master of science (chemistry) -...
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M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 1
Study & Evaluation Scheme
of
Master of Science
(Chemistry) [Applicable for Academic Session 2017-18]
[Approved by Hon’ble VC dated August 08, 2017]
TEERTHANKER MAHAVEER UNIVERSITY N.H.-24, Delhi Road, Moradabad, Uttar Pradesh-244001
Website: www.tmu.ac.in
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 2
TEERHANKER MAHAVEER UNIVERSITY (Established under Govt. of U. P. Act No. 30, 2008) Delhi Road, Bagarpur, Moradabad (U.P)
Study & Evaluation Scheme Master of Science
SUMMARY Programme : M.Sc. (Chemistry)
Duration : Two-year full time (Four Semesters)
Medium : English Minimum Required Attendance
: 75 %
Credit :
Maximum Credit : : 90
Minimum credit required for the degree
: 82 (Maximum One non-core paper can be audit per year of program)
Assessment
: Internal External Total
40 60 100
Internal Evaluation (Theory Papers)
Class
Test
I
Class
Test
II
Class
Test
III
Assignment(s)
Attendance
Total
Best two out of three
10
Marks
10
Marks
10
Marks
10
Marks
10
Marks
40
Marks
Evaluation of Practical
: Internal External Total
50 50 100
Evaluation of Seminar/Viva
:
Internal External Total
50 50 100
Duration of Examination : External Internal
3 hrs. 112
hrs
(To qualify the course a student is required to secure a minimum of 45% marks in aggregate in
each course including the semester-end examination and the teacher’s continuous evaluation shall be
essential for passing the course and earning its assigned credits. A candidate, who secures less than
45% marks in a course, shall be deemed to have failed in that course.)
Question Paper Structure
1. The question paper shall consist of six questions. All six are compulsory. First question shall be of
short answer type (not exceeding 50 words). Question No. 1 shall contain 8 parts representing all
units of the syllabus and students shall have to answer any five (weightage 2 marks each).
2. Remaining five questions will be one from each unit with internal choice. The student has to answer
one of the two in each question. The weightage of Question No. 2 to 6 shall be 10 marks each.
3. Usually each question in the examination should be designed to have a numerical component,
where part of syllabus.
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 3
Note 1:
Evaluation Scheme for MOOC, Short Term Courses:
University allows students to undertake additional subjects/course(s) (In-house offered by the university through
collaborative efforts or courses in the open domain by various internationally recognized universities) and to
earn additional credits on successful completion of the same. Each course will be approved in advance by the
University following the standard procedure of approval and will be granted credits as per the approval.
Keeping this in mind the Academic Council in its 10th meeting on February 13, 2016, approved the University
proposal and allowed a maximum of two credits to be allocated for MOOC courses. In the pilot phase it is
proposed that a student undertaking and successfully completing a MOOC course through edX, Coursera, IIRS
and NPTEL could be given a maximum credit of two with 1 credit for credit with 30-60 contact hours and 2
credits for courses having more than 60 credit hours.
For smooth functioning and monitoring of the scheme the following shall be the guidelines for MOOC courses,
Add-on courses carried out by the College from time to time.
1. There shall be a MOOC co-ordination committee in the College with a faculty at the level of Professor
heading the committee and all Heads of the Department being members of the Committee.
2. The Committee will list out courses to be offered during the semester, which could be requested by the
department or the students and after deliberating on all courses finalise a list of courses to be offered
with credits defined for each course and the mode of credit consideration of the student. The complete
process including the approval of the Vice Chancellor shall be obtained by the College before end of
June and end of December for Odd and Even semester respectively of the year in which the course is
being offered. In case of MOOC course the approval will be valid only for the semester on offer.
3. A student can opt for a maximum of two MOOC courses for credit during the complete duration of the
course other than offered under SWAYAM.
4. College can offer upto 20% credit through courses offered by SWAYAM. However, if the college is
offering courses on other MOOC platforms, the total credit offered under MOOC will not exceed 20%
including those offered under SWAYAM.
5. Students will register for the course and the details of the students enrolling under the course along with
the approval of the Vice Chancellor will be forwarded to the Examination department within fifteen days
of start of the semester by the Co-ordinator MOOC through the Principal of the College.
6. Where the MOOC course or Add-on on courses are only offering certificate of successful completion,
and credit has been assigned to the course, the University examination division will conduct a MCQ
examination for the course with 50 MCQ with 100 marks to facilitate inclusion of the courses in CPI
computation.
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 4
7. College will define whether the credits are regular credits or to be considered only in case a student fails
to secure minimum required credits then the additional subject(s) shall be counted for calculating the
minimum credits required for the award of degree.
8. In case the College wants the additional course to be shown in the mark sheet as additional course
completed by the students the same shall also be mentioned by the College and the student will opt for
the same at the time of taking admission to the course.
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 5
Study & Evaluation Scheme
Semester I
S.
No.
Category
(Core &
Non-core)
Course
Code
Subject Periods Credit Evaluation Scheme
L T P Internal External Total
1 Core MCH111 Inorganic Chemistry-I 4 - - 4 40 60 100
2 Core MCH112 Organic Chemistry-I 4 - - 4 40 60 100
3 Core MCH113 Physical Chemistry-I 4 - - 4 40 60 100
4 Non-core MAT115 Research Methodology 3 1 - 4 40 60 100
5 Core
MCH161 Inorganic Chemistry-I (Lab) - - 4 2 50 50 100
6 Core
MCH162 Physical Chemistry-I (Lab) - - 4 2 50 50 100
7 Non-core
MOOC11 MOOC Program-I (Optional) - - - - - 100 100
8
MSC111 Discipline & General
Proficiency - - - - 100 - 100
Total 15 1 8 20 260 340 600
Semester-II
S.
No.
Category
(Core &
Non-core)
Course
Code
Subject Periods Credit Evaluation Scheme
L T P Internal External Total
1 Core MCH211 Inorganic Chemistry-II 4 - - 4 40 60 100
2 Core MCH212 Organic Chemistry-II 4 - - 4 40 60 100
3 Core MCH213 Physical Chemistry-II 4 - - 4 40 60 100
4 Core MCH214 Spectroscopy-I 4 - - 4 40 60 100
5 Core
MCH261 Organic Chemistry-I (Lab) - - 4 2 50 50 100
6 Core
MCH262 Inorganic Chemistry-II (Lab) - - 4 2 50 50 100
7 Non-core MOOC12 MOOC Program-II (Mandatory) - - - 2 - 100 100
8
MSC211 Discipline & General
Proficiency - - - - 100 - 100
Total 16 0 8 22 260 440 700
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 6
Semester III
S.
N
o.
Category
(Core &
Non-
core)
Course
Code
Subject Periods Credit Evaluation Scheme
L T P Internal External Total
1 Core MCH311 Spectroscopy-II 4 - - 4 40 60 100
2 Core
Departmental Elective-I
MCH 312 Polymer Chemistry
4 - - 4 40 60 100 MCH313 Chemistry of Nano-materials
MCH314 Chemistry of Natural Products
3 Core
Departmental Elective-II
MCH315 Organometallic Chemistry
4 - - 4 40 60 100 MCH316 Medicinal Chemistry
MCH317 Quantum Chemistry and Solid-
State Chemistry
4 Non-core
Open Elective
MSC011 Industrial Safety & Health
Hazards
4 - - 4 40 60 100
MSC012 Elementary Biophysics
MSC013 Statistical Techniques in Data
Mining
MSC014/
ECS411/
511/611 Database Management System
5 Core MCH361 Organic Chemistry-II (Lab) - - 4 2 50 50 100
6 Core MCH362 Physical Chemistry-II (Lab) - - 4 2 50 50 100
7 Non-core MOOC13 MOOC Program-III
(Mandatory) - - - 2 - 100 100
8 MSC311 Discipline & General
Proficiency - - - 1 100 - 100
Total 16 0 8 23 360 440 800
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 7
Semester IV
S.
No.
Category
(Core &
Non-core)
Course
Code
Subject Periods Credit Evaluation Scheme
L T P Internal External Total
1 Core
Departmental Elective-III
MCH411 Biochemistry
4 - - 4 40 60 100 MCH412 Photochemistry
2 Core
Departmental Elective-IV
MCH413 Bio-Inorganic Chemistry
4 - - 4 40 60 100 MCH414 Bio-Organic Chemistry
MCH415 Bio-Physical Chemistry
3 None-core MCH416 Environmental Chemistry 4 - - 4 40 60 100
4 Core MCH492 Project, Seminar & Viva - - 24 12 50 50 100
5
MSC411 Discipline & General
Proficiency - - - 1 100 - 100
Total 12 0 24 25 270 230 500
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 8
Semester-I
Inorganic Chemistry-I Course Code: MCH111 L T P C
4 0 0 4
Objective:
This syllabus deals with the basic concepts i.e. stereochemistry, bonding & reaction mechanism of
transitional metal complexes.
Course Outcomes: The student will able to learn:
Stereochemistry & bonding aspects of main group elements. The students will be able to explain the
reaction mechanism of transition metal complexes & factors affecting it & can develop generalized
idea of application in the field of medicine, pharmacy, Polymer chemistry & Agriculture etc.
Course Contents:
UNIT I (Lectures 08)
Stereochemistry and Bonding in Main Group Compounds: VSEPR theory and its application for
treating structures of inorganic molecules and ions containing lone pairs of electrons, shortcomings of
VSEPR model. MO treatment of polyatomic molecules, e.g., ozone, nitrite, nitrate, hydarzoic acid and
benzene.
UNIT II (Lectures 08)
Metal-Ligand Bonding: Molecular orbital theory. Qualitative aspects of metal-ligand sigma-bonding
in octahedral, tetrahedral and square planar complexes. Jahn-Teller Effect
Electronic Spectra and of Transition Metal Complexes. Spectroscopic term, terms and microstates for
the p2 and d2 configurations, Hund’s rules for ground state terms, the correlation of spectroscopic terms
into Mulliken symbols, electronic transition selection rules, Orgel diagrams for transition metal
complexes (d1-d9 states). Jahn-teller effect and electronic spectra of complexes
UNIT III (Lectures 08)
Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their relationship,
trends in stepwise constants, factors affecting the stability of metal complexes with reference to the
nature of metal ion and ligand, chelate effect and its thermodynamic origin, determination of binary
formation constants by Bjerrum method, Job’s and Mole ratio methods.
UNIT IV (Lectures 08)
Reaction Mechanisms of Transition Metal Complexes I: Energy profile of a reaction, reactivity of
a metal complexes, inert & labile complexes, kinetics of octahedral substitution, acid hydrolysis, factors
affecting acid hydrolysis, base hydrolysis, conjugate base mechanism, direct & indirect evidence in
favour of conjugate mechanism, anation reaction, reaction without metal ligand bond cleavage.
Substitution reaction in square planar complexes, the trans effect, mechanism of the substitution
reaction.
UNIT V (Lectures 08)
Reaction Mechanisms of Transition Metal Complexes II: Redox reaction, Electron transfer
reactions, outer and inner sphere electron transfer process, Marcus-hush theory, doubly bridged inner-
sphere transfer, other electron transfer reactions; two electron transfers, Non-complementary reaction,
Ligand exchange via electron exchange, reductions by hydrated electrons.
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 9
Reference Books:
1. Huheey, J. E. Inorganic Chemistry, Pearson.
2. Cotton, F.A. and Wilkinson, G. Advanced Inorganic Chemistry, Wiley eastern.
3. Shriver, D. F., Atkins, P. W. and Langford, C. H. Inorganic Chemistry, ELMS, Oxford.
4. William W. Porterfield, Inorganic Chemistry.
5. K.F. Purcell and J.C. Kotz. An Introduction to Inorganic Chemistry.
* Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 10
Semester-I
Organic Chemistry-I Course Code: MCH112 L T P C
4 0 0 4
Objective: The present syllabus designed to explain the stereochemistry & reaction mechanism of the
organic compounds.
Course Outcomes: Knowledge of basic concept of organic chemistry will help students to develop
idea to synthesize new organic molecules which find potential application in the field of drug design,
medicine and other molecules of industrial importance
Course Contents:
UNIT I (Lectures 08)
Stereochemistry. Chirality, elements of symmetry, molecules with more than one chiral center, threo
and erythro isomers. R and S configuration. Separation of enantiomers. Regioselective, stereospecific
and stereoselective rections. Asymmetric synthesis. Optical activity in the absence of chiral carbon
(atropisomerism)biphenyls, allenes and spiranes, and their nomenclature. Conformational analysis of
cyclohexanes and decalins. Effect of conformation on reactivity
UNIT II (Lectures 08)
Reaction Mechanism. Types of mechanisms, types of reactions, thermodynamic and kinetic
requirements, and control, Potential energy diagrams, transition states and intermediates, methods of
determining mechanisms, isotope effects. Effect of structure on reactivity -resonance and field effects,
steric effect. The Hammett equation and linear free energy relationship, substituent and reaction
constants. Taft equation.
UNIT III (Lectures 08)
Aliphatic Nucleophilic Substitution. The SN2, SN1, mixed SN2 and SN1, and SET mechanisms. The
SNi mechanism. Reactivity effects of substrate structure, attacking nucleophile, leaving group and
reaction medium. The neighbouring group mechanism, neighbouring group participation by Pi and
Sigma bonds. Classical and nonclassical carbocations, norbornyl system, carbocation rearrangements
Aromatic Nucleophilic Substitution. The SNAr, SN1, benzyne and SRN1 mechanisms. Reactivity, effect
of substrate structure, leaving group and attacking nucleophile. Bucherer reaction, alkylation, and
amination. The Bamberger rearrangement. The von Richter rearrangement
UNIT IV (Lectures 08)
Free Radicals. Free radical reactions and their stereochemistry. Allylic halogenation (NBS), oxidation
of aldehydes to carboxylic acids, hydroperoxide formation, replacement of diazonium group.
Hunsdiecker reaction.
Electron spin resonance (ESR) spectroscopy. Electron paramagnetism, derivative curves, g values and
hyperfine splitting.
UNIT V (Lectures 08)
Addition to Carbon-Carbon Multiple Bonds. Mechanistic and stereochemical aspects of addition
reactions. Hydroboration. Michael reaction. Sharpless asymmetric epoxidation. Addition to Carbon-
Hetero atom Multiple Bonds. Mechanism of metal hydride reduction of carbonyl compounds, acids,
esters and nitriles. Wittig reaction. Mechanism of condensation reactions involving enolates. Mannich,
Benzoin, Perkin, and Stobbe reactions.
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 11
Reference Books:
1. March, Jerry. Advanced Organic Chemistry: Reactions, Mechanism and Structure, John Wiley.
2. Sykes, Peter. A Guide Book to mechanism in Organic Chemistry, Longman.
3. Morrison, R. T. and Boyd, R. N. Organic Chemistry, Prentice Hall.
4. Kalsi, P. S. Organic Reactions and their Mechanisms, New Age International Publishers.
5. Mukherji and Singh Reactions Mechanism in Chemistry, Vol. I, II, III, Macmillan.
* Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 12
Semester-I
Physical Chemistry-I Course Code: MCH113 L T P C
4 0 0 4
Objective: The content of this syllabus will give a precise idea about Schrodinger wave equation, its
solution & applications. The student gets familiar with classical thermodynamics & chemical dynamics.
Course Outcomes: The students will be able to find out the solution & applicability of Schrodinger
wave equation, classical thermodynamics & chemical dynamics in day to day life.
