m/s. kemz resibond private limited
TRANSCRIPT
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DRAFT ENVIRONMENTAL IMPACTASSESSMENT REPORT
FOR THE PROPOSED PROJECT OFRESIN MANUFACTURING PLANT
[ Project/Activity No.- 5(f), Cat.-‘B’ ]
M/s. Kemz Resibond Private LimitedSurvey No: 84/1,84/2, Village: Fofadiya, Tal: Dabhoi,
Dist:Vadodara-391210
Prepared ByENTECH LABORATORIES
[ISO 9001:2008, NABL Accredited Laboratory/ GPCB recognized Env. Auditor (Sch-II)]Laboratory : 33,34 Kushal Estate, Sanket Industrial Estate, Village - Moraiya, Taluka -
Sanand, Ahmedabad 382213 Gujarat.
Office: 202, Trade Square, Opp. Torrent Power House, Sabarmati, Ahmedabad - 380013
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INDEXSr no. Title
Table of ContentsList of TablesList of Figures
List of AnnexureTOR & It’s Compliance
Executive SummaryChapter-1: Introduction 1-161.1. PREAMBLE 11.2. Purpose of EIA 11.3. Objectives of EIA study 21.4. Project Proponent 21.5. Location 51.6. Study Area 101.7. Nearest location from the site 101.8. Scope and Methodology of EIA 121.9. Regulatory Framework 131.10. Structure of EIA 141.11. Photographs of the project site 16Chapter-2: Project Description 17-542.1. Introduction 172.2. Location of the Project 172.3. Justification of proposed activity 172.4. Promoters and their background 182.5. Infrastructure facilities 182.6. Land use Breakup for total plot area 192.7. Product Details 202.8. Packing and final application of products 202.9. Raw materials requirement 212.10. Properties of raw materials & products 222.11.1. Physical and chemical properties of the raw material & product 232.11.2. Storage details of raw material & products 252.11.3. Transportation details of raw material & product 272.11.4. Project Cost 272.11.5. Project Implementation Schedule 272.12. Manufacturing process details, chemical reaction and mass balance 282.13. Water requirement & wastewater generation 382.13.1 Wastewater management 402.13.2 Characteristics of effluent 402.14. Details of effluent treatment plant 412.15. Flue gas emission 422.16. Process gas emission 432.17. Fuel requirement 432.18. Fugitive emission control 442.18.1. VOC management plan 442.18.2. Odour control action plan 45
Table of Contents
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2.19. Hazardous waste management 452.20. Noise pollution 462.21. List of hazardous chemicals 472.22. Safety & occupational measure for storage & handling of the raw material &
product48
2.23. Action plan for transportation of raw materials and products including hazardous chemicals
49
2.24. Cost of the project 502.25. Power requirement 512.26. Man power 512.27. Green belt development 512.28. Scheme for rain water harvesting 532.29. Solvent management system 54Chapter-3: Base line environment quality 55-1103.1. Introduction 553.2. Study Area 553.3. Environmental standards of the region 603.4. Air environment 633.4.1. Ambient air quality (AAQ) in the study area 633.4.1.1. The location of AAQ stations 633.4.1.2. Base line data 65
Photographs showing AAQ monitoring 743.4.1.3. Sample analysis 753.5. Meteorology 763.6. Baseline Data 763.6.1. Ambient Temperature 763.6.2. Wind Speed 763.6.3. Wind Direction 763.6.4. Relative Humidiy 783.6.5. Rain Fall 783.6.6. Mixing Height 793.7. Atmospheric stability 793.8. Noise Environment 803.9. Water Quality 833.9.1. Baseline data collection of ground water & surface water 83
Photographs of water sampling 883.10. Land Environment 893.10.1. Geology & Hydrogeology 893.10.2. Characteristics of soils 92
Photographs of soil sampling 943.11. Land use pattern 963.12. Hydrology 983.13. Ecology 1013.13.1. Period of the study area 1013.13.2. Methodology 1013.13.3. Topography of the study area 1023.13.4. Floral diversity 1023.14. Socio Economic Environment 107
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3.15. Traffic Survey 110Chapter-4: Anticipated Environmental Impacts & Mitigation Measures 111-1474.1. Introduction 1114.2. Impact Identification 1124.3. Impact prediction and assessment with mitigative measures 1184.4. Impact on Air environment & Mitigation Measures 1194.5. Impact on Water Environment & Mitigation Measures 1364.6. Impact of Soild/Hazardous waste & Mitigation Measures 1384.7. Impact on Noise Environment & Mitigation Measures 1404.8. Impact on Land Environment & Mitigation Measures 1424.9. Impact on Ecology & Mitigation Measures 1444.10. Impact on Socio-Economic Environment & Mitigation Measures 1464.11. Impact on Occupational Health & Safety & Mitigation Measures 147Chapter-5: Analysis of Alternatives 148-1495.1. Site Alternative 1485.2. Alternative for Technologies 149Chapter-6: Environmental Monitoring Program 150-1536.1. Introduction 1506.2. Objectives of Environment Monitoring Program 1506.3. Post project Environment Monitoring Program 1516.4. Administrative actions & documentation 1536.5. Budgetary Provisions 153Chapter-7: Additional Studies 154-1797.1 Public Consultation 1547.2 Risk Assessment 1547.2.1. Introduction 1547.2.2. Storage and Handling 1567.2.3. Risk rating 1577.2.4. Procedure for treatment of workers affected during accident 1597.3. Hazards and their control measures 1607.4. Risk identification 1617.4.1. Maximum credible loss accident scenarios 1617.4.2. Damage criteria 1627.5. Risk assessment and consequence analysis 1627.5.1. Software used for calculations 1627.6. Preventive measures 1637.6.1. Site selection 1637.6.2. Choice of technology 1637.6.3. Equipment design 1637.6.4. Plant layout 1647.6.5. Safety awareness for key management 1647.6.6. Safety training for all operational staff 1647.6.7. Safety audits and inspections 1657.7. Mitigation measures 1657.7.1. Personal protective equipment 1657.7.2. Medical facilities 1677.7.3. Firefighting systems 1677.7.4. Emergency control centre 167
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7.8. Checklist of Do’s and Don’ts 1687.9. Disaster management plan 1697.9.1. Objectives of emergency procedures 1697.9.2. Basis of plan and handling of emergency 1697.9.3. Information about emergency and subsequent actions 1707.9.4. Instructions to employees 1707.9.5. Instructions to contractors 1717.9.6. Mitigation of consequences during major accident 1717.10. Emergency control centre with list of equipment and accessories 1717.10.1. Documents 1717.10.2. Personal protective equipment 1727.10.3. Equipment list 1727.11. Information regarding key persons and their responsibilities during
emergency172
7.11.1. Site main controller 1727.11.2. Incident controller 1737.11.3. Technical staff / department head 1737.11.4. Employees near the spot (incident area) 1737.11.5. Personnel officer 1737.11.6. Engineering services key personnel 1747.11.7. Security & fire in-charge 1747.11.8. First aid attendants 1747.11.9. Safety officer 1747.11.10. Emergency organization for idle hours 1757.11.10.1
Security 175
7.11.11. List of important authorities with their role in emergency and telephone numbers
175
7.11.12. Information about external communication system 1757.11.13. Announcement system details 1757.11.14. Outside important addresses and phone numbers 1757.11.15. Rehearsal and updation of plan 1767.12. Occupational health and safety program for the project 1767.12.1. Medical aid scheme 1777.13. Leak Detection And Repair (LDAR) 1777.14. Details of various SOP’s prepared 1787.15. Fire control plan 179Chapter-8: Project Benefits 180-1828.1. Improvements in the Infrastructure 1808.2. Employment potential 1808.3. Corporate Social Responsibility (CSR) & socio-economic development 1808.4. Direct revenue earning to the national and state exchequer 182
