microfacies analysis and sequence stratigraphy of eocene

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MINISTRY OF HIGHER EDUCATION AND SCIENTIFIC RESEARCH UNIVERSITY OF BAGHDAD COLLEGE OF SCIENCE MICROFACIES ANALYSIS AND SEQUENCE STRATIGRAPHY OF EOCENE -MIOCENE SUCCESSTION AT KARBALA NAJAF SAMAWA AREA SOUTH WEST IRAQ A THESIS SUBMITTED TO THE COLLEGE OF SCIENCE UNIVERSITY OF BAGHDAD IN PARTIAL FULFILLMENT OF THE REQUIREMENT FOR THE DEGREE OF MASTER OF SCIENCE IN GEOLOGY BY DHIYA KHURBAT SHATHER B.Sc. IN GEOLOGY (1994) SUPERVISED BY Asst. Prof. LAMEES SADIQ HASSOUN 2011

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Page 1: MICROFACIES ANALYSIS AND SEQUENCE STRATIGRAPHY OF EOCENE

MINISTRY OF HIGHER EDUCATION

AND SCIENTIFIC RESEARCH

UNIVERSITY OF BAGHDAD

COLLEGE OF SCIENCE

MICROFACIES ANALYSIS AND

SEQUENCE STRATIGRAPHY OF

EOCENE -MIOCENE SUCCESSTION AT

KARBALA – NAJAF – SAMAWA AREA

SOUTH WEST IRAQ

A THESIS SUBMITTED TO THE COLLEGE OF SCIENCE

UNIVERSITY OF BAGHDAD IN PARTIAL FULFILLMENT

OF THE REQUIREMENT FOR THE DEGREE OF

MASTER OF SCIENCE IN GEOLOGY

BY

DHIYA KHURBAT SHATHER B.Sc. IN GEOLOGY (1994)

SUPERVISED BY

Asst. Prof. LAMEES SADIQ HASSOUN

2011

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The Supervisor Certification

I certify that this thesis (Microfacies Analysis and Sequence Stratigraphy of

Eocene –Miocene succession at Karbala-Najaf-Samawa area south west

Iraq),was prepared under my supervision at the Department of Geology, College

of Science , University of Baghdad, in partial fulfillment of the requirements for

the Degree of Master of Science in Geology (Stratigraphy and Paleontology).

Signature:

Name: Lamees Sadiq Taha

Scientific Degree: Assistant Professor

Address: Department of Geology

College of Science University of Baghdad

Date: / /2011

Recommendation of the Head of Committee of Postgraduate Studies in the

Department of Geology

In view of the available recommendations I forward this thesis for debate by the

examining committee.

Signature:

Name: Dr. Ahmad Shehab Al - Banna

Title: Professor

Address: University of Baghdad (Head of the Department of Geology)

Date: / /2011

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Committee Certification

We certify that we have read this thesis entitled (Microfacies Analysis

and Sequence Stratigraphy of Eocene –Miocene succession at Karbala-Najaf-

Samawa area south west Iraq), and as the examination committee examined the

student in its content and in our opinion it is adequate for award of the degree of

Master Geology Master of Science in Geology (Stratigraphy and Paleontology).

Chief Signature:

Name: Saad S. Al- Sheikhly

Title: Professor

Address: Department of Geology

College of Science University of Baghdad

Date: / 11 / 2011

Member

Member Signature: Signature:

Name: Rafah Tariq Ismail Name: Saad S. Al- Jumaily

Title: Assistant Professor Title: Assistant Professor

Address: Department of Geology Address: Department of

Geology College

College of Science University of Baghdad of Science University of Baghdad

Date: / 11 / 2011 Date: / 11 / 2011

Approved by the Deanery of the College of Science.

Signature:

Name:

Title:

Address:

Date:

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بسم الله الرحمن الرحيم

ق ل سيروا في الأرض ف انظروا

عى ثم الله ينشى النشأة الآخرة أن الله قكيف بدأ الخل كل شيء قدير

دق الله اللظيم

/20)سورة اللنكبوت(

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Acknowledgements

I am gratefully indebted to my supervisor Asst. Prof Lamees

Sadiq Hassoun for her supervision , guidance , help and reading

the manuscript.

Thanks are also due to the Department of Geology , College of

Science , Baghdad University for providing the opportunity and

facilities for the present study.

Im greatly indebted to the State Company of Geological Survey

and Mining for offering me the opportunity to study for the master

level with special thanks to the D.G.Dr.Khaldoun S. Al-Bassam .

I extend my sincere thanks and appreciation to Prof . Dr.Ali ,

D.Gayara

I also owe many thanks to Dr.Buthaina Salman (senior chief

geologist) for her help in this thesis , Mr.Dhiya Aldeen Kadhim ,Mr.

Mohamed Karim and Mr. Ahmed khalil for their help during The

field work.

Thanks and appreciation to all my family who expressed

supports , love and care .

DHIYA

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ABSTRACT

The Eocene – Miocene succession in the southwest desert of Iraq revealed the

presence of the Dammam , Euphrates and Nfayil Formations . Two hundred and

thirty nine of thin sections from three boreholes and two outcrops have undergone

detailed petrographic identification and used to build both stratigraphic and

diagenetic models .

Microfacies characteristics of the whole successions showed the presence of

skeletal and non-skeletal grains within the Nfayil and Euphrates Formations.

Only skeletal grains are observed in the Dammam formation .

Details gained from textural and faunal properties helped in the designation of

microfacies zones leading to environmental subdivisions for a suggested ramp .For

the Nfayil formation : peritidal , shoal , restricted , and deep marine environments .

For the Euphrates formation : restricted , shoal , open marine , and deep marine

environments .For the Dammam formation : peritidal , restricted , shoal , and open

marine environments.

Generally the diagenetic model of the three sections showed two dolomitization

episodes . The first dolomitized the lower part of the Dammam Formation , by a

subtidal model , considering the crystal sizes and the maintenance of the original

textures of deposition . The top of the Dammam Formation probably persisted

longer in the mixing zone due to high stand conditions at the end of the Eocene

until the second episode of dolomitization . For the Euphrates and Nfayil

Formations . The absence of dolomite is due to the fast rising sea – level after the

Oligocene break ( above basal conglomerate) . Silicification sometimes

accompanied the dolomitization .

Neomorphism in addition to different types of cement , in the Dammam

Formation occurred at Karbala and Samawa sections , suggesting an active

freshwater zone of diagenesis due to the rising sea level . For the Euphrates and

Nfayil Formations , neomorphism and cement occurred too.

Dedolomitization may be due to the presence of many aquifers known in the

Dammam Formation at Najaf and Samawa sections.

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Five 3rd

order cycles were designed for the Dammam succession at Samawa

section, minor fluctuations during the four cycle divided it into two 4th order ones .

At Najaf section another cycle was recognized . At Karbala section , the first two

cycles may not be encountered . Cycles represented episodes of sea-level rises(

represented by shallow open marine and deep marine facies) followed still stand

represented by shoal facies .

An (SB1) boundary occurs between the Euphrates Formation and the Dammam

Formation . It is a basal conglomerate , with different thicknesses : 0.8 meter at

Karbala section , 4.0 meter at Najaf and Samawa sections.

During sea-level rise after the Oligocene , three 3rd

order cycles were designed

for the three sections .These cycle are different in their symmetry , thickness and

stacking pattern from one section to the other . This may be attributed to local

changes in tectonic subsidence which have affected the velocity of relative sea-

level rise .

In the current study the Miogypsina sp.(index fossil of the Euphrates Formation)

is found above the olive green marl unite of the lower part of the Nfayil Formation.

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1.1 preface ………………………………………………………………………. …. 1

1.2 Location of study area ……………………………………………………….1

1.3 Aim of the study ………………………………………………………............1

1.4 Methodology …………………………………………………………..………4

1.4.1 Field work ……………………………………………….…..……….4

1.4.1.1. Samawa composite section …………………….....…..4

1.4.1.2 Najaf composite section ……………………………..…..…..……4

1.4.1.3 Karbala borehole section ……………………………………….……..5

1.4.2 Workshop ……………………………………. …………….……..…….5

1.4.2.1 Thin section preparing …………………………….………….…….5

1.4.2.2 Staining……………………………………………………….…..……..5

1.5 Previous study …………………………………………………….……..……….5

1.5.1 Nfayil Formation ………………………………………….………....5

1.5.2 Euphrates Formation ………………………………………..……….. .7

1.5.3 Dammam Formation …………………………………………..………..8

1.6 Geological setting ………………………………………………………….…..……13

Chapter One : INTRODUCTION

Contents

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2.1 Petrography………………………………………………………………………………..14

2.1.1 preface…………………………………………………………………………………14

2.1.2 Nfayil Formation………………………………………………………………..14

2.1.2.1 Skeletal grains …………………………………………………….15

2.1.2.2 Non- Skeletal grains …………………….………………………………...16

2.1.3 Euphrates Formation ………………………………………………….……….17

2.1.3.1 Skeletal grains……………………………………………………………. 18

2.1.3.2 Non-skeletal grains ………………………………………………..……..19

2.1.4 Dammam Formation ……………………………………………………………19

2.1.4.1 Skeletal grains ……………………………………………………………..20

2.2 Diagenetic Processess ………………………………………………………………….27

2.2.1 Cementation ……………………………………………………………………….27

2.2. 1.1 Syntaxial rim overgrowth ………………………………………..…..……28

2.2.1.2 Geopetal cement ………………………………………….……..…………..28

2.2.1.3 Intraparticle cement ……………………………………..…….…………28

2.2.1.4 Interparticle cement ……………………………………..………………29

2.2.2 Silicification ……………………………………………………………………….29

2.2.3 Dolomitization ……………………………………………………………………30

2.2.4 Dedolomitization …………………………………………………………….31

Chapter Two : PETROGRAPHY AND DIAGENESIS

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2.2.5 Neomorphism …………………………………………………………..……..32

2.2.6 Dissolution…………………………………………………………………..……32

2.2.6.1 Intraparticle porosity …………………………………………..……….33

2.2.6.2 Moldic porosity ………………………………………………….………33

2.2.6.3 Vugy porosity …………………………………………………….………34

2.2.6.4 Channel porosity …………………………………………………….……34

3.1 Preface ……………………………………………………………………………….43

3.2 Nfayil Formation ……………………………………………………………………..43

3.2.1 Peritidal Environment ……………………………………………..……43

3.2.2 Shoal Environment ………………………………………………………44

3.2.3 Restricted Environment …………………………………………...……45

4.2.4 Deep Environment ……………………………………………….…..…..45

3.3 Euphrates Formation ………………………………………………………...…...46

3.3.1 Restricted Environment ……………………………………….……….46

3.3.2 Shoal Environment ……………………………………………….…….46

3.3.3 Open marine Environment ……………………………………….….……46

3.3.4 Deep Environment ………………………………………………..…….47

3.4 Dammam Formation ……………………………………………………….….…….48

3.4.1 Shoal Environment ……………………………………………….…..…..48

3.4.2 Restricted Environment ……………………………………….……..…..49

3.4.3 Open marine Environment …………………………………………………49

Chapter Three : MICROFACIES AND ENVIRONMENTS

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3.4.4 Peritidal Environment ………………………………………..…….………50

4.1 Contacts…………………………………………………………………….…….56

4.1.1 Lower contact of the Dammam Formation ………………………….…….56

4.1.2 Lower contact of the Euphrates Formation……………..…………….……56

4.1.3 Nfayil Formation contacts ………………..……………………………….…56

4..1.3.1 Lower contact of the Nfayil Formation……………...…… ….….56

4.1.3.2 Upper contact of the Nfayil Formation ……………...……….57

4.2 Sequence Stratigraphy ……………………………………………………………..58

4.2.1 preface ………………………………………………………………………58

4.2.2 Concept and Definition………………………………………………………..58 4.2.2.1 Parasequence ……………………………………………………….……59

4.2.2.2 Key Surfaces ……………………………………………………..……60

4.2.2.2.A Sequence Boundaries ………………………………….……60

4.2.2.2.B Transgressive Surface (TS) …………………………………61

4.2.2.2.C Marine flooding surface……………………………………..61

4.2.2.2.D Maximum Flooding Surface (MFS)………………………....61

4.2.3 Sequence Development ………………………………………………….……62

4.2.3.1 Dammam Cycles ………………………………………………..………62

4.2.3.2 Euphrates-Nfayil cycles…………………..………………………….………63

Chapter Four: Sequence Stratigraphy

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4.2.4 Basin development in the Miocene …………………….………………..…..64