Course Contents:
UNIT I (Lectures 08)
Introduction to exact quantum mechanical results. The Schrodinger equation and the postulates of
quantum mechanics. Discussion of solutions of the Schrodinger equation to systems such as particle in
a box, the harmonic oscillator, the rigid rotor, the hydrogen atom.
UNIT II (Lectures 08)
Approximate Methods. The variation theorem, linear variation principle. Perturbation theory
(introductory idea). Application of variation method to the Helium atom.
Angular Momentum. Ordinary angular momentum, generalized angular momentum, eigen functions
for angular momentum, eigen values of angular momentum, addition of angular momenta, spin,
antisymmetric and Pauli exclusion principle.
UNIT III (Lectures 08)
Classical Thermodynamics. Brief resume of concepts of laws of thermodynamics, free energy,
chemical potential and entropies. Partial molar properties; partial molar free energy, partial molar
volume and partial molar heat content and their significance. Determinations of these quantities.
Concept of fugacity and determination of fugacity.
Derivation of phase rule and its application to three component systems, second order phase transitions.
UNIT IV (Lectures 08)
Chemical Dynamics (Part I). Methods of determining rate laws, Arrhenius equation, collision theory
of reaction rates, steric factor, activated complex theory, ionic reactions, kinetic and thermodynamic
control of reactions.
UNIT V (Lectures 08)
Chemical Dynamics (Part II). Dynamic chain (hydrogen-bromine reaction, pyrolysis of acetaldehyde,
decomposition of ethane), photochemical (hydrogen-bromine and hydrogen-chlorine reactions) and
oscillatory reactions, homogeneous catalysis, kinetics of enzyme reactions
Reference Books:
1. Atkins, P.W. Physical Chemistry, ELBS.
2. Young, R-J and Lovell, P.A. Introduction to Polymers, Replika Press Pvt. Ltd.
3. Flory, P.J. Principles of Polymer Chemistry, Asian Book Private Ltd.
4. Thomas, E. and Philip, R. Thermodynamics: Statistical Thermodynamics and Kinetics, Pearson
Education.
5. Moore, J.W. and Pearson, R.G. Kinetics and Mechanism, John Wiley and Sons.
* Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 13
Semester-I
Research Methodology
Course Code: MAT115 L T P C
3 1 0 4
Objective:
• Students should understand a general definition of research design
• Students should know why educational research is undertaken, and the audiences that profit
from research studies
• Students should be able to identify the overall process of designing a research study from its
inception to its report
Course Outcomes: At the end of this course, the students should be able to:
• understand some basic concepts of research and its methodologies
• identify appropriate research topics
• select and define appropriate research problem and parameters
• prepare a project proposal (to undertake a project)
• organize and conduct research (advanced project) in a more appropriate manner
• write a research report and thesis
Course Contents:
UNIT I (Lectures 08)
Research Methodology: Introduction to Research methodology: Meaning, Objective Types of
research & research approaches, Criteria for Good research .Review of Literature. Research problem:
Statement, Purpose, Objective, Necessity of defining the problems. Research design: Meaning, Need
Features, Different research design.
UNIT II (Lectures 08)
Measurement of scaling techniques: Measurement scales, sources of error in measurement, technique
of developing measurement tools, Meaning of scaling, its classification, important scaling techniques.
Methods of collection, Sampling Techniques
UNIT III (Lectures 08)
Introduction to statistics: Meaning, Definition, Characteristics, importance of the study of statistics
.Tabulation of Data: Basic principles of graphical representation, Types of diagrams histograms,
frequency polygons, smooth frequency polygons, cumulative frequency curve. Measures of central
Tendency: Mean, Median Mode, Measures of Dispersion: Range, mean deviation and standard
deviation.
UNIT IV (Lectures 08)
Testing of Hypotheses, Level of significance, Degree of freedom, Student t-test, F- test, Chi Square-
test, Anova-one way & two way; Correlation & regression: Significance, Types of Correlation, Linear
Regression
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 14
UNIT V (Lectures 08)
Interpretation and report writing: Meaning, Techniques of interpretation, significance of report
writing, steps in writing, layout of the research report, types of report and precautions for writing
research report. Use of SPSS in Data Analysis.
Text Books:
1. Dr. J. A Khan: Biostatistics & Research Methodology, APH Publishing.
2. C. R Kothari: Research Methodology, Methods & techniques New age international Publishers.
3. R. Paneerselvam Research Methodology, PHI Learning Second Edition.
4. Kapoor B.K & Gupta S.C, Fundamental of Statistics, S. Chand Publication, New Delhi.
5. Malhotra Naresh K. Marketing Research, Pearson Education.
* Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 15
Semester-I
Inorganic Chemistry-I (Lab) Course Code: MCH161 L T P C
0 0 4 2
Objective: It consists of theoretical principles in qualitative analysis of mixture including basic radicals
& acidic radicals, Separation of cations & anions by chromatography & preparation of inorganic
complexes.
Course Outcomes: After performing this lab students will be able to do qualitative analysis of mixture
including basic radicals & acidic radicals, Separation of cations & anions by chromatography &
preparation of inorganic complexes & identification of unknown complexes by spectral studies.
List of Experiment:
I- Qualitative analysis:
To identify the given cation, anion and interfering radicals (total six including one interfering radical)
from the given inorganic mixture.
II- Chromatography
1. Separation of cations and anions by Paper Chromatography
2. Separation of cations and anions by Column Chromatography; Ion exchange
III- Synthesis:
Preparation of selected inorganic compounds and their studies by measurements of decomposition
temperature, molar conductance and magnetic susceptibility measurements. (Any five)
1. [Co(NH3)6] [Co(NO2)6]
2. cis-[Co(trien) (NO2)2]Cl.H2O
3. Hg[Co(SCN)4]
4. [Co(Py)2Cl2]
5. [Ni(NH3)6]Cl2
6. [Ni(dmg)2]
7. [Cu(NH3)4]SO4. H2O
8. aquabis(acetylacetonato) nitrosylchromium (I), [Cr(NO)(acac)2(H2O)]
9. Cis-Bis(glycinato) copper(II) and trans-Bis (glycinato) copper (II)
10. Preparation of Zn, Cd and Hg thiocyanates from their respective chlorides
11. Bis (benzoylacetonato) copper (II)
12. Bis (acetylacetonato) oxovanadium (IV), [VO(acac)2][MoO2(acac)2]
13. Hexaammminenickel (II) tetrafluoroborate, [Ni(NH3)6](BF4)2 and determination of nickel
content gravimetrically.
14. Potassium tris (oxalato) ferrate, K3[Fe(C2O4)3] and determination of oxalate using
permanganate.
15. Preparation of N, N-bis(salicylaldehyde)ethylenediamine [salenH2], Co(salen)
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 16
Evaluation Scheme of Practical Examination:
Internal Evaluation (50 marks)
Each experiment would be evaluated by the faculty concerned on the date of the experiment on a 4-
point scale which would include the practical conducted by the students and a Viva taken by the faculty
concerned. The marks shall be entered on the index sheet of the practical file.
Evaluation scheme:
PRACTICAL PERFORMANCE & VIVA DURING THE
SEMESTER (35 MARKS)
ON THE DAY OF EXAM
(15 MARKS)
TOTAL
INTERNAL
(50 MARKS) EXPERIMENT
(5 MARKS)
FILE WORK
(10 MARKS)
VIVA
(10 MARKS)
ATTENDANCE
(10 MARKS)
EXPERIMENT
(5 MARKS)
VIVA
(10 MARKS)
External Evaluation (50 marks)
The external evaluation would also be done by the external Examiner based on the experiment
conducted during the examination.
EXPERIMENT
(20 MARKS)
FILE WORK
(10 MARKS) VIVA
(20 MARKS) TOTAL EXTERNAL
(50 MARKS)
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 17
Semester-I
Physical Chemistry-I (Lab) Course Code: MCH162 L T P C
0 0 4 2
Objective: It consists of various principles involved during Lab work. During experiments, students
can perform experiments concerning adsorption, phase equilibria, and chemical kinetics etc.
Course Outcomes: After completion of all the experiments students will be able to perform various
experiments for example, adsorption, Polarimetry, chemical kinetics etc.
List of Experiment:
1. To study surface tension -concentration relationship for solutions (Gibbs equation).
2. To construct the phase diagram for three component system (e.g., chloroform-acetic acid-
water).
3. To calculate specific rotation of sucrose
4. Enzyme kinetics -inversion of sucrose
5. Determine the rate constant of hydrolysis of an ester as methyl acetate catalysed by an acid.
Determine also the energy of activation of the reaction
6. Determination of the primary salt effect on the kinetics of ionic reactions and testing of the
Bronsted relationship (iodide ion is oxidised by persulphate ion)
7. Determination of the velocity constant of hydrolysis of an ester and to study the effect of change
of concentration on it.
8. To study the adsorption of oxalic acid on charcoal and to prove the validity of Freundlich
adsorption isotherm.
9. To study the adsorption of oxalic acid on charcoal and to prove the validity of Langmuir’s
adsorption isotherm.
10. To study the variation of thermo emf with the temperature for the copper-iron thermocouple.
11. To study forward and reverse characteristics of Si and Ge semiconductor diode
Evaluation Scheme of Practical Examination:
Internal Evaluation (50 marks)
Each experiment would be evaluated by the faculty concerned on the date of the experiment on a 4-
point scale which would include the practical conducted by the students and a Viva taken by the faculty
concerned. The marks shall be entered on the index sheet of the practical file.
Evaluation scheme:
PRACTICAL PERFORMANCE & VIVA DURING THE
SEMESTER (35 MARKS)
ON THE DAY OF EXAM
(15 MARKS)
TOTAL
INTERNAL
(50 MARKS) EXPERIMENT
(5 MARKS)
FILE WORK
(10 MARKS)
VIVA
(10 MARKS)
ATTENDANCE
(10 MARKS)
EXPERIMENT
(5 MARKS)
VIVA
(10 MARKS)
External Evaluation (50 marks)
The external evaluation would also be done by the external Examiner based on the experiment
conducted during the examination.
EXPERIMENT
(20 MARKS)
FILE WORK
(10 MARKS) VIVA
(20 MARKS) TOTAL EXTERNAL
(50 MARKS)
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 18
Semester I DISCIPLINE & GENERAL PROFICIENCY
Course Code: MSC111
There shall be continuous evaluation of the student on the following broad parameters:
1. Observance of dress code.
2. Participation in Conferences /Workshops / Seminars.
3. Attendance in guest lectures, invited talks and special technical sessions organized from time to
time.
4. Participation in community projects including NSS.
5. Exhibiting team spirit in different Culture & extra curriculum activities, Department Club activities
of the University and College organized from time to time.
6. Observance of rule & regulations in the College/University, Behavior in Campus Premises, Bus,
hostel mess and hostel.
7. Performance and awards received in different events (sports/ co-curricular activities) organized at
College / University and other level.
8. General behavior
9. Any extraordinary achievement.
The above is an indicative list of parameters on which the students shall be continuously evaluated.
The college may evaluate the student on the specific parameters by informing them through a notice
displayed on the notice board before evaluation. There shall be no external examination for this course;
however, the marks shall be included for calculation of cumulative Performance Index (CPI).
Head of Department would be display GP marks on notice board in prescribed format after IInd &
IIIrd CT in semester:
S
N
o
Enroll
No.
Student
Name
Dress
code
Participation
in
Conferences
/Workshops
/ Seminars
Participation
in guest
lectures,
invited talks
and special
technical
sessions
Participation
in
community
Services
Participation
in Culture &
extra
curriculum
activities,
Department
Club
Activities
Participation
in
sports/ co-
curricular
activities
General
Behavior
Any Extra
Achievement
(5) (15) (20) (10) (20) (20) (5) (5)
Res
po
nsi
ble
fo
r
ma
rks
Men
tor
Hea
d
Hea
d
Men
tor
Cu
ltura
l E
ven
ts
Co
ord
inat
or
&
Dep
artm
ent
Clu
b
Co
ord
inat
or
Sp
ort
s C
oo
rdin
ator
Men
tor
Dir
ecto
r o
r
Pri
nci
pal
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 19
Semester-II
Inorganic Chemistry-II
Course Code: MCH211 L T P C
4 0 0 4
Objective: The course content consists of synthesis, reactivity & nature of bonding of transition metal
π acid complexes. The wade's rule & the capping rule have been applied to predict the geometry of
HNCC. ESR spectroscopy has used for deterring the unpaired electron in complexes. X-ray
crystallography has been applied for crystallographic studies. Mossbauer spectroscopy has been
specially taught to know the nuclear environment of Iron & Tin compounds.
Course Outcomes: The nature of bonding synthesis & reactivity of transition metal π-acid complexes
has been studied with a special reference to CO, NO etc. The kinetics & reaction mechanism of
inorganic complexes have been studied. ESR & Mossbauer spectroscopy have been applied for the
structural determination of the complexes.
Course Contents:
UNIT I (Lectures 08)
Metal π-complexes: Metal carbonyls, structure & bonding, important reactions of metal carbonyls,
preparation, bonding, structure & important reactions of transition metal nitrosyls, dinitrogen, dioxygen
complexes & tertiary phosphine as ligands.
UNIT II (Lectures 08)
Metal cluster compounds: Introduction, metal carbonyl clusters; Low Nuclearity (M3 M4) clusters:
isoelectronic and isolobal relaltionships high nuclearity carbonyl clusters; hetero atoms in metal atom
clusters, electron counting schemes for HNCC: HNCC of Fe, Ru, Os, Co, Rh,
a) Lower halide and chalcogenide clusters, octahedral metal halide, chalocogenide clusters, triangular
clusters.
b) Compounds with M-M multiple bonds; I) Major structural types; quadrupole bonds
Bonding and topology of boranes, 4-digit coding (s, t, y, x) numbers for B2H6, B4H10, B5H9, B5H11 and
B6H10 and their utilities
UNIT III (Lectures 08)
Organic Reagents in Inorganic Chemistry: Chelation, factors determining the stability of chelates
(effect of ring size, oxidation state of the metal, coordination number of the metal); Use of the following
reagents in analysis:
(a) Dimethylglyoxime (in analytical chemistry)
(b) EDTA (in analytical chemistry)
(c) 8-Hydroxyquinoline (in analytical chemistry)
(d) 1,10-Phenanthroline (in analytical chemistry)
(e) Thiosemicarbazones (in analytical chemistry)
(f) Dithiazone (in analytical chemistry)
UNIT IV (Lectures 08)
Magneto chemistry: Origin of Magnetic moment, factors determining Para magnetism, application of
magneto chemistry in co-ordination chemistry (spin only moment, Russell Saunder’s coupling,
quenching of orbital angular moment, orbital contribution to a magnetic moment) in spin free and spin
paired octahedral and tetrahedral complexes. Magnetic susceptibility (diamagnetic, paramagnetic) and
its measurements, Van Vlecks formula for magnetic susceptibility, temperature dependence of
magnetic
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 20
UNIT V (Lectures 08)
Mossbauer spectroscopy - Mossbauer effect, recoilless emission and absorption, hyperfine
interaction, chemical isomer shift, magnetic hyperfine and quadruple interaction, Application of the
technique to the studies of (1) bonding and structures of Fe+2 and Fe+3 compounds including those of
intermediate spin, (2) Sn+2 and Sn+4 compounds and (3) detection of oxidation state
Reference Books:
1. Cotton, F.A. and Wilkinson, G. Advanced Inorganic Chemistry, Wiley eastern.
2. Shriver, D.F., Atkins, P.W. and Langford, C.H. Inorganic Chemistry, ELMS, Oxford.
3. William W. Porterfield, Inorganic Chemistry.
4. K.F. Purcell and J.C. Kotz. An Introduction to Inorganic Chemistry.
5. Huheey, J.E. Inorganic Chemistry, Pearson.
* Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 21
Semester-II
Organic Chemistry-II Course Code: MCH212 L T P C
4 0 0 4
Objective: The course content consists of scope & mechanism of Elimination reaction, Pericyclic
reaction oxidation reactions & reduction reactions.
