Upload File

monitoring chemical climate change in america the case for ammonia v. bowersox, c. lehmann, b....

  • Home
  • Documents
  • Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
54
Monitoring Monitoring Chemical Climate Change Chemical Climate Change in America in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office

Upload: elisabeth-west

Post on 22-Dec-2015

213 views

Category:

Documents


0 download

Report

TRANSCRIPT

Page 1: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office

Monitoring Monitoring Chemical Climate ChangeChemical Climate Change

in Americain America

The Case for Ammonia

V. Bowersox, C. Lehmann, B. LarsonAcknowledge – R. Claybrooke

NADP Program Office

Page 2: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office

Air and Rain– the Beginnings of a Chemical Climatology

by Robert Angus Smith (1872)

“When the sulphuric acid increases more rapidly than the ammonia, the rain becomes acidic.”

Page 3: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 4: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 5: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 6: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 7: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 8: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 9: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 10: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 11: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 12: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 13: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 14: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 15: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 16: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 17: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 18: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 19: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 20: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 21: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 22: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 23: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office

Ammonia/Ammonium TrendsAmmonia/Ammonium Trends

Methods:Methods:

trends period: 1985 through 2002

applied Seasonal Kendall Trend Test meteorological seasons (Dec-Feb, etc.) applied four NADP data completeness criteria to accept/reject a season & a site

calculated Sen’s Estimator to quantify trends

Page 24: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 25: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office

Ammonia/Ammonium TrendsAmmonia/Ammonium Trends

Results:Results:

139 sites met completeness criteria for the 18-year trends period

Ammonium Increasing• 124 (89.2%) sites• 58 (41.7%) significant (p<0.05)

Ammonium Decreasing• 15 (10.8%) sites• 2 (1.4%) significant

Page 26: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 27: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 28: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office

Sulfate, Nitrate & Ammonium TrendsSulfate, Nitrate & Ammonium Trends

Results:Results:

Up Sig | Down SigSulfate 7 0 | 132 106Ammonium 124 58 | 15 2Nitrate 70 23 | 69 17

Page 29: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office

Chemical Climate: Chemical Climate: SO4/NH4/NH3/NO3/HNO3

Inorganic SO4 has low volatility & reacts readily with NH3 to form stable salts

• (NH4)2SO4 : NH4/SO4 = 1.00• (NH4)3H(SO4)2 : NH4/SO4 = 0.75• (NH4)HSO4 : NH4/SO4 = 0.50• H2SO4 : NH4/SO4 = 0.00

Ammonia-rich environment: NH4/SO4>1.00 (Seinfeld, Saxena,Tanner,etal.)

Page 30: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 31: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 32: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office

Chemical Climate: Chemical Climate: SO4/NH4/NH3/NO3/HNO3

NH4/NH3/NO3/HNO3 : distribution between aerosol & gas phases depends on SO4, T, TD, PHNO3, PNH3

Ammonia-excess: NH4-[(SO4+NO3+Cl) - (base cations)] > 0 (Blanchard, etal., 2000, JAWMA)

Page 33: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 34: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 35: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 36: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office

NH4 increased at ~90% (42% significant) of sites & SO4 decreased at ~95% (76% significant) of sites between 1985 and 2002.

Monitoring Monitoring Chemical Climate ChangeChemical Climate Change

in Americain AmericaThe Case for Ammonia

These trends, accompanied by locally significant changes in NO3, have increased the ammonia-excess, altering the SO4/NH4/NH3/NO3/HNO3

chemistry in air and precipitation in the United States.

Page 37: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office

Monitoring Monitoring Chemical Climate ChangeChemical Climate Change

in Americain AmericaThe Case for Ammonia

The NADP provides a long-term high-quality database for studying our chemical climate.

Page 38: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 39: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 40: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 41: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 42: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 43: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 44: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 45: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 46: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 47: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 48: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 49: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 50: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 51: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 52: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 53: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office
Page 54: Monitoring Chemical Climate Change in America The Case for Ammonia V. Bowersox, C. Lehmann, B. Larson Acknowledge – R. Claybrooke NADP Program Office

NADP NOS/Joint Committee Minutes Fall 2000nadp.slh.wisc.edu/committees/minutes/fall00/nos-Joint...NADP 2000 Technical Committee Meeting - Saratoga Springs, New York - Joint Session

2 J. Richard Bowersox , David A. Williams , John B. Hickman

160912 - UKAD v Slowey - NADP Decision

NATIONAL AGRICULTURE DEVELOPMENT PROGRAMME (NADP)

