metal panel corrosion testing with deforest corrosion
TRANSCRIPT
DeForest Enterprises, Inc.Focusing On Product Differentiation, Market Needs, &
Performance Improvement
Metal Panel Submersion Testing, 4/2/19
Metal Panel Submersion Testing
DeForest Standard Method Panels submerged halfway into solution with corrosion inhibitor, in sealed glass jars Top half of panels are in the vapor phase Tested in solutions of standard hard water (100ppm as CaCO3 & 71ppm as chlorides),
unless otherwise noted Corrosion inhibitors tested at varying concentrations (by weight) “Blank” panels- same testing water, no corrosion inhibitor
Standard Metals Aluminum Panels: Bare Aluminum, #2024 Steel Panels: Cold Rolled Steel (Mild), SAE 210 Copper Panels: #110 Copper (99.95% Cu) Brass Panels: #260 Brass Alloy (30% Zn / 70% Cu)
DeForest Enterprises, Inc.Water Soluble Corrosion InhibitorsCorrosion Testing
DeForest Enterprises, Inc.Water Soluble Corrosion InhibitorsComparison of Multi-Metal Inhibitors
Blank 1% 0.5% 0.25%
2024 Bare Aluminum 120 days RT
1% 0.25% Blank
2024 Bare Aluminum90 Days RT
• Bottom half of panels are submerged in solution containing corrosion inhibitor, top half of panels are in the vapor phase• Solution contains 0.25% to 1.0% by weight corrosion inhibitor in hard water (100ppm CaCO3 / 71ppm as chloride)
DeCORE AFCI-45 45% active, mixed carboxylate (alkali salt) Amine-free No azoles, borates, phosphorous, nitrites
DeCORE APCI-95MOD 100% active, amine carboxylate Contains MEA and TEA Contains azole chemistry
DeForest Enterprises, Inc.Water Soluble Corrosion InhibitorsComparison of Multi-Metal Inhibitors
0.25% 0.5% 1.0%
2024 Bare Aluminum 1 Year RT
1% 0.25% Blank
2024 Bare Aluminum1 Year RT
• Bottom half of panels are submerged in solution containing corrosion inhibitor, top half of panels are in the vapor phase• Solution contains 0.25% to 1.0% by weight corrosion inhibitor in hard water (100ppm CaCO3 / 71ppm as chloride)
DeCORE AFCI-45 45% active, mixed carboxylate (alkali salt) Amine-free No azoles, borates, phosphorous, nitrites
DeCORE APCI-95MOD 100% active, amine carboxylate Contains MEA and TEA Contains azole chemistry
DeForest Enterprises, Inc.Water Soluble Corrosion InhibitorsComparison of Multi-Metal Inhibitors
Blank 0.25% 0.5% 1.0%
SAE 210 Cold Rolled Steel120 Days RT
1% 0.25% Blank
SAE 210 Cold Rolled Steel90 Days
• Bottom half of panels are submerged in solution containing corrosion inhibitor, top half of panels are in the vapor phase• Solution contains 0.25% to 1.0% by weight corrosion inhibitor in hard water (100ppm CaCO3 / 71ppm as chloride)
DeCORE AFCI-45 45% active, mixed carboxylate (alkali salt) Amine-free No azoles, borates, phosphorous, nitrites
DeCORE APCI-95MOD 100% active, amine carboxylate Contains MEA and TEA Contains azole chemistry
DeForest Enterprises, Inc.Water Soluble Corrosion InhibitorsComparison of Multi-Metal Inhibitors
0.25% 0.5% 1.0%
SAE 210 Cold Rolled Steel1 Year RT
1% 0.25% Blank
SAE 210 Cold Rolled Steel1 Year RT
• Bottom half of panels are submerged in solution containing corrosion inhibitor, top half of panels are in the vapor phase• Solution contains 0.25% to 1.0% by weight corrosion inhibitor in hard water (100ppm CaCO3 / 71ppm as chloride)
DeCORE AFCI-45 45% active, mixed carboxylate (alkali salt) Amine-free No azoles, borates, phosphorous, nitrites
DeCORE APCI-95MOD 100% active, amine carboxylate Contains MEA and TEA Contains azole chemistry
DeForest Enterprises, Inc.Water Soluble Corrosion InhibitorsComparison of Multi-Metal Inhibitors
Blank 0.25% 0.5% 1.0%
110 Copper Panels120 Days RT
1% 0.25% Blank
110 Copper Panels90 Days RT
• Bottom half of panels are submerged in solution containing corrosion inhibitor, top half of panels are in the vapor phase• Solution contains 0.25% to 1.0% by weight corrosion inhibitor in hard water (100ppm CaCO3 / 71ppm as chloride)
