material safety data sheet - georgian bay fire & safety

LCGL48 Glycerine Antifreeze Premix50610448, 50612048, 50612548Not available.

Material Safety Data Sheet

Product name

Material usesCode

In case of emergency

1. Product and company identification

LCGL48 Glycerine Antifreeze Premix

:

:

:

:

KMK Regulatory Services Inc.:MSDS authored by

Conforms to ANSI Z400.1-2004 Standard

Supplier/Manufacturer : LynCar Inc.100 Westcreek blvd., unit 2Brampton, ONT L6T 5V7Tel: (800) 263-7011Fax: (800) 459-6227

CHEMTREC, U.S. : 1-800-424-9300 International: +1-703-527-3887

2. Hazards identification

Potential acute health effectsNo known significant effects or critical hazards.

No known significant effects or critical hazards.

No known significant effects or critical hazards.No known significant effects or critical hazards.

EyesSkin

InhalationIngestion

Physical state Liquid. [Sirupy.]

See toxicological information (Section 11)

NOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE HEALTH EFFECTS WHENTHE RECOMMENDED INSTRUCTIONS FOR USE ARE FOLLOWED.

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::

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Medical conditionsaggravated by over-exposure

None known.:

OSHA/HCS status : While this material is not considered hazardous by the OSHA Hazard CommunicationStandard (29 CFR 1910.1200), this MSDS contains valuable information critical to thesafe handling and proper use of the product. This MSDS should be retained andavailable for employees and other users of this product.

Potential chronic health effects

Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : No known significant effects or critical hazards.Developmental effects : No known significant effects or critical hazards.

Chronic effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.Over-exposure signs/symptoms

Ingestion : No specific data.:nikS No specific data.:seyE No specific data.

Inhalation : No specific data.

:roloC Water white to yellow.

Emergency overview

Hazard statements :

Precautionary measures : No known significant effects or critical hazards. Avoid prolonged contact with eyes, skinand clothing.

1/6KMK Regulatory Services Inc. Tel : +1-888-GHS-7769 (447-7769)/+1-450-GHS-7767 (447-7767); Services Réglementaires KMK Inc.www.kmkregservices.com


3. Composition/information on ingredients

Glycerol 56-81-5 30 - 60

Name CAS number %

Canada

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, areclassified as hazardous to health or the environment and hence require reporting in this section.

4. First aid measures

Notes to physician :

Eye contact

Wash out mouth with water. Do not induce vomiting unless directed to do so by medicalpersonnel. Never give anything by mouth to an unconscious person.

Immediately flush eyes with plenty of water for at least 20 minutes, occasionally liftingthe upper and lower eyelids.Wash with soap and water.Move exposed person to fresh air.

Skin contactInhalationIngestion

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:::

No specific treatment. Treat symptomatically.

Use an extinguishing agent suitable for the surrounding fire.

5. Fire-fighting measures

Extinguishing media

None known.Suitable :Not suitable :

Flammability of the product No specific fire or explosion hazard.:

Special protectiveequipment for fire-fighters

No special protection is required.:

Hazardous decompositionproducts

: Decomposition products may include the following materials:carbon dioxidecarbon monoxide

6. Accidental release measuresPersonal precautions Put on appropriate personal protective equipment (see Section 8).

Prevent entry into sewers, water courses, basements or confined areas. Contain andcollect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite ordiatomaceous earth and place in container for disposal according to local regulations(see section 13). Dispose of via a licensed waste disposal contractor. Note: see section1 for emergency contact information and section 13 for waste disposal.

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air).

:

Large spill :

Absorb with an inert dry material and place in an appropriate waste disposal container.Dispose of via a licensed waste disposal contractor.

Small spill :Methods for cleaning up

7. Handling and storage:gnildnaH Put on appropriate personal protective equipment (see Section 8). Eating, drinking and

smoking should be prohibited in areas where this material is handled, stored andprocessed. Workers should wash hands and face before eating, drinking and smoking.


LynCar


7. Handling and storageStore between the following temperatures: 10 to 32°C (50 to 89.6°F). Store inaccordance with local regulations. Store in original container protected from directsunlight in a dry, cool and well-ventilated area, away from incompatible materials (seesection 10) and food and drink. Keep container tightly closed and sealed until ready foruse. Containers that have been opened must be carefully resealed and kept upright toprevent leakage. Do not store in unlabeled containers. Use appropriate containment toavoid environmental contamination.

Storage :

8. Exposure controls/personal protection

Consult local authorities for acceptable exposure limits.

Canada

Occupational exposure limitssnoitatoNrehtO³m/gmmpprehtO³m/gmmpprehtO³m/gmmppeman tsiLtneidergnI

]a[-------01-0102/2 HIGCA SUlorecylGAB 4/2009 - 10 - - - - - - - [3] [b]BC 9/2010 - 10 - - - - - - - [b]

- 3 - - - - - - - [c]ON 7/2010 - 10 - - - - - - - [a]QC 6/2008 - 10 - - - - - - - [b]

TWA (8 hours) STEL (15 mins) Ceiling

[3]Skin sensitizationForm: [a]Inhalable fraction [b]Mist [c]Respirable mist

Recommended monitoringprocedures

Respirator selection must be based on known or anticipated exposure levels, thehazards of the product and the safe working limits of the selected respirator.

Safety eyewear should be used when there is a likelihood of exposure. Recommended:Safety glasses with side shields.No special protective clothing is required.

Personal protection

Eyes

Skin

Respiratory

:

:

:

Use gloves appropriate for work or task being performed.:sdnaH

Engineering measures : No special ventilation requirements. Good general ventilation should be sufficient tocontrol worker exposure to airborne contaminants.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period.

: Personal, workplace atmosphere or biological monitoring may be required to determinethe effectiveness of the ventilation or other control measures and/or the necessity to userespiratory protective equipment.

Environmental exposurecontrols

: Emissions from ventilation or work process equipment should be checked to ensure theycomply with the requirements of environmental protection legislation.

Not available.

Liquid. [Sirupy.]

Not available.

Not applicable.

Not available.Not available.

Water white to yellow.

Boiling/condensation point

9. Physical and chemical propertiesPhysical state

Molecular weight

pH

OdorTaste

Color

Not applicable.Molecular formula

:

:::::::

Flash point : Not available.

Not available.:Auto-ignition temperatureFlammable limits : Not available.

Burning time Not applicable.:Burning rate : Not applicable.


LynCar


9. Physical and chemical properties

Not available.

Not available.

Not available.

Not available.Not available.

Not available.Not available.Not available.

Not available.

Not available.

Melting/freezing point

Not available.

Not available.

Not available.

Critical temperatureRelative densityVapor pressureVapor densityVolatilityOdor thresholdEvaporation rate

ViscosityIonicity (in water)Dispersibility propertiesSolubilityPhysical/chemicalproperties comments

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SADT : Not available.

The product is stable.

Reactive or incompatible with the following materials: oxidizing materials.

10. Stability and reactivityChemical stabilityConditions to avoidIncompatible materials

:::

Possibility of hazardousreactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

No specific data.

Decomposition products may include the following materials:carbon dioxidecarbon monoxide

:Hazardous decompositionproducts

11. Toxicological informationAcute toxicity

-gk/g 01>tibbaRlamreD 05DLlorecylG-gk/gm 00621taRlarO 05DL

erusopxEesoDseicepStluseReman tneidergni/tcudorP

Irritation/CorrosionSkinEyesRespiratory

:::

SensitizerSkin

Respiratory

:

::HLDI Not available.

Synergistic products : Not available.

There are no data available.There are no data available.There are no data available.

There are no data available.

There are no data available.


LynCar


12. Ecological informationEcotoxicity : No known significant effects or critical hazards.Aquatic ecotoxicity

Glycerol Acute LC50 54000 mg sruoh 69hsiFl/

seicepSeman tneidergni/tcudorP erusopxEtluseR

The generation of waste should be avoided or minimized wherever possible. Dispose ofsurplus and non-recyclable products via a licensed waste disposal contractor. Disposalof this product, solutions and any by-products should at all times comply with therequirements of environmental protection and waste disposal legislation and any regionallocal authority requirements. Waste packaging should be recycled. This material and itscontainer must be disposed of in a safe way. Avoid dispersal of spilled material andrunoff and contact with soil, waterways, drains and sewers.

Waste disposal

13. Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations.

:

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handlinginformation and protection of employees.

14. Transport informationInternational transport regulationsTDG / IMDG / IATA : Not regulated by any transport mode.

15. Regulatory information

None of the components are listed.

Australia inventory (AICS): All components are listed or exempted.China inventory (IECSC): All components are listed or exempted.Japan inventory: All components are listed or exempted.Korea inventory: All components are listed or exempted.New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted.Philippines inventory (PICCS): All components are listed or exempted.

WHMIS (Canada) Not controlled under WHMIS (Canada).

International regulationsInternational lists

:

:

Canada

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all theinformation required by the Controlled Products Regulations.

Canadian NPRI :

Canada inventory : All components are listed or exempted.CEPA Toxic substances : None of the components are listed.

Canadian lists

16. Other information

Hazardous MaterialInformation System (U.S.A.)

National Fire ProtectionAssociation (U.S.A.)

NOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE HEALTH EFFECTS WHENTHE RECOMMENDED INSTRUCTIONS FOR USE ARE FOLLOWED.

Label requirements :

:

:

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards orrisks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings areto be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS®materials may be purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.

Health : 0Flammability :0 Physical hazards : 0

Health : 000 Instability :Flammability :


LynCar


16. Other informationReprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, NationalFire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire ProtectionAssociation, on the referenced subject which is represented only by the standard in its entirety.

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only byproperly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number ofchemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals areclassified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.

History

Date of previous issueVersion :

: 09/15/2011Date of issue : 02/15/2013

1

KMK Regulatory Services Inc. Tel : +1-888-GHS-7769 (447-7769)/+1-450-GHS-7767 (447-7767); Services Réglementaires KMK Inc.www.kmkregservices.com 6/6

Dr. Luc Séguin, PhD chemist, 25 years asa professional in regulatory compliance

Global - Multilingual authoring servicesfor all regulatory documents

Optimizing your company's GHSdeployment

Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of itssubsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should beused with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

LynCar

material safety data sheet - georgian bay fire & safety

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