mineralogical and geochemical studies of the placer ... · mineralogical and geochemical studies of...

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108 Current Science International 3(2): 108-121, 2014 ISSN: 2077-4435 Corresponding Author: Dr. EL-Wekeil, S.S.,Geological Sciences Department, National Research Center, Cairo, Egypt. E-mail: [email protected] Mineralogical and geochemical studies of the placer deposits of Gebel El-Massaid area, north Eastern Desert,Egypt: as a new occurrence for gold mineralization 1 EL-Wekeil, S.S. and 2 Gaafar, F.Sh. 1 Geological Sciences Department, National Research Center, Cairo, Egypt. 2 Egyptian Mineral Resources Authority. ABSTRACT Gold deposits and occurrences located in Nubian Shield have been known in Egypt since Predynastic times.Up till now, economic gold deposits in Egypt are related to the auriferous quartz veins and adjacent alteration zones, in addition to its association with other ore deposit types. Today, alluvial gold deposits are actually important targets for gold in Egypt. Top priority must be given to this target particularly in areas of source rocks with sub- economic concentrations of gold andalso to the large wadies draining towards the Red Sea which may be contain erosional products from known gold occurrences. Gebel El- Massaid area which occupied a part of Esh El-Mallaha range at thenorth part of the Eastern Desert of Egypt is one of the areas where gold in wadi alluvium was located. The study area is drained by Wadi Belli, Wadi Umm Sidrah and Wadi Umm Baqia andcovering an area of about 95 km 2 . Two - hundred and fifty tow (252) samples were collected from the placer depositsat the study area. These samples are subjected to investigations using Flam Atomic Absorption Spectroscopy (F.A.A.S).The study focuses on investigation the mineralogical and geochemical characteristics of the promising samples (55) in order to evaluate the gold concentrations from placer deposits of the study area using several techniques includingfire assay analyses,shaking table,heavy mineral separation usingbromo-form solution (sp. gr. 2.85) and low and high intensity electromagnetic separator. The results of chemical analysis of the collected samples by Atomic Absorption (AA) showedplacer gold in therange of< 0.20 to 0.50 ppm with an average of (0.34 ppm) and silver ranged from 0.02 to 0.50 ppm with an average of (0.24 ppm) in the pit samples from the wadi deposits. While, gold values in the trenches from the wadi deposits that formed high relief old terraces in the study area ranged from < 0.20 to 0.60 ppm with an average of (0.40 ppm) and silver ranged from 0.02 to 1.50 ppm with an average of (0.358 ppm). For promising samples (40 pit samples and 15 trench samples), gold contents in heavy concentrates after fire assay analyses range from 0.33 to 1.59 ppm with an average of (0.52 ppm) in vertical pits (wadi deposits) and from 0.23 to 1.06 ppm with an average of (0.58 ppm) in heavy concentrate of channel samples (trenches samples). The study of heavy fraction revealed that the heavy minerals of the studied samples are consisting of opaque and non- opaque minerals. The opaque minerals constitute a considerable part of the separated heavy fraction, mainly represented by ilmenite, magnetite and rarely hematite. The non- opaque minerals consists of xenotime associated with rutile, monazite, garnet, zircon, heavy silicate and sphene suggesting derivation from mixed igneous (mostly granitic rocks) and metamorphic rocks. The placer gold recorded in the studied area may be coming from: (1) erosion products of granitic sources having gold occurrences where the disintegration and mechanical weathering of these rocks for long time may be sufficient to concentrate economic gold deposits in the alluvial sediments of these rocks or intheir near vicinity, (2) paleosurfaces of erosion (paleoplacers) which are occupied by auriferous conglomerates which may occur at the base of the Upper Proterozoic molasse sediments (Hammamat unit) on the top of gold bearing basement in the studied area, (3) erosion products of known gold occurrence nearby the studied area either from the north ( e.g. Umm Mongul; Umm Balad and Wadi Dib) or from the south (e.g. Fatira), then transported by water stream and deposited in the wadies draining in the studied area (Wadi Belli, Wadi Umm Sidrah and Wadi Umm Baqia). Keywords:Placergold,Wadi deposits, Atomic Absorption Spectroscopy,Mineralogy, Fire assay analyses. Introduction The Eastern Desert of Egypt is well known as a gold-mining area since Pharaonic and Roman times, and more than 90 gold occurrences are reported over the whole area covered by the basement rocks of Precambrian age (Fig. 1).Since ancient times, the gold was extractedfromauriferous quartz veinsin most mineswith various dimensions in open- pits and underground workings. In Egypt, gold is associated with other ore deposit types in addition to the auriferous quartz veins that constituted the main target for gold. Gold mining and process mineralogy receivesmore and more attention from mineralogist (cf. Kochine and Bassuni 1968;El- Ramlyet al., 1970; Sabet and Bordonosov, 1984;Hussein, 1990; Botros, 1991, 1993a and 2004; Hassaan, et al., 1995 and

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Page 1: Mineralogical and geochemical studies of the placer ... · Mineralogical and geochemical studies of the placer deposits of Gebel El-Massaid area, north Eastern Desert,Egypt: as a

108

Current Science International 3(2): 108-121, 2014

ISSN: 2077-4435

Corresponding Author: Dr. EL-Wekeil, S.S.,Geological Sciences Department, National Research Center, Cairo, Egypt.

