material safety data sheets (msds): hazardous chemicals- shamu stadium, seaworld

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The Clorox Company 1221 Broadway Oakland, CA 94612 Tel. (510) 271-7000 Material Safety Data Sheet I Product: Description: CLEAR, LIGHT YELLOW LIQUID WITH A CHARACTERISTIC CHLORINE ODOR Other Designations Distributor Emergency Telephone Nos. Clorox Bleach EPA Reg. No. 5813-50 Clorox Sales Company 1221 Broadway Oakland, CA 94612 For Medical Emergencies call: (800) 446-1014 For Transportation Emergencies Chemtrec (800) 424-9300 II Health Hazard Data III Hazardous Ingredients May cause severe irritation or damage to eyes and skin. Vapor or mist may irritate. Harmful if swallowed. Keep out of reach of children. Some clinical reports suggest a low potential for sensitization upon exaggerated exposure to sodium hypochlorite if skin damage (e.g., irritation) occurs during exposure. Under normal consumer use conditions the likelihood of any adverse health effects are low. Medical conditions that may be aggravated by exposure to high concentrations heart conditions or chronic respiratory problems such as asthma, emphysema, chronic bronchitis or obstructive lung disease. FIRST AID : Eye Contact : Hold eye open and rinse with water for 15-20 minutes. Remove contact lenses, after first 5 minutes. Continue rinsing eye. Call a physician. Skin Contact : Wash skin with water for 15-20 minutes. If irritation develops, call a physician. Ingestion : Do not induce vomiting. Drink a glassful of water. If irritation develops, call a physician. Do not give anything by mouth to an unconscious person. Inhalation : Remove to fresh air. If breathing is affected, call a physician. Ingredient Concentration Exposure Limit Sodium hypochlorite 5 - 10% Not established CAS# 7681-52-9 Sodium hydroxide <1% 2 mg/m 1 CAS# 1310-73-2 2 mg/m 2 1 ACGIH Threshold Limit Value (TLV) - Ceiling 2 OHSA Permissible Exposure Limit (PEL) – Time Weighted Average (TWA) None of the ingredients in this product are on the IARC, NTP or OSHA carcinogen lists. IV Special Protection and Precautions V Transportation and Regulatory Data No special protection or precautions have been identified for using this product under directed consumer use conditions. The following recommendations are given for production facilities and for other conditions and situations where there is increased potential for accidental, large-scale or prolonged exposure. Hygienic Practices : Avoid contact with eyes, skin and clothing. Wash hands after direct contact. Do not wear product-contaminated clothing for prolonged periods. Engineering Controls: Use general ventilation to minimize exposure to vapor or Personal Protective Equipment: Wear safety goggles. Use rubber or nitrile gloves if in contact liquid, especially for prolonged periods. KEEP OUT OF REACH OF CHILDREN DOT/IMDG/IATA - Not restricted. EPA - SARA TITLE III/CERCLA : Bottled product is not reportable under Sections 311/312 and contains no chemicals reportable under Section 313. This product does contain chemicals (sodium hydroxide <0.2% and sodium TSCA/DSL STATUS : All components of this product are on the U.S. TSCA Inventory and Canadian DSL. VI Spill Procedures/Waste Disposal VII Reactivity Data Spill Procedures : Control spill. Containerize liquid and use absorbents on residual liquid; dispose appropriately. Wash area and let dry. For spills of multiple products, responders should evaluate the MSDS’s of the products for incompatibility with sodium hypochlorite. Breathing protection should be worn in enclosed, and/or poorly ventilated areas until hazard assessment is complete. Waste Disposal : Dispose of in accordance with all applicable federal, state, and local regulations. Stable under normal use and storage conditions. Strong oxidizing agent. Reacts with other household chemicals such as toilet bowl cleaners, rust removers, vinegar, acids or ammonia containing products to produce hazardous gases, such as chlorine and other chlorinated species. Prolonged contact with metal may cause pitting or discoloration. VIII Fire and Explosion Data IX Physical Data Flash Point : None Special Firefighting Procedures : None Unusual Fire/Explosion Hazards : None. Not flammable or explosive. Product does not ignite when exposed to open flame. Boiling point........................................................................ approx. 212 F/100 C Specific Gravity (H20=1) ................................................................. ~ 1.1 at 70 o F Solubility in Water ................................................................................. complete pH ............................................................................................................... ~11.9 1963, 1991 THE CLOROX COMPANY DATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH DATE PREPARED 08/09 Health Hazard Data DANGER: CORROSIVE. May cause seve re irritation or damage to eyes and skin. Vapor or mist may irritate. Harmful if swallowed. Medical conditions that may be aggravat ed by exposure to high concentrations of vapor or mist: heart conditions or chronic resp iratory problems such as asthma, emphysema, chronic bronchiti s or obstructive lung disease. Hazardous Ingredients Sodium hypochlorite Sodium hydroxide This product does contain chemicals (sodium hydroxide <0.2% and sodium hypochlorite <7.35% ) that are regulated under Section 304/CERCLA. For spills of multiple products, responders should eval uate the MSDS’s of the products for incompatibility with sodium hypochlorite. Reactivity Data Strong oxidizing agent. Spill Procedures/Waste Disposal Transportation and Regulatory Data Avoid contact with eyes, skin Wear safety goggles. Special Protection and Precautions Material Safety Data Sheet CLOROX REGULAR-BLEACH mi nimize exposure to vapor or mist. Reacts with other household chemicals

