liquid nitrate test solution #2 - mars fishcare inc

13
Liquid Nitrate Test Solution #2 Hazard Alert Code: HIGH Chemwatch Material Safety Data Sheet Dec-12-2012 CHEMWATCH 4650-20 B293LP Version No:5.1.1.1 Page 1 of 13 Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME Liquid Nitrate Test Solution #2 STATEMENT OF HAZARDOUS NATURE CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200. NFPA FLAMMABILITY 0 HEALTH HAZARD 1 INSTABILITY 0 SUPPLIER Company: Mars Fishcare Inc Address: 50 East Hamilton Street Chalfont PA, 18914 United States of America Telephone: +1 215 822 8181 Fax: +1 215 822 1906 PRODUCT USE Nitrate test solution for product LR1800, 34 and 401M. SYNONYMS "Solution ID# 3307" Section 2 - HAZARDS IDENTIFICATION HAZARD RATINGS continued...

Upload: others

Post on 03-Feb-2022

2 views

Category:

Documents


0 download

TRANSCRIPT

Liquid Nitrate Test Solution #2

Hazard Alert Code: HIGHChemwatch Material Safety Data SheetDec-12-2012 CHEMWATCH 4650-20B293LP Version No:5.1.1.1

Page 1 of 13

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAMELiquid Nitrate Test Solution #2

STATEMENT OF HAZARDOUS NATURECONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

NFPA

FLAMMABILITY0HEALTH HAZARD1 INSTABILITY0

SUPPLIERCompany: Mars Fishcare IncAddress:50 East Hamilton StreetChalfontPA, 18914United States of AmericaTelephone: +1 215 822 8181Fax: +1 215 822 1906

PRODUCT USENitrate test solution for product LR1800, 34 and 401M.

SYNONYMS"Solution ID# 3307"

Section 2 - HAZARDS IDENTIFICATION

HAZARD RATINGS

continued...

Liquid Nitrate Test Solution #2

Hazard Alert Code: HIGHChemwatch Material Safety Data SheetDec-12-2012 CHEMWATCH 4650-20B293LP Version No:5.1.1.1

Page 2 of 13Section 2 - HAZARDS IDENTIFICATION

Flammability Toxicity

Body Contact Reactivity

Chronic

SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4

CANADIAN WHMIS SYMBOLS

EMERGENCY OVERVIEW

RISKPossible risk of irreversible effects.Cumulative effects may result following exposure*.Limited evidence of a carcinogenic effect*.May affect fertility*.May possibly be harmful to the fetus/ embryo*.May produce discomfort of the eyes, respiratory tract and skin*.* (limited evidence).

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED■ The material has NOT been classified as "harmful by ingestion". This is because of the lack ofcorroborating animal or human evidence. The material may still be damaging to the health of the individual,following ingestion, especially where pre-existing organ (e.g. liver, kidney) damage is evident. Presentdefinitions of harmful or toxic substances are generally based on doses producing mortality (death) ratherthan those producing morbidity (disease, ill-health). Gastrointestinal tract discomfort may produce nauseaand vomiting. In an occupational setting however, unintentional ingestion is not thought to be cause forconcern.

EYE■ Limited evidence or practical experience suggests, that the material may cause eye irritation in asubstantial number of individuals. Prolonged eye contact may cause inflammation characterized by a temporaryredness of the conjunctiva (similar to windburn).■ Eye drops with sulfonamides can cause local irritation, sensations of burning and stinging, blurred visionand loss of depth perception. The conjunctiva and cornea may become inflamed, and the cornea and lens maybecome clouded.

continued...

Liquid Nitrate Test Solution #2

Hazard Alert Code: HIGHChemwatch Material Safety Data SheetDec-12-2012 CHEMWATCH 4650-20B293LP Version No:5.1.1.1

Page 3 of 13Section 2 - HAZARDS IDENTIFICATION

SKIN■ There is some evidence to suggest that the material may cause mild but significant inflammation of the skineither following direct contact or after a delay of some time. Repeated exposure can cause contact dermatitiswhich is characterized by redness, swelling and blistering.■ Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injurywith harmful effects. Examine the skin prior to the use of the material and ensure that any external damageis suitably protected.

INHALED■ There is some evidence to suggest that the material can cause respiratory irritation in some persons. Thebody's response to such irritation can cause further lung damage.

