module c1.4
DESCRIPTION
Module C1.4. Crude oil and fractional distillation. Objectives. Must Recall that crude oil is a mixture of a large number of compounds Should Define the term hydrocarbon Could Explain how the compounds in crude oil can be separated using physical methods including fractional distillation. - PowerPoint PPT PresentationTRANSCRIPT
Module C1.4
Crude oil and fractional distillation
Objectives
MustRecall that crude oil is a mixture of a large number of compoundsShouldDefine the term hydrocarbonCouldExplain how the compounds in crude oil can be separated using physical methods including fractional distillation
Starter
• In your class books leave a gap to stick in your C1.3 booklets.
• Write a new titles C1.4 Crude Oil
Starter
• Video about crude oil (BP education)
• Watch the video about crude oil and jot down answers to the following:
• What is crude oil made of?• What do we use crude oil for?
Crude oil
Crude oil is a mixture of a very large number of compounds and is made from the the bodies of plants and animals that have decayed many millions of years ago.
A mixture is two or more substances NOT chemically combined together (such as a mixture of sand and water that can be separated by filtration).
Hydrocarbons
• Most of the compounds in crude oil consist of molecules made up of hydrogen and carbon atoms only.
• We call these HYDROCARBONS• We can separate the different unchanged
hydrocarbons from crude oil by FRACTIONAL DISTILLATION.
Uses of crude oil
• Crude oil can be separated using a technique called FRACTIONAL DISTILLATION
• Fractional distillation produces products we can use for lots of different applications.
• What applications did you come up with?
Jet fuel
Petrol and diesel
Plastics and polymers
Fractional distillation• Fractional distillation separates a mixture into a number of
different parts, called fractions. • A tall column is fitted above the mixture, with several
condensers coming off at different heights. • The column is hot at the bottom and cool at the top.
Substances with high boiling points condense at the bottom and substances with low boiling points condense at the top.
• Fractional distillation works because the different substances in the mixture have different boiling points.
• Click above link for BP Education service videos.
Fractional distillation
Key points for exam questions
To explain fractional distillation [3 marks]1. Heat crude oil to make it a gas/vapour2. Cool to condense3. Hydrocarbons condense at different
temperatures (boiling points).
Different hydrocarbon – different BP
• Different hydrocarbons have different numbers of carbon atoms.
• The higher the number of carbon atoms the higher its boiling point.
Key points for exam questions
• A fraction is a set of hydrocarbon molecules of similar size and similar boiling points
Plenary
• Now attempt booklet questions • Q2(a) and 2(b).• Q3 (i) and (iii)• Q5 (a)(i) AND• Q6 (a)(i)
C1.4 Crude oil
Lesson 2 - alkanes
Objectives
Must• Recall that most of the compounds in crude oil
consist of hydrocarbons called alkanes.Should• Describe the general formula of an alkane and
draw the structure.Could• Explain the naming of alkanes up to a chain length
of four carbon atoms.
Starter
Oil samples
Using BP oil sampleshttp://www.bp.com/genericResource.do?categoryId=8043&contentId=7037455
Identify low molecular weight (gases), medium molecular weight (liquids) that can be obtained from fractional distillation of crude oil
Alkanes
• Alkanes are the name of a type of chemical that makes up the compounds in crude oil.
• They are hydrocarbons (contain only hydrogen and carbon) and form a series of increasing molecular weight.
Hydrocarbons video
• http://www.bp.com/liveassets/bp_internet/bpes_new/bpes_new_uk/STAGING/protected_assets/flash/secondary_resources/clip_bank/index.html#properties_of_hydrocarbons
Carbon chains
• Alkanes are chains of carbon atoms with hydrogen atoms attached to them.
• There is an alkane with one carbon atom, two carbon atoms, three, four, five and so on. The chains can be massive with hundreds of carbon atoms.
• You need be able to name and draw the first four and recognise some larger ones.
MethaneOne carbon atom bonded to four hydrogen atoms.
Each line represents a single covalent bond.
Ethane
Two carbon atoms six hydrogen atoms
Propane
Three carbon atoms eight hydrogen atoms
Butane
Four carbon atoms ten hydrogen atoms
AfL
• Now attempt question 2(c) in your booklets.• Then attempt question 6(b) in your booklets• Then attempt question 9 in your booklets
Can you spot a pattern?
Every time we increase the number of carbons what happens to the number of hydrogens?
We can work out a general formula for any alkane it is:
CnH2n+2 where n is the number of carbon atomsand 2n+2 is the number of hydrogen atoms
Counting in chemistry
• Rather than the numbers 1,2,3 and 4 when we are counting in chemistry we use the terms:
• meth_ = 1• eth_ = 2• prop_ = 3• but_ = 4• The first four alkanes are therefore called
methane, ethane, propane and butane.