Chapter-9: Environment Cost Benefit Analysis 1839.1. Cost Benefit Analysis 183Chapter-10: Environmental Management Plan (EMP) 184-19610.1. Introduction 18410.2. The Environmental Management Plan (EMP) 18410.3. Scope & objectives of EMP 185
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10.4. Administrative actions 18610.4.1. Operational philosophy 18610.4.2. Management Support –Environment Policy 18610.4.3. Environmental Management Cell 18710.5. Mitigative Measures 18810.6. In-House Laboratory 19010.7. Greenbelt development 19010.8. Occupational health and safety 19210.9. Expenditure on Environmental Matters 19310.10. Concept of waste minimization, recycle / reuse / recover techniques, energy
conservation and natural resources conservation194
Chapter-11: Summary of Env. Impacts & Conclusion 197-20211.1. Introduction 19711.2. Salient features of the project 19811.3. Air environment 20011.4. Water Environment 20011.5. Noise environment 20111.6. Hazardous wastes 20111.7. Ecology 20111.8. Socio-Economic Environment 20111.9. Land Use 20211.10 Conclusion 202Chapter-12: Disclosure Of Consultants Engaged 203-205
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LIST OF TABLES Page No.Table 1.1 List of Directors 3Table 1.2 Nearest Location from the site 10Table 1.3 Nearest industries from the project site 11Table 2.1 Location of the project site 17Table 2.2 Details of sources 18Table 2.3 List of Plant & Machineries 19Table 2.4 Land use break-up for total plot area 19Table 2.5 List of Products 20Table 2.6 Packing and final application of products 20Table 2.7 Details of raw materials 21Table 2.7.1
Project implementation schedule 27
Table 2.8 Details of water consumption & effluent generation 38Table 2.9 Characteristics of industrial effluent 40Table 2.10 Details of proposed effluent treatment plant units 41Table 2.11 Flue gas stack details 42Table 2.12 Emission rate of the pollutants 42Table 2.13 Fuel details 43Table 2.14 Details of hazardous wastes 45Table 2.15 Typical noise levels of equipment 46Table 2.16 List of hazardous chemicals 47Table 2.17 Capital cost & recurring cost of the project 50Table 2.18 Power requirement 51Table 2.19 Details of man power 51Table 2.20 Land area breakup and estimation of runoff 53Table 2.21 Details of solvent 54Table 3.1 Name of villages in study area 57Table 3.2 National Ambient Air Quality Standards 60Table 3.3 Indian Standard Specification for Drinking water 61Table 3.4 Ambient Air Quality Standards with respect to noise 62Table 3.5 Locations of ambient air quality monitoring stations 63Table 3.6 Ambient Air Quality Analysis Results 65Table 3.7 Ambient Air Quality Analysis Report for the Month of March to May 2019 66Table 3.8 Details of ambient air quality monitoring & analysis procedures 75Table 3.9 Wind Rose (Frequency Distribution Data) 78Table 3.10 Relative Humidity 78Table 3.11 Rainfall pattern at vadodara rain gauge station 78Table 3.12 Hourly mixing depth over Indian region 79Table 3.13 Stability classification 79Table 3.14 Maximum ambient noise levels within study area 80Table 3.15 Ambient Noise analysis in the study report 82Table 3.16 Locations of water quality monitoring stations 84Table 3.17 Water quality analysis reports 85Table 3.18 Analysis results of soil samples 93Table 3.19 Land use distribution in study area (10 km Radial Zone) 96Table 3.20 Methodology adopted for the evaluation of biodiversity status of the study
region101
Table 3.21 Flora & Fauna in the study area 102Table 3.22 Demography of the study area 108Table 3.23 Traffic Counts 110Table 3.24 Existing Traffic Scenario and Level of Services 110
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Table 4.1 Impact identification matrix 113Table 4.2 Impact prediction matrix 115Table 4.3 Basis of emission rate calculations 121Table 4.4 Maximum computed ground level concentration at project site 124Table 4.5 Cumulative concentrations due to incremental GLC's 125Table 4.6 1st highest 24-hr Average Concentration values of PM (µg/m3) 126Table 4.7 1st highest 24-hr Average Concentration values of SO2 (µg/m3) 129Table 4.8 1st highest 24-hr Average Concentration values of NOX (µg/m3) 132Table 4.9 Solid/Hazardous waste generation and disposal mode 138Table 6.1 Environmental monitoring plan 151Table 6.2 Break up of budget for environmental monitoring plan 153Table: 7.1 Storage details of raw material & products 156Table: 7.2 Storage and disposal of solid / hazardous waste 156Table: 7.3 Overall severity/consequence 157Table: 7.4 Occurrence frequency/probability 157Table: 7.5 Risk rating 158Table: 7.6 Hazards and its control measure 160Table: 7.7 Earthquake control measures 161Table: 7.8 Flood control measures 161Table: 7.9 List of Proposed Personal Protective Equipments 166Table: 7.10
List of proposed fire fighting equipment’s 167
Table: 8.1 Proposed planned social activities 181Table 10.1 List of major laboratory instruments 190Table 10.2 Budgetary expenditure for GBD 191Table 10.3 Expenditure on environmental matters 193
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LIST OF FIGURES Page No.Figure 1.1 Map of Gujarat State & Project Location 6Figure 1.2 Google image showing corner co-ordinates of proposed plant 6Figure 1.3 Google image with 5 & 10 km radius around the plant 7Figure 1.4 Plant Layout 8Figure 1.5 Topography Map 9Figure 2.1 Water balance diagram 39Figure 2.2 Effluent Treatment Plant Diagram 41Figure 3.1 Study area map of base line study for 5 km and 10 km radius 58Figure 3.2 Toposheet 59Figure 3.3 Locations map of the AAQ monitoring station 64Figure-3.4 Wind rose diagram for the month of March– April – May 2019 77Figure 3.5 Land use / land cover map of 5 km & 10 km radius area around project site 97Figure 4.1 Isoplathes of PM concentration for 24hrs 128Figure 4.2 Isoplathes of SO2 concentration for 24hrs 131Figure 4.3 Isoplathes of NOx concentration for 24hrs 134Figure10.1 Environmental Management Cell 187
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LIST OF ANNEXURES
Annexure- I Copy of Granted TOR, Dated: 30/07/2019
Annexure- II ToR Compliance Report
Annexure- 1 CTE From GPCB
Annexure- 2 NA Certificate
Annexure- 3 Undertaking for complying the three conditions, Water consumption <25 m3/Day, Fuel Consumption < 25 TPD, not covered under category of MAH
Annexure- 4 Land Possession Documents (LPD)
Annexure- 5 CGWA Application Copy
Annexure- 6 Undertaking for underground drainage connection will not be taken and will be achieve Zero Liquid Discharge
Annexure- 7 NOC Letter from BEIL Infrastructure Limited (For TSDF & CHWIF)
Annexure- 8 MSDS of raw materials & products
Annexure-A Consultant’s Certificate of accreditation (High Court stay order)
Annexure-B NABL accreditation Certificate
Annexure-C EMS Adequacy Certificate
Annexure-D Undertaking by the EIA consultant
Annexure-E Undertaking by the Project Proponent
TOR conditions & It’s ComplianceClarifications, information and data as required in Terms of Reference (ToR) and Terms of Reference (TOR) was obtained in hard copy vide letter no SEIAA/GUJ/TOR/5(f)/1093/2019, dated 30-07-2019. TOR copy is attached as Annexure- I
A tabular chart with index for point wise compliance is as given below:Sr.No.
ToR Point Compliance Report
Page No.