CHRONIC HEALTH EFFECTSThere has been some concern that this material can cause cancer or mutations but there is not enough data tomake an assessment.Prolonged oral treatment with sulfonamides has caused nausea, vomiting, diarrhea, abdominal pain, loss ofappetite, inflammation of the mouth cavity, impaired folic acid absorption, exacerbation of porphyria,acidosis, liver damage with impaired blood clotting, jaundice and inflammation of the pancreas. Effects onthe kidney include blood and crystals in the urine, painful and frequent urination or lack of urine withnitrogen retention. Nervous system symptoms include headache, drowsiness, trouble sleeping, dizziness,ringing in the ears, hearing loss, depression, hallucinations, inco-ordination, paralysis of muscles,numbness in the extremities, spinal cord damage and inflammation, convulsions and unconsciousness. Effects onthe blood includes a change in blood cell distribution with loss of white blood cells and platelets, andanemia, which Africans seem to be more prone to developing than Europeans. Cyanosis can occur owing tocomplexes being formed by hemoglobin. Eye effects include inflamed cornea and conjunctiva with eyelidswelling and in severe cases, fear of the light. Allergies and cross-sensitivity is common, and can causeitches, wheals and sometimes a severe red rash with blisters that is often fatal. This class of drugs canscar the cornea and conjunctiva, swelling around the eyes, painful and inflamed joints, reduced sperm counts,pneumonia, fever, chills, hair loss, inflammation of vessels, lupus, reduced lung function, infertility,hypothyroidism and goiter, and increased urinary output. More seriously, the lungs may become permanentlyscarred and there may be irreversible damage to the nervous system and muscles. Inflammation of the skin hasoccurred after the drug is ingested and has traveled through the bloodstream. Skin effects often occur whenthere has been exposure in conjunction with UV light. Clothed areas are initially less likely to be affectedbut may be in later stages. Rarely there may be persistence of inflammation on light contact even after thedrug has been removed.

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS RN %polyethylene glycol 25322-68-3 98sulfanilamide 63-74-1 <5

Section 4 - FIRST AID MEASURES

SWALLOWED• Immediately give a glass of water.• First aid is not generally required. If in doubt, contact a Poisons Information Center or a doctor.

continued...

Liquid Nitrate Test Solution #2

Hazard Alert Code: HIGHChemwatch Material Safety Data SheetDec-12-2012 CHEMWATCH 4650-20B293LP Version No:5.1.1.1

Page 4 of 13Section 4 - FIRST AID MEASURES

EYE■ If this product comes in contact with the eyes:• Wash out immediately with fresh running water.• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.• If pain persists or recurs seek medical attention.• Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

SKIN■ If skin contact occurs:• Immediately remove all contaminated clothing, including footwear• Flush skin and hair with running water (and soap if available).• Seek medical attention in event of irritation.

INHALED• If fumes or combustion products are inhaled remove from contaminated area.• Other measures are usually unnecessary.

NOTES TO PHYSICIANTreat symptomatically.In cases of recent sulfonamide overdose the stomach should be emptied by aspiration and lavage. If kidneyfunction is adequate, a saline purgative, such as sodium sulfate, 30 g in 250 ml water, may be given topromote peristalsis and elimination of sulfonamide in the urine may be assisted by giving alkalis, such assodium bicarbonate and increasing fluid intake. Severe crystalluria may require ureteric catheterization andirrigation with warm 2.5% sodium bicarbonate solution. Treatment should be continued until it can be assumedthat the sulfonamide has been eliminated. The majority of sulfonamides are metabolized to acetylatedderivatives which retain the toxicity of the parent compound and thus may indicate more active removal whenadverse effects are very severe. Active measures may include forced diuresis, peritoneal dialysis andcharcoal hemoperfusion. [Martindale: The Extra Pharmacopoeia, 28th Ed.].

Section 5 - FIRE FIGHTING MEASURES

Vapour Pressure (mmHg): Not AvailableUpper Explosive Limit (%): Not ApplicableSpecific Gravity (water=1): 1.127Lower Explosive Limit (%): Not Applicable

EXTINGUISHING MEDIA• Water spray or fog.• Foam.• Dry chemical powder.• BCF (where regulations permit).• Carbon dioxide.

FIRE FIGHTING• Alert Emergency Responders and tell them location and nature of hazard.• Wear full body protective clothing with breathing apparatus.• Prevent, by any means available, spillage from entering drains or water course.• Use water delivered as a fine spray to control fire and cool adjacent area.• Avoid spraying water onto liquid pools.• Do not approach containers suspected to be hot.• Cool fire exposed containers with water spray from a protected location.• If safe to do so, remove containers from path of fire.

continued...