E-mail: [email protected]

Mineralogical and geochemical studies of the placer deposits of Gebel El-Massaid area,

north Eastern Desert,Egypt: as a new occurrence for gold mineralization

1EL-Wekeil, S.S. and

2Gaafar, F.Sh.

1Geological Sciences Department, National Research Center, Cairo, Egypt.

2Egyptian Mineral Resources Authority.

ABSTRACT

Gold deposits and occurrences located in Nubian Shield have been known in Egypt since Predynastic

times.Up till now, economic gold deposits in Egypt are related to the auriferous quartz veins and adjacent

alteration zones, in addition to its association with other ore deposit types. Today, alluvial gold deposits are

actually important targets for gold in Egypt. Top priority must be given to this target particularly in areas of

source rocks with sub- economic concentrations of gold andalso to the large wadies draining towards the Red

Sea which may be contain erosional products from known gold occurrences. Gebel El- Massaid area which

occupied a part of Esh El-Mallaha range at thenorth part of the Eastern Desert of Egypt is one of the areas where

gold in wadi alluvium was located. The study area is drained by Wadi Belli, Wadi Umm Sidrah and Wadi Umm

Baqia andcovering an area of about 95 km2. Two - hundred and fifty tow (252) samples were collected from the

placer depositsat the study area. These samples are subjected to investigations using Flam Atomic Absorption

Spectroscopy (F.A.A.S).The study focuses on investigation the mineralogical and geochemical characteristics of

the promising samples (55) in order to evaluate the gold concentrations from placer deposits of the study area

using several techniques includingfire assay analyses,shaking table,heavy mineral separation usingbromo-form

solution (sp. gr. 2.85) and low and high intensity electromagnetic separator. The results of chemical analysis of

the collected samples by Atomic Absorption (AA) showedplacer gold in therange of< 0.20 to 0.50 ppm with an

average of (0.34 ppm) and silver ranged from 0.02 to 0.50 ppm with an average of (0.24 ppm) in the pit samples

from the wadi deposits. While, gold values in the trenches from the wadi deposits that formed high relief old

terraces in the study area ranged from < 0.20 to 0.60 ppm with an average of (0.40 ppm) and silver ranged from

0.02 to 1.50 ppm with an average of (0.358 ppm). For promising samples (40 pit samples and 15 trench

samples), gold contents in heavy concentrates after fire assay analyses range from 0.33 to 1.59 ppm with an

average of (0.52 ppm) in vertical pits (wadi deposits) and from 0.23 to 1.06 ppm with an average of (0.58 ppm)

in heavy concentrate of channel samples (trenches samples). The study of heavy fraction revealed that the heavy

minerals of the studied samples are consisting of opaque and non- opaque minerals. The opaque minerals

constitute a considerable part of the separated heavy fraction, mainly represented by ilmenite, magnetite and

rarely hematite. The non- opaque minerals consists of xenotime associated with rutile, monazite, garnet, zircon,

heavy silicate and sphene suggesting derivation from mixed igneous (mostly granitic rocks) and metamorphic

rocks. The placer gold recorded in the studied area may be coming from: (1) erosion products of granitic sources

having gold occurrences where the disintegration and mechanical weathering of these rocks for long time may

be sufficient to concentrate economic gold deposits in the alluvial sediments of these rocks or intheir near

vicinity, (2) paleosurfaces of erosion (paleoplacers) which are occupied by auriferous conglomerates which may

occur at the base of the Upper Proterozoic molasse sediments (Hammamat unit) on the top of gold bearing

basement in the studied area, (3) erosion products of known gold occurrence nearby the studied area either from

the north ( e.g. Umm Mongul; Umm Balad and Wadi Dib) or from the south (e.g. Fatira), then transported by

water stream and deposited in the wadies draining in the studied area (Wadi Belli, Wadi Umm Sidrah and Wadi

Umm Baqia).

Keywords:Placergold,Wadi deposits, Atomic Absorption Spectroscopy,Mineralogy, Fire assay analyses.

Introduction

The Eastern Desert of Egypt is well known as a gold-mining area since Pharaonic and Roman times, and

more than 90 gold occurrences are reported over the whole area covered by the basement rocks of Precambrian

age (Fig. 1).Since ancient times, the gold was extractedfromauriferous quartz veinsin most mineswith various

dimensions in open- pits and underground workings. In Egypt, gold is associated with other ore deposit types in

addition to the auriferous quartz veins that constituted the main target for gold. Gold mining and process

mineralogy receivesmore and more attention from mineralogist (cf. Kochine and Bassuni 1968;El- Ramlyet al.,

1970; Sabet and Bordonosov, 1984;Hussein, 1990; Botros, 1991, 1993a and 2004; Hassaan, et al., 1995 and

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109 Curr. Sci. Int. 3(2): 108-121, 2014

2013 ; Bekhit, et al., 2000; El- Shimi and Soliman, 2002; Abdel Fattah, 2005; Rasmussen and Mortensen, 2007;

Kamel, 2012 ; El- Kazzaz, 2012;Abd El – Rahim, et al., 2013 and Neesse, 2014).

