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1 Mechanism of electric conductance in crystals

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Page 1: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

1

Mechanism of electric conductance

in crystals

Page 2: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

2

A

Electric current in conductors

When the conductor is in electric field, the field accelerates free

electrons

Electrons moving (drifting) in electric field transfer the electric

charge.

Moving electric charges create electric current through the

conductor

Page 3: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

3

Electric current in crystalline conductors

Electric Field +++

---

t

QI =

Factors determining the electric current in crystalline conductors:

1. How many free electrons the crystal has

2. How fast the charge carriers (i.e. electrons)

can move in the electric field

Page 4: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

4

How many free electrons are there in the conductor?

Metals have ~ 1023 atoms per 1 cm3

Every atom donates 1 free electron:

Therefore, every 1 cm3 of the metal contains ~ 1023 free electrons

n ~ 1023 cm-3 = 1023 (1/cm3)

n is the electron concentration

The concentration shows the number of particles per unit volume

Page 5: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

5

Conductors, Insulators and Semiconductors

Metal:

~ 1023 atoms per 1 cm3

Every atom donates 1 free electron:

n ~ 1023 cm-3

Insulator:

~ 1023 atoms per 1 cm3;

No free electrons:

n ~ 0

Semiconductor:

~ 1023 atoms per 1 cm3;

Some atoms donate free

electrons

n ~ 1010 - 1019 cm-3

Page 6: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

6

Example problem 1

0

of

5

The metal bar dimensions are 2mm x 3 mm x 0.5 mm;

Free electron concentration in the metal is 2x1023 cm-3.

How many free electrons the bar contains?

Timed response

120120

Page 7: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

7

Example problem 2

0

of

5

Thin-film wire is 2 µm thick, 5 mm long and 20 µm wide.

Free electron concentration in the metal is 5x1022 cm-3.

How many free electrons the wire contains?

Timed response

120120

Page 8: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

8

How fast the electrons can move:

electron mobility in crystals

Equilibrium condition, no electric field (voltage) applied

Free electron experiences very frequent collisions with atoms in the

metal.

As a result it moves randomly (with the velocity of around 105 m/s).

On average, the electron does not go anywhere!

Average electric current is equal to zero

(There is a flicker charge transfer, or the NOISE current though)

Page 9: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

9

Electric field applied:

There is an electric force, F = e E exerting on any free electron.

Electron still experiences very frequent random collisions.

However, after each collision the electron’s velocity has a component toward the positive electrode (against the field direction)

On average, the electron drifts from negative electrode toward positive.

There is a current flowing through the metal.

Electron in motion in conductors

Page 10: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

10

Electron mobility in crystals

Ignoring the collisions, which are completely random, we can say that

average electron velocity (drift velocity) is proportional to the electric

field applied:

v ~ E

v = µ E

µ is called the electron mobility: µ = v/E [(m/s)/(V/m) = m2/(V.s)]

Let us ignore the

random collisions

and only monitor

the drift in the

electric field

Page 11: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

11

A

Electric current in conductors

Electron drift velocity increases with electric field:

v = µ E

Electric field

Ele

ctri

c cu

rre

nt

Higher electron concentration

Page 12: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

12

A

Mechanism of electric conductance

A = wire cross-section area

n= free electron concentration, i.e. the number of electrons per unit

volume

L

∆∆∆∆L = = = = v.∆∆∆∆ t

In the ∆∆∆∆t time interval, how many electrons will cross the dashed area A?

∆Ν∆Ν∆Ν∆Ν = n (v ∆∆∆∆t) A

How much charge will pass through?

∆∆∆∆Q = e ∆Ν∆Ν∆Ν∆Ν = e n (v ∆∆∆∆t) A; where e = abs (electron charge)

Avnet

QI =

∆=The electric current

Gnome is

counting the

electrons

E

If the conductor volume is A×L, the total number of electrons, N = n ×A×L

Page 13: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

13

A A = wire cross-section area

v.

Anet

QI v=

∆=The electric current

The electron drift velocity, v = µ E,from this,

Mechanism of electric conductance

( )EAneI µ=

Electric current is proportional to the electric field (external parameter)

Electric current is proportional to n, µ and A (conductor parameters)

E

Page 14: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

14

A

v.

1. The external power source (the battery) creates a potential

difference along the conductor: V;

2. The potential difference (the voltage) creates an electric field

across the conductor

E = V/L;

3. Electric field accelerates free electrons and produces the

current

VL

AneV

L

AneI

== µµ

E

Mechanism of electric conductance

( )EAneI µ=

Using E = V/L:

Page 15: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

15

VL

AneV

L

AneI

== µµ

Mechanism of electric conductance

This product contains only the material parameters,

does not depend on applied voltage or on the geometrical

shape of the conductor.

