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List of Publications Youhei Takeda

As of May 30, 2018

Original Papers 1. “Conformationally-Flexible and Moderately Electron-Donating Units-Installed D-A-D Triad Enabling

Multi-Color-Changing Mechanochromic Luminescence, TADF and Room-Temperature Phosphorescence” Takeda, Y.*; Kaihara, T.; Okazaki, M.; Higginbotham, H.; Data, P.*; Tohnai, N.; Minakata, S. Chem. Commun. Advance Manuscript [DOI: 10.1039/c8cc02365d] an open-access article Invited as the part of the themed collection “Chem Commun 2018 Emerging Investigators”.

2. “FRET-Mediated Near Infrared Whispering Gallery Modes: Studies on the Relevance of Intracavity Energy Transfer with Q-Factor” Oki, O.; Kushida, S.; Mikosch, A.; Hatanaka, K.; Takeda, Y.; Minakata, S.; Kuwabara, J.; Kanbara, T.; Dao, T. D.; Ishii, S.; Nagao, T.; Kuehne, A. J. C.; Deschler, F.; Friend, R.; Yamamoto, Y.* Mater. Chem. Front. 2018, 2, 270–274. [DOI: 10.1039/C7QM00498B] Invited as the part of the themed collection “Pi conjugated system bricolage (figuration) toward functional organic molecular systems”.

3. “An Optical and Electrical Study of Fully Thermally Activated Delayed Fluorescent White Organic Light-emitting Diodes” Pereira, D.*; Santos, P. L.; Ward, J.; Data, P.; Okazaki, M.; Takeda, Y.; Minakata, S.; Bryce, M.; Monkman, A. P.

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Sci. Rep. 2017, 7, 6234/1–8. [DOI: 10.1038/s41598-017-06568-3] http://www.nature.com/articles/s41598-017-06568-3 an open-access article

4. “Thermally Activated Delayed Fluorescent Phenothiazine-dibenzo[a,j]phenazine-phenothiazine Triads Exhibiting Tricolor-Changing Mechanochromic Luminescence” Okazaki, M.; Takeda, Y.*; Data, P.*; Pander, P.; Higginbotham, H.; Monkman, A. P.; Minakata, S.* Chem. Sci. 2017, 8, 2677–2686. [DOI: 10.1039/C6SC04863C] http://pubs.rsc.org/en/Content/ArticleLanding/2017/SC/C6SC04863C#!divAbstract an open-access article Press Release (Osaka University, January 13, 2017) Highlighted in ResOU, Chem-Station, AlphaGalileo, EurekAlert!, ScienceDaily, Phys Org, Optronics, UPI, Asian Scientist, and American Laboratory, and Kodomo-no-Kagaku. Ranked in the most downloaded Chemical Science articles of 2017 (within top 7 in Inorganic and Physical Chemistry field)

5. “Oxidative Self-annulation of 2,5-Diaryl-3,4-diaminothiophene via C–C and C–S Bond Cleavage of the Thiophene Ring: A New Synthesis of An Amino-substituted Triarylthieno[3,4-b]pyrazines and Their Photophysical Properties” Takeda, Y.*; Ueta, S.; Minakata, S.* Heterocycles 2017, 95, 137–144. (Professor Masakatsu Shibasaki’s Special Issues) [DOI: 10.3987/COM-16-S(S)11] https://www.heterocycles.jp/newlibrary/libraries/abst/24813

6. “Palladium-Catalyzed Regioselective and Stereo-invertive Ring-Opening Borylation of 2-Arylaziridines with Bis(pinacolato)diboron: Experimental and Computational Studies” Takeda, Y.*; Kuroda, A.; Sameera, W. M. C.; Morokuma, K.*; Minakata, S.*

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Chem. Sci. 2016, 7, 6141–6152. [DOI: 10.1039/C6SC01120A] http://pubs.rsc.org/en/content/articlelanding/2016/sc/c6sc01120a#!divAbstract an open-access article Highlighted in J. Synth. Org. Chem. Jpn.