In Egypt, several attempts were done to classify gold mineralization,among these is the early classification

mentioned by Kochine and Bassuni (1968), where they classified thismineralization on the bases of the mode of

occurrence and the nature of mineralization, into three types namely: 1-dyke- type, 2- vein- type and 3- placer-

type.In this classification, there is no sharp boundary between-dyke type andvein- type(Botros, 1991).Sabet and

Bordonosov (1984) classified gold deposits into three formations namely: gold- sulphide formation, skarn gold-

ferruginous quartzite formation and gold quartz vein formation. Thisclassification ignores the tectonic setting of

host rocks, aswellas, the source of the mineralizing fluids(Botros, 2004).A new classification of gold deposits in

Egypt utilizing the geological and tectonic environments that were prevailing during mineralization is offered by

Botros(2004) to serve as a framework for the detailed study of these deposits and to facilitate their correlation

with worldwide deposits.Botros (op. cit.) classified the gold mineralization deposits in Egypt into three types.

These are 1- strata- bound deposits which are subdivided into (gold- bearing Alogma- type Banded Iron

Formation, Gold- bearing tuffaceous sediments and gold- bearing volcanogenic massive sulphide deposits). 2-

non- strata- bound depositswhich are divided into ( vein- type mineralization hosted in wide range of rocks and

disseminated- type mineralization hosted in hydrothermally altered rocks “alteration zone”).3- placer deposits

which are divided intomodern placers (alluvial placers and beach placers) and paleoplacers (lithified placers).

The lithified placers represents by conglomerates which may occur at the base of the Upper Proterozoic molasse

sediments (Hammamat unit) on the top of gold bearing basement and / or the base of Upper Cretaceous Nubian

Formation that overlies on Precambrian igneous and metamorphic rocks hosting the different styles of gold

deposits in Egypt (Botros, 1993a and 2004).

The origin of gold mineralization in the Eastern Desert of Egypt is a matter of controversy. Some opinions

have been proposed, namely that: (1) gold mineralization is a result of hydrothermal activity related to diorite

intrusions of Metarchean (Proterozoic) age (Hume, 1937); (2)gold mineralization is related to the Gattarian

granites (El- Shazly, 1957) or to tectonic and magmatic stages from the geosynclinals stage to the platform

stage, Sabetet al., 1976 b; (3) Taklaet al., 1990 found a relationship between gold mineralization and younger

gabbro in south Eastern Desert. He stated that younger gabbros were favorable source for gold because of their

elevated gold abundance, high above the average background. Moreover, gold contained in the primary

sulphides of these gabbros was available for leaching during oxidation of these sulphides attendant upon the

associated granites. Al- Boghdady (1995) assumed that the granite is the source of the mineralizing fluid while

the younger gabbro is the source of gold, as earlier suggested by (Taklaet al., 1990).Botros (2004) emphasized

that gold mineralization occurs in almost all the island arc and syn- magmatic stage and there is no specific

lithology that could be responsible for gold mineralization, but certain gold mineralization could be hosted in

certain lithology.

Steadily rising gold prices are almoststimulating the need for gold process mineralogy due to increasing

demand for and production of the yellow metal. At the present, low production of gold and the activities are

concentrated on the evaluation of the old closed gold mines and tailing. Therefore, placer gold deposits are

actually important targets as possible gold resources in Egypt by many workers.

Most placer gold deposits accessible to ancient Egyptians were near to the auriferous quartz veins. The

predominant accumulation of ore materials in a mechanically dispersed form in the wadies (dry water courses)

of the Eastern Desert favors the collection of panned samples from the alluvial placers even where the alluvium

contains considerable amounts of wind- blown sand (Bugrov,1974). This method was successfully applied in

Egypt while prospecting for gold in alluvial placers (Sabetet al., 1976 a and b; Botros, 1998 and 2004; Abdel

Rahman et al., 2001 and Abd El- Rahman et al., 2009).

The present level of gold price and recent advances in the extractive metallurgy of gold, deserve the

examination of the possibility of exploration some of the Egyptian placer gold deposits. Indeed, most placer

gold deposits are low grade, but can be exploited because they are loose easily worked materials which require

no expensive mining or crushing. So, the aim of the present work was initiated to look for placer gold deposits

found in the erosion products in the alluvial fill of wadies and from the old high terraces in the area of Gebel El-

Massaid which occupied a part of Esh El-Mallaha range.