Course Outcomes: This syllabus will have boon to the students appearing for various competitive
exam. A vast knowledge of this paper used in future to solve problem in research & Industries.
Course Contents:
UNIT I (Lectures 08)
Elimination Reactions. The E2, E1 and E1cB mechanisms and their spectrum. Orientation of the double
bond. Reactivity, effect of substrate structure, attacking base, the leaving group and the medium.
Elimination versus substitution. Mechanism and orientation in pyrolytic elimination. The Hofmann
degradation. Dihalo-elimination. Decomposition of toluene-p-sulphonylhydrazones. Conversion of
ketoximes to nitriles. N-Nitrosoamine to diazoalkane transformation
UNIT II (Lectures 08)
Pericyclic Reactions: Molecular orbitals and their symmetry. Molecular orbitals of ethylene, 1,3-
butadiene, 1,3,5-hexatriene and allyl system, and their symmetry properties.
Pericyclic reactions. Characteristics and classification. Electrocyclic reactions: conrotatory and
disrotatory motions, 4n, 4n+2 and allyl systems. Woodward-Hoffmann correlation diagrams. FMO and
PMO approach.
Cycloaddditions. Woodward-Hoffmann correlation diagrams. FMO and PMO approach. Antarafacial
and suprafacial additions. 4n and 4n+2 systems, 2+2 addition of ketenes. Ene synthesis.
Sigmatropic Rearrangements. Suprafacial and antarafacial 1,3- and 1,5- shifts of H, sigmatropic shifts
involving carbon moieties, 2,3-, and 3,3-sigmatropic rearrangements. Claisen, Cope, aza-Cope,
Sommlet-Hauser, and Fisher Indole rearrangements
UNIT III (Lectures 08)
Oxidation. Oxidation of carboncarbon double bond. Perhydroxylation, potassium permanganate,
osmium tetroxide, iodine together with silver carboxylates, ozonolysis. Enantioselective epoxidation
of allylic alcohols (Sharpless epoxidation). Oxidation of alcohols. Chromic acid, chromiun (VI) oxide-
pyridine complexes, manganese (IV) oxide, silver carbonate, oxidation via alkoxysulphonium salts.
Baeyer-Villiger oxidation of ketones. Oxidation with ruthenium tetroxide, thallium(III) nitrate and
iodobenzene diacetate.
UNIT IV (Lectures 08)
Reduction. Catalytic hydrogenation (homogeneous and heterogenous). Stereochemistry and
mechanism, selectivity of reduction.
Reduction by dissolving metals. Metal and acid, metal and alcohol, metal and ammonia.
Reduction by hydride-transfer reagents. Aluminium alkoxides, lithium aluminium hydride, sodium
borohydride, lithium hydrido-alkoxyaluminates.
Wokff-Kishner reduction. Reduction with di-imide
UNIT V (Lectures 08)
Designing organic synthesis. The Disconnection Approach. Basic principles, synthons, functional
group interconversions. Order of events in organic synthesis. One group CX disconnections and two
group CX disconnections. Chemos electivity. Reversal of polarity (umpolung). Amine synthesis
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 22
Rearrangements
General mechanistic considerations-nature of migration, migratory aptitude,
memory effects. A detailed study of the following rearrangements: Benzil-Benzilic acid,
Favorskii,Arndt-Eistert synthesis, Neber, Backmann, Hofmann, Curtius, Schmidt, Benzidine, Baeyer-
Villiger, Shapiro reaction, Witting rearrangement and Stevens rearrangement
Reference Books:
1. March, Jerry. Advanced Organic Chemistry: Reactions, Mechanism and Structure, John Wiley.
2. Sykes, Peter. A Guide Book to mechanism in Organic Chemistry, Longman.
3. Morrison, R. T. and Boyd, R. N. Organic Chemistry, Prentice Hall.
4. Kalsi, P. S. Organic Reactions and their Mechanisms, New Age International Publishers.
5. Mukherji, S.M. and Singh, S.P. Reactions Mechanism in Chemistry, Vol. I, II, III, Macmillan.
6. Kalsi, P.S. Stereochemistry of Organic Compounds, New Age International.
7. Kalsi, P.S. Stereochemistry: Conformation and Mechanism, Wiley Eastern Limited.
* Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 23
Semester-II
Physical Chemistry-II Course Code: MCH213 L T P C
4 0 0 4
Objective: Chemical kinetics consists of basic concept of order of the reaction, molecularity, and rate
law. The impact of temperature on the rate of reaction & determination of rate constant. The physical
& chemical reactions have been explained through collision theory, Activated complex theory &
kinetics of complex reaction. The potential energy surface & reaction mechanism are of great interest.
The theories of unimolecular gaseous reactions and their applications of state theory to unimolecular
decomposition. The statistical & mechanical derivation of rate constant of a gaseous bimolecular
reactions have been used using TST.
Course Outcome:
Chemical kinetics is of great interest to know the rate of reactions. The rate of complex reaction is
determined by slow step of the complex reaction. The rate law has given experimental proof to express
the order of the reactions. The reaction rates have been studied by different theories. Potential energy
surface & reaction mechanism are used to calculate molecular dynamics. The partition function &
chemical equilibrium are very important to understand RRK & RRKM theories. The rate constant of
gaseous bimolecular reactions has been determined using TST.
Course Contents:
UNIT I (Lectures 08)
Chemical Dynamics (Part III). General features of fast reactions, study of fast reactions by flow method,
relaxation method, flash photolysis and the nuclear magnetic resonance method. Dynamics of
molecular motions and of barrier less chemical reactions in solution, probing the transition state.
Dynamics of unimolecular reactions; Lindemann-Hinshelwood and Rice-Ramsperger-Kassel-Marcus
and Slater theories of unimolecular reactions.
UNIT II (Lectures 08)
Adsorption. Surface tension, capillary action, pressure difference across curved surface, Laplace
equation, vapour pressure of droplets, Kelvin equation; Gibbs adsorption isotherm. Multilayer
adsorption, BET equation. Calculation of surface area, catalytic activity at surfaces. Surface films on
liquids; electrokinetic phenomena; surface active agents. Micellisation, hydrophobic interaction.
Critical micellar concentration. Solubilisation. Donnan’s membrane equilibria.
UNIT III (Lectures 08)
Electrochemistry of solutions. Debye-Huckel -Onsager treatment and its extension to concentrated
solutions. Ion size factor and ion-solvent interactions. Concept of activity. Determination of mean ionic
activity and activity coefficient. Lippmannn electrocapillary phenomenon. Electrocapillary curves of
mercury and their interpretation. Structure of electrified interfaces. Helmholtz, Guoy and Chapmann
and Stern models. Introductory idea of advancements in electrified surfaces. Electro kinetic potential,
its determination and significance.
UNIT IV (Lectures 08)
Irreversible electrode phenomenon. Decomposition voltage and overvoltage. Consecutive electrode
processes. Exchange current density. Butler-Volmer’s equation. Tafel’s plot. Theory of polarography.
Ilkovic equation. Half wave potential and its significance.
Introduction to corrosion. Forms of corrosion. Corrosion monitoring and prevention
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 24
UNIT V (Lectures 08)
Applied Electrochemistry Electro chemistry: Nernst equation, electrode kinetics, electrical double
layer, Debye-Huckel theory. Voltammetry, Current voltage relationship, Characteristic of DME, Half
wave potential. Amperometric titrations, Corrosion: Introduction to corrosion, forms of corrosion,
corrosion monitoring and prevention methods.
Reference Books:
1. Maron, S. HandPrutton, C.F. Principles of Physical Chemistry, Oxford and IBH publishing.
2. Laidler, Keith J. Chemical Kinetics, New York: Harper & Row Publishers.
3. Atkins, P.W. Physical Chemistry, ELBS.
4. Thomson, S.J. and Webb, G. Heterogeneous Catalysis, Edinburgh; London: Oliver & Boyd.
5. Moore, J.W. and Pearson, R.G. Kinetics and Mechanism, John Wileyand Sons.
6. Silbey, R.J., Alberty, R.A. and Bawendi, M.G. Physical Chemistry, Wiley-Interscience
Publication.
* Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 25
Semester-II
Spectroscopy-I Course Code: MCH214 L T P C
4 0 0 4
Objective: The syllabus deals with theory, principal & instrumentation of various spectroscopic
techniques like Microwave, rotational, vibrational & electronic spectroscopy.
Course Outcomes: After thorough study of this paper, students get able to explain how & why spectral
transition in a molecule can occurs.
Course Contents:
UNIT I (Lectures 08)
Unifying Principles. Electromagnetic radiation, interaction of electromagnetic radiation with matter-
absorption, emission, transmission, reflection, refraction, dispersion, polarization and scattering.
Uncertainty relation and natural line width and natural line broadening, transition probability, transition
moment, selection rules, intensity of spectral lines.
UNIT II (Lectures 08)
Microwave Spectroscopy. Classification of molecules, rigid rotor model, effect of isotopic substitution
on the transition frequencies, intensities, non-rigid rotor. Stark effect, nuclear and electron spin
interaction and effect of external field. Applications.
UNIT III (Lectures 08)
Infrared Spectroscopy. Review of linear harmonic oscillator, vibrational energies of diatomic
molecules, zero-point energy, force constant and bond strengths; anharmonicity, Morse potential
energy diagram, vibration-rotation spectroscopy, P, Q, R branches. Vibrations of polyatomic
molecules. Selection rules, normal modes of vibration, group frequencies, overtones, hot bands, factors
affecting the band positions and intensities, far IR region.
UNIT IV (Lectures 08)
Raman Spectroscopy. Classical and quantum theories of Raman effect. Pure rotational, vibrational and
vibrational-rotational Raman spectra, selection rules, mutual exclusion principle. Resonance Raman
spectroscopy, coherent anti Stokes Raman spectroscopy (CARS).
UNIT V (Lectures 08)
Infrared and Raman Spectroscopy. Instrumentation and sample handling. Calculation of vibrational
frequencies. Characteristic vibrational frequencies of alkanes, alkenes, alkynes, carbonyl compounds,
alcohols, ethers, amines, phenols and aromatic compounds. Finger-print region. Effect of hydrogen
bonding and solvent effect on vibrational frequencies, overtones, combination bands and Fermi
resonance. FT-IR.
Resonance Raman effect. Concept and factors that influence group frequencies
Reference Books:
1. Drago, R. S. Physical Methods in Chemistry, Reinhold Publishing Corporation.
2. Silverstein, R.M. Bassler, G. C. and Morrill, T.C. Spectrometric Identification of Organic
Compounds, Wiley.
3. Kemp, W. Organic Spectroscopy, Macmillan.
4. Dyer, J. R. Application of Absorption Spectroscopy of Organic Compounds, Prentice Hall.
5. Williams, D. H. and Fleming, I. Spectroscopic Problems in Organic Chemistry, McGraw Hill.
6. Barrow, G.M. Introduction to Molecular Spectroscopy, McGraw Hill.
7. Banwell, C.N. Fundamentals of Molecular Spectroscopy, McGraw Hill.
* Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 26
Semester-II
Organic Chemistry-I (Lab) Course Code: MCH261 L T P C
0 0 4 2
Objective: The course content consists of design of organic compounds using oxidation reactions, aldol
condensation, Sand Meyer reaction & electrophilic substitution.
Course Outcomes: After performing these lab experiments student will be able to design the strategy
for synthesize organic compounds using various chemical processes & their purification by
chromatographic technique.
List of Experiments:
I- Analysis
Separation, purification and identification of compounds of binary mixture (one solid and one
liquid/solid) using chemical separation and sublimation/distillation, etc. Their analysis by semi-micro
chemical tests and spot tests.
II- Organic Synthesis
Aromatic electrophilic substitutions:
1. Synthesis of m-dinitrobenzene from nitrobenzene
2. Synthesis of 2,4-dinitro-1-chlorobenzene from chlorobenzene
3. Synthesis of 4-bromoaniline from acetanilide
Reduction reaction:
4. Synthesis of m-nitroaniline from m-dinitrobenzene
Oxidation reaction:
5. Synthesis of 9,10-anthraquinone by oxidation of anthracene by chromium trioxide
6. Synthesis of 4-nitrobenzaldehyde by oxidation of 4-nitrotoluene by chromium trioxide
Cannizzaro reaction:
7. Synthesis of benzyl alcohol from benzaldehyde
Claisen-Schmidt reaction:
8. Synthesis of dibenzylidene acetone (1,5-diphenylpenta-1,4-dien-3-one) from acetone and
benzaldehyde
Sandmeyer reaction:
9. Synthesis of 2-chlorobenzoic acid from anthranilic acid
Methylation:
10. Synthesis of methyl 2-naphthyl ether (2-methoxynaphthalene, nerolin) by methylation of 2-
naphthol by dimethyl sulphate.
Purification of compounds by TLC and column chromatography.
Evaluation Scheme of Practical Examination:
Internal Evaluation (50 marks)
Each experiment would be evaluated by the faculty concerned on the date of the experiment on a 4-
point scale which would include the practical conducted by the students and a Viva taken by the faculty
concerned. The marks shall be entered on the index sheet of the practical file.
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 27
Evaluation scheme:
PRACTICAL PERFORMANCE & VIVA DURING THE
SEMESTER (35 MARKS)
ON THE DAY OF EXAM
(15 MARKS)
TOTAL
INTERNAL
(50 MARKS) EXPERIMENT
(5 MARKS)
FILE WORK
(10 MARKS)
VIVA
(10 MARKS)
ATTENDANCE
(10 MARKS)
EXPERIMENT
(5 MARKS)
VIVA
(10 MARKS)
External Evaluation (50 marks)
The external evaluation would also be done by the external Examiner based on the experiment
conducted during the examination.
EXPERIMENT
(20 MARKS)
FILE WORK
(10 MARKS) VIVA
(20 MARKS) TOTAL EXTERNAL
(50 MARKS)
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 28
Semester-II
Inorganic Chemistry-II (Lab) Course Code: MCH262 L T P C
0 0 4 2
Objective: This course content consists of gravimetric & volumetric estimation of pairs of metal ions
in solutions. Separation & identification of cations & anions by paper chromatography using aqueous
& non-aqueous media have been included.
Course Outcomes: The quantitative separation & determination of Silver & Copper, copper & Zinc,
Iron & calcium, magnesium & calcium have been done gravimetrically & volumetrically. Separation
of cations & anions has been done by paper chromatography using aqueous & non-aqueous media.
