methods1 - iodp publications

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Proc. IODP | Volume 308 doi:10.2204/iodp.proc.308.102.2006 Flemings, P.B., Behrmann, J.H., John, C.M., and the Expedition 308 Scientists Proceedings of the Integrated Ocean Drilling Program, Volume 308 Introduction to Expedition 308 shipboard methods The “Methods” chapter is designed to document the primary pro- cedures and methods employed during Expedition 308 by the sci- entists in the various shipboard laboratories in order to under- stand the basis for our preliminary interpretations of the core and logging data. This information concerns only shipboard methods, the results of which are presented in the site reports in the “Expe- dition reports” section of the Expedition 308 Proceedings of the In- tegrated Ocean Drilling Program volume. Methods for shore-based analysis of Expedition 308 samples and data will be described in the individual scientific contributions to be published in scien- tific journals and the “Research results” section of the Expedition 308 Proceedings volume. Operations Two standard coring systems were used during Expedition 308: the advanced piston corer (APC) and the extended core barrel (XCB) systems. These standard coring systems and their charac- teristics are summarized in the “Explanatory Notes” chapters of previous Initial Reports volumes of the Ocean Drilling Program (ODP). The Leg 139 Initial Reports volume includes a particularly detailed description (Davis, Mottl, Fisher, et al., 1992), as does a variety of ODP Technical Notes (www-odp.tamu.edu/publi- cations/pubs_tn.htm). Additional measurement-while-drilling (MWD) and logging-while-drilling (LWD) tools deployed during Expedition 308 are described in detail in “Downhole measure- ments.” Drilled intervals are measured from the Kelly bushing on the rig floor to the bottom of the drill pipe and referred to in meters be- low rig floor (mbrf). Meters below seafloor (mbsf) references for the core tops are calculated by subtracting the seafloor depth. When sediments of substantial thickness cover the seafloor, the mbrf depth of the seafloor is determined with a mudline core, as- suming 100% recovery for the cored interval in the first partly filled core barrel. Water depth is calculated by subtracting the dis- tance from the rig floor to sea level from the mudline measure- ment in mbrf. This water depth usually differs from precision depth recorder measurements by a few to several meters. Methods 1 Expedition 308 Scientists 2 Chapter contents Introduction to Expedition 308 shipboard methods . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 Lithostratigraphy. . . . . . . . . . . . . . . . . . . . . . . . 2 Biostratigraphy . . . . . . . . . . . . . . . . . . . . . . . . . 5 Paleomagnetism . . . . . . . . . . . . . . . . . . . . . . . . 7 Geochemistry and microbiology. . . . . . . . . . . . 8 Physical properties . . . . . . . . . . . . . . . . . . . . . 10 Downhole measurements . . . . . . . . . . . . . . . . 13 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 Figures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24 Tables . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42 1 Expedition 308 Scientists, 2006. Methods. In Flemings, P.B., Behrmann, J.H., John, C.M., and the Expedition 308 Scientists, Proc. IODP, 308: College Station TX (Integrated Ocean Drilling Program Management International, Inc.). doi:10.2204/iodp.proc.308.102.2006 2 Expedition 308 Scientists’ addresses.

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Page 1: Methods1 - IODP Publications

Proc. IODP | Volume 308

Flemings, P.B., Behrmann, J.H., John, C.M., and the Expedition 308 ScientistsProceedings of the Integrated Ocean Drilling Program, Volume 308

Methods1

Expedition 308 Scientists2

Chapter contents

Introduction to Expedition 308 shipboard methods . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

Lithostratigraphy. . . . . . . . . . . . . . . . . . . . . . . . 2

Biostratigraphy . . . . . . . . . . . . . . . . . . . . . . . . . 5

Paleomagnetism . . . . . . . . . . . . . . . . . . . . . . . . 7

Geochemistry and microbiology. . . . . . . . . . . . 8

Physical properties . . . . . . . . . . . . . . . . . . . . . 10

Downhole measurements . . . . . . . . . . . . . . . . 13

References . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21

Figures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24

Tables. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42

1Expedition 308 Scientists, 2006. Methods. In Flemings, P.B., Behrmann, J.H., John, C.M., and the Expedition 308 Scientists, Proc. IODP, 308: College Station TX (Integrated Ocean Drilling Program Management International, Inc.). doi:10.2204/iodp.proc.308.102.20062Expedition 308 Scientists’ addresses.

Introduction to Expedition 308 shipboard methods

The “Methods” chapter is designed to document the primary pro-cedures and methods employed during Expedition 308 by the sci-entists in the various shipboard laboratories in order to under-stand the basis for our preliminary interpretations of the core andlogging data. This information concerns only shipboard methods,the results of which are presented in the site reports in the “Expe-dition reports” section of the Expedition 308 Proceedings of the In-tegrated Ocean Drilling Program volume. Methods for shore-basedanalysis of Expedition 308 samples and data will be described inthe individual scientific contributions to be published in scien-tific journals and the “Research results” section of the Expedition308 Proceedings volume.

OperationsTwo standard coring systems were used during Expedition 308:the advanced piston corer (APC) and the extended core barrel(XCB) systems. These standard coring systems and their charac-teristics are summarized in the “Explanatory Notes” chapters ofprevious Initial Reports volumes of the Ocean Drilling Program(ODP). The Leg 139 Initial Reports volume includes a particularlydetailed description (Davis, Mottl, Fisher, et al., 1992), as doesa variety of ODP Technical Notes (www-odp.tamu.edu/publi-cations/pubs_tn.htm). Additional measurement-while-drilling(MWD) and logging-while-drilling (LWD) tools deployed duringExpedition 308 are described in detail in “Downhole measure-ments.”

Drilled intervals are measured from the Kelly bushing on the rigfloor to the bottom of the drill pipe and referred to in meters be-low rig floor (mbrf). Meters below seafloor (mbsf) references forthe core tops are calculated by subtracting the seafloor depth.When sediments of substantial thickness cover the seafloor, thembrf depth of the seafloor is determined with a mudline core, as-suming 100% recovery for the cored interval in the first partlyfilled core barrel. Water depth is calculated by subtracting the dis-tance from the rig floor to sea level from the mudline measure-ment in mbrf. This water depth usually differs from precisiondepth recorder measurements by a few to several meters.

doi:10.2204/iodp.proc.308.102.2006

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Core handling and shipboard analysisAs soon as cores arrived on deck, gas void samplesand headspace samples were taken by means of a sy-ringe, if applicable, for immediate analysis as part ofthe shipboard safety and pollution prevention pro-gram. Core catcher samples were taken for biostrati-graphic analysis. When the core was cut in sections,whole-round samples were taken for shipboard inter-stitial water examinations and microbiology analysis(both shipboard and shore based).

Before splitting, whole-round core sections not dedi-cated to microbiology were run through the multi-sensor track (MST), and thermal conductivity mea-surements were taken. Whole-round samplesdedicated to geotechnical analysis were then taken.Finally, the cores were split into working and archivehalves, from bottom to top, so investigators shouldbe aware that older material could have been trans-ported upward on the split face of each section. Theworking half of each core was sampled for both ship-board analyses, such as physical properties, carbon-ate, and X-ray diffraction (XRD) mineralogy, andshore-based studies. The archive halves were photo-graphed with both black-and-white and color film,scanned with the digital imaging system (DIS), de-scribed visually and by means of smear slides, mea-sured for color reflectance on the archive-half multi-sensor track (AMST), and run through the cryogenicmagnetometer. Close-up photographs were taken ofparticular features for illustrations in site summaryreports, as requested by scientists.

Both halves of the core were then put into labeledplastic tubes, sealed, and transferred to cold storagespace aboard the ship. At the end of the expedition,the cores were transferred from the ship to cold stor-age at the Integrated Ocean Drilling Program (IODP)Gulf Coast Core Repository at Texas A&M Universityin College Station, Texas.

Curatorial procedures and sample depth calculations

Numbering of sites, holes, cores, and samples followsthe standard IODP procedure. A full curatorial iden-tifier for a sample consists of the expedition, site,hole, core number, core type, section number, andinterval in centimeters measured from the top of thecore section. For example, a sample identification of308-U1319A-1H-1, 10–12 cm, represents a sample re-moved from the interval between 10 and 12 cm be-low the top of Section 1, Core 1 of Hole U1319A dur-ing Expedition 308 (H designates that this core wastaken with the APC system [X = XCB]). Cored inter-vals are also referred to in “curatorial” mbsf. Thembsf depth of a sample is calculated by adding the

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depth of the sample below the section top and thelengths of all higher sections in the core to the core-top datum measured with the drill string.

A sediment core from less than a few hundred mbsfmay, in some cases, expand upon recovery (typically10% in the upper 300 m), in which case its lengthwill not match the drilled interval. In addition, acoring gap typically occurs between cores, as shownby composite depth construction (see the “Explana-tory Notes” chapters for Legs 138, 177, and 184[Shipboard Scientific Party, 1992, 1999, 2000]). Thus,a discrepancy may exist between the drilling mbsfand the curatorial mbsf. For instance, the curatorialdepth (mbsf) of a sample taken from the bottom of acore may be larger than that of a sample from thetop of the subsequent core. During Expedition 308,multiple APC/XCB holes were cored but continuouscomposite sections were not constructed.

If a core has incomplete recovery, all cored materialis assumed to originate from the top of the drilled in-terval as a continuous section for curation purposes.The true depth interval within the cored interval isnot known, resulting in an uncertainty, for instance,in age-depth analysis and correlation of core facieswith downhole log signals.

LithostratigraphyThe techniques and procedures used to describe, an-alyze, and name the lithologies recovered during Ex-pedition 308 are detailed below and follow ODPTechnical Note 8 (Mazzullo and Graham, 1988). Theseinclude visual core descriptions (VCDs), smear slideand thin section descriptions, XRD analyses, colorspectrophotometry, and high-resolution digital colorimaging. Any significant deviations from the proce-dures outlined in this section are discussed in the in-dividual site chapters.

Sediment classificationPrincipal names were assigned to sediments based oncomposition, texture, and degree of lithification asdetermined primarily from visual description andsmear slide analyses. Modifiers to the principal namewere determined based on both the abundance andtype of the nonprincipal component or components(e.g., siliciclastic or biogenic). Total inorganic carboncontent, including calcium carbonate, of the sedi-ments (see “Solid-phase chemistry” in “Geochemis-try and microbiology” in the “Site U1319,” “SiteU1320,” “Site U1322,” and “Site U1324” chapters)was also used to aid in classifying sediments. Majormodifiers, those components that form >25% of thesediment, precede the principal name and are listedin order of increasing abundance. Genetic terms,

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such as “pelagic,” “neritic,” “turbidite,” and “debrisflow,” were not used in classifying the sediments andare used only in geologic interpretations of the sedi-mentary unit. The conventions used here were ap-plied only to granular sediments. Chemical sedi-ments were only encountered as accessory mineralsand nodules.

Siliciclastic sedimentsFor sediments and rocks composed of >60% silici-clastic components, the principal name was deter-mined by the size of the grains, derived from the Ud-den-Wentworth grain-size scale (Wentworth, 1922)(Fig. F1). In this classification scheme, the term“clay” is independent of mineralogy and refers to allsiliciclastic grains <3.9 µm in size. The relative pro-portion of different grain sizes was determined by vi-sual percentage estimation using a standard compar-ison chart with half-φ unit intervals (e.g., Terry andChilingar, 1955). Where possible in sand beds, themodifiers “upper” and “lower” are used to describewhether the sediment is predominantly in the upperhalf or lower half of an individual φ-size class (e.g.,medium upper sand for grains with a typical size be-tween 1.5φ and 1φ). For silt and clays, the grain sizewas estimated using smear slides. Once the relativeproportion of the various grain sizes was estimated, amodified Shepard (1954) classification scheme wasused to modify, if necessary, the principal name us-ing the ternary diagram in Figure F2. Clay, silt, andsand are the principal names in the diagram. If eitherthe silt or sand component exceeds 25% of the totalsiliciclastic grains, it becomes a modifier to the prin-cipal name. For example, sediment composed of10% clay and 90% silt is simply silt, whereas sedi-ment composed of 30% silt and 70% sand is siltysand. Where the proportions of silt and clay weredifficult to quantify, the term “mud” was used forsediment containing mixtures of clay and silt.

Where diagnostic minerals (e.g., glauconite), bio-genic sediments (e.g., foraminifers), or unusual com-ponents (e.g., volcanic glass) compose ≥5% of thesediment, the naming conventions of biogenic andmixed sediments were adopted. Thus, if the mineralcomponent represents between 5% and 10% of thesediment, it is hyphenated with the suffix “-bearing”and precedes the major siliciclastic componentname. If the component is 10%–40% of the sedi-ment, it is hyphenated with the suffix “-rich” in-stead. For example, sediment composed of 15%sand-sized foraminifer tests, 30% silt, and 55% clayis called a foraminifer-rich silty clay. Where volcanicglass composed >40% of the sedimentary compo-nents, the name volcanic ash was used.

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Biogenic sedimentsUnlike siliciclastic sediments, biogenic sediments,defined as containing >60% biogenic components,are not described based on grain size. Rather, theprincipal name for all biogenic sediments is ooze. Ifthe siliciclastic component represents 5%–40% of asediment, the naming conventions using “-rich” and“-bearing” as described for mixed sediments beloware used. Thus, a sediment composed of 30% silici-clastic clay and 70% sand-sized foraminifers is calleda clay-rich foraminifer ooze, not a clay-rich foramin-ifer sand.

Mixed sedimentsMixtures of biogenic and nonbiogenic material,where the biogenic content is 40%–60%, are termed“mixed sediments” (Mazzullo and Graham, 1988).The name of a mixed sediment consists of a majormodifier(s) consisting of the name(s) of the majorfossil group(s), with the least common fossil listedfirst, followed by the principal name appropriate forthe siliciclastic components (e.g., foraminifer clay).The same naming conventions for using “-bearing”and “-rich” apply to mixed sediments as describedabove. Sediment containing 5% foraminifers, 40%nannofossils, and 55% silt is, thus, called foramini-fer-bearing nannofossil silt. Sediment containing 5%diatoms, 40% clay, and 55% nannofossils is calleddiatom-bearing nannofossil clay.

Visual core descriptionsDetailed sedimentologic observations and descrip-tions were recorded manually for each core sectionon paper (barrel sheets). A variety of features thatcharacterize the sediments were recorded, includinglithology, sedimentary structures, color, diageneticprecipitates, and core disturbance. Compositionaldata were obtained from smear slides. The color ofthe sediments was determined first by visual obser-vation at the description table and then quantita-tively by color spectrophotometry using the AMST.This information was then transcribed into VCDforms using AppleCORE software (version 9.4a),which generated a one-page graphical description ofeach core. An example of such a VCD from Expedi-tion 308 is shown in Figure F3. The legend for thesymbols used for lithology, sedimentary structures,and other features seen in Expedition 308 cores areexplained in Figure F4. The VCD forms are availabledigitally in the core descriptions, and the scannedbarrel sheets are available upon request.