Geology of the study area:

Gebel El- Massaid area, north Eastern Desert of Egypt, represents a part of the Late Protrozoic Arabian-

Nubian Shield which in turn constitutes a part of the larger Pan African Orogeny. The area of Gebel El- Massaid

included one of the most conspicuous volcanic of the Late Precambrian rocks in Egypt, referred to as “Dokhan

volcanic’. The area was subject of geological studies by many authors (e.g. Akaad and El- Ramly, 1960; Dardir

and Abu – Zeid, 1972; Abdel Magidet al., 1997). It is occupied by subordinate intermediate to basic and acid to

intermediate volcanic, frequently intercalated with bedded volcaniclastics and Hammamat sediments.

Theintermediate to basicvolcanic were subjected to low grade regional metamorphism, preserving the primary

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110 Curr. Sci. Int. 3(2): 108-121, 2014

structures(e.g. bedding, cross-bedding, layering and lamination). These rocks are associated with few small

outcrops of intrusive gabbro- diorite and tonalite- granodiorite bodies. The above mentioned rocks were intruded

by extensive monzogranite to alkali feldspar granite, hosting large roof pendants of volcanic. The area is

extremely dissected by various types of dykes and veins, felsites and basaltic plug. According to AbdelMagidet

al., ( 1997),the lithostratigraphy ofGebel El- Massaid area beginning with the oldest as follows (Intermediate to

basicmetavolcanics,Gabbro- diorite associations, Tonalite- granodiorite rocks, Dokhanvolcanic, Hammamat

sediments, Monzogranite to alkali feldspar granites, Felsites, Dykes and veins, Basalt plug and Magmatic

rocks).The studied area is characterized by low to high relief. The northern and south central parts have rugged

valleys (wadies) and high mountains, whereas the eastern and western parts form low to moderate hilly

country.The most conspicuous peaks in the area are Gebel Al Khurm Al Asmar, Abu Marwah, Abu Dokhan and

Gebel Qatar. The drainage patterns in the area comprise trellis and dendritic patterns. Most of the wadies belong

to the Red Sea basin. The main wadies draining towards the Red Sea are Wadi Abu Marwah, Wadi El- Massaid,

WadiMalaha, Wadi Umm Sidrah, Wadi Belli and Wadi Umm Baqia (Fig.2 a and b).

The investigated area is located between Lats. 27º 16ʹ and 27º 21ʹ Nand Longs. 33º 21ʹ 11ʺ and 33º 27ʹ 20ʺ

E.It covers an area of about 95 km2. It is drained by WadiBelli, Wadi Umm Sidrah and Wadi Umm Baqiawhere,

they are running from west to east and then to the NE direction (Fig. 2a and b). The wadies follow the major

structure trends in the area. The floor of the wadi is rugged and covered by sands and gravels derived from

nearby lithologic outcrops (Fig. 3), whereas the eastern and western partsformedhigh reliefold terraces, having

fan shape (Fig. 4 and 5).

Fig. 1:Gold deposits and occurrences in the Eastern Desert of Egypt (compiled from Kochine and Bassuni,

1968).

(1) Umm Mongul; (2) UmmBalad; (3) Wadi Dib; (4) Fatira; (5) Abu Marawat; (6) WadiGasus; (7) Semma;

(8) Gebel Semna; (9) Abu Qarahish; (10) KabAmiri; (11) Sagi; (12) Gidami; (13) Hamana; (14) Erediya; (15)

Abu Had; (16) Atalla; (17) Rebshi; (18) Umm Esh; (19) Fawakhir; (20) Hammamat; (21) UmmHad; (22) El Sid;

(23) Umm Selimat; (24) Hammuda; (25) El Nur; (26) Kareim; (27) Kab El Abyad; (28) Tarfawi; (29) Sherm El

Bahaari; (30) Zeidum; (31) WadiZeidum; (32) Umm Rus; (33) Sigdit; (34) TalatGadalla; (35) Abu Muawaad;

(36) Daghbag; (37) El Hisimat; (38) Bokari; (39) Umm Samra; (40) Abu Dabbad; (41) Abu Qaria; (42) Umm

Saltit; (43) Bezah; (44) Umm Selim; (45) Barramiya; (46) Dungash; (47) Samut; (48) Umm Hugab; (49) Urf El

Fahid; (50) Atud; (51) Sukkari; (52) Umm Tundeba; (53) Hanglaliya; (54) Kurdeman; (55) Sabahia; (56) Umm

Ud; (57) Allawi; (58) Lewewi; (59) Dweig; (60) Hamash; (61) Geli; (62) Qulan; (63) Kab El Rayan; (64)

Sheialik; (65) Abu Rahaya; (66) WadiKhashb; (67) Umm Eleiga; (68) Betan; (69) Qurga Rayan; (70) Hutit; (71)

Kalib; (72) Kurtunos; (73) El Hudi; (74) Hariari; (75) UmShira; (76) Neqib; (77) Haimur; (78) The Nile Valley

(Block E); (79) Umm Garaiart; (80) Marahib; (81) Atshani; (82) Murra; (83) Filat; (84) Seiga I; (85) Seiga II;

(86) Umm Shashoba; (87) Abu Fass; (88) Umm Tuyur; (89) Betam; (90) Umm Egat; (91) Kurbiai; (92) Romit.

