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YUKON EXPLORATION AND GEOLOGY 2015 197 Mapping magma prospectivity for Cordilleran volcanogenic massive sulphide (VMS) deposits using Nd-Hf isotopes: Preliminary results S.J. Piercey*, L.P. Beranek and J.M. Hanchar Department of Earth Sciences, Memorial University of Newfoundland Piercey, S.J., Beranek, L.P. and Hanchar, J.M., 2017. Mapping magma prospectivity for Cordilleran volcanogenic massive sulphide (VMS) deposits using Nd-Hf isotopes: Preliminary results. In: Yukon Exploration and Geology 2016, K.E. MacFarlane and L.H. Weston (eds.), Yukon Geological Survey, p. 197-205. ABSTRACT Preliminary whole rock Nd-Hf isotopic data for porphyritic rhyolitic intrusive rocks from the Wolverine volcanogenic massive sulphide (VMS) deposit are presented herein. Pre-VMS (~352 Ma) quartz-feldspar porphyritic intrusive rocks (QFP) have Nb/Ta ratios (~12) and lower eNd t and eHf t values, compared to syn-VMS (~347 Ma) feldspar porphyritic intrusive rocks (FP), which have higher Nb/Ta ratios (~17) and lower eNd t and eHf t . Both suites have Proterozoic to Archean depleted mantle model ages indicative of crustal inheritance; however, the FP suite has a more juvenile signature. The progression from the crustal-dominated QFP suite, to a more basalt-influenced FP suite reflects the progressive opening of the Wolverine back-arc rift where early QFP magma was dominated by continental crustal melting, whereas the FP magma reflects greater back-arc basin extension, upwelling of basaltic magma beneath the rift, and enhanced continental crust-juvenile basalt mixing. Basalt upwelling beneath the Wolverine basin likely created the elevated geothermal gradient required for Wolverine VMS deposit formation. * [email protected]

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Page 1: Mapping magma prospectivity for Cordilleran volcanogenic ...spiercey/Piercey_Research...Piercey et al. - MagMa prospectivity for cordilleran vMs deposits using nd-Hf isotopes YUKON

YUKON EXPLORATION AND GEOLOGY 2015 197

Mapping magma prospectivity for Cordilleran volcanogenic massive sulphide (VMS) deposits using Nd-Hf isotopes:

Preliminary results

S.J. Piercey*, L.P. Beranek and J.M. Hanchar Department of Earth Sciences, Memorial University of Newfoundland

Piercey, S.J., Beranek, L.P. and Hanchar, J.M., 2017. Mapping magma prospectivity for Cordilleran volcanogenic massive sulphide (VMS) deposits using Nd-Hf isotopes: Preliminary results. In: Yukon Exploration and Geology 2016, K.E. MacFarlane and L.H. Weston (eds.), Yukon Geological Survey, p. 197-205.

ABSTRACT

Preliminary whole rock Nd-Hf isotopic data for porphyritic rhyolitic intrusive rocks from the Wolverine volcanogenic massive sulphide (VMS) deposit are presented herein. Pre-VMS (~352 Ma) quartz-feldspar porphyritic intrusive rocks (QFP) have Nb/Ta ratios (~12) and lower eNdt and eHft values, compared to syn-VMS (~347 Ma) feldspar porphyritic intrusive rocks (FP), which have higher Nb/Ta ratios (~17) and lower eNdt and eHft. Both suites have Proterozoic to Archean depleted mantle model ages indicative of crustal inheritance; however, the FP suite has a more juvenile signature. The progression from the crustal-dominated QFP suite, to a more basalt-influenced FP suite reflects the progressive opening of the Wolverine back-arc rift where early QFP magma was dominated by continental crustal melting, whereas the FP magma reflects greater back-arc basin extension, upwelling of basaltic magma beneath the rift, and enhanced continental crust-juvenile basalt mixing. Basalt upwelling beneath the Wolverine basin likely created the elevated geothermal gradient required for Wolverine VMS deposit formation.

* [email protected]

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YUKON EXPLORATION AND GEOLOGY 2016198

resistant minerals (e.g., zircon, monazite, apatite) record similar geochemical and isotopic signatures. Presented herein are preliminary results from bulk rock Nd and Hf isotope geochemistry of pre and syn-VMS high-level (~synvolcanic) footwall porphyritic intrusive rock (i.e., porphyries) from the Wolverine deposit, which provide initial data to test the “hot” rift hypothesis.