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Material Safety Data Sheets (MSDS) for hazardous chemicals found stored with killer whale food supply at Shamu Stadium, SeaWorld Orlando, Florida. Includes Clorox bleach, CompAir CS300 air compressor oil and Dawn detergent. For more info visit www.theorcaproject.com

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Page 1: Material Safety Data Sheets (MSDS): Hazardous Chemicals- Shamu Stadium, SeaWorld

The Clorox Company 1221 Broadway Oakland, CA 94612 Tel. (510) 271-7000

Material Safety Data Sheet

I Product: CLOROX REGULAR-BLEACH

Description: CLEAR, LIGHT YELLOW LIQUID WITH A CHARACTERISTIC CHLORINE ODOR

Other Designations Distributor Emergency Telephone Nos.

Clorox Bleach EPA Reg. No. 5813-50

Clorox Sales Company 1221 Broadway

Oakland, CA 94612

For Medical Emergencies call: (800) 446-1014

For Transportation Emergencies Chemtrec (800) 424-9300

II Health Hazard Data III Hazardous Ingredients

DANGER: CORROSIVE. May cause severe irritation or damage to eyes and skin. Vapor or mist may irritate. Harmful if swallowed. Keep out of reach of children. Some clinical reports suggest a low potential for sensitization upon exaggerated exposure to sodium hypochlorite if skin damage (e.g., irritation) occurs during exposure. Under normal consumer use conditions the likelihood of any adverse health effects are low. Medical conditions that may be aggravated by exposure to high concentrations of vapor or mist: heart conditions or chronic respiratory problems such as asthma, emphysema, chronic bronchitis or obstructive lung disease.

FIRST AID:Eye Contact: Hold eye open and rinse with water for 15-20 minutes. Remove contact lenses, after first 5 minutes. Continue rinsing eye. Call a physician. Skin Contact: Wash skin with water for 15-20 minutes. If irritation develops, call a physician. Ingestion: Do not induce vomiting. Drink a glassful of water. If irritation develops, call a physician. Do not give anything by mouth to an unconscious person.Inhalation: Remove to fresh air. If breathing is affected, call a physician.

Ingredient Concentration Exposure LimitSodium hypochlorite 5 - 10% Not established

CAS# 7681-52-9

Sodium hydroxide <1% 2 mg/m1

CAS# 1310-73-2 2 mg/m2

1ACGIH Threshold Limit Value (TLV) - Ceiling

2OHSA Permissible Exposure Limit (PEL) – Time Weighted Average (TWA)

None of the ingredients in this product are on the IARC, NTP or OSHA carcinogen lists.

IV Special Protection and Precautions V Transportation and Regulatory Data

No special protection or precautions have been identified for using this product under directed consumer use conditions. The following recommendations are given for production facilities and for other conditions and situations where there is increased potential for accidental, large-scale or prolonged exposure.

Hygienic Practices: Avoid contact with eyes, skin and clothing. Wash hands after direct contact. Do not wear product-contaminated clothing for prolonged periods.Engineering Controls: Use general ventilation to minimize exposure to vapor or mist.

Personal Protective Equipment: Wear safety goggles. Use rubber or nitrile gloves if in contact liquid, especially for prolonged periods.

KEEP OUT OF REACH OF CHILDREN

DOT/IMDG/IATA - Not restricted.

EPA - SARA TITLE III/CERCLA: Bottled product is not reportable under Sections 311/312 and contains no chemicals reportable under Section 313.This product does contain chemicals (sodium hydroxide <0.2% and sodium hypochlorite <7.35% ) that are regulated under Section 304/CERCLA.

TSCA/DSL STATUS: All components of this product are on the U.S. TSCA Inventory and Canadian DSL.

VI Spill Procedures/Waste Disposal VII Reactivity Data Spill Procedures: Control spill. Containerize liquid and use absorbents on residual liquid; dispose appropriately. Wash area and let dry. For spills of multiple products, responders should evaluate the MSDS’s of the products for incompatibility with sodium hypochlorite. Breathing protection should be worn in enclosed, and/or poorly ventilated areas until hazard assessment is complete. Waste Disposal: Dispose of in accordance with all applicable federal, state, and local regulations.