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111 Curr. Sci. Int. 3(2): 108-121, 2014

Fig. 2a: Geologic map of the study area after Conoco (1987).

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112 Curr. Sci. Int. 3(2): 108-121, 2014

Fig. 2b:Landsat imageof the study area.

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113 Curr. Sci. Int. 3(2): 108-121, 2014

Fig. 3: Photograph showing Gebel El-Massaid and wadi deposits.

Fig. 4: Photograph show the thickness of wadi deposits that formed high relief old terraces and have fan shape

in the study area.

Fig. 5: The exploratory trench was done to study the wadi depositsthat formedhigh reliefoldterraces in the study

area.

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114 Curr. Sci. Int. 3(2): 108-121, 2014

Material and Methodology

One- hundred and fifty (150)alluvial samples were collected from forty vertical pits at theWadideposits(Fig.

3)with depth from 0.75- 2 m (sampling range from 1- 4 samples in each pit), and one- hundred and two

(102)samplesfrom fifteen exploratory trenches(channel samples, Fig. 4 and 5) were collected from the high

relief old terraces in the study area(sampling rangefrom 1- 16 samplesin each trench). The weight of these

samples range from 10 to 15 kgthen sieve to size -250µmand a representative sample portion ~ 500 gm. are

taken to grind to <100 µm. Then 10 gm from these portion were digested with aqua regia, after that the silver

(Ag) was measured in the resultant solution by Flame Atomic Absorption Spectroscopy (F.A.A.S) GBC Avanta

∑at Wavelength 328.1nm. The gold (Au) was extractfrom the remaining solution by methyl isobutyl ketone

solvent (MIBK) then measured byFlame Atomic Absorption Spectroscopy (F.A.A.S) GBC Avanta∑ at

Wavelength 242.8 nm.Forty(40) promising alluvial samples of the pits and fifteen (15) samples of the trenches

were subjected tothe following laboratory examinations:1- The collected samples were prepared by weighing

the bulk (head) samples at the beginning.2-The samples were concentrated using shaking table Model;

WILFLEY TABLE BALDOR Humphries to separate heavy minerals(heavy concentrate) from light minerals

(quartz and feldspars). The percent of the heavy concentrate was calculated for all the samples pits andtrenches.

A riffle splitterwas used to divide representative dry samplesfrom the heavy crops and three fractions were

used to (1) 50 gramswas taken to analyze gold by fire assay method,in which thepromising samples were

grinded to <100µmthen fused with a suitable fluxing materials and a piece of silver wire in a muffle furnace at

1000ºC. Once the lead(Pb) button is separated from the slag, the Au- Agalloyis extracted from the lead collector

through a process called cupellation at ~ 900ºC. Where lead oxidized and absorbed into the cupel leaving the

alloy bead. Finally, the silver was dissolved by means of nitric acid, washing the gold bead so; we can weigh

gold or dissolve it in aqua regia and measure gold byFlame Atomic Absorption Spectroscopy (F.A.A.S) GBC

Avanta ∑(Fig 6 A and B). (2) 50 gramswas taken to separate heavy minerals from heavy crops using bromoform

solution (sp. gr. 2.85). The weight of heavy concentrate (gm) was calculated. A thin spray of heavy mineral

grains was mounted in Canada balsam. Mineralogical identification was performed by a polarizing

microscope.(3)The rest of heavy crops were subjected to magnetic separation using Laboratory Induced-Roll

High intensity Magnetic Separator Carpco Model; MIH (13) 111-5. Four fractions are obtained according to

magnetic behavior (highly magnetic, moderately, weakly and non- magnetic). All the fractions were studied

under stereoscopic microscope to detect the presence of free gold grains or not.

Sample preparations, Atomic Absorption spectroscopy (AA) and fire assay analysis were done in the

Central Laboratories of the Geological Survey in Cairo, Egypt.

Fig. 6: (A) Photograph of Au – Ag alloy after cupellation process.

(B) Photograph of gold bead extracted by fire assaymethod.

Results and Discussion

Results of Microscopic Investigations:

The study of heavyfraction in heavy concentrates using bromoform solution by polarizing microscope

revealed that the heavy mineralsof the studied samples areconsisting of opaque and non- opaque minerals. The

opaque minerals constitute a considerable part of the separated heavy fraction, mainly represented by ilmenite,

magnetite and rarely hematite. The counts of opaque minerals didn’t take in consideration. Thenon- opaque

minerals consists of xenotime associated with rutile, monazite, garnet, zircon, heavy silicate and sphene.The

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115 Curr. Sci. Int. 3(2): 108-121, 2014

percentages of the heavy minerals (non- opaque) recorded in the studied samples are shown in Tables 1 and 2

and illustrated in Figs. 7 and 8.