DeCORE AFCI-45 45% active, mixed carboxylate (alkali salt) Amine-free No azoles, borates, phosphorous, nitrites
DeCORE APCI-95MOD 100% active, amine carboxylate Contains MEA and TEA Contains azole chemistry
DeForest Enterprises, Inc.Water Soluble Corrosion InhibitorsComparison of Multi-Metal Inhibitors
0.25% 0.5% 1.0%
110 Copper Panels1 Year RT
1% 0.25% Blank
110 Copper Panels1 Year RT
• Bottom half of panels are submerged in solution containing corrosion inhibitor, top half of panels are in the vapor phase• Solution contains 0.25% to 1.0% by weight corrosion inhibitor in hard water (100ppm CaCO3 / 71ppm as chloride)
DeCORE APCI-95MOD 100% active, amine carboxylate Contains MEA and TEA Contains azole chemistry
DeCORE AFCI-45 45% active, mixed carboxylate (alkali salt) Amine-free No azoles, borates, phosphorous, nitrites
DeForest Enterprises, Inc.Water Soluble Corrosion InhibitorsComparison of Multi-Metal Inhibitors
Blank 0.25% 0.5% 1.0%
260 Brass Panels120 Days RT
1% 0.25% Blank
260 Brass Panels90 Days RT
• Bottom half of panels are submerged in solution containing corrosion inhibitor, top half of panels are in the vapor phase• Solution contains 0.25% to 1.0% by weight corrosion inhibitor in hard water (100ppm CaCO3 / 71ppm as chloride)
DeCORE AFCI-45 45% active, mixed carboxylate (alkali salt) Amine-free No azoles, borates, phosphorous, nitrites
DeCORE APCI-95MOD 100% active, amine carboxylate Contains MEA and TEA Contains azole chemistry
DeCORE AFCI-45 45% active, mixed carboxylate (alkali salt) Amine-free No azoles, borates, phosphorous, nitrites
DeCORE APCI-95MOD 100% active, amine carboxylate Contains MEA and TEA Contains azole chemistry
DeForest Enterprises, Inc.Water Soluble Corrosion InhibitorsComparison of Multi-Metal Inhibitors
0.25% 0.5% 1.0%
260 Brass Panels1 Year RT
1% 0.25% Blank
260 Brass Panels1 Year RT
• Bottom half of panels are submerged in solution containing corrosion inhibitor, top half of panels are in the vapor phase• Solution contains 0.25% to 1.0% by weight corrosion inhibitor in hard water (100ppm CaCO3 / 71ppm as chloride)
DeForest Enterprises, Inc.Water Soluble Corrosion InhibitorCorrosion Testing: Flash Rust Protection at pH ~3 to ~5.5
Procedure: Cold rolled steel panels were placed into each solution and allowed to soak for ~1 hour at room temperature. The steel panels were removed and allowed to air dry without rinsing.
No rust forms on the panels if DeCORE AFCI-45 present.
DeCORE AFCI-45 @ 1% by weight (0.45% active)
SAE 210 Cold Rolled Steel
First Beaker: Acidified tap water (pH 7.01) with a few drops of a10% citric acid solution to finalpH 5.35
Second Beaker: 1% by weight DeCORE AFCI-45 added to acidified tap water to final pH 5.39
Third Beaker: Acidified distilled water (pH 5.53) with a few drops of a 10% citric acid solution to final pH 3.45
Fourth Beaker: 1% by weight DeCORE AFCI-45 added to acidified distilled water to final pH 5.38
DeForest Enterprises, Inc.Hydrotrope Cloud Point Comparison5% NP-9 w/ 3.75% hydrotrope (by weight, as-is)
SMP = Sodium Metasilicate Pentahydrate / TKPP = Tetrapotassium Pyrophosphate / SXS-40 = Sodium Xylene Sulfonate 40%
0
10
20
30
40
50
60
70
80
90
5% NaOH 10% NaOH 5% TKPP 5% SMP
Clou
d Po
int (
C)
Test Formulation: 5% NPE-9, 3.75% Hydrotrope (by wt.), 91.25% Electrolyte
DeCORE AFCI-45DeTROPE CA-100 (50% soln)
DeTROPE SA-45
DePHOS H-66-872
SXS-40
No hydrotrope
DeCORE AFCI-45: multi-metal, amine-free corrosion inhibitor also an excellent hydrotrope
DeForest Enterprises, Inc.Water Soluble Corrosion InhibitorsCorrosion Testing- In Standard Hard Water
Blank 0.25%, 0.5% Blank 0.25% 0.5%• Bottom half of panels are submerged in solution containing corrosion inhibitor, top half of panels are in the vapor phase• Solution contains 0.25% to 1.0% by weight corrosion inhibitor in hard water (100ppm CaCO3 / 71ppm as chloride)