Liquid Nitrate Test Solution #2

Hazard Alert Code: HIGHChemwatch Material Safety Data SheetDec-12-2012 CHEMWATCH 4650-20B293LP Version No:5.1.1.1

Page 5 of 13Section 5 - FIRE FIGHTING MEASURES

GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS• Combustible.• Slight fire hazard when exposed to heat or flame.• Heating may cause expansion or decomposition leading to violent rupture of containers.• On combustion, may emit toxic fumes of carbon monoxide (CO).• May emit acrid smoke.• Mists containing combustible materials may be explosive.May emit poisonous fumes.May emit corrosive fumes.

FIRE INCOMPATIBILITY■ Avoid contamination with oxidizing agents i.e. nitrates, oxidizing acids,chlorine bleaches, pool chlorineetc. as ignition may result.

Section 6 - ACCIDENTAL RELEASE MEASURES

MINOR SPILLS• Remove all ignition sources.• Clean up all spills immediately.• Avoid breathing vapors and contact with skin and eyes.• Control personal contact by using protective equipment.• Contain and absorb spill with sand, earth, inert material or vermiculite.• Wipe up.• Place in a suitable labeled container for waste disposal.

MAJOR SPILLSModerate hazard.• Clear area of personnel and move upwind.• Alert Emergency Responders and tell them location and nature of hazard.• Wear breathing apparatus plus protective gloves.• Prevent, by any means available, spillage from entering drains or water course.• No smoking, naked lights or ignition sources. Increase ventilation.• Stop leak if safe to do so.• Contain spill with sand, earth or vermiculite.• Collect recoverable product into labeled containers for recycling.• Absorb remaining product with sand, earth or vermiculite.• Collect solid residues and seal in labeled drums for disposal.• Wash area and prevent runoff into drains.• If contamination of drains or waterways occurs, advise emergency services.

Section 7 - HANDLING AND STORAGE

PROCEDURE FOR HANDLING• Avoid all personal contact, including inhalation.• Wear protective clothing when risk of exposure occurs.• Use in a well-ventilated area.• Prevent concentration in hollows and sumps.

continued...

Liquid Nitrate Test Solution #2

Hazard Alert Code: HIGHChemwatch Material Safety Data SheetDec-12-2012 CHEMWATCH 4650-20B293LP Version No:5.1.1.1

Page 6 of 13Section 7 - HANDLING AND STORAGE

• DO NOT enter confined spaces until atmosphere has been checked.• Avoid smoking, naked lights or ignition sources.• Avoid contact with incompatible materials.• When handling, DO NOT eat, drink or smoke.• Keep containers securely sealed when not in use.• Avoid physical damage to containers.• Always wash hands with soap and water after handling.• Work clothes should be laundered separately.• Use good occupational work practice.• Observe manufacturer's storing and handling recommendations.• Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions.

RECOMMENDED STORAGE METHODS• Metal can or drum• Packing as recommended by manufacturer.• Check all containers are clearly labeled and free from leaks.

STORAGE REQUIREMENTSSUITABLE CONTAINER• Metal can or drum• Packing as recommended by manufacturer.• Check all containers are clearly labeled and free from leaks.

STORAGE INCOMPATIBILITY■ Avoid reaction with oxidizing agents.

STORAGE REQUIREMENTS

_____________________________________________________

SAFE STORAGE WITH OTHER CLASSIFIED CHEMICALS

+ X + X X +_____________________________________________________+: May be stored togetherO: May be stored together with specific preventionsX: Must not be stored together

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLSThe following materials had no OELs on our records

continued...

Liquid Nitrate Test Solution #2

Hazard Alert Code: HIGHChemwatch Material Safety Data SheetDec-12-2012 CHEMWATCH 4650-20B293LP Version No:5.1.1.1

Page 7 of 13Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

• polyethylene CAS:25322- 68- 3 CAS:8038- 37- 7 CAS:9081- 95- 2 CAS:9085- 02- 3 CAS:9085-glycol: 03- 4 CAS:12676- 74- 3 CAS:12770- 93- 3 CAS: 25104- 58- 9 CAS:25609- 81- 8