GEOLOGICAL SETTINGThe Finlayson Lake district is located northeast of the Tintina fault in southeastern Yukon (Fig. 1). The district is underlain by pericratonic rocks of the Yukon-Tanana terrane and oceanic rocks of the Slide Mountain terrane, which are juxtaposed against rocks of the North American continental margin along the Inconnu thrust of post-Late Triassic age (Fig. 2; Murphy et al., 2006). The Finlayson Lake district is subdivided into several informal fault and unconformity-bounded groups and formations; the Wolverine deposit is hosted by the Wolverine Lake group within the Big Campbell thrust sheet (Fig. 2; Murphy et al., 2006). The Wolverine Lake group consists of Mississippian felsic metavolcanic and high level meta-intrusive rocks, metasedimentary units, and locally mafic metavolcanic and metaplutonic rocks (Figs. 2 and 3; Murphy et al., 2006).

In the Wolverine deposit area, the Wolverine Lake group consists of a footwall dominated by felsic tuffaceous rocks, meta-intrusive rocks, and interlayered black shale (Figs. 3 and 4; Bradshaw et al., 2008; Piercey et al., 2008, 2016). The hanging wall consists of interlayered felsic siltstone, black shale, iron formation, carbonate exhalative rocks, felsic siltstone breccia, and mafic intrusive and lesser volcanic rocks (Figs. 3 and 4; Bradshaw et al., 2008; Piercey et al., 2008, 2016).

In the immediate footwall to the deposit there are very distinctive felsic porphyritic intrusive rocks. These coherent intrusive rocks occur at the Wolverine deposit proper, as well as along strike at other VMS prospects, including the Fisher, Puck, and Sable zones (Figs. 3 and 4). Previous work has documented the field relationships and ages of the porphyries and documented an older, ~352 Ma pre-VMS suite of quartz feldspar porphyries, and a younger ~347 Ma, syn-VMS suite of feldspar porphyritic rocks (Figs. 4 and 5; Piercey et al., 2008).

INTRODUCTIONVolcanogenic massive sulphide (VMS) deposits are important sources of base (Cu, Zn, Pb) and precious metals (Ag, Au) to the Canadian economy (e.g., Galley et al., 2007). Volcanogenic massive sulphide deposits in Yukon have been the focus of past exploration and production (e.g., Wolverine), and are the current focus of exploration in some locales (e.g., BMC Minerals Ltd. at Kudz Ze Kayah, Finlayson Lake district). Both globally and in Yukon examples, VMS deposits are associated with specific geodynamic environments and specific magma clans (e.g., Piercey, 2011). In particular, VMS deposits are associated with extensional geodynamic environments (e.g., ridges, arc rifts, back arc basins) and with magma that was emplaced at high temperatures (T >900oC; Piercey, 2011). More generally, extensional geodynamic environments provide the structural conduits and permeability required for hydrothermal fluid recharge, and eventual discharge onto the seafloor (e.g., Franklin et al., 2005; Galley et al., 2007; Piercey, 2011), whereas high temperature magmatism provides the heat engine required to drive hydrothermal circulation critical to VMS formation (Lesher et al., 1986; Barrie, 1995; Lentz, 1998; Piercey et al., 2001, 2008; Hart et al., 2004; Piercey, 2010, 2011).

In the Wolverine deposit, recent research illustrates that even in felsic-dominated successions mantle heat and upwelling of juvenile basaltic magma beneath a rift may be an important driver of VMS hydrothermal circulation (Piercey et al., 2008). Furthermore, the signature of mantle upwelling and juvenile crust-mantle mixing is recorded in the trace element signature of felsic rocks, and could be used as a proxy for heat flow of a given VMS environment. In particular, Piercey et al. (2008) illustrated that higher temperature felsic rocks have elevated high field strength element (HFSE) and rare earth element (REE) contents, but also have element ratios (e.g., Nb/Ta, Ti/Sc) indicative of evolved crust – juvenile basalt mixing. These authors also argued that this record of juvenile basalt involvement may be a critical feature for delineating prospective “hot” rifts in felsic dominated successions.