Stable under normal use and storage conditions. Strong oxidizing agent. Reacts with other household chemicals such as toilet bowl cleaners, rust removers, vinegar, acids or ammonia containing products to produce hazardous gases, such as chlorine and other chlorinated species. Prolonged contact with metal may cause pitting or discoloration.

VIII Fire and Explosion Data IX Physical Data Flash Point: None Special Firefighting Procedures: None Unusual Fire/Explosion Hazards: None. Not flammable or explosive. Product does not ignite when exposed to open flame.

Boiling point........................................................................approx. 212 F/100 CSpecific Gravity (H20=1) ................................................................. ~ 1.1 at 70oFSolubility in Water ................................................................................. complete pH ...............................................................................................................~11.9

1963, 1991 THE CLOROX COMPANYDATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH DATE PREPARED 08/09

II Health Hazard Data III Hazardous Ingredients

DANGER: CORROSIVE. May cause severe irritation or damage to eyes and DANGER: CORROSIVE. May cause severe irritation or damage to eyes and skin. Vapor or mist may irritate. Harmful if swallowed. Keep out of reach of

Medical conditions that may be aggravated by exposure to high concentrations Medical conditions that may be aggravated by exposure to high concentrations of vapor or mist: heart conditions or chronic respiratory problems such as of vapor or mist: heart conditions or chronic respiratory problems such as asthma, emphysema, chronic bronchitis or obstructive lung disease.

II Health Hazard Data III Hazardous Ingredients

IngredientSodium hypochlorite 5 - 10% Not established

Sodium hydroxide <1% 2 mg/m

als reportable under Section 313.This product does contain chemicals (sodium hydroxide <0.2% and sodium This product does contain chemicals (sodium hydroxide <0.2% and sodium hypochlorite <7.35% ) that are regulated under Section 304/CERCLA.

: Control spill. Containerize liquid and use absorbents on Wash area and let dry. For spills of residual liquid; dispose appropriately. Wash area and let dry. For spills of

multiple products, responders should evaluate the MSDS’s of the products for multiple products, responders should evalincompatibility with sodium hypochlorite. Breathing protection should be worn in

VI Spill Procedures/Waste Disposal VII Reactivity Data Stable under normal use and storage conditions. Strong oxidizing agent.

VI Spill Procedures/Waste Disposal VII Reactivity Data

V Transportation and Regulatory Data

: Avoid contact with eyes, skin and clothing. Wash hands

Wear safety goggles. Use rubber or nitrile

IV Special Protection and Precautions

Material Safety Material Safety Data Sheet

CLOROX REGULAR-BLEACH

minimize exposure to vapor or Engineering Controls:mist.

Stable under normal use and storage conditions. Strong oxidizing agent. Reacts with other household chemicals

Page 2: Material Safety Data Sheets (MSDS): Hazardous Chemicals- Shamu Stadium, SeaWorld

12630 Allard Street Santa Fe Springs, CA 90670 United States of AmericaTelephone +1 (562) 406 8881 Facsimile +1 (562) 406 8887 www.CompAirUSA.com

MATERIAL SAFETY DATA SHEET

Section I: Chemical Product & Company Identification

Product Name: CS300 Applies to All Grades

Product Category: Synthetic Hydrocarbons MSDS Form: APL Manufacturer: CompAir Street: 12630 Allard Street Mfg. Phone 562-406-8881 City, State, Zip: Santa Fe Springs, CA 90670 Emergency Only (Chemtrec): 800-424-9300

Section II: Components & Hazard Data

Components: CAS Number(s) Concentration Exposure Limit Synthetic Lubricant containing This products is not a hazard 100%

Total Productphthalate diester, synthetic as defined 100% in 29 CFR1910.1200 5mg/m3 for oil Hydrocarbon and additives mist hour work day Mixture

Section III: Health Hazard Data

HMIS RATING: Health: 1 Fire: 1 Reactivie: 0 Personal Protection: See Sec. VIII

Route of Exposure: Ingestion: Minimal toxicity Inhalation: Negligible hazard at 0 to 100°F. Avoid breathing vapors or mist. Eyes: Slightly irritating, but does not injure eye tissue. Skin: Low order of toxicity. Emergency Overview: This product has a low order of toxicity and does not require a cancer hazard warning.

Section IV: First Aid Procedures

MATERIAL SAFETY DATA SHEET

Product Name: CS300 : Synthetic Hydrocarbons

Hydrocarbon and additives mist hour

phthalate diester, synthetic as defined 100% in

Synthetic Lubricant containing This products is not

Section II: Components & Hazard Data

Negligible hazard at 0 to 100°F. Avoid breathing vapors or mist.