List of Experiments:
I. Gravimetric and Volumetric Estimation.
1. Estimate mixture of two metal ions (Copper and Zinc)
II. Sectrophotometric Determination
1. Determination of molecular composition of ferric salicilate /iron-phenanthroline/iron-dipyridyl
complex by Job’s method of continuous variation
2. Stability constant of FeSCN2+ complex
3. Determination of the pH of a given solution by spectrophotometry using methyl red indicator
III. Synthesis (Any Five)
1. Aquabis(acetylacetonato)nitrosylchromium(I), [Cr(NO)(acac)2(H2O)]
2. cis-Bis(glycinato)copper(II) and trans-Bis(glycinato)copper(II)
3. Preparation of Zn, Cd and Hg thiocyanates from their respective chlorides
4. Bis(benzoylacetonato)copper(II)
5. Bis(acetylacetonato)oxovanadium(IV), [VO(acac)2]
6. [MoO2(acac)2]
7. Hexaammminenickel(II)tetrafluoroborate, [Ni(NH3)6](BF4)2 and determination of nickel
content gravimetrically. 8. Potassium tris(oxalato)ferrate, K3[Fe(C2O4)3] and determination of oxalate using permanganate.
9. Preparation of N, N-bis(salicylaldehyde)ethylenediamine [salenH2], Co(salen)
Evaluation Scheme of Practical Examination:
Internal Evaluation (50 marks)
Each experiment would be evaluated by the faculty concerned on the date of the experiment on a 4-
point scale which would include the practical conducted by the students and a Viva taken by the faculty
concerned. The marks shall be entered on the index sheet of the practical file.
Evaluation scheme:
PRACTICAL PERFORMANCE & VIVA DURING THE
SEMESTER (35 MARKS)
ON THE DAY OF EXAM
(15 MARKS)
TOTAL
INTERNAL
(50 MARKS) EXPERIMENT
(5 MARKS)
FILE WORK
(10 MARKS)
VIVA
(10 MARKS)
ATTENDANCE
(10 MARKS)
EXPERIMENT
(5 MARKS)
VIVA
(10 MARKS)
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 29
External Evaluation (50 marks)
The external evaluation would also be done by the external Examiner based on the experiment
conducted during the examination.
EXPERIMENT
(20 MARKS)
FILE WORK
(10 MARKS) VIVA
(20 MARKS) TOTAL EXTERNAL
(50 MARKS)
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 30
Semester II DISCIPLINE & GENERAL PROFICIENCY
Course Code: MSC211
There shall be continuous evaluation of the student on the following broad parameters:
1. Observance of dress code.
2. Participation in Conferences /Workshops / Seminars.
3. Attendance in guest lectures, invited talks and special technical sessions organized from time to
time.
4. Participation in community projects including NSS.
5. Exhibiting team spirit in different Culture & extra curriculum activities, Department Club activities
of the University and College organized from time to time.
6. Observance of rule & regulations in the College/University, Behavior in Campus Premises, Bus,
hostel mess and hostel.
7. Performance and awards received in different events (sports/ co-curricular activities) organized at
College / University and other level.
8. General behavior
9. Any extraordinary achievement.
The above is an indicative list of parameters on which the students shall be continuously evaluated.
The college may evaluate the student on the specific parameters by informing them through a notice
displayed on the notice board before evaluation. There shall be no external examination for this course;
however, the marks shall be included for calculation of cumulative Performance Index (CPI).
Head of Department would be display GP marks on notice board in prescribed format after IInd &
IIIrd CT in semester:
S
N
o
Enroll
No.
Student
Name
Dress
code
Participation
in
Conferences
/Workshops
/ Seminars
Participation
in guest
lectures,
invited talks
and special
technical
sessions
Participation
in
community
Services
Participation
in Culture &
extra
curriculum
activities,
Department
Club
Activities
Participation
in
sports/ co-
curricular
activities
General
Behavior
Any Extra
Achievement
(5) (15) (20) (10) (20) (20) (5) (5)
Res
po
nsi
ble
fo
r
ma
rks
Men
tor
Hea
d
Hea
d
Men
tor
Cu
ltura
l E
ven
ts
Co
ord
inat
or
&
Dep
artm
ent
Clu
b
Co
ord
inat
or
Sp
ort
s C
oo
rdin
ator
Men
tor
Dir
ecto
r o
r
Pri
nci
pal
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 31
Semester-III
Spectroscopy-II
Course Code: MCH311 L T P C
4 0 0 4
Objective: This course content consists of principles & application of UV & visible spectroscopy,
NMR, Mass spectroscopy.
Course Outcomes: Methods particularly UV IR, NMR & X-ray diffractions is helpful in structural
elucidation & interpretation structure of unknown f Organic compounds which ultimately help in
modern technology in Bio chemistry, Biotechnology, Nanoscience etc.
Course Contents:
UNIT I (Lectures 08)
UV and Visible Spectroscopy of organic molecules: Measurement techniques, Beer – Lambert's Law,
molar extinction coefficient, oscillator strength and intensity of the electronic transition, Frank Condon
Principle, Ground and first excited electronic states of diatomic molecules, relationship of potential
energy curves to electronic spectra, Chromophores, auxochromes, blue shift, red shift, hypo and
hyperchromic effect, transitions in organic molecules, Woodward rules for conjugated dienes,
unsaturated carbonyl groups, , Quantitative applications.
UNIT II (Lectures 08)
Nuclear Magnetic Resonance Spectroscopy: PMR: The spinning nucleus, effect of external magnetic
field, processional motion and frequency, Energy transitions, Chemical shift. Factors influencing
chemical shift, anisotropic effect; spin-spin coupling coupling constant, Methods of resolving complex
spectra, Applications of PMR in structural elucidation of simple and complex compounds. 13C NMR,
Deuterium, fluorine and phosphorus NMR, Structural applications of 13C-NMR.
Electron paramagnetic resonance: EPR spectroscopy of inorganic and organic compounds with
unpaired electrons. Measurement of hyperfine splitting.
UNIT III (Lectures 08)
Mass Spectroscopy: Introduction, methods of ionization EI & CI, Ion analysis methods (in brief),
isotope abundance, Metastable ions, general rules predicting the fragmentation patterns. Nitrogen rule,
determination of molecular ion peak, index of H deficiency, fragmentation patterns for aliphatic
compounds, amines, aldehydes, Ketones, esters, amides, nitriles, carboxylic acids ethers, aromatic
compounds etc.
UNIT IV (Lectures 08)
Photoelectron Spectroscopy: Basic principles; photo-electric effect, ionization process, Koopman's
theorem. Photoelectron spectra of simple molecules, ESCA, chemical information from ESCA. Auger
electron spectroscopy -basic idea. Photoacoustic Spectroscopy. Basic principles of photoacoustic
spectroscopy (PAS), chemical and surface applications
UNIT V (Lectures 08)
X-ray Diffraction. Bragg condition, Miller indices, Laue method, Bragg method, Debye-Scherrer
method of X-ray structural analysis of crystals, index reflections, identification of Unit cells from
systematic absences in diffraction pattern. Structure of simple lattices and X-ray intensities, structure
factor and its relation to intensity and electron density. Description of the procedure for an X-ray
structure analysis.
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 32
Reference Books:
1. Drago, R. S. Physical Methods in Chemistry, Reinhold Publishing Corporation.
2. Silverstein, R. M. Bassler, G.C. and Morrill, T.C. Spectrometric Identification of Organic
Compounds, Wiley.
3. Kemp, W. Organic Spectroscopy, Macmillan.
4. Dyer, J. R. Application of Absorption Spectroscopy of Organic Compounds, Prentice Hall.
5. Williams, D. H. and Fleming, I. Spectroscopic Problems in Organic Chemistry, McGraw Hill.
6. Barrow, G.M. Introduction to Molecular Spectroscopy, McGraw Hill.
7. Banwell, C.N. Fundamentals of Molecular Spectroscopy, McGraw Hill.
8. Pavia, D.L., Lampan, G.M. and Kriz, G. S. Introduction to Spectroscopy, Hartcourt College
Publishers, 2001.
* Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 33
Semester-III
Polymer Chemistry Course Code: MCH312 L T P C
4 0 0 4
Objective: This course aims to develop the fundamental, critical thinking, problem solving and
communication skills of students who will be subsequently working as professional chemists with a
specialization in the area of polymer chemistry.
Course Outcomes: On completion of this course students should be able to:
• develop a systematic approach to solving problems in areas related to polymer science;
• apply a range of laboratory techniques to the study of the properties, and to the characterization, of
polymers
Course Contents:
UNIT I (Lectures 08)
Basics of Polymers. Repeating Units, degree of polymerization, linear, branched and network
polymers. Classification of polymers. Addition, radical, ionic, coordination and condensation
polymerization; their mechanism and examples.
Polymerization conditions and polymer reactions. Polymerization in homogeneous and heterogeneous
systems.
UNIT II (Lectures 08)
Polymer Characterization. Significance of molecular weight of polymer. Polydispersive average
molecular weight. Number, weight and viscosity average weights. Measurement of molecular weights.
End group, viscosity, light scattering, osmotic and ultracentrifugation methods.
Chemical and spectroscopic analysis of polymers. X-Ray diffraction study. Thermal analysis, tensile
strength, fatique, impact. Tear resistance. Hardness and abrasion resistance.
UNIT III (Lectures 08)
Structure and Properties. Configuration of polymer chains. Crystal structure of polymers. Morphology
of crystalline polymers. Polymer structure and physical properties; crystalline melting point Tm,
melting points of homogeneous series, effect of chain flexibility and other steric factors, entropy and
heat of fusion. The glass transition temperature, Tg relationship between Tm and Tg, effects of
molecular weight, diluents, chemical structure, chain topology, branching and cross linking. Property
requirements and polymer utilization.
UNIT IV (Lectures 08)
Polymer Processing. Plastics, elastomers and fibres. Compounding. Processing techniques,
Calendering, die casting, rotational casting, film casting, injection moulding, blow moulding, extrusion
moudling, thermoforming, foaming, reinforcing and fibre spinning.
UNIT V (Lectures 08)
Properties of Polymers. Properties of polyethylene, polyvinyl chloride, polyamides, polyesters,
phenolic resins, epoxy resins and silicone polymers. Functional polymers. Fire retarding polymers, and
electrically conducting polymers. Biomedical polymers. contact lens, dental polymers, artificial heart,
kidney, skin and blood cells.
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 34
Reference Books:
1. Shashi Chawala, Polymer Chemistry, Dhanpat Rai.
2. Gowariker, A text book of Polymer Chemistry Wiley
* Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 35
Semester-III
Chemistry of Nano-materials Course Code: MCH313 L T P C
4 0 0 4
Objective: This course content consists of classification, processing, Characterization of nano-
materials & their application in day to day life.
Course Outcomes: The student will be able to learn the role of Chemistry in designing the material of
nanometer scale and the principles behind advanced experimental and computational techniques for
studying nonmaterial.
Course Contents:
UNIT I (Lectures 08)
Introduction: Definition, Role of Bottom-up and Top-Down approaches in Nano technology,
Challenges in Nano technology, History of Nanomaterials, Causes of interest in nanomaterials,
Fundamental issues in nanomaterials, Basic concepts of Nano science and technology, Quantum wire,
Quantum well, Quantum dot, Properties and technological advantages of Nano materials.
UNIT II (Lectures 08)
Processing of nanomaterials-I: Material processing by Sol-Gel method, Chemical Vapour deposition
and Physical Vapor deposition, Microwave Synthesis of materials, Top-down (Nanolithography,
CVD), Bottom-up (Sol-get processing, chemical synthesis). Wet Deposition techniques, Self-assembly
(Supramolecular approach).
UNIT III (Lectures 08)
Processing of nanomaterials-II: Use of bacteria, fungi, Actinomycetes for nanoparticle synthesis,
Magneto tactic bacteria for natural synthesis of magnetic nanoparticles; Viruses as components for the
formation of nanostructured materials; Synthesis process and application, Role of plants in nanoparticle
synthesis.
UNIT IV (Lectures 08)
Characterization Techniques: Crystallography, particle size determination, surface structure,
Scanning Prob Microscopy (SPM), Atomic Force Microscopy (AFM), Field Ion Microscopy, Scanning
Electron Microscopy, Transmission Electron Microscopy (TEM), Infra red and Raman Spectroscopy,
X-ray Spectroscopy, Magnetic resonance, Optical and Vibrational Spectroscopy, Luminescence.
UNIT V (Lectures 08)
Applications: Solar energy conversion and catalysis, Polymers with a special architecture, Liquid
crystalline systems, Applications in displays and other devices, Advanced organic materials for data
storage, Photonics, Plasmonics, Chemical and biosensors, Nanomedicine and Nanobiotechnology.
Reference Books:
1. Nano materials by J. Dutta & H. Hofman.
2. Mick Wilson, Kamali Kannagara et.al., “NANOTECHLOGY-basic science and emerging
technologies, University of new south wales press ltd.
3. Hari Singh Nalwa, “Nanostructured Materials and Nanotechnology”, Academic Press.
4. A. Nabok, “Organic and Inorganic Nanostructures”, Artech House.
5. C. Dupas, P. Houdy, M. Lahmani, Nanoscience: “Nanotechnologies and Nanophysics”, Springer-
Verlag Berlin Heidelberg.
6. Nanomedicine, Vol. IIA: Biocompatibility by Robert A. Freitas.
7. Nanotechnology by Mark Ratner and Daniel Ratner, Pearson Education. * Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 36
Semester-III
Chemistry of Natural Products
Course Code: MCH314 L T P C
4 0 0 4
Objective: The course content consists of classification, isolation & biosynthesis of common plant
products. A natural product has also been prepared by coenzyme. The compounds & their derivatives
have been studied for their applications. Synthesis, application & structural studies of Antibiotics,
Terpenoids, and alkaloids have been done. The steroids are the chemical compounds which are widely
used to control acute diseases & they are given in specific condition. The biogenesis of pyridine,
morphine carbohydrates & protein has been studied.
Course Outcomes: The natural products have been synthesized and their derivatives have been studied
in detail as they are industrially important. The antibiotics & their actions have been studied to know
more about antibiotics their derivatives. The steroids are the targeted chemical compounds and they are
used in sever diseases otherwise their use is not recommended by doctors. The alkaloids, cholesterol &
vitamins have been synthesized & their impact has been studied on human physiology.
Course Contents:
UNIT I (Lectures 08)
Terpenoids. General methods of structure elucidation. Isoprene rule. Structure determination,
stereochemistry, and synthesis of the following representative molecules: citral, geraniol, -terpineol,
menthol, -pinene, camphor, and abietic acid. Biosynthesis of terpenoids.
UNIT II (Lectures 08)
Alkaloids. General methods of structure elucidation. Structure determination, stereochemistry, and
synthesis of the following representative molecules: ephedrine, nicotine, atropine, quinine and
morphine. Biosynthesis of alkaloids.
UNIT III (Lectures 08)
Steroids. Structure elucidation, stereochemistry and chemical synthesis of cholesterol, bile acids,
androsterone, testosterone, estrone, progestrone and aldosterone. Biosynthesis of steroids.
UNIT IV (Lectures 08)
Plant Pigments. Carotenoids. Structure and synthesis of -carotene.
Flavonoids. Nature, general methods for structure elucidation and synthesis of anthocyanins and
flavones. Structure and synthesis of cyanidin chloride, cyanin, flavone, flavonol and quercetin.
Biosynthesis of flavonoids. Chlorophyll. Chemistry of chlorophyll.
UNIT V (Lectures 08)
Vitamins and Antibiotics. Vitamins. Structure and synthesis of vitamin B1 (thiamine), B2 (riboflavin)
and B6 (pyridoxine). Chemistry of Vitamin B12.
Antibiotics. Structure and synthesis of penicillins and chloramphenicol.