Lithology and grain sizeLithology and grain size of the described sedimentsare represented graphically in a column on the VCD

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using the symbols illustrated in Figure F4. A maxi-mum of three different lithologies (for interbeddedsediments) or three different components (for mixedsediments) can be represented within the same coreinterval using AppleCORE software. Intervals thatare a few centimeters thick or thicker can be por-trayed accurately in the Lithology column. Percent-ages are rounded to the nearest 10%, and lithologiesthat constitute <10% of the core are generally notshown but are listed in the Description column.

Sedimentary structuresEach type of sedimentary structure and its exact lo-cation are displayed in the Structure column of theVCD (Fig. F3). Symbols used for sedimentary struc-tures encountered throughout Expedition 308 arelisted in Figure F4. Some of the more common struc-tures and accessories observed were parallel lamina-tions, climbing ripples, graded bedding, mud clasts,contorted beds, wood fragments, plant debris, andmottling.

FossilsThe presence of macroscopic fossils such as shellfragments and preserved whole shells were identifiedwhenever possible and displayed in a separate col-umn on the barrel sheet.

Sediment disturbanceDrilling-related sediment disturbance is recorded inthe Disturbance column on the VCD (Fig. F3). Sepa-rate terms are used to describe the degree of drillingdisturbance:

• Slightly disturbed = bedding contacts are slightly deformed.

• Moderately disturbed = bedding contacts have undergone extreme bowing.

• Highly disturbed = bedding is completely deformed as flow-in, coring/drilling slough, and other soft-sediment stretching and/or compres-sional shearing structures attributed to coring/drilling (e.g., gas expansion).

• Soupy = intervals are water saturated and have lost all primary sedimentary structures.

• Drilling biscuits = drilling slurry surrounding an intact or slightly fractured drilling biscuit, usually associated with XCB coring.

Cores recovered from gas-bearing sediments are of-ten disturbed by gas expansion and fracturing asthey are brought to surface conditions. In caseswhere it is possible to distinguish between distur-bance of the core resulting from drilling and distur-bance resulting from gas expansion, notes were

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made in the Comments section of the barrel sheetlisting the depths at which gas fracturing was ob-served.

SamplesThe locations of samples are indicated in the Samplecolumn on the VCD. The abbreviations used are asfollows:

SmS = smear slide.IW = interstitial water.MBI/BIO = microbiology.PAL = micropaleontology.WHC = whole-round core.

Smear slide analysesSmear slides were prepared from the archive halvesof the cores. With a toothpick, a small amount ofsediment was taken and put on a 2.5 cm × 7.5 cmglass slide, homogenized, and dispersed over theslide with a drop of deionized water. The sample wasthen dried on a hot plate at a low temperature. Adrop of Norland optical adhesive and a 2.5 cm × 2.5cm cover glass were added. The smear slide was fixedin an ultraviolet light box. With a transmitted-lightpetrographic microscope, both the grain size andabundance of dominant components in a samplewere determined. Abundance was estimated with thehelp of a comparison chart for visual percentage esti-mation (after Terry and Chilingar, 1955). Note thatsmear slide analyses tend to underestimate theamount of sand-sized and larger grains because thesegrains are difficult to incorporate into the slide. Thesmear slide results are available from the IODP data-base, and the tables include information about thelocation of samples, their grain-size distribution, andwhether the sample represents the dominant or theminor lithology in the core. Additionally, it providesestimates of the major mineralogical and biologicalcomponents from the examination of each smearslide. The presence of authigenic minerals, such asmanganese oxides, iron sulfides, or carbonates, aswell as the presence of rare trace minerals, was notedin the Comments column. The mineralogy of themajor smear slide components was also validated byXRD analysis, and the relative proportion of carbon-ate and noncarbonate material was validated bychemical analysis of the sediments (see “Solid-phasechemistry” in “Geochemistry and microbiology” inthe “Site U1319,” “Site U1320,” “Site U1322,” and“Site U1324” chapters).

X-ray diffraction analysesXRD analyses were used to support and verify smearslide descriptions. Each sample was freeze-dried,

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ground, and mounted with a random orientationinto an aluminum sample holder. For these measure-ments, a Philips PW-1729 X-ray diffractometer witha CuKα source (40 kV and 35 mA) and a Ni filter wasused. Peak intensities were converted to values ap-propriate for a fixed slit width. The goniometer scanwas performed from 2°2θ to 70°2θ at a scan rate of1.2°/min (step = 0.01° and count time = 0.5 s). Dif-fractograms were peak-corrected to match the (100)quartz peak at 4.26 Å. Common minerals were iden-tified based on their peak position and relative inten-sities in the diffractogram using the software packageMacDiff (version 4.2.5; www.pangaea.de/Software).

Color reflectance spectrophotometryIn addition to visual estimates of color, reflectance ofvisible light from soft sediment was measured usinga Minolta spectrophotometer (model CM-2002)mounted on the AMST. The AMST measures the ar-chive half of each core section and provides pointmeasurements of downcore color variations for thevisible wavelengths (400–700 nm). Freshly split coreswere covered with clear plastic wrap and placed onthe AMST. The AMST skips empty intervals and in-tervals where the core surface is well below the levelof the core liner but does not recognize relativelysmall cracks or disturbed areas of core. Thus, AMSTdata may contain spurious measurements thatshould be edited out of the data set before use. Eachmeasurement consists of 31 separate determinationsof reflectance in 10 nm wide spectral bands from 400to 700 nm. Additional detailed information aboutthe measurement and interpretation of spectral datawith the Minolta spectrophotometer can be found inBalsam et al. (1997, 1998) and Balsam and Damuth(2000). The AMST was also used to acquire pointmagnetic susceptibility measurements (see “Paleo-magnetism”). Color reflectance and magnetic sus-ceptibility measurements were useful to distinguishturbidites and hemipelagic sediments.

Digital color imagingAll core sections were imaged using the Geotek X-YDIS soon after being split and scraped. Scraping thecores immediately prior to imaging helped captureephemeral sedimentary features, particularly faintcolor banding and laminations, which often becomeoxidized within minutes of core splitting. Core sec-tions were routinely loaded into each imaging trayof the DIS as soon as the previous sections were im-aged so that the imaging system ran continuouslyduring section loading and unloading. Digital im-ages were displayed after scanning to ensure theywere stored.

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All images were acquired at a crosscore and down-core resolution of 100 pixels/cm. At the beginning ofExpedition 308, the acquisition aperture was variedin an attempt to maximize the dynamic range cap-tured. The barcode label and the polystyrene inserts(e.g., for voids and whole-round samples) wereplaced at the end of each section. Output from theDIS includes an uncompressed TIFF file (availableupon request) and a compressed Mr.Sid (.sid) file(available in the Janus database) for each scannedsection. Red-green-blue (RGB) profiles for all imageswere also automatically saved (available upon re-quest) but were generally not used on board. Addi-tional postprocessing of the color imagery was doneto achieve a “medium”-resolution JPEG (.jpg) imageof each section and a composite PDF (.pdf) image ofeach core.

In addition to the DIS scanning of the core sections,whole-core photographs were acquired with a large-format color camera. The photographs took place be-tween 30 and 60 min after the core was scraped.Consequently, some of the sedimentary details maybe lost using the more conventional archive-core ta-ble photographs. For this reason, cores were scrapedbefore close-up digital photographs were taken.

BiostratigraphyDuring Expedition 308, calcareous nannofossils andforaminifers were examined for age dating of sam-ples taken primarily from core catchers. Chronobios-tratigraphy was mainly based on the zonationscheme of Berggren et al. (1995) (Fig. F5). As mostdrilling activities were on late Quaternary sequences,local species datums and zonations based on speciesabundance such as those of Kennett and Huddlestun(1972) were also used. Ages for assemblage zonalboundaries were adjusted to marine isotope stages(MIS) given in Bassinot et al. (1994).

Calcareous nannofossilsZonation and taxonomic conceptWe have referred primarily to the zonation and codeof Hine and Weaver (1998) (Fig. F6) for dating thecored sediments. We followed taxonomic conceptssummarized in Perch-Nielsen (1985).

MethodsStandard smear slides were prepared for all samplesusing Norland optical adhesive as a mounting me-dium.

Assemblages of calcareous nannofossils were studiedfrom smear slides prepared for each core catcher

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sample and a few samples from selected cores. In thelatter case, hemipelagic and pelagic beds were sam-pled in order to avoid effects of resedimentation re-sulting from turbidites and mass transport deposits(MTDs), and special attention was given to lithologicchanges. Examination was done exclusively with atransmitted light microscope, and a magnification of1000× was used to estimate relative abundances.

We used Bugwin (version 2002.3.8) software for col-lecting and analyzing nannofossil data. BugCamsoftware, specifically designed by the University ofFlorida, was used for taxa identification. All specieswere counted within 10 fields of view. Abundance ofindividual species is reported on the basis of 100fields of view. On collecting data the species distribu-tion charts were created and analyzed.

Individual species abundances were determined asfollows:

Rare = 1–3 specimens/100 fields of view (FOV).Sparse = 4–10 specimens/100 FOV.Frequent = 11–25 specimens/100 FOV.Frequent–common = 26–100 specimens/100 FOV.Common = 101–500 specimens/100 FOV.Abundant = 501–1000 specimens/100 FOV.Very abundant = 1001–10,000 specimens/100 FOV.Ooze = >10,000 specimens/100 FOV.

The total abundance of calcareous nannofossils foreach sample was estimated as follows:

B = barren.R = rare (<100 specimens/100 FOV [half of a

traverse]).F = frequent (100–500 specimens/100 FOV).C = common (501–1000 specimens/100 FOV).A = abundant (1001–10,000 specimens/100 FOV).W = very abundant (>10,000 specimens/100 FOV).

The preservation of calcareous nannofossils was clas-sified as good, moderate, or poor. These categoriesrepresent subjective impressions with the followingdefinitions:

P = poor (strong and severe dissolution, over-growth, and/or fragmentation has occurred;primary diagnostic features may have beendestroyed, impossible to identify many spec-imens at the species level).

M = moderate (dissolution and/or overgrowth areevident; a significant proportion [as much as25%] of the specimens cannot be confidentlyidentified at the species level with absolutecertainty).

G = good (evidence of dissolution and/or over-growth is very little; diagnostic characteris-tics are preserved nearly in all nannofossils;~95% of all specimens or more can be identi-fied).

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ForaminifersMethodsSamples of ~40 cm3 were soaked in a Calgon solutionand washed through a 63 µm sieve. Samples wererinsed and then dried under a heat lamp or in anoven at 60°C.

Preservation characteristics were divided into fourcategories:

P = poor (almost all specimens were dissolved orbroken and fragments dominated).

M = moderate (30%–60% of specimens showeddissolved or broken chambers).

G = good (61%–90% of specimens were well pre-served and unbroken).

VG = very good (>90% of specimens were wellpreserved and unbroken).

Planktonic foraminifers

The >125 µm size fraction was examined for plank-tonic foraminifers and the 63–125 µm size fractionwas studied for zonal markers if these were absent inthe larger size fractions.

The abundance of planktonic foraminifers is definedas follows:

B = barren.T = trace (1 or 2 specimens).VR = very rare (3–10 specimens).R = rare (11–30 specimens).F = frequent (31–100 specimens).C = common (101–500 specimens).A = abundant (>500 specimens).

We mainly referred to Bolli and Saunders (1985) forplanktonic foraminifer taxonomy. The zonal schemeand species datum levels of Berggren et al. (1995)were used for dating major stratigraphic boundaries(Fig. F5). The planktonic foraminifer assemblagezones based on Globorotalia menardii for subdividingthe late Quaternary in the Gulf of Mexico region(Kennett and Huddlestun, 1972; Martin et al., 1990)(Fig. F7) were also attempted when time allowed.Ages for these assemblage zone boundaries weremodified according to the timescale of Bassinot et al.(1994).

Benthic foraminifers

Benthic foraminifer relative abundance was definedas follows:

B = barren.R = rare (<1% of the fauna).F = frequent (1%–5% of the fauna).C = common (6%–20% of the fauna).A = abundant (>20% of the fauna).

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Benthic foraminifers were examined from the >63µm size fraction. Paleobathymetry estimates wereprimarily based on Poag (1981) and van Morkhovenet al. (1986). Bathymetric zones were defined as fol-lows:

Neritic = 0–200 m. Upper bathyal = 200–600 m. Middle bathyal = 600–1000 m. Lower bathyal = 1000–2000 m. Abyssal = >2000 m.

PaleomagnetismMagnetic measurements

Paleomagnetic and rock magnetic measurementsduring Expedition 308 included natural remanentmagnetization (NRM) and volume magnetic suscep-tibility (κ), both performed on continuous archive-half core sections.

NRM was measured on board at 5 cm intervals usingan automated pass-through cryogenic direct-current(DC) superconducting quantum interference device(SQUID) rock magnetometer (2G Enterprises model760-R) with an in-line alternating-field (AF) demag-netizer (model 2G600). The archive-half sectionswere demagnetized in 0, 10, 20, and, in some cases,30 mT AF field increments (for details see “Paleo-magnetism” in the site chapters). The pass-throughcryogenic magnetometer and AF demagnetizer arecontrolled by 2G LongCore Labview software (ver-sion 207.3) (Shipboard Scientific Party, 2004).

NRM intensity, declination, direction, and inclina-tion were measured. For the latter two parameters, acore orientation correction was applied using thedigital multishot tool (Tensor, Inc.), which is rigidlymounted onto a nonmagnetic sinker bar during APCcoring. The Tensor tool consists of three mutuallyperpendicular magnetic field sensors and two per-pendicular gravity sensors. The information fromboth sets of sensors allows the azimuth and dip ofthe hole to be measured as well as the azimuth of theAPC core double orientation line. The IODP core ori-entation scheme designates the positive x-axis direc-tion as the horizontal (in situ) line radiating fromthe center of the core through the space between thedouble line scribed lengthwise on the working halfof each core liner.

Volume magnetic susceptibility measurements werecarried out at 1–6 cm resolution on whole-core sec-tions as part of the MST analyses (see “Physicalproperties”). On the archive-half sections, the AMSTanalyzed color reflectance at 10 cm resolution (see“Lithostratigraphy”) and additional point magneticsusceptibility at 5–10 cm resolution using a Barting-

Proc. IODP | Volume 308

ton MS2F sensor at a sensitivity setting of 0.1 instru-ment units. The instrument automatically zeroesand records a free-air value for the magnetic suscep-tibility at the start and end of each section run. In-strument drift during a section run is then correctedby subtraction of a linear interpolation between thefirst and last free-air measurements (Shipboard Scien-tific Party, 2003).