The studied of the heavy fractions under stereoscopic microscope (Plate: 1) revealed that four fractions are

obtained according to magnetic behavior. These are highly magnetic, moderately, weakly and non- magnetic.

The high magnetic fraction ismainly made up of magnetite (Plate: 1A), heavy silicate, garnet, sphene and rare

goethite while, the moderately magnetic one is mainly composed of ilmenite (Plate: 1B) with minor garnet,

sphene, goethite, hematite and heavy silicate. The weakly magnetic fraction consists of heavy silicate with

garnet and sphene. The non- magnetic fraction is composed of xenotime, rutile, monazite, garnet, zircon, heavy

silicate and sphene (Plate: 1C). One free gold grain is detected from vertical pit samples (wadi deposits, sample

No. 12, Plate: 1 D). This is more or less confirmed with the results obtained fromseparate heavy minerals from

heavyconcentrates using bromoform solution.Xenotime occurs in the studied samples as sub-roundedshort

prisms with bipyramidal terminations grains, with yellowish brown colors and resinous luster. Rutile occurs in

the form of red to reddish brown long prismatic grains with rounded outlines or sub-rounded grains. Monazite

commonly occurs as well rounded, oval, yellowish green grains. Garnet is present in the form of colorless to

pale pink grains having irregular outlines. Zircon is found as euhedral to sub-hedral, colorless to smoky grains

and sometimes has inclusions of opaque and quartz grains. Sphene occurs as sub-rounded, brown grains.

The association of xenotime associated with rutile, monazite, garnet, zircon and sphene suggesting

derivation from mixed igneous (mostlygranitic rocks)and metamorphic rocks (Blatt and Murray, 1980; Morton

et al., 1992;Larsen, 1996;Gaines et al., 1997; Rosa et al., 2010 Ramadan et al., 2012).

Table 1:Heavy mineralsanalysis of the pit samples.

Ser. No.

Wt. Heavy conc. (gm)

Heavy minerals in frequency (Wt. %)

Xen

oti

me

%

Ruti

le

%

Mon

azit

e

%

Gar

net

%

Zir

con

%

Hea

vy

Sil

icat

e

%

Sp

hen

e

%

1 0.21 0.002 0.020 0.008 0.008 0.040 0.030 0.010

2 0.12 0.005 0.010 0.006 0.005 0.030 0.005 0.020

3 0.26 0.010 0.010 0.003 0.010 0.060 0.010 0.030

4 0.24 0.002 0.010 0.0 0.003 0.020 0.010 0.090

5 0.20 0.0 0.004 0.0 0.0 0.100 0.010 0.080

6 0.23 0.002 0.020 0.002 0.030 0.040 0.060 0.080

7 0.16 0.008 0.010 0.001 0.010 0.040 0.030 0.030

8 0.16 0.0 0.001 0.0 0.008 0.040 0.0 0.020

9 0.14 0.008 0.008 0.002 0.010 0.030 0.030 0.010

10 0.17 0.002 0.010 0.008 0.008 0.050 0.008 0.010

11 0.19 0.002 0.010 0.002 0.010 0.040 0.010 0.030

12 0.19 0.0 0.010 0.002 0.010 0.040 0.010 0.010

13 0.19 0.002 0.020 0.008 0.010 0.010 0.020 0.020

14 0.24 0.002 0.020 0.012 0.010 0.040 0.010 0.030

15 0.11 0.002 0.006 0.0 0.006 0.040 0.006 0.010

16 0.17 0.0 0.010 0.002 0.002 0.050 0.002 0.020

17 0.17 0.010 0.010 0.002 0.010 0.100 0.020 0.020

18 0.14 0.002 0.010 0.002 0.010 0.030 0.020 0.020

19 0.19 0.010 0.008 0.002 0.010 0.010 0.030 0.020

20 0.14 0.007 0.010 0.002 0.010 0.020 0.020 0.010

21 0.15 0.0 0.010 0.0 0.007 0.030 0.010 0.010

22 0.20 0.0 0.010 0.002 0.002 0.030 0.010 0.070

23 0.16 0.008 0.100 0.002 0.008 0.050 0.030 0.030

24 0.13 0.010 0.010 0.010 0.010 0.090 0.006 0.010

25 0.17 0.0 0.020 0.006 0.002 0.040 0.002 0.030

26 0.20 0.0 0.010 0.002 0.010 0.060 0.002 0.060

27 0.19 0.0 0.020 0.002 0.010 0.050 0.010 0.050

28 0.18 0.002 0.010 0.002 0.002 0.040 0.010 0.020

29 0.16 0.0 0.008 0.002 0.008 0.010 0.008 0.010

30 0.20 0.0 0.020 0.002 0.010 0.040 0.0 0.030

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31 0.15 0.007 0.010 0.0 0.010 0.030 0.010 0.030