Mechanistic Insights into Ferredoxin-NADP(H)-Reductase ... · Mechanistic Insights into Ferredoxin-NADP(H)-Reductase Catalysis Involving the Conserved Glutamate in the Active Site

NADP Advocacy in Action

p42922a gce biol u4 6bi04 01 jun14 v2 - Cherry Hill Tuitioncherryhilltuition.com/A.Bio.EDEXCEL(B).QP23.pdfA ADP and oxidised NADP B ADP and reduced NADP C ATP and oxidised NADP D ATP

NADP Proceedings 99-01nadp.slh.wisc.edu/lib/proceedings/abstracts99.pdf · 2006. 3. 16. · NADP TECHNICAL COMMITTEE MEETING Proceedings Sacramento, California October 25-28, 1999

Naval Acquisition Development Program (NADP) · PDF fileNaval Acquisition Development Program (NADP) The NADP is a premier program within the Department of Defense. The purpose of

Rodney Bowersox TEXAS ENGINEERING EXPERIMENT STATION ... · AFRL-AFOSR-VA-TR-2018-0401 SecAF 2030 S&T Study Rodney Bowersox TEXAS ENGINEERING EXPERIMENT STATION COLLEGE STATION Final

NADP Passive Ammonia Monitoring Network ( AMoN )

NADP -Dependent Dehydrogenase SCO3486 and Cycloisomerase

NADP Site Selection and Installation Manual

NADP Data Use State of Wisconsin

Govt Schemes Nadp Dap Tirunelveli

Purification and Characterization of Glutamine Synthetase NADP

Presented by: Douglas Bowersox Product Manager

NADP Program Office Publications › old_attachements › 1718_att3... · 2020-05-14 · NADP Program Office Publications National Atmospheric Deposition Program. 2001. NADP 2001

Naval Acquisition Development Program (NADP) - … Acquisition Development Program (NADP) - Associate Master Development Plan (MDP) Test and Evaluation (T&E) Career Field. Employee:

Dyscalculia in Further and Higher Education NADP 20101

NADP Network Quality Assurance Plan 2016 04nadp.slh.wisc.edu/lib/qaplans/NADP_Network_Quality... ·  · 2016-05-03NADP Network QAP, Revised 2016-04 Version 1.8 NADP Network Quality

10229 Claybrooke Drive, Charlotte, NC 28262

2015 NADP Reference Listingnadp.slh.wisc.edu/lib/citations/2015nadpCitations.pdf · Page 1 of 24. 2015 NADP Reference Listing . Includes 226 publications that used NADP data, or compared

NADP Newsletter- Winter 2010

Generating NADP Deposition Maps using Cokriging

The NADP Atmospheric Integrated Research Monitoring

biologysc.weebly.combiologysc.weebly.com/.../photosynthesis_handout_cram_2.pdfOxidised NADP Reduced NADP Energy level H20 tosyste High energy electron otosys ADP ATP Light Chain of

Home Care Medicine MELISSA VOURLITIS, DO MICHAEL BOWERSOX, MD

NATIONAL AGRICULTURE DEVELOPMENT PROGRAM (NADP …rkvy.nic.in/static/SAIDP/TN_SAIDP.pdfnational agriculture development program (nadp / rkvy) state agriculture infrastructure development

NADP Quality Management Plan 2010 12nadp.slh.wisc.edu/...Quality_Management_Plan_2011.pdf · 2.0 NADP Quality Management System (QMS) 2.1 NADP Governance Handbook 2.2 Quality Management

Snyder County, PA War Veteran Listing Veterans Listing.pdf · Snyder John Snyder Simon ... Bowersox Phares Gaugler Jacob R. Jury Daniel Bowersox R.C. Gaugler George Kahley Henry

Naval Acquisition Development Program (NADP) - Associate ... … · Naval Acquisition Development Program (NADP) - Associate Master Development Plan (MDP) Engineering ... Rotation/Technical

List of Farmers Beneficiaries under NADP S. No. Farmers ...agritech.tnau.ac.in/ta/success_stories/pdf/B.F Tech NADP Farmers... · List of Farmers Beneficiaries under NADP S. No. Farmers

LEAF-TARGETED FERREDOXIN-NADP OXIDOREDUCTASE (FNR)

AMERICA by Bob Bowersox copyright R. T. Bowersox Registered … · 2013. 11. 15. · The Trashman flips the lids from the cans, grabs the plastic bags within, tosses them into the