Reference Books:
1. Finar, I.L. Organic Chemistry, ELBS.
2. Nogradi, M. Stereoselective Synthesis: A Practical Approach, VCH.
3. Hostettmann, Kurt, Gupta, M.P. and Marston, A. Chemistry, Biological and Pharmacological
Properties of Medicinal Plants, Americas, Harwood Academic Publishers.
4. Aggarwal, O.P. Chemistry of Organic Natural Products, Goel Publishing House.
5. Rahman, A. and Choudhary, M.I. New Trends in Natural Product Chemistry, Harwood
Academic Publishers. * Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 37
Semester-III
Organometallic Chemistry Course Code: MCH315 L T P C
4 0 0 4
Objective: Structure and bonding issues in organometallic compounds are discussed in view of the
18-electron rule. Different reactive ligand types are discussed, including σ-bonded ligands such as
alkyl, aryl, hydride, as well as π-bonded ligands such as carbonyl, alkene, diene, alkyne,
cyclopentadienyl, and arene. The role of few important organometallic complexes as a catalyst is
thoroughly discussed.
Course Outcomes: After learning this paper the student has a good overview of the fundamental
principles of organotransition-metal chemistry and know how chemical properties are affected by
metals and ligands. The student will be able to use knowledge about structure and bonding issues to
understand the stability and reactivity of simple organometallic complexes.
Course Contents:
UNIT I (Lectures 08)
The 18-electron rule, counting of electrons and finding metal-metal bonds and related problems. Alkyls
& Aryls of Transition Metals: Types & routes of synthesis, stability & decomposition Pathways.
Carbenes & carbines: Synthesis, nature of bond, structural characteristics.
UNIT II (Lectures 08)
Transition Metal π-Complexes: Transition metal π-complexes with unsaturated organic molecules,
alkenes, alkynes, allyl, dienyl, arene & trienyl complexes, preparation, properties, nature of bonding &
structural features.
UNIT III (Lectures 08)
Applications of Organometallic Complexes to Catalysis: Catalysis, Terminology in Hydrogenation
catalysts, classification of hydrogenation catalysts, catalytic cycle of Wilkinson’s catalyst, catalytic
cycles of iridium and ruthenium based catalysts, hydrogenation by lanthanide organometallic
compounds, catalytic asymmetric synthesis, Hydroformylation: Cobalt catalysts and phosphine
modified cobalt catalysts, Rhodium-phosphine catalysts, Methanol Carbonylation and Olefin
Oxidation: Monsanto, Cativa and Wacker Processes,; Polymerisation and oligomerisation of olefins
and dienes, carboxylation of olefins, carbonylation of methanol, Synthetic gas.
UNIT IV (Lectures 08)
Fluxional Organometallic Compound: Stereo-chemical non-rigidity & fluxionality, stereo
chemically non-rigid coordination compounds, Trigonal bipyramidal molecules, η2-olefins, η3 –allyl
& dienyl compounds, isomerization & racemization of tris chelate complexes.
UNIT V (Lectures 08)
Bioorganometallic Chemistry: Role of organometallics in heavy metal poisoning: Mercury and
Arsenic poisoning, organometallic compounds as drugs: ruthenium and ferrocene based drugs;
Organometallics as radiopharmaceutical, tracers, ionophores and sensors.
Reference Books:
1. Huheey, J. E. Inorganic Chemistry, Principles of Structure and Reactivity, Harper Inter-Science.
2. Cotton, F. A. and Wilkinson, G. Advanced Inorganic Chemistry,6th edition, Wiley Inter-
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 38
Science.
3. Gupta, B. D. and Elias, A. J. Basic Organometallic Chemistry, Universities Press.
4. Salzer, C. E. and Elchinbroich, A. E. Organometallics, A Concise Introduction Chemistry,
VCH.
* Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 39
Semester-III
Medicinal Chemistry
Course Code: MCH316 L T P C
4 0 0 4
Objective: This module will explore the role played by organic chemistry in the discovery and
synthesis of important compounds widely used as medicines.
Course Outcomes:
The course describes the overall process of drug discovery, and the role played by medicinal chemistry
in this process. It relates the structure and physical properties of drugs to their pharmacological activity.
The student demonstrates an understanding of concepts such as drug metabolism, bioavailability and
pharmacokinetics and the role of medicinal chemistry in improving these parameters. The student will
be able to discuss examples of pharmaceutical drug discovery in detail, and relate patterns and lessons
from discovery of these examples to other seen and unseen examples.
Course Contents:
Unit I (Lectures 08)
Structure and activity. Relationship between chemical structure and biological activity (SAR). Receptor
Site Theory. Approaches to drug design. Introduction to combinatorial synthesis in drug discovery.
Factors affecting bioactivity. QSAR-Free-Wilson analysis, Hansch analysis, relationship between Free-
Wilson analysis and Hansch analysis.
Unit II (Lectures 08)
Pharmacodynamics. Introduction, elementary treatment of enzymes stimulation, enzyme inhibition,
sulfonamides, membrane active drugs, drug metabolism, xenobiotics, biotransformation, significance
of drug metabolism in medicinal chemistry.
Unit III (Lectures 08)
Antibiotics and antibacterial. Introduction, Antibiotic β-Lactam type - Penicillins, Cephalosporins,
Antitubercular. Streptomycin, Broad spectrum antibiotics. Tetracyclines, Anticancer – Dactinomycin
(Actinomycin D)
Unit IV (Lectures 08)
Antifungal polyenes, Antibacterial. Ciprofloxacin, Norfloxacin, Antiviral. Acyclovir Antimalarial.
Chemotherapy of malaria. SAR. Chloroquine, Chloroguanide and Mefloquine
Unit V (Lectures 08)
Non-steroidal Anti-inflammatory Drugs. Diclofenac Sodium, Ibuprofen and Netopam Antihistaminic
and antiasthma tic agents: Terfenadine, Cinnarizine, Salbutamol and Beclomethasone dipropionate.
Reference Books:
1. A. Burger, Medicinal Chemistry, Wiley Inter-Science Publications, New York.
2. W. O. Foye, Principles of Medicinal Chemistry, Lea & Febiger/ Varghese Publishing House,
Bombay.
3. D. Lednicer and L. A. Mitscher, The Organic Chemistry of Drug Synthesis, Wiley Inter-Science.
4. A. Kar, Medicinal Chemistry, Wiley Eastern Ltd., New Delhi.
5. N. K. Terrett, Combinatorial Chemistry, Oxford Univ. Press, Oxford.
6. Daniel Lednicer Stretegies for organic drug synthesis and design, John Wiley & Sons, New York.
* Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 40
Semester-III
Quantum Chemistry and Solid-State Chemistry
Course Code: MCH317 L T P C
4 0 0 4
Course Contents:
UNIT I (Lectures 08)
Term symbols and selection rules, spin –orbit coupling, regular and inverted multiples The variation
method, theorem and applications, non-degenerate perturbation method
UNIT II (Lectures 08)
Application of LCAO-MO theory on the basis of Huckel approximation to conjugated aliphatic
molecules and monocyclic conjugated polyenes. Huckel (4n+2) rule, calculation of resonance
stabilization energy from Schaad and Hess model, antiaromatic molecules.
UNIT III (Lectures 08)
Properties of metals and semiconductors: band theory, types of solids, intrinsic and extrinsic
semiconductors, p-n junctions, optical properties, photoconductivity of crystals
Imperfections and related phenomenon: Defects in solids: point defects line defects, diffusion in
solids- mechanism, elastic and plastic deformations
UNIT IV (Lectures 08)
Crystal growth techniques: General principles, growth from solution, growth from melts, growth from
vapour Solid state reactions: reactions of single solids and their kinetic characteristics, gas -solid, solid
-solid, addition and double decomposition reactions, photographic process.
UNIT V (Lectures 08)
Imperfections and physical properties crystals: Electrical properties, Optical properties: Colour centers
in ionic crystals: types, creation, Magnetic properties, Thermal properties and Mechanical properties.
Text Books:
1. Introduction of Solids L.V Azaroff, Tata McGraw Hill.
2. Principles of the solid-state H. V. Keer, Wiley Eastern.
3. Defects and diffusion in solids. S. Mrowec Elseivier publication.
4. Quantum chemistry (4th edition), Ira N. Levine, Prentice Hall, Englewood Cliffs, NJ.
5. Quantum Chemistry- A.K. Chandra.
6. D. A. McQuarrie, Quantum Chemistry, Viva Books, New Delhi.
7. Treatise on solid state chemistry, ED-N.B. Hannay, Plenum Press.
* Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 41
Semester-III
Industrial Safety & Health Hazards
Course Code: MSC011 L T P C
4 0 0 4
Objective: The course content focuses on t Industrial safety programs and toxicology, Industrial laws,
regulations, fire and explosion, preventive methods, relief and its sizing methods. The course helps to
analyse industrial hazards and its risk assessment.
Course Outcomes: By the end of the course the students will be able to analyze the effect of release
of toxic substances, understand the industrial laws, regulations and source models which helps them to
apply the methods of prevention of fire and explosions. This course also helps to understand the
methods of hazard identification and preventive measures.
Course Contents:
UNIT I (Lectures 08)
Physical and Chemical Hazards: Noise, noise exposure regulation, properties of sound, occupational
damage, risk factors, sound measuring instruments, permissible exposure limit. Ionizing radiation,
types, effects, monitoring instruments, control programs, OSHA standard- non-ionizing radiations,
effects, types, radar hazards, microwaves and radio-waves, lasers, TLV- cold environments,
hypothermia, wind chill index, control measures- hot environments, thermal comfort, heat stress
indices, acclimatization, estimation and control.
Recognition of chemical hazards-dust, fumes, mist, Air Sampling instruments, Types, Measurement
Procedures.
UNIT II (Lectures 08)
Occupational Health and Toxicology: Concept and spectrum of health - functional Units and
activities of occupational health services, notifiable occupational diseases such as silicosis, asbestosis,
pneumoconiosis, siderosis, anthracosis, aluminosis and anthrax, lead-nickel, chromium and manganese
toxicity, gas poisoning (such as CO, ammonia, coal and dust etc) their effects and prevention – cardio
pulmonary resuscitation, audiometric tests, eye tests, vital function tests.
UNIT III (Lectures 08)
Hazardous Waste Management: Hazardous waste management in India-waste identification,
characterization and classification technological options for collection, treatment and disposal of
hazardous waste-selection charts for the treatment of different hazardous wastes-methods of collection
and disposal of solid wastes-health hazards-toxic and radioactive wastes-incineration and vitrification
- hazards due to bio-process dilution- standards and restrictions – recycling and reuse
UNIT IV (Lectures 08)
Radiation Control: Radiation shielding – radiation dose – dose measurements – Units of exposure –
exposure limits – barriers for control of radioactivity release – control of radiation exposure to plant
personnel – health physics surveillance – waste management and disposal practices – environmental
releases.
UNIT V (Lectures 08)
Occupational Physiology: Man as a system component – allocation of functions – efficiency –
occupational work capacity – aerobic and anaerobic work – evaluation of physiological requirements
of jobs – parameters of measurements – categorization of job heaviness – work organization – stress –
strain – fatigue – rest pauses – shift work – personal hygiene.
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 42
Reference Books:
1. L.M Deshmukh Industrial safety management.
2. Ralph king and John magid industrial hazard and safety.
* Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 43
Semester-III
Elementary Biophysics
Course Code: MSC012 L T P C
4 0 0 4
Objective: The Objective of this Course is to provide an idea of various physical process and
phenomena which are applicable in bioscience.
Course Outcomes: After Completion of this course student will learn the physical process such as
bonding in atom and molecules, spectroscopic techniques, isotopes and radioactivity, radiation and
biophysics which are used in understanding the bioscience.
Course Contents:
Unit – I: (Lectures 08)
Foundations of Biophysics-I: Biophysics as an interdisciplinary science, aim and scope of biophysics.
Chemical and physical forces between atoms and molecules: Atomic and molecular forces. Inter-
atomic molecular bonds: Ionic, covalent and Vander Waals bonds, Coordinate bonds and hydrophobic
interaction. Mechanism of bond formation based on electronic orbitals. Formation of molecular
orbitals, Sigma and Pi bonds, Hybridization. Examples of bond formation between C-C, C-N and
carbon and other atoms.
Unit – II: (Lectures 08)
Physical methods of investigation of macromolecules: Biological macromolecules, General
classification, Physical methods of determining size and shape of molecules. Separation methods:
Diffusion, Sedimentation and osmosis. Viscosity and surface tension measurements.
Unit – III: (Lectures 08)
Instrumental methods of analysis of biological systems: Light scattering by macromolecules.
Optical activity, Absorption spectroscopy and spectrophotometry, Calorimetry, IR and Raman
spectroscopy for study of biomolecules. NMR spectroscopy for studying interactions and identification
of biomolecules. X-ray diffraction and microscopy for studying living matter (basics).
Unit – IV: (Lectures 08)
Isotopes and radioactivity: Radioactive decay laws, production of radioisotopes (radio nuclides),
allocation of radioactive traces, isotopic tracer method. Assay using radioactive substances, Labelling
and detection methods using fluorescent molecules (a few examples).
Unit – V: (Lectures 08)
Radiation biophysics: Radiation sources, Interaction of radiation with matter (general discussion),
energy transfer process, measurement of radiation, Dosimetry, Biological effects of radiation, effect of
radiation on living systems, radiation protection and radiation therapy.
Reference Books:
1. Essential of Biophysics – P. Narayanan, New Age International Publications.
2. Aspects of Biophysics- William Hughes, John Wiley and Sons.
3. Biochemistry of Nucleic acids- Adams et al. Chapmann and Hall.
4. Biophysics- Vasantha Pattabi and N. Goutham, Narosa Publishing House, New Delhi.
5. Biophysics- Cotterill. * Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 44
Semester III
Statistical Techniques in Data Mining
Course Code: MSC013 L T P C
4 0 0 4
Unit I (Lectures 08)
Introduction: Fundamentals of data mining, Data Mining Functionalities, Classification of Data
Mining systems, Data Mining Task Primitives, Integration of a Data Mining System with a Database
or a Data Warehouse System, Major issues in Data Mining.
Data Preprocessing: Need for Preprocessing the Data, Data Cleaning, Data Integration and
Transformation, Data Reduction, Discretization and Concept Hierarchy Generation.
Unit II (Lectures 08)
Mining Frequent Patterns, Associations and Correlations: Basic Concepts, Efficient and Scalable
Frequent Itemset Mining Methods, Mining various kinds of Association Rules, From Association
Mining to Correlation Analysis, Constraint-Based Association Mining.
Unit III (Lectures 08)
Classification and Prediction: Issues Regarding Classification and Prediction, Classification by
Decision Tree Induction, Bayesian Classification, Rule-Based Classification, Classification by Back
propagation, Support Vector Machines, Associative Classification, Lazy Learners, Other Classification
Methods, Prediction, Accuracy and Error measures, Evaluating the accuracy of a Classifier or a
Predictor, Ensemble Methods.
Unit IV (Lectures 08)
Cluster Analysis Introduction :Types of Data in Cluster Analysis, A Categorization of Major
Clustering Methods, Partitioning Methods, Hierarchical Methods, Density-Based Methods, Grid-
Based Methods, Model-Based Clustering Methods, Clustering High-Dimensional Data, Constraint
Based Cluster Analysis, Outlier Analysis - Mining Streams, Time Series and Sequence
Unit V (Lectures 08)
Mining Object, Spatial, Multimedia, Text and Web Data: Multidimensional Analysis and
Descriptive Mining of Complex Data Objects, Spatial Data Mining, Multimedia Data Mining, Text
Mining, Mining the World Wide Web.