7. “Thieno[3,4-c]phosphole-4,6-dione: A Versatile Building Block for Phosphorus-containing Functional p-Conjugated Systems” Takeda, Y.*; Hatanaka, K.; Nishida, T.; Minakata, S.* Chem. Eur. J. 2016, 22, 10460–10364. [DOI: 10.1002/anie.201602392] http://onlinelibrary.wiley.com/doi/10.1002/chem.201602392/full Highlighted in Atlas of Science (October 7, 2016).

8. “Dibenzo[a,j]phenzine-Cored Donor-Acceptor-Donor (D-A-D) Compounds as Green-to-Red/NIR Thermally Activated Delayed Fluorescence Organic Light Emitters” Data, P.*; Pander, P.; Okazaki, M.; Takeda, Y.*; Minakata, S.; Monkman, A. P. Angew. Chem., Int. Ed. 2016, 55, 5739–5744. [DOI: 10.1002/anie.201600113] http://onlinelibrary.wiley.com/doi/10.1002/anie.201600113/full Press Release (Osaka University, April 7, 2016) Highlighted in a newspaper (The Science News, April 29, 2016). Highlighted in ResOU, AlphaGalileo, EurekAlert!, ScienceDaily, Materials Today, Phys Org, and Optronics.

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9. “Ring-Contractive and –Closing Skeletal Rearrangement of 1,1’-Binaphthalene-2,2’-Diamines (BINAMs) Induced by an Iodine-containing Oxidant: Synthesis of Spiro[benzo[e]indole-1,1’-inden]-2-amines and Application to an AIEE-active BF2 Complex” Okazaki, M.; Takahashi, K.; Takeda, Y.*; Minakata, S.* Heterocycles 2016, 93, 770–782. (Professor Lutz F. Tietze’s Special Issues) [DOI: 10.3987/COM-15-S(T)33] https://www.heterocycles.jp/newlibrary/libraries/abst/24396

10. “A Facile Synthesis of Functionalized 7,8-Diaza[5]helicenes through an Oxidative Ring-closure of 1,1’-Binaphthalene-2,2’-diamines (BINAMs)” Takeda, Y.*; Okazaki, M.; Maruoka, Y.; Minakata, S.* Beilstein J. Org. Chem. 2015, 11, 9–15. [DOI: 10.3762/bjoc.11.2] http://www.beilstein-journals.org/bjoc/single/articleFullText.htm?publicId=1860-5397-11-2&vt=f&tpn=0&bpn=home an open-access article

11. “2-Halogenoimidazolium Salt Catalyzed Aza-Diels–Alder Reaction through Halogen-Bond Formation”

Takeda, Y.*; Hisakuni, D.; Lin, C.-H.; Minakata, S.*

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Org. Lett. 2015, 17, 318–321. [DOI: 10.1021/ol503426f] http://pubs.acs.org/doi/abs/10.1021/ol503426f

12. “Revisiting Phosphorus Analogues of Phthalimides and Naphthalimides: Syntheses and Comparative Studies” Takeda, Y.*; Nishida, T.; Hatanaka, K.; Minakata, S.* Chem.—Eur. J. 2015, 21, 1666–1672. [DOI: 10.1002/chem.201405494] http://onlinelibrary.wiley.com/doi/10.1002/chem.201405494/abstract

13. “Oxidative Skeletal Rearrangement of 1,1’-Binaphthalene-2,2’-Diamines (BINAMs) via C–C Bond Cleavage and Nitrogen Migration: A Versatile Synthesis of U-Shaped Azaacenes” Takeda, Y.*; Okazaki, M.; Minakata, S.* Chem. Commun. 2014, 50, 10291–10294. [DOI: 10.1039/C4CC04911J] http://pubs.rsc.org/en/content/articlelanding/2014/cc/c4cc04911j an open-access article Highlighted in Synfacts 2014, 10, 1036.