CAS:34802- 42- 1 CAS:37361- 15- 2 CAS:50809- 04- 6 CAS:50809- 59- 1CAS:54510- 95- 1 CAS: 54847- 64- 2 CAS:59763- 40- 5 CAS:60894- 12- 4CAS:61840- 14- 0 CAS:64441- 68- 5 CAS:64640- 28- 4 CAS:67411- 64- 7 CAS:70926- 57- 7 CAS:75285- 02- 8 CAS:75285- 03- 9 CAS:77986- 38- 0 CAS:79964-26- 4 CAS:80341- 53- 3 CAS:85399- 22- 0 CAS: 85945- 29- 5 CAS:88077- 80- 9CAS:88747- 22- 2 CAS:90597- 70- 9 CAS:99264- 61- 6 CAS:99333- 89- 8CAS:101677- 86- 5 CAS: 106186- 24- 7 CAS:107502- 63- 6 CAS:107529- 96- 4CAS:109550- 27- 8 CAS:112384- 37- 9 CAS:112895- 21- 3 CAS:114323- 93- 2CAS:116549- 90- 7 CAS:119219- 06- 6 CAS:125223- 68- 9 CAS:133573- 31- 6CAS:134919- 43- 0 CAS:150872- 82- 5 CAS:154394- 38- 4 CAS:156948- 19- 5CAS:169046- 53- 1 CAS:174460- 08- 3 CAS:174460- 09- 4 CAS:188364- 77- 4CAS:188924- 03- 0 CAS:189154- 62- 9 CAS:191743- 71- 2 CAS:196696- 84- 1CAS:201163- 43- 1 CAS:206357- 86- 0

• sulfanilamide: CAS:63- 74- 1

MATERIAL DATALIQUID NITRATE TEST SOLUTION #2:

Not available

PERSONAL PROTECTION

Consult your EHS staff for recommendations

EYE• Safety glasses with side shields.• Chemical goggles.• Contact lenses pose a special hazard; soft lenses may absorb irritants and all lenses concentrate them. DO

NOT wear contact lenses.

HANDS/FEET■ Wear chemical protective gloves, eg. PVC.Wear safety footwear or safety gumboots, eg. Rubber.

RESPIRATOR•Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or nationalequivalent)

The local concentration of material, quantity and conditions of use determine the type of personal protectiveequipment required.Use appropriate NIOSH-certified respirator based on informed professional

continued...

Liquid Nitrate Test Solution #2

Hazard Alert Code: HIGHChemwatch Material Safety Data SheetDec-12-2012 CHEMWATCH 4650-20B293LP Version No:5.1.1.1

Page 8 of 13Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

judgement. In conditions where no reasonable estimate of exposure can bemade, assume the exposure is in a concentration IDLH and use NIOSH-certifiedfull face pressure demand SCBA with a minimum service life of 30 minutes, ora combination full facepiece pressure demand SAR with auxiliary self-containedair supply. Respirators provided only for escape from IDLH atmospheres shall beNIOSH-certified for escape from the atmosphere in which they will be used.

ENGINEERING CONTROLS■ General exhaust is adequate under normal operating conditions. Local exhaust ventilation may be required inspecial circumstances. If risk of overexposure exists, wear an approved respirator An approved respirator(supplied air type) may be required in special circumstances. Correct fit is essential to ensure adequateprotection. Provide adequate ventilation in warehouses and enclosed storage areas.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL PROPERTIESLiquid.Mixes with water.

State Liquid Molecular Weight Not ApplicableMelting Range (°F) Not Available Viscosity Not AvailableBoiling Range (°F) Not Available Solubility in water (g/L) MiscibleFlash Point (°F) Not Applicable pH (1% solution) Not AvailableDecomposition Temp (°F) Not Available pH (as supplied) Not AvailableAutoignition Temp (°F) Not Applicable Vapour Pressure (mmHg) Not AvailableUpper Explosive Limit (%) Not Applicable Specific Gravity (water=1) 1.127Lower Explosive Limit (%) Not Applicable Relative Vapor Density Not Available

(air=1)Volatile Component (%vol) Not Available Evaporation Rate Not Available

APPEARANCETranslucent light gray liquid with no odour; mixes with water.

Section 10 - CHEMICAL STABILITY

CONDITIONS CONTRIBUTING TO INSTABILITY• Presence of incompatible materials.• Product is considered stable.• Hazardous polymerization will not occur.

STORAGE INCOMPATIBILITY■ Avoid reaction with oxidizing agents.

For incompatible materials - refer to Section 7 - Handling and Storage.

continued...