Applications and Trends in Data Mining: Data Mining Applications, Data Mining System Products
and Research Prototypes, Additional Themes on Data Mining and Social Impacts of Data Mining.
Text Books:
1. 1. Data Mining – Concepts and Techniques - Jiawei Han & Micheline Kamber, Morgan
Kaufmann Publishers.
2. Introduction to Data Mining – Pang-Ning Tan, Michael Steinbach and Vipin Kumar, Pearson
education.
3. Data Mining Techniques – Arun K Pujari, University Press.
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 45
Reference Books:
1. Data Warehousing in the Real World – Sam Aanhory & Dennis Murray Pearson Edn Asia.
2. Data Warehousing Fundamentals – Paulraj Ponnaiah Wiley student Edition.
3. The Data Warehouse Life cycle Tool kit – Ralph Kimball Wiley student edition.
4. Building the Data Warehouse By William H Inmon, John Wiley & Sons Inc.
5. Data Mining Introductory and advanced topics –Margaret H Dunham, Pearson education.
* Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 46
Semester III
Database Management System
Course Code: MSC014/ECS411/511/611 L T P C
4 0 0 4
Objective: Introducing the fundamental concepts necessary for designing, using, and implementing
database systems and applications. The goal of this course is for students to become well-grounded in
basic concepts necessary for understanding DB and their users, DBMS concepts, architecture , the
concepts of the Entity Relationship(ER) model, the data abstraction and semantic modeling concepts
leading to EER data model, describe the basic relational model, its integrity constraints and update
operations, and the operation of relational algebra, describe relational schema design, and it covers the
normalization and functional dependency algorithm.
Course Outcomes:
1. Be familiar with a commercial relational database system (Oracle) by writing SQL using
the system.
2. Be familiar with the relational database theory, and be able to write relational algebra
expressions for queries.
3. Be familiar with basic database storage structures and access techniques: file and page
organizations, indexing methods including B‐tree, and hashing.
4. Be familiar with the basic issues of transaction processing and concurrency control.
Course Contents:
Unit I: (Lectures 08)
Introduction: Scope and purpose of database system, view of data, relational databases, database
architecture, transaction management, database system Vs filesystem, Database system concept and
architecture, data definitions language, DML.
Data Models: The importance of data models, Basic building blocks, Business rules, The evolution of
data models, Degrees of data abstraction
Unit II: (Lectures 08)
Database design and ER Model: overview, ER-Model, Constraints, ER-Diagrams, ERD Issues, weak
entity etc, Codd’s rules, Relational Schemas, Introduction to UML, Relational database model: Logical
view of data, keys, integrity rules.
Relational Database design: features of good relational database design, atomic domain and
Normalization (1NF, 2NF, 3NF, BCNF)
Unit III: (Lectures 08)
Relational data Model and Language: Relational algebra: introduction, Selection and projection, set
operations, renaming, Joins, Division, syntax, semantics. Operators, grouping and ungrouping,
Relational comparison. Calculus: Tuple relational calculus, Domain relational Calculus, calculus vs
algebra, Computational capabilities, constraints, Views.
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 47
Introduction on SQL: Characteristics of SQL, advantage of SQL. SQL data type and literals. Types
of SQL commands. SQL operators and their procedure. Tables, views and indexes. Queries and sub
queries. Aggregate functions. Insert, update and delete operations, Joins, Unions, Intersection, Minus,
Cursors, Triggers, and Procedures in SQL/PL SQL.
Unit IV: (Lectures 08)
Usage of Oracle:
1. Installing oracle
2. Creating Entity-Relationship Diagram using case tools.
3. Writing SQL statements Using ORACLE
4. MYSQL: a) Writing basic SQL SELECT statements.
b) Restricting and sorting data.
c) Displaying data from multiple tables.
d) Aggregating data using group function.
e) Manipulating data.
f) Creating and managing tables.
5. Normalization in ORACLE.
6. Creating cursor in oracle.
7. Creating procedure and functions in oracle.
8. Creating packages and triggers in oracle.
Unit V: (Lectures 08)
Transaction management: ACID properties, serializability and concurrency control Lock based
concurrency control (2PL, Deadlocks), Time stamping methods, optimistic methods, database recovery
management.
Text Books:
1. Elmasri, R., Navathe, S., Fundamentals of Database Systems, Addison-Wesley.
2. G. K. Gupta, “Data Base Management”, Tata Mc Graw Hill.
3. Atul Kahate, “Introduction to Database Management Systems” Pearson Education, New
Delhi, 2006.
*Latest editions of all the suggested books are recommended.
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 48
Semester-III
Organic Chemistry-II (Lab)
Course Code: MCH361 L T P C
0 0 4 2
Objective: The course content consists of analysis of biomolecules & multistep synthesis of organic
compounds of industrial importance with interpretation using spectroscopic technique.
Course Outcomes: The student will be able to learn the steps involve in multistep organic synthesis &
their characterization. The student will get ability to demonstrate the analysis of various biomolecules.
List of Experiments:
I. Analysis
1. Estimation of protein by Lowry’s method.
2. Estimation of carbohydrate by Anthrone’s method
3. Isolation of caffeine and alkaloids from tea.
4. To determine the iodine value of the given oil or fat
5. To determine the Saponification value of the given oil or fat
6. Estimation of Ascorbic Acid i.e. vitamin C.
7. Estimation of Amino acid by Sorenson’s method
8. Spectrophotometric estimation of Glucose with the help of Fehling solution
II. Multi Step Synthesis (Any three)
1. Benzoin- benzal- benzilic acid
2. Benzophenone –benzpinacole- benzpinacolone
3. Ethyl acetoacetate 3-methyl-1-phenylpyrazol-5-one antipyrin (phenazone)
4. Benzaldehyde benzoin benzil 5,5-diphenylhydantoin
5. Phenylhydrazine acetophenone phenylhydrazone 2-phenylindole
6. Chlorobenzene 1-chloro-2,4-dinitrobenzene 2,4-dinitrophenylhydrazine
III. Spectral Analysis
Interpretation of pre-recorded UV-Vis, IR, NMR, Mass, Raman spectrum and characterization of one
organic compound.
Evaluation Scheme of Practical Examination:
Internal Evaluation (50 marks)
Each experiment would be evaluated by the faculty concerned on the date of the experiment on a 4-
point scale which would include the practical conducted by the students and a Viva taken by the faculty
concerned. The marks shall be entered on the index sheet of the practical file.
Evaluation scheme: PRACTICAL PERFORMANCE & VIVA DURING THE
SEMESTER (35 MARKS)
ON THE DAY OF EXAM
(15 MARKS)
TOTAL
INTERNAL
(50 MARKS) EXPERIMENT
(5 MARKS)
FILE WORK
(10 MARKS)
VIVA
(10 MARKS)
ATTENDANCE
(10 MARKS)
EXPERIMENT
(5 MARKS)
VIVA
(10 MARKS)
External Evaluation (50 marks)
The external evaluation would also be done by the external Examiner based on the experiment
conducted during the examination. EXPERIMENT
(20 MARKS)
FILE WORK
(10 MARKS) VIVA
(20 MARKS) TOTAL EXTERNAL
(50 MARKS)
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 49
Semester-III
Physical Chemistry- II (Lab)
Course Code: MCH362 L T P C
0 0 4 2
Objective: The course content consists the determination of strength of acids & bases using
conductivity meter, potentiometer & validation of Lambert-Beer’s law. The student also learns about
various factors affecting the enzyme activity.
Course Outcomes: After performing this lab student will be able to determine the strength of acids &
bases using conductivity meter, potentiometer & validation of Lambert-Beer’s law. The student also
gets generalized thinking about factors affecting the enzyme activity
List of Experiments:
Conductometry
1. To determine the strength of unknown (given weak) acid conductometrically using standard
alkali solution (strong).
2. To determine the strength of unknown (given strong) acid conductometrically using standard
alkali solution (weak).
3. To determine the dissociation constant of weak electrolyte and to verify Ostwald’s dilution law.
4. To determine the equivalent conductance of strong electrolyte at the several concentrations and
hence verify Onsager equation.
Potentiometry
5. To determine the strength of unknown (given weak) acid potentiometrically using standard
alkali solution (strong).
6. To determine the strength of unknown (given strong) acid potentiometrically using standard
alkali solution (weak).
Spectrophotometry
7. To verify Lambert-Beer’s law using a spectrophotometer.
8. To determine the basicity of an acid.
9. To study the effect of temperature on invertase enzyme activity and determine its optimum pH
10. To study of the effect of substrate concentration on enzyme activity.
11. Effect of enzyme concentration on enzyme activity.
12. To find the solubility and solubility product of sparingly soluble salt conductometrically.
Evaluation Scheme of Practical Examination:
Internal Evaluation (50 marks)
Each experiment would be evaluated by the faculty concerned on the date of the experiment on a 4-
point scale which would include the practical conducted by the students and a Viva taken by the faculty
concerned. The marks shall be entered on the index sheet of the practical file.
Evaluation scheme:
PRACTICAL PERFORMANCE & VIVA DURING THE
SEMESTER (35 MARKS)
ON THE DAY OF EXAM
(15 MARKS)
TOTAL
INTERNAL
(50 MARKS) EXPERIMENT
(5 MARKS)
FILE WORK
(10 MARKS)
VIVA
(10 MARKS)
ATTENDANCE
(10 MARKS)
EXPERIMENT
(5 MARKS)
VIVA
(10 MARKS)
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 50
External Evaluation (50 marks)
The external evaluation would also be done by the external Examiner based on the experiment
conducted during the examination.
EXPERIMENT
(20 MARKS)
FILE WORK
(10 MARKS) VIVA
(20 MARKS) TOTAL EXTERNAL
(50 MARKS)
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 51
Semester III DISCIPLINE & GENERAL PROFICIENCY
Course Code: MSC311 C-1
There shall be continuous evaluation of the student on the following broad parameters:
1. Observance of dress code.
2. Participation in Conferences /Workshops / Seminars.
3. Attendance in guest lectures, invited talks and special technical sessions organized from time to
time.
4. Participation in community projects including NSS.
5. Exhibiting team spirit in different Culture & extra curriculum activities, Department Club activities
of the University and College organized from time to time.
6. Observance of rule & regulations in the College/University, Behavior in Campus Premises, Bus,
hostel mess and hostel.
7. Performance and awards received in different events (sports/ co-curricular activities) organized at
College / University and other level.
8. General behavior
9. Any extraordinary achievement.
The above is an indicative list of parameters on which the students shall be continuously evaluated.
The college may evaluate the student on the specific parameters by informing them through a notice
displayed on the notice board before evaluation. There shall be no external examination for this course;
however, the marks shall be included for calculation of cumulative Performance Index (CPI).
Head of Department would be display GP marks on notice board in prescribed format after IInd &
IIIrd CT in semester:
S
N
o
Enroll
No.
Student
Name
Dress
code
Participation
in
Conferences
/Workshops
/ Seminars
Participation
in guest
lectures,
invited talks
and special
technical
sessions
Participation
in
community
Services
Participation
in Culture &
extra
curriculum
activities,
Department
Club
Activities
Participation
in
sports/ co-
curricular
activities
General
Behavior
Any Extra
Achievement
(5) (15) (20) (10) (20) (20) (5) (5)
Res
po
nsi
ble
fo
r
ma
rks
Men
tor
Hea
d
Hea
d
Men
tor
Cu
ltura
l E
ven
ts
Co
ord
inat
or
&
Dep
artm
ent
Clu
b
Co
ord
inat
or
Sp
ort
s C
oo
rdin
ator
Men
tor
Dir
ecto
r o
r
Pri
nci
pal
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 52
Semester-IV
Biochemistry
Course Code: MCH411 L T P C
4 0 0 4
Objective: The course consists polymeric biomolecules and their monomeric building blocks,
specificity of enzymes (biochemical catalysts), and the chemistry involved in enzyme action,
metabolism of glucose & generation of large quantities of ATP.
The course also describe how fats and amino acids are metabolized, and explain how they can be used
for fuel. It also focuses on the structure of DNA, and explain how it carries genetic information in its
base sequence.
Course Outcomes:
Students will explain/describe the synthesis of proteins, lipids, nucleic acids, and carbohydrates and
their role in metabolic pathways along with their regulation at the epigenetic, transcriptional,
translational, and post-translational levels including RNA and protein folding, modification, and
degradation. Regulation by non-coding RNAs will be tied to the developmental and physiological
functioning of the organism.
Course Contents:
UNIT-I (Lectures 08)
Carbohydrates: Types of naturally occurring sugars: Deoxy-sugars, amino sugars, branched
chainsugars. General methods of structure and ring size determination with particular reference
tomaltose, lactose, sucrose, pectin, starch and cellulose, photosynthesis of carbohydrates, metabolism
of glucose, Glycoside- (amygdalin).
UNIT-II (Lectures 08)
Amino acid, peptides and proteins: General methods of peptide synthesis, sequence determination.
Chemistry of insulin and oxytocin. Purines and nucleic acid. Chemistry of uric acid, adenine, protein
synthesis.
UNIT-III (Lectures 08)
Vitamins: A general study, detailed study of chemistry of thiamine (Vitamin B1), Ascorbic acid
(Vitamin C), Pantothenic acid, biotin (Vitamin H), α-tocopherol (Vitamin E), Biological importance of
vitamins.
UNIT-IV (Lectures 08)
Enzymes: Nomenclature and classification, extraction and purification, Remarkable properties of
enzymes like catalytic power, specificity and regulation, Proximity effects and molecular adaptation,
Chemical and biological catalysis. Mechanism of enzyme action: Transition state theory, orientation
and steric effect, acid base catalysis, covalent catalysis, strain or distortion. Examples of some typical
enzyme mechanisms (chymotrypsin, ribo nuclease, lysozyme and carboxypetidase A). Fischer’s lock
and key and Koshland’s induced fit hypothesis, concept and identification of active site by the use of
inhibitors affinity labeling and enzyme modification by site directed mutagenesis. Enzyme kinetics,
Michaelis-Menten and Lineweaver-Burk plots, reversible and irreversible inhibition.
UNIT-V (Lectures 08)
(a) Kinds of reactions catalyzed by Enzymes: Nucleophilic displacement on a phosphorus atom,
multiple displacement reactions and the coupling of ATP cleavage to endergonic processes. Transfer
of sulphate addition and elimination reactions, enolic intermediates in isomerization reactions, β-
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 53
cleavage and condensation, some isomerization and rearrangement reactions. Enzyme catalyzed
carboxylation and decarboxylation reactions.
(b) Coenzyme Chemistry: Cofactors as derived from vitamins, coenzymes, prosthetic groups and
apoenzymes. Structure and biological functions of coenzyme A, thiamine pyrophosphate pyridoxal
phosphate, NAD+, NADP+, FMN, FAD, Lipoic acid, vitamin B12. Mechanisms of reactions catalyzed
by the above cofactors.
Reference Books:
1. L. Lehinger, Principles of Biochemistry, Worth Publications.
2. L. Stryer, W. H. Freeman Biochemistry.
3. J. David Rawn, Neil Patterson Biochemistry.
4. E. E. Conn and P. K. Stumpt, John Wiley. Outlines of Biochemistry.
* Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 54
Semester-IV
Photochemistry
Course Code: MCH412 L T P C
4 0 0 4
Objective: The course Unit consists of photochemistry & its photochemical reactions like photo
reduction & photo-oxidation. Photo physical phenomenon has been applied to study electronic structure
of molecules, molecular orbitals & molecules in excited singlet state. The application of
chemiluminescence & fluorescence has been applied to study photo-excited donor & acceptor system.