To test the significance of juvenile magmatism and “hot” rifts, a project was initiated at the Wolverine deposit utilizing bulk rock Sm-Nd and Lu-Hf tracer isotopes, and in situ mineral-scale analyses of Lu-Hf and U-Pb in zircon, to identify the “mantle” trace element signatures recorded in Wolverine porphyritic rhyolite, and to determine if

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YUKON EXPLORATION AND GEOLOGY 2016 199

were undertaken. Throughout the course of the study repeat analysis of the JNDi-1 reference material yielded an average 143Nd/144Nd value of 0.512100 ± 6 (1 s.d, n = 27); the published value of Tanaka et al. (2000) is 0.512115. Lu-Hf isotopes were prepared using standard method of spiking, sample dissolution, column chemistry and subsequent analysis by multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS) following the methods of Vervoort et al. (2004). During the course of this study the JMC-475 Hf standard yielded an average value of 176Hf/177Hf = 0.282171 ± 17 (1 s.d, n = 12); the published values are 176Hf/177Hf = 0.282160 (Vervoort and Blichert-Toft, 1999). Initial 143Nd/144Nd ratios and eNdt were calculated at 350 Ma, the mid-point between the ages of the two porphyry suites presented in this paper. The chondritic uniform reservoir (CHUR) values used for

LITHOGEOCHEMISTRY AND RADIOGENIC ISOTOPE GEOCHEMISTRYSamples of the quartz-feldspar and feldspar porphyries were analyzed previously for lithogeochemistry as part of the study by Piercey et al. (2008). The samples were taken from drill core from the footwall in various zones of the Wolverine deposit (Fig. 4), and the full dataset will be released in future publications. A subsample of this dataset were subsequently analyzed for Sm-Nd and Lu-Hf isotopes at Memorial University of Newfoundland following the methods outlined in Phillips (2015). For Sm-Nd, standard methods of spiking, sample dissolution, column chemistry and subsequent analysis by isotope dilution thermal ionization mass spectrometry (ID-TIMS)

128°W

59°N

140°

W

67°N

160°

W

56°N

124°W124°W

Tintina

Kaltag

Denali

Ak

Ak

YT

BCB

.C.

YT

NW

TYT

Wh

FbFb

WL

PacificOcean

limitlimit ofof

CordilleranCordilleran

easterneastern

deformation

deformation

ST +

CC

ee

E

Ε

EE

EE

b

b Finlayson Lake

Delta

Bonnifield

Ambler

Gataga

Tulsequah

Macmillan Pass

C A N A D AC A N A D A0 300

km

Scale

PALEOZOIC PERICRATONICASSEMBLAGES

CONTINENT MARGINASSEMBLAGES

Devonian - Permian Stikine assemblage

Devonian - Jurassicoceanic assemblages

PermianKlondike SchistPennsylvanian - Permian Klinkit Devonian - Mississippianarc assemblages

Neoproterozoic - Devonian basinal facies

Neoproterozoic - Missrift and basinal facies

Proterozoic - Devonian platformal faciesNeoproterozoic - Paleozoicother cont margin assembl

Devonian - Mississippian mineral districts

Yukon-Tanana terrane

Figure 1. Terrane map of northern Cordillera showing location of Finlayson Lake district. Modified from Colpron et al. (2006). Abbreviations: Wh = Whitehorse; Fb = Fairbanks; WL = Watson Lake; ST + CC = Stikine and Cache Creek; E = eclogite (Permian); e = eclogite (Mississippian); and b = blueschist (Permian).

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Yukon GeoloGical ReseaRch

YUKON EXPLORATION AND GEOLOGY 2016200

1 23

4

VHMS & VSHMSDEPOSITS

Kudz Ze Kayah

Fyre Lake

Wolverine

Ice

GP4F5

0 20

kilometres

132°00'62°00'

130°00'

61°00'

61°45'

INCONNU INCONNU

MCTMCT

MCTMCT

BIG CAMPBELLWINDOW

BIG CAMPBELLWINDOW

JCFJCF

JCFJCF

JCFJCF

JCFJCF

BCT

FAULT

CREEK

JULES

NRFNRF

CLTCLT

CLTCLT

THRUST THRUST

INCONNU

INCONNU

THRU

ST TH

RUST

THRUST

MONEY CREEK

THRUST

MONEY CREEK

PellyPelly RiverRiver

Finlayson Lake

Finlayson Lake

FrancesLake

FrancesLake

Wolverine Lake

Wolverine Lake

FireLakeFireLake

Campbell HighwayCampbell Highway

YUKON

Finlayson Lake(105G)

Frances Lake(105H)

Ross River~ 40 km

Watson Lake~ 110 km

TINTINA

FAULT

Mississippianeclogite (KMC)

North Klippen

Money Klippe

1

2

3

4

5

ultramafic and mafic intrusions

polymictic conglomerate, sandstone,siltstone, mafic and felsic volcanic rocks,limestone

basalt and varicolored chert

dark phyllite and chert, varicoloredchert, chert-pebble conglomerate,sandstone, limestone, felsic and maficmetavolcanic rocks

