models & model development
DESCRIPTION
Models & Model development. ThermoTech key-note lecture by Tore Haug-Warberg Department of Chemical Engineering NTNU December 4, 2003. What is a model ?. - PowerPoint PPT PresentationTRANSCRIPT
Models & Model development
ThermoTech key-note lecture
by
Tore Haug-Warberg
Department of Chemical Engineering
NTNU
December 4, 2003
What is a model ?
The model (i.e. the abstract concept) is used virtually everywhere e.g. in: Organization theory, economy, politics, planning, computer science, mathematics, physics, psychology, ... Several of these disciplines are represented in this room, and we should really look for a common definition to secure the planning of the ThermoTech project!
Definitions
Law: Regularities existing in objects and events - both observed and posited.
Theory: Postulation system from which laws are deducible as theorems.
Model : Set of constitutional equations turning a theory into a closed equation hierarchy.
2nd lawGravity
Examples (I)
Definitions are OK but examples are some-times better. Let’s have a closer look at the ideal gas (this is the most unifying non-trivial concept I can think of).
Ideal gas (PV=NRT)
Law : R. Boyle (1627-91), J. Charles (1746-1823) and A. Avogadro (1778-1850).
Theory: J. C. Maxwell (1831-79), L. Boltzmann (1844-1906) and J. W. Gibbs
(1839-1903) => statistical mechanics
Model : L. Tisza (1961)
Ideal gas law
The works of Robert Boyle (1627-91), Jaques Charles (1746-1823) and Amedo Avogadro (1778-1850) indicated that PV=NRT is a good approximation for typical gases like air and air components, This investigation took about 150 years of pondering and experimental work!
Ideal gas theory
Statistical mechanics was founded by James Clerk Maxwell (1831-79), Ludwig Boltzmann (1844-1906) and Josiah Willard Gibbs (1839-1903):
Ideal gas is reached by setting: U=0 (model)
V
ZkTp
rdrdeN
Z NkTrrU
NN
ln!
11
/,,3
1
Ideal gas model
Laszlo Tisza formulated in 1961 the Gibbsian thermodynamics as 4 postulates. Within this framework it can be shown that any pV equation-of-state must be on the form p=f(N/V,T). Hence, the simplest conceivable model is p=a(N/V)T. Note that parameter a cannot be resolved by thermodynamic theory alone => measurements (instantition problem)!
Examples (II)
James Clerk Maxwell formulated in 1876 the theory of electromagnetism
which in fact is a closure (no models needed)
dsIudl
dsdl
ds
qds
dtd
dtd
uεB
uBε
uB
uε
0
/
Examples (III)
Fluid mechanics:
Constitutional models:
vΠjqvv
vvΠ
jvvv
:htu
t
iiitc
uh
p
cci
IvvvΠ
j
q
32T
ii cD
T
Examples (IV)
Thermodynamics phase equilibrium:
Saul-Wagner 235-parameter model for water and steam:
ii
iAcrobat Document
Paradigm
A model can be “anything” from a simple statement U=0 to a set of equations with hundreds of parameters. The more advanced a theory is, the less complex the model needs to be:
This follows from the requirement that
ConstantComplexityComplexity TheoryModel
ClosureModelTheory
Conclusion
In mathematical “modeling” it is important to know where the theory stops and the modeling starts, and what are the assumptions and parameters:
TheoryAssumptions
Simplification
Constitutional models
ClosureParameters
Simulation model