14. “2,6-Diphospha-s-indacene-1,3,5,7(2H,6H)-tetraone: A Phosphorus Analogue of Aromatic Diimides with

the Minimal Core Exhibiting High Electron-accepting Ability” Takeda, Y.*; Nishida, T.; Minakata, S.*

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Chem.—Eur. J. 2014, 20, 10266–10270. [DOI: 10.1002/chem.201403735] http://onlinelibrary.wiley.com/doi/10.1002/chem.201403735/abstract

15. “Pd/NHC-Catalyzed Enantiospecific and Regioselective Suzuki-Miyaura Arylation of 2-Arylaziridines:

Synthesis of Enantioenriched 2-Arylphenethylamine Derivatives” Takeda, Y.*; Ikeda, Y.; Kuroda, A.; Tanaka, S.; Minakata, S.* J. Am. Chem. Soc. 2014, 136, 8544–8547. [DOI: 10.1021/ja5039616] http://pubs.acs.org/doi/abs/10.1021/ja5039616 Highlighted in “Some Items of Interest to Process R&D Chemists and Engineers” (Org. Process Res. Dev. 2014, 18, 922–927.)

16. “Oxidative Dimerization of (Hetero)aromatic Amines Utilizing t-BuOI Leading to (Hetero)aromatic Azo Compounds: Scope and Mechanistic Studies” Okumura, S.; Lin, C.-H.; Takeda, Y.*; Minakata, S.* J. Org. Chem. 2013, 78, 12090–12105. [DOI: 10.1021/jo402120w] http://pubs.acs.org/doi/abs/10.1021/jo402120w

17. “PCy3-Catalyzed Ring-Expansion of Aziridinofullerenes with CO2 and Aryl Isocyanates: Evidence for a Two-Consecutive Nucleophilic Substitution Pathway on the Fullerene Cage”

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Takeda, Y.; Kawai, H.; Minakata, S.* Chem.—Eur. J. 2013, 19, 13479–13483. [DOI: 10.1002/chem.201301617] http://onlinelibrary.wiley.com/doi/10.1002/chem.201301617/abstract

18. “Hypervalent Iodine(III)-Induced Oxidative [4+2] Annulation of o-Phenylenediamines and Electron-Deficient Alkynes: Direct Synthesis of Quinoxalines from Alkyne Substrates under Metal-Free Conditions” Okumura, S.; Takeda, Y.*; Kiyokawa, K.; Minakata, S.* Chem. Commun. 2013, 49, 9266–9268. [DOI: 10.1039/C3CC45469J] http://pubs.rsc.org/en/content/articlelanding/2013/cc/c3cc45469j an open-access article Highlighted in Synfacts 2014, 38.

19. “A Practical Synthesis of Azobenzenes through Oxidative Dimerization of Aromatic Amines Using

tert-Butyl Hypoiodite” Takeda, Y.; Okumura, S.; Minakata, S.* Synthesis 2013, 45, 1029–1033. [DOI: 10.1055/s-0032-1318388] https://www.thieme-connect.com/ejournals/abstract/10.1055/s-0032-1318388 Invited as a “PSP(Practical Synthetic Procedures)-article”.

20. “Straightforward and Versatile Synthesis of Fullerooxazoles from C

60 and Carboxamides through Radical Reactions under Mild Conditions” Takeda, Y.; Enokijima, S.; Nagamachi, T.; Nakayama, K.; Minakata, S.*

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Asian J. Org. Chem. 2013, 2, 91–97. [DOI: 10.1002/ajoc.201200114] http://onlinelibrary.wiley.com/doi/10.1002/ajoc.201200114/abstract Selected as the “Cover Picture” of the issue (Jan 10, 2013). Highlighted in ChemistryViews as a “Noteworthy Paper” (Oct 23, 2012). Highlighted in “ワイリー・サイエンスカフェ” (Oct 23, 2012). Ranked as the most-accessed article for February, March, April and May 2013 in a row.

