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Isolation: J. Org. Chem. 2001, 5901; Bioorg. Med. Chem. 2006, 5995. lyconadin A is weakly cytotoxic (IC50 0.46 mg/mL against murine lymphoma) lyconadin B is not cytotoxic Lycopodium “creeping cedar”

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  • Isolation: J. Org. Chem. 2001, 5901; Bioorg. Med. Chem. 2006, 5995. lyconadin A is weakly cytotoxic (IC50 0.46 mg/mL against murine lymphoma) lyconadin B is not cytotoxic

    Lycopodium “creeping cedar”

  • JACS 2013, ASAP; JACS 2011, 418

  • Mechanism? Class (name) of rxn

  • Hendrick J. Prins

    A unique gold-catalyzed alkynyl Prins

  • Ring expansion

    Danheiser TL 1981 4205

  • Formation of 10: conrotatory or disrotatory…what would Fukui say?

  • Mechanism? Regiochemistry? Explain disrotatory ring opening.

    Buchner ring expansion (a modern take – Synlett 2011, 1449)

  • Reagents??

  • Ac2O, CSA, tol, reflux

    Mechanism?, Name?

    Mechanism?

  • Mechanism?


AgNO 3 ( aq ) + NaCl( aq ) AgCl( s ) + NaNO 3 ( aq )

Section 14.1 Nature of Acids and Bases Arrhenius Definition n Acids produce hydrogen ions in aqueous solution. –HCl (aq) H + (aq) + Cl - (aq) n Bases

CHEMISTRY MULTIPLE CHOICE QUESTIONS · NaOH(aq) C12(aq) NaCN (in aqueous ethanol) NaOH(aq) K2Cr207(aq) NaOH(aq) dilute H2S04 C02 Halogenoalkanes react with aqueous alkali. pathway

1 Solubility Equilibria Dissolution M m X x (s) m M n+ (aq) + x X y- (aq) Precipitation m M n+ (aq) + x X y- (aq) M m X x (s) For a dissolution process,

1.Which change in oxidation number represents oxidation? 9 ... · A)Sn2+(aq) ®Sn4+(aq) B)Sn2+(aq) ® Sn(s) C)Sn4+(aq) ® Sn2+(aq) D)Sn4+(aq) ® Sn(s) E)Sn(s) ® Sn2–(aq) 1.Which

Writing Net Ionic Equations - PC\|MACimages.pcmac.org/SiSFiles/Schools/SC/Georgetown/WaccamawHigh… · AgC1(s) + Na+(aq) + N03-(aq) Net Ionic Equations AgN03(aq) + NaC1(aq) + NaN03(aq)

A My n me is Wh t’s your n me?

Installation Instructions - Aquasana Water Filters › assets › AQ-5100-5200-5300_Install.pdfInstallation Instructions AQ-5100, AQ-5200 & AQ-5300 Under Counter Water Filter Single

Fe 3+ (aq) + SCN - (aq) Fe(SCN) 2+ (aq) colorless

C C C A | M o n d aq

Sodium hydroxide and hydrobromic acid. NaOH (aq) +HBr (aq) NaBr (aq) +H 2 O (l)

DIGITAL.CSIC: Homedigital.csic.es/bitstream/10261/24478/1/SAD_DIG_ILC... · 2019-02-19 · 318 BASILIO PAV~N AQ, xv, 1994 AQ, xv, 1994 ARTE ARQUITECTURA Y ARQUEOLOG~A 319 ABSTRACT

Me n jessie

CH3CH2COOH(aq) + H2O(l) CH3CH2COO-(aq) + H3O+(aq)

AQ-1. AQ-2, AQ-3, AQ-4, AQ-5

Installation Instructions - Aquasanacdn.aquasana.com/assets/AQ-5100-5200-5300_Install.pdf · 2018-02-14 · Installation Instructions AQ-5100, AQ-5200 & AQ-5300 Under Counter Water