MagnetostratigraphyClassical magnetostratigraphy using field reversalcorrelations (e.g., Cande and Kent, 1992) could notbe used to establish an age model because the Brun-hes/Matuyama Chron boundary was not recovereddue to high sedimentation rates.

Instead, we used high-resolution variations of theEarth’s magnetic field such as changes in declinationand inclination. High-resolution rock magneticrecords such as NRM intensity and magnetic suscep-tibility were potentially helpful tools for multi-parameter correlations. Such rock magnetic recordsare capable of exhibiting Milankovitch cyclicities,sometimes in close agreement with δ18O profiles.This correlation is generally explained by climaticimpact on fluxes of magnetically enriched terrige-nous and nonmagnetic biogenic or siliciclastic sedi-mentary components. Paleoclimatic signatures ofmagnetic susceptibility and various remanence pa-rameters (such as NRM) are increasingly employedfor high-resolution core correlation and have beendescribed and used as stratigraphic correlation toolsin paleoceanographic studies from all major oceans(e.g., Radhakrishnamurty et al., 1968; Kent, 1982;Robinson, 1986; Bloemendahl et al., 1988; deMeno-cal et al., 1991; Bickert et al., 1997; von Dobeneckand Schmieder, 1999). Frederichs et al. (1999) out-lined the physical and sedimentological principles ofrock magnetic climate proxies.

For marine sediments, κ may vary from an absoluteminimum of –15 × 10–6 SI (diamagnetic mineralssuch as pure carbonates or silicates) to a maximumof ~10.000 × 10–6 SI for basaltic debris rich in (ti-tano)magnetite. In most cases, κ is primarily deter-mined by the concentration of ferrimagnetic miner-als, whereas paramagnetic components such as claysare of minor importance. Enhanced susceptibiltiesindicate higher concentrations of lithogenic or au-thigenic ferrimagnetic components. This relationmay serve for correlating sedimentary sequences de-posited under similar global or regional conditions.

NRM intensity and κ were further compared with thesediment bulk density to perform multiparametercorrelation of the rock magnetic shipboard data. Us-ing these multiple logs is suitable to establish a re-

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gional stratigraphic correlation and tentatively de-rive preliminary age estimates. Correlations areattempted by comparing the individual peaks andtroughs of the records and constraining the tiepoints. These magnetostratigraphic tie points (re-ferred to as “MTP”) were then, if possible, correlatedto the δ18O record published by Bassinot et al. (1994).This provided the basis to establish a rough initialchronology and detect Milankovitch cyclicity.

Geochemistry and microbiologyInorganic geochemistry

Whole-round pore water sample collectionShipboard analyses were performed on interstitialwaters extracted from 5 cm long whole-roundsediment samples. Samples were collected every 1.5m to the estimated base of the sulfate reduction zoneat 50 mbsf. Below 50 mbsf, whole rounds werecollected every 10 m to terminal depth (TD). Thehigher sampling frequency above 50 mbsf provided abetter definition of the sulfate/methane interface(SMI). The whole-round sections were cut from thecore immediately after recovery on deck. Thesurfaces of the samples were scraped with a polytet-rafluoroethylene (PTFE)-coated spatula to removesediment potentially contaminated with drillingfluids. Interstitial water was extracted by applying upto 40,000 lb of pressure in a titanium squeezer. Thepore water samples were collected directly into a 60mL plastic syringe, and sample splits were filteredthrough a 0.45 µm filter. The pore water volumeextracted was ~40 mL. Whole-round intervals wereincreased to 10 cm long when pore water recoverywas not sufficient to provide the volume required foranalysis. Sample splits were sealed in plastic vials forshipboard analysis, IODP archives, and for shore-based elemental and isotopic analysis.

Rhyzon sample collectionHigh-resolution pore water sampling was conductedon the upper 15 m of selected holes using soilmoisture probes called Rhyzon samplers. Rhyzonsamplers enable discrete sampling with minimaldisturbance to the sediment surface. The methoddoes not require filtering or removal of wet sedimentfrom the piston core. Rhyzon samplers used duringExpedition 308 were 2.5 mm wide × 30 mm longfilters with a pore size of 1 µM. The use of Rhyzonsamplers to extract pore waters from marinesediments is potentially a powerful and novelalternative to the technique of squeezing whole-round sediments.

Samplers were inserted into the sediment at ~10 cmintervals. Pore water was withdrawn under vacuum

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into acid-washed 60 mL syringes or He-purged head-space vials. Whole-round cores were sampled priorto splitting for sedimentological description. Ship-board samples were stored in plastic vials in a refrig-erator prior to analysis. Sediment samples were alsocollected for physical property testing including per-meability and porosity. MST scans (see “Physicalproperties”) were run before and after sampling toassess potential alteration of sediment properties (see“Rhyzon” in “Supplementary material”).

Shipboard analysesInterstitial water samples were analyzed for routineshipboard measurements according to standardprocedures and calibrated against International Asso-ciation of the Physical Sciences of the Oceans(IAPSO) standards (Gieskes et al., 1991). Alkalinityand pH were determined immediately followingsample collection using the Metrohm autotitratorwith a Brinkman combination pH electrode. Theelectrode was calibrated before the analyses and waschecked periodically for drift. Salinity was estimatedusing an Index Instruments digital refractometer tomeasure the total dissolved solids. Chlorinity wasdetermined by titration with silver nitrate.Concentrations of anions (SO4

2– and Cl–) and cations(Ca2+, Mg2+, K+, and Na+) were determined induplicate using a Dionex ion chromatograph. Allsamples were run at 1:200 dilution. Standards weremeasured at the start and end of each run to test fordrift in the response of the conductivity detector.Precision on separate dilutions was better than 2%.Concentrations of NH4

+ and PO43– were determined

using a Milton Roy spectrophotometer. Minorelement concentrations (Fe2+, Mn2+, Li+, B3+, Si2+, Sr2+,and Ba2+) were analyzed using a JY2000 inductivelycoupled plasma–atomic emission spectrometer (ICP-AES) run at 1:10 dilution. Dissolved inorganic car-bon (DIC) content was determined by coulometry.

Total inorganic carbon (TIC) content of the sedimentwas determined by coulometry. Total carbon (TC),nitrogen, and hydrogen sediment concentrationswere determined with a Carlo Erba NCS analyzer.Total organic carbon (TOC) content was calculatedas the difference between TC and TIC, where

TOC = TC – TIC.

Total sulfur analyses were inaccurate and of poorprecision. These results were considered qualitativeand are not reported.

Sample collection for shore-based analysesPore water splits were collected from whole-roundinterstitial water samples for shore-based elemental(minor and trace metal constituents) and isotopic

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(δ13C, δ15N, δ18O, δD, δ34S, δ11B, and 87Sr/86Sr) analyses.Samples for elemental analysis were acidified withultrapure HNO3, whereas samples for isotopicanalysis were preserved with mercuric chloride orzinc acetate, with exception of water samplescollected for hydrogen and oxygen isotopic analysis.Pore waters were stored in cryogenic vials.Nontreated interstitial water aliquots were preparedfor isotopic analysis of oxygen, hydrogen, DIC,carbon, boron, and strontium immediately afterarrival in a shore-based laboratory.

Sedimentary pyrite was sampled for δ34S analysiswhen collected in sufficient quantities. Sedimentswere collected from squeezed whole rounds for ICP-mass spectrometry (MS) analysis of major (Na, Mg,K, Ca, Ti, Mn, Fe, Al, Si, and P) and trace (Sr, Ba, Y, Zr,Co, Ni, Sc, and Rb) elements.

Organic geochemistrySediment hydrocarbon accumulations were quanti-fied by headspace gas analysis (Pimmel andClaypool, 2001). A 5 cm3 sediment headspace samplewas collected every 10 m, heated, and the evolvedgases were analyzed on gas chromatographs (GCs)dedicated to gas monitoring. Compositions of gasesin sediment were determined at least once per core.Headspace gases were analyzed on either a HewlettPackard 5890 Series II GC or a Hewlett-Packard5890A natural gas analyzer (NGA). The first systemdetermines concentrations of C1 through C3

hydrocarbons with a flame ionization detector (FID).A broader suite of hydrocarbon concentrations,ranging from C1 to C7, was detected with an FID and,concentrations of N2, O2, CO2, Ar, and He were mea-sured with a thermal conductivity detector (TCD) inthe NGA. Chromatographic response on both GC in-struments was calibrated against six different gasstandards with variable quantities of low molecularweight hydrocarbons, N2, O2, CO2, Ar, and He.Representative expansion void gases (EVGs) werecollected directly through the core liner with an EVGsampler to prevent contact with ambient air. Gasconcentrations were quantified, without the heatingstep, using the headspace GC method describedabove. Sediment samples were collected for land-based analysis of amino acid chirality, adenosinetriphosphate (ATP), and acid and alkalinephosphatases (enzymatic activity).

MicrobiologyMost subseafloor environments (deeper than 10 cm)are now recognized as very silent and low-activitybiospheres based on recent advancements ofsubsurface microbiology (Whitman et al., 1998;

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D’Hondt et al., 2004; DeLong, 2004). However, theenvironments where energy sources for microbes areprovided by geohydrological flow or sedimentationof organic matter are candidates for active oractivated microbial processes. In the Gulf of Mexico,high sedimentation rates have been observed andstrong geohydrological activity was expected. Thissituation suggests the possible presence of an activeshallow subseafloor biosphere dependent on organiccarbon as well as microbial communities in the deepsubseafloor, activated by geohydrological flow.

Contamination testingIt is important to assess potential seawater contami-nation of sediments sampled for microbial analysis.Sediment microbial biomass decreases with depthand is in low abundance relative to the microbialbiomass found in seawater. The fluorescent micro-particle tracer method, as described in ODP TechnicalNote 28 (Smith et al., 2000), was applied during theexpedition to quantify the extent of contaminationproduced during the coring process.

Latex fluorescent microspheres (Fluoresbritecarboxylate microspheres, 0.5 µm YG) were used as aparticulate tracer. A 2 mL stock solution ofmicrospheres was diluted with 40 mL of distilledwater and sealed into a plastic bag. The bag wasattached to the inside of the core catcher. The bagburst on impact into the sediments, andmicrospheres mixed with seawater and coated thecore surface. During processing of whole-roundcores, sediments from outer and inner layers weresampled by syringe for microscopic examination.The weighed samples were suspended in saturatedNaCl solution to extract microspheres. The mixturewas centrifuged at 1000 rpm for 5 min (Minispin,Eppendorf), and the supernatant was filtered ontoblack polycarbonate filters (Millipore; 0.2 µm).Fluorescent microsphere analysis was conductedwith a Zeiss Axioplan fluorescence microscopeequipped with the Zeiss number 9 filter set (BP 450–490; LP 520). The number of spheres observed wasused to quantify contamination in spheres per gramof sample.

Core collection and samplingIn order to avoid contact with oxygen and monitorcontamination, samples for microbiology weresampled immediately on the catwalk and broughtinto a glove box following subsampling forcontamination testing. In the glove box, 2–3 cm3

and 20–30 cm3 of sediment were collected with asyringe for cultivation and tracer incubationanalyses, respectively. Samples for cultivation

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analysis were suspended in 20 mL of sterilizedseawater, with and without Na2S in glass vials, andsediment designated for tracer analysis was packedin anaerobic bags and stored at –80°C. Thecultivation slurries were pressurized with nitrogengas at 1.5 atm and stored at 5°C. An additional 1 cm3

of sediment was extracted for microscopicobservation (acridine orange direct counts [AODC]and fluorescence in situ hybridization [FISH], etc.)using a syringe. After these subsampling routines,the sediments for culture-independent molecularanalyses based on deoxyribonucleic acid (DNA) (16Sribosomal ribonucleic acid [rRNA] gene cloneanalysis, quantitative polymerase chain reaction[PCR], etc.) were taken by spatula and stored in 50mL plastic tubes at –80°C.

Microscopic observation (biomass count)The sediments (1 cm3) were sampled by syringe fromwhole-round core samples and suspended in 9 mL ofsterilized seawater containing 3.7% neutralizedformaldehyde. A 1 mL aliquot of the sedimentsuspension was stained with acridine orange. Afterstaining for 1 h at 4°C, the sediment suspension wascentrifuged for 5 s at 2000 × g and the supernatantwas filtered through a 0.2 µm Isopore membranefilter (Millipore). The cells on the filters werecounted under fluorescent light using a microscope.At least 50 microscopic fields for each sample wereexamined to determine the direct cell counts.

Physical propertiesShipboard measurements of physical propertiesquantify and contribute to characterizing variationsin the sediment records caused by environmentalchanges, depositional and erosional events, andother geological phenomena. They further help tocorrelate core lithology, downhole geophysical logs,and seismic data.

Wet bulk density, compressional wave velocity,magnetic susceptibility, and electrical resistivity weremeasured on whole-core sections on the MST.Thermal conductivity measurements using theneedle probe method were performed at discreteintervals in whole-round sections. Measurementsmade in undisturbed sections of split cores includedcompressional wave velocity in three directions,vane shear strength, and moisture and density(MAD) measurements, used to define bulk density,water content, grain density, dry bulk density,porosity, and void ratio. These laboratory methodswere performed according to ODP laboratorypractices (Blum, 1997). The undrained peak shearstrength was also measured with a handheld

Proc. IODP | Volume 308

penetrometer. Most measurements were performedat regularly spaced intervals, although some weretaken in thin lithologic units that would have beenmissed by the regular sampling patterns. Theflowchart of the analyses in the laboratory is shownin Figure F8.

Multisensor TrackThe MST incorporates the gamma ray attenuation(GRA) densitometer, P-wave logger (PWL), magneticsusceptibility logger (MSL), and noncontactresistivity (NCR) detector. All MST measurements de-pend on core diameter and/or volume and thereforeare most reliable in APC cores and undisturbed XCBcores. XCB cores often show drilling disturbance,have irregular variations in core diameter, andcontain voids; corrections must be applied whenthese data are analyzed. At the drilling sites, drilloverafter APC refusal and XCB coring were used. Allsections, excluding core catchers and those withdeformed core liners, were run through the MST andthe data were stored in the Janus database. Coresections were run through the MST after they hadwarmed to at least 17°C (measured at the top of thesection).

All cores were processed through the MST beforesplitting. For Sites U1319 and U1320, NCR and mag-netic susceptibility measurements were taken at 2cm intervals. PWL and GRA measurements weretaken at 4 cm intervals. At Site U1324 from Core308-U1324B-5H and beyond and for all cores at SiteU1322, all MST measurements were taken at 6 cmintervals because of the high core recovery rate.