4.3 Diagenetic Model ………..…………………….…………………………….…66

Summary and Conclusions ………………………………………………………………..69

References …………………………………………………………………………………73

1.1 Location map of the study area …………………………………………………….…3

1.2 Stratigraphic correlation Eocene Formations …………………………………………11

1.3 Stratigraphic correlation Miocene Formations………………………………………12

2.1 Legend for figures 2.2 , 2.3 and 2.4 …………………………………………………...38

2.2 Distribution of Microfacies, Environments, Diagenetic processes and Sequence

stratigraphic subdivisions at Karbala section ………………………………………39

2.3 Distribution of Microfacies, Environments, Diagenetic processes and Sequence

stratigraphic subdivisions at Najaf section……………………………………...……40

2.4 Distribution of Microfacies, Environments, Diagenetic processes and Sequence

stratigraphic subdivisions at Samawa section……………………………………..…41

2.5 Chert layer and Alveolina sp. in the field………………………………………….…42

4.1 Sequence Stratigraphic subdivision of the Eocene –Miocene succession……. ……65

4.2 Diagenetic Model of Eocene –Miocene succession at Karbala-Najaf –Samawa sections..69

Chapter Five: SUMMARY AND CONCLUSIONS

Figures

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1.1 Geographic coordinates thickness and total samples of the selected sections

at the study area ……………………………………………………………………..…..2

Plate (1) Non-Skeletal grains……………………………………………………………22

Plate (2) Non –Skeletal grains…………………………………………………………..23

Plate (3) Skeletal grains……………………………………………………………………24

Plate (4) Skeletal grains…………………………………………………………………25

Plate (5) Skeletal grains………………………………………………………………..…..26

Plate (6) Diagenetic processess………………………………………………………....35

Plate (7) Diagenetic processess…………………………………………………………36

Plate (8) Diagenetic processes ………………………………………………….....37

Plate (9) Nfayil microfacies ………………………………………………………...51

Plate (10) Nfayil and Euphrates microfacies ……………………………………...52

Plate (11) Euphrates microfacies…………………………………………………….53

Plate (12) Dammam microfacies……………………………………………………....54

Plate (13) Dammam microfacies………………………………………………….55

Table

Plates

Chapter Two

Chapter Three

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CHAPTER ONE

INTRODUCTION

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CHAPTER ONE INTRODUCTION

1.1 Preface:

The Eocene-Miocene succession in Karbala- Najaf- Samawa area south west

Iraq is represented by Dammam, Euphrates, and Nfayil Formations. Some of these

are regarded as a source of limestone for cement factory, such as Euphrates

Formation, and a good water aquifer such as the Dammam Formation .

1.2. Location of study area

The study area is located within the Karbala , Najaf and Samawa Governorates

in South west Iraq ( Table 1.1 , Fig.1.1)

1.3. Aim of the study:

The aim of the study is to investigate the Eocene-Miocene succession in

Karbala-Najaf-Samawa area from the following aspects:

1- Detailed microfacies analysis and depositional environment interpretation aimed

to better understanding of the formations.

2-Fossil identification to assist age determination and environment

characterization.

3- Designing depositional and diagenetic models .

4- Sequence stratigraphic interpretation and basin analysis.

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Table (1.1) Geographic coordinates , thicknesses and total samples of selected

Karbala –Najaf-Samawa at the study area

Section Name

Geographic Coordinate

Total Samples

Latitude Longitude Thickness

Karbala borehole

Section

32° 34′ 05″

43° 29′ 21″

Nafyil Fn. 26.5m 11

75 Euphrates Fn. 22.4m 17

Dammam Fn. 51.5m 47

Najaf composite

Section

31° 27′ 26″

44° 28′ 48″

Nafyil Fn. 15.0m 11

87

Euphrates Fn. 7.5m 5

Dammam Fn. 97.5m 70

Rus Fn. 4.0 1

Samawa

composite Section

31° 14′ 53″

45° 04′ 52″

Nafyil Fn. 10.5 6

77 Euphrates Fn. 7.0m 3

Dammam Fn. 115.5m 67

Rus Fn. 3.5m 1

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1.4. Methodology and Study Area:

This study deals with three formations. Detailed description and sample

collection was carried on every noticeable change for the three studied formations ,

Dammam, Euphrates and Nfayil.

To achieve the goals of this study, two stages of work were performed. They

are :

1.4.1. Field work:

The field work included sampling of two composite sections (Najaf section

and Samawa section) , the third is Karbala borehole section (Fig 1.1).Selection of

samples from these sections was based on facies change , colour change ,hardness

of the beds and difference in other factors.

The studied composite sections and borehole sections were as follows

1.4.1.1. Samawa composite section

Samawa section is a composite section showing borehole (Euphrates and

Dammam Formations) located at (31° 14’ 53˝N) (45° 04’ 52˝ E) and an outcrop

showing Nfayil and Euphrates Formations . Total thickness is 137.0 meters .

Samples were selected from this composite section mostly of limestone ,marl

beds, in addition to some gypsum beds. Six samples are taken from the Nfayil

Formation, three samples from the Euphrates Formation, sixty seven samples from

the Dammam Formation and one sample from the Rus Formation .( Table 1-1).

1.4.1.2. Najaf composite section

Najaf section is a composite section showing borehole (Euphrates and Dammam

Formations) located at (31° 27’ 26˝ N) , (44° 28’ 48˝ E) and an outcrop

showing Nfayil and Euphrates Formations. Total thickness is 124.0 meters.

Samples selected from this composite section were mostly of limestone and marl

beds, in addition to samples from Rus Formation. Eleven samples are taken from

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the Nfayil Formation, five samples from the Euphrates Formation , seventy

samples from the Dammam Formation and one sample from the Rus Formation.

1.4.1.3. Karbala borehole section

Karbala borehole section is located (32° 34’ 05˝ N) , (43° 29’ 21˝ E) . Its

elevation is 56.5 meters with a total thickness of 100 meter.

Samples selected from borehole were mostly of limestone , clastic rocks and

marl beds. Eleven samples were taken from the Nfayil Formation , seventeen

samples from the Euphrates Formation, forty seven samples from the Dammam

Formation .

1.4.2. Workshop

The workshop included two stages .These are :

1.4.2.1 Thin section preparation

Two hundred and thirty nine thin sections were prepared at the state company

of Geological Survey and Mining . The thin sections were done for the Samawa

composite section and Najaf composite section. While the Karbala borehole thin

sections were previously prepared .

1.4.2.2 Staining

Distinction between calcite and dolomite minerals required staining process to

239 thin sections , for clear identification of diagenetic features specially

dedolomitization . The staining effects calcite (red colour) and dose not effect

dolomite.

1-5 Previous study

1-5-1 Nfayil Formation

The Formation type locality lies near the (Qariat Al-Nfayil) (Al-Nfayil village )

which is 23km , west of Haditha town.

This Formation was divided into two members (Sissakian,1999) .

1- The lower member consists of three cycles , each cycle consists of marl and

limestone. The marl is olive green, soft, papery or massive ,concoidally fractured,

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fractures are filled with secondary gypsum. The thickness of marl beds range from

(0.5- 5.0)m . The limestone is yellowish white to greenish grey, fractured, jointed,

locally undulated and deformed slightly oolitic, partly recrystallized and shelly

,shells are mainly pelecypods, gastropods, and Oysters . Oysters found only in the

second cycle and considered as good markers over the whole exposed area of the

Nfayil Formation.

2- The upper member is exposed in the extreme west part of the exposed area in

Al-Kherish vicinity along the Iraq-Syrian border. It consists of claystone and

limestone. The claystone is reddish ,bedded, and calcareous ,whereas the limestone

is pinkish with quartz grains , bedded and hard.

The top of the upper member is always capped by splintery limestone and very

hard in the type locality and ranges in thickness from (10.0-50.0)m.

The Nfayil Formation is deposited in shallow to very shallow marine

environment with normal to high saline water ,with clear oscillation in the sea

level. The upper part of the upper member may indicate near shore environment

,with some deltaic influences, as indicated by the type of the clastics, fining

upward of the uppermost part of the Nfayil Formation ,(Sissakian,1999).

Other author’s opinion about the Nfayil Formation position are as follows:-

1-Al-Mubarak,(1972) named the sequence (unit c) of the Euphrates Formation in

Al-Qaim vicinity.

2- Al-Jumaily,(1974) named the sequence as (the unit B) of the second Miocene

sedimentary cycle .

3- Tyracek and Youbert ,(1975) adopted the same terminology in Haditha, as that

of Al- Jumaily .

4- Hamza ,( 1975 ) named the sequence as (unit of alternating limestone and green

marl ).

5- Al-Mubark and Amin,(1983) named the sequence as (unit C) of the Euphrates

Formation in west of Najaf and Karbala vicinities.

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6- Jassim et .al.,(1981) named the sequence with the overlying sediments as

(Kherish Beds) and (Najaf and Habbanya Beds).

7- Mahdi et .al .(1986) named the sequence as (Nfayil unit ) in Haditha .

8- Sissakian and Salih ,(1994) named the upper member as (Nfayil member ) of the

Fatha Formation in Haditha vicinity .

The age of the Nfyail Formation according to the fossil assemblage is Middle

Miocene ,(Sissakian,1999).

The lower contact between the Nfayil Formation and the underlying Euphrates

Formation is conformable .

1.5.2. Euphrates Formation

The original description was given by Boeck (1929). It was later amended by

Bellen in 1957. The Formation 's type locality lies near wadi Fuhaimi Anah trough

on the stable shelf.

The Formation is composed at the type locality , of shelly , chalky , well-

bedded , recrystallized limestone ,(Van Bellen et . al ., in 1959) .

The thickness in the surrounding areas , as well as in the boreholes is usually

many times more , reaching to a maximum of 100.0 meters , with an average

thickness of around ( 60.0-70.0 ) meters , ( Buday,1980).

Ctyrocy and Karim ,(1971) , Al-Greri , (1985) made a very detailed evaluation

of the fauna and determined its age to be lower Miocene and early Middle

Miocene.

The Euphrates Formation was deposited under shallow marine –reef and

lagoonal conditions , with local coral and lithophyllid reef and with intermittently

occurring fore-reef condition , on the one side , and lagoonal condition on other

side , ( Buday,1980) .

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Al-Mubarak (1971) divided the formation into four units named A ,B ,C and

D, whereas Al-Mehaidi (1975), described this formation from outcrops between

Al-Razaza – Habanyia area and divided the formation into three member :-

A- Basal braccia member consist of fragmented Nummulitic limestone and chert .

B- Om Sufaya chalky limestone .

C- Limestone marl member.

Euphrates Formation overlies various formations all unconformably and with

thick conglomerate , near Anah and Haditha area the formation overlies Upper

Oligocene Anah Formation , in Khan Al-Baghdadi Area it overlies Lower

Oligocene Sheikh Alas Formation. In the southern desert , the Euphrates

Formation overlies various units of Dammam Formation ,(Buday,1980).

Near wadi Hauran , the Euphrates formation overlies Eocene , Oligocene ,

Lower Cretaceous and Jurassic sequence all with basal conglomerate

(Buday,1980).

The formation in Iraq is a facies equivalent to the Ghar ,Serikagni and Dhiban

Formations and has no other age and /or facies equivalents ,(Buday,1980),(Fig 1-

2).

1.5.3 Dammam Formation

The Dammam Formation in its type locality in Saudi Arabia was described by

Bramkamp (1931) in (Van Bellen et a., 1959) as a sequence of partly chalky and

organodetrital or dolomitic limestones , marl and shales , representing the Eocene

with no recorded intra formational break.

A supplementary type section from Zubair 3 oil well was chosen by Owen and

Nasr (1958) in (Van Bellen et al,. 1959) for the same formation represented by “

whitish grey ,porous dolomitized limestone ; limestones are sometimes chalky and

near the base a persistent grey green waxy shale body is encountered” .

Huber and Ramsdon (1945) in Van Bellen et al., (1959) divided the formation

into 10 informal unites for the convenience of field mapping ; their stratigraphical

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value as such , is limited . However later devision by Ramsdon and Andre in

(1953)Van Bellen et al ., (1959) introduced four unites as combinations of

previous ones these are from top :

1- Tiqiaiyid –Ghanimi – Barbak – Radhuma unit which is mainly characterized by

bryozoans and peneroplid limestones and shoal limestones.

2- Chabd – Shawiya –Huweimi ( a shoal Nummulites units) .

3- Huweimi ( chalk ) ,Shbicha and sharaf units .

4- Wagsa units.

Further work by Al- Hashimi(1972) led to the a assignment of the formation to

whole Eocene (lower Ypresian –Upper Eocene ) and subdivision of the formation

into four faunal benthonic foraminiferal zones and three planktonic zones in the

southern and western desert of Iraq . The same zonation was followed by the

paleontologists of GEOSURV during the evaluation of the Dammam Formation .