1 Details with respect to justification for proposed expansion: (1) To address proportionate availability of space forproduction plant. (2) To address proportionate availability ofstorage area for raw materials finished goods, utilities and goods carrier movement within premises. (3) To address proportionate captive/common infrastructure available to accommodate additional load due to proposed expansion. (4) Environment impact and its mitigation measures for common/ captive infrastructure due to proposed production.
Please refer Chapter 2, Section 2.6 and Chapter 10, Section 10.5
19 & 188-189
2. Compliance of MoEF&CC’s OM dated 01/05/2018 regarding “Corporate Environment Responsibility” (CER). Fund allocation for Corporate Environment Responsibility (CER) shall be made as per MoEFCC’s O.M. No. 22-65/2017-IA.III dated 01/05/2018 for various activities therein. The details of fund allocation and activities for CER shall be incorporated in EIA/EMP report.
Please referChapter 8,Table 8.1
181
3. Explore the use of renewable energy to the maximum extent possible. Details of provisions to make the project energy-efficient through energy efficient devices and adoption of modes of alternative eco-friendly sources of energy like solar water heater, solar lighting etc. Measures proposed for energyconservation.
Please refer Chapter 10, Section 10.10
194-195
4 Leak Detection and Repairing Programme (LDAR) for all the volatile organic solvent proposed for use in-house with detailed chemical properties including vapour pressure. LDAR shall endeavour prevention of losses of solvents to the bestminimum extent.
Please referChapter 7,Section 7.13
177-178
5 Safety precautions including flame proof electric fittings to be taken to avoid fire hazard during unloading, storage,transportation, handling and processing of Solvents.
Please referChapter 2,Section 2.22
48
6 Submit CTE (NOC) from GPCB & NA copy stating that Sr. No. 84/1, 84/2, Village: Fofadiya, Taluka, Dabhoi, Dist. Vadodara shall be utilized for establishment of Chemical Industry
Please refer Annexure 1 & Annexure 2
--
7 Legal undertaking stating that unit is complying the three conditions (i.e. water consumption less than 25 m3/d, fuel consumption less than 25 TPD, and not covered in the category of MAH units as per the Management Storage, Import of Hazardous Chemicals Rules (MSIHC Rules) 1989) as per the amendment \to EIA Notification, 2006 vide SO 1599 (E) dated 25/06/2014.
Please refer Annexure 3
--
8 A tabular chart for the issues raised and addressed during public hearing/consultation and commitment of the project proponent on
-- --
the same should be provided. An action plan to address the issues raised during public hearing and the necessary allocation of funds for the same should be provided.
9 PP shall ensure participation of people during Public Hearing with equality in gender so as to encourage woman participation in Public hearing and the necessary allocation of funds for the same. Should be provided.
-- --
10 Unit shall provide Adequate Stack Height with Single Stage Evaporator along with suitable APCM considering type ofEmission.
Please refer Chapter 2,Section 2.15,Table 2.11
42
Sr.No.
ToR Point Compliance Report
Page No.
1 A tabular chart with index for point-wise compliance of below mentioned TORs.
--
2 Executive summary of the project - giving a prima facie idea of the objectives of the proposal, use of resources, justification, etc. ln addition, it should provide a compilation of EIA report, including EMP and the post -project monitoring plan in brief.
Executive Summary in English is given in EIA reportafter TOR compliance
--
3 Justification for selecting the proposed product and unit size. Please refer Chapter-2, Section 2.3
17
4 Land requirement for the project including its break up for various purposes, its availability and optimization.
Please refer Chapter-2, Section 2.6, Table 2.4
19
5 Land possession documents. Copy of NA order showing permission to use the project land for industrial purpose. lf located in GIDC, copy of plot holding certificate obtained from GIDC Authority.
Please refer Annexure 4: Land Possession Documents
Annexure 2: Copy of NA
--
6 Location of the project site and nearest habitats with distances from the project site to be demarcated on a toposheet (1: 50000 scale).
Please refer chapter 1,Figure 1.5
9
7 Topography details of the project area. Please refer Chapter-1, Figure 1.5
9
8 Geological features and geo-hydrological status of the study area. Please refer Chapter-3, Section 3.10.1 for Geological features, Section 3.12 for hydrological status
89-91 and 98-101
9 ln case of project located outside notified area: Legal Undertaking stating that unit is complying the three conditions [i.e. water consumption less than 25 M3/day; Fuel consumption less than 25 TPD; and not covered in the category of MAH units as per theManagement, Storage, import of Hazardous Chemical Rules (MSIHC Rules), 1989] as per the amendment to EIA Notification, 2006 vide SO 1599 (E) dated 25/06/2014.
Please refer Annexure:3
--
10 Present land use pattern of the study area shall be given based on satellite imagery.
Please refer Chapter-3, Section 3.11
96-97
11 Layout plan of the factory premises clearly demarcating various units within the plant. Provision of separate entry & exit and adequate margin all round the periphery for unobstructed easy movement of the emergency vehicle / fire tenders without reversing back. Mark the same in the plant layout.
Please refer Chapter-1, Figure 1.4
8
12 Technical details of the plants along with details on best available technologies (BAT), proposed technology and reasons for selecting the same.
Please refer Chapter-2, Section 2.12
28-37
13 Product spectrum (Proposed products along with production Capacity) and processes.
Please refer Chapter-2, Section 2.7, Table 2.5
20
14 Chemical name of each proposed product to be manufactured. Details on end use of each product. (Provide CAS number of all the products & raw materials. ln case of Dyes, Cl number).
Please refer Chapter-2, Section 2.10
22-23
15 Details on raw materials, source and storage within the premises. Please refer Chapter-2, Section 2.11.3 & 2.11.2
25-27
16 Details of complete manufacturing process / operations of each product along with chemical reactions, process flow diagram describing each unit processes and unit operations along with material balance, consumption of raw materials etc.
Please refer Chapter-2, Section 2.12
28-37
17 Details on strategy for the implementation of cleaner production activities.
Unit has incorporated necessary considerations in project planning.
--
18 Assessment of source of the water supply with adequacy of the same to meet with the requirements for the project. Permission obtained from the concern authority for supply of raw water.
Please refer Chapter-2, Section 2.13, Please refer Annexure 5
38
19 Undertaking stating that no bore well shall be dug within the premises (lf project is located within the industrial estate).
Not Applicable --
20 Details on water balance including quantity of effluent generated, recycled & reused. Details of methods to be adopted for the water conservation.
Please refer Chapter-2, Figure 2.1
39
21 Efforts to minimize effluent discharge and to maintain quality of receiving water body.
Unit will maintain ZLD.
--
22 Explore the possibilities for Zero Liquid Discharge (ZLD) option Unit will maintain --
for the proposed project. ZLD.23 Segregation of waste streams, characterization and quality with
specific treatment and disposal of each stream including action plan for maximum recycle of treated waste water and minimum discharge for effluent.
Please refer Chapter-2, Section 2.14,Table 2.10
41
24 Capacity of ETP in KL/Day. Details of ETP including dimensions of each unit along with schematic flow diagram. lnlet, transitional and treated effluent qualities with specific efficiency of each treatment unit in reduction in respect of all concerned/regulated environmental parameters. lnlet effluent quality should be based on worst case scenario considering production of most polluting products that can be manufacturedin the plant concurrently.
Please refer Chapter-2, Section 2.14 andTable 2.10
41
25 In case of discharge into GIDC Drainage/Pipeline:i. Copy of permission letter with quantity (KL/day) from the concern authority of drainage network/pipeline with confirmation for spare capacity available to take additional effluent.
Not Applicable --ii. Characteristics of the combined effluent and treated water to be sent to Common pipeline with reference to the MoEFCC/CPCB/GPCB discharge norms.iii. Provision for Continuous Monitoring System for waste water discharge.