DeCORE IDMT-100100% Active Amine Carboxylate
110 Copper Alloy 90 Days RT
110 Copper Alloy 9 Months RT
DeForest Enterprises, Inc.Water Soluble Corrosion InhibitorsCorrosion Testing- In Standard Hard Water
Blank 0.25%, 0.5% Blank 0.25% 0.5%• Bottom half of panels are submerged in solution containing corrosion inhibitor, top half of panels are in the vapor phase• Solution contains 0.25% to 1.0% by weight corrosion inhibitor in hard water (100ppm CaCO3 / 71ppm as chloride)
260 Brass Alloy 90 Days RT
260 Brass Alloy 9 Months RT
DeCORE IDMT-100100% Active Amine Carboxylate
DeForest Enterprises, Inc.Water Soluble Corrosion InhibitorsCorrosion Testing- In Standard Hard Water
Blank, 0.25%, 0.5%
90 Days 9 Months
Blank, 0.25%, 0.5%
DeCORE IDMT-100100% Active Amine Carboxylate
DeForest Enterprises, Inc.Water Soluble Corrosion InhibitorsCorrosion Testing- In Standard Hard Water
Blank, 0.25%, 0.5%
90 Days 9 Months
Blank, 0.25%, 0.5%, 1%
DeCORE IDMT-100100% Active Amine Carboxylate
DeForest Enterprises, Inc.Water Soluble Corrosion InhibitorsCorrosion Testing- In Standard Hard Water
Blank, 0.25%, 0.5%
90 Days 9 Months
Blank, 0.25%, 0.5%, 1%
DeCORE IDMT-100100% Active Amine Carboxylate
DeForest Enterprises, Inc.Water Soluble Corrosion InhibitorsCorrosion Testing- In Standard Hard Water
0.5% DeCORE IMT-100LF, Steel Panels100% Active Amine-Carboxylate
30 Days in Standard Hard Water (71 ppm as chloride)
Blank Room Temp 50°C
DeForest Enterprises, Inc.Water Soluble Corrosion InhibitorsCorrosion Testing- In Standard Hard Water
Blank Room Temp
0.5% DeCORE IMT-100LF, Steel Panels100% Active Amine-Carboxylate
9 Months in Standard Hard Water @ RT (71 ppm as chloride)
DeForest Enterprises, Inc.Water Soluble Corrosion InhibitorsCorrosion Testing- In Higher Chlorides
Blank Room Temperature
0.5% DeCORE IMT-100LF, Steel Panels100% Active Amine-Carboxylate
30 Days in Higher Chlorides(200 ppm as CaCO3 & 142 ppm as chloride)
DeForest Enterprises, Inc.Water Soluble Corrosion InhibitorsCorrosion Testing- In Standard Hard Water
DeTROPE CA-100, 9 Month Results100% Active Amine- Carboxylate
Blank, 0.25%, 0.5%, 1%
2024 Bare Aluminum SAE 210 Cold Rolled Steel
Blank, 0.25%, 0.5%, 1%
DeForest Enterprises, Inc.DeTERIC LP Corrosion Inhibition PropertiesCorrosion Testing in Standard Hard Water
DeTERIC LP, Sodium Lauriminodipropionate
Hard Water: 100ppm CaCO3 / 71ppm as chlorideCold Rolled Steel, 72 hours
Blank 0.5% active
DeForest Enterprises, Inc.DeTERIC LP Corrosion Inhibition PropertiesCorrosion Testing in Standard Hard Water
DeTERIC LP, Sodium Lauriminodipropionate
Hard Water: 100ppm CaCO3 / 71ppm as chlorideBare Aluminum, 72 hours
Blank 0.5% active
DeForest Enterprises, Inc.DeTERIC LP Corrosion Inhibition PropertiesCorrosion Testing- In Acids
DeTERIC LP, Sodium Lauriminodipropionate
In 10% HCl (by weight)Cold Rolled Steel, 72 Hours
Blank 0.1% active
DeForest Enterprises, Inc.DeTERIC LP Corrosion Inhibition PropertiesCorrosion Testing- In Acids
Blank 0.1% active
72 hours 72 hours
Blank 0.1% active
In 10% Phosphoric Acid (by wt.)Cold Rolled Steel
In 10% Sulfuric Acid (by wt.)Cold Rolled Steel
DeTERIC LP, Sodium Lauriminodipropionate
DeForest Enterprises, Inc.DeTERIC LP Corrosion Inhibition PropertiesCorrosion Testing- In Acids
DeTERIC LP, Sodium LauriminodipropionateIn 10% HCl (by weight)
24 hours, Aluminum Panels
Blank 0.1% active
48 hours, Aluminum Panels
Blank 0.1% active
DeForest Enterprises, Inc.DeTERIC LP Corrosion Inhibition PropertiesCorrosion Testing- In Acids
DeTERIC LP, Sodium LauriminodipropionateIn 10% Sulfuric Acid (by weight)
24 hours, AluminumBlank 0.1% active
DeForest Enterprises, Inc.Thank You!
DeForest Enterprises, Inc.Amtec Center6421 Congress AvenueBoca Raton, FL 33487
561-994-9696561-994-9995 (fax)
Website: www.deforestenterprises.comSend inquiries to [email protected]