These zones from bottom to top are:

1-Nummulites desert - N. frassi zone .

Recorded from Akashat and Ratga sections,Wagsa unit.

2-Nummulites planulates - N. lacsanus zone .

Recorded in Akashat and Ratga section .

3-Nummulites discorpinus - N gizehensis zone .

4-Nummulites baullei – N.icrassatus zones .

Three planktonic zones were recognized from the western desert at these area

only:-

1- Globorotalia lehneri zone equivalent to N.discorbinus .

2-Truncorotaloides rohri zone .

3- Globorotalia cerroazulensis zone

So the Dammam Formation is restricted to Middle –Upper Eocene . The

formation has two close correlatives in Iraq : the Avanah Formation and the Pilaspi

Formation ,the first is almost of the same facies , and includes proved Upper

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Eocene beds too, the second correlative of the Dammam , is the Pilaspi Formation,

it differs from the Dammam by its facies, however it probably represents the

equivalent of the upper parts of the Dammam Formation only. The lower parts of

the Dammam Formation is contemporaneous with the Gercus Formation ,Buday

(1980). Figure (1.3)

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Figure (1.2) Stratigraphic correlation Miocene Formations (compiled according

Jassim and Goff , 2006)

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Figure (1.3) stratigraphic correlation Eocene Formations (compiled according to

Jassim and Goff , 2006 )

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1.6 Geological Setting

The studied area is located within the Southwest Desert .Tectonically , the

Southern Desert is a part the stable shelf of the Arabian platform , which is

characterized by the presence of block tectonics and the absence of tectonic folds (

Buday and Jassim , 1987 ). It is characterized by flat nature , due to almost

horizontal beds , with regional dip towards east and northeast . The Euphrates

Fault Zone with NW-SE trend is the main outstanding feature along the exterior

(northeastern ) part of the Southern Desert (Al-Amiri ,1979; Al-Ani and Ma'ala

,1983;Al-Hadithi and Al-Mehaidi,1983 ; Al-Mubarak and Amin,1983;Buday and

Jassim,1987) .

Straigraphically , the denudation processes have exposed a sequence of

marine and continental sediments , which range in age from Paleocene to

Pleistocene . The Paleogene rock units are shallow marine sediments ,which cover

most of the Southern Desert .The oldest formation , which is exposed along the

Iraqi- Saudi Arabian border , is Umm Erdhuma Formation .The carbonate facies of

this formation passes laterally to anhydrite facies of the Rus Formation .The

Dammam Formation of carbonate facies overly conformably forenamed two

formations .A gap exists between Eocene and Early Miocene rock units due to

missing of the Oligocene rock units (Al-Hashmi,1972 ;Al-Ani and Ma'ala ,1983 ,

Al-Hadithi and Al-Mehaidi,1983).

The Neogene rock units are expressed by shallow marine and continental

sediments . The former is represented by Euphrates, Ghar and Nfayil formations ,

whereas the Zahra and Dibdibba formations represent the latter.

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CHAPTER TWO

Petrography and

Diagenesis

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Petrography and Diagenesis Chapter Two

2.1 Petrography

2.1.1 Preface

The aim of this chapter is to diagnose the petrography characteristic of 239 thin

sections in order to delineate the depositional environment of the Eocene-Miocene

studied sections. Thin sections were classified on the bases of Dunham’s

classifications (1962) .Study reveals that the carbonate grains represented within

the Eocene-Miocene successions are both skeletal and non-skeletal grains. The

main components of the skeletal grains are benthonic foraminifera, Molluscs

(pelecypoda and gastropoda) ,algae,ostrcoda,while non-skeletal grains are

represented by peloids,Ooids , grapstone , and lithoclastes. The Eocene-Miocene

succession is represented in this study by the Nfayil Formation, Euphrates

Formation and Dammam Formation , each will be described separately .

2.1.2 Nfayil formation

Rhythmic cyclicity characterizes the Nfayil Formation in the field . At Karbala ,

two cycles are recorded for the lower Nfayil Formation ,each comprises green marl

and grey fossiliferous limestone . Three cycles were recognized at Najaf outcrop ,

they are from the bottom to the top : The first ( 4.0 meters thick ) consisted of

green marl alternating with thin beds of recrystallized limestone followed by grey

,tough, and fossiliferous limestone. The second (1.5 meters thick ) yellow -green

marl ,fissile , followed by (1.5 meters ) grey oyster bearing limestone , the oyster

bearing bed is a marker to the second cycle of the Nfayil Formation (previous

studies) . The third (3.0 meters) green marl , is followed by grey, tough , well –

bedded , fossiliferous limestone with yellow stains .At Samawa outcrop two cycles

are recognized from the bottom to the top . The first (1.0 meter thick) olive green

marl followed by 0.75 meter pink to creamy , soft limestone with rusty patches

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,also viens filled with secondary calcite .This is followed by 2.25 meters of

fossiliferous white , steep –forming cliff limestone , thinly bedded at its upper parts

. The second cycle is represented by marl followed by ( 4.0 meters thick ) , light

grey , fossiliferous limestone with secondary calcite filling , followed by 1.0 meter

yellow brown limestone , fossiliferous ,containing calcite viens . Limestone

interbedded with marly limestone is the capping unit of the lower Nfayil

Formation .

2.1.2.1 Skeletal grains

Benthonic foraminifera are found as whole tests in most of the studied thin

sections . Fragmented test are found at depth 10.0 meters at Najaf outcrop and at

depth 21.0 meters at Karbala section .

Benthonic foraminifera within the Nfayil Formation are : miliolid ,Dendiritina

sp. , rotalid , Ammonia beccarii (Plt 3.F) . At Samawa composite section miliolid

was profound from 1.5 – 2.5 meter .

Miogypsina sp.( Middle Oligocene- Early Miocene ) was recorded for the first

time within the lower part of the Nfayil Formation. at Karbala borehole section at

depth 25.0 meters , and at Samawa composite section at 9.0 meters below the top

of the outcrop.

Generally the last appearance of Miogypsina sp. is used to delineate the top of

the Euphrates Formation , but in the current study , the occurrence of Miogypsina

sp. is recorded at the lower part of the Nfayil Formation (Plt.3-C ) exactly above

the green marl unit both at Karbala and Samawa Sections , whereas no occurrence

recorded at Najaf section which may be due to neomorphism of the unit above the

green marl . It is important to denote that the green marl unit forms the contact

between Nfayil and Euphrates formation ( Sissakian,1999).

Molluscs represent the most dominant skeletal component within the Nfayil

Fomation , and found generally as shell fragments which resulted from the effect

of tides or currents activation or high energy environment .This occurs at 4.5-6.5

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meters from the outcrop at Najaf composite section and at 9.0 meters below the top

of the outcrop at Samawa section .Molluscs are recognized as whole shells at 8.75-

9.5 meters at Samawa composite section (Plt 3.B) , and at depth 20.5, 25.5 meters

at Karbala borehole section . At Karbala section , however , and because of

diagenetic processes the molluscans (Mainly pelecypods) are vanished and only

its moldic pore spaces at 25.0 meters are left . Oysters at the field are recognizable

by the naked eyes . There width reaches (3) centimeter differentiating the

limestone of the second cycles within the lower part of Nfayil formation . It may

also be as coquina , rare occurrence of algae (Dasycladacea ), Ostracoda , and

bioclasts (echinodermata fragments and shell fragments) are found in the Nfayil

Formation .

2.1.2.2 Non-skeletal grains

Non-skeletal grains within the Nfayil formation are peloids , lithoclasts and

ooids . Peloids are sand-sized grains with an average size of 100-200 micron,

composed of microcrystalline carbonate .They are generally rounded or

subrounded ,spherical, ellipsoidal to irregular in shape and are internally

structureless (Mckee and Gutshick,1969). Peloids were observed at depth 24.8

meter at Karbala section. while in the Samawa composite section, peloids are

found in the uppermost part of the formation at 2.0 meters from top of the outcrop,

whereas no occurrence recorded at Najaf section (Plt.2.C) . Lithoclasts are

millimeter-to centimeter-sized redoposited grains , intraclasts and extraclasts

(Folk,1959).

An intraclast is a carbonate fragment of lithified or partly lithified sediment,

derived form erosion of nearby penecontemporaneous sediment, from within the

basin and redepositied within the same area. An extraclast is a fragment of

carbonate rock derived from the erosion of an exposed ancient limestone on land

outside the depositional basin in which it is found (Flugel,2004).

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Lithoclasts are found as intraclast in intraclastic packstone-grainstone in

Najaf composite section at 4.5-5.5 meters from top of the outcrop(plt.1.C) .

Lithoclasts found as extraclast in extraclastic wackestone-packstone from top of

the outcrop down to 1.5 meters in Samawa composite section (plt.1.B) . This unit

is characterized by extraclasts of two types ,one is a silt-sized bearing quartz, the

other is diagenetically different , also with appreciable quantity of sand grains . Its

margins are oxidized (plt.1-F) .whereas, lithoclasts are found as intraclast in

intraclastic mudstone (plt.1.A) and as intraclast in intraclastic mudstone-

wackestone in Karbala borehole section .

Ooids are spherical or ovoid grains, consisting of smooth and regular lamina

formed as successive concentric coatings around anucles. Lamina may exhibit

tangential or radial microfabrics-size between 0.20 and about 2mm,commonly

between 0.5 and 1mm (Flugel,2004).

Ooids were diagnosed, in Karbala borehole section at depth 25.5 meters (Plt.2.A

and B) . in Najaf composite section, Ooids are found at top of the outcrop down to

1.5 meters and from 5.5-6.5 meters in the same section. (Plt.2.D), whereas no

occurrence recorded at Samawa section . Ooids are small and of superfacial

type(Plt.2.A ), also with grapstone (Plt.2.E )

Ooids are generally limited to the shoal facies , which indicate tropical and sub

tropical , normal marine or hypersaline in the area and generally high-energy

shallow water ( tides and wave action) usually at depths 25 (about to 15 m)

(Fugel,1984).

2.1.3 Euphrates Formation

The Oligocene break at the western part of Iraq , has left a recognizable basal

conglomerate . At Karbala section it is represented by 0.8 meter thick layer ,

increasing to 4.0 meters thick at Najaf and Samawa sections . Its pebbles are sub –

angular to subrounded in shape . Its length ranges from 1 to 4 centimeters . These

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pebbles were cemented by carbonate material . Under the microscope , the pebbles

are made of dolomite rock fragments . The basal conglomerate is overlain by

recrystallized limestone at Samawa , become intraclastic , peloidal packstone to

grainstone with moldic porosity and vugs at Najaf section .

As mentioned before , the basal conglomerate at Karbala is thin , but the

overlying succession of Euphrates is thicker than they are at Najaf and Samawa .It

is rich in fossils , shows deep facies as marl units , restricted facies bearing peloids

, Miogypsina , Dendiritina , miliolid , Peneroplis , and open marine facies bearing

Miogypsina associated with pelecypods and bioclasts.

The main microfacies characters of the Euphrates Formation were obtained

from the Karbala borehole section , while in both Samawa and Najaf composite

sections carbonate grains were not recognized because the limestones were highly

recrystallized . Peloids were the major component of the non–skeletal grains.

2.1.3.1 Skeletal grains

Miogypsina sp. :It is an excellent index fossil for the middle Oligocene-early

Miocene time interval . It occurs both in lagoon and shallow subtidal environments

of open platform (Flugel,2004). Sartorio and Ventarini (1988) indicated a fore

barrier environment for these .

The first appearance of Miogypsina sp. In Karbala section is at 38.8 meters (Plt

4.B) and last appearance at 26.5 meters (Plt 4.A) . It is accompanied with many

other foraminifera such as , Dendiritina , miliolid , Peneroplis , rotalid , Elphidium

,also with pelecypods , and gastropods . Miogypsina is abundant at the first 4.5

meters of Euphrates Formation within a Miogypsina packstone facies (Plt 4.F) .

Dendiritina : restricted or lagoonal environment (Flugel,2004)) .In this study,

Dendiritina is observed abundant at Karbala borehole section with its last

appearance occurring at 34.4 meters (Plt 4.C) and its first appearance is at 45.5

meters (Plt 4.E) . It is abundant enough to classify the rock as Dendiritina

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packstone . Peneroplis : Peneroplis and Dendiritina both are Peneroplidae .