26 ln case of waste water sent to Common Facilities (CF) like CETP MEE, Spray Dryer etc.a. Details of Common facilities including (1) Total capacity of the CF (2) Copy of CC&A of the CF. (3) Actual load at present (Qualitative and Quantitative - KL per day) (4) Booked quantity & Spare capacity of CF (5) Copies of XGN generated inspection reports with analysis reports of theWater/Air/Hazardous samples collected by GPCB (Last 2 year). Copies of instructions issued by GPCB in last 2 year and point wise compliance thereof. (6) Copies of Show- cause notices,closure notices etc. served by the GPCB and its compliance (6) Recommendations and suggestions of the last two Environment Audit reports of CETP and its compliance report. (7)Common Facility Up gradation scheme, if any. Not Applicable --b. Status of compliance to the 18(1) (b) direction issued by the CPCB with respect to CETP compliance & CEPI area action plan along with relevant supportive document.c. Give status of compliance of Environmental norms of existingCommon lnfrastructure i.e. CETP, MEE & Spray Dryer (Whichever is applicable) in which you are a member.d. Submit adequacy of Common infrastructure i.e. CETP, MEE & Spray Dryer for additional load (Whichever is applicable) along with written confirmation/membership certificate mentioning thesame (Total consented quantity, total quantity booked so far, quantity booked for the unit, spare " quantity available).
27 ln case of Zero Liquid Discharge (ZLD) :i. Action plan for 'Zero' discharge of effluent shall be included. Notarized undertaking for assuring that underground drainage connection will not be taken in the unit and there shall be no
Please refer Chapter-2, Section 2.14 and
41
effluent discharge outside the plant premises. Annexure 6
ii. Economical and technical viability of the effluent treatment system to achieve Zero Liquid Discharge (ZLD).
Please refer Chapter-2, Section 2.14
41
iii. Certification of adequacy of proposed ZLD scheme through credible institutes of National repute.
Please refer Annexure C
--
iv. To estimate & monitor ground water quality & its contamination status, piezometer wells, one on up gradient of the groundwater flow and other three on the down gradient side of the ground water flow of the proposed project at different depth based on available ground water depth shall be established and all the parameters mentioned in IS 10:500 for potable water standard shall be monitored.
Please refer Chapter-3, Table 3.17
85-86
28 ln case of in-house MEE/Spray dryer for waste water treatment: Capacity of MEE/Spray dryer in KL/hr, Technical details of MEE including evaporation capacity, steam required for evaporation, adequacy of the proposed boiler to supply steam for evaporation in addition to the steam required for the process etc.Techno-economical viability of the evaporation system. Control measures proposed for the evaporation system in order to avoid/reduce gaseous emission VOC from evaporation of industrial effluent containing solvents & other chemicals.
Not Applicable --
29 Technical details of ATFD/Crystallizer/spray Dryer, RO/NF system etc. (lf any).
Not Applicable --
30 Details of the treatability and feasibility of wastewater to be disposed off by means of spray dryer and its impact on environment and Human Health.
Not Applicable. Treated water is 100 % evaporated.
--
31 Undertaking stating that a separate electric meter will be provided for the waste water treatment system viz. ETP, RO, MEE, Spray dryer etc. (Whichever is applicable)
We will provide separate electric meter with ETP.
--
32 Economical and technical viability of the effluent treatment system.
Please refer Chapter-2, Section 2.14
41
33 Plans for management, collection and disposal of waste streams to be generated from spillage, leakages, vessel washing, used container washing etc. Measures proposed for preventing effluent discharge during unforeseen circumstances
34 Action plan for reuse of liquid waste streams like Spent acids, Poly Aluminium Chloride etc. Within premises to convert into valuable products instead of sending outside to actual end-users.
Not Applicable --
35 Adequacy of the proposed EMS with respect to the pollution load envisaged in terms of Air, Water and hazardous waste.
Please refer Annexure C
--
36 On season Site-specific micro-meteorological data using temperature, relative humidity, hourly wind speed and direction and rainfall should be incorporated.
Please refer Chapter-3, Section 3.6
76-79
37 Anticipated environmental impacts due to the proposed project/production may be evaluated for significance and basedon corresponding likely impacts VECs (Valued EnvironmentalComponents) may be identified Baseline studies may be conducted within the study area for all the concerned/identifiedVECs and likely impacts will have to be assessed for their
Please refer Chapter-4, Section 4.2
112-117
magnitude in order to identify mitigation measures.38 One complete season base line ambient air quality data (except
monsoon season) to be given along with the dates of monitoring. The parameters to be covered shall be in accordance with the revised National Ambient Air Quality Standards (NAAQS) as well as project specific parameters like NH3, HCl, Cl2 , HBr, VOC etc. Locations of the monitoring stations should be so decided so as to take into consideration the pre-dominant downwind direction, population zone and sensitive receptors. There should be at least one monitoring station in the upwind direction. There should be at least one monitoring station in the pre-dominant downwind direction at a location where maximum ground level concentration is likely to occur.
Please refer Chapter-3, Table 3.7
66-73
39 Modelling indicating the likely impact on ambient air quality due to proposed activities. The details of model used and input parameters used for modelling should be provided. The air quality contours may be shown on location map clearly indicating the location of sensitive receptors, if any, and the habitation. The windrose showing pre-dominant wind direction should also be indicated on the map. lmpact due to vehicular movement shall also be included into the prediction using suitable model. Results of Air dispersion modeling should be superimposed on satellite image / geographical area map.
Please refer Chapter-4, Section 4.4, Figure 4.1 to 4.3 (Contour Map)Figure 3.4 (Windrose Diagram)
77 & 128-134
40 Base line status of the noise environment, impact of noise on present environment due to the project and proposed measures for noise reduction including engineering controls.
Please refer Chapter 3, Table 3.15 and Chapter 4, Section 4.7
82 & 140-141
41 Specific details ofa) Process gas emission from each unit process with its quantification.
Please refer Chapter 2, Section 2.16
43
b) Air pollution Control Measures (APCM) proposed for process gas emission. Adequacy of the air pollution control measures (APCM) for process gas emission measures to achieve GPCB norms.
Please refer Chapter 2, Section 2.16
43
c) Details of the utilities required. Please refer Chapter 2, Table 2.3
19
d) Type and quantity (MT/Hr & MT/Day) of fuel to be used foreach utility.
Please refer Chapter 2, Table 2.13
43
e) Flue gas emission rate emission from each utility. Please refer Chapter 2, Table 2.12
28-37
f) Air Pollution Control Measures (APCM) proposed to each of the utility along with its adequacy
Not Applicable --
g) List the project specific sources of fugitive emission along with its quantification and proposed measures to control it.
Please refer Chapter 2, Section 2.18
44
h) Details on tail gas treatment.(If any) Not Applicable --
42 Provision of CEMS (Continuous Emission Monitoring system). Not Applicable --
We are not falling in any category which require to install CEMS
43 Action plan for odour control to be submitted. Please refer Chapter 2, Section 2.18.2
45
44 Management plan for hazardous/Solid waste including storage, handling, utilization and safe disposal as per the Hazardous and Other Wastes (Management and Transboundary Movement) Rules 2016- CPCB guidelines in respect of specific treatment, such as solar evaporation, incineration, etc. need to be followed.
Please refer Chapter 2, Table 2.14
45
45 How the manual handling of the hazardous wastes will be minimized? Methodology of de-contamination and disposal of discarded containers and its record keeping.
Please refer Chapter 2, Section 2.23
49
46 Management of by-products which fall under the purview of(Management and Transboundary Movement) Rules 2016 asPer the said rules and necessary permissions from the concern authority.
Not Applicable --
47 Membership of Common Environmental infrastructure like TSDF, Common incineration Facility (CHWIF), MEE, Spray dryer etc.