21. “An Inclusion Complex of C60 with Organosilylated �-Cyclodextrin: Drastic Enhancement of Apparent Solubility of C60 in Nonpolar and Weakly Polar Organic Solvents” Takeda, Y.; Nagamachi, T.; Nishikori, K.; Minakata, S.* Asian J. Org. Chem. 2013, 2, 69–73. [DOI: 10.1002/ajoc.201200160] http://onlinelibrary.wiley.com/doi/10.1002/ajoc.201200160/abstract Highlighted in ChemistryViews as a “Noteworthy Paper” (Jan 7, 2013). Highlighted in “ワイリー・サイエンスカフェ” (Jan 7, 2013). Highlighted in “Angewandte Spotlights” (Angew. Chem. Int. Ed. 2013, 52, 796–798.) Ranked as one of the most-accessed articles (6th) for February 2013.

22. “Transition-metal-free Benzylic C–H Bond Intermolecular Amination Utilizing Chloramine-T and I2” Takeda, Y.; Hayakawa, J.; Yano, K.; Minakata, S.* Chem. Lett. 2012, 41, 1672–1674. [DOI: 10.12461/cl.2012.1672] https://www.jstage.jst.go.jp/article/cl/41/12/41_CL-120942/_article

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23. “Nucleophilic Ring-Opening of N-o-Nosylaziridines with N-Chloro-N-Sodiocarbamate: Facile Preparation of Differentially Protected Vicinal Diamines” Takeda, Y.; Murakami, Y.; Ikeda, Y.; Minakata, S.* Asian J. Org. Chem. 2012, 1, 226–230. [DOI: 10.1002/ajoc.20120070] http://onlinelibrary.wiley.com/doi/10.1002/ajoc.201200070/abstract

24. “Cyclizative Atmospheric CO2 Fixation by Unsaturated Amines with t-BuOI Leading to Cyclic

Carbamates” Takeda, Y.; Okumura, S.; Tone, S.; Sasaki, I.; Minakata, S.* Org. Lett. 2012, 14, 4874–4877. [DOI: 10.1021/ol302201q] http://pubs.acs.org/doi/abs/10.1021/ol302201q Highlighted in “Noteworthy Chemistry” (October 1, 2012).

25. “Selective Functionalization of Fullerenes with N,N-Dihalosulfonamides as an N1 Unit: Versatile Syntheses of Aza[60]fulleroids and Aziridino[60]fullerenes and their Application to Photovoltaic Cells” Nagamachi, T.; Takeda, Y.; Nakayama, K.; Minakata, S.* Chem.—Eur. J. 2012, 18, 12035–12045. [DOI: 10.1002/chem.201201680] http://onlinelibrary.wiley.com/doi/10.1002/chem.201201680/abstract

26. “An Air-stable Low-Bandgap n-Type Organic Polymer Semiconductor Exhibiting Selective Solubility in

Perfluorinated Solvents” Takeda, Y.; Andrew, T. L.; Lobez, J. M.; Mork, A. J.; Swager, T. M.* Angew. Chem., Int. Ed. 2012, 51, 9042–9046. [DOI: 10.1002/anie.201204066] http://onlinelibrary.wiley.com/doi/10.1002/anie.201204066/abstract

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27. “Oxidative Dimerization of Aromatic Amines Using t-BuOI: Entry to Unsymmetric Aromatic Azo Compounds” Takeda, Y.; Okumura, S.; Minakata, S.* Angew. Chem., Int. Ed. 2012, 51, 7804–7808. [DOI: 10.1002/anie.201202786] Selected as a “Hot Paper” (July 4, 2012). Highlighted in “ワイリー・サイエンスカフェ” (July 4, 2012). Highlighted in “Noteworthy Chemistry” (August 27, 2012). Highlighted in Synfacts 2012, 1091. http://onlinelibrary.wiley.com/doi/10.1002/anie.201202786/abstract

28. “1,4-Bis(diarylamino)-2,5-bis(4-cyanophenylethenyl)benzenes: Fluorophores Exhibiting Efficient Red and Near-Infrared Emissions in Solid State” Shimizu, M.*; Kaki, R.; Takeda, Y.; Hiyama, T.; Nagai, N.; Yamagishi, H.; Furutani, H. Angew. Chem., Int. Ed. 2012, 51, 4095–4099. [DOI: 10.1002/anie.201108943] http://onlinelibrary.wiley.com/doi/10.1002/anie.201108943/abstract

29. “Mechanistic Study on the Palladium-catalyzed Stereoselective Cross-coupling Reaction of 1,1-Dibromo-3,3,3-trifluoro-2-tosyloxypropene” Shimizu, M.*; Takeda, Y.; Hiyama, T. Bull. Chem. Soc. Jpn. 2011, 84, 1339–1341. [DOI: 10.1246/bcsj.20110240] http://www.jstage.jst.go.jp/article/bcsj/advpub/0/advpub_1111210383/_article Chosen as a BCSJ “Selected Papers” of the issue (December, 2011).