Fe 3+ (aq) + SCN - (aq) ⇆ FeSCN 2+ (aq) (blood red) EQUILIBRIUM CONSTANT DETERMINATION

Section 7.6: Solubility Equilibria and the Solubility Product ...Write the solubility product constant equation. K sp=[Ag +(aq)][I!(aq)] [Ag+(aq)]=[I!(aq)] K sp=[Ag +(aq)]2 Step 3

Weak Acids and Bases Mg (s) + 2HCl (aq) --> MgCl 2 (aq) + H 2 (aq) Mg (s) + 2CH 3 COOH (aq) --> Mg(CH 3 COO 2 ) 2 (aq) + H 2 (aq)

pc pc 2012 - examenbac.com · NS28 / (aq) (s) (s) (aq) 10 —2 + = ] (aq) i 4(aq) mol. L; 1 + = ' (aq) i (aq) 4(aq) 7m +Cu2+ + 4....*àA.Z = 5.1036 F = 9, 65.104 C.mol- —2

First published May 2001...jencës dhe veqorive tjera superiore të mikut të vet.Çka, atëherë, e bën Omerin aq të emocionuar? Pse ai është aq i fascinuar me botën e milingon

67socialstudies.weebly.com · tri aq aq o o '9, Q. 00 aq 2. o g aq o . Created Date: 8/15/2018 3:55:54 PM

AgNO 3 ( aq ) + NaCl ( aq ) AgCl ( s ) + NaNO 3 ( aq )

Zn(s) + H SO (aq) ----> ZnSO (aq) + H (g)

LQs lW · 2020. 12. 9. · LQs lW =IX@} 5 km-¼-¯n-I,km-aq-ln-I A-k-a-Xz-§Ä H-cp k-aq-l-¯nsâ h-fÀ-¨-¡p-Å X-SÊ-§-fm-Wv. km-aq-ln-I- ]n-¶m-¡w s]-s«-¶p-ïm-¡p-¶-X-Ã

Second Edition Julia Burdge & Jason Overbyacidic hydrogen atoms. Polyproticacids lose protons in a stepwise fashion: H2SO4(aq) H+(aq) + HSO4(aq) – – HSO4(aq) H+(aq) + SO 4(aq)

Neutralization Reactions AcidBaseAcid + Base Salt + Water Double Replacement HX(aq)MOH(aq)HX(aq) + MOH(aq) MX(aq) + H 2 O(l) Not Redox Balance by

Eastman AQTM polymers · 4 Aqueous dispersion clarity AQ 48 . AQ 55 . AQ 38 Solvent tolerance AQ 48 . AQ 38 . AQ 55 Water resistance AQ 55 5 AQ 38 . AQ 48 Eastman AQ linear polyesters

AT 91* Qll 'V14A% OUX FILE Aq/ -1 n

White space Challenge: AQ-1. AQ-2, AQ-3, AQ-4, AQ-5 Introduction: Materials: Procedure: Vocabulary: Data: Analysis: Lesson 1: Into the Field How would

aQ-...aQ- ... 2

Me SO Ph H N Me H O H R SO Ph O Dipolar CycloadditionsPh Me O Ph Me O N O N H H O Ph Me Me Ph N N H Bn MeO Me Ph H O H N Me O Bn H N H H Ph O Me H vs. disfavored favored White, J

ELECTROCHEMISTRY. Electrode potential and half cell Half cell 2 possible electron transfer reactions occur: M(s) M n+ (aq) + ne - (Oxidation) M n+ (aq)

Net Ionic Equations HCl(aq) + NaOH(aq) NaCl(aq) + H 2 O(l) What really happens: H + (aq) + OH - (aq) H 2 O(l) Sodium ion and chloride ion are “spectator

CHEMISTRY 161 Chapter 4. REVISION HCl(aq) + NaOH(aq) → NaCl(aq) + H 2 O(l) H + (aq) + OH - (aq) → H 2 O(l) (Arrhenius) HCl(aq) + NH 3 (aq) → NH 4 Cl(aq)