32 0.22 0.0 0.020 0.002 0.040 0.060 0.040 0.040

33 0.12 0.0 0.010 0.002 0.002 0.090 0.040 0.030

34 0.14 0.002 0.010 0.002 0.002 0.070 0.009 0.040

35 0.14 0.002 0.010 0.002 0.0 0.090 0.030 0.040

36 0.15 0.0 0.010 0.002 0.002 0.040 0.010 0.030

37 0.16 0.0 0.020 0.002 0.008 0.030 0.0 0.040

38 0.22 0.0 0.011 0.002 0.011 0.070 0.0 0.060

39 0.16 0.002 0.010 0.002 0.008 0.040 0.010 0.060

40 0.11 0.002 0.050 0.0 0.020 0.030 0.050 0.050

Min. 0.11 0.0 0.001 0.0 0.0 0.010 0.0 0.010

Max. 0.26 0.010 0.100 0.012 0.040 0.100 0.060 0.090

Aver. 0.173 0.003 0.015 0.003 0.009 0.046 0.016 0.033

Fig. 7:3D pie chart of heavy mineralsdistribution in the pit samples.

Table 2:Heavy mineralsanalysis of the trenchsamples.

Ser.

No.

Wt. Heavy

conc. (gm)

Heavy minerals in frequency (wt.%)

xen

oti

me

%

Ruti

le

%

Mon

azit

e

%

Gar

net

%

Sp

hen

e

%

Zir

con

%

Hea

vy

Sil

icat

e %

1 0.10 0.001 0.005 0.001 0.010 0.005 0.030 0.020

2 0.06 0.0 0.030 0.0 0.003 0.001 0.010 0.003

3 0.11 0.001 0.005 0.001 0.030 0.050 0.020 0.020

4 0.07 0.003 0.003 0.0 0.010 0.001 0.010 0.010

5 0.10 0.005 0.010 0.0 0.010 0.010 0.020 0.020

6 0.12 0.0 0.010 0.0 0.001 0.060 0.005 0.020

7 1.49 0.015 0.030 0.015 0.020 0.150 0.030 0.470

8 0.06 0.001 0.010 0.0 0.010 0.003 0.020 0.020

9 0.11 0.0 0.010 0.0 0.0 0.060 0.010 0.005

10 0.17 0.002 0.010 0.002 0.020 0.010 0.060 0.020

11 0.14 0.0 0.007 0.001 0.001 0.010 0.080 0.070

12 0.10 0.005 0.005 0.0 0.010 0.020 0.010 0.160

13 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0

14 0.08 0.004 0.004 0.0 0.010 0.010 0.020 0.030

15 0.18 0.010 0.010 0.0 0.020 0.020 0.030 0.050

Min. 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0

Max. 1.49 0.015 0.030 0.015 0.030 0.150 0.080 0.470

Aver. 0.193 0.003 0.010 0.001 0.010 0.027 0.024 0.061

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117 Curr. Sci. Int. 3(2): 108-121, 2014

Fig. 8: 3D pie chart of heavy mineralsdistribution in the trench samples.

Plate. 1: (A) Photomicrograph showing sub-angular to angular grayish black metallic luster grains of magnetite.

(B) Photomicrograph showing angular to sub-angular purplish gray to black metallic luster grains of

ilmenite.

(C) Photomicrograph showing heavy mineral varieties: 1-2 Rutile 3- Sphene 4- Heavy silicates 5-6 Zircon7-

Garnet.8- Xenotime 9- Monazite:

(D) One free gold grain is detected from vertical pit samples disseminated with rutile and fractions of zircon

(wadi deposits, sample No. 12).

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118 Curr. Sci. Int. 3(2): 108-121, 2014

Results ofChemical Analyses:

The geological and geochemical exploration revealed the presence of gold in the wadi depositsin the area

under investigation. The chemical analysis of the collected samplesby Atomic Absorption (AA) for gold(Au)and

silver (Ag)from forty (40) vertical pits andfrom fifteen (15) exploratory trenches were collected from thehigh

relief old terraces at Wadi deposits revealed that gold values in the alluvium ranged from < 0.20 to 0.50 ppm

with an average of (0.34 ppm) and silver ranged from 0.02 to 0.50 ppm with an average of(0.24 ppm).While,

gold values in the trenches ranged from < 0.20 to 0.60 ppm with an average of (0.40 ppm) and silver ranged

from 0.02 to 1.50 ppm with an average of (0.358 ppm). For promising samples (40 pit samples and 15 trench

samples), gold contents in heavy concentrates after fire assay analyses range from 0.33 to 1.59 ppm with an

average of (0.52 ppm) in vertical pits (wadi deposits, Table3) and from 0.23 to 1.06 ppm with an average of

(0.58 ppm) in heavy concentrate of channel samples (Table4). Theresults of chemical analyses revealed that the

gold contents in heavy concentrates from nearby sample No. 10 and sample No. 12 from vertical pits have a

relatively high values than all samples examined (1.59 and 5.93 ppm, respectively), which gives a promising

aureoles in this site.

Table3: Heavy concentrate and gold content in pits.