Dateiname: Z202786E Pagina: 6Pfad: L:/daten/Verlage/VCH/ACH/hefte/pool/ Seite: 6 te von 6Status Neusatz Umfang (Seiten): 6Datum: 26 KW., 21. Juni 2012 (Donnerstag) Zeit: 10:46:39 Uhr

CommunicationsSynthetic Methods

Y. Takeda, S. Okumura,S. Minakata* &&&&—&&&&

Oxidative Dimerization of AromaticAmines using tBuOI: Entry toUnsymmetric Aromatic Azo Compounds

It’s all the hype : An oxidative dimeriza-tion reaction of aromatic amines utilizingtert-butyl hypoiodite (tBuOI) under mildreaction conditions leads to aromatic azocompounds (see scheme). The method

allows access to unsymmetric aromaticazo compounds, which are difficult toprepare by conventional synthetic meth-ods, in a selective manner.&picture wastoo big&

Synthesemethoden

Y. Takeda, S. Okumura,S. Minakata* &&&&—&&&&

Oxidative Dimerization of AromaticAmines using tBuOI: Entry toUnsymmetric Aromatic Azo Compounds

Hypo hilft : Eine oxidative Dimerisierungvon aromatischen Aminen mit tert-Butyl-hypoiodit (tBuOI) unter milden Reak-tionsbedingungen f!hrt zu aromatischenAzoverbindungen (siehe Schema). Die

Reaktion bietet selektiven Zugang zuunsymmetrischen aromatischen Azover-bindungen, die durch herkçmmlicheSynthesemethoden schwer herzustellensind.

.AngewandteCommunications

6 www.angewandte.org ! 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Angew. Chem. Int. Ed. 2012, 51, 1 – 6! !

These are not the final page numbers!

1 12 23 34 45 56 67 78 89 9

10 1011 1112 1213 1314 1415 1516 1617 1718 1819 1920 2021 2122 2223 2324 2425 2526 2627 2728 2829 2930 3031 3132 3233 3334 3435 3536 3637 3738 3839 3940 4041 4142 4243 4344 4445 4546 4647 4748 4849 4950 5051 5152 5253 5354 5455 5556 5657 5758 5859 59

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30. “Twisting Strategy Applied to N,N-Diorganoquinacridones Leads to Organic Chromophores Exhibiting Efficient Solid-state Fluorescence” Shimizu, M.*; Asai, Y.; Takeda, Y.; Yamatani, A.; Hiyama, T. Tetrahedron Lett. 2011, 52, 4084–4089. [DOI: 10.1016/j.tetlet.2011.05.087] http://www.sciencedirect.com/science/article/pii/S004040391100846X

31. “Synthesis and Photophysical Properties of Dimethoxybis(3,3,3-trifluoropropen-1-yl)benzenes: Compact Chromophores Exhibiting Violet Fluorescence in the Solid State” Shimizu, M.*; Takeda, Y.; Higashi, M.; Hiyama, T. Chem.—Asian J. 2011, 6, 2536–2544. [DOI: 10.1002/asia.201100176] http://onlinelibrary.wiley.com/doi/10.1002/asia.201100176/abstract

32. “Diastereoselective Aziridination of Chiral Electron-deficient Olefins with N-Chloro-N-sodio- carbamates Catalyzed by Chiral Quaternary Ammonium Salts” Murakami, Y.; Takeda, Y.; Minakata, S.* J. Org. Chem. 2011, 76, 6277–6285. [DOI: 10.1021/jo2010632] http://pubs.acs.org/doi/abs/10.1021/jo2010632