Gamma ray attenuation bulk densityGRA bulk density is determined by comparing theattenuation of gamma rays through the cores withtheir attenuation through aluminum and distilledwater standards. Recalibration was requiredapproximately every 24 h. GRA bulk densities werecalculated by means of shipboard software usingcalibration coefficients from the aluminum standardruns. Aluminum has a Compton mass attenuationcoefficient of 0.10 cm2/g, which is also valid for mostcommon minerals. GRA bulk densities were notcorrected for the presence of water, which has anattenuation coefficient of 0.11 cm2/g. GRA bulkdensity provides a high-resolution data set used tofill trends between the MAD measurements and tocompare with log-derived bulk density.

P-wave loggerThe PWL transmits a 500 kHz compressional pulsewave through the core and core liner. Transmitting

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and receiving transducers are aligned perpendicularto the long axis of the core. A pair of displacementtransducers monitors the separation between thecompressional wave transducers; variations in theoutside diameter of the liner, therefore, do notdegrade the accuracy of velocities. Water was sprayedon the outer surface of the core liner to enhancecontact between transducers and liner. Poor contactbetween liner and sediment significantly degradesdata.

Magnetic susceptibility loggerMagnetic susceptibility was measured on all sectionsusing the 1.0 range on the Bartington Instrumentsmagnetic susceptibility meter (model MS2) with an80 mm diameter loop. Magnetic susceptibility, inaddition to assisting with correlation between holes,aids in the detection of fine variations in magneticintensity associated with magnetic reversals andlithologic changes. The quality of these results isdegraded if the core liner is not completely filledand/or the core is disturbed. However, generaldownhole trends may still be used for core to well-log correlation.

Noncontact resistivityThe NCR technique operates by inducing a high-frequency magnetic field in the core from atransmitter coil, which induces electrical currents inthe core that are inversely proportional to theresistivity. A receiver coil measures very smallmagnetic fields that are regenerated by the electricalcurrent. To measure these very small magnetic fieldsaccurately, a differential technique has beendeveloped to compare the readings generated fromthe measuring coils with the readings from anidentical set of coils operating in air. This techniqueprovides the accuracy and stability required. Themeasurements are sensitive to core temperature andshould be obtained in a stable temperatureenvironment for best results. Calibration wasachieved by filling short lengths (~25 cm each) ofcore liner with water containing knownconcentrations of NaCl. This provides a series ofcalibration samples with known resistivities that arethen placed on the MST and logged. Resistivity is de-termined using the following equation;

r = AxB, (1)

where

r = resistivity (Ωm), A = calibration constant (0.1249), B = calibration constant (–0.7836), and x = resistivity output from the logger (mV).

Proc. IODP | Volume 308

NCR data are used for correlation with log-derivedresistivity and as complementary data forinterpretation of porosity and lithology.

Thermal conductivityThermal conductivity measurements on whole-round samples were made using the TK04 (TekaBolin) system described by Blum (1997).Measurements were made once per core. Cores wereallowed to equilibrate to ambient temperature beforemeasurement. The measurement system employs asingle needle probe (Von Herzen and Maxwell, 1959)heated continuously in full-space configuration. Theneedle probe contains a heater wire and a calibratedthermistor. At the beginning of each measurement,temperatures in the samples were monitoredautomatically, without applying a heater current,until the background thermal drift was <0.04°C/min.Once the samples were equilibrated, the heatercircuit was closed and the temperature rise in theprobe was recorded. The probe is assumed to be aperfect conductor because of its high conductancerelative to the core sediments. Thus, during heating,temperature in the probe shows a linear relationshipwith the natural logarithm of time:

T(t) = (q/4πk) ln(t) + C, (2)

where

T = temperature, q = heat input per unit length per unit time, k = thermal conductivity, t = time after heat initiation, and C = a constant.

Thermal conductivity (k) was determined usingEquation 2 by fitting the temperatures measuredduring the first 150 s of each heating experiment (seeKristiansen, 1982; Blum, 1997). The reportedthermal conductivity value for each sample is theaverage of three repeated measurements. Data arereported in watts per meters degree Kelvin (W/[m·K]), with measurement errors of 5%–10% in high-quality cores. Corrections were not attempted for insitu temperature or pressure effects.

Compressional wave velocityP-wave velocity measurements on split cores werecarried out on the working-half core station alongthe x-, y-, and z-axis (Fig. F9). One measurement ev-ery two sections was performed. The locations forthe P-wave measurements were generally next to thediscrete MAD samples. When measuring PWS1,along the z-axis, and PWS2, along the y-axis, trans-ducer pairs were inserted into the soft semiconsoli-dated sediment so that the measurement does notinvolve the core liner. PWS3 is designed to measure

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the P-wave velocity along the x-axis through thecore liner. The P-wave measurements were carriedout in the order PWS3, PWS1, and PWS2 to mini-mize the disturbance by the transducer in the work-ing half. When gas expansion prevented accuratemeasurements of P-wave velocity using PWS3; PWS2and PWS1 were not used.

P-wave velocity is calculated by measuring thetraveltime between transducers that are separated bya known distance. The distance is regularly measuredwith calipers and then assumed to be constant. Thedistance between the probe surfaces does not exactlycorrespond to the distance between the transducers.In addition, there is some electrical delay. The totaldelay was determined by inserting the probes intodistilled water of known temperature and thereforeof known acoustic velocity. This calibration was onlyperformed after repeated use of the tool, whichcould have resulted in a change in distance betweenthe probes. The temperature within the cores wasmeasured for correction of the measured P-wavevelocity. The presented data are uncorrected for insitu temperature and pressure. These corrections canbe made using the relationships outlined in Wyllie etal. (1956), Wilson (1960), and Mackenzie (1981). Formeasurements with the PWS3 contact probe, theinstrument is equipped with a digital scale unit thatallows precise determination of sample thickness. ATectronix signal generator, differential amplifier, andoscilloscope are used to transmit and receive signalsfrom all three transducer pairs and to digitize analogwaveform data.

The anisotropy of P-wave velocity (or acoustic aniso-tropy, measured in percent) is defined here, follow-ing Carlson and Christensen (1977), as the differ-ence between velocities in the horizontal andvertical directions expressed as a percentage of themean velocity:

Anisotropy = [(vpl – vpt)/0.5(vpl + vpt)] × 100, (3)

where

vpl = P-wave velocity measured in the direction parallel (longitudinal or z-axis) to the core axis and

vpt = P-wave velocity in the horizontal (transverse, x- or y-axis) direction.

In clay-rich marine sediments, positive transverseanisotropy will vary from 0% near the surface (iso-tropic) to >12% at depths of several hundred meters(Brückman et al., 1997). Sources for P-wave aniso-tropy include (but are not limited to) (1) compac-tional anisotropy (preferential alignment of poresand particles parallel to bedding because of gravita-

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tional compaction under increasing overburden) and(2) presence of microstructures such as microfrac-tures and microcracks.

Moisture and densityMAD parameters including bulk density, graindensity, and porosity were determined from wetmass, dry mass, and dry volume measurements ofsplit core sediments after method C of Blum (1997).For each core section, at least one sample of ~10 cm3

was taken and placed in a 10 mL glass beaker. Carewas taken to sample undisturbed parts of the coreand to avoid sampling drilling fluid. The wet weightof the samples was measured, and then the sampleswere dried for at least 24 h in an oven at 105°C. Thesamples cooled in a desiccator to room temperature.Dry weight was measured, after which volume wasdetermined using a pycnometer.

Sample mass was determined to a precision of 0.01 gusing two Scientech 202 electronic balances and acomputer averaging system to compensate for shipmotion. The reference mass was always set to bewithin a 5 g margin of the actual sample weight.Sample volumes were determined using two helium-displacement penta-pycnometers with a precision of0.02 cm3. Volume measurements were repeated threetimes, until the last two measurements exhibited<0.1% standard deviation. A reference volume wasused to calibrate the pycnometers and to check forinstrument drift and systematic error.

Moisture content, grain density, bulk density, andporosity were calculated from the measured wetmass, dry mass, and dry volume as described byBlum (1997). The presented data are corrected forthe mass and volume of evaporated seawater assum-ing a seawater salinity of 35 ppt. This results in afluid density of 1.024 g/cm3 assuming a salt densityof 2.20 g/cm3.

Shear strengthUndrained shear strength was measured using theautomatic vane shear (AVS) and a pocket penetrome-ter. The measurements were not performed at in situstress conditions and thereby underestimate the trueundrained peak shear strength in situ. All shearstrength measurements were performed in the y–zplane (see Fig. F9).

Automatic vane shear systemUndrained shear strength (τfu) was measured in fine-grained, plastic sediment using the AVS systemfollowing the procedures of Boyce (1977). The vanerotation rate was set to 90°/min. Measurements were

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made only in fine-grained sediment. Peak undrainedshear strength was measured typically at everysecond section. The instrument measures the torqueand strain at the vane shaft using a torquetransducer and potentiometer. The peak shearstrength was determined from the torque versusstrain plot. The experiment was set up to run for 6min, which equals 1.5 vane laps. The residual shearstrength was taken to be the lowest measured shearstrength after reaching the peak value during the testcycle. All shear strengths were measured with the ro-tation axis parallel to the bedding plane.

PenetrometerA pocket penetrometer (Geotester STCL-5) was usedto obtain additional undrained shear strengthmeasurements. The penetrometer is a flat-footed,cylindrical probe that is pushed 6.4 mm into thesplit-core surface. The penetrometer is calibrated asan unconfined compression test, which (for an idealclay) measures twice the undrained shear strength,or 2τfu (Holtz and Kovacs, 1981). The scale on thedial is converted into shear strength (in kilopascals)using the following equation:

τfu = [(Su × 10) × g]/2, (4)

where

τfu = undrained shear strength (kPa), Su = penetrometer reading (kg/cm2), andg = acceleration due to gravity (9.81 m/s2).

The maximum shear strength that can be measuredwith the pocket penetrometer is 220 kPa.Penetrometers are designed for use in soft sediment,and readings were discarded if the sediment crackedduring measurement. Measurements using thepenetrometer were typically performed every secondsection.

Presentation of undrained shear strengthFor every site, the undrained shear strength ispresented in plots with the undrained peak and theresidual shear strength from the AVS system, acomparsion between the undrained peak shearstrength measured by the AVS system and thepenetrometer, the sensitivity, and a plot of theundrained peak strength versus the hydrostatic verti-cal effective stress.

The peak undrained shear strength measured withthe AVS system is defined as the peak value duringthe shearing procedure, and the residual undrainedshear strength is defined as the lowest measuredundrained shear strength during the shearing period(1.5 laps). If a negative value was achieved duringthe test, the residual shear strength was set to 0 kPa.

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The penetrometer only measured the undrainedpeak shear strength.

Sensitivity (Sn) is here defined as the ratio betweenthe peak and residual undrained shear strength fromthe AVS system.

. (5)

Sensitivity allows estimation of the loss in strengthof a sediment sample when the undrained shearstress exceeds the corresponding undrained peakshear strength.

The total vertical stress (σv) and vertical hydrostaticeffective stress (σvh′) are estimated using bulk densitydata and hydrostatic stress conditions (Equations 6and 7);

and (6)

, (7)

where

z = depth beneath the seafloor, ρ(z) = bulk density at depth z, g = acceleration due to gravity (9.81 m/s2), andρw = the pore fluid density, which is assumed to

be 1.024 g/cm3 (seawater) (= 1024 kg/m3).

Downhole measurementsIn situ temperature andpressure measurements

Several downhole tools were deployed during Expe-dition 308 to measure in situ temperature, formationpressure, and hydraulic conductivity. Temperatureand pressure data are critical for constraining sedi-ment properties and flow fields. In addition, temper-ature affects sediment diagenesis and microbial ac-tivity.

Temperature, pressure, and hydraulic conductivitywere measured in situ with a newly developed tem-perature/dual pressure (T2P) probe and the Davis-Vil-linger Temperature-Pressure Probe (DVTPP). In situtemperature measurements were also made using theAPC temperature (APCT) tool.

Temperature/dual pressure probeA narrow-diameter penetration probe with one tem-perature and two pressure sensors (T2P) was de-ployed during Expedition 308 to evaluate in situfluid pressure, hydraulic conductivity, and tempera-ture in low-permeability sediments. The T2P mea-

Snτpeak

fu

τ resfu

-------------=

σv ρ z( )g zd0

z

∫=

σvh′ ρ z( ) ρw–( )g zd0

z

∫=

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sures pressure and temperature at the tool tip andpressure 21 cm up-probe from the tip measurement(Fig. F10). The needle probe diameter is 0.6 cm at thetip and 3.6 cm at the upper pressure port. A 3.6 cmdiameter drive tube extends 100 cm above the shaftpressure sensor where the drive tube connects withthe data acquisition unit. All deployment data arestored in memory in the data acquisition unit.

The T2P interfaces with the colleted delivery system(CDS) used to deploy other downhole tools such asthe DVTPP. The CDS is lowered by wireline and en-gages in the bottom-hole assembly (BHA). Once theCDS is engaged in the BHA, the drill string is used topush the needle shaft and drive the tube into the for-mation. This penetration causes pressure and tem-perature increases. After penetration into the forma-tion, the drill string is raised 3–4 m uphole and theCDS telescopes. The telescope action leaves the T2Pin the formation and effectively decouples the probefrom the drill string. The T2P remains in the forma-tion to measure pressure and temperature. Dissipa-tion of pressure and temperature is used to deter-mine in situ pressure, hydraulic conductivity, andtemperature. After adequate time for dissipation (30–90 min), the wireline pulls the CDS to its extendedposition and then pulls the T2P out of the forma-tion. The CDS and T2P are pulled to the surface,where the data are downloaded from the data acqui-sition unit.

The slim design of the T2P facilitates rapid, high-quality measurement of in situ conditions in low-permeability sediment. The design minimizes pres-sure and temperature pulses generated during pene-tration. The two pressure sensors have different dissi-pation rates because they are at different diameterson the tool. Comparison of the dissipation curves al-lows equilibrium pressure to be interpreted with lessrecorded dissipation than if one sensor was used.

Davis-Villinger Temperature-Pressure ProbeThe DVTPP is a modified version of the Davis-Vil-linger Temperature Probe (DVTP) (see Davis et al.,1997; Pribnow et al., 2000; Graber et al., 2002). TheDVTPP provides simultaneous measurement of for-mation temperature and pressure. The probe tip in-corporates a single thermistor in an oil-filled needleand ports that allow hydraulic transmission of for-mation pressure to an internal Paroscientific pressuregauge. A standard data logger records the pressureand temperature data. Thermistor sensitivity is 0.02K in an operating range of –5° to 20°C.