Liquid Nitrate Test Solution #2

Hazard Alert Code: HIGHChemwatch Material Safety Data SheetDec-12-2012 CHEMWATCH 4650-20B293LP Version No:5.1.1.1

Page 9 of 13

Section 11 - TOXICOLOGICAL INFORMATION

Liquid Nitrate Test Solution #2

TOXICITY AND IRRITATION

LIQUID NITRATE TEST SOLUTION #2:

POLYETHYLENE GLYCOL:TOXICITY IRRITATIONOral (rat) LD50:33750 mg/kg Skin (rabbit):500mg/24h - mild.Intravenous (Cat) TDLo:1000 mg/kg Eye (rabbit):500mg/24h - mild.Oral (Rabbit) LD50:17300 mg/kgIntraperitoneal (Mouse) LD50:7500 mg/kgOral (Rat) LD50:31640 mg/kgOral (Rat) LD50:27500 mg/kgIntravenous (Rat) LD50:7130 mg/kgOral (Guinea pig) LD50:19600 mg/kgOral (Rat) LD50:30200 mg/kgIntraperitoneal (Rat) LD50:9708 mg/kgIntravenous (Rat) LD50:7312 mg/kgOral (Mouse) LD50:28915 mg/kgIntraperitoneal (Mouse) LD50:473 mg/kgIntravenous (Mouse) LD50:8550 mg/kgOral (Rabbit) LD50:26800 mg/kgOral (Guinea pig) LD50:15700 mg/kgOral (Rat) LD50:600 mg/kgIntraperitoneal (Rat) LD50:14100 mg/kgIntraperitoneal (Rat) LD50:15570 mg/kgOral (Guinea pig) LD50:22500 mg/kgOral (Rat) LD50:1054 mg/kgOral (Rat) LD50:51310 mg/kgOral (Rat) LD50:44200 mg/kgIntraperitoneal (Rat) LD50:17700 mg/kgOral (Rabbit) LD50:28900 mg/kgOral (Guinea pig) LD50:28900 mg/kgOral (Rat) LD50:51200 mg/kgIntraperitoneal (Rat) LD50:15390 mg/kgIntraperitoneal (Rat) LD50:9700 mg/kgIntravenous (Rat) LD50:7500 mg/kgOral (Guinea pig) LD50:50900 mg/kgIntraperitoneal (Rat) LD50:6790 mg/kgIntraperitoneal (Rat) LD50:12600 mg/kgIntravenous (Mouse) LD50:7.9 mg/kgOral (Rat) LD50:31600 mg/kgIntravenous (Rat) LD:3 mg/kg■ The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated orprolonged exposure to irritants may produce conjunctivitis.The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skinredness, swelling, the production of vesicles, scaling and thickening of the skin.for molecular weights (200-8000) *Oral (rat) LD50: 31000->50000 mg/kg

continued...

Liquid Nitrate Test Solution #2

Hazard Alert Code: HIGHChemwatch Material Safety Data SheetDec-12-2012 CHEMWATCH 4650-20B293LP Version No:5.1.1.1

Page 10 of 13Section 11 - TOXICOLOGICAL INFORMATION

Oral (mice) LD50: 38000->50000 mg/kgOral (g.pig) LD50: 17000->50000 mg/kgOral (rabbit) LD50: 14000->50000 mg/kg * AIHA WEEL GuidesIntraperitoneal (mice) LD50: 3100-12900 mg/kg

SULFANILAMIDE:

SKINpolyethylene glycol GESAMP/EHS Composite List - GESAMP Hazard D1: skin 1

Profiles irritation/corrosion

Section 12 - ECOLOGICAL INFORMATION

SULFANILAMIDE:POLYETHYLENE GLYCOL:DO NOT discharge into sewer or waterways.

POLYETHYLENE GLYCOL:

BOD 5 if unstated: 0-0.02,1%COD: 1.62-1.74,98%Toxicity Fish: TLm(96)>10000mg/L

SULFANILAMIDE:Toxic to soil organisms.

EcotoxicityIngredient Persistence: Persistence: Air Bioaccumulation Mobility

Water/Soilpolyethylene glycol LOW No Data LOW HIGH

Availablesulfanilamide HIGH No Data LOW HIGH

Available

Section 13 - DISPOSAL CONSIDERATIONS

Disposal InstructionsAll waste must be handled in accordance with local, state and federal regulations.¦ Puncture containers to prevent re-use and bury at an authorized landfill.