We will apply for membership after obtained CCA from the board. We have already taken NOC from BEIL Infrastructure Limited. Please refer Annexure 7.
--
48 Name and quantity of each type of solvents to be used for proposed production. Details of in-house solvent recovery system including mass balance, solvent loss, recovery efficiency (% recovery), feasibility of reusing the recovered solvents etc for each type of solvent.
Please refer Chapter 2, Section 2.29
54
49 Appropriate monitoring network has to be designed and proposed, to assess the possible residual impacts on VECs.
Please refer Chapter 6, Table 6.1
151-152
50 A detailed EMP including the protection and mitigation measures for impact on human health and environment as well as detailed monitoring plan and environment management cell proposed for implementation and monitoring of EMP. The EMP should also include the concept of waste-minimization, recycle/reuse/recover techniques, energy conservation and natural resource conservation. Total capital cost and recurring cost/annum earmarked for environment pollution control measures.
Please refer Chapter 10, Section 10.5,Section 10.4.3,Section 10.10 and Table 10.3
187-196
51 Details of in-house monitoring capabilities and the recognized agencies if proposed for conducting monitoring.
Please refer Chapter 10, Section 10.6
190
52 Permission from PESO, Nagpur for storage of solvents, other toxic chemicals, if any
Not Applicable --
53 Occupational health impacts on the workers and mitigation Please refer 147 & 192
measures proposed to avoid the human health hazards along with the personal protective equipment to be provided. Provision of industrial hygienist and monitoring of the occupational injury to workers as well as impact on the workers. Plan for periodicmedical checkup of the workers exposed. Details of work place ambient air quality monitoring plan as per Gujarat Factories Rules.
Chapter 4, Section 4.11 and Chapter 10, Section 10.8
54 Details on volatile organic compounds (VOCs) from the plant operations and occupational safety and health protection measures. Proposal for Leak Detection and Repair (LDAR) program as per the CPCB guidelines.
Please referChapter 2,Section 2.18.1 and Chapter 7, Section 7.13
44 & 177-178
55 Risk assessment including prediction of the worst-case scenario and maximum credible accident scenarios should be carried out The worst-case scenario should take into account the maximumInventory of storage at site at any point of time. The risk contours should be plotted on the plant layout map clearly showing which of the facilities would be affected in case of an accident taking place. Based on the same, proposed safeguard measures including On-Site / Off-Site Emergency plan should be provided.
Please referChapter 7, Section 7.2
154-159
56 MSDS of all the products and raw materials. Please refer Annexure 8
--
57 Details of hazardous characteristics and toxicity of raw materials and products to be handled and the control measures proposed to ensure safety and avoid the human health impacts. This shall include the details of Antidotes also.
Please refer Chapter 2, Section 2.11.1and Section 2.22
23-24 & 48
58 Details of quantity of each hazardous chemical (including solvents) to be stored, Material of Construction (MoC) of major hazardous chemical storage tanks, dyke details, threshold storage quantity as per schedules of the Manufacture, Storage & lmport of Hazardous Chemicals Rules of major hazardous chemicals, size of the biggest storage tank to be provided for each raw material & product etc. How the manual handling of the hazardous chemicals will be minimized?
Please refer Chapter 2, Section 2.11.2
25-26
59 Details of the separate isolated storage area for flammable chemicals. Details of flame proof electrical fittings, DCP extinguishers and other safety measures proposed. Detailed fire control plan for flammable substances and processes showing hydrant pipeline network, provision of DG Sets, fire pumps, jockey pump, toxic gas detectors etc.
Please refer Chapter 7, Section 7.15
179
60 Submit checklist in the form of Do's & Don'ts of preventive maintenance, strengthening of HSE, manufacturing utility staff for safety related measures.
Please refer Chapter 7,Section 7.8
168-169
61 Specify safety precautions to be taken for Chemical storage, process and handling & transportation hazard.
Please refer Chapter 2, Section 2.22
48
62 Details on workers training before engaging work, periodical, in-house, outside etc.
Please refer Chapter 2, Section 2.26
51
63 Details on various SOP to be prepared. Please refer Chapter 7, Section 7.14
178
64 Details on safety audit to be carried out and their compliance status.
Not Applicable(As we will carry out safety audit by safety organization after we will start operation of plant.)
--
65 Specific safety measures to be taken for general Public living in the vicinity.
Please refer Chapter 7, Section 7.2.4
159
66 Details on hazard identification i.e. HMOP, HAZAN, Fault tree analysis, Event tree analysis, Checklist, Audit etc. to be adopted for the safety operation of the plant.
Please refer Chapter 7, Section 7.3
160-161
67 Detection and monitoring of VOC's / gases. Please refer Chapter 3, Table 3.7
66-73
68 Detailed five year greenbelt development program including annual budget, planning schedule, species, width of plantations, number of trees to be planted, area under green belt development [with map], budgetary outlay etc. along with commitment of the management to carry out the tree plantation activities outside the premises at appropriate places in the nearby areas and elsewhere.
Please refer Chapter 2, Section 2.27 and Chapter 10, Section 10.7
51-52 & 190-191
69 Action plan for the greenbelt development - species, width of plantations, planning schedule, etc., in accordance to CPCB published guidelines.
Please refer Chapter 10, Section 10.7
190-191
70 Detailed socio-economic development measures including community welfare program most useful in the project area for the overall improvement of the environment. Submit a detailed plan for social corporate.
Please refer Chapter 8, Table 8.1
181
71 (a) Does the company have a well laid down Environment Policy approved by its Board of Directors? If so it may be detailed in the EIA report. (b) Does the Environment Policy prescribe for standard operating process / procedures to bring into focus any infringement / deviation / violation of the environmental or forest norms / conditions ? lf so it may be detailed in the ElA.
Not Applicable --
72 What is the hierarchical system or administrative order of the company to deal with the environmental issues and for ensuring compliance with the EC conditions. Details of this system may be given.
Please refer Chapter 10, Section 10.4.3
187
73 Does the company have a system of reporting of non compliances / violations of environmental norms to the Board of Directors of the company and / or shareholders or stakeholders at large? This reporting mechanism should be detailed in the EIA Report.
Not Applicable We will develop the system for the same.
--
74 Phase wise project implementation schedule with bar chart and time frame, in terms of site development, infrastructure provision, EMS implementation etc.
Please referChapter 2,Table 2.7.1
27
75 Certificate of accreditation issued by the NABET, QCI to the environmental consultant should be incorporated in the EIA Report.
Not Applicable --
76 An undertaking by the Project Proponent on the ownership of the EIA report as per the MoEFCC OM dated 05/10/2011 and an
Please referAnnexure: D & E
--
undertaking by the Consultant regarding the prescribed TORs have been complied with and the data submitted is factually correct as per the MoEFCC OM dated 04/08/2009.
77 All documents to be properly referenced with index and continuous page numbering.
All documents are referenced with Index (Provided below ToR compliance) and continuous page numbering.
--
78 Where data are presented in the Report especially in Tables, the period in which the data were collected and the sources should be indicated.
Mentioned in all the analysis data.
--
79 Project Proponent shall enclose all the analysis/testing reports of water, air, soil, noise etc. using the MoEFCC/NABL accredited laboratories. All the original analysis/testing reports should be available during appraisal of the Project.
Enclosed in Chapter 3
--
80 ln case of Expansion of the projecta. Need for the proposed expansion should be justified in detail.