Ser. No. Heavy concentrate of Pit

(%)

Gold content of pit by fire

assay (ppm) Ser. No.

Heavy concentrate

of Pit (%)

Gold content of pit by fire

assay (ppm)

1 4.06 0.35 21 4.94 0.41

2 2.80 0.42 22 3.43 0.33

3 3.75 0.55 23 4.80 0.39

4 2.20 0.38 24 3.88 0.36

5 2.15 0.67 25 4.19 0.37

6 4.04 0.51 26 2.99 0.45

7 2.98 0.57 27 4.36 0.37

8 2.60 0.39 28 4.60 0.46

9 3.06 0.55 29 4.44 0.47

10 2.62 1.59 30 5.30 0.62

11 3.49 0.57 31 4.15 0.86

12* 3.20* 5.93* 32 4.20 0.38

13 2.93 0.44 33 3.19 0.51

14 2.50 0.38 34 4.61 0.83

15 1.76 0.48 35 4.54 0.59

16 2.47 0.39 36 3.08 0.67

17 3.45 0.54 37 3.41 0.49

18 3.34 0.46 38 2.63 0.65

19 3.80 0.43 39 1.40 0.44

20 1.97 0.39 40 4.01 0.45

Minimum 1.40 0.33

Maximum 5.30 1.59

Average 3.44 0.52

*Sample No. 12 excluded from statistics calculation.

Table4: Heavy concentrate and gold content in trenches.

Ser.No. Heavy concentrate of trench(%) Gold content in trench by fire assay (ppm)

1 6.30 0.26

2 5.16 0.30

3 11.47 0.23

4 6.36 0.30

5 5.51 0.47

6 5.92 0.87

7 6.57 0.32

8 7.67 0.43

9 5.36 1.06

10 4.94 0.64

11 4.89 0.81

12 4.70 0.82

13 3.51 0.98

14 6.17 0.58

15 7.79 0.62

Min. 3.51 0.23

Max. 11.47 1.06

Aver. 6.15 0.58

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119 Curr. Sci. Int. 3(2): 108-121, 2014

Conclusion and recommendations:

The previously held opinion that gold deposits in Egypt are restricted to some quartz veins that were

extensively worked out in pharaonic times can’tbe acceptedtoday. Recently,alluvial gold deposits are actually

important targets for gold in Egypt, although, most placer gold deposits are low grade. The present paper

advocated that gold can be extracted from the wadi deposits. In the present work, the area under investigation is

drained by WadiBelli, Wadi Umm Sidrah and Wadi Umm Baqia. The results offire assay

analysisofheavyconcentratesrevealed that gold contents in the alluvium (40 pit samples and 15 trench samples)

in the area are ranging from0.33 to 1.59 ppm with an average of (0.52 ppm) in vertical pits fromwadi deposits

and from 0.23 to 1.06 ppm with an average of (0.58 ppm) in trenches samples from high relief old terraces.

The writers believe that the placer gold recorded in the studied area may be coming from(1)erosion

products of granitic sources having gold occurrences where the disintegration and mechanical weathering

ofthese rocks for long time may be sufficient to concentrate economic gold deposits in the alluvial sediments of

these rocks or in their near vicinity, (2) paleosurfaces of erosion (paleoplacers) which are occupied by auriferous

conglomerates which may occur at the base of the Upper Proterozoic molasse sediments (Hammamat unit) on

the top of gold bearing basement in the studied area, (3) erosion products of known gold occurrence nearby the

studied area either from the north( e.g. Umm Mongul; Umm Balad and Wadi Dib) or from the south ( e.g.

Fatira), then transported by water stream and deposited in thewadies draining in the studied area ( Wadi Belli,

Wadi Umm Sidrah and Wadi Umm Baqia).

From the previous study the following recommendations should be taken in consideration:

Gebel El- Massaid area is highly recommended for further detailed work. Exploration for placer gold

deposits is also recommendedat this area.

Most of the old mines have dumps and tailings containing appreciable amount of gold. This may be

due to the primitive technologies existed or low price of gold at that time or due to sudden shut down of

mines.So, more attention must be paid to this concern and encourage small scale miners.

Attention should be paid to prospecting for the dispersed- type gold deposits in Egypt. These include:

(1) banded iron formation of Alogma type, (2) massive sulphide deposits, (3) wall- rock alterations”alteration

zones”, (4) auriferous felsites dykes and (5) disseminated gold in volcanic rocks.

The future of gold mining and processing in Egypt is a bright one. Extensive exploration,

mineralogical, petrographic and processing research work is necessary for profitable exploration of the gold

resources in Egypt.

Recently, using multi gravity separator model Mozley increasing the concentration of gold. The main

benefits of this tool are: (1) Suitable for the recovery of ultra fine particles (down to one micron) which may be

contain gold that lost in shaking table. (2) Selectivity, by separating particles with specific gravity differences

down to 0.5 (specific gravity of gold is 19.3). (3) This tool considered as environmental friendly in the field of

ores dressing for separation processes without using any chemicals.

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