Section 14 - TRANSPORTATION INFORMATION

NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: DOT, IATA, IMDG

continued...

Liquid Nitrate Test Solution #2

Hazard Alert Code: HIGHChemwatch Material Safety Data SheetDec-12-2012 CHEMWATCH 4650-20B293LP Version No:5.1.1.1

Page 11 of 13

Section 15 - REGULATORY INFORMATION

REGULATIONS

Regulations for ingredients

polyethylene glycol (CAS: 25322-68-3, 8038-37-7, 9081-95-2, 9085-02-3, 9085-03-4, 12676-74-3, 12770-93-3, 25104-58-9, 25609-81-8, 34802-42-1, 37361-15-2, 50809-04-6, 50809-59-1, 54510-95-1,54847-64-2, 59763-40-5, 60894-12-4, 61840-14-0, 64441-68-5, 64640-28-4, 67411-64-7, 70926-57-7,75285-02-8, 75285-03-9, 77986-38-0, 79964-26-4, 80341-53-3, 85399-22-0, 85945-29-5, 88077-80-9,88747-22-2, 90597-70-9, 99264-61-6, 99333-89-8, 101677-86-5, 106186-24-7, 107502-63-6, 107529-96-4, 109550-27-8, 112384-37-9, 112895-21-3, 114323-93-2, 116549-90-7, 119219-06-6, 125223-68-9, 133573-31-6, 134919-43-0, 150872-82-5, 154394-38-4, 156948-19-5, 169046-53-1, 174460-08-3, 174460-09-4, 188364-77-4, 188924-03-0, 189154-62-9, 191743-71-2, 196696-84-1, 201163-43-1, 206357-86-0) is found on the following regulatory lists;"Acros Transport Information", "Canada - Alberta Ambient Air Quality Guidelines", "Canada - Alberta Ambient Air Quality Objectives", "Canada - British Columbia Occupational Exposure Limits", "Canada - Ontario Occupational Exposure Limits", "Canada - Quebec Permissible Exposure Values for Airborne Contaminants (English)", "Canada CEPA Environmental Registry Substance Lists - List of substances on the DSL that meet the human health criteria for categorization (English)", "Canada National Pollutant Release Inventory (NPRI)", "Canada Substances in Products Regulated Under the Food and Drugs Act (F&DA) That Were In Commerce between January 1, 1987 and September 13, 2001 (English)", "FisherTransport Information", "GESAMP/EHS Composite List -GESAMP Hazard Profiles", "IMO IBC Code Chapter 17: Summary of minimum requirements", "IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances", "International Fragrance Association (IFRA) Survey: Transparency List", "International Numbering System for Food Additives", "OECD List of High Production Volume (HPV) Chemicals", "OSPAR National List of Candidates for Substitution – United Kingdom", "Sigma-AldrichTransport Information", "US - California Permissible Exposure Limits for Chemical Contaminants", "US - Michigan Exposure Limits for Air Contaminants", "US - Minnesota Hazardous Substance List", "US - Oregon Permissible Exposure Limits (Z-1)", "US - Tennessee Occupational Exposure Limits - Limits For Air Contaminants", "US - Wyoming Toxic and Hazardous Substances Table Z1 Limits for Air Contaminants", "US American Cleaning Institute Cleaning Product Ingredient Inventory", "US Clean Air Act (CAA) National Ambient Air Quality Standards (NAAQS)", "US DOE Temporary Emergency Exposure Limits (TEELs)", "US DOT Coast Guard Bulk Hazardous Materials -List of Flammable and Combustible Bulk Liquid Cargoes", "US EPA High Production Volume Program Chemical List","US FDA CFSAN Food Additives Status List", "US FDA Everything Added to Food in the United States (EAFUS)", "US FDA Indirect Food Additives - Substances for use as Components of Coatings - Resinous and polymeric coatings 21CFR 175-300", "US FDA Indirect Food Additives: Adhesives and Components of Coatings - Substances for Use Only as Components of Adhesives - Adhesives", "US FDA List of ""Indirect"" Additives Used in Food Contact Substances", "US Inventory of Effective Food Contact Substance Notifications", "US NFPA Fire Hazard Properties of Flammable Liquids, Gases, and Volatile Solids Table", "US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory"

sulfanilamide (CAS: 63-74-1) is found on the following regulatory lists;"Canada - Alberta Ambient Air Quality Guidelines", "Canada - Alberta Ambient Air Quality Objectives", "Canada - British Columbia Occupational Exposure Limits", "Canada - Ontario Occupational Exposure Limits", "Canada -

continued...