Course Outcomes: Photochemistry & photochemical laws are of great utility to understand the Beer's
lamber's law & its applications. The photochemistry of environment & greenhouse effects is of great
applications in plant kingdom. The fluorescence quenching, concentration quenching is of great interest
to study photo physical phenomenon.
Course Contents:
Unit-I (Lectures 08)
Photochemical Reactions. Interaction of electromagnetic radiation with matter, types of excitations,
fate of excited molecule, quantum yield, transfer of excitation energy, actinometry.
Unit II (Lectures 08)
Determination of Reaction Mechanism. Classification, rate constants and life times of reactive energy
state determination of rate constants of reactions. Effect of light intensity on the rate of photochemical
reactions. Types of photochemical reactions-photo dissociation, gas-phase photolysis.
Unit III (Lectures 08)
Photochemistry of Alkene. Intramolecular reactions of the olefinic bond-geometrical isomerism,
cyclisation reactions, rearrangement of 1,4- and 1,5-dienes.
Photochemistry of Aromatic Compounds. Isomerization, additions and substitutions.
Unit IV (Lectures 08)
Photochemistry of Carbonyl Compounds. Intramolecular reactions of carbonyl compounds-saturated,
cyclic and acyclic, unsaturated and α, β-unsaturated compounds, cyclohexadiene’s. Intermolecular
cycloaddition reactions-dimerization and oxetane formation.
Unit V (Lectures 08)
Miscellaneous Photochemical Reactions. Photo-Fries reactions of annelid’s, Photo-Fries
rearrangement. Barton reaction. Singlet molecular Oxygen reaction. Photochemical formation of smog.
Photodegradation of polymers. Photochemistry of vision.
Reference Books:
1. Organic Photochemistry by James Morriss Coxon, Brian Halton, [London, New York]
Cambridge University Press.
2. Introduction to Organic Photochemistry John D. Coyle, The Open University.
3. Molecular Reactions and Photochemistry by Charles H. De Puy, Orville Lamar Chapman,
Pearson Education, Limited.
* Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 55
Semester-IV
Bio-Inorganic Chemistry
Course Code: MCH413 L T P C
4 0 0 4
Objective: This course content consists of bio inorganic chemistry of alkali & alkaline earth metal &
their importance in biological systems of Plant, animals & human beings. Iron & copper are of great
importance in our physiological processes. Iron is the main constituent of haemoglobin & copper
catalyse a large number of biological reactions. Nitrogen fixation in nature plays a important role in
soil changing ammonia into nitrates which are absorbed by the plants. Trace elements called
micronutrients are also important for biodegradation of minerals by bacteria.
Course Outcomes: we hope that with the help of this curriculum students will develop the spices
necessary in bioinorganic chemistry of alkali & alkaline earth metal., Photosynthesis, use of ATP &
ADP, structure & mechanism of Haemoglobin, myoglobin. Cellular nitrogen fixation in soil will prove
very useful.
Course Contents:
UNIT I (Lectures 08)
Bioinorganic Chemistry of Alkali and Alkaline Earth Metals: Essential and trace elements in
biological systems; Structure and functions of biological membranes; mechanism of ion transport
across membranes; Sodium pump; Ionophores: valinomycin and crown ether complexes of Na+ and
K+; ATP and ADP; Photosynthesis: chlorophyll a PS I and PS II; Role of calcium in muscle
contraction; Blood clotting mechanism and biological calcification.
UNIT II (Lectures 08)
Bioinorganic Chemistry of Iron and Copper: Iron-sulphur proteins: Rubredoxin and ferredoxins;
Metalloporphyrins; Heme proteins: hemoglobin, Structure and Mechanism of hemoglobin, myoglobin
and cytochrome c; Non-heme proteins: hemerythrin and hemocyanin.
UNIT III (Lectures 08)
Nitrogen Fixation, Metal poisoning and their treatment: Nitrogen in biosphere; Nitrogen cycle;
Role of micro-organisms in nitrification; Nitrogen fixation in soils; Metal poisoning and drug action of
Inorganic complexes compounds; Metal poisoning, treatment by using chelating agent, mercury, lead
& cadmium poisoning & treatment; Platinum complexes in treatment of cancer. metal deficiency.
UNIT IV (Lectures 08)
Trace Metals in Plant Life: Micronutrients present in soil and role in plant life; Biodegradation of
minerals by bacteria and its applications in treatment of soil and water pollution.
UNIT V (Lectures 08)
Supramolecular Chemistry: Definition and Development of Supramolecular Chemistry,
classification of Supramolecular Host-Guest compounds, Pre- organization and Complementarily,
Receptors, Nature of Supramolecular interactions. Crown ethers, Lariat ether and Podands, Cryptands,
spherands, selectivity, Macro cyclic effects.
Reference Books:
1. Eichhorn: Inorganic Biochemistry: Vol I , 2 Elsevier.
2. Ochiai: Bioinorganic Chemistry: Allyn & Bacon Burton.
3. Williams: An Introduction to Bioinorganic Chemistry, C.C. Thomos Spring III.
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 56
4. Wallace: Decade on synthetic chelating agent in Inorganic plant nutrition, Wallace.
5. Williams: Metals in Life.
6. Zagic: Microbial Biogeochemistry, Academic press.
7. Ahuja: Chemical Analysis of the Environment, Plenum press.
* Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 57
Semester-IV
Bio-Organic Chemistry Course Code: MCH414 L T P C
4 0 0 4
Objective: Bioorganic Chemistry is a scientific discipline at the intersection of organic chemistry &
biology. The syllabus involves the various type of organic substances viz enzyme, carbohydrate, lipids
& nucleic acids for their biological functions.
Course Outcomes: I hope that the students will enjoy & benefit from the learning of this syllabus
regarding cell structure & its function etc. Each Unit starts with learning objectives these will be
important in the study of bio-Organic chemistry.
Course Contents:
Unit-I (Lectures 08)
Introduction: Basic Consideration, Proximity effects and molecular adoption. Enzymes: Introduction,
Chemical and Biological catalysis, remarkable properties of enzymes, Nomenclature and classification,
concept and identification of active site by use of inhibitors,
reversible & irreversible inhibition.
Unit-II (Lectures 08)
Kinds of Reactions Catalyzed by Enzymes: B-cleavage and consideration, some isomerization and
rearrangement reactions. Enzyme catalyzed carboxylation and decarboxylation. Mechanism of Enzyme
action: Transition state theory, Orientation and steric effect, acid-base catalysis, covalent catalysis.
Co-Enzyme Chemistry: Cofactors as derived from vitamins, coenzymes, prosthetic groups,
apoenzymes, Structure and biological functions of coenzyme A.
Unit-III (Lectures 08)
Enzyme Models: Host guest chemistry, Chiral recognition and catalysis, molecular recognition,
molecular asymmetry and prochirality, Biomimetic chemistry, crown ethers, cryptates, cyclodextrins,
cyclodextrin based enzyme models, Calixarenes, ionophores, micelles synthetic enzyme or synzymes.
Unit-IV (Lectures 08)
Biotechnological Application of enzymes: Large scale production and purification of enzymes,
techniques and methods of immobilization of enzyme activity, application of immobilized enzymes,
effect of immobilization on Enzyme activity, application of immobilized enzymes. Clinical uses of
enzymes, enzyme therapy, enzymes and recombinant DNA technology.
Unit-V (Lectures 08)
Metalloenzymes, Copper enzymes, superoxide dismutase, cytochrome oxidase and ceruloplasmin;
Coenzymes; Molybdenum enzyme: xanthine oxidase; Zinc enzymes: carbonic anhydrase, carboxy
peptidase and interchangeability of zinc and cobalt in enzymes; Vitamin B12 and B12 coenzymes; Iron
storage, transport, biomineralization and siderophores, ferritin and transferrins.
Reference Books:
1. Eichhorn: Inorganic Biochemistry: Vol I, 2 Elsevier.
2. Ochiai: Bioinorganic Chemistry: Allyn & Bacon Burton.
3. Williams: An Introduction to Bioinorganic Chemistry, C.C. Thomos Spring III.
4. Wallace: Decade on synthetic chelating agent in Inorganic plant nutrition, Wallace.
5. Williams: Metals in Life. * Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 58
Semester-IV
Bio-Physical Chemistry Course Code: MCH415 L T P C
4 0 0 4
Objective: Biophysical Chemistry is a scientific discipline at the intersection of Physical chemistry &
biology. The syllabus involves the various type of organic substances viz enzyme, carbohydrate, lipids
& nucleic acids for their biological functions.
Course Outcomes: I hope that the students will enjoy & benefit from the learning of this syllabus
regarding cell structure & its function etc with reference to physical phenomenon.
Course Contents:
UNIT – I (Lectures 08)
Cell membrane and its structure: The Cell Membrane, lipids in biological membranes, types and
arrangements of proteins in membranes, lipo proteins. Danielli and Davson model, Fluid Mosaic
Model, permeability of cell membrane. Bio-Energetics: Thermodynamic Considerations: standard free
energy change in bio-chemical reactions, exergonic, endergonic reactions, hydrolysis of ATP and its
synthesis from ADP.
UNIT – II (Lectures 08)
Thermodynamics of Biopolymers Solutions: Osmotic pressure, membrane equilibrium, muscular
contraction and energy generation in mechanochemical system. Statistical mechanics in biopolymers
chain configuration of macromolecules, statistical distribution end – to – end dimensions, calculation
of average dimensions for various chain structures. Polypeptide and protein structures and protein
folding.
UNIT – III (Lectures 08)
Mechanism of Membrane Transport: Transport through cell membrane, active and passive transport
systems, Ping - pong mechanism for transport of diffusion, Macromolecules across the Plasma
Membrane, Role of Intercellular spaces in transport process, Homocellular, Transcellular Intracellular
transport, Irreversible thermodynamic treatment of membrane transport. Nerve conduction, Donnan
effect in Osmosis, its dependence on pH difference across the membrane. Semipermeable membrane
and Donnan membrane equilibrium.
UNIT – IV (Lectures 08)
Biomolecular Interactions: Interactions between biomolecules (proteins), Interaction of biomolecules
with small ligands, independent ligand binding sites, the Scatchard plot, forces involved in the stability
of proteins, hydrophobic interactions, hydrogen bonding, electrostatic interactions, electron
delocalization, van der Waal’s forces Scope of Genomics, proteomics and bioinformatics, ribosomes:
Site and Function of protein synthesis.
UNIT –V (Lectures 08)
Protein molecules: Protein sequence and structure (primary structure), secondary structure: α-Helix,
β- Sheet, classification of proteins, torsion angles, tertiary structure, quaternary structure, Protein
folding and refolding, computer simulation: thermodynamic-kinetic approach, statistical mechanics
approach, Homolog Modelling, De Novo prediction, Protein misfolding, Biological factors
(Chaperones) and chemical factors(Intra and intermolecular interactions) leading
folding/refolding/misfolding. Brain diseases associated with it.
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 59
Reference Books:
1. Physical Chemistry of Macromolecules: S.F.Sun
2. The Enzyme Molecules: W. Ferdinand
3. Outlines of Biochemistry: E.E. Conn and P.K. Stumph
4. Biochemistry: Zubay
5. Principles of Biochemistry: A.I. Leninger
* Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 60
Semester-IV
Environmental Chemistry Course Code: MCH416 L T P C
4 0 0 4
Objective: Air & water pollution are the worth problem. The physico-chemical studies of air & water
pollution & their abatement is of great interest to clean the environment. Methods of control of air
pollution & water pollution have been included at large scale to clean the air & water. The sampling &
analysis is done for CO, CO2, SO2, H2S etc. Radiation pollution effects directly on plants & animals &
human beings. The different methods of protection & control have been studied.
Course Outcomes: The concentration of poisonous gases is done by continuous monitoring in the
environment. If concentration increases the pollution control department check the gaseous inflow of
industries in to the environment. Similarly, water pollution is monitored and necessary steps are taken
to stop the pollution. Protection of ozone layer is of great importance & all countries in the word has
stop the use of solvent & CFCs. To check the environmental toxicology everyone has to be alert
otherwise it will be like Bhopal gas Tragedy & Minimatta Disaster everywhere in the world.
Course Contents:
Unit I (Lectures 08)
Environment:
Introduction. Composition of atmosphere, vertical temperature, temperature inversion, heat budget of
the earth, atmospheric system, vertical stability atmosphere, Biochemical cycles of C, N, P, S and O.
Biodistribution of elements.
Hydrosphere:
Chemical composition of water bodies-lakes, streams, rivers and wet lands etc. Hydrological cycle
Aquatic pollution – Inorganic, organic, pesticide, agriculture, industrial and sewage, detergents, oil
spills and oil pollutants. Water quality parameters – dissolved oxygen, biochemical oxygen demand,
solids, metals, content of chloride, sulphate, phosphate, nitrate and microorganisms. Water quality
standards. Analytical methods of measuring BOD, DO, COD, F, Oils, metals (As, Cd, Cr, Hg, Pb, Se
etc.), residual chloride and chlorine demand. Purification and treatment of water.
Unit II (Lectures 08)
Soils: Composition, micro and macro nutrients, pollution – fertilizers, pesticides, plastics and metals.
Waste treatment.
Atmosphere: Chemical composition of atmosphere – particles, ions and radicals and their formation.
Chemical and photochemical reactions in atmosphere, smog formation, oxides of N, C, S, O and their
effect, pollution by chemicals, petroleum, minerals, chlorofluorohydrocarbons. Green house effect,
acid rain, air pollution controls and their chemistry. Analytical methods for measuring air pollutants.
Continuous monitoring instruments.
Unit III (Lectures 08)
Industrial Pollution:
Cement, sugar, distillery, drug, paper and pulp, thermal power plants, nuclear power plants, metallurgy.
Polymers, drugs etc.
Environmental disasters – Cherbonyl, Three-mile island, Seveso and minamata disasters,
Japan tsunami.
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 61
Unit IV (Lectures 08)
Environmental Toxicology:
Toxic heavy metals: Mercury, lead, arsenic and cadmium. Causes of toxicity. Bioaccumulation, sources
of heavy metals. Chemical speciation of Hg, Pb, As, and Cd. Biochemical and damaging effects.
Toxic Organic Compound: Pesticides, classification, properties and uses of organochlorine and
ionospheres pesticides detection and damaging effects.
Unit-V (Lectures 08)
Aquatic Chemistry and Water Pollution. Redox chemistry in natural waters. Dissolved oxygen,
biological oxygen demand, chemical oxygen demand, determination of DO, BOD and COD. Aerobic
and anaerobic reactions of organic sulphure and nitrogen compounds in water acid-base chemistry of
fresh water and sea water. Aluminum, nitrate and fluoride in water. Petrification. Sources of water
pollution. Treatment of waste and sewage. Purification of drinking water, techniques of purification
and disinfection.
Reference Books:
1. A.K. De, Environmental Pollution.
2. Wark & Werner Air Pollution.
3. S.P. Mahajan Environmental Pollution Control in Process Industries
4. B.K. Sharma & H. Kaur Environmental Pollution.
5. P.K. Trivedi Introduction to Air Pollution.
* Latest editions of all the suggested books are recommended
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 62
Semester-IV
Project, Seminar & Viva Course Code: MCH492 L T P C
0 0 24 12
For students to enter into preliminary research field both in theory and experiment the concept of
Project has been introduced in the final Semester. In the Project, the student will explore new
developments from the books and journals, collecting literature / data and write a Dissertation based
on his / her work and studies. The Project Work can also be based on experimental work in industries
/ research laboratories.