It is called conductivity:

µσ ne=

Material properties are also often characterized by

resistivity:

1 1

enρ

σ µ= =

Page 16: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

16

VL

AI σ=

Using conductivity or resistivity the current – voltage

relationship is:

The term

or VL

AI ⋅=

ρ

1

L

A

ρ

1does not depend on the applied voltage

but only on the material properties and the sample dimensions.

is called resistance.

Using the resistance, the I-V relationship is:

VR

I1

= or RIV ⋅=

These two relationships are called the Ohm’s law

A

LR ⋅= ρ

Page 17: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

17

The Ohm’s Law

George Ohm has established experimentally in 1827 the following

law1

I VR

=

- + I

V

V is the voltage across a conductor

I is the current thought a conductor

1/R is a proportionality factor;

R is called “resistance”

Voltage

Ele

ctri

c

curr

en

t

Less resistance

Page 18: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

18

Ohm’s Law and electron charge transfer rate

comparison

1I V

R=

Voltage

Ele

ctri

c

curr

en

t

Less resistance

Electric field

Ele

ctri

c cu

rre

nt

Higher e

lectron concentra

tion

v = µ E

Page 19: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

19

Experimental observations of Ohm’s Law

1I V

R=

VoltageE

lect

ric

curr

en

t

Conductor length

decreases

Current increases,

i.e. R decreases

Page 20: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

20

Experimental observations of Ohm’s Law

1I V

R=

VoltageE

lect

ric

curr

en

t

Conductor area

increases

Current increases,

i.e. R decreases

Page 21: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

21

Ohm’s law, resistance and resistivity - summary

V I R= × Ohm’s law in the form of V(I): the voltage needed to

maintain the current I = current times resistance.

L is the length of the conductor

in the direction of the current flow;

A is the cross-section area;

µρ

ne

1=

A

LR ρ=

ρ describes the material ability to conduct the current.

The higher ρ is, the higher R and the lower the current

VIR

=Ohm’s law in the form of I(V): the current through the

conductor = applied voltage divided by the resistance

LR

Aρ=

Page 22: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

22

The units for resistance and resistivity

A

LR ρ=

RIV ×=I

VR =

Resistance R is measured in Ohms (Ohm, ΩΩΩΩ)

1 Ohm is the resistance of the sample that passes the current of 1A

when the voltage of 1 V is applied across it.

⋅== mOhm

m

mOhm

L

AR

2

ρ

Resistivity is measured in Ohm - meters (Ohm· m)

Page 23: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

23

Ohms’ law using conductance and conductivity

1G R/=Conductance

L

AG σ=

I G V= ⋅

Using the conductance, the Ohm’s law can be written as

Also, from 1G R/=

1enσ µ

ρ= = σ is the conductivity of the material

(does not depend on the conductor shape)

Using conductivity, the conductance of the sample is given by

11

AG R

L/

ρ= =

LR

A,ρ=and

Page 24: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

24

Ohm’s Law using conductance - summary

material theofty conductivi the

(wire), sample theof econductanc

,

isne

theisL

AG

whereVGI

µσ

σ

=

=

×=

The expression that relates the electric current to the applied

voltage

is called the Ohm’s Law (established experimentally in 1827)

A is the conductor cross-section area;

L is the conductor length along the current direction

n is the concentration of free electrons

µ is the electron mobility

Page 25: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

25

The units for conductance and conductivity

L

AG σ=

VGI ×=V

IG =

Conductance is measured in Siemens (S)

1 S is the conductance of the sample that passes the current of 1A

when the voltage of 1 V is applied across it.

== mS

m

mS

A

LG /

Conductivity is measured in Siemens per meter (S/m)

Page 26: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

26

Ohm’s Law in the differential (“microscopic”) form:

( )EAneI µ=

or

I A Eσ=

where A is the cross-section area,

E is the electric field in the conductor

where σ = enµ is the conductivity of

the material

or

VI A

Lσ=

where V is the voltage across the conductor

and L is the conductor length in the direction

of current flow

Page 27: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

27

Problem 3.

What is the current in the circuit below?

1 2 3 4

0% 0%0%0%

1. 3 A

2. 4 A

3. 36 A

4. 12 A

6060

Page 28: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

28

Resistivity of different materials

Wires are used to connect different components in the network;

Wires have very low resistance

Resistors are used to dissipate the power and to change the voltage

(potential).