C1.4 Crude Oil
Lesson 3 – properties of hydrocarbons
Objectives
Mustrecall the term alkane and the names for the first four alkanes in the series. State that these substances are commonly used as fuels.Should describe the difference between a saturated and an unsaturated hydrocarbonCould explain the boiling points, flammability and viscosity of hydrocarbon fuels.
Starter - Quiz
1. What is the name of the alkane with the formula CH4
2. What is the name of this alkane?
3. Draw a molecule of propane showing all the bonds.
Starter - Quiz
1. What is the name of the alkane with the formula CH4 - methane
2. What is the name of this alkane? ethane
3. Draw a molecule of propane showing all the bonds.
Spot the difference
Spot the difference
Ethane• All single bonds• Full of hydrogen• Saturated
Ethene• Has double bond• Fewer hydrogens• Unsaturated
Properties
• Some properties of hydrocarbons depend on the size of their molecules.
• These properties influence how hydrocarbons are used as fuels.
• Identify solids, liquids and gases in the following images…
Liquid or gaseous fuels
Liquid/Gas
For this list of substance state whether liquid or gas at room temperature?
Hydrocarbon Boiling point in °C Solid/Liquid/Gas
methane, CH4 -162
butane, C4H10 0
pentane, C5H12 +36
decane, C10H22 +175
Viscosity – new keyword• This simply means thickness of solution.
• For example water has a lower viscosity than treacle
• Generally the higher the molecular weight (longer carbon chain) the more viscous the substance is.
• Bitumen has very long chain molecules and is very viscous and stick (tar).
Plenary - AfL
• Attempt question 1(a)• Attempt question 8(a)
Burning Fuels
Objectives: Complete combustion
Incomplete combustionRemoving impurites
Fuel Examples (where do they come from?)
• Methane• Propane• Butane• Petrol• Diesel• Kerosene• Fuel oil• + many more
Combustion• Complete combustion occurs when
there is enough oxygen – for example when the hole is open on a Bunsen burner.
• The products of complete combustion are carbon dioxide and water.
CH4 + 2O2 CO2 + 2H2O
AfL - Complete combustion
Incomplete combustion• Incomplete combustion occurs
when there is not enough oxygen – for example when the hole is closed on a Bunsen burner.
• The products of incomplete combustion include carbon monoxide and carbon (soot). It is often called a sooty flame.
AfL – incomplete combustion
Carbon dioxide
• Carbon dioxide is a greenhouse gas.• This means it causes GLOBAL WARMING by
trapping heat from the sun within the Earth’s atmosphere.
Carbon monoxide
• Carbon monoxide is an odourless and tasteless POISONOUS GAS.
• If produced in an enclosed space it can be deadly.
Soot/smoke particles
• Particles of carbon from incomplete combustion can be released into the atmosphere.
• This contributes to GLOBAL DIMMING
Other pollutants
• Sulphur present in fuels burns to produce sulphur dioxide.
• At high temperatures oxides of nitrogen may also be formed from nitrogen in the atmosphere.
• These react with water in the atmosphere to form ACID RAIN
Acid rain
Cleaning up
• Undesirable combustion products can be cleaned from emissions before they leave the chimney by using a filter or catalytic converter (cars).
Exam question 1d
Exam question 7c
Exam question 10
Exam question 10
Homework
• Now complete questions 11, 12 and 13 for homework.
C1.4 Crude Oil
Lesson 5 - Biofuels
Objectives
• Recall that biofuels are produced from plant material
• Describe the fuels that can be produced from plant material
• Evaluate the advantages and disadvantages of making fuel from renewable sources.
Starter
• Can you recall some of the uses of crude oil?
The problem with crude
• Crude oil is a limited resource that will eventually run out.
• Alternatives are needed and some are already under development.
Alternative fuels
• http://www.bp.com/liveassets/bp_internet/bpes_new/bpes_new_uk/STAGING/protected_assets/flash/secondary_resources/clip_bank/index.html#combustion_of_fuels
Ethical and environmental issues
• The video described some potential issues with biofuels.
• Can you describe any?
Ethical and environmental issues
• Clearance of rainforests to plant fuel crops• Using land formerly used for food crop
(causing hardship)• Not replacing crops with sufficient crops after
harvest for the process to remain carbon neutral
• Erosion – replacing trees with crops with shallow roots
Carbon neutral• Plants photosynthesise using carbon (dioxide) from
the air• Biodiesel/biothanol releases carbon (dioxide) from
plants • Plants are replanted and photosynthesise,
removing the carbon (dioxide) again.
• (fossil) diesel from crude oil releases ‘locked up’ carbon (dioxide) and doesn’t absorb any CO2
Different types of biofuels
• Ethanol – produced by fermentation of sugars in sugarcane
• Biodiesel – produced from hydrolysis of vegetable oils
Examination question Q14 (b)
Examination question Q14(b)
Mark scheme
Past paper question.
Mark scheme