33. “Generation of Nitrile Oxides from Oximes Using t-BuOI and Their Cycloaddition”

BULLETINOF THE

CHEMICAL SOCIETY OF JAPAN

Selected PapersMechanistic Study of the Palladium-CatalyzedStereoselective Cross-Coupling Reaction of1,1-Dibromo-3,3,3-trifluoro-2-tosyloxypropene

We prepared a Pd complex by the oxidative addition of 1,1-dibromo-3,3,3-trifl uoro-2-tosyloxypropene to [Pd(PPh3)4 ]. The atomic distance between Pd andF in the complex was 2.95 ¡, which was shorter than the sum of the van derWaals radii. Based on NMR studies of the oxidative addition step, a catalyticcycle for the Pd-catalyzed cross-coupling reaction of the propene is proposed,with the Pd­F interaction as the key element for the Z-selectivity.

TsO

F3C Ph

BrTsO

Pd

Br

FFF

Br

PPh 3

Ph 3 P

TsO

F3C Br

Br

[Pd(PPh 3 )4 ](5 mol%) PhB(OH)2

Z /E = ca. 9 : 1

aq. Cs2 CO3toluene

Masaki Shimizu,* Youhei Takeda,and Tamejiro Hiyama

Bull. Chem. Soc. Jpn.1–3

BULLETIN 2011/11/16 20110240 (OB)

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Minakata, S.*; Okumura, S.; Nagamachi, T.; Takeda, Y. Org. Lett. 2011, 13, 2966–2969. [DOI: 10.1021/ol2010616] http://pubs.acs.org/doi/abs/10.1021/ol2010616 Ranked in “the top 20 most downloaded articles” of May 2011.

34. “New Preparation and Synthetic Reactions of 3,3,3-Trifluoropropynyllithium, -borate and -stannane: Facile Synthesis of Trifluoromethylated Allenes, Arylacetylenes and Enynes” Shimizu, M.*; Higashi, M.; Takeda, Y.; Murai, M.; Jiang, G.; Asai, Y.; Nakao, Y.; Shirakawa, E.; Hiyama, T. Future Med. Chem. 2009, 1, 921–945. [DOI: 10.4155/fmc.09.69] http://www.future-science.com/doi/abs/10.4155/fmc.09.69

35. “1,4-Bis(alkenyl)-2,5-dipiperidinobenzenes: Minimal Fluorophores Exhibiting Highly Efficient Emission in the Solid State” Shimizu, M.*; Takeda, Y.; Higashi, M.; Hiyama, T. Angew. Chem., Int. Ed. 2009, 48, 3653–3656. [DOI: 10.1002/anie.200900963] http://onlinelibrary.wiley.com/doi/10.1002/anie.200900963/abstract Highlighted in “Noteworthy Chemistry” May 4, 2009. Highlighted in Synfacts 2009, 734. Highlighted in Biotechnol. J. 2009, 4, 791–792.

36. “Preparation, Structure, and Diels–Alder Reaction of Phenyl(trifluoromethanesulfonate)-

(3,3,3-trifluoropropynyl)-�3-iodane” Shimizu, M.*; Takeda, Y.; Hiyama, T. Chem. Lett. 2008, 37, 1304–1305. [DOI: 10.1246/cl.2008.1304] http://www.jstage.jst.go.jp/article/cl/37/12/37_1304/_article

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37. “Stereoselective Preparation and Cope Rearrangement of 2-CF3-Cis-2,3-bis(alkenyl)oxiranes: A Facile

Route to 2-CF3-Substituted Oxacycles” Shimizu, M.*; Fujimoto, T.; Liu, X.; Takeda, Y.; Hiyama, T. Heterocycles 2008, 76, 329–351. (Professor Ryoji Noyori’s Special Issues) [DOI: 10.3987/COM-08-S(N)13] http://www.heterocycles.jp/library/abstract.php?article=3162

38. “Straightforward Synthesis of CF3-Substituted Triarylethenes by Stereoselective Threefold Cross-coupling Reactions” Takeda, Y.; Shimizu, M.*; Hiyama, T. Angew. Chem., Int. Ed. 2007, 46, 8659–8661. [DOI: 10.1002/anie.200703759] http://onlinelibrary.wiley.com/doi/10.1002/anie.200703759/abstract Highlighted in Synfacts 2008, 172.