YUKON-TANANA TERRANE

YUKON-TANANA TERRANE

POST - YTT / SMTAMALGAMATION

SLIDE MOUNTAIN TERRANE

SLIDE MOUNTAIN TERRANELEGEND

INTRUSIVE ROCKS

INTRUSIVE ROCKS

SIMPSON LAKE GROUP

Campbell Range formation

Early Permian

granite, quartz monzoniteaugen granite

Late Devonian to Early Mississippian

Lower Permian

granite, quartz monzonite,granodiorite

SIMPSON RANGE PLUTONIC SUITE

GRASS LAKES PLUTONIC SUITE

ultramafic and mafic intrusions,Big Campbell and Cleaver Lake thrust sheets

FORTIN CREEK GROUP Carboniferous to Permian?

undifferentiated intrusions

undifferentiated volcanic rocks

Mesozoic and Cenozoic

grey shale, siltstone and limestone

Triassic

Permian - Triassic

dark shale, siltstone and limestone

Triassic

NORTH AMERICANCONTINENTAL MARGIN

undifferentiated formations of SelwynBasin, McEvoy Platform, Earn Groupand Mt. Christie Formation

Paleozoic

limestone and quartzite

LAYERED ROCKS

Gatehouse formation Lower to Middle Permian

dark phyllite and sandstone, chert,chert-pebble conglomerate, diamictite

LAYERED ROCKS

Money Creek formation Lower Permian

massive bioclastic limestoneFinlayson Creek limestone

Mid-Pennsylvanian to Lower Permian

massive bioclastic limestoneWhitefish limestone

Upper Mississippian

intermediate, felsic and mafic volcanicrocks, sandstone, chert, limestone

Tuchitua River formation Lower Mississippian

undifferentiated mafic and felsic volcanic rocks and dark clastic rocksof the Fire Lake, Kudz Ze Kayah andWind Lake formations

GRASS LAKES GROUP

calc-alkaline basalt, rhyolite, chertand volcanic-derived sandstone

Cleaver Lake formation

North River formation

felsic to intermediate metavolcanicrocks and carbonaceous phyllite

Waters Creek formation

Upper Devonian to Lower Mississippian

Pre-Upper Devonian

quartzose metaclastic rocks, marbleand non-carbonaceous pelitic schist

undifferentiated mafic and felsic volcanic rocks and dark clastic rocks

WOLVERINE LAKE GROUP

green and pink chert, limestone, sandstone, conglomerate, mafic metavolcanic rocks

undifferentiated White Lake and King Arctic formations Upper Mississippian to mid-Pennsylvanian

Figure 2. Geological map of Finlayson Lake district showing locations of volcanogenic massive sulphide deposits (from Murphy et al., 2006).

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YUKON EXPLORATION AND GEOLOGY 2016 201

eNdt calculations are 143Nd/144Nd = 0.512638 and 147Sm/144Nd = 0.1967 (Hamilton et al., 1983). Depleted mantle model ages (TDM) are calculated using the values of 143Nd/144Nd = 0.513163 and 147Sm/144Nd = 0.2137 (Goldstein et al., 1984). Initial 176Hf/177Hf ratios and eHft were calculated at 350 Ma similar to the Nd isotopic data. The chondritic uniform reservoir (CHUR) values used for eHft calculations are 176Hf/177Hf = 0.282772 and 176Lu/177Hf = 0.0332 (Blichert-Toft and Albarede, 1997). Depleted mantle model ages (TDM) are calculated using the values of 176Hf/177Hf = 0.28325 and 176Lu/177Hf = 0.0334 (Vervoort and Blichert-Toft, 1999).

RESULTS

Sm-Nd and Lu-Hf results are shown in Figures 6 and 7. In Figure 6 Wolverine quartz-feldspar and feldspar porphyritic rhyolite samples are plotted against the whole-rock Nb/Ta ratio. The Nb/Ta data are from Piercey et al. (2008) and are shown as they are reflective of the source region (i.e., upper crust vs. juvenile basalt) for the felsic rocks. Nb and Ta are geochemical twins and rarely fractionated from one another during partial melting and fractional crystallization, with upper crustal rocks and rocks derived therefrom having Nb/Ta ~12, whereas Nb/Ta ~17 for rocks derived from more juvenile,

435000 437500 440000 442500

6805

000

6807

500

6810

000

6812

500

6815

000

6817

500

Fisher zone

Wolverine/Lynx zone

Sablezone

Puckzone

0 0.8 1.6 2.4 3.2

km

LegendGeology

Campbell Range FormationSulphidezone

Slide Mountain terrane

Yukon-Tanana terrane

Wolverine Lake Group

Kudz Ze Kayah Formation

Permian ultramafics

Money Creek Formation

hanging wall basalt

footwall carbonaceous sedimentary rocksfootwall felsic volcaniclastics and iron fmnshanging wall aphyric rhyolite & volcaniclastics

footwall basal clastic rocksGrass Lake Group

normalfault

Symbols

Figure 5

Figure 3. Geology of local Wolverine deposit area, illustrating locations of different zones. Geology from Murphy et al. (2006).