A typical DVTPP deployment consists of connectingthe DVTPP to the CDS and lowering the tool stringby wireline to the seafloor and then holding for 10min. The drill bit is then raised 12 m off the bottom

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of the hole. Subsequently, the tool string is lowereduntil the CDS engages in the BHA, with the tip of thetool extending 1.1 m below the drill bit. The DVTPPis pushed into the sediment by lowering the drill bit,the CDS is telescoped to decouple the DVTPP andthe drill string, and pressure is recorded for ~40 min.The tool string is then recovered via wireline. Alldata are stored in memory. If smooth pressure decaycurves are recorded after penetration then theoreti-cal extrapolations to in situ pore pressure are possi-ble. Decay time is a function of the sediment perme-ability and the magnitude of the initial insertionpressure, which is a function of the taper angle anddiameter of the tool (Whittle et al., 2001; Heeseman,2002). Temperature decay of the frictional heat gen-erated during insertion of the DVTPP can be used tointerpret the formation temperature. Temperaturedecays faster than pressure.

Advanced Piston Corer Temperature toolThe APCT tool fits into the cutting shoe on the APCand is used to measure sediment temperatures dur-ing regular APC coring. The tool contains electroniccomponents, including battery packs, a data logger,and a platinum resistance-temperature device that iscalibrated from 0° to 30°C. Descriptions of the tooland of the principles behind data analysis can befound in Pribnow et al. (2000) and Graber et al.(2002). The thermal time constant of the cuttingshoe assembly where the APCT tool is inserted is ~2–3 min. The only modification to normal APC proce-dures required to obtain temperature measurementsis to hold the corer in place for ~10 min after cuttingthe core. During this time, the APCT tool logs tem-perature on an internal microprocessor. Followingdeployment, the data are downloaded for process-ing. The tool can be preprogrammed to record tem-peratures at a range of sampling rates. A samplingrate of 10 s was used during Expedition 308. A typi-cal APCT measurement consists of a seafloor temper-ature record lasting 10 min for the first deploymentin each borehole and 2 min during subsequent de-ployments. This is followed by frictional heatingpulse when the piston is fired, and the resultant tem-perature decay is monitored for 10 min. A final fric-tional pulse is generated upon removal of the corerfrom the sediment.

Downhole loggingThe downhole logging program during Expedition308 was designed to • Assess how pressure, stress, and geology control

fluid migration on a passive margin; • Establish reference geotechnical and petrophysical

properties at a location where overpressure is notpresent as well when overpressure is present;

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• Learn about factors controlling slope (in)stability;

• Determine major depositional events and timingof landslides; and

• Provide information about turbidite processesalong the continental slope.

In addition, the downhole measurements plan wasestablished to define structural and lithologicboundaries, establish site-to-site correlations, pro-vide ties to seismic data, produce direct correlationswith laboratory data, and identify conduits that mayserve as pathways for fluid migration. Finally, down-hole measurements complemented core measure-ments by filling gaps in stratigraphy, determinedlithogical interpretations in intervals of poor core re-covery, and provided the means for correlation withthe seismic data.

Logging while drilling and measurement while drilling

During Expedition 308, four Schlumberger logging-while-drilling (LWD) and measurement-while-drill-ing (MWD) tools were deployed at each site in theBrazos-Trinity and Ursa Basins. LWD surveys havebeen successfully conducted during ODP Legs 156(Shipley, Ogawa, Blum, et al., 1995), 170 (Kimura,Silver, Blum, et al., 1997), 171A (Moore, Klaus, et al.,1998), 174A (Austin, Christie-Blick, Malone, et al.,1998), 188 (O’Brien, Cooper, Richter, et al., 2001),193 (Binns, Barriga, Miller, et al., 2002), 196 (Mi-kada, Becker, Moore, Klaus, et al., 2002), 204 (Tréhu,Bohrmann, Rack, Torres, et al., 2003), and 209 (Kele-men, Kikawa, Miller, et al., 2004).

LWD and MWD tools measure different parameters.LWD tools measure formation properties with instru-ments located in the drill collars above the drill bit.MWD tools are also located in the drill collars andmeasure downhole drilling parameters (e.g., weighton bit, torque, etc.). The difference between LWDand MWD tools is that LWD data are recorded inmemory and retrieved when the tools reach the sur-face, whereas MWD data are transmitted throughthe drilling fluid within the drill pipe by means of amodulated pressure wave, or mud pulsing, and mon-itored in real time. MWD tools enable both LWDand MWD data to be transmitted uphole when thetools are used in conjunction. LWD is often used ge-nerically for LWD and MWD measurements.

LWD and MWD tools used during Expedition 308 in-cluded the GeoVision Resistivity (GVR) tool, Power-Pulse MWD tool, Array Resistivity Compensated(ARC) tool, and Vision Density Neutron (VDN) tool.This was the first time the ARC tool was used withinODP/IODP. Figure F11 shows the configuration of

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the LWD/MWD BHA, and Table T1 lists the set ofmeasurements recorded.

LWD provides measurements before the sedimentsexperience the adverse effects of continued drillingor coring operations. Fluid invasion into the bore-hole wall is reduced relative to wireline logging be-cause of the shorter elapsed time between drillingand logging.

The LWD tools are battery powered and use erasable/programmable read-only memory chips to store datauntil they are downloaded. The LWD tools take mea-surements at evenly spaced time intervals and aresynchronized with a system on the drilling rig thatmonitors time and drilling depth. LWD data aredownloaded from each tool through an RS-232 seriallink to a laptop computer. Synchronization of theuphole and downhole clocks allows merging of thetime-depth data (from the surface system) and thedownhole time-measurement data (from the tools).The resulting depth-measurement data are trans-ferred in the downhole measurements laboratory(DHML) on board the JOIDES Resolution for reduc-tion and interpretation.

Depth-tracking systemsLWD tools record data versus time. The Schlum-berger Integrated Drilling and Logging (IDEAL) sys-tem records the time and depth of the drill string be-low the rig floor. As shown in Figure F12, LWDoperations aboard the JOIDES Resolution require ac-curate and precise depth tracking and the ability toindependently measure and evaluate the movementof (1) the position of the traveling block in the der-rick, (2) the heave of the vessel by the action ofwaves/swells and tides, and (3) the action of the mo-tion compensator.

Motion compensator and drawworks encodersThe length of the drill string (combined lengths ofthe BHA and the drill pipe) and the position of thetop drive in the derrick are used to determine thedepth of the drill bit and rate of penetration. Thesystem configuration is illustrated in Figure F12 andis further described below.

Drilling line is spooled on the drawworks. From thedrawworks, the drilling line extends to the crownblocks, which are located at the top of the derrick,and then down to the traveling block. The drillingline is passed several times, usually six or eight times,between the traveling blocks and the crown blocksand then fastened to a fixed point called the dead-man anchor. The driller controls the drawworks,which, via the pulley system, control the position ofthe traveling block in the derrick.

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Aboard the JOIDES Resolution, the heave motioncompensator is suspended from the traveling block.The top drive is attached to the motion compensa-tor. The motion compensator uses pressure-chargedpistons to provide a buffer against waves and swell.As the vessel rises, the pressure on the pistons in-creases and they extend to keep the bit on bottom,whereas when the vessel drops, the pistons retractand diffuse any extra weight from being stacked onthe bit.

The drill string is connected to the top drive; there-fore, movement of the top drive needs to be mea-sured to provide the drill string depth.

To measure the movement of the traveling blocks, adrawworks encoder (DWE) is mounted on the shaftof the drawworks. One revolution of the drawworkswill pay out a certain amount of drilling line and, inturn, move the traveling blocks a certain distance.Calibration of the movement of the traveling blockto the revolutions of the drawworks is required.

Hookload sensorA hookload sensor measures the weight of the loadon the drill string and can detect whether the drillstring is disconnected from the traveling block andheld fast at the rig floor (“in-slips”). When drillingahead, the string is “out-of-slips.” When the drillstring is in-slips, motion from the blocks or motioncompensator will not have any effect on the depthof the bit (i.e., it will remain stationary) and theDWE information does not augment the recorded bitdepth. When the drill string is out-of-slips, the DWEinformation augments the recorded bit depth. Thedifference in hookload weight between in-slips andout-of-slips is distinguishable. The heave of the shipwill continue to affect the bit depth whether the drillstring is in-slips or out-of-slips.

Heave motion sensorsOn the JOIDES Resolution, vessel heave is measured intwo ways. The rig instrumentation system measuresand records the heave of the ship and the motion ofthe cylinder of the active compensator on the rigfloor. The motion compensator cylinder extends andretracts to compensate for ship heave, which is de-tected by fixed accelerometers. Heave and cylinderposition are transmitted to the Schlumberger record-ing system via the Wellsite Information Transfer Sys-tem (WITS) line. Software filtering may be used tosmooth the time-depth file by applying a weightedaverage to the time-depth data based on the ob-served amplitude and period of ship heave. Depth-filtering has improved the quality of GVR image logsfrom previous ODP holes.

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GeoVision Resistivity toolThe GVR tool provides formation resistivity andelectrical images of the borehole wall, similar to theFormation MicroScanner (FMS), but with completecoverage of the borehole walls and lower vertical andhorizontal resolution. In addition, the GVR tool con-tains a scintillation counter that provides a totalgamma ray measurement (Fig. F13). Because a cali-per log is not available without other LWD measure-ments, the influence of the shape of the borehole onthe log responses cannot be directly estimated.

The GVR tool is connected directly above the drillbit and uses the lower portion of the tool and the bitas a measuring electrode. This provides a bit resistiv-ity measurement with a vertical resolution just a fewcentimeters longer than the length of the bit. A 2.5cm electrode located 91 cm from the bottom of thetool provides a focused lateral resistivity measure-ment (RES_RING) with a vertical resolution of 5 cm.The characteristics of RES_RING are independent ofwhere the GVR tool is placed in the BHA; its depth ofinvestigation is ~18 cm. Button electrodes provideshallow-, medium-, and deep-focused resistivitymeasurements and azimuthally oriented images.These images reveal information about structure andlithologic contacts. The button electrodes are ~2.5cm in diameter and reside on a clamp-on sleeve. Thebuttons are longitudinally spaced along the GVRtool to render staggered depths of investigation of~2.5, 7.6, and 12.7 cm. The tool’s orientation systemuses Earth’s magnetic field as a reference to deter-mine tool position with respect to the borehole asthe drill string rotates, thus allowing azimuthal resis-tivity and gamma ray measurements. Measurementsare acquired with a ~6° azimuthal resolution. Thevertical resolution for each resistivity measurementis shown in Figure F13.The diameter of the GVR measuring button sleeve is23.3 cm, and the diameter of the three-cone rotarybit used during Expedition 308 is 25 cm. This resultsin a 1.7 cm gap, or “standoff,” between the resistivitybuttons and the formation. The standoff causes theformation resistivity to be underestimated slightly,depending on the ratio between the formation andborehole fluid resistivity. For a resistivity ratio <100,as expected for Expedition 308 sites, a resistivity cor-rection factor of as much as 4% may be applied toeach GVR measurement. Estimated correction fac-tors for the GVR tool are given in Table T2 (Schlum-berger, unpubl. data [2001]). Because of its limiteddepth of penetration into the formation, the correc-tion factor for shallow button resistivity cannot beconstrained.

GVR programming

All data are collected at a minimum vertical densityof 15 cm whenever possible; hence, a balance must

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be determined between rate of penetration (ROP)and sampling rate. This relationship depends on therecording rate, the number of data channels torecord, and the memory capacity (46 MB) of theLWD tool. During Expedition 308, we used samplingrate of 5 s for high-resolution GVR images. The max-imum ROP allowed to produce 1 sample/15 cm in-terval is given as follows:

ROP (m/h) = 548/sample rate. (8)

This relationship gives 110 m/h maximum ROP forthe GVR and 18 m/h minimum. For Expedition 308,the target ROP was 25 m/h, ~23% of the maximumROP. This rate improves the vertical resolution of theresistivity images to 5–10 cm per rotation. Under thisconfiguration, the GVR tool has enough memory torecord 150 h of data. This was sufficient to completethe scheduled LWD operations at the Expedition 308drill sites.

Bit resistivity measurements

For the bit resistivity measurements, a lower trans-mitter (T2) produced a current and a monitoringelectrode (M0) located directly below the ring elec-trode measured the current returning to the collar(Fig. F13). When connected directly to the bit, theGVR tool used the lower few inches of the tool aswell as the bit as a measurement electrode. The bitresistivity measurement (RES_BIT) had a depth of in-vestigation of 81 cm.

Ring resistivity measurements

The upper and lower transmitters (T1 and T2, respec-tively) produce currents in the collar that meet at thering electrode. The sum of these currents is focusedradially into the formation. These current patternscan become distorted depending on the strength ofthe fields produced by the transmitters and the for-mation around the collar. Therefore, the GVR tooluses a cylindrical focusing technique that takes mea-surements in the central (M0) and lower (M2) moni-tor coils to reduce distortion and create an improvedring response. The ring electrode is held at the samepotential as the collar to prevent interference withthe current pattern. The current required for main-taining the ring at the required potential is measuredand related to the resistivity of the formation. Thenarrow ring electrode (~4 cm) provides a resistivitymeasurement (RES_RING) with 5 cm vertical resolu-tion.

Button resistivity measurements

The button electrodes function the same way as thering electrode. Each button is electrically isolatedfrom the body of the collar but is maintained at the

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same potential to avoid interference with the currentfield. The amount of current required to maintainthe button at the same potential is related to the re-sistivity of the formation. The buttons are 4 cm in di-ameter, and the shallow-, medium-, and deep-resis-tivity measurements (RES_BS, RES_BM, and RES_BD,respectively) can be acquired azimuthally as the toolrotates within 56 sectors to produce a borehole im-age.

Array resistivity compensated toolThe ARC tool is capable of multidepth borehole-compensated real-time and memory resistivity andgamma ray measurements at 2 MHz and 400 kHz(Fig. F14). The measured resistivity utilizes electro-magnetic wave propagation in the formation. It hasfive transmitters and two receivers, giving five phaseand five attenuation resistivities for each frequency.Each measurement is compensated for borehole rug-osity using mixed borehole compensation. It alsocontains a plateau gamma ray detector for correla-tion. The gamma ray measurement point for theARC tool is 7.6 cm behind the resistivity measure-ment point. Also included in the collar is the annu-lar pressure-while-drilling (APWD) sensor, located 69cm ahead of the resistivity measure point. TheAPWD sensor measures borehole annulus pressureand temperature.

Measurement-While-Drilling (PowerPulse) tool The Schlumberger MWD PowerPulse tool (Fig. F15)was deployed in combination with LWD tools. TheMWD tool had previously been deployed duringODP Legs 188 (O’Brien, Cooper, Richter, et al., 2001),196 (Mikada, Becker, Moore, Klaus, et al., 2002), and204 (Tréhu, Bohrmann, Rack, Torres, et al., 2003).MWD tools measure downhole drilling parameters,immediately above the ARC tool (Fig. F11).