Liquid Nitrate Test Solution #2

Hazard Alert Code: HIGHChemwatch Material Safety Data SheetDec-12-2012 CHEMWATCH 4650-20B293LP Version No:5.1.1.1

Page 12 of 13Section 15 - REGULATORY INFORMATION

Quebec Permissible Exposure Values for Airborne Contaminants (English)", "Canada List of Prohibited and Restricted Cosmetic Ingredients (The Cosmetic Ingredient ""Hotlist"")", "Canada National Pollutant Release Inventory (NPRI)", "FisherTransport Information", "Sigma-AldrichTransport Information", "US - California Permissible Exposure Limits for Chemical Contaminants", "US - Michigan Exposure Limits for Air Contaminants", "US - Oregon Permissible Exposure Limits (Z-1)", "US - Tennessee Occupational Exposure Limits - Limits For Air Contaminants", "US - Wyoming Toxic and Hazardous Substances Table Z1 Limits for Air Contaminants", "US Clean Air Act (CAA) National Ambient Air Quality Standards (NAAQS)", "US DOE Temporary Emergency Exposure Limits (TEELs)", "US FDA CFSAN Food Additives Status List", "US FDA List of ""Indirect"" Additives Used in Food Contact Substances", "US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory", "US Toxic Substances Control Act (TSCA) - Premanufacture Notice (PMN) Chemicals", "US TSCA Section 5(a)(2) - Significant New Use Rules (SNURs)"

No data for Liquid Nitrate Test Solution #2 (CW: 4650-20)

Section 16 - OTHER INFORMATION

LIMITED EVIDENCE■ Cumulative effects may result following exposure*.■ May produce discomfort of the eyes, respiratory tract and skin*.■ Limited evidence of a carcinogenic effect*.■ May affect fertility*.■ May possibly be harmful to the fetus/ embryo*.* (limited evidence).

Denmark Advisory list for selfclassification of dangerous substancesSubstance CAS Suggested codessulfanilamide 63- 74- 1 R52/53

INGREDIENTS WITH MULTIPLE CAS NUMBERSIngredient Name CASpolyethylene glycol 25322-68-3, 8038-37-7, 9081-95-2, 9085-02-3, 9085-03-4, 12676-74-3, 12770-93-3,25104-58-9, 25609-81-8, 34802-42-1, 37361-15-2, 50809-04-6, 50809-59-1, 54510-95-1, 54847-64-2, 59763-40-5, 60894-12-4, 61840-14-0, 64441-68-5, 64640-28-4, 67411-64-7, 70926-57-7, 75285-02-8, 75285-03-9,77986-38-0, 79964-26-4, 80341-53-3, 85399-22-0, 85945-29-5, 88077-80-9, 88747-22-2, 90597-70-9, 99264-61-6, 99333-89-8, 101677-86-5, 106186-24-7, 107502-63-6, 107529-96-4, 109550-27-8, 112384-37-9,112895-21-3, 114323-93-2, 116549-90-7, 119219-06-6, 125223-68-9, 133573-31-6, 134919-43-0, 150872-82-5,154394-38-4, 156948-19-5, 169046-53-1, 174460-08-3, 174460-09-4, 188364-77-4, 188924-03-0, 189154-62-9,191743-71-2, 196696-84-1, 201163-43-1, 206357-86-0

■ Classification of the mixture and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.A list of reference resources used to assist the committee may be found at: www.chemwatch.net/references.

■ For detailed advice on Personal Protective Equipment, refer to the following U.S. Regulations and Standards:OSHA Standards - 29 CFR:1910.132 - Personal Protective Equipment - General requirements1910.133 - Eye and face protection1910.134 - Respiratory Protection1910.136 - Occupational foot protection

continued...

Liquid Nitrate Test Solution #2

Hazard Alert Code: HIGHChemwatch Material Safety Data SheetDec-12-2012 CHEMWATCH 4650-20B293LP Version No:5.1.1.1

Page 13 of 13Section 16 - OTHER INFORMATION

1910.138 - Hand ProtectionEye and face protection - ANSI Z87.1Foot protection - ANSI Z41Respirators must be NIOSH approved.

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700.

Issue Date: Dec-12-2012Print Date: Feb-5-2013