Not Applicable --
b. Adequacy of existing EMS (Environmental Management System).c. Explore the possibility to achieve Zero Liquid Discharge (ZLD) for existing as well as proposed activity.d. Records of any legal breach of Environmental laws i.e. details of show- cause notices, closure notices etc. Served by the GPCB to the existing unit in last five years and actions taken then after for prevention of pollution.e. Copies of Environmental Clearances obtained for the existing plant, its point wise compliance report.f. Environmental audit reports for last 3 years and compliance of its recommendations/Suggestions. (lnclude latest audit report and its compliance.)g. Copy of Consent to Operate (CC&A) obtained along with point wise compliance status of all the conditionsstipulated therein.h. Compliance of MoEFCC circulars vide No: J-11011/618/2010-lAll (l) dated 30/05/2012 and J-110113/41/2006-IA-l(l) dated 20/10/2009.i. Copies of XGN generated inspection reports with analysis reports of the water/Air/Hazardous samples collected by GPCB (Last 2 year). Copies of instructions issued by GPCB in last 2 year and point wise compliance thereof.
81 ln case of project is located in Ankleshwar-Panoli, Vatva-Narol & Vapi GIDC.(A) Compliance of MOEFCC's OM no. J-11013/5/2010-lA.ll (l) daled 25/11/2016 regarding lifting of moratorium on the consideration of projects for environmental clearance.
Not Applicable --(B) Compliance of direction under section 18 (1) (b) of the Water (Prevention and Control of Pollution) act, 1974 issued by CPCB dated 31/0312016 regarding compliance of CETP.a) Action initiated by GPCB, if any, against proposed unit regarding non-compliance of prescribed standards under the
various environmental laws.b) Performance of CETP with respect to current hydraulic load & prescribed standards with No Objection Certificate of CETP regarding incorporation of the proposed unit for acceptance of waste water.c) Performance of TSDF site with respect to current load & prescribed standards with No Objection Certificate of TSDF site regarding incorporation of the proposed unit for acceptance of hazardous waste to the common infrastructure.d) Copies of quarterly action report taken for the above points submitted to the CPCB.e) Report of GPCB which have conducted monitoring as per the said direction by CPCB dated 31/03/2016.
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Draft EIA Report of M/s Kemz Resibond Private Limited I
EXECUTIVE SUMMARYProject Name: Kemz Resibond Private LimitedProject: Proposed Resin manufacturing Plant
Manufacturing Capacity: Total capacity 1270 MT/Month
Location: Survey No: 84/1, 84/2, Village: Fofadiya, Tal: Dabhoi, Dist: Vadodara-391210.
Corporate Office Address: 7, Shivabhi Shopping, Maneja, Vadodara-390013
1. INTRODUCTION:
M/s. Kemz Resibond Private Limited is a proposed unit at Survey No: 84/1, 84/2, Village: Fofadiya, Tal: Dabhoi, Dist: Vadodara-391210.The unit intends to manufacture Synthetic Organic Resins viz. Unsaturated Polyester Resin, Alkyd Resin, Epoxy Resin, Saturated Polyester Resin, Vinyl Ester Resins total to the tune of 1270 MT/Month.
Looking at prospective market scenario and considering the large market demand of the Resins in the domestic as well as global market, the company is keen to set up industrial unit for Resin manufacturing.
The proposed project falls under Category “5(f) – B” as stated in Environment Impact Assessment Notification Published on 14th September, 2006. Hence, project proponent has to obtain the Environmental Clearance from the State Level Environmental Impact Assessment Authority, Gujarat.
2. PROJECT DESCRIPTION:
This proposal is prepared for the purpose of resin manufacturing capacity of 1270 MT/Monthto fulfill the present demands of resin in the market.
Indigenous raw materials & Chemicals are available from local market. Due to Developed location, proposed resin activity will be facilitated with good infrastructure and other facilities such as availability of skilled as well as unskilled workforce, contractors, superior communication facilities, transportation facilities etc.
The total land area of the company is 7551.74 m2. Total available gardening area is 1667 m2.
The details of proposed products along with the capacity & end use are listed below in Table 2.1
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Draft EIA Report of M/s Kemz Resibond Private Limited II
Table 2.1 Details of Product
Sr. No. Name of Product CAS No. Total Quantity
(MT/Month)
Final Application of
Product1 Unsaturated Polyester Res in 26123-45-5 1000
Artificial Quartz Stone & Marble
Stone
2 Alkyd Resin 63148-69-6 120
3 Epoxy Resin 24969-06-0 50
4 Saturated Polyester Res in 61926-16-7 50
5 Vinyl Ester Resin 68002-44-8 50
Raw material consumption is given in Table 2.2
Table 2.2 Details of Raw material
Sr. no.
Name of the Products Name of the Raw Materials CAS No. QuantityMT/Month
1 UNSATURATED POLYESTER RESIN
Glycol( MEG/DEG/PG/NPG)
107-21-1 271
Acid Anhydride (PA/IPA/PTA/AA)
85-44-9 264
Maleaic Anhydride (MA) 108-31-6 156Styrene Monomer 100-42-5 400
2 ALKYD RESIN Castor Oil/Linseed Oil/Soya bean Oil
8001-79-4/8001-26-1/8001-22-7
34.32
Glycerin/MEG/Pentaerithritol/NPG/ Trimethalol Propane
56-81-5 23.28
Acid Anhydride(PA/MA/AA/Resin)
85-44-9/108-31-9
37.8
Xylene 1330-20-7 303 SATURATED POLYESTER
RESINAcid Anhydride (IPA/PTA) 121-91-5 24.5
5 Sodium Di Methyl SulfoIsopthate
(DMS Salt)
3965-55-7 13.5
Glycol( MEG/DEG/PG/NPG) 107-21-1 23Di Butyl Tin Oxide 818-08-6 0.5
4 EPOXY RESIN Epoxy Resin 24969-06-0 30Bisphenol-A 80-05-7 7.5Caustic Soda 1310-73-2 0.005
Xylene 1330-20-7 12.55 VINYL ESTER RESIN Epoxy Resin 24969-06-0 15
Bisphenol A 80-05-7 7Methacrylic Acid 79-41-4 5.5Styrene Monomer 100-42-5 22.5
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Draft EIA Report of M/s Kemz Resibond Private Limited III
Water Requirement: The water requirement for Proposed project will be sourced from Borewell and application has been already submitted to Central Ground Water authority. For the project, water is only required for Cooling, Gardening & Domestic use. For proposed project total water requirement will be 5.5 KLD (Industrial: 0.5 KLD + Gardening: 3 KLD + Domestic: 2 KLD).
Wastewater Generation: There will be zero discharge of Industrial effluent. Total industrial waste water generation will be 3.55 KLD. The waste water will be generated from process due to water extraction process and also in form of Cooling Blow down which will be treated in ETP having treatment units like collection cum neutralization tank and finally evaporated in evaporator. Unit will achieve Zero Liquid Discharge by evaporated in evaporator.
Table 2.3 Details of Water requirement and Wastewater generation
Sr.No.
Category Water consumption
(KL/Day)
Wastewater Generation (KL/Day)
Mode of Disposal
1 Domestic 2 1.2 To soak pit
2 Gardening 3 Nil
2 Process
a Process NIL 3.5 To ETPFollowed byEvaporationb Cooling 0.5 0.05
Total 5.5 4.75
Fuel, energy & Stack: Electricity will be supplied by Madhaya Gujarat Vij Company Ltd (MGVCL). Load requirement will be 125 KVA from MGVCL. DG Sets will be used as standby back-up supply for emergency conditions & safe shutdowns. The unit having emergency power supply provision by one D. G. Set of 100 KVA. Unit has proposed to install Thermic Oil Heater (4 Lac Kcal/Hr) in which LDO (44 Lit/Hr) will be used as fuel.Unit has proposed to install Reactors (3 Nos.) & Blenders (3 Nos.) in which scrubber will be installed as APCM to control of VOCs for exceptional cases if it is generated.
Table 2.3 Details of Flue gas stack
Sr. No.