Selection of Topic:
1. Students will make project which should be preferably a working of third thoughts based on their
subject.
2. The student will be assigned a faculty guide who will be the supervisor of the students. The faculty
would be identified at the end of the III semester.
3. The assessment of performance of the students should be made at least twice in the semester.
Internal assessment shall be for 50 marks. The students shall present the final project live using
overhead projector PowerPoint presentation on LCD to the internal committee and the external
examiner.
4. The evaluation committee shall consist of faculty members constituted by the college which would
be comprised of at least three members comprising of the department Coordinator’s Class
Coordinator and a nominee of the Director/Principal. The students guide would be special in
invitee to the presentation. The seminar session shall be an open house session. The internal marks
would be the average of the marks given by each members of the committee.
The Marking shall be as follows.
Internal: 50 marks
By the Faculty Guide – 25 marks
By Committee appointed by the Director/Principal – 25 marks
External: 50 marks
By External examiner by the University – 50
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 63
Top Cover- The sample top cover shall be as under:
TITLE (18 pt Times New Roman CAPS)
DISSERTATION/PROJECT (14)
Submitted in Partial Fulfillment of the Requirements for the Degree of (14)
MASTER OF SCIENCE (16)
In (16)
Chemistry (16)
Submitted by (12)
Name
Enrollment No
Under the guidance of (12)
Name of Guide & Designation (14)
Department of Chemistry (14)
Faculty of Engineering
Teerthanker Mahaveer University (14)
Moradabad-244001(14)
(December, 2017) (14)
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 64
Order of Contents (14)
Orders of contents are as follows:
1. Title Page
2. Certificate
3. Candidate’s Declaration
4. Acknowledgement
5. Abstract
6. Contents with page numbers
7. List of Figures
8. List of Tables
9. List of Abbreviations
10. List of Symbols
11. Chapter 1: Introduction
Chapter 2: Literature Review
Chapter 3: ….
Chapter 4: ….
Chapter 5: Conclusion
Appendix: Code
12. References
13. Publications
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 65
CERTIFICATE
This is to certify that dissertation/Project entitled “……………………………………………
………………….….” which is submitted by ………………………… in partial fulfillment of the
requirement for the award of degree M.Sc. in Chemistry, Faculty of Engineering, Teerthanker
Mahaveer University, Moradabad is a record of the candidate own work carried out by him under
my/our supervision. The matter embodied in this dissertation/Project is original and has not been
submitted for the award of any other degree.
Signature of Supervisor(s) Head,
Name & Designation of Supervisor(s) Department of Chemistry
. FOE, TMU
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 66
CANDIDATE’S DECLARATION
This is to certify that Dissertation/Project entitled “…………………………” which is submitted by
me in partial fulfilment of the requirement for the award of degree M.Sc. in Chemistry, Faculty of
Engineering, Teerthanker Mahaveer University, Moradabad comprises only my original work and due
acknowledgement has been made in the text to all other material used.
I, hereby, further declared that in case of legal dispute in relation to my M.Sc.
dissertation/Project, I will be solely responsible for the same.
Date: Name of Candidate
Enrollment No.
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 67
ACKNOWLEDGEMENT
Apart from the efforts of me, the success of this dissertation/project depends largely on the
encouragement and guidelines of many others. I take this opportunity to express my gratitude to the
people who have been instrumental in the successful completion of this dissertation/project.
I would like to show my greatest appreciation to _ _ _ _. I can’t say thank you enough for his/her
tremendous support and help. I feel motivated and encouraged every time I attend his/her meeting.
Without his/her encouragement and guidance this dissertation/project would not have materialized.
The guidance and support received from _ _ _ (Name of Guide) was vital for the success of the
dissertation/project. Without the wise counsel and able guidance, it would have been impossible to
complete the dissertation/project in this manner I am grateful for his/ her constant support and help.
I express gratitude to other faculty members of Chemistry Department, FoE for their intellectual
support throughout the course of this work. Finally, I am indebted to all whosoever have contributed in
this dissertation/project work and friendly stay at FoE.
Place: Name of Candidate
Date
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 68
Contents
Certificate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i
Candidate’s Declaration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ii
Acknowledgement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . iii
Abstract . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . iv
List of Figures. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . v
List of Tables. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . vi
List of Abbreviations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . vii
List of Symbols . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . viii
1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
1.1 Introduction of Topic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
1.2 Associate Problems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
1.3 Overview of Potential Solution. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
1.4 Key Benefits of Potential Solution. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
1.5 Motivation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
1.6 Aim / Problem Definition. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
1.7 Objective of Thesis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
1.8 Thesis Structure / Organization of Thesis . . . . . . . . . . . . . . . . . . . . . . . . 10
2 Literature Survey . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
2.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
2.2 Literature Survey . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
2.3 Problem Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
3 Proposed Work / Proposed Methodology . . . . . . . . . . . . . . . . . . . . . . . . . . 35
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 69
3.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35
3.2 Proposed Work . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37
3.2.1 Idea /Method / Sub Heading . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40
3.3 Heading . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45
4 Result and Discussion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47
4.1 Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48
4.2 Discussion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49
5 Conclusion, Recommendation and Future Scope . . . . . . . . . . . . . . . . . . . 53
5.1 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54
5.2 Recommendation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55
5.3 Future Scope . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56
Appendix A Program Listing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 60
A.1 MATLAB Code 60
Appendix B Kit Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65
B.1 Overview of kit 65
References 70
List of Publications 73
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 70
List of Figure
Figure Page
1.1 Caption of figure 1.1 ........................………..………..……………………….. 1
2.1 Caption of figure 2.1 ........................………..………..……………………….. 8
2.2 Caption of figure 2.2 ........................………..………..……………………….. 10
2.3 Caption of figure 2.3 ........................………..………..……………………….. 11
2.4 Caption of figure 2.4 ........................………..………..……………………….. 12
3.1 (a) Caption of subfigure 3.1(a), (b) caption of subfigure 3.1(b) ……………... 13
3.2 Caption of figure 3.2 (a) caption of subfigure 3.2(a), (b) caption of subfigure
3.2(b) ........................………..………..……………………………………….
15
4.1 Caption of figure 4.1 ........................………..………..……………………….. 24
4.2 Caption of figure 4.2 ........................………..………..……………………….. 25
5.1 Caption of figure 5.1 ........................………..………..……………………….. 28
B.1 Caption of figure in appendix A…..…………………………………………… 52
B.2 Caption of figure in appendix B…..…………………………………………… 52
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 71
LIST OF TABLES
Table Page
1.1 Caption of Table 1.1 ................……………………………………………….. 2
3.1 Caption of Table 3.1 ................……………………………………………….. 20
3.2 Caption of Table 3.2 ................……………………………………………….. 27
4.1 Caption of Table 4.1 ................……………………………………………….. 30
A.1 Caption of Table in Appendix A .......………………………………………….. 51
B.1 Caption of Table in Appendix B.......………………………………………….. 53
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 72
List of Abbreviations
RFID Radio Frequency Identity
IVRS Interactive Voice Response Service
ASR Automatic Speaker Recognition
PSK Phase Shift Keying
DFT Discrete Fourier Transform
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 73
List of Symbols
N Time index
Ω Frequency in radian
Σ Standard deviation
x(n) Signal variable
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 74
CHAPTER (Font size 14)
GUIDELINES
1.1 Size
Standard bond paper size A4 (297x210mm) should be used.
1.2 Page number
Page should be numbered consecutively and clearly. No page number should be indicated on title page.
Certificate, candidate’s declaration and acknowledgement, pages are to be counted & from certificate
to acknowledgement Greek numbers should be used. From main text to end of dissertation Indian
numerals should be used. All typing should be on right hand pages only.
1.3 Margin
Top 1.0”, Bottom 1.0” Left 1.5” Right 1.0”
1.4 Line spacing
Line spacing should 1.5.
1.5 Font
Times new roman, size 12 for text, 12 (BOLD) may be used for headings & subheadings.
1.6 CD-ROM
All dissertation/project report should include soft copy on CD-ROM accompanied with
dissertation/project report in pocket pasted on inside of back cover.
1.7 Text
Before producing the final copies of a dissertation /project report the candidate should ensure that all
the spelling, grammar, punctuation and bibliography is complete and exact. Text should in 3rd person
form. One is not supposed to use the words like I, we etc.
1.8 File Binding
The Project Report should be hard bound with Title page in Maroon color. The name of the candidate,
degree (specifying the specialization) etc shall be printed in golden color on the Title page.
A candidate/group will submit two hardcopies with soft copies in CD to the department and
candidate/group will also make an extra copy for themselves.
1.9 Figure
Figure 1.1: Waveform of ECG signal
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 75
1.10 Table
Table 1.1: Comparison of different methods
Method Base Result (%)
Method 1 ABCD 50.98
Method 2 AB 23.67
Method 3 CD 42.77
1.11 Reference
All the references should be arranged year wise. Examples are in reference page
1.11.1 First reference is for book.
1.11.2 Second reference is for article of journal.
1.11.3 Third reference is for proceeding of conference paper.
References
[1] C. Brusaw, C. Aired, and W. Oliu, Handbook of Technical Writing, 3rd ed., New York St. Martine’s
Press, 1987.
[2] S. K. Kenue and J. F. Greenleaf, “Limited angle multi frequency diffiation tomography”, IEEE
Trans. Sonic Utrason. Vol. SU-29, no. 6, pp. 213-217, July 1982.
[3] R. Finkel, R. Taylor, R. Paul and J. Francklin, “An overview of AL programming system for
automation”, in proc. Forth int. Joint Conf. on Artif. Intell. , Sept 3-7, 1975 pp. 758-755.
List of Publications
Journals
• S. K. Kenue and J. F. Greenleaf, “Limited angle multi frequency diffiation tomography”, IEEE
Trans. Sonic Utrason. Vol. SU-29, no. 6, pp. 213-217, July 1982.
• S. K. Kenue and J. F. Greenleaf, “Limited angle multi frequency diffiation tomography”,
accepted for publication in IEEE Trans. Sonic Utrason. 2012
• S. K. Kenue and J. F. Greenleaf, “Limited angle multi frequency diffiation tomography”,
communicated to IEEE Trans. Sonic Utrason. 2012
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 76
International Conferences
• R. Finkel, R. Taylor, R. Paul and J. Francklin, “An overview of AL programming system for
automation”, in proc. Forth int. Joint Conf. on Artif. Intell. , Sept 3-7, 1975, pp. 758-755.
• R. Finkel, R. Taylor, R. Paul and J. Francklin, “An overview of AL programming system for
automation”, accepeted for publication in proc. Forth int. Joint Conf. on Artif. Intell. , Sept 3-
7, 2012
• R. Finkel, R. Taylor, R. Paul and J. Francklin, “An overview of AL programming system for
automation”, communicated to the proc. Forth int. Joint Conf. on Artif. Intell. , Sept 3-7, 2012,
National Conferences
• R. Finkel, R. Taylor, R. Paul and J. Francklin, “An overview of AL programming system for
automation”, in proc. Forth national. Joint Conf. on Artif. Intell. , Sept 3-7, 1975, pp. 758-755.
• R. Finkel, R. Taylor, R. Paul and J. Francklin, “An overview of AL programming system for
automation”, accepeted for publication in proc. Forth national . Joint Conf. on Artif. Intell. ,
2012
• R. Finkel, R. Taylor, R. Paul and J. Francklin, “An overview of AL programming system for
automation”, communicated to the proc. Forth national Conf. on Artif. Intell. , 2012,
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 77
EVALUATION SHEET
(To be filled by the GUIDE & Internal Examiners only)
Name of Candidate:
Roll No:
Class and Section:
Please evaluate out of Five marks each.
S. No. Details Marks (5) Marks (5) Marks (5)
Guide Int. Exam. 1 Int. Exam. 2
1. Objective Identified & Understood
2. Literature Review /
Background Work
(Coverage, Organization, Critical
Review)
3. Discussion/Conclusions
(Clarity, Exhaustive)
4. Slides/Presentation
Submitted
(Readable, Adequate)
5. Frequency Of
Interaction (Timely
Submission, Interest Shown, Depth,
Attitude)
Total (Out of 25)
Average out of 50
Signature: Signature: Signature:
Date: Date: Date:
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 78
EVALUATION SHEET FOR EXTERNAL EXAMINER
(To be filled by the External Examiner only)
Name of Candidate:
Roll No:
I. For use by External Examiner ONLY
S. No. Details Marks (10) each
1. Objective Identified & Understood
2. Literature Review / Background Work
(Coverage, Organization, Critical Review)
3. Discussion/Conclusions
(Clarity, Exhaustive)
4. Power Point Presentation
(Clear, Structured)
5. Slides
(Readable, Adequate)
Total (Out of 50)
Signature:
Date:
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 79
EVALUATION SUMMARY SHEET
(To be filled by External Examiner)
Name and Roll
Internal External Result
Examiners Examiner Total (100) (Pass/Fail)
No.
(50) (50)
Note: The summary sheet is to be completed for all students and the same shall also be Compiled
for all students examined by External Examiner. The Format shall be provided by the
course coordinator.
M.Sc.(Chemistry) Syllabus Applicable w.e.f. Academic Session 2017-18 Page 80
Semester IV DISCIPLINE & GENERAL PROFICIENCY
Course Code: MSC411 C-1
There shall be continuous evaluation of the student on the following broad parameters:
1. Observance of dress code.
2. Participation in Conferences /Workshops / Seminars.
3. Attendance in guest lectures, invited talks and special technical sessions organized from time to
time.
4. Participation in community projects including NSS.
5. Exhibiting team spirit in different Culture & extra curriculum activities, Department Club activities
of the University and College organized from time to time.
6. Observance of rule & regulations in the College/University, Behavior in Campus Premises, Bus,
hostel mess and hostel.
7. Performance and awards received in different events (sports/ co-curricular activities) organized at
College / University and other level.
8. General behavior
9. Any extraordinary achievement.
The above is an indicative list of parameters on which the students shall be continuously evaluated.
The college may evaluate the student on the specific parameters by informing them through a notice
displayed on the notice board before evaluation. There shall be no external examination for this course;
however, the marks shall be included for calculation of cumulative Performance Index (CPI).
Head of Department would be display GP marks on notice board in prescribed format after IInd &
IIIrd CT in semester:
S
N
o
Enroll
No.
Student
Name
Dress
code
Participation
in
Conferences
/Workshops
/ Seminars
Participation
in guest
lectures,
invited talks
and special
technical
sessions
Participation
in
community
Services
Participation
in Culture &
extra
curriculum
activities,
Department
Club
Activities
Participation
in
sports/ co-
curricular
activities
General
Behavior
Any Extra
Achievement
(5) (15) (20) (10) (20) (20) (5) (5)
Res
po
nsi
ble
fo
r
ma
rks
Men
tor
Hea
d
Hea
d
Men
tor
Cu
ltura
l E
ven
ts
Co
ord
inat
or
&
Dep
artm
ent
Clu
b
Co
ord
inat
or
Sp
ort
s C
oo
rdin
ator
Men
tor
Dir
ecto
r o
r
Pri
nci
pal