1730

0 m

1680

0 m

1100 m

1400 m

SW

NE

0 50 100

metres

K-feldspar porphyry

LEGEND

massive basalt

basaltic volcaniclasticinterbedded graphitic argillite & greywackerhyolitic siltstone brecciamagnetite iron formation

carbonate exhalitemassive sulphide

finer grained rhyolitic siltsone/tuff

coarser grained rhyolitic siltsone/tuffcoarse grained felsic volcaniclastic (± qtz, fsp crystals)

graphitic argillitetrace of diamond drill hole

Figure 4. Geological cross sections Wolverine deposit illustrating deposit stratigraphy and the presence of feldspar porphyritic rhyolites in the deposit footwall. Sections modified from Bradshaw et al. (2008).

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YUKON EXPLORATION AND GEOLOGY 2016202

mantle sources (e.g., basalt; Green, 1995; Barth et al., 2000; Kamber and Collerson, 2000; McLennan, 2001). The pre-VMS QFP (352 Ma) suite have Nb/Ta ~12 and eNdt ranging from -7.7 to -11.5, eHft ranging from -12.4 to -19.0, and with TDM(Nd) ages of 1.66-2.58 Ga and TDM(Hf) ages of 1.59-2.22 Ga (Figs. 6 and 7). The younger, syn-VMS FP (347 Ma) suite of porphyries have higher Nb/Ta ratios and eNdt ranging from -7.9 to -8.1, eHft ranging from -13.4 to -18.0, and with TDM(Nd) ages of 1.59-1.67 Ga and TDM(Hf) ages of 1.62-1.97 Ga (Figs. 6 and 7).

DISCUSSION AND SUMMARYPorphyritic rocks from the Wolverine deposit have distinct variations in Nd-Hf isotopic signatures that are indicative of varying contributions of upper crust vs. juvenile (basaltic) material to their genesis. Both suites of high level intrusive rocks have been influenced by upper crustal materials

as indicated by their negative eNdt and eHft values and Proterozoic to Archean depleted mantle model ages (Figs. 6 and 7); it is implied that these rocks melted continental crustal sources, or assimilated continental crustal material during emplacement (Lentz, 1998; Piercey et al., 2008). These data are also consistent with previously reported data for the felsic rocks throughout the Yukon-Tanana terrane, which show strong evidence of crustal inheritance from Laurentian-derived, peri-continental material (e.g., Piercey et al., 2006). There are notable differences between the suites, however. The older QFP suite has lower Nb/Ta ratios, lower eNdt and overlapping, but generally lower eHft, compared to the younger FP suite (Figs. 6 and 7). Piercey et al. (2008) suggested that the lower Nb/Ta in the QFP suite reflected a greater upper crustal contribution relative to the FP suite, which had a greater juvenile contribution, likely derived from underplated basaltic magma at the base of the Wolverine back-arc rift. The isotopic results herein support this hypothesis and the FP suite is shifted towards higher eNdt and eHft, consistent with a greater juvenile contribution to its genesis relative to the QFP suite.

The progression from the more crustally-derived QFP suite at 352 Ma to the FP suite with a greater juvenile contribution at 347 Ma is interpreted to represent the progressive opening of the Wolverine back-arc basin, upwelling of juvenile basaltic magma beneath the rift, and greater crust-basalt mixing as the basin widened (Piercey et al., 2008). The latter authors also argued that the upwelling of mantle-derived magma beneath the rift was also critical in increasing heat flow to the basin, which in turn enhanced hydrothermal circulation and ultimately led to the formation of the Wolverine deposit.