Name of Unit Stack height
(m)
Type Of Fuel
Quantity of Fuel
Parameter Air Pollution Control System
01 Thermic Oil Heater
12 LDO 44Lit/Hr PMSO2
N.A.
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Draft EIA Report of M/s Kemz Resibond Private Limited IV
(4 Lac Kcal/Hr) NOx
02D.G. Set
(100 KVA)(Standby Use)
6 HSD 10 Lit. /Hr Acoustic Enclosure
Table 2.3 Details of Process gas stack
Sr. No.
Name of Unit Stack height
(m)
Parameter Air Pollution Control System
01 Reactors (Sealed Vessels)
3 Nos.
Close Circuit System VOCs
Scrubber
02Blenders3 Nos.
Hazardous Waste: Following hazardous waste will be generated
Table 2.4 Details of Hazardous waste generation and its management
Sr. No.
Type of Hazardous
Waste
Source Cat. No.
Quantity(MT/Year)
Management
01 ProcessWaste/Residue
Process 21.1 35 Collection, Storage and Reuse and Non-Reusable disposed to CHWIF Site.
02 ETP Sludge ETP Plant 35.3 4 Collection, Storage and Disposal atTSDF Site.
03 EvaporationResidue
From Evaporator
37.3 3 Collection, Storage and disposal at CHWIF Site.
04 Used Oil Lubrication/D.G.set
5.1 0.05 Collection, Storage and reuse as Lubricant withinPremises.
05 Discardeddrums/bags
MaterialHandling
33.1 5 Collection, Storage and Sold to Recycler
3. BASELINE ENVIRONMENT QUALITY:
For the present EIA study, the area falling within 10 km radial distance from project site has been selected and was carried out in summer Season during March-2019 to May -2019. The sampling locations were selected on the basis of surface influence, demographic influence and meteorological influence and based on CPCB guideline. Ambient air monitoring was
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Draft EIA Report of M/s Kemz Resibond Private Limited V
collected from 8 locations including Project site and meteorological station was installed at Project site. 8 Ground water samples, 1 surface water sample, 7 noise monitoring samples &8 soil sample were collected including for project site (Please refer table 3.1).
Table 3.1: Sampling and Monitoring Locations
Name of village/ location
Direction w.r.t.Project site
Approx. distance
from project
site (km)
Environmental Attributes
monitored*
Type of area
1 Project Site (A1) -- -- A, GW, S, N, MET
Industrial
2 Puniyad (A2) NWW 2.75 A, GW, S, N Residential
3 Menpur (A3) N 2.05 A, GW, S, N Residential
4 Raman Gamdi(A4)
NW 6.79 A, GW, S, N Residential
5 Kayavarohan (A5) E 3.8 A, GW, SW, S, N
Residential
6 Dhanora (A6) SWW 4.92 A, GW, S, N Residential
7 Karjan (A7) SWW 9.42 A, GW, S Commercial
8 Gandhara (A8) S 3.13 A, GW, S Residential
Map of study area showing sampling & monitoring locations are illustrated below in Figure.Seismology: According to the Seismic-zoning Map of India [IS 1893 (Part I):2002], the study region falls in Zone III – Fairly Medium Intensity.
Land Use Pattern: The land use pattern of the study area comprised of the major with Crop land, Fallow land, Grass land etc. with about settlements with 12 m2.
Google image shows the study area of 10 km radius sampling & monitoring locations
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Draft EIA Report of M/s Kemz Resibond Private Limited VI
Meteorology & Micrometeorology: Continuous monitoring with hourly data recording throughout the study period Micro controller based Automatic Weather station with data logger was installed at Project Site that monitored Surface Temperature, Relative Humidity, Wind Speed & direction and rain fall data.
Ambient Air Quality: Ambient Air Quality Monitoring was carried out for 3 months. Parameters Particulate Matter10 (PM10), Particulate Matter2.5 (PM2.5), Sulphur Dioxide (SO2), Oxide of Nitrogen (NOx), was measured on the basis of 24 hourly monitoring periods, Volatile Organic Compound (VOC) was measured on the basis of 8 hourly monitoring and Noise level were measured based on grab sampling.
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Draft EIA Report of M/s Kemz Resibond Private Limited VII
Table 3.2: Summary of Ambient Air Quality
Sr no. Sampling
Location
Statistical index PM10 PM2.5 SO2 NO2 VOC
µg/m3
1 Project Site (A1)
Average
(Min-Max)
75.6
(69.2-80.6)
35.8
(30.4-41.9)
20.6
(18.2-24)
33.9
(29.3-38.5)
BDL
(DL=1)
98th Percentile 80.2 40.79 23.5 38.2
2 Puniyad (A2) Average
(Min-Max)61.7
(54.6-68.9)27.8
(22.3-32.5)13.4
(9.8-15.1)25.8
(20.2-28.9)BDL (DL=1)
98th Percentile 67.5 31.8 14.8 28.3
3 Menpur (A3) Average
(Min-Max)
63.5
(56.6-70.2)
25.7
(21.1-30.5)
12.0
(9.1-14.5)
28.7
(24.1-32.2)
BDL
(DL=1)
98th Percentile 68.8 29.9 14.2 31.5
4 Raman Gamdi(A4)
Average
(Min-Max)54.2
(50.2-60.2)
17.7
(14.1-21.5)
13.6
(11.2-16.3)
24.6
(21.2-28.9)
BDL
(DL=1)
98th Percentile 59.0 21.0 15.8 28.3
5 Kayavarohan(A5)
Average
(Min-Max)
64.7
(59.9-70.6)
28.2
(22.1-33.7)
18.2
(15.5-20.2)
35.3
(30.2-39.5)
BDL
(DL=1)
98th Percentile 70.4 32.7 19.8 38.7
6 Dhanora (A6) Average
(Min-Max)
67.6
(56.3-76.6)
28.8
(24.2-36.7)
16.7
(12.2-21.2)
32.7
(24.2-38.5)
BDL
(DL=1)
98th Percentile 75.49 34.86 20.74 38.22
7 Karjan (A7) Average
(Min-Max)50.1
(40.2-64.2)21.9
(17.7-25.9)13.3
(11.3-16.2)27.1
(20.2-30.9)BDL (DL=1)
98th Percentile 62.22 25.57 15.69 30.71
8 Gandhar(A8)
Average
(Min-Max)
55.8
(50.6-60.9)
16.3
(11.9-19.2)
11.4
(9.3-13.9)
21.6
(14.9-25.1)
BDL
(DL=1)
98th Percentile 60.9 19.1 13.7 25.0
Standard 100
(24 hrs.)
60
(24 hrs.)
80
(24 hrs.)
80
(24 hrs.)
2
(8 hrs.)
BDL: Below Detectable LimitAll pollutant parameters are found below prescribed norms of AAQM circular. VOC found below detectable limit at all locations.
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Draft EIA Report of M/s Kemz Resibond Private Limited VIII
Water Environment:
Study area falls in command area of Narmada Canal. It was observed that ground water is supplied to house hold via tank. At some places Canal water, ground water and pond water are major sources of irrigation water.
At all locations ground water is utilized for domestic as well as drinking purpose. As per Drinking water standard of IS: 10500 ground water of all the locations can be used for domestic purpose. The water can be used for drinking purpose after proper treatment of hardness (softener/ boiling of water); TDS & chlorides (RO); bacteria (UV/ boiling of water); as alkalinity is not so high than standard it can be removed along with TDS.
Large dia, collector type wells, generally for regional water supply or for industrial uses are common in sandy beds of Mahi and Orsang rivers. Category of dabhoi taluka is safe for ground water extraction.
Soil Environment:
The soil of Vadodara district can be broadly classified into three groups. They are black soils, alluvial soils and hilly soils.