Section III: Health Hazard Data

Manufacturer: CompAir Manufacturer: CompAir

Page 3: Material Safety Data Sheets (MSDS): Hazardous Chemicals- Shamu Stadium, SeaWorld

Ingestion: First aid is not normally required.

Inhalation: Using proper respiratory protection, immediately remove the affected victim from exposure. Administer artificial respiration if breathing is stopped. Keep at rest. Call for prompt medical attention. Eye Contact: Flush eyes with large amounts of water until irritation subsides. If irritation persists, get medical help. Skin: Wash thoroughly after exposure. Remove and launder contaminated clothing.

Section V: Fire & Explosion Hazard Data

NFPA RATINGS: Health: 1 Fire: 1 Reactivity: 0 Flashpoint: >400°F, COC LEL: No Data UEL:

No Data

Extinguishing Media: Foam, dry chemical or water spray. Special Fire Fighting Procedures: Use water spray to cool containers and protect personnel. Fire & Explosion Hazards: Vapors may ignite. Minimize breathing vapors, gases, fumes and decomposition products. Use proper protective equipment and self-contained breathing apparatus in confined and/or enclosed areas. Products Produced From Thermal Decomposition: Fumes, smoke, carbon monoxide and oxides of nitrogen and of phosphorous.

Section VI: Physical Data The following data is typical, approximate data and should not be used for precise

design purposes.

Boiling Range: >460°F Solubility (in water): Negligible Physical Form: Oily Liquid Vapor Density (air=1): >1 Evaporation Rate (water=1): <.01 Specific Gravity: 96 % Volatile by Volume: Negligible Vapor Pressure, mmHG @ deg F: Negligible.

Section VII: Reactivity Data Stability: This product is stable and will not react violently with water. Hazardous polymerization will not occur. Avoid contact with oxidizing agents.

Section V: Fire & Explosion Hazard Data

Fire & Explosion Hazards: Vapors may ignite. Minimize breathing vapors, gases, fumes and decomposition products. Use proper prote

Section VII: Reactivity Data

polymerization will not occur. Avoid contact with oxidizing agents.

Inhalation: Using proper respiratory protection, immediately Using proper respiratory protection, immediately remove the affected victim from exposure. Administer artificial respiration if breathing is stopped. Keep at rest. Call for prompt medical attention.

Page 4: Material Safety Data Sheets (MSDS): Hazardous Chemicals- Shamu Stadium, SeaWorld

Section VIII: Personal Protection & Exposure Controls Respiratory Protection: Not usually required. Use supplied-air respiratory protection in confined or enclosed spaces, if needed. Supply sufficient ventilation so permitted exposure levels are not exceeded.

Skin Protection: Use chemical resistant gloves, aprons, shoes, etc. to avoid prolonged and repeated skin contact. Launder soiled clothing before reuse.

Eye Protection: Use splash goggles or face shield when eye contact may occur.

Hygienic Practices: Wash thoroughly before meals, breaks, and at the end of work period. Remove contaminated clothing and launder before reuse. Product is readily removed from skin by waterless hand cleaners, followed by washing thoroughly with soap and water.

Storage & Handling Practices: Do not alter or pressurize container. Do not store or use near any source of ignition or strong oxidizers.

Section IX: Transportation Information U.S. DOT Shipping Description, Label, Number, Class: None, not regulated. For transportation spill, refer to latest DOT Emergency Response Guidebook for Hazardous Materials Incidents.

Section X: Environmental Information Spill or Release Information: This products may be classified as an oil under Section 311 of the Clean Water Act and Oil Pollution Act. Spills or discharges into or leading to surface waters, that cause a sheen, must be reported to the National Response Center. Recover free product. Divert product from watercourses and sewers. Contain and absorb all product. Assure conformity with all applicable governmental regulations for reporting and disposal.

OSHA: Product requires a warning label.

SARA Sec. 301-304: No TPQ or RQ for product or any constituent greater than 1% or 0.1% for carcinogen.

SARA Sec. 311-312: Check with local Emergency Planning Committee for reportable quantity of hazardous substances.

SARA Sec. 313: No toxic chemical is present greater than 1% or 0.1% for carcinogen.

Section VIII: Personal Protection & Exposure Controls Section VIII: Personal Protection & Exposure Cont

Do not alter or pressurize container. Do not store or use near any source of ignition or strong oxidizers. Storage & Handling Practices: Do not alter or pressurize container. Do not store or

Section X: Environmental Information This products may be classified as an oil under

Section 311 of the Clean Water Act and Oil Pollution Act. Spills or discharges into or

OSHA: Product requires a warning label.

Supply sufficient ventilation so permitted exposure levels are not exceeded.

Use chemical resistant gloves,

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