%quartz, size, %feldspar, size

QFP

QFP

QFP

QFP withmm-scale wisps

or argillite

QFP withmm-scale wisps

or argillite

carbonaceous

2-3%, <2 mm, 5%, 2-3 mm

2-3%, <1 mm, 5-7%, 2-3 mm

10-12%, 4-6 mm, <3%, 2 mm-1.3 cm

10-12%, 4-6 mm, 4-5%, 2 mm-1.3 cm

10-12%, 4-6 mm, 3-5%, 2 mm-1 cm

10-12%, 3-5 mm, 5-7%, 1-1.5 cm

10-12%, 4-6 mm, 3-5%, 2 mm-1.1 cm

10-12%, 4-6 mm, 3-5%, 2 mm-1.1 cm

10-12%, 4-6 mm, ~3%, 2-9 mm

10%, ~5 mm, ~3%, 2 mm-1 cm

10%, ~5 mm, <1% feldspars destroyed

10-12%, 3-6 mm, 5%, up to 1.5 cm

10-12%, ~4 mm, 3%, 3 mm

10-12%, ~3 mm, 3%, 2 mm

10%, <2 mm, 3-5%, <3 mm

10-12%, <3 mm, 5%, <4 mm

210

220

230

240

240

260

metres argi

llite

volc

anic

silt

ston

e

porp

hyry

argi

llite

& s

iltst

one

QFP

WV96-33 (Sable zone)Type QFP Section

chill

zone

QFP

QFP

155

165

175

metres

%feldspar, size

3-5%, <3 mm

5-6%, 3-7 mm, up to 7 mm

6-8%, 5-7 mm, up to 1 cm6-8%, 5-8 mm, up to 1.2 cm

7-8%, 5-8 mm, up to 1.1 cm

6-8%, 4-8 mm, up to 1.1 cm

WV97-81 (Wolverine/Lynx zone)Type FP Section

chill

zone

chill

zone

6-7%, 4-7 mm, up to 0.9 cm<1%, minor fsp laths

argi

llite

volc

anic

silt

ston

e

porp

hyry

argi

llite

& s

iltst

one

Figure 5. Graphic logs of type sections of (a) quartz-feldspar porphyries and (b) feldspar-porphyries from the Wolverine deposit. Figure modified from Piercey et al. (2008).

a b

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YUKON EXPLORATION AND GEOLOGY 2016 203

The presence of distinctive, more juvenile eNdt-eHft

signatures in the FP suite, which is intimately associated with mineralization and syn-VMS formation, suggests that rhyolitic rocks with similar juvenile signatures within the Yukon-Tanana terrane and other pericratonic terranes may also be prospective for VMS mineralization. This hypothesis requires further testing and will be the focus of ongoing research by the authors. Moreover, future work will focus on comparing both bulk rock Nd-Hf and in situ Hf-Nd-U-Pb signatures of heavy mineral phases (e.g., zircon, monazite, apatite) within the pericratonic terranes to see if there are important isotopic differences between barren and VMS-bearing assemblages, testing geochemical and isotopic relationships as a function of VMS deposit grade and tonnage, and seeing if such methods allow mapping of VMS potential and fertility of felsic-dominated assemblages.

ACKNOWLEDGEMENTSFieldwork on this research was undertaken in 2000 and 2005 and logistical support was provided by Yukon Zinc Corporation. Discussions with Geoff Bradshaw, Gilles Dessureau, Jason Dunning, Harold Gibson and Jan Peter were very helpful during the fieldwork phase of this research. The research was previously funded by an NSERC Discovery Grant and the NSERC-Altius Industrial Research Chair at Memorial University, and ongoing research is being funded by the Yukon Geological Survey and the Geological Survey of Canada through the Targeted Geoscience Initiative 5 program. Will Bradford, Anne Westhues, and Sherri Strong are acknowledged for assistance with Nd-Hf isotope data acquisition. Ongoing discussions with Mo Colpron and Don Murphy on the Yukon-Tanana terrane and Finlayson Lake geology are

gratefully acknowledged. We thank Alana Hinchey for her review of this manuscript. A special thanks to Karen MacFarlane for her patience and for accommodating the late arrival of this paper!

-12 -11 -10 -9 -8 -710

12

14

16

18

Nb/

Ta

εNdt

Nb/Ta = 12

Nb/Ta = 17

FP (347 Ma)QFP (352 Ma)

-21 -19 -17 -15 -1310

12

14

16

18

Nb/

Ta

εHft

Nb/Ta = 12

Nb/Ta = 17

FP (347 Ma)QFP (352 Ma)

(A)

(B)

Figure 6. (a) Nb/Ta versus eNdt and (b) Nb/Ta versus eHf

t

for porphyritic rhyolitic rocks from the Wolverine VMS deposit. Nb/Ta values ~12 reflect crustal sources, whereas Nb/Ta ~17 reflect more basaltic/juvenile sources. While all samples have negative eNd

t and eHf

t, the younger, FP suite

tends towards more juvenile signatures relative to the QFP suite.

