785335.2018

1.21331476.32142535.2018

1.22504876.30265135.2018

1.20392676.45988835.2018

1.17107176.56784335.2018

2.05582876.51855935.2018

2.10041776.44815435.2018

2.12388676.36366835.2018

2.05582876.33785335.2018

1.9572676.32142535.2018

1.87981576.30265135.2018

1.83522576.26744835.2018

-0.08213976.27214235.2018

0.13846376.25571435.2018

0.31682376.21347135.2018

0.38253476.23224534.1043

0.48344876.23928634.1043

0.63833976.24632734.1043

0.81669976.29326334.1043

0.92776.41529934.1043

1.05842376.43407334.1043

1.22504876.525634.1043

1.41514276.39652434.1043

1.5794276.39417734.1043

1.72492476.46692934.1043

1.94552676.60304534.1043

2.0018576.55610934.1043

2.05582876.4364234.1043

6.67674676.38244334.1043

6.81990376.41764534.1043

6.97244776.52794734.1043

7.22590576.67579734.1043

7.41365276.72273434.1043

7.65537676.66875734.1043

7.8079276.56080234.1043

7.86424576.44815434.1043

8.04025776.3918334.1043

8.25851376.34254734.1043

8.24677976.36366834.1043

8.22565776.37305634.1043

8.38993676.4810134.1043

8.66451576.55845634.1043

8.98133876.64998234.1043

9.25591876.6147834.1043

9.55161976.60069934.1043

9.81211876.57253734.1043

9.96466276.49978534.1043

10.00925276.44815434.1043

9.70416376.4293834.1043

9.39672876.45050134.1043

9.24418476.46223534.1043

9.20194176.45050134.1043

9.28877376.39417734.1043

9.24418476.33081334.1043

8.11535676.22755234.1043

8.10596976.18061534.1043

7.93934376.12194434.1043

7.84077676.14541334.1043

7.92995676.22051134.1043

8.04964472.75423634.1043

8.14821272.82933534.1043

8.11535672.94432934.1043

7.28222973.07105934.1043

7.30335173.17666634.1043

7.20478473.188434.1043

7.02877173.22360334.1043

6.8292973.3221734.1043

6.95132673.43247134.1043

7.18131573.47002134.1043

7.31508573.6037934.1043

7.30335173.6929734.1043

5.60658973.70235734.1043

5.59485573.65307434.1043

5.60658973.66480834.1043

5.60658971.87182634.1043

5.63005771.88121334.1043

5.63005773.12034234.1043

5.63005773.10626134.1043

5.63005773.12972934.1043

5.63005773.8854134.1043

5.63005773.86194234.1043

5.63005773.82439334.1043

5.60658973.7821534.1043

5.55261273.77510934.1043

5.44231173.76102834.1043

5.34139773.72347934.1043

5.33200973.70705134.1043

5.32027573.7000134.1043

5.26395173.71174534.1043

5.26395173.69531734.1043

5.25456473.72113234.1043

5.27568573.73286634.1043

5.2874273.76337534.1043

5.27568573.80327134.1043

5.18650673.81500534.1043

5.1982473.81969934.1043

5.16538473.84316734.1043

5.05508373.85255534.1043

4.93304773.85020834.1043

4.80162573.86194234.1043

4.69132373.88071734.1043

4.5904173.84316734.1043

4.51296473.80327134.1043

4.34868573.75398834.1043

4.29236173.74225334.1043

4.17032673.68358334.1043

4.0928873.62491234.1043

3.98257973.58501534.1043

3.87227873.54746634.1043

3.75024373.54746634.1043

3.66106373.53807934.1043

3.56249673.50522334.1043

3.46392973.49583634.1043

3.33015973.48879534.1043

3.13067873.48410234.1043

-0.14785173.4629834.1043

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0.13846373.44420534.1043

0.25111173.44655234.1043

0.25111173.39961534.1043

0.26049973.35502634.1043

0.29335473.31278334.1043

0.48344873.33155734.1043

0.67119573.30808934.1043

0.84955473.2705434.1043

1.07015773.24237834.1043

1.28137273.21421634.1043

1.50197473.16493234.1043

1.69206873.11799534.1043

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