MWD data are transmitted by means of a pressurewave (mud pulsing) through the fluid within thedrill pipe. The 17.15 cm diameter MWD PowerPulsetool generates a continuous mud-wave transmissionwithin the drilling fluid and changes the phase ofthis signal (frequency modulation) to transmit rele-vant bits representing the sensor data (Fig. F16).Pressure sensors attached to a standpipe on the rigfloor and on the gooseneck on the crown block mea-sure the pressure wave pulsed by the MWD tool.Pulse rates of 12 bps were achieved during Expedi-tion 308.

Parameters transmitted by mud pulses includeddownhole weight on bit (DWOB), downhole torqueon bit (DTOR), torsional vibration, lateral shock, andtool stick-slip (Table T1). Measurements are made us-

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ing paired strain gauges, accelerometers, and lateralshock near the base of the MWD collar. Comparisonof MWD drilling parameter data, rig instrumentationsystem data, and ship-heave information was used toimprove drilling control and to assess the quality ofthe recorded LWD data.

The mud pulse system also transmitted annular pres-sure, temperature, equivalent circulating density,gamma radiation, resistivity, density, and porosityfrom the LWD tools. Measurement parameters fromeach LWD collar were updated at rates correspond-ing to 15 cm to 1.5 m depth intervals, depending onthe initialized values and ROP of the tool. These dataconfirmed the operational status of each tool andprovided real-time logs for identifying lithologiccontacts and potential shallow-water flow or over-pressured zones.

Vision Density Neutron toolThe density section of the VDN tool uses a 1.7 Ci(Curie = 3.7 × 1010 Bq), 137Cs gamma ray source inconjunction with two gain-stabilized scintillationdetectors to provide borehole-compensated density.The detectors are located 12.7 and 30.48 cm belowthe source (Fig. F17). The number of Compton scat-tering collisions (change in gamma ray energy by in-teraction with the formation electrons) is related toformation density. Returns of low-energy gammarays are converted to a photoelectric effect (PEF)value, measured in barns per electron. PEF dependson electron density and hence responds to bulk den-sity and lithology (Anadrill-Schlumberger, 1993). Itis particularly sensitive to low-density and high-po-rosity zones.

The gamma ray source and detectors are positionedbehind holes in the fin of a full-gauge 24.5 cm diam-eter clamp-on stabilizer (Fig. F17). This geometryforces the sensors against the borehole wall to reducethe effects of borehole irregularities. The vertical res-olution of the density and PEF measurements is ~15and 5 cm, respectively. For measurement of toolstandoff, a 670 kHz ultrasonic caliper is available onthe VDN tool. The ultrasonic sensor is aligned withand located just below the density detectors. Thesensor can also be used as a quality control check forthe density measurements. Neutron porosity mea-surements are obtained using fast neutrons emittedfrom a 10 Ci americium oxide–beryllium (AmBe)source. Hydrogen quantities in the formation largelycontrol the rate at which the neutrons slow down toepithermal and thermal energies. The energy of thedetected neutrons has an epithermal component be-cause much of the incoming thermal neutron flux isabsorbed as it passes through the 2.54 cm drill collar.Neutrons are detected in near- and far-spacing detec-

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tor banks, located 30.48 and 60.96 cm above thesource. The vertical resolution of the tool under opti-mum conditions is ~34 cm. The neutron logs are af-fected by the different lithologies because the tool iscalibrated for 100% limestone. Neutron porosity logsare processed to eliminate the effects of borehole di-ameter, tool size, temperature, drilling mud hydro-gen index (dependent on mud weight, pressure, andtemperature), and mud. Formation fluid salinity, li-thology, and other environmental factors also affectneutron porosity. These parameters must be esti-mated for each borehole during neutron log process-ing (Schlumberger, 1994).

Data output from the VDN tool includes apparentneutron porosity (i.e., the tool does not distinguishbetween pore water and lattice-bound water), forma-tion bulk density, and PEF. Because of the lack ofquadrant data, density logs have been “rotationallyprocessed” to show the image-derived density(IDRO). The IDRO algorithm uses the bulk densityimage from the VDN tool to compute a single den-sity. It identifies which sectors at each depth levelprovide the highest-quality density measurementsand computes a density based on those sectors whilethe tool is rotating. The VDN tool also outputs adensity caliper record based on the standard devia-tion of density measurements made at high sam-pling rates around the circumference of the bore-hole. The measured standard deviation is comparedwith that of an in-gauge borehole, and the differenceis converted to the amount of borehole enlargement(Anadrill-Schlumberger, 1993). A standoff of <2.54cm between the tool and the borehole wall indicatesgood borehole conditions, for which the density logvalues are considered to be accurate to ±0.015 g/cm3

(Anadrill-Schlumberger, 1993).

LWD/MWD data flow MWD data were monitored in the onboard down-hole measurements laboratory (DHML) and dis-played in the drillers shack, operations superinten-dent’s office, co-chiefs’ office, and core laboratory.

The main parameters monitored were the equivalentcirculating density relative to seafloor (ECDrsf), annu-lar pressure while drilling (APWD), annular pressurewhile drilling above hydrostatic (APWD*), resistivitymeasurements from the GVR, gamma ray measure-ments from the GVR, and the density caliper(DCAV). ECDrsf was calculated as follows:

ECDrsf = (Papwd – Pwsf)/[(Dapwd – Dw – RKB) × 0.0519], (9)

where

ECDrsf = equivalent circulating density relative to seafloor (lb/gal [ppg]);

Papwd = APWD reading (lb/in2 [psi]);

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Pwsf = water pressure at seafloor (lb/in2 [psi]); Dapwd = TVD (true vertical depth) of APWD sen-

sor (ft); Dw = water depth (ft); RKB = distance from sea level to dual elevator

stool (ft); and 0.0519 = conversion factor.

Hydrostatic pressure at the seafloor is

Pwsf = ECDsw × Dw × 0.0519, (10)

where ECDsw = equivalent mud weight of seawater(8.65 lb/gal [ppg]).

Wireline logging tools Wireline logs reveal the physical, chemical, andstructural properties of formations. Where core re-covery is good, core data are used to calibrate thegeophysical signature of the rocks. In intervals oflow core recovery or disturbed cores, log data mayprovide the only way to characterize sediments.Wireline logs also aid in linking core data and seis-mic reflection data. Individual logging tools arejoined together into tool strings (Fig. F18); conse-quently, several measurements can be made duringone logging run (Table T3). The tool strings are low-ered to the bottom of the borehole on a wireline,and data are logged as the tool string is pulled backup the borehole. Repeat runs improve coverage andconfirm the reproducibility of logging data.

Wireline logging tool stringsThree logging strings were deployed during Expedi-tion 308 (Fig. F18; Table T3):

• The triple combination (triple combo) tool stringconsisting of the Hostile Environment GammaRay Sonde (HNGS), Phasor Dual Induction–Spher-ically Focused Resistivity (DIT-SFR) tool, HostileEnvironment Litho-Density Tool (HLDT), andAccelerator Porosity Sonde (APS). The Lamont-Doherty Earth Observatory (LDEO) high-resolu-tion Temperature/Acceleration/Pressure (TAP) toolwas attached at the bottom of this tool string, andthe Inline Check Shot Tool (QSST) was added atthe top.

• The FMS-sonic tool string consisting of the FMS,General Purpose Inclinometer Tool (GPIT), Scintil-lation Gamma Ray Tool (SGT), and Dipole SonicImager (DSI).

• The Well Seismic Tool (WST).

Tool acronyms, parameters measured sample inter-vals, and vertical resolution are summarized in Ta-bles T3 and T4.

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Wireline logging data flow and processing Data for each wireline logging run were recorded andstored digitally and monitored in real time using theSchlumberger MAXIS 500 system. After logging wascompleted in each hole, data were transferred to theshipboard DHML for preliminary processing and in-terpretation. FMS image data were interpreted usingthe Schlumberger GeoFrame (version 4.0.42) soft-ware package. Well seismic, sonic, and density datawere used for calculation of synthetic seismogramsto establish the seismic-to-borehole tie.

Logging data were also transmitted to LDEO Bore-hole Research Group (BRG) using a satellite high-speed data link for processing. Data processing atLDEO-BRG consisted of (1) depth-shifting all logsrelative to a common datum (i.e., mbsf), (2) correc-tions specific to individual tools, and (3) qualitycontrol. Processed data were transmitted back to theship. Further postcruise processing of the loggingdata from the FMS was performed at LDEO-BRG.Postcruise-processed data in ASCII are available fromiodp.ldeo.columbia.edu/DATA/index.html. At theend of each expedition, a summary of “logging high-lights” is posted on the USIO JOI Alliance Web site(iodp.ldeo.columbia.edu/LOG_SUM/index.html).

Wireline log data quality Log data quality may be degraded where borehole di-ameter greatly decreases or is washed out. Deep-investigation measurements such as resistivity andsonic velocity are least sensitive to borehole condi-tions. Nuclear measurements (density and neutronporosity) are more sensitive because of their shallowdepth of investigation and the effect of drilling fluidvolume on neutron and gamma ray attenuation.Corrections can be applied to the original data to re-duce these effects. The effects of very large washouts,however, cannot be corrected. HNGS and NGT dataprovide a depth correlation between logging runs.Logs from different tool strings may have minordepth mismatches caused by either cable stretch orship heave during recording.

Interpreting structure from GVR and FMS images Structural data were determined from unwrapped360° GVR images using the Schlumberger GeoFramesoftware. The image orientation is referenced tonorth, as measured by the magnetometers inside thetool, and the hole is assumed to be vertical. Horizon-tal features appear horizontal on the images, whereasplanar dipping features are sinusoidal in unwrappedimages. Sinusoids are interactively fitted to beds andfractures to determine dip and azimuth, and the dataare exported from GeoFrame for further analysis.

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Resolution for GVR images is 5–10 cm, compared tomillimeters within cores and 0.5 cm for FMS images.This should be considered when directly comparingreports. The GVR tool provides 360° coverage;whereas the FMS provides higher-resolution data,but coverage is restricted to ~30% of the borehole.Fractures were identified within GVR images by theiranomalous resistivity or conductivity and from con-trasting dip relative to surrounding bedding trends.Differentiating between fractures and beddingplanes can be problematic, particularly if both aresteeply dipping with similar orientations.

During processing, quality control of the data ismainly performed by cross-correlation of all loggingdata. Large (>30 cm) and/or irregular borehole diam-eter affects most recordings, particularly the HLDS,which requires centralization and good contact withthe borehole wall. Hole deviation can also negativelyaffect the data; the FMS, for example, is not designedto be run in holes with >10° deviation, as the toolweight might cause the caliper to close.

FMS image processing is required to convert the elec-trical current in the formation into an image repre-sentative of the conductivity. This is achievedthrough two processing phases: data restoration andimage display. During the data restoration process,speed corrections, image equalization, button correc-tion, emitter exciter (EMEX) voltage correction, anddepth-shifting techniques are applied.

Speed corrections use the data from the z-axis accel-erometer to correct the vertical position of the datafor variations in the speed of the tool (i.e., GPITspeed correction), including tool sticking and slip-ping. In addition, an image-based speed correction isalso applied to the data. This correction checks theGPIT speed correction.

Image equalization is the process whereby the aver-age response of all the buttons is normalized overlarge intervals to correct for various tool and bore-hole effects. These effects include differences in thegain and offset of the preamplification circuits asso-ciated with each button and differences in contactwith the borehole wall between buttons on a padand between pads. If the measurements from a par-ticular button are unreasonably different from adja-cent buttons (e.g., “dead buttons”) over a particularinterval, they are declared faulty and the defectivetrace is replaced by traces from adjacent good but-tons. The button current response is controlled bythe EMEX voltage, which is applied between the but-ton electrode and the return electrode. The EMEXvoltage is regulated to keep the current responsewithin the operating range. The button response isdivided by the EMEX voltage, and, as a result, the re-

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sponse corresponds more closely to the conductivityof the formation.

Each of the logging runs are depth-matched to acommon scale by means of lining up distinctive fea-tures of the natural gamma log from each of the toolstrings. If the reference-logging run is not the FMS-sonic tool string, the specified depth shifts are ap-plied to the FMS images. The position of data locatedbetween picks is computed by linear interpolation.

Once the data are processed, both static and dy-namic images are generated. In static normalization,a histogram equalization technique is used to obtainthe maximum quality image. In this technique, theresistivity range of the entire interval of good data iscomputed and partitioned into 256 color levels. Thistype of normalization is best suited for large-scale re-sistivity variations. The image can be enhancedwhen it is desirable to highlight features in sectionsof the borehole where resistivity contrasts are rela-tively low when compared with the overall resistiv-ity range in the section. This enhancement is calleddynamic normalization. By rescaling the intensityover a smaller interval, the contrast between adja-cent resistivity levels is enhanced. With dynamicnormalization, resistivities in two distant sections ofthe hole cannot be directly compared. The intervalused for the dynamic normalization was 2 m.

FMS images are displayed as an unwrapped boreholecylinder with a circumference derived from the bitsize. Several passes can be oriented and merged to-gether on the same presentation to give additionalborehole coverage where the tool pads followed adifferent track during the second logging pass. A dip-ping plane in the borehole can be displayed as a si-nusoid on the image, and the amplitude of this sinu-soid is proportional to the dip of the plane. Theimages are oriented with respect to north.

Core-log-seismic correlation We correlated core physical properties, wireline logs,LWD logs, and two-dimensional (2-D) and three-di-mensional (3-D) seismic survey data in the Brazos-Trinity IV and Ursa Basins. To ensure accurate corre-lation of the data, it was important to ascertain theaccuracy of the navigation of each survey, the holedeviation, the drill string position at the seafloor rel-ative to the sea surface, the accuracy of the depth-converted seismic data, and the vertical and horizon-tal seismic resolution. Accurate correlation is criticalto extend the study of the direct measurements ofthe subsurface physical properties away from theborehole using the seismic data. In order to correlatethe 2-D/3-D seismic data with the LWD data, syn-thetic seismograms were constructed using densitiesand velocities for each site.