1.4 1.6 1.8 2.0 2.2 2.4 2.61.0

1.2

1.4

1.6

1.8

2.0

2.2

2.4

T DM

(Hf)

(Ga)

TDM(Nd) (Ga)

FP (347 Ma)QFP (352 Ma)

Figure 7. Depleted mantle model ages for Hf and Nd for the Wolverine porphyritic rhyolites. Notably all samples have Proterozoic to Archean model ages indicative of crustal inheritance from old upper crustal sources.

a

b

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Green, T.H., 1995. Significance of Nb/Ta as an indicator of geochemical processes in the crust-mantle system. Chemical Geology, vol. 120, p. 347-359.

Hamilton, P.J., O’Nions, R.K., Bridgwater, D. and Nutman, A., 1983. Sm-Nd studies of Archaean metasediments and metavolcanics from West Greenland and their implications for the Earth’s early history. Earth and Planetary Science Letters, vol. 63, p. 263-273.

Hart, T.R., Gibson, H.L. and Lesher, C.M., 2004. Trace element geochemistry and petrogenesis of felsic volcanic rocks associated with volcanogenic massive Cu-Zn-Pb sulfide deposits. Economic Geology, vol. 99, p. 1003-1013.

Kamber, B.S. and Collerson, K.D., 2000. Role of ‘hidden’ deeply subducted slabs in mantle depletion. Chemical Geology, vol. 166, p. 241-254.

Lentz, D.R., 1998. Petrogenetic evolution of felsic volcanic sequences associated with Phanerozoic volcanic-hosted massive sulfide systems: the role of extensional geodynamics. Ore Geology Reviews, vol. 12, p. 289-327.

Lesher, C.M., Goodwin, A.M., Campbell, I.H. and Gorton, M.P., 1986. Trace element geochemistry of ore-associated and barren felsic metavolcanic rocks in the Superior province, Canada. Canadian Journal of Earth Sciences, vol. 23, p. 222-237.

McLennan, S.M., 2001. Relationships between the trace element composition of sedimentary rocks and upper continental crust. Geochemistry, Geophysics, Geosystems, vol. 2, p. 24 (Paper 2000GC000109).

Murphy, D.C., Mortensen, J.K., Piercey, S.J., Orchard, M.J. and Gehrels, G.E., 2006. Tectonostratigraphic evolution of Yukon-Tanana Terrane, Finlayson Lake massive sulphide district, southeastern Yukon. In: Paleozoic Evolution of Pericratonic Terranes at the Ancient Pacific Margin of North America, Canadian and Alaskan Cordillera, M. Colpron and J.L. Nelson (eds.), Geological Association of Canada, Special Paper 45, p. 75-105.

Phillips, S.E., 2015. High spatial-resolution Sm-Nd and U-Pb and Lu-Hf and U-Pb isotope geochemistry of monazite and zircon in the Old Woman-Piute batholith, California. Unpublished MSc thesis, Memorial University of Newfoundland, 163 p.

REFERENCESBarrie, C.T., 1995. Zircon thermometry of high-

temperature rhyolites near volcanic-associated massive sulfide deposits. Abitibi subprovince, Canada. Geology, vol. 23, p. 169-172.

Barth, M.G., McDonough, W.F. and Rudnick, R.L., 2000. Tracking the budget of Nb and Ta in the continental crust. Chemical Geology., vol. 165, p. 197-213.

Blichert-Toft, J. and Albarede, F., 1997. The Lu-Hf isotope geochemistry of chondrites and the evolution of the mantle-crust system. Earth and Planetary Science Letters, vol. 148, p. 243-258.

Bradshaw, G.D., Rowins, S.M., Peter, J.M. and Taylor, B.E., 2008. Genesis of the Wolverine volcanic sediment-hosted massive sulfide deposit, Finlayson Lake district, Yukon, Canada: mineralogical, mineral chemical, fluid inclusion, and sulfur isotope evidence. Economic Geology, vol. 103, p. 35-60.

Colpron, M., Nelson, J.L. and Murphy, D.C., 2006. A tectonostratigraphic framework for the pericratonic terranes of the northern Canadian Cordillera. In: Paleozoic Evolution amd Metallogeny of Pericratonic Terranes at the Ancient Pacific Margin of North America, Canadian and Alaskan Cordillera, M. Colpron and J.L. Nelson (eds.), Geological Association of Canada, Special Paper 45, p. 1-23.