Material Electric Resistivity (×10-9 Ohm·m)

Aluminum [Al] 27

Aluminum Alloy 50

Brass 20 - 61

Carbon [C] 1.4 × 104

Copper [Cu] 17

Copper Alloy 17 - 490

Gold [Au] 24

Iron [Fe] 97

Page 29: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

29

Problem 4.

Find the resistance of a wire made of copper [Cu] (ρ = 17*10-9 Ohm-m).

The wire is 1 m long and is 1 mm in diameter.

1 2 3 4

0% 0%0%0%

180180

1. 0.043 Ohm

2. 2.17*10-2 Ohm

3. 1.39 *10-2 Ohm

4. 435 S

Page 30: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

30

Solution

Find the resistance of a wire made of copper [Cu] (ρ = 17*10-9 Ohm-m).

The wire is 1 m long and is 1 mm in diameter.

R = ρ *L/A

L = 1 m; D = 1mm = 10-3 m;

The area, A = π*D2/4 = 3.14*(10-3)2/4 = 7.85*10-7 m2

The resistance

R = 17*10-9 Ohm*m*1m/ 7.85*10-7 m2 = 2.17*10-2 Ohm = 21.7 mOhm

Conclusion: wires do not change the potentials in the circuit;

Voltage across the wire can be taken as 0 in most problems

Find the voltage across this wire, in the current through it is 1 A

V = I ×R = 1 A × 21.7 m Ohm = 21.7 mV

Page 31: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

31

Problem 5.

Find the resistance of a carbon resistor (ρ ρ ρ ρ = 1.4 × 10-5 Ohm*m), that is

1 cm long and 0.1 mm in diameter

1 2 3 4

0% 0%0%0%

180180

1. 0.178 Ohm

2. 17.8 Ohm

3. 1.78 Ohm

4. 0.0178 Ohm

Page 32: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

32

Solution

Find the resistance of a carbon resistor, which is 1 cm long and 0.1 mm

in diameter

R = ρ *L/A; ρ = 1.4 × 104 * 10-9 Ohm*m = 1.4 × 10-5 Ohm*m ;

L = 1 cm = 10-2m; A = 7.85*10-9 m2

R = 1.4*10-5 Ohm*m*10-2 m/ 7.85*10-9 m2 = 17.8 Ohm

Compare: Cu – wire, R1 = 21.7 mOhm ≈ 0.02 Ohm;

Carbon-resistor, R2 = 17.8 Ohm ≈ 18 Ohm;

Given electric circuit with the current of 1 A, the voltage dropacross the Cu- wire, V1 = I*R1 = 0.02 V;

The voltage drop across the Carbon-resistor, V2 = I*R2 = 18 V;

Resistors significantly change the potentials in the circuit.

Page 33: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

33

Problem 6. Two wires are made of the same material.

The lengths and the diameters are as follows:

1 2 3

0% 0%0%

1 mm10 cmWire 1

2 mm20 cmWire 2

DiameterLength

Which wire, #1 or #2, has higher resistance?

1. Wire #1

2. Wire #2

3. Equal resistances

120120

Page 34: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

34

Problem 7. The bar made of carbon (ρ = 1.4 × 10-5 Ohm*m)

The current flows through the bar in the direction shown by a blue arrow.

L = 10 cm; W=5 mm; d = 2 mm. What is the resistance of the bar?

1 2 3

0% 0%0% 180180

L

d

W

I

1. 5.6e-5 Ohm

2. 0.14 Ohm

3. 3.5e-4 Ohm

Page 35: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

35

Problem 8. The bar made of carbon (ρ = 1.4 × 10-5 Ohm*m)

The current flows through the bar in the direction shown by a blue arrow.

L = 10 cm; W=5 mm; d = 2 mm. What is the resistance of the bar?

1 2 3

0% 0%0% 180180

L

d

W

I

1. 5.6e-5 Ohm

2. 0.14 Ohm

3. 3.5e-4 Ohm

Page 36: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

36

Problem 9.

What voltage is needed

to generate the current of 2A in a resistor of 100 Ohm?

1 2 3 4

0% 0%0%0%6060

1. 50 V

2. 2 V

3. 200 V

4. 25 V

Page 37: Mechanism of electric conductance in crystals Electric conducta… · The Ohm’s Law George Ohm has established experimentally in 1827 the following law 1 I V R = - + I V V is the

37

Problem 10.

What voltage is needed

to generate the current of 2A in a resistor of 0.01 Ohm?

1 2 3 4

0% 0%0%0%6060

1. 0.2 V

2. 0.02 V

3. 20 V

4. 25 V