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ReferencesAnadrill-Schlumberger, 1993. Logging While Drilling: Hous-

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Balsam, W.L., and Damuth, J.E., 2000. Further investiga-tions of shipboard vs. shore-based spectral data: impli-cations for interpreting Leg 164 sediment composition. In Paull, C.K., Matsumoto, R., Wallace, P., and Dillon, W.P. (Eds.), Proc. ODP, Sci. Results, 164: College Station, TX (Ocean Drilling Program), 313–324. [HTML]

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Balsam, W.L., Deaton, B.C., and Damuth, J.E., 1998. The effects of water content on diffuse reflectance measure-ments of deep-sea core samples: an example from ODP Leg 164 sediments. Mar. Geol., 149:177–189. doi:10.1016/S0025-3227(98)00033-4

Bassinot, F.C., Labeyrie, L.D., Vincent, E., Quidelleur, X., Shackleton, N.J., and Lancelot, Y., 1994. The astronomi-cal theory of climate and the age of the Brunhes-Matu-yama magnetic reversal. Earth Planet. Sci. Lett., 126:91–108. doi:10.1016/0012-821X(94)90244-5

Berggren, W.A., Hilgen, F.J., Langereis, C.G., Kent, D.V., Obradovich, J.D., Raffi, I., Raymo, M.E., and Shackle-ton, N.J., 1995. Late Neogene chronology: new perspec-tives in high-resolution stratigraphy. Geol. Soc. Am. Bull., 107:1272–1287. doi:10.1130/0016-7606(1995)107<1272:LNCNPI>2.3.CO;2

Bickert, T., Curry, W.B., and Wefer, G., 1997. Late Pliocene to Holocene (2.6–0 Ma) western equatorial Atlantic deep-water circulation: inferences from benthic stable isotopes. In Shackleton, N.J., Curry, W.B., Richter, C., and Bralower, T.J. (Eds.), Proc. ODP, Sci. Results, 154: Col-lege Station, TX (Ocean Drilling Program), 239–253.

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Bloemendal, J., Lamb, B., and King, J., 1988. Paleoenviron-mental implications of rock-magnetic properties of late Quaternary sediment cores from the eastern equatorial Atlantic. Paleoceanography, 3:61–87.

Blum, P., 1997. Physical properties handbook: a guide to the shipboard measurement of physical properties of deep-sea cores. ODP Tech. Note, 26 [Online]. Available from World Wide Web: <http://www-odp.tamu.edu/publications/tnotes/tn26/INDEX.HTM>.

Bolli, H.M., and Saunders, J.B., 1985. Oligocene to Holocene low latitude planktic foraminifera. In Bolli, H.M., Saunders, J.B., and Perch-Nielsen, K. (Eds.), Plank-ton Stratigraphy: Cambridge (Cambridge Univ. Press), 155–262.

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Boyce, R.E., 1977. Deep Sea Drilling Project procedures for shear strength measurement of clayey sediment using modified Wykeham Farrance laboratory vane apparatus. In Barker, P.F., Dalziel, I.W.D., et al., Init. Repts. DSDP, 36: Washington (U.S. Govt. Printing Office), 1059–1068.

Brückmann, W., Moran, K., and Housen, B.A., 1997. Direc-tional properties of P-wave velocities and acoustic ani-sotropy in different structural domains of the northern Barbados Ridge accretionary complex. In Shipley, T.H., Ogawa, Y., Blum, P., and Bahr, J.M. (Eds.), Proc. ODP, Sci. Results, 156: College Station, TX (Ocean Drilling Pro-gram), 115–123.

Bukry, D., 1973. Low-latitude coccolith biostratigraphic zonation. In Edgar, N.T., Saunders, J.B., et al., Init. Repts., DSDP, 15: Washington (U.S. Govt. Printing Office), 685–703.

Bukry, D., 1975. Coccolith and silicoflagellate stratigraphy, northwestern Pacific Ocean, Deep Sea Drilling Project Leg 32. In Larson, R.L., Moberly, R., et al., Init. Repts. DSDP, 32: Washington (U.S. Govt. Printing Office), 677–701.

Cande, S.C., and Kent, D.V., 1992. A new geomagnetic polarity time scale for the Late Cretaceous and Ceno-zoic. J. Geophys. Res., 97(10):13917–13951.

Cande, S.C., and Kent, D.V., 1995. Revised calibration of the geomagnetic polarity timescale for the Late Creta-ceous and Cenozoic. J. Geophys. Res., 100:6093–6095.

Carlson, R.L., and Christensen, N.I., 1977. Velocity aniso-tropy and physical properties of deep-sea sediments from the western South Atlantic. In Supko, P.R., Perch-Nielsen, K., et al., Init. Repts. DSDP, 39: Washington (U.S. Govt. Printing Office), 555–559.

Davis, E.E., Mottl, M.J., Fisher, A.T., et al., 1992. Proc. ODP, Init. Repts., 139: College Station, TX (Ocean Drilling Pro-gram).

Davis, E.E., Villinger, H., MacDonald, R.D., Meldrum, R.D., and Grigel, J., 1997. A robust rapid-response probe for measuring bottom-hole temperatures in deep-ocean boreholes. Mar. Geophys. Res., 19(3):267–281. doi:10.1023/A:1004292930361

DeLong, E.F, 2004. Microbiology: microbial life breathes deep. Science, 306:2198–2200. doi:10.1126/sci-ence.1107241

deMenocal, P., Bloemendal, J., and King, J., 1991. A rock-magnetic record of monsoonal dust deposition to the Arabian Sea: evidence for a shift in the mode of deposi-tion at 2.4 Ma. In Prell, W.L., Niitsuma, N., et al., Proc. ODP, Sci. Results, 117: College Station, TX (Ocean Drill-ing Program), 389–407.

D’Hondt, S.D., Jørgensen, B.B., Miller, D.J., Batzke, A., Blake, R., Cragg, B.A., Cypionka, H., Dickens, G.R., Fer-delman, T., Hinrichs, K.-H., Holm, N.G., Mitterer, R., Spivack, A., Wang, G., Bekins, B., Engelen, B., Ford, K., Gettemy, G., Rutherford, S.D., Sass, H., Skilbeck, C.G., Aiello, I.W., Guerin, G., House, C., Inagak, F., Meister, P., Naehr, T., Niitsuma, S., Parkes, R.J., Schippers, A., Smith, D.C., Teske, A., Wiegel, J., Naranjo Padillo, C., and Solis Acosta, J.L., 2004. Distributions of microbial activities in deep subseafloor sediments. Science, 306:2216–2221. doi:10.1126/science.1101155

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Frederichs, T., Bleil, U., Däumler, K., von Dobeneck, T., and Schmidt, A.M., 1999. The magnetic view on the marine paleoenvironment: parameters, techniques, and poten-tials of rock magnetic studies as a key to paleoclimatic and paleoceanographic changes. In Fischer, G., and Wefer, G. (Eds.), Use of Proxies in Paleoceanography: Examples from the South Atlantic: Berlin (Springer-Ver-lag), 575–599.

Gieskes, J.M., Gamo, T., and Brumsack, H., 1991. Chemical methods for interstitial water analysis aboard JOIDES Resolution. ODP Tech. Note, 15 [Online]. Available from World Wide Web: <http://www-odp.tamu.edu/publi-cations/tnotes/tn15/f_chem1.htm>.

Graber, K.K., Pollard, E., Jonasson, B., and Schulte, E. (Eds.), 2002. Overview of Ocean Drilling Program Engi-neering Tools and Hardware. ODP Tech. Note, 31 [Online]. Available from World Wide Web: <http://www-odp.tamu.edu/publications/tnotes/tn31/INDEX.HTM>.

Heeseman, M., 2002. Modeling and analysis of transient pressure measurements in ODP boreholes for undis-turbed formation pressure estimation [Diplomarbeit im Fach Geophysik]. Univ. Bremen, Germany.

Hine, H., and Weaver, P.P.E., 1998. Quaternary. In Bown, P.R. (Ed.), Calcareous Nannofossil Biostratigraphy: Dor-drecht, The Netherlands (Kluwer Academic Publ.), 266–283.

Holtz, R.D., and Kovacs, W.D., 1981. An Introduction to Geo-technical Engineering: Englewood Cliffs, NJ (Prentice-Hall).

Kelemen, P.B., Kikawa, E., Miller, D.J., et al., 2004. Proc. ODP, Init. Repts., 209 [CD-ROM]. Available from: Ocean Drilling Program, Texas A&M University, College Sta-tion TX 77845-9547, USA. [HTML]

Kennett, J.P., and Huddlestun, P., 1972. Late Pleistocene paleoclimatology, foraminiferal biostratigraphy, and tephrochronology, western Gulf of Mexico. Quat. Res., 2:38–69. doi:10.1016/0033-5894(72)90004-X

Kent, D.V., 1982. Apparent correlation of paleomagnetic intensity and climatic records in deep-sea sediments. Nature (London, U. K.), 299:538–539. doi:10.1038/299538a0

Kimura, G., Silver, E.A., Blum, P., et al., 1997. Proc. ODP, Init. Repts., 170: College Station, TX (Ocean Drilling Pro-gram). [HTML]

Kristiansen, J.I., 1982. The transient cylindrical probe method for determination of thermal parameters of earth materials [Ph.D. dissert.]. Åarhus Univ.

Mackenzie, K.V., 1981. Nine-term equation for sound speed in the oceans. J. Acoust. Soc. Am., 70:807–812. doi:10.1121/1.386920

Martin, R.E., Johnson, G.W., Neff, E.D., and Krantz, D.W., 1990. Quaternary planktonic foraminiferal assemblage zones of the northeast Gulf of Mexico, Columbia basin (Caribbean Sea), and tropical Atlantic Ocean: graphic correlation of microfossil and oxygen isotope datums. Paleoceanography, 5:531–555.

Martini, E., 1971. Standard Tertiary and Quaternary calcar-eous nannoplankton zonation. In Fainacci, A. (Ed.),

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Martini, E., and Müller, C., 1986. Current Tertiary and Quaternary calcareous nannoplankton stratigraphy and correlations. Newsl. Stratigr., 16:99–112.

Mazzullo, J., and Graham, A.G. (Eds.), 1988. Handbook for shipboard sedimentologists. ODP Tech. Note, 8.

Mikada, H., Becker, K., Moore, J.C., Klaus, A., et al., 2002. Proc. ODP, Init. Repts., 196 [CD-ROM]. Available from: Ocean Drilling Program, Texas A&M University, College Station TX 77845-9547, USA. [HTML]

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O’Brien, P.E., Cooper, A.K., Richter, C., et al., 2001. Proc. ODP, Init. Repts., 188 [CD-ROM]. Available from: Ocean Drilling Program, Texas A&M University, College Sta-tion TX 77845-9547, USA. [HTML]

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Tréhu, A.M., Bohrmann, G., Rack, F.R., Torres, M.E., et al., 2003. Proc. ODP, Init. Repts., 204 [CD-ROM]. Available from: Ocean Drilling Program, Texas A&M University, College Station TX 77845-9547, USA. [HTML]

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Figure F1. Grain size classification of Wentworth (1922).

1/2

1/4

1/8

1/16

1/32

1/64

1/128

1/256

2.00

1.00

0.50

0.25

0.125

0.0625

0.031

0.0156

0.0078

0.0039

0.00006

15.6

-12.0

-8.0

-6.0

-2.0

-1.0

0.0

1.0

2.0

3.0

4.0

5.0

6.0

7.0

8.0

14.0

Boulder

Cobble

Pebble

Granule

Very coarse sand

Coarse sand

Medium sand

Fine sand

Very fine sand

Coarse silt

Medium silt

Fine silt

Very fine silt

Gra

vel

San

dS

ilt

Clay

Millimeters (mm) Micrometers (µm) Phi (φ) Wentworth size class

4096

256

64

4

Mud

63

500

250

125

31

7.8

3.9

0.06

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Figure F2. Ternary diagram for naming siliciclastic sediments, modified from Shepard (1954).

75 75

75

Sand Silt

Clay

Clay

SiltSandSandy

siltSiltysand

Mud

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Figure F3. Example of visual core description (VCD) form. IW = interstitial water, WHC = whole-round coresample.

Date: June 10, 2005 03:28:46Described By:Water Depth: 1480.40 m Rig Floor to Sea Level: 10.40 mLeg 308 Site 1320 Hole A Core 3H [describe, depth unit (mbsf)]

16

18

20

22

ME

TE

RS

12

34

56

78

SE

CT

ION

claysilt

vfmcv

sandgranulepebblecobble

STR

UC

TUR

E

AC

CE

SS

OR

IES

ICH

NO

.

FO

SS

ILS

DIS

TU

RB

.IW

IW WHCWHC

SA

MP

LE

MAJOR LITHOLOGY: SANDFine lower to fine upper,massive brown sand,commonly with fining upwardtops. Plant/woody debris,mud clasts, and shellfragments are common.Interpreted to be turbiditesands.

MINOR LITHOLOGY: MUDHighly bioturbated, greenishgray mud.

Interpreted to be successionof turbidite deposits, eachwith massive sands at the base and finer grained mudat the tops.

DESCRIPTION

Site 1320 Hole A Core 3H Cored 14.0-23.5 mbsf

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Figure F4. Legend for symbols used in the visual core description forms.

LEGEND

LITHOLOGY

Sand or sandstone

Silty sand

Silt or siltstone

Sandy silt

Mud

Clay or claystone

Gravel

Conglomerate

Breccia

Lost core

CONTACTS

Sharp Erosional Bioturbated

Uncertain Inclined

SEDIMENTARY STRUCTURES

Cross lamination Climbing ripples

Lenticular bedding Convolute bedding

Chaotic bedding

Graded bedding Reverse-graded bedding

Planar lamination

Contorted bedding Load cast

Massive bedding

LITHOLOGIC ACCESSORIES

Sand lamina Silt lamina Shale lamina

Calcareous Ash layer

Rip-up clastsWood fragments Mottled

Nodule/Concretion Mud clasts

ICHNOFOSSILS

Undefined burrow Bioturbation

FOSSILS

Foraminifers (undifferentiated) Shell fragmentsPlant remains

FRACTURES

Fracture, general Extension fracture Clastic intrusion

Shear fracture

CORE DISTURBANCE

Slightly disturbed Moderately disturbed Very disturbed

Soupy Slightly fractured Moderately fractured

Highly fractured Drilling breccia Gas expansion

Biscuit Extreme disturbance

Benthic foraminifers

Pyrite concretion

Fining upward

Planktonic foraminifers

Silt-filled burrow

Black shale lamina

Pelecypods

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Figure F5. Chronostratigraphy of Berggren et al. (1995) showing the correlation of planktonic foraminifer (PF;blue) and nannofossil (N; green) zones and species datum levels. FO = first occurrence, LO = last occurrence.

Pt1a

Pt1b

NN21

NN20

NN19

C1n Bru

nhes

Ple

isto

cene

late

mid

dle

early

Sta

ge

Pol

arity

Chr

on

Cal

abria

n

Epo

ch

Planktonicforaminifer

zone

Calcareousnannofossil zone

FO N: Emiliania huxleyi (0.26)

LO N: Pseudoemiliania lacunosa (0.46)**

FO N: Gephyrocapsa lumina (1.67)

LO N: Calcidiscus macintyrei (1.59)

LO N: small Gephyrocapsa spp. Acme Zone (1.0)

FO N: small Gephyrocapsa spp. Acme Zone (1.0-1.2)

FO N: medium Gephyrocapsa spp. (1.7)

LO PF: Globorotalia tosaensis (0.65)

FO N: Emiliania huxleyi acme (0.09)

Bioevent (Ma)Cande and Kent (1995)Berggren et al. (1995)

C1r

C2n

1

0

FO PF: Globorotalia truncatulinoides (1.77)

Mat

uyam

aCN15

CN

14

a

CN

13 b

Bukry(1973,1975)

b

Tim

e (M

a)Martini(1971)

LO PF: Globorotalia flexuosa (0.068)

FO PF: Globorotalia flexuosa (0.401)

LO N: Helicosphaera inversa (0.150)**

FO N: Helicosphaera inversa (0.48)

LO PF: Pulleniatina finalis (1.40)

2 LO N: Discoaster brouweri (1.95)

LO N: Helicosphaera selii (1.47)

(Takayama and Sato, 1987)**

LO PF: Globorotalia inflata (0.010-0.015)*

(Berggren et al., 1995)(Kennett and Huddlestun, 1972)*

Timescale

Berggren et al. (1995)

Martini and Müller

(1986)

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Figure F6. Acme intervals determined from Deep Sea Drilling Project (DSDP) Site 610 (Hole 610B). Graphsrefer to percentage relative abundance of nannoplankton species (after Hine and Weaver, 1998).

0 50 100 00 505050 100100100

0

200

E. huxleyi(%)

G. muellerae(%)

G. aperta(%)

G. caribbeanica(large and small)

(%)

QAZ1E. huxleyi

Acme Zone

Transitional

G. aperta

G. caribbeanica

0

50

100

150

Age

(ka

)

Zone

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Figure F7. Low-latitude oxygen isotopic stack for the late Quaternary, showing marine isotope stages (MIS)and events (Bassinot et al., 1994). Planktonic foraminifer assemblage zones and subzones as well as ash layers(stars) from the Gulf of Mexico are after Kennett and Huddlestun (1972), with boundary ages adjusted usinglow-latitude MIS events (Bassinot et al., 1994). Purple text stands for planktonic foraminifer datum and greentext stands for nannofossil datum.

Z

Y

X

W

V

Age

(ka

)

1

2

3

4

5

6

7

MIS

QAZ1

QA

Z2 A

CB

Emiliania huxleyi acme (90 ka)

Globorotalia flexuosa (68 ka)??

Helicosphaera inversa (150 ka)?

? Globorotalia inflata (10 ka)

ash

84 ka

Pl. foramzone

Datum0

50

100

150

200

2 1 0 -1 -2

Gulf of Mexico late Quaternary isotope biostratigraphy

2.2

3.1

3.3

4.2

5d

5a

5c

5e6.2

7.2

7.4

7.1

7.3

5b

Low-latitude stack(δ18O‰)

Y3

Y2

Y8

Y7

Y6Y5Y4

Y1

X3

X2

X5X4

X1

W2

W1

1016

100

83

70

57

4842

24

180

90

110

150

129124120

Age(ka)

Nannofossilzone

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Figure F8. Core flow chart in the core laboratory. MST = multisensor track: GRA = gamma ray attenuation(density), PWL = P-wave logger (velocity), MSL = magnetic susceptibility logger, NCR = noncontact resistivity.MAD = moisture and density.

Core into lab

Equilibrate core to ambient temperature (~17°C)

MST(GRA, PWL, MSL, NCR)

Thermal conductivity

Split core to archive halfand working half

P-wave velocity, vane shearand pocket penetrometer

Sampling (10 cm3 core plug)

MAD

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Figure F9. Definition of axis orientation on working-half sections. The z-axis is positive in the downholedirection of the core orientation.

zx

y

Up

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Figure F10. Diagram of the temperature/dual pressure (T2P) probe. A. T2P probe with narrow, straight needleshaft. B. T2P probe with narrow, tapered needle shaft.

Drive tube2R2 = 36

223

1256

11.20

182

Thermistor

Pressure port

All dimensions in mm

2R1 = 6

2R3 = 6

2756

Data acquisition housing2R4 = 105

1182

223

1256

11.20

182

2R1 = 6

2R3 = 9

2756

1182

Needle probe

A B

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Figure F11. Configuration of the drill string used for logging-while-drilling (LWD) operations. VDN = VisionNeutron Density tool, PowerPulse = Measurement-While-Drilling tool, ARC = Array Resistivity Compensatedtool, and GVR = GeoVision Resistivity tool.

GVR

ARC

PowerPulse

VDN

17.1 cm (6-3/4 in)

25.1 cm (9-7/8 in)

25.76

19.66

10.52

4.42

Distanceabove bit (m)

0.34

0.00

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Figure F12. Schematic figure of rig instrumentation. DWOB = downhole weight on bit, DTOR = downholeweight on torque, APWD = annular pressure while drilling, ECD = equivalent circulating density, TEMP = tem-perature.

Bit acceleration

Ship heave Midshipaccelerometer

Dead-lineload cell

Heave compensatorposition

Crown blockload cell

Surface-drillingparameter

DWOB, DTOR,APWD, ECD,

TEMP parameters

Pulseddata

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Figure F13. Schematic illustration of the GeoVision Resistivity (GVR) tool. BS = button resistivity shallow, BM= button resistivity medium, BD = button resistivity deep, RING = ring resistivity, GR = gamma radiation.

61.5 cm

BS

BM

BD

48.8 cm

31.0 cm

Ring

15.2 cm

22.1 cm

GR

GeoVision Resistivity (GVR) tool

Resistivity measurement specificationsAccuracy: ~5% Range: 0.2 - 250 ΩmVertical resolution RES_BIT: 31 - 61 cm RES_RING: 8 - 10 cm RES_BS: 5 - 8 cm RES_BM: 5 - 8 cm RES_BD: 5 - 8 cmDepth of investigation RES_BIT: 81 cm RES_RING: 56 - 64 cm RES_BS: 48 - 61 cm RES_BM: 38 - 53 cm RES_BD: 28 - 41 cm

Gamma ray measurement specificationsAccuracy: ±7% Range: 0 - 250 gAPIStatistical repeatability: ±2% 1 @ 100 gAPI, 30 m/h with 46 cm averaging

3.1 m

0.0 m

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Figure F14. Schematic illustration of the Array Resistivity Compensated (ARC) tool.

5.5 m

3.3 m

2.2 m

2.1 m

Gamma ray measure point

Resistivity measure point

Read-out port

Resistivity measurement specificationsAccuracy: ~2% Range: 0.2 - 60 ΩmVertical resolution: 21 - 31 cmDepth of investigation: 33 - 76 cm

Gamma ray measurement specificationsAccuracy: ~3% Range: 0 - 250 gAPIVertical resolution: 15 cmStatistical repeatability: ±2 at 100 gAPI and 30 m/h 3-pt average

Array Resistivity Compensated (ARC) tool

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Figure F15. Schematic illustration of the MWD PowerPulse tool.

PowerPulse tool

1.3 m

0.9 m

1.8 m

Vibrational chassismeasuring

point

1.7 m

2.4 m

8.4 m

Weight/Torque measuring point

Directional inclination measuring point

Gamma ray measuring point

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Figure F16. Schematic illustration of the MWD operation method. Drilling fluids are constantly pumpeddown the drill string, and periodic closure of the MWD valve creates pressure pulses that can be detected onthe rig floor.

Open Closed

Time

Pressure

0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0

Mud pressure

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Figure F17. Schematic illustration of the Vision Density Neutron tool. PEF = photoelectric factor.

Vision Density Neutron (VDN) tool

Density measurement specificationsAccuracy: 0.015 g/cm3 Range: 1.7 - 3.05 g/cm3

Vertical resolution: 15.2 cmStatistics @ 60 m/h: ± 0.008 g/cm3

Neutron porosity measurement specificationsAccuracy: 5% Vertical resolution: 31 cmStatistics @ 60 m/h: ±2.5 pu

PEF measurement specificationsAccuracy: 5% Vertical resolution: 5 cmStatistics @ 3 units: ± 0.35 units

Distance fromtool bottom (m)

Diameter

6-3/4 in.

9-5/8 in.Clamp-onstabilizer

7.3 in.Wearband Batteries

6.02

4.28 Neutron detectors (far)

4.12 Neutron detectors (near)

3.82 Neutron source

3.39 Gamma source

3.26 Gamma detector (short)

3.16 Gamma detector (long)

2.78 Ultrasonic measurement point

2.22 Read-out port

0.00

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Figure F18. Configuration of the tool strings used for wireline logging operations. See Tables T3 and T4 fornames of tool strings.

FMS-Sonic

31.1 m

0 m

Triple combo with QSST Well Seismic Tool

0.0 m

6.74 m

0 m

31 m

Cablehead

Hydraulicclamping

arms

Cablehead

Telemetry catridges

SGTScintillation

Gamma Ray Tool

DSI

FMSFormation

MicroScanner

Dipole SonicImager

GPITGeneral PurposeInclinometer Tool

FormationMicroScanner

(cartridge)

Centralizer

Centralizer

Cablehead

Telemetry catridge

HNGSHostile EnvironmentGamma Ray Sonde

APSAccelerator

Porosity Sonde

HLDTHostile Environment

Litho-Density Tool

TAPTemperature/Acceleration/Pressure tool

DITDual Induction Tool

QSSTInline Checkshot

Tool

Caliper

NPLC

ILD-EEccentralizer

Nuclear PorosityLithology Cartridge

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Table T1. Acronyms and units used for wireline logging tools.

Table T2. Correction factors for GVR tool.

Note: NA = not applicable.

Tool Output Tool name/Data point description Unit

VDN VISION Density NeutronTNPH Thermal neutron porosity %IDRO Image derived density g/cm3

RHOB (L,R,U,B) Bulk density (left, right, up, bottom) g/cm3

IDDR Image derived density correction g/cm3

DRHO (L,R,U,B) Bulk density correction (left, right, up, bottom) g/cm3

DCAV Density caliper inchIDPE Image-derived photoelectric factor —PE (L,R,U,B) Photoelectric factor (left, right, up, bottom) —

PowerPulse PowerPulseDTOR_RT Real-time downhole torque kft·lbDWOB_RT Real-time downhole weight on bit klbfVIBTOR_RT Real-time downhole torque ft/lbTRPM_RT Real-time powerpulse turbine rpm rpmSHKPK_RT Real-time powerpulse peak shock GSHKRSK_RT Real-time powerpulse shock risk —STICK_RT Real-time powerpulse peak to peak collar RPM Variation rpmCRPM_RT Real-time powerpulse collar RPM rpm

ARC Array Resistivity CompensatedGR_ARC_UNC ARC uncorrected gamma ray gAPIPxxB ARC blended phase resistivity xx inches ΩmAxxB ARC blended attenuation resistivity xx inches ΩmPxxH ARC phase resistivity xx inches at 2 MHz ΩmAxxH ARC attenuation resistivity xx inches at 2 MHz ΩmPxxL ARC phase resistivity xx inches at 400 kHz ΩmAxxL ARC attenuation resistivity xx inches at 400 kHz ΩmAPRS ARC annulus pressure psiATMP ARC annulus temperature °CECD_ARC ARC equivalent circulating density ppg

GVR GeoVISION ResistivityGR_RAB GVR gamma ray gAPIRES_BS GVR shallow button resistivity ΩmRES_BM GVR medium button resistivity ΩmRES_BD GVR deep button resistivity ΩmRES_RING GVR ring resistivity ΩmRES_BIT GVR bit resistivity ΩmRPM_RAB GVR rotational speed rpmAAI GVR angular acceleration indicator —

Measurement

Correction factor (%)

Resistivity-at-the-bit 3Ring resistivity 1Deep resistivity 2Medium resistivity 4Shallow resistivity NA

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Table T3. Measurements made by wireline tool strings.

Notes: All tool and tool string names presented in this table are trademarks of Schlumberger. For the complete list of acronyms used in the IODPand for additional information consult IODP Downhole Logging Tools at iodp.ldeo.columbia.edu/TOOLS_LABS/tools.html. See Table T4,for explanation of acronyms used to describe tool string and tools. NA = not applicable.

Tool string Tool Measurement

Sampling interval

(cm)

Approximate vertical

resolution (cm)

Triple combination QSST Inline check shot TD – tool string lengthHNGS Spectral gamma ray/Total gamma ray 15 51APS Porosity 5 and 15 43HLDS/HLDT Bulk density, photoelectric factor 2.5 and 15 38/46DIT Resistivity, spontaneous potential 15 61TAP Temperature, pressure 1 per second NA

Formation MicroScanner(FMS)-sonic combination

DSI Acoustic velocity 15 107SGT Total gamma ray 15 46GPIT Tool orientation 0.25 and 15 NAFMS Microresitivity imaging 0.25 0.5

Well Seismic Tool (stationary) WST Sonic traveltime Variable NA

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Table T4. Acronyms and units used for wireline logging tools.

Notes: All tool and tool string names (except the TAP and MGT) are trademarks of Schlumberger. For the complete list of acronyms used in theIODP and for additional information about tool physics and use consult IODP Downhole Logging Tools at iodp.ldeo.columbia.edu/TOOLS_LABS/tools.html.

Tool Output Tool name/Explanation of output Unit

APS Accelerator Porosity SondeAPLC Near array porosity (limestone calibrated) %SIGF Formation capture cross section (Σf) Capture unitsSTOF Tool standoff (distance from borehole wall) in

DIT Dual Induction ToolIDPH Deep induction resistivity ΩmIMPH Medium induction resistivity ΩmSFLU Spherically focused resistivity Ωm

DSI Dipole Sonic ImagerDTCO Compressional wave delay time (∆t) ms/ftDTSM Shear wave delay time (∆t) ms/ftDTST Stoneley wave delay time (∆t) ms/ft

FMS Formation MicroScannerC1, C2 Orthogonal hole diameters inchP1AZ Pad 1 azimuth Degrees

Spatially oriented resistivity images of borehole wall

GPIT General Purpose Inclinometer ToolDEVI Hole deviation DegreesHAZI Hole azimuth DegreesFx, Fy, Fz Earth’s magnetic field (three orthogonal components) OerstedAx, Ay, Az Acceleration (three orthogonal components) m/s2

HLDT Hostile Environment Litho-Density ToolRHOB Bulk density (corrected) g/cm3

PEF Photoelectric effect b/e–

CALI Caliper (measure of borehole diameter) inchDRHO Bulk density correction g/cm3

HNGS Hostile Environment Gamma Ray SondeHSGR Standard (total) gamma ray gAPIHCGR Computed gamma ray (HSGR minus uranium contribution) gAPIHFK Potassium wt%HTHO Thorium ppmHURA Uranium ppm

QSST Inline Check shot Tool

SGT Scintillation Gamma Ray ToolECGR Environmentally corrected gamma ray gAPI

TAP Temperature/Acceleration/Pressure tool °C, m/s2, psi

WST Well Seismic ToolAcoustic arrival times ms

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