39. “Novel Generation of 3,3,3-Trifluoropropynyllithium and Transformation of the Carbonyl Adducts to Trifluoromethyl-substituted Allenes” Shimizu, M.*; Higashi, M.; Takeda, Y.; Jiang, G.; Murai, M.; Hiyama, T. Synlett 2007, 1163–1165. (Cluster issue: Invited Paper) [DOI: 10.1055/s-2007-977422] https://www.thieme-connect.com/ejournals/abstract/synlett/doi/10.1055/s-2007-977422

40. “Facile Synthesis of Trifluoromethyl-substituted Enynes: Remarkable Reactivity and Stereoselectivity of Tributyl(3,3,3-trifluoropropynyl)stannane in Carbostannylation of Alkynes” Shimizu, M.*; Jiang, G.; Murai, M.; Takeda, Y.; Nakao, Y.; Hiyama, T.; Shirakawa, E. Chem. Lett. 2005, 34, 1700–1701. [DOI: 10.1246/cl.2005.1700] http://www.jstage.jst.go.jp/article/cl/34/12/34_1700/_article

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Reviews and Accounts 1. “Creation of Novel Functional Aza-Containing p-Conjugated Molecules Based on the Development of

Novel Oxidative Transformations of Aromatic Amines” (accounts) Takeda, Y. J. Synth. Org. Chem., Jpn. 2016, 74, 955–964.

Conference Proceedings 1. “Design and Synthesis of Highly Emissive Solid Fluorophores”

Shimizu, M.; Mochida, K.; Takeda, Y.; Asai, Y.; Hiyama, T. Proceedings of SPIE 2009, 7415, 74151G. [DOI: 10.1117/12.825442] http://spiedigitallibrary.org/proceedings/resource/2/psisdg/7415/1/74151G_1

Patents 1. “Compositions, Methods, and Systems Comprising Fluorous-soluble Polymers”

Swager, T. M.; Lim, J.; Takeda, Y. U.S. Pat. Appl. Serial No.: 13/213,647 (08/19/2011) Books 1. “イミノフラーレンの選択的合成反応“武田洋平，南方聖司

フラーレン誘導体・内包技術の最前線（松尾 豊監修），シーエムシー出版，2014，第 2章 4節．

2. “N1 Unit Transfer Reaction to C–C Double Bonds” Minakata, S.; Takeda, Y.; Kiyokawa, K. In Methods and Applications of Cycloaddition Reactions in Organic Syntheses, Nishiwaki, N. Ed.; Wiley-VCH: 2013; Chapter 2.

3. “Heterocyclic Reagents Containing Nitrogen-Halogen Bond: Recent Applications” Minakata, S.; Takeda, Y.; Hayakawa, J. In Halogenated Heterocycles: Synthesis, Application and Environment, Topics in Heterocyclic Chemistry Series, Vol. 27; Iskra, J. Ed.; Springer: Berlin, 2012; Chapter 5, pp 139–183.

Contribution Articles and Others 1. “PROFILE: Early Excellence in Physical Organic Chemistry”

Takeda, Y. J. Phys. Org. Chem. 2016, 29, 116–117. [DOI: 10.1002/poc.3528] http://onlinelibrary.wiley.com/doi/10.1002/poc.3528/full

2. “有機機能性材料を指向した新規リン含有π共役分子の創製” 武田洋平 生産と技術 技術解説 平成 28年 新春号（68巻 1号）pp27–30. http://seisan.server-shared.com/681/681-27.pdf

3. “ハロゲン結合，結晶工学からの脱却〜有機合成的展開を求めて” 武田洋平，南方聖司 月刊化学 2013, 68(8), 68–69.

R1 R2

+

R1

Bu3Sn

R2

CF3Pd2(dba)3 (1 mol%)t-Bu3P (2 mo%)

toluener.t.

Bu3Sn CF3

single stereoisomer !

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4. “MIT 化学科 Swager研究室での研究生活” 武田洋平 Organometallic News, 2013, 38–39.

5. “マルコフニコフ則を覆す？！〜逐次的触媒反応によるアルケンの位置選択的水和反応〜” Takeda, Y. Kagaku 2012, 67(1), 65.

6. “Cheap Precursor for Arynes” Swager, T. M.; Takeda, Y. Synfacts 2011, 154. [DOI: 10.1055/s-0030-1259251] https://www.thieme-connect.com/ejournals/abstract/synfacts/doi/10.1055/s-0030-1259251

7. “Perfluorobenzene Captures Fullerene” Swager, T. M.; Takeda, Y. Synfacts 2011, 148. [DOI: 10.1055/s-0030-1259252] https://www.thieme-connect.com/ejournals/abstract/synfacts/doi/10.1055/s-0030-1259252

8. “A New Method for Hypersilyl Aromatic Compounds” Swager, T. M.; Takeda, Y. Synfacts 2011, 34. [DOI: 10.1055/s-0030-1259153] https://www.thieme-connect.com/ejournals/abstract/synfacts/doi/10.1055/s-0030-1259153

9. “A Versatile Synthetic Method for Silaindenes” Swager, T. M.; Takeda, Y. Synfacts 2011, 31. [DOI: 10.1055/s-0030-1259152] https://www.thieme-connect.com/ejournals/abstract/synfacts/doi/10.1055/s-0030-1259152

10. “A New Functionalization Method of SWCNTs through Cycloaddition” Swager, T. M.; Takeda, Y. Synfacts 2010, 1361. [DOI: 10.1055/s-0030-1258936] https://www.thieme-connect.com/ejournals/abstract/synfacts/doi/10.1055/s-0030-1258936

11. “Highly Selective Synthesis of Dibenzo[a,c]cyclooctatetraenes” Swager, T. M.; Takeda, Y. Syntfacts 2010, 1360. [DOI: 10.1055/s-0030-1258937] https://www.thieme-connect.com/ejournals/abstract/synfacts/doi/10.1055/s-0030-1258937

12. “Swollen-up Molecules by Fragmentation” Swager, T. M.; Takeda, Y. Synfacts 2010, 1246. [DOI: 10.1055/s-0030-1258734] https://www.thieme-connect.com/ejournals/abstract/synfacts/doi/10.1055/s-0030-1258734

13. “Interplay of Heteroatoms” Swager, T. M.; Takeda, Y. Synfacts 2010, 1241. [DOI: 10.1055/s-0030-1258735] https://www.thieme-connect.com/ejournals/abstract/synfacts/doi/10.1055/s-0030-1258735

14. “Renaissance of Diels-Alder Reaction of Borylalkenes” Swager, T. M.; Takeda, Y. Synfacts 2010, 1140. [DOI: 10.1055/s-0030-1258629] https://www.thieme-connect.com/ejournals/abstract/synfacts/doi/10.1055/s-0030-1258629

15. “Break Symmetry, and Get Benefits” Swager, T. M.; Takeda, Y. Synfacts 2010, 1137. [DOI: 10.1055/s-0030-1258640] https://www.thieme-connect.com/ejournals/abstract/synfacts/doi/10.1055/s-0030-1258640

16. “Low Band Gap Polymers Having Multi-Fused Heterocycles” Swager, T. M.; Takeda, Y. Synfacts 2010, 1010. [DOI: 10.1055/s-0030-1257923] https://www.thieme-connect.com/ejournals/abstract/synfacts/doi/10.1055/s-0030-1257923

17. “Electrical Stimuli Induced Reversible Self-Assembly” Swager, T. M.; Takeda, Y. Synfacts 2010, 1009. [DOI: 10.1055/s-0030-1257917] https://www.thieme-connect.com/ejournals/abstract/synfacts/doi/10.1055/s-0030-1257917