Franklin, J.M., Gibson, H.L., Galley, A.G. and Jonasson, I.R., 2005. Volcanogenic Massive Sulfide Deposits. In: Economic Geology 100th Anniversary Volume, J.W. Hedenquist, J.F.H. Thompson, R.J. Goldfarb and J.P. Richards (eds.), Society of Economic Geologists, p. 523-560.

Galley, A.G., Hannington, M. and Jonasson, I., 2007. Volcanogenic massive sulphide deposits. In: Mineral Deposits of Canada: A Synthesis of Major Deposit-types, District Metallogeny, the Evolution of Geological Provinces, and Exploration Methods, W.D. Goodfellow (ed.), Special Publication 5, Mineral Deposits Division, Geological Association of Canada, p. 141-161.

Goldstein, S.L., O’Nions, R.K. and Hamilton, P.J., 1984. A Sm-Nd isotopic study of atmospheric dusts and particulates from major river systems. Earth and Planetary Science Letters, vol. 70, p. 221-237.

Page 9: Mapping magma prospectivity for Cordilleran volcanogenic ...spiercey/Piercey_Research...Piercey et al. - MagMa prospectivity for cordilleran vMs deposits using nd-Hf isotopes YUKON

Piercey et al. - MagMa prospectivity for cordilleran vMs deposits using nd-Hf isotopes

YUKON EXPLORATION AND GEOLOGY 2016 205

Piercey, S.J., Peter, J.M., Mortensen, J.K., Paradis, S., Murphy, D.C. and Tucker, T.L., 2008. Petrology and U-Pb geochronology of footwall porphyritic rhyolites from the Wolverine volcanogenic massive sulfide deposit, Yukon, Canada: implications for the genesis of massive sulfide deposits in continental margin environments. Economic Geology, vol. 103, p. 5-33.

Tanaka, T., Togashi, S., Kamioka, H., Amakawa, H., Kagami, H., Hamamoto, T., Yuhara, M., Orihashi, Y., Shigekazu, Y., Shimuzu, H., Kunimaru, T., Takahashi, K., Yanagi, T., Nakano, T., Fujimaki, H., Shinjo, R., Asahara, Y., Tanimizu, M. and Dragusanu, C., 2000. JNdi-1: a neodymium isotopic reference in consistency with LaJolla neodymium. Chemical Geology, vol. 168, p. 279-281.

Vervoort, J.D. and Blichert-Toft, J., 1999. Evolution of the depleted mantle; Hf isotope evidence from juvenile rocks through time. Geochimica et Cosmochimica Acta, vol. 63, p. 533-556.

Vervoort, J.D., Patchett, P.J., Söderlund, U. and Baker, M., 2004. Isotopic composition of Yb and the determination of Lu concentrations and Lu/Hf ratios by isotope dilution using MC-ICPMS. Geochemistry, Geophysics, Geosystems, vol. 5, p. 15 doi:10.1029/2004GC000721).

Piercey, S.J., 2010. An overview of petrochemistry in the regional exploration for volcanogenic massive sulphide (VMS) deposits. Geochemistry: Exploration, Environment, Analysis, vol. 10, p. 119-136.

Piercey, S.J., 2011. The setting, style, and role of magmatism in the formation of volcanogenic massive sulfide deposits. Mineralium Deposita, vol. 46, p. 449-471.

Piercey, S.J., Paradis, S., Murphy, D.C. and Mortensen, J.K., 2001. Geochemistry and paleotectonic setting of felsic volcanic rocks in the Finlayson Lake volcanic-hosted massive sulfide (VHMS) district, Yukon, Canada. Economic Geology, vol. 96, p. 1877-1905.

Piercey, S.J., Gibson, H.L., Tardif, N. and Kamber, B.S., 2016. Ambient redox and hydrothermal environment of the Wolverine volcanogenic massive sulfide deposit, Yukon: insights from lithofacies and lithogeochemistry of Mississippian host shales. Economic Geology, vol. 111, p. 1439-1463.

Piercey, S.J., Nelson, J.L., Colpron, M., Dusel-Bacon, C., Simard, R.-L. and Roots, C.F., 2006. Paleozoic magmatism and crustal recycling along the ancient Pacific margin of North America, northern Cordillera. In: Paleozoic Evolution and Metallogeny of Pericratonic Terranes at the Ancient Pacific Margin of North America, Canadian and Alaskan Cordillera, M. Colpron and J.L. Nelson (eds.), Geological Association of Canada, Special Paper 45, p. 281-322.

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