Soil texture of the study area is either salty loam or clay which is moderately well drained fine soils on very gently sloping alluvial plain with moderate erosion. pH value is found to be moderately alkaline. Organic Carbon is found to be medium to high which indicates soil of the some area is poor in fertility and some of them are fertile soil. Available potassium is medium to high and available phosphorous is found to be very low to high. Soil is salt-free.
Noise Environment:
The noise level measurement was carried out by using Noise Meter for eight locations in day and night time, including project site and are found within prescribed norms.
Ecology & Biodiversity:
The trees, herbs, shrubs and major crops, observed during the biological survey conducted within study area. During study 88 flora observed belongs to 48 Family are enumerated from the study area.
Among the enumerated flora in the study area, no rare and endangered flora was observed.
The agriculture is major land use of the study area. During study 67 fauna observed belongs to 41Family are enumerated from the study area.
This report is based on a short duration study. The following lists are obviously incomplete. It does not include many other species which might occur in this part of Vadodara District, either as resident or as migrant in the other seasons of years. This data is based on the survey conducted.
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Draft EIA Report of M/s Kemz Resibond Private Limited IX
Socio- Economic Structure: The Project Influence Area (PIA) has total population of 49815 per 2011 census. As per the 2011 census, the area is having facilities in terms of education, communication, and health services and banking facilities. All the basic amenities like post, telephone, transportation, drinking water, school, health center/dispensary, electricity are available in almost all the villages of the study area.
4. ANTICIPATED ENVIRONMENTAL IMPACTS & MITIGATION MEASURES:
There may be various types of environmental impact arising due to the proposed project. Various environmental concerns due to proposed project are as below.
(1) Air Environment(2) Water Environment(3) Noise Environment(4) Land/Soil Environment(5) Ecology(6) Socio Economic Environment(7) Health & Safety
Air:
Impact during Construction Phase: Main Impacts during construction period is dusting and Air Pollution from vehicles. The impact during construction phase will be short term and reversible.
The main sources of emission during the construction period are the movement of equipment at site and dust emitted during handling, grading, earthwork, and exhaust emissions from vehicles and equipment deployed during the construction phase is also likely to result in marginal increase in the levels of SO2, NOx and SPM.
Impact during Operation phase: The air modelling software is used to evaluate the air emission due to the flue gas from stack attached to TFH in to the environment as it may affect beyond the project industrial boundary. The model stimulates the relationship between air pollutants emission, meteorology and air chemistry, all of which are determined by formulating impact scenario.
As mentioned above TFH will be installed for Proposed Project. The AERMOD is used and inserted the ground level concentration in Table 4.1
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Draft EIA Report of M/s Kemz Resibond Private Limited X
Table 4.1: Maximum Computed Ground Level Concentration At Project Site
Sr.No.
Description ValueConcn *( µg/m3)
Co-ordinatesX (m) Y (m)
A PM1 1st Highest 24 hr. Result 1.35560 321.39 383.022 2nd Highest 24 hr. Result 1.33896 383.02 321.39
B SO21 1st Highest 24 hr. Result 2.54827 321.39 383.022 2nd Highest 24 hr. Result 2.51574 383.02 321.39
C NOx1 1st Highest 24 hr. Result 0.85586 321.39 383.022 2nd Highest 24 hr. Result 0.84487 383.02 321.39
The maximum computed ground level concentration at project site is mentioned in Table 4.1 and cumulative concentrations due to incremental GLC’s are mentioned in Table 4.2.
Table 4.2: Cumulative Concentrations Due To Incremental GLC's
Pollutant
MaximumBaseline
Conn
( g/m3)
IncrementalConn due to
Proposed Project
( g/m3)
Resultant Conn
( g/m3)
NAAQStandards( g/m3)
PM 88.66 1.35560 90.0156 100
SO2 33.62 2.54827 36.16827 80
NOx 48.7 0.85586 49.55586 80
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Draft EIA Report of M/s Kemz Resibond Private Limited XI
Water :
The unit will segregate the waste streams for effective treatment. Domestic Wastewater @ 1.2 KL/day will be disposed off through Soak Pit/Septic Tank System. Industrial Effluent generation @ 3.5 KL/day will be sent to ETP for Primary treatment and then it will be evaporated in Evaporated System. So, unit will achieve Zero Liquid Discharge, will not have impact on water environment.
The water requirement for Proposed project will be sourced from Borewell and application for the same has been already submitted.
Noise :
There will be slightly increase in noise level during construction phase due to construction activity and movement of vehicles. But it is restricted to construction phase only and it will occur during daytime, when construction activities will be in progress.
Land :
In proposed unit needs to do Excavation for plant activity. Unit will do construction activity for proposed foundation work. Hence there will be minor impact on the surrounding soil environment and there will be only change in Land Use Pattern for the project site.Hence, due to the proposed project the land use pattern; land cover and topography of the area will be changed only for the project premises.
Ecology:
Any construction activity brings changes in some components of the local Terrestrial ecosystem. The proposed project will not involve removal of any vegetation from the soil and loosening of the topsoil generally causes soil erosion as it is. However, such impacts will be confined to the plant site and will be minimized through paving and water sprinkling and greenbelt development. Thus, there will no major adverse impacts are envisaged on ecological environment due to project activities.
Socio Economic:
Local people involved as contract labors will have benefits of getting employment. Proposed project will generate temporary employment for personnel during operational phase. Due to proposed project there is no major negative impact on socio economic environment.
Health & Safety:
The impact on health and safety hazard is due to Fire, handling of raw material and products. The company will provide sufficient fire fighting system. Therefore, no adverse impact is anticipated.
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Draft EIA Report of M/s Kemz Resibond Private Limited XII
5. ANALYSIS OF ALTERNATIVES
The alternatives analysis plays a key role for evaluation of the proposed technologies. Other two land was selected for proposed project but both are dropped because of one was found gouchar land and other was taken by some trust. Finally, the unit has selected this land which is fulfilling all criteria for setting up the proposed project. Also from all the available technologies latest and best technology with automated machinery will be selected.
6. ENVIRONMENT MONITORING PROGRAMME:
The Project Proponent has planned out the Environmental Monitoring Programme with budgetary allocations annually. The Company has planned for five years fund allocation under the Corporate Environmental Responsibility as per the MoEF&CC circular.
7. RISK ASSESSMENT (RA), CONTENT OF ON-SITE EMERGENCY PLAN (ONEP), HEALTH & SAFETY MEASURES
The probable hazards are Leakages of Hazardous chemicals, Spillage of Acid/Alkali, during charging/transfer of chemicals and also due to electrical spark in solvent storage area which are addresses along with preventive measures in the RA study.
Project Proponent will prepare the onsite Emergency Plan for such hazardous chemicals handling. The content of the On-site Emergency Plan are as per the requirement of GFR. Details of possibilities of occupational health hazard from the proposed manufacturing activities and proposed measure to prevent are addressed in the chapter for acute and chronic health effect and its preventive measures are addressed. Same way, Hazardous Characteristics and toxicity of raw materials and products and proposed measures to control it are addressed.
8. PROJECT BENEFITS
The proposed project activities will become beneficial to the surrounding area or community in terms of infrastructure, employment, social development and other benefits.
9. COST BENEFIT ANALYSIS
Environmental cost benefit analysis is not applicable and therefore the same has not been carried out.
10. ENVIRONMENT MANAGEMENT PLAN
The Environmental Management Plan (EMP) consists of a set of mitigation, monitoring and institutional measures to be taken during the design, construction and operation (post construction) stages of the project. The plan also includes the actions needed for implementation of these measures. The probable impacts identified & the mitigation measures envisaged for protection of Environmental Components during the construction and operational phase are as also tabulated in the Chapter 10.
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11. SUMMARY OF ENV. IMPACTS & CONCLUSION
M/s. