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    Use of Gas Concentrations Ratios to Interpret LTC

    Dissolved Gas Data

    Fredi Jakob, Karl Jakob, Simon JonesWeidmann-ACTI

    Rick Youngblood

    Cinergy Corporation

    I. Introduction

    Fifteen years ago a common belief was that dissolved gas analysis, DGA, was not

    applicable to oil circuit breakers, OCBs or load tap changers, LTCs. This assumption

    was based on the idea that the gases produced during normal operation of an OCB or

    LTC would be more significant than gases produced by a fault process such as contact

    overheating.

    The association of certain fault gases with fault types or key gas DGA interpretation

    method is summarized in Table 1. These empirical correlations were developed for main

    tanks of transformers but are applicable to any type of oil filled electrical apparatus. This

    concept led investigators such as Youngblood1to theorize that specific fault gases are

    formed when arcing under oil occurs, which is a normal process in an LTC. Overheating,

    an abnormal process in an LTC, produces different key gasses. Specifically, he

    suggested that acetylene and hydrogen are generated during the normal arcing process

    and the hydrocarbons, methane, ethane and especially ethylene are generated when

    overheating occurs in a problem LTC. These three hydrocarbons are often called hot

    metal gases since they are produced when a heated conductor is in contact with mineral

    oil based dielectric fluid.

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    Table 1. Key Fault Gasses.

    II. Data Interpretation.

    A. Concept

    The interpretation of DGA data for transformers, LTCs and OCBs is empirical in

    nature. The development of interpretation protocols for OCBs and LTCs parallels the

    development of DGA diagnostics for the main tanks of transformers. Key gases

    associated with heating problems are methane, ethane and ethylene. These gases are

    listed by Halstead2in order of increasing energy required for their production. Initially

    Youngblood ignored the levels of arcing gases, acetylene and hydrogen that developed

    whenever an LTC operated. Subsequent work by Youngblood5indicated that arcing gases

    are also diagnostically significant. For example, increased acetylene levels were often

    followed by increased heating gases. The increased acetylene is due to changes in the arc

    duration and/or characteristics as the contacts are eroded or covered with carbon.

    The next step in the development of diagnostic protocols for LTCs was the empirical

    determination of normal or threshold values. The gas retention rate in an LTC is very

    dependent on breathing configuration, so this is a major factor in determining threshold

    Cellulose insulation degradationCarbon OxidesArcingAcetylene

    Hot Metal GassesEthylene, Ethane, Methane

    Partial Discharge,Heating ArcingHydrogen

    IndicationGasses

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    levels. Free breathing LTCs rapidly lose gases to the environment while sealed LTCs

    retain most of the gas produced.

    Threshold levels have been determined for specific models and types of LTCs by

    Doble3and Baker

    4. Generic levels have been set by Youngblood

    5, and are useful for

    specific LTC models where the threshold values have not yet been determined. Fault gas

    ratios should be considered applicable for unit evaluation only when threshold values are

    reached.

    B. Fault Gas Concentration Ratios.

    1. Normal Operation

    Arcing, which generates very high temperatures, occurs with each switching

    operation in an LTC. Arcing produces acetylene and hydrogen. When arcing gases are

    being produced, heating gases are also produced since the oil temperature varies with

    distance from the arcing contacts. At the lower oil temperatures, heating gases are

    produced rather than acetylene.

    If one accepts this hypothesis, one would expect that the ratios of heating to arcing

    gases in a problem free unit would remain fairly constant with operational count. Since

    the contact surface is being eroded and additional deposits are being formed with each

    operation, these ratios will predictably increase slightly with operation count. The data

    presented in a paper by Duval5supports this hypothesis. Note that all of the significant

    ratios in these problem free units are well below those found in a LTC that has developed

    a heating or other problem.

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    2. Heating Problems

    Initially a resistive film develops on contacts, which results in an increase in contact

    resistance, increased heating and an increase in heating gas concentrations. Since more

    heating gases are now being produced, the ratio of heating to arcing gases increases. This

    change in gas concentrations and gas concentration ratios indicates problems. As the

    resistance increases, the amount of energy dissipated increases. The ratios of ethane to

    methane and ethylene to ethane both increase with increasing temperature. Thus these

    two heating gas ratios should also reflect increased contact resistance and heating.

    Table 2. Gas Formation as a Function of Operation Count. (Duval

    5

    )Operations: 500 3600 49000 Gas produced/operation

    Gas/500 Gas/3600 Gas/49000

    Hydrogen 6870 12125 14320 13.74 3.37 0.29

    Methane 1028 5386 10740 2.05 1.50 0.22

    Acetylene 5500 35420 53670 11.00 9.84 1.10

    Ethylene 900 6400 35839 1.80 1.78 0.73

    Ethane 79 400 3944 0.16 0.11 0.08

    *Note: Some gas is always lost with time. Therefore, the gas concentration per

    operation is expected to decrease with operation count. Duval did not provide breathing

    configurations for this data.

    Heating to Arcing Ratios

    HydrogenAcetylene

    Ethylene

    +

    Acetylene

    Ethylene

    HydrogenAcetylene

    EthaneEthyleneMethane

    +

    ++

    Temperature Dependant Ratios

    ethane

    Ethane

    Ethane

    Ethylene

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    C. Application of Gas Concentration Ratios.

    As is the case with main tank DGA, ratios are not valid unless at least one of the

    fault gases exceeds its threshold value. Threshold values used by Weidmann-ACTI are

    model specific, whenever this data is available. If model specific data is not available,

    we use the monthly watch levels developed by Youngblood5as our threshold values.

    Normal values we use for the ratios represent the 90th

    percentile of fault gas

    concentrations from a very large number of DGA results (~2500 units). These 90th

    percentile values which are listed in Table 3are generic and do not take into account the

    difference in gassing rates of specific units. Ratios are, as expected, model specific.

    Table 4lists the ratios calculated for a Westinghouse LTC, which according to Bakers5

    threshold levels requires attention.

    Table 3. Generic 90th

    Percentile Fault Gas Ratios.

    Note the difference between these model specific ratios listed in Table 4, and the

    generic values which are listed in Table 3.

    R1 R2 R3 R4 R5

    Acetylene

    Ethylene

    HydrogenAcetylene

    Ethylene

    +

    HydrogenAcetylene

    MethaneEthaneEthylene

    +

    ++

    Methane

    Ethane

    Ethane

    Ethylene

    0.3378 0.5000 0.9157

    0.2067

    4.83

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    Table 4. Unit Specific Ratio Comparison.WESTINGHOUSE LTC UTT

    Ethylene Ethane Methane Acetylene Hydrogen CO CO2

    LT3 Gas

    Level

    3,000 250 1,000 5,000 5,000 3,000 10,000

    Ratio 1 Ratio 2 Ratio 3 Ratio 4 Ratio 5

    0.60 0.30 0.43 0.25 12

    McGRAW EDISON LTC 550-BL

    LT3

    2,000 400 400 400 500 1,000 3,000

    Ratio 1 Ratio 2 Ratio 3 Ratio 4 Ratio 5

    5.00 2.22 3.11 1.00 5

    * LT3 is Bakers designation of a unit requiring inspection.

    III. Case Studies

    Two case studies for Cinergy data are presented below. This data, from Cinergys

    initial work, was interpreted without consideration of fault gas concentration ratios. Case

    history II is of particular interest since serious damage occurred in the six month interval

    between scheduled tests. The data indicates that critical gas ratios such as the ratio of

    ethylene to acetylene doubled from March 92 to Feb 93. This points out the necessity

    of trending both ratios and gas concentrations. We believe that the extent of the coking

    would have been less severe if the unit had been inspected in Feb 93 based on the

    doubling of the significant ratios, rather than to have waited for six additional months.

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    IV. Future Work

    The empirical analysis of DGA data for LTCs is well developed. Gas

    concentration levels and gas concentration ratios can differentiate between normal and

    problem units. We believe that both the concentration and ratio values will work best if

    they are model specific. The compilation of these values requires user feedback on

    problem units. Trending of both the gas concentrations and ratios is always the best

    method to identify incipient problems.

    Another concept under investigation is normalization of fault gas data. We

    believe that during normal switching operations, the ratio of ethylene to acetylene is

    fixed. This ratio should remain constant for different numbers of operations.

    Furthermore, since these two gases have approximately the same solubility in mineral oil

    and approximately the same escape rates from the oil, the ratios should remain fairly

    constant even for free breathing units. For example if the concentration of both ethylene

    and acetylene are 100 ppm then the ratio is one. If a heating problem is superimposed on

    the normal arcing process and the gas levels are 175 ppm for ethylene and 150 ppm for

    acetylene there would be an additional 25 ppm of ethylene due to the heating problem.

    One could thus normalize our results using a ratio of:

    acetylene

    arcingnormalduringproducedethyleneethylenetotal

    arcingtodueacetylene

    heatingtodueethylene )____(_

    )__(

    )__( =

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    Date Comments C2H2 CH4 C2H6 C2H4 H2

    8/31/92 Removed from Service 8527 3279 1135 9606 9083

    12/17/93 Post Repair 501 387 16 375 2883

    5/1/94 Normal 541 534 9 313 3800

    8/17/95 placed on 6 month watch 648 590 52 836 3995

    LTC Case Study I

    Westinghouse UTT-A 138KV x 69KV x 13.8KV Sealed

    Date Comments Ratio 1 Ratio 2 Ratio 3 Ratio 4 Ratio 5

    8/31/1992 Removed from Service 1.13 0.55 0.8 0.35 0.15

    12/17/1993 Post Repair 0.75 0.11 0.23 - -5/1/1994 Normal 0.58 0.07 0.2 - -

    8/17/1995 Placed on 6 Month Watch 1.29 0.18 0.32 0.06 0.09

    C2H4 / C2H6Ratio5

    C2H6 / CH4Ratio4

    CH4 + C2H4 + C2H6 / C2H2 + H2Ratio3

    C2H4 / C2H2 + H2Ratio2

    C2H4 / C2H2Ratio 1

    31-Aug-92Based on the DGA result this unit was immediately removed from service. The fault

    was determined to be due to contact misalignment.

    17-Dec-93

    Typical levels of gasses for a sealed, unit, annual monitoring was indicated.

    1-May-94

    Again gas levels are typical for a sealed unit, annual monitoring continued.

    17-August-95

    Again the Gas levels are indicative on normal operation, however the fifty percent increase

    in the level of Acetylene indicated increased surveillance.

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    12-Mar-92

    This unit indicated the early stages of mechanical difficulties. While the

    Acetylene and Hydrogen levels are elevated, the level of Ethylene is less than 100

    ppm. Indicating a continuance of annual monitoring

    LTC Case Study II

    Federal Pacific TC-25 69KV x 12KV 20MVA Desiccant Breather

    Date Comments C2H2 CH4 C2H6 C2H4 H2

    3/12/1992 Annual DGA Test Cycle 589 60 2 89 144

    2/1/1993 6 Month Test Cycle 1625 342 70 534 3099

    8/12/1993 Thermal Runaway 1633 53434 55535 253024 2217

    Date Comments Ratio 1 Ratio 2 Ratio 3 Ratio 4 Ratio 5

    3/12/92 Annual DGA Test Cycle 0.15 0.12 0.21 - 0.15

    2/1/93 6 Month Test Cycle 0.32 0.11 0.2 0.21 0.33

    8/12/93 Thermal Runaway 155 66 94 1.03 155

    C2H4 / C2H6Ratio5

    C2H6 / CH4Ratio4

    CH4 + C2H4 + C2H6 / C2H2 + H2Ratio3

    C2H4 / C2H2 + H2Ratio2

    C2H4 / C2H2Ratio 1

    1-Feb-93

    At this time the unit was placed on a 6 month monitoring, due to the elevated,

    Acetylene, Hydrogen, and Ethylene levels. At 534 ppm Ethylene immediate

    removal from service was not indicated.

    12-Aug-96

    Too late, by August, the unit was in thermal runaway. As indicated by the extremely

    high level of Ethylene, at 253,024 ppm. Repairs included a Tap Shaft board, Slip

    Rings, and a New Reversing Switch assembly.

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    References:

    1. Youngblood, R., Jacob, F., Haupert, T.J. Application of DGA to Detection of HotSpots in Load Tap-Changers, Minutes of the Sixtieth Annual International

    Conference of Doble Clients, 1993, Sec. 6-4.1.

    2. Halstead, W. D., A Thermodynamic Assessment of the Formation of Gaseous

    Hydrocarbons in Faulty Transformers,Journal of the Institute of Petroleum, Vol. 59,

    Sept. 1959, pp. 239-241.

    3. Doble Client Transformer Committee Subcommittee Report on Transformer Load

    Tap Changer Dissolved Gas Analysis September 24, 2001.

    4. Baker, Charles. Personal correspondence. 2002.

    5. Youngblood, R., Baker, C., Jacob, F., Perjanik, N. Application of Dissolved GasAnalysis to Load Tap Changers.

    6. Duval, Michel. A Review of Faults Detectable by gas-in-Oil Analysis inTransformers. IEEE Electrical Insulation Magazine May/June 2002, Vol. 18 no. 3,

    pp. 8-17.