Peneroplis is recognized at 29.3 meters (pl.4.D) , 42.1 meters and 45.5 meters at

Karbala section . The latter two depths may be Peneroplis Planatas .Other

foraminifera such as miliolids, rotalids are recognized within formation , (pl.4.F)

.Molluscs : mainly pelecypods,whole shells are abundant at 26.5 m with many

Miogypsina sp. , and shell fragments . At depth 40.1 m pelecypods are also

abundant , some of them are recognized as thin small shell fragments . It becomes

rare at 41.6 m . Pelecypods are sometimes affected by diagenesis (Plt 3.A) Shell

fragments leached by meteoric water and left its molds . Bioclasts are shell

fragments and echinodermata fragments are found in Karbala section and never in

Samawa and Najaf sections . And microtube occurs only at the base of the

formation. (Plt11.D ) .

2.1.3.2 Non-skeletal grains

Non-skeletal grains within the Euphrates Formation are represented by peloids

only . Peloids are well sorted at depth 44.6 m ,with Dendiritina sp. at depth from

34.1-35.5 meters at Karbala section , it occurred at Najaf section (Plt 10.E).

2.1.4 Dammam Formation

The Dammam Formation consists mainly of light grey to white , hard and

Nummulitic limestone , alternating with white massive recrystallized sugary and

chalky limestone followed by whitish grey , hard ,fossiliferous and dolomitic

limestone ,chert layers are recorded at the lower part of the formation , sometime

silicified , locally with chert nodules , grey – green marl (2.0-3.0) meters

alternating with thin dolomite at or near the base of the formation .The lowermost

of the upper part of the Dammam Formation consists of grey, thick bedded , very

hard , recrystallized and dolomitic limestone , whereas the uppermost of the upper

Dammam formation consists of grey massive , fossiliferous , dolomitic limestone ,

with silicified bands.

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The Dammam Formation is rich in skeletal grains only . At Karbala section

there is Nummulites sp. with Lindrina sp. , Alveolina sp. and Discocyclina sp. at

Samawa section , Bryozoa and shell fragments were also present . At Najaf section

, Dammam Formation was highly and intensively affected by diagenesis leaving

molds of Nummulites sp. and other fossils .

2.1.4.1 Skeletal grains

Nummulites sp. It characterizes shallow waters both inner and outer platform or

ramp, (Flugel,2004). Sartorio and Ventarini (1988) suggested a platform edge

environment.

Nummulies sp. is the index fauna of the Dammam Formation .It is found both

as whole tests and broken ones. Nummulites sp. is found within different

assemblages of fossils :

1- Nummulites sp., with shell fragments and echinodermata fragments . This

assemblage is repeated many times at both Karbala and Samawa sections (Plt 5.B).

2- Nummulites sp. with Alveolina sp. .This assemblage Is repeated two times in

Samawa section and one time in Karbala section (Plt 5.E) (Fig 2.2,2.4).

3- Nummulites sp., Linderina sp. with Bryozoa occur in Karbala section only .(Plt

5.A) .

4- Nummulites sp, with miliolids occur only in Samawa section .

5- Nummulites sp. with Assilina sp. occur in Samawa section only , (Plt 5.D) .It is

also associated with shell fragments and echinodermata fragments .

At Najaf , most of the Nummulites sp. have left its molds in the rock , in

response to meteoric water diagenesis. At Samawa it never appeared at the upper

most part of the Dammam Formation because of the diagenetic process ; the

dolomatization at the top of Dammam , Figure (2.4 ) shows the microfacies and

environments for Samawa section.

Nummulites sp. The last appearance in Samawa section is at depth 61.0 meters

and its first appearance is at depth 126.0 meter . At Karbala section , its first

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appearance as broken fragments is at depth 100.0 meters , and its last appearance

was at depth 49.7 meter .

Nummulites sp. and Alveolina sp. are index fossils for the biozonation of

early Tertiary shallow inner platform and shelf edge carbonate , ( Flugel ,2004 ) .

At Samawa section , the Alveolina sp. first appearance at depth 103.0 meters

. It appeares twice only . Its last appearance is at depth 70.0 meters .It always

appears as Alveolina , Nummulites sp. packstone .

Miliolids occurred at Samawa section and at Karbala section only .

Dammam bioclasts are : echinodermata fragments , Nummulites sp. fragments

and shell fragments.

Three main groups of benthic biota according to light dependence are :Euphotic

biota need relatively high light conditions , live in shallow – water environments ,

oligophotic biota inhibits environments with low light level , and photo –

independent biota ( Pomer,2001). In the current study fossils like Nummulites sp.,

Alveolina sp. , Miogypsina sp., and others are oligophotic biota which are common

in the Eocene – Miocene marginal shelves bordering Tethys , they seen to here

mainly accumulated in situ through winnowings events and have formed extensive

lithosomes (Pomer,2001) within ramp.

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A- Intraclasts in intraclastic mudstone (Karbala section) ,sample no.1

B- Extraclasts with sand grains in extraclastic wackestone-packstone (Samawa section)

,sample no.1

C- Intraclasts in intraclastic packstone-grainstone (Najaf section),sample no.1/14

D-Marl with fine silt size (Najaf section), sample no.1/12

E- marl with rotalid ( Najaf section), sample no.1/9

F- Oxized extraclasts in extraclastic wackstone -packstone (Samawa section) ,sample no.1

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A- Superficial ooids with vugs in ooids pelecypod packstone(Karbala section) , sample

no.10

B- Ooids in ooids pelecypod packstone (Karbala section) , sample no.10

C- Peliods in peliodal packstone (Samawa section) , sample no.2

D- Ooids constrict in ooid packstone (Najaf section) ,sample no.1/16

E- grapstone ooid in ooid packstone (Najaf section), sample no.1/13

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A- Effect of diagenesis (pelecypod mold) (Karbala section) ,sample no.13

B- whole pelecypods (Samawa section) ,sample no.5

C- Miogypsina sp. Above green marl in miogypsina packstone (Samawa section) at Nfayil

Formation ,sample no.5

D- Pebble from the basal conglomerate showing shelly pelecypods (Najaf section) sample

no.2

E- Miogypsina sp. with miliolid , Ammonia beccarii in Miogypsina packstone (Samawa

section) ,sample no.5

F-Ammonia beccarii in intraclastic bioclastic packstone-grainstone(Karbala section),sample

no.8

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A- Last appearance of Miogypsina sp.in the Euphrates Formation (Karbala section) sample

no.12

B- First appearance Miogypsina sp.in Miogypsina packstone in the Euphrates Formation

(Karbala section) ,sample no.18

C- Last appearance of Dendiritina sp.in peloidal packstone in the Euphrates Formation

(Karbala section),sample no.15

D-Dendiritina with Peneroplis in Dendritina packstone(Karbala section)sample no.12

E- First appearance of Dendiritina in Dendiritina packstone(Karbala section) sample no.24

F-Miogypsina sp.with miliolid in Miogypsina packstone(Karbala section) sample 12

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A- Lindrina sp. with Bryozoa in lindrina packstone (Karbala section) Dammam Fn.,

sample no.29d

B- Last appearance of Nummulites sp. in (Karbala section) , sample no.29

C- Whole pelecypoda in (Karbala section) , sample no.13

D- Nummulites sp. with Assilina sp. (Dammam Fn.) at Samawa section, sample no.61

E- Alveolina sp. with Nummulites sp. in Nummulitic Alveolinid packstone (Dammam Fn.)

at Samawa section ,sample no.44

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2.2 Diagenetic processess

Rhymond ( 1995 ) defined diagenesis as all physical ,chemical and biological

processes that collectively result in transformation of sediment into sedimentary

rocks . Diagenetic processes continue to operate after the sediment has become

rock ,altering the rock texture and mineralogy . Diagenetic processes give the

sedimentary rocks many characteristics observed in outcrop , hand specimen , and

thin section .

Diagenesis refers primarily to the reactions which take place within the

sediment between one or several minerals and the interstitial fluid ( Selly ,2000 ) .

Diagenesis is a term used somehow to define all the changes that occur in

sediments during the interval between deposition and before the transition to

metamorphism . These diagenetic changes may take place in submarine , subarial –

fresh water and subsurface environments ( Larson and Chilingar ,1979 )

The studied samples of Nfayil , Euphrates and Dammam Formations have

undergone some diagenetic processes through their geologic history . The

following diagenetic processes are thought to be the main ones that observed in the

studied samples .

2.2.1 Cementation :

Cementation is the diagenetic process by which voids and porosities are filled

with newly precipitated materials during the deposition by filling the interpartical

porosity or after deposition by filling dissolution porosity such as fractures and

joints resulting from compaction .

Cementation has affected most of the Eocene-Miocene formations with

different types of cement :

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2.2.1.1 Syntaxial rim overgrowth

Syntaxial rim cement (overgrowth) found as syntaxial growth of calcite

particles on echinoderms fragments indicating an early fresh water phreatic cement

( Koch and Schorr ,1986 ) .

Syntaxial rim cement has affected the Dammam Formation only in Karbala

section at depths 92.2 m , 78.0 m , 73.0 m , 70.0 m , 68.0 m , and at 56.5 m .

At Samawa section ,this type of cement appears in the Dammam Formation too , at

depths 89.0 m, 80.5 m , and at 69.0 m . (Plt 7.B)

Syntaxial rim overgrowth is associated with or without neomorphism Figures

(2.2 ,2.4). The former indicates active fresh water phreatic zone the latter indicates

stagnant fresh water phreatic zone .

2.2.1.2 Geopetal cement :

Sander, (1936) in Flugel ,(2004) indicated the relationship between top and

bottom at the time the rock was formed recognizing that geopetal cement in

limestones is crucial for understanding the depositional post –depositional history

of carbonate rocks ( Flugel,2004) .

Geopetal cement occurs at Karbala section only within Dammam Formation at

depths 94.8 , 89.5 , 83 .0 , and at 65.5 meter.

Geopetal cement indicates active fresh water phreatic zone.

2.2.1.3 Intraparticle cement :

This type shows an early stage of diagenesis within the marine phreatic zone .

This type of cement is the only cement within Nfayil formation occurring at 1.0 ,

5.0 meters in Najaf section , at depth 9.0 meters in Samawa section and at 21.0

meters in Karbala section .(Plt 7.A)

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Euphrates Formation never showed any cement type both at Najaf and

Samawa sections . At Karbala section , the intraparticle cement occurred at depths

42.5, 36.0 -40.5 meters , and at depth 30.0 meters .

No cement occurred within the Dammam Formation at Najaf section , while at

Karbala section , the intraparticle cement is profound nearly throughout the

Dammam succession, clogged the intraparticle vugs of the main skeletal grains the

Nummulites sp. . Middle part of the Dammam Formation at Samawa section shows

also intraparticle cement .

2.2.1.4 Interparticle cement :

Interparticle cement occurred only within Dammam Formation in Karbala

section at depths 59.0 – 61.0 meters and at 62.5-64.0 meters , and was associated

with both neomorphism and intraparticle cement . (Plt 7.D)

2.2.2 Silicification :

The appropriate chemical conditions to dissolve calcite and precipitation of silica

include supersaturation of pores solutions by silica and decrease of pH and

temperature (Blatt et al., 1972). The source of silica probably is from siliceous

skelton debris including sponge spicules and radiolarian or the corrosion of quartz

and clay minerals at high pH; when pH decreases, precipitation of dissolved silica

occurs. Moreover, the silica precipitation is produced by the decreases of

temperature (Engelhardt, 1977). Silicification are recognized within the Dammam

Formation in the study area , at Karbala , Samawa , and Najaf sections . Fig .(2.2,

2.3 ,and 2.4).(Plt 7.E) .

In marine setting cherts occur as nodules varying in size from a few

millimeters to about 2 cm , or in layer often interbedded with shale or limestone .

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Most chert nodules are formed early during diagenesis . They are common in

pelagic chalks . In shallow – marine area , (ramp, Platforms ) the input of silica

from land is an important source , Laschet ,(1984) in Flugel (2004) . In shallow –

marine setting chert nodules are sometimes related to mixing zones .

Field observations has confirmed the silicification within the Dammam

Formation in Samawa section , as chert nodules within the Nummulitic packstone

at depth from 91.5-94.0 meters , as chert layer about 10cm .occurring at depth

125.0 meters , (Fig .2.5.A) .

2.2.3 Dolomitization :

Amthor and Friedman (1992) style of dolomitization as a subtidal one is

acceptable in the current study on the basis that rising of sea level had led to the

deposition of the Dammam formation (chapter four) giving subtidal conditions for

semi evaporative dolomitizing fluids showed by the fine crystals of dolomite and

the maintance of textural characters . This may explain the dolomitization of the

lower parts of the Dammam formation . Evidence for the mixing model of

dolomitization also present in the thick dolomite beneath the unconformity , the

euhedral coarse size , and the associated silicification sometimes (at the top of the

Dammam formation. Mixing model may be suggested for the upper part of the

formation .

Dolomitization had a major impact on the sediments of the Dammam

formation . It affected Najaf and Samawa sections . The upper part of Dammam

Formation at Samawa section begins with thick microcrystalline dolomite,

subhedral – anheadral ,about 41.5 meters . This interval shows medium – coarse

euhedral crystals also , at depth 123m ,euhedral cloudy center clear rim is seen

dolomitizing Nummalitic wackestone microfacies . Fig.(2.2 , 2.3 , and 2.4 ) .

All the Dammam Formation at Najaf section was dolomitized with the same

above characteristics with fine – medium , subheadral –anheadral crystals . The

dolomitization was fast enough , dolomitizing the fossils (Nummulites ) and others

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like echinoderm fragments and the matrix maintaining their original structure and

texture .

Cloudy center- clear rim are found at 123.0 meter in Samawa section and at

28.0 meter in Najaf section . No dolomitization is recorded at Karbala section .

According to (Amthor and Friedman ,1992) ,two stages of late – diagenetic

replacement dolomites are observed for the dolomitization. This is adapted for the

dolomitization of the Dammam Formation on the bases of crystal size and shape of

crystal boundary

The method concluded is that of syn depositional subtidal dolomitization . Two

types of texture are recognized ; the fine , subhedral to anhedral , unimodel which

indicate shallow burial dolomitization , and the coarse , euhedral indicating

intermediate burial .

Amthor and Friedman suggested that the coarser –grained and more porous

lithofacies remained undolomitized during early diagenesis and could have served

as permeable horizons for late dolomitizing fluids .(Plt 6.A , 6.B and 6.E) .

2.2.4 Dedolomitization :

The alteration of dolomite to calcite take place in several diagenetic settings ,

but is a common feature of near-surface vadose zone , Kenny,(1992) in Flugel

(2004) .

Different dedolomitization textures are recognized within the Dammam

Formation , at Samawa and Najaf sections .

At Najaf section , dedolomitization is more effective .Textures recognizable

are :

1- Blocky calcite , cleaveged or non- cleaveged with fine relict rhombs of dolomite

even where the blocky calcite is filling Nummulite molds .(Plt 7.F), (Plt8.D).

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2-Calcite spar ,coarse crystals fused with each other by serrated boundaries

(Plt8.C)

3- Dolomite rhombs with calcite cores .

4- Cleaveged rhombs of dolomite (Plt 6 .D and 6.F) .

2.2.5 Neomorphism :

The term neomorphism involved three processes, the first by which aragonite

was altered to calcite by inversion, while the second where the calcite become new

calcite particles by recrytallization, or forming new calcite by crystal growth (Folk

1965).

Neomorphism dominates the Eocene-Miocene succession at Karbala section

except the marl lithofacies in Nfayil Formation , but it occur at Najaf section at

Nfayil and Dammam Formations, whereas this type of diagenetic process occur at

Samawa section in Nfayial Formation especially in its lower parts , and it

dominates the Dammam Formation , Fig (2.2, 2.3 and 2.4).

Neomorphism in this study included the transformation of micrite into microspraite

and sometimes to sparite , for the matrix and / or the grains.

2.2.6 Dissolution :

Dissolution is the most important diagenetic process affecting the Eocene –

Miocene succession because it is responsible of forming the vugy, channel and

moldic porosities , these porosity types are described and classified according to

Chaquitte and Pray (1970 ) where porosity types are divided into fabric selective

and non-selective .

Four types of porosity are recognized in the study area through thin sections

examination of the Eocene – Miocene succession in Dammam, Euphrates , and

Nfayil Formations ,they are :

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1-Intraparticle porosity

2- Moldic porosity

3- Vugy porosity

4-channal porosity

2.2.6.1 Intraparticle porosity :

This type of porosity is noticed within individual particles or grain particles

within skeletal grains ( internal chambers and other openings ) such as Nummulites

sp.(Plt 8.B) , pelecypods , and other fossils . Intraparticle porosity may also be

developed within peloids or intraclasts . Sometimes ,the intraparticle pores are

clogged by calcite cement .

2.2.6.2 Moldic porosity :

Moldic porosity usually forms by the selective removal normally by solution of

former individual constituent of the sediment or rock such as shell or Ooids

especially common in limestone where molds are of primary aragonite constituents

( Nummulites sp. , gastropods , pelecepod shells ), molds in dolomite are usually

formed by selective solution of either aragonite or calcite primary constituents may

also result in the formation of molds .

This type of porosity occurs in the Nfayil Formation at Karbala section only at

depth 25.0 m (Plt8.A). And at depth from`15.0- 18.2 meters ,at Najaf section in

the Euphrates Formation , while it occurs in the Dammam Formation at Samawa

section at depth from 72.0-74.0 m . No moldic porosity is recorded in the

Dammam Formation at Karbala section , moldic porosity occur throughout the

Dammam Formation at Najaf section except in some place. Fig.( 2.2 , 2.3 and 2.4 )

Moldic porosity typically indicates differential solubility between more and

less soluble carbonate constituents in the rock fabric. In some cases , the more

soluble constituents may be metastable mineral such as Mg-calcite or aragonite (

Ahr, 2008).

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2.2.6.3 Vugy porosity : Vugs are pores nearly equant large enough to be visible

with unaided eye . The dominant type is (usually larger than 1/16 mm and

generally not dependent on fabric .They represent solution enlargement of fabric

selective,( Tuker ,1990) . Vugs are found mainly at Najaf section , Figure ( 2.3 )

Fig.2.5.B

2.2.6.4 Channel Porosity :

Limestone is prone to dissolution in undersaturated water and a common

product is channel pores , developed along fractures .Near-surface karstic solution

pipes are a common example in the geological record .

Intraparticle pores are fabric-selective indicating depositional textures , while

vugs and moldic pores might be of intermediate diagenetic stage . The channel

indicates stress or tectonic forces or may be solution effect , then it might be of

later stages of diagenesis .Tuker(1990).

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A- Medium to coarse dolomite crystals , cloudy center - clear rim (CCCR) sample no.68

B- Coarse crystalline dolomite in the Dammam Formation (Samawa section),sample no.17

C- Fine crystalline dolomite in the Dammam Formation (Samawa section),sample no.13

D- Dedolomitization in Dammam Fn.(Najaf section) sample no.62

E- Coarse crystalline dolomite in the Dammam Formation (Najaf section),sample no.36

F- Dedolomitization in the Dammam Fn.(Najaf section) sample no.63

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A- Intraparticle cement (Karbala section) sample no.8

B- Syntaxial rim cement in the Dammam Fn.(Karbala section) sample no.48

C- Vugs within Nummulites sp. (Karbala section) sample no. 51

D- Interparticle cement (Karbala section), sample no.55

E-Silicification in the Dammam Fn.(Samawa section) sample no.46

F-Dedolomitization,blocky calcite filled Nummulites sp. mold (Najaf section) sample no.33

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A-Moldic porosity ,Nfayil Formation (Karbala section ),sample no.10

B-Intraparticle porosity ,Dammam Formation (Samawa section), sample no.43

C-Dedolomitization ,calcite spare, coarse crystals,Dammam Formation(Najaf

section),sample no.33

D- Dedolomitization,blocky calcite ,Dammam Formation((Najaf section),sample no.26

Plate 8

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Figure(2.1) Legend of figures (2.2 , 2.3 and 2.4 ).

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Figure 2.5A Chert layer(10 centimeter) in the Dammam Formation at Samawa

section sample no.70

Figure 2.5 B Vugs in the Dammam Formation at Najaf section , sample no. 51

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CHAPTER THREE

MICROFACIES AND

DEPOSITIONAL

ENVIRONMENTS

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Microfacies And Depositional Environment chapter three

3.1 Preface

Detailed examination of Eocene-Miocene thin sections carried on the

bases of Dunham’s classification, (1962) and using the Ramp Microfacis

(RMF) in Flugel (2004) and Standard Microfacies (SMF) assigned by Wilson

(1975), a range of environments are designated for each rock based on its

depositional texture and its fossil content.

3.2 Nfayil Formation

The Nfayil microfacies reveal four types of environments using the ramp

standard microfacies of (Flugel ,2004).

3.2.1 Peritidal Environment

Peritidal carbonates are shallow-subtidal, intertidal and supratidal sediments

found in marginal-marine and shoreline depositional environments. These facies

are vertically arranged (regressive) shallowing upward succession consisting of

shallow-marine sediment overlain by intertidal and supratidal carbonates that are

subject to periods of subaerial exposure (Flugel,2004) .Facies responsible for the

designation of this environment is the intraclastic mudstone -wackestone at

Karbala with quartz (sand – silt size) clastic influx , and extraclastic wackstone -

packstone at Samawa section at depth 0.0-1.5 meter and intraclastic wackstone -

packstone at depth 8.0 meter in same section .Both are matching ramp standard

microfacies number 24 (Flugel ,2004) which is intraclast mudstone /wackestone.

Microfacies responsible for this environment is not found at Najaf section .

Fig.(2.2 and 2.4) ( Plt.9A , D)

.

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3.2.2 Shoal Environment

Carbonate sand shoal sediments are composed of sand to granule –sized loose

carbonate material occurs in shallow, high energy areas, these shoal carbonate may

be made up of ooids, mixture of broken shelly debris or may be an accumulation of

benthonic foraminifera reworked by wave and tidal currents which results in a

deposit made up of well-sorted, well rounded material: when lithified these form

beds of grainstone or sometimes packstone , (Gary,2009)

Two types of microfacies were recognized for this environment:

A- An Ooid wackestone-packstone, at 0.0-1.5 meter at Najaf section another

occurrence is at 5.5-6.5meters in the same section (Plt10.F), with the presence of

Dendiritina , peloids, grapstones , pelecypods, gastropods, and shell fragments.

whereas at Karbala section ,this facies occur at depth 25.5 meter as Ooid

pelecypod packstone. Ooids are small and of superfacial , concentric types , also

with grapstones, peloids, and shell fragments (Plt10.B). Corresponds to ramp

microfacies 29 (Flugel,2004),ooid grainstone with concentric ooids.

B- Intraclastic packstone- grainstone with Miogypsina sp. ,others are Elphidium

, Ammonia beccarii , miliolid , rotalid , pelecypods , and shell fragments (Plt10.A).

At Karbala and Najaf sections this diversified assemblage of fauna similar to ramp

microfacies 26 (Flugel,2004) bioclastic packstone-grainstone with divers skeletal

grains. Both microfacies never recognized at Samawa section ,Fig.(2.2 and 2.3) .

3.2.3 Restricted Environment

Four types of microfacies characterize this environment .

A-Bituminous siltstone (1.4 meters thick) at depth 14.5 meter at Karbala section ,

followed by silty lime mudstone (7.1 meters thick) interbedded with bituminous

siltstone. ( Plt 9.B )

B-Recrystallized lime mudstone at Najaf and Karbala sections , similar to

standard microfacies number 23 which is homogeneous , non-fossiliferous micrite.

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C- Peloidal intraclastic packstone at the top of Samawa outcrop . Associated

fossils are: miliolid , Dendiritina matching ramp microfacies number16 (Flugel

,2004) which is mudstone /wackestone with miliolids . ( Plt 9.C )

The dominance of family miliolidea as Dendiritina , Articulina ,and others

unidentified miliolds is due to restricted water conditions .

D- Miogypsina packstone with miliolid , pelecypods and shell fragments, more

restricted conditions are reflected at 8.75 -9.5 meters at Samawa section similar to

ramp microfacies number (13) (Flugel,2004) wackestone -packstone with larger

foraminifera . C and D microfacies present only at Samawa section. ( Plt 9.E)

Miogypsina packstone with miliolid at depth 9.5 meters is designated as

restricted at the Samawa section and intraclastic, bioclastic packstone to

grainstone with presence of Miogypsina sp. at depth 25.0 meters in Karbala

section as shoal environment , both are located above the olive green marl (the

index unit of the Nfayil Formation ). Then if the Miogypsina is the index of the

Euphrates formation both above mentioned microfacies might be within the

Euphrates Formation.

3.2.4 Deep Environment

Deep sediments are medium-bedded, fine grained bioclastic limestone and

marls ,often burrowed . Skeletal grains are often worn, echinodermata, mudstone ,

wackestone , packstone and some grainstone. (Flugel ,2004)

Many layers of marl are found in the succession of the Nfayil Formation .Some

are bearing echinodermata fragments ,rotalids , and unidentified fauna, such that at

depth 11.0 meters below the top of Najaf outcrop (Plt1.E ) , and at Karbala at depth

24.0 meters . Some layers of marl are olive green color which may indicate deep

marine environment .It is present in all three sections. This unit is a characteristic

one defining the contact between the Nfayil and the Euphrates Formation

(Sissakian,1999) . Other marl unites with fine clastic influx are also present .

Fig.(2.2, 2.3,and 2.4)

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3.3 Euphrates Formation

Four types of environments involved in the formation of the Euphrates

sediments .They are:

3.3.1 Restricted Environment:

This was reflected by:

A- Recrystallized limestone unit at Karbala and Samawa sections only. It is

similar to microfacies (I9) , which is finely laminated dolomitic or lime

mudstone microfacies, facies zone number 8 .

B- peloidal packstone at Karbala section depth 35.0 meters . Associated fossils

are : Dendritina, Miogypsina and other unidentified. (Plt 10.D ) .

C- Dendritina packstone with Peneroplis and gastropods at depths 45.5 , 42.5

meters at Karbala section (Plt 10.C ), similar to microfacies no. 18 , which is

packstone with abundant foraminifera or algae . (Flugel,2004) .

3.3.2 Shoal Environment

Shoal is represented by peloidal grainstone microfacies ,consisting mainly of

abundant peloids , Dendritina ,bioclasts ,and intraclasts . Peloids are well sorted

and rounded at depth 44.5 meters at Karbala section (Plt 10.E ) . It appeared as

intraclastic peloidal packstone–grainstone at depth from 15.0-18.0 meters at

Najaf section , similar to ramp microfacies no. 27 , which is bioclastic grainstone

and packstone composed of few dominant skeletal grains, this facie is not found at

Samawa section .

3.3.3 Open marine Environment

Three types of microfacies are recognized indicating this environment at

Karbala section only :

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A- Miogypsina packstone at depths 26.5-31.0 meters and at 36.0 -39.0 meters .

Associated fauna : pelecypods, gastropods, rotalid , echinoderm fragments, shell

fragments similar to ramp microfacies (13) (Flugel,2004), which is bioclastic

wackestone with abundant larger foraminifera (Plt11.A). .

B- Fossiliferous packstone at depth 39.0-40.5 meters. Associated fauna

are pelecypoda , gastropods , ostracoda , and shell fragments similar to ramp

microfacies (13) which is wackestone /packstone with larger foraminifera

.(Plt11.B)

C- Bioclastic wackstone –packstone at depth 40.5 and 41.8 meters . Associated

fauna are pelecypoda ,rotalids whole tests accompanied with abundant shell

fragments and echinodermata fragments similar to microfacies no.10

(Flugel,2004), which is bioclastic wackestone- packstone with skeletal

grains.(Plt11.C)

3.3.4 Deep Environment

Two microfacies possibly fit in this environment at Karbala section only , they

are:

A-marls :

Marl thin sections show few silt size quartz grains, echinodermata fragments and

rotalids. It is similar to ramp microfacies 11 (Flugel,2004) ,which is marl with

intraclasts and limestone pebbles ,referring to distally steepened ramps (Flugel,

2004).

B-Microbioclastic packstone

Characterized by the presence of microtubes , shell fragments, echinodermata

fragments , rotalids, and others, at Karbala section only depth , 46.2 -48.0 meters ,

similar to ramp microfacies (7) (Flugel,2004) which is bioclastic packstone with

abundant echinodermata .(Plt11.D).

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3.4 Dammam Formation

This formation is widely distributed in southwest Iraq . It was characterized

by vertical changes in lithology and faunal assemblages . Therefore different

environments and microfacies are recognized throughout the succession of the

formation. They are :

3.4.1 Shoal Environment

The domination of Nummulites sp. in the Dammam Formation came in

different styles , as mentioned in chapter two. Although the Nummulites sp. is the

main constituent of these microfacies, texture is different grainstone, packstone ,

and wackestone .The important bases for the designation of this environment are:

either the larger size of the Nummulites sp. , (Fig.2.2, 2.3,and 2.4) such as : the

larger Nummulitic packstone at depth 65.0 meters, Karbala section(Plt12.A,C )

.Matching ramp microfacies 27 , bioclastic grainstone / packstone with few

dominant skeletal grains. Reekman and Friedman (1982) suggested that the larger

size of the grain (Nummulites sp. in the current study ) would be a perfect

indicator of shoal or barrier, or concentration of one type of fossils or bioclasts

(Flugel,2004).This is also found at Karbala section , sample no. 67 the Nummulites

packstone / grainstone (Plt12.B). Algae ( indicate of shallow water conditions)

were also found nearly at the base of the same section.

At Samawa section the shoal microfacies showed large sized Nummulites sp,

echinodermata fragments , Nummulites sp. fragments ,shell fragments , rotalid and

algae. At the base of Samawa section ,the Dammam Formation shows the presence

of Assilina sp. (Plt12.C), Fig.2.4

Even though the Nummulites sp. were ghosts nearly all over the Dammam

Formation at Najaf but the detection of larger sized Nummulites sp. was easy at

depth 61.0-63.5 meters indicate shoal environment .

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3.4.2 Restricted Environment

Characteristic microfacies for restricted environment are :

A- Alveolina sp. and miliolids thrive in restricted conditions . In this study they

are the main key to distinguish this environment ,with or without the presence of

Nummulites sp. The bearing microfacies for this assemblage is at Karbala section

at depth 80.0 -82.0 meters with Nummulites sp. , Alveolina sp. , Dasycladacea

packstone. At Samawa section at depth 70.0-72.0 meters Nummulites sp.,

Alveolina wackestone with miliolid , echinodermata fragments(Plt12.D) .And at

depth 97.0- 103.0 meters Nummulites sp. , Alveolina sp. , with Lindrina sp.

packstone, it is similar to ramp microfacies (13) , wackestone- packstone with

larger foraminifera ,and ramp microfacies (17) ,bioclastic wack estone with

dasycladacea.

The presence of miliolid ,rotalid ,ostracode or may be pelecypods, and quartz

grains within the fossiliferous packstone at depth 57.25 meters in Karbala ,similar

to ramp microfacies (16) which is mudstone -packstone with miliolid also

characterizes restricted environment. At Samawa section miliolid appeared with

Nummulite sp. within Nummulitic wackestone or packstone at depth 85.5-91.2

meters , the presence of miliolids also characterized restricted environment ,

similar to ramp microfacies (13) and (16) (Flugel ,2004 ).

B-Recrystalized limestone unit within the Dammam Formation at Najaf section

only at depth 53.5 -57.0 and at 59.0-61.0 meters , It is similar to microfacies (19)

which is non- burrowed lime mudstone .

( Fig 2.3 ) .

3.4.3 Open marine Environment

Earlier consideration for the larger Nummulites sp. was to be on the edge of the

ramp giving shoal environment , wherever the Nummulites sp. are smaller in size ,

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it means imperfect conditions for building a shoal . It is considered to show an

open marine conditions especially with the presence of bioclasts (Nummulites sp.

fragments ,echinodermata fragments, and shell fragments, Lindrina sp., Asslina sp.

,bryozoa and other small foraminifera. ) , (Plt13. A , B, D)

The texture is packstone ,sometimes wackestone (Fig 2.2, 2.3, 2.4 ) ,the

matching microfacies are ramp microfacies (7) and (13) at open marine

environments, which is wackestone / packestone with larger foraminifera

(Flugel,2004).

3.4.4 Peritidal Environment

The dolostone showen in ( Fig 2.3 , 2.4 ), indicates the presence of this

environment .It is similar to ramp microfacies 22 dolomite being fine crystalline

subhedral, euhedral dolomite . (Plt13.C,E)

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A- Intraclastic mudstone-wackestone , Nfayil Formation ( Karbala section) ,sample no.2

B- Bituminous siltstone , Nfayil Formation ( Karbala section) ,sample no.5

C- Peloidal packstone , Nfayil Formation ( Samawa section) ,sample no.2

D- Extraclastic wackestone – packstone ,Nfayil Formation ( Samawa section) ,sample no.1

E- Miogypsina packstone , Nfayil Formation ( Samawa section) ,sample no.5

Plate 9

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A- Intraclastic packstone- grainstone ,Nfayil Formation(Najaf section),sample no.1/14

B- Ooids packstone ,Nfayil Formation ( Karbala section ) , sample no.8

C- Dendritina packstone,Euphrates Formation (Karbala section) ,sample no.12

D- Dendritina packstone,Euphrates Formation (Karbala section) ,sample no.24

E- Intraclastic peloidal packstone-grainstone,Euphrates Formation(Najaf section)

sample no.1/5

F- Ooid wackstone – packstone , Nfayil Formation (Najaf section ), sample 1/13

Plate 10

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A- Miogypsina packstone , Euphrates Formation (Karbala section), sample no.12

B- Fossiliferous packstone , Euphrates Formation (Karbala section), sample no.19

C- Bioclastic wackestone-packstone , Euphrates Formation (Karbala section), sample

no. 20

D- Microbioclastic packstone , Euphrates Formation (Karbala section), sample no. 26

Plate 11

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A-Larger Nummulitic packstone, Dammam Formation(Karbala section),sample no.65

B-Nummulitic packstone-grainstone, Dammam Formation(Karbala section),sample no.67

C- Larger Nummulitic packstone, Dammam Formation(Samawa section),sample no.62

D-Nummulitic-Alveolinid-wackestone, Dammam Formation(Karbala section),sample no.44

Plate 12

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A-Lindrina packstone , Dammam Formation (Karbala section),sample no.29c

B-Nummulitic packstone , Dammam Formation (Karbala section),sample no.29

C-Dolomite , , Dammam Formation (Samawa section),sample no.51

D-Nummulitic packstone, Dammam Formation (Karbala section),sample no.31

E- Dolomite , , Dammam Formation (Najaf section),sample no.49

Plate 13

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CHAPTER FOUR

SEQUENCE

STRATIGRAPHY

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Sequence Stratigraphy chapter four

4.1 Contacts

4.1.1 Lower contact of the Dammam Formation

In the study area , the contact is conformable with the Rus underlying

Formation which is encountered at Najaf and Samawa boreholes . It is the first

appearance of anhydrite that underlies the grey –green marl , papery with rusty

stains. This contact is not encountered at Karbala borehole .

4.1. 2 Lower contact of the Euphrates Formation

The contact is between the Euphrates Formation and the underlying Dammam

Formation . It is unconformable , sharp contact , represented by the basal

conglomerate indicating the Oligocene absence . Thickness of basal conglomerate

is 0.8 meter at Karbala borehole above Nummulitic packstone , 4.0 meters at

Najaf borehole above whitish grey dolomite with secondary calcite filling

fractures , and 4.0 meters at Samawa borehole above 42.0 meters whitish grey ,

tough ,fractures filled with secondary calcite . The conglomerate consisted of 1-4

centimeter long pebbles of dolomite bearing recrystallized pelecypod shells .

4.1.3 Nfayil Formation contacts

The Nfayil Formation consists of two member according to previous studies

(Sissakian,1999),the upper and lower Nfayil Formation

At Karbala both upper and lower members are encountered . At Najaf and

Samawa , the upper member of the formation is absent .

4.1.3.1 Lower contact of the Nfayil Formation

In the study area, the lower contact of the Nfayil Formation is conformable

with the underlying Euphrates Formation , it is assumed to be above the olive

green marls . This is acceptable at the field . The current study reveals different

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contact using the Miogypsina sp. which is an index fossil for the Euphrates

Formation and it is present within the limestone unit overlying the olive green marl

marker . This marl marker is 4.0 meters thick at the Najaf outcrop , interbedded

with thinly – bedded marly limestone .The latter is seen recrystallized under the

microscop , (Miogypsina sp. is not detected at the Najaf outcrop) . At Samawa

outcrop the olive green marl is 1.0 meter thick , limestone unit overlying the olive

green marl bearing Miogypsina sp, whereas at Karbala borehole the olive green

marl is 0.75 meter thick , Miogypsina sp. is present within the limestone unit

overlying the olive green marl. The contact between the Nfayil and Euphrates

formations must be constructed on the bases of Miogypsina (index fossil for the

Euphrates Formation ) then the contact will be based on the Miogypsina

disappearance which occurs above the olive green marl unit in the current study .

4.1.3.2 Upper contact of the Nfayil Formation

The upper contact of the Nfayil Formation is not seen in the field of the study

area. At Karbala borehole section (0.3) meter of soil , pale brown ,friable with rock

fragments capping the formation .

At Najaf borehole , the Nfayil Formation is not encountered . The studied

section is a composite section of both Najaf borehole and Najaf outcrop (distance

between outcrop and borehole is 3 km). At Najaf outcrop the Nfayil is capped by

tough , well- bedded ,fossiliferous limestone with black stains , represented by

sample number 1/16 which is ooid wackestone-packstone .

At Samawa the studied section is a composite one , both outcrop and borehole

,distance between them is 7 km . The Nfayil Formation is not encountered at

Samawa borehole , at the outcrop a cap of marly limestone represented by (sample

no. 1) which is an extraclastic wackestone – packstone.

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4.2 Sequence Stratigraphy

4.2.1 Preface

Sequence stratigraphy is the study of rock relationship within a

chronostratigraphic framework (Van Wagoner et al ., 1990).

The fundamental unit of sequence stratigraphy is the sequence . A sequence

is a relatively conformable succession of genetically related strata bounded by

unconformities and their correlative conformities .(Mitchum ,1977; Posaentier et al

., 1988).

4.2.2 Concept and Definition

The individual sequence generally consists of three genetically related facies

packages known as “ systems tract” that are deposited during a single cycle of sea

level rise , stillstand , and eventual fall .

These system tracts are the fundamental architectural components carbonate

platform , they are referred as lowstand systems tract (LST) ,transgressive systems

tract (TST), and high stand systems tract (HST) ,(Sarg ,1988; Van Wagoner et

al.,1988, Postamentire et al ., 1988) .

The lowstand systems tract is deposited during an interval of relative sea level

fall at the offlap break , and subsequent slow relative sea level , (Emery , and

Myers ,1966 ). The base of the lowstand systems tract is represented by type -1

Sequence boundary .The transgressive systems tract is deposited during that part

of a relative sea level rise cycle when top set accommodation volume is increasing

faster than the rate of sediment supply ,(Emery and Myers,1996).

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The transgressive systems tract may exhibit catch up or keep up sedimentation

depending on the wetter conditions and rate of rise of sea level .

The high stand systems tract represents progradational top set clinoform

system deposited after maximum transgression and before a sequence boundary ,

when the rate of creation of accommodation is less than the rate of sediment supply

(Emery and Myers ,1996).

The top of the transgressive systems tract a down lap surface bound below the

high stand systems tract are genetically characterized by a relatively thick

aggradational to progradational geometry . Deposition of high stand systems tract

are generally characterized by early and late stages that reflect different rate of

accommodation and associated water mass condition during early and late high

stand.

4.2.2.1 Parasequence

The fundamental building blocks of a sequence are parasequences and

parasequence sets . Parasequence is defined as a relatively conformable succession

of genetically related beds bounded by marine flooding surfaces or their correlative

surfaces. A marine flooding surface is a surface separating younger from older

strata across which there is evidence of an abrupt increase in water depth . While

the parasequence set is a succession of genetically related parasequences which

from a distinctive stacking pattern bounded by marine flooding surface ,( Van

Wagoner et al., 1990 ). Stacking patterns of parasequences may be :

A- progradational stacking that result when the long term rate of a accommodation

exceeded by rate of sedimentation .

B-Aggradation stacking pattern results when the long- term rate of

accommodation closely matches the long term rate of sedimentation .

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C- Retrogradational stacking results when the long term rate of accommodation

exceeds the long term of sedimentation .

Accommodation space is defined as the space available for sediment to

accumulate at any point in time (Jervey,1988) .This space is controlled by the rate

of subsidence , rate of eustatic sea level change ,and sedimentation rates (Hanford

and Loucks , 1993) .

4.2.2.2 Key Surfaces

4.2.2.2.A Sequence Boundaries

Two types of sequence boundaries can be recognized in the rock record , they

are defined and identified on the basis of arrangement of strata into systems tracts

between the sequence boundaries and types of bounding unconformities (Van

Wagoner et al., 1990).

Type -1 sequence boundary is characterized by subaerial exposure and

concurrent subaerial erosion associated with stream rejuvenation , a basin ward

shift in facies , a downward shift in coastal onlap , and onlap of the overlying

strata.

As a result of the basin ward shift in facies , non-marine facies such braided

stream or estuarine sandstone or very shallow marine facies above a sequence

boundary may directly overlain deeper water marine rocks.

A type-1 sequence boundary is interpreted to from when the rate of eustatic fall

exceeds the rate of basin subsidence at the depositional shore line

break,(Posamentier et . al., 1988 ;Van Wagoner et. al., 1990 ).

A type -2 sequence boundary marked by subaerial exposure and down ward

shift in coastal on lap landward of the depositional shoreline break .However it

lacks both subareial erosion associated with stream rejuvenation and basin ward

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Shift in facies . A type -2 sequence boundary is interpreted to form when the rate

of eustatic fall is less than the rate of basin subsidence at the deposition shoreline

break,(Van Wagoner et .al.,1990).

4.2.2.2.B Transgressive Surface (TS)

This surface is the first significant marine flooding surface on top of the low

stand systems tract (Einsele,2000) , and it is the limit between lowstand systems

tract and transgressive systems tract (Loutit ,et .al.,1988) .

This surface considers the first indication of marine flooding on the shelf

within a succession (Van Wagoner et .al., 1988).

4.2.2.2.C Marine flooding surface

Diachronons surface indicating minor submarine erosion (nosubaerial erosion )

and separating strata of shallower environment (bottom) from deposits deeper

environment (top) ,(Einsele,2000).

This surface correspond with stratigraphic relationship like (onlap) than it is

considered a sequence boundary (Van Wagoner et . al.,1988).

4.2.2.2.D Maximum Flooding Surface (MFS).

This surface is represented as the boundary between a transgressive unit , or

retrogradational parasequence sets , and an overlying regressive unit, or

progradational parasequence sets , (Emery and Myers ,1996).

At this surface the stacking patterns change from retrogradational to

progradational (Van Wagoner et. al.,1988).

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4.2.3 Sequence development

4.2.3.1 Dammam cycles

Five third order cycles (A,B,C,D,E ) can be recognized within the Dammam

succession , minor fluctuation within the third order cycle D can be recognized and

divided into two fourth order cycles represented by D1 and D2 at Samawa section

At Najaf section , six third order cycles (A,B,C,D,E,F) are recognized , cycle D is

divided into two fourth order cycles D1 ,D2 , Cycle E is also divided into three

fourth cycles (E1,E2,E3).

At Karbala section , only four third order cycles (C,D,E,F) can be recognized

within the Dammam succession .

The asymmetry of cyclicity was due to the changing magnitude of eustatic sea-

level (Van Wagoner et al ., 1990).These cycles represent successive episodes of the

sea-level rises and still stands. Cycle A at Samawa section is symmetrical where

the shallow open and deep facies represented by the transgressive systems tract

(TST) and separated from the underlying conformable contact with the Rus

Formation by a transgressive surface (TS). It was overlain by the shoal facies of

the high stand systems tract .

Cycle A at the Najaf section on the other hand is asymmetrical where the thick

transgressive systems tract (TST) consists of deep facies followed by thin peritidal

facies of the high stand systems tracts (HST).

Cycle B shows a marked difference at the Najaf section in terms of being thick

(thicker than the section at Samawa specially the transgressive systems tract (TST)

and the nature of its symmetry where the thick transgressive systems tract (TST) at

Najaf may reflect a keep up situation due to the balance between carbonate

production and relative sea –level rise , in this case the major controlling factor is

the tectonic subsidence . .

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The nature of cycle C is similar at Samawa and Najaf sections , although cycle

C is not complete at the Karbala section .The nature of succession may suggest its

similarity with the Najaf section .

Cycle D shows an almost equal thickness in all studied sections but can be

divided into two fourth order cycles D1 and D2 at Najaf and Samawa sections due

to minor fluctuation of the relative sea –level .These minor fluctuations may be

due to lower rates of subsidence at these sections.

Cycle E shows a similar behavior and can be divided into three fourth order

cycles at Najaf section , cycle F is incomplete due to the truncation by the upper

unconformable surface (SB1) of the Dammam Formation . The massive

dolomitized interval at the top of Dammam at the Samawa section masked the

original depositional texture and facies and consequencetly the nature of cycles E

and F.

4.2.3.2 Euphrates –Nfayil cycles

Deposition of the Euphrates and the Nfayil was due to a major sea-level rise

and three third order cycles were recognized in the studied sections . These cycles

are different in all aspect (symmetry , thickness and stacking pattern ) from one

section to another . This may be attributed to local changes in tectonic subsidence

which have affected the velocity of relative sea –level rise and the nature and

subdivision of these cycles.

Cycle G is bounded below by a transgressive surface (TS) which coincides

with the lower unconformable contact with the underlying Dammam Formation .

This cycle is underlain by SB1surface .Cycle G at Samawa and Najaf sections are

nearly of the same thickness and represented by transgressive systems tract.This

parasequence at these sections consists of restricted facies in Samawa and shoal

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facies at the Najaf section .This cycle can be divided into four fourth order cycles

(G1,G2,G3 and G4) at Karbala section, this together with its high stand systems

tract being thicker at Karbala section may suggest the almost equal effect of

eustatic and tectonic component . This is contrary to the case at the Samawa and

Najaf where eustacity was the major controlling factor . This may explain the

difference in thickness of the basal conglomerate .

Cycle H is thin and shows the change into lower accommodation in all sections

and can be divided at the Najaf section into two fourth order cycles in that area of

relatively low rate of subsidence .

Cycle I is incomplete and truncated by (SB1) and shows the maximum

thickness at Karbala section where the transgressive systems tract is represented by

deep facies followed by a thick high stand systems tract (HST) of the shoal ,

restricted and peritidal facies . This cycle was divided into a number of fourth

order cycles at the Najaf section .It may also be due to the major control of the

eustatic component in this area of low rate of subsidence .Fig 4.1

4.2.4 Basin development in the Miocene

The Miocene succession in the study area was developed in an area of low

subsidence which reflects the major effect of eustacy as the main controlling factor

in sequence development . .

The Euphrates-Nfayil succession was deposited on a slowly subsiding carbonate

platform as a result of a major transgression where successive episode of sea level

rise and still stand , were responsible for the formation of three third order cycles

and a number of fourth order cycles within third order cycles . A block movement

may explain the variation in potential accommodation from one section to another

.This may result of the tectonic component being the major controlling factors

during the deposition of the Miocene succession at Karbala area.

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4-2-4 Diagenetic Model

For simplicity ,the diagenetic characters for the three formations, will be

discussed separately .

The Nfayil Formation was diagenetically less affected. On the basis of former

studies , Nfayil can be divided into upper and lower members ,both are present at

Karbala section only. The upper Nfayil (mostly cycle I) was affected by

neomorphism . The lower (interbedded marls and limestones ) , limestone units

also gained neomorphism . Intraparticle cement is found at its upper limestone

unit. Vugs and moldic pores is found at its lower limestone unit. The presence of

intraparticle cement indicates passing through marine phreatic zone ,while

neomorphism is gained by passing through fresh water phreatic zone. Reaching the

vadose zone , dissolution has affected the rocks creating vugs porosity .

At Najaf and Samawa sections , only the lower member of Nfayil Formation is

encountered . It shows the same diagenetic imprints , neomorphism is less

effective, cement nearly rare at Samawa , vugs also present .

The succession of these processes may indicate a state of fast rising of the sea-

level. Tuker , (2005) suggested the rates of sea level change are too rapid , then

there may not be sufficient time for dolomitization to take place. This fact will

clarify absence of dolomite in the Nfayil Formation.

The Euphrates Formation at Samawa shows neomorphism and vugs for the

crystalline limestone while at Najaf only vugs and moldic pores. At Karbala

section the same features are present but with different pattern i.e. cementation is

on and off, vugs also . Current study suggest that the lower part stayed at the

stagnant fresh water phreatic while the upper part when cement and neomorphism

appeared together in the same rock meaning its presence within the active fresh

water phreatic zone ( Longman,1980).

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The basal conglomerates are dolomite pebbles with cementing material .

Dolomite pebbles may be the result of the exposure of the Dammam Formation .

The Dammam Formation is affected by diagenesis differently in the studied

sections .The rising sea-level at Karbala section gave the rocks ,neomorphism with

cementation types like syntaxial rim overgrowth , geopetal and interparticle

cements ,also intraparticle cement (an early diagenetic cement type) . The

association of neomorphism with syntaxial rim overgrowth indicates passing

through the active fresh water phreatic zone ( Longman ,1980) .Tuker , (2005)

suggested that during relative sea-level rise , ground water zones move landward

through carbonate platform , so the transgressive system tracts sediment will be

subject to marine diagenetic processes and sediments could well have abundant

marine cements, but if they move into the shallow –burial , a stagnant marine

diagenetic environment relatively rapidly then they will not suffer any further

cementation. Cycle B,C, D, E and parts of A at Samawa also shows the same

features .

The dolomite at Samawa section is thick and beneath an unconformity (both

features are indicative of mixing zone dolomitization ). Tuker (2005) suggested

that during the high stand , the main diagenetic pattern will be an initial marine

diagenesis replaced in time either by supratidal diagenesis and evaporative

dolomitization or meteoric dissolution , cementation and mixing zone related

dolomitization depending on climate( Tuker ,2005 ). This study adapted the above

explanation for the Dammam Formation . .

The Dammam Formation at Najaf section undergone dolomitization and leaching

of Nummulite fauna (cycle A-D2 ) (only D1 showed some neomorphism )After

that cycles E1-F show dolomitization and vugs .

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Diagenetic model for the studied Eocene-Miocene succession suggests : after

the deposition of the Dammam Formation by rising sea-level a subtidal model of

dolomitization at Najaf section affected the succession while neomorphism

associated with different cements took place at Karbala and Samawa. Reaching D

cycle , a high stand condition might begin causing another episode of

dolomitization by mixing conditions which was associated with silicification .

Dedolomites are caused by aquifers . After the Oligocene break , fast rising sea-

level put the Euphrates and Nfayil formation in the fresh water phreatic zone of

diagenesis (both stagnant and active ) showing neomorphism with or without

cementation . No dolomitization occurred .(Fig.4-2)

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CHAPTER FIVE

Summary and

Conclusions

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Summary and Conclusion chapter five

Summary and Conclusions

1. On the west of the Euphrates river ,south west of Iraq , three boreholes and

two outcrops were fully investigated for the study of the Eocene- Miocene

succession. It revealed three formations : the Dammam Formation , the

Euphrates Formation, and the Nfayil Formation .

2. Thin sections were petrographically studied . Two types of grains ; skeletal

and non-skeletal were found within the Nfayil formation ; they are miliolid ,

Dendritina , rotalid , and Elphidium , mollusks as skeletal ones . Non-skeletal are

Peloids , Ooids, intraclasts , and extraclasts .

Moulluscs , a most dominant skeletal component , are found as whole shells

and fragmented . Molluscs molds are found at Karbala section due to the effect

of diagenesis . Oysters at the field were recognizable with unaided eyes

differentiating limestone of the second cycle within the lower part of the Nfayil

formation , may be as coqina .

3. Miogypsina SP.( an index fossil for the Euphrates formation) is recorded for

the first time , included in the limestone unit directly above the olive green marl

index unit of the Nfayil Formation .

4. The Euphrates Formation consists of the lower part ( basal conglomerate) and

the upper (limestone ) . Basal conglomerate consisted of (1-4 cm ) pebbles of

dolomite imbracing recrystallized mollusks .

Limestone under the microscope reveals : Miogypsina sp. ( an index fossil )

Peneroplis , Dendritina , Ammonia beccarii , rotalid , mollusks , echinodermata

fragments , and microtubes .

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Peloids are the major non- skeletal elements.

5. The current study suggests that if the Nfayil Formation is a different formation

than the Euphrates Formation , the boundary between them must be shifted to a

new position . This will be taken above the Miogypsina sp. index fossil

disappearance. The latter includes the limestone unit directly above the olive

green marl .

6. The Dammam Formation is rich in skeletal grains only . The index fossil is

the Nummulites sp. others are Lindrina sp ; Alveolina sp ., Discocyclina ; also

bryozoa and shell fragments .

Tremindes diagenetic effect left Nummulitic moldic pores and other fossils at

Najaf section .

The Nummlites sp. is associated with different groups of fauna ; a. Nummulites

sp. with shell fragments and echinodermata fragments.

b. Nummulites sp. with Alveolina sp. , c- Nummulites sp. with bryozoa , d.

Nummulites sp. with miliolid .

Large size Nummulites sp. is a fundamental concept in differentiation shoal

environment.

7. Four environments are distinguished in the Nfayil Formation. These include

:A) Peritidal environment which is characterized by intraclastic mud-

wackestone , extraclastic wackestone –packstone and intraclastic wackestone

–packstone. B) Restricted environment is represented by Bituminous siltstone ,

Silty lime mudstone , recrystallized lime mudstone , peloidal intraclastic

packstone and more restricted environment which include Miogypsina sp. with

miliolid. C) shoal environment is characterized by the Ooid wackestone –

packstone and intraclastic bioclastic packstone-grainstone . D) deep marine

environment represented by many layers of green marl.

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8. Facies analysis shows four environments for the Euphrates Formation ; A)

restricted environment represented by recrystallized limestone , peloidal

packstone , Dendritina packstone facies . B) shoal environment which is

characterized by peloidal grainstone , intraclastic peloidal packstone-

grainstone microfacies . C) open marine environment represented by

Miogypsina sp. packstone , fossiliferous packstone , bioclastic wackestone-

packstone microfacies . D) deep marine environment ,two facies possibly fit in

this environment were : marl beds and microbioclastic packstone .

9. Four environments are recognized within the Dammam succession , these are

: A) peritidal environment represented by the dolomite , B) restricted

environment characterized by the presence of Alveolina sp. , miliolid with or

without the presence of Nummulites sp. and represented by recrystallized

limestone. C) open marine environment represented by Nummulites sp. were

small size with presence of bioclastics , Nummulites fragments , echinodermata

fragments as packstone or wackestone microfacies . D) shoal environment

characterized by either larger size of Nummulites sp. or texture is grainstone like

Nummulitic packstone – grainstone .

10. Several diagenetic processes affected the Eocene – Miocene succession ,

they include : neomorphism , dissolution ( mold porosity , vugs ) ,

dolomitization , cementation , silicification , and dedolomitization , these

processes are related to three main diagenetic environments ; marine phreatic ,

mixing , meteoric phreatic .

Cementation processes is recognized within the succession resulting in the

formation of many types of cement such as syntaxial rim cement , intraparticle

cement , interparticle cement , geopetal cement . Neomorphism which has

resulted in microsparite , dissolution (moldic porosity and vugs ) highly affected

the Dammam Formation and formed many types of porosity making the

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Dammam Formation a good water aquifer . Four types of porosity are

recognized throughout the succession , they are : intraparticle porosity , moldic

porosity , vugy porosity and channel pores . Silicification process is limited but

the cementation , neomorphism and dolomatization are common .

11. Five third order cycles ( A, B,C, D and E) are designed for the Dammam

formation . Cycle D is divided into two 4th

order cycles due to minor fluctuations

at Samawa and Najaf . Another cycle( F ) is designed at the top of Najaf and

Karbala sections, cycle E is divided into three 4th order cycles only at Najaf

section . Cycles A and B is not detected at Karbala section .The asymmetry of

cyclicity is due to changing of eustatic sea-level magnitude .

Cycle A is symmetrical at Samawa but asymmetrical at Najaf section .

Cycle B gives opposite situation as being thick and asymmetrical at Najaf

than at Samawa .Thickening may be related a keep up situation due to the

balance between carbonate production and relative sea-level rise .

Euphrates and Nfayil deposition is due to major sea-level rise .Three third

order cycles are designed for this reason , cycles are different in symmetry ,

thickness , and stacking pattern due to local tectonic changes .

Cycle G is underlain by SB1 surface due to the presence of the basal

conglomerate which indicates Oligocene absence from the study sections , and is

divided into four 4th order cycles at Karbala section . Cycle H is divided into two

4th

order cycles at Najaf , Cycle I is incomplete and truncated by an SB1 surface

also it is divided into three 4th order cycles at Najaf section .

12. The current study suggests analyzing the microfossils of the basal

conglomerate between Euphrates and Dammam formations to determine its

origin and age of deposition and comparing it with the basal conglomerate of the

upper Euphrates area .

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المستخلص

يبس ف انصذشاء انجثخ انغشثخ ي انعشاق كشف ع -رزبثع عصشالاس

ششذخ صخشخ ي ثلاثخ أثبس يبئزب رسع ثلاث ,انفشاد، انفبم,جد ركب انذيبو

انطجبل اندم يكشف صخش خضعذ نزذذذ انصخبسخ انفصهخ انز اسزخذيذ نجبء

.نزذش ا

ف كم انمبطع إن جد انذججبد انجشخ انكهخ أشبسد انسذبد انجشخ نهززبثع

غش انكهخ ض ركب انفشاد ،انفبم، انذججبد انجشخ انكهخ فمظ ض رك

.انذيبو

عذد ف رصى اطمخ انصفبد انسجخ انزذجشاد سب انبرجخ ي دساسخ أ انزفبصم

ثئخ ، انمشجخ ي انذ ثئخال رشمانز انسذبد انجشخ انز أدد إن انزمسبد انجئخ

انذبجض انزضذم ، انجئخ انجذشخ انضذهخ انذصسح ثئخ انجذش انعك ثبنسجخ نزك

ح انجذشخ انضذهخ ، انجئانزضذم انفبم رشم انجئخ انجذشخ انذصسح ، ثئخ انذبجض

انفزدخ ثئخ انجذش انعك ثبنسجخ إن رك انفشاد أيب رك انذيبو فأ رشست ض

، انجئخ انجذشخ انذصسح ، ثئخ انذبجض انزضذم ثئخ انجذش انمشجخ ي انذ ثئبدال

. انفزح

الأن ، ي انذنزخ يشدهزإن ف كم انمبطع اشبس نهززبثع انرج انزذش عيب ،

أنذ انذسح انثبخ انزثهخ ثبنجضء ثبندمف انجضء الأسفم ي رك انذيبو انزثهخ

ثجبد ثمبء فزشح أطل ف طبق انخهظ ثسجت ظشف انز أشبسد إن الأعه نهزك فس

انفشاد انفبم ثسجت الاسرفبع لادع غبة انذنزخ نزكبانعبن ، يسز سطخ انجذش

نسهكزخ أدبب كبذ الامطبع انذبصم ف صي الانغس ، ا دانسشع نسز سطخ انجذش ثع

. يصبدجخ إن عهخ انذنزخ

افخ إن أاع يخزهفخ ي انزسذ ف رك انذيبو ضراجذ عهخ انزشكم انجذذ ثبلإ إ

طبق انب انعزثخ ) ثأ انزك رشست ض انجئخ انزذشخ سجخدنمبطع كشثلاء انسب

إعبدح .أضب خلال ركب انفشاد انفبم دذثذ عهخ انزشكم انجذذ انسزخ .(انفعبل

. دذثذ ثست جد انكثش ي انخضابد انبئخ انعشفخ ف انطمخ اوةانذنزخ س

ح ي انذسجخ انثبنثخ رى رشخصب ض رك انذيبو ف يمطع خسخ دساد سسث

انسبح ثسجت انزمهجبد انثبخ نسز سطخ انجذش ف انذسح انشاثعخ فأب لسذ إن

، ف يمطع انجف فمذ رى رض دسح سسثخ أخش، دسر سسثز ي انذسجخ انشاثعخ

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انذساد انشسثخ رثم فزشاد ي ، ر نى رخزشق ف يمطع كشثلاء فب أل دسر سسث

رزجعب ( رزثم ثسذبد انب انجذشخ انضذهخ انفزدخ انعمخ ) اسرفبع يسز سطخ انجذش

. فزشاد ثجبد نسز سطخ انجذش انزثهخ ثسذبد انذبجض انضذم

ثبنذيهكبد انمبعذخ انزثم SB1انذذ انفبصم ث رك انفشاد انذيبو ي ع

يزش ف يمطع كشثلاء ثسك لذس أسثعخ أيزبس ف كم ي يمطع 0.8ثسبكبد يخزهفخ ،

.انسبح انجف

خلال اسرفبع يسز سطخ انجذش ثعذ عصش الانغس أد إن راجذ ثلاثخ دساد

رهف ثزبثهب ثسبكبرب أبط ز انذساد رخ، سسثخ ي انذسجخ انثبنثخ نهمبطع انثلاثخ

انزكذس انسذ نب ي يمطع لأخش زا ادزبل ست إن انزغشاد انذهخ ف انزجهس

. انزكز انز اثش ف سشعخ اسرفبع يسز سطخ انجذش انسج

انفشاد فأ راجذ فق دذح نزك( انبججسب) ف انذساسخ انذبنخ ، انزذجش انذال

. انبسل الأخضش ي انجضء الأسفم نزك انفبم

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وزارة التعليم العالي والبحث العلمي جامعة بغداد

العراق ـ بغداد

مايوسين في –تتابع الايوسين تحليل السحنات المجهرية وطباقية ، جنوب غرب العراق ( السماوة-النجف-كربلاء)

رسالة مقدمة إلى كلية العلوم ـ جامعة بغداد

وهي جزء من متطلبات نيل درجة الماجستير في علم الأرض

من قبل

ضياء خرباط شذر

بأشراف الأستاذ المساعد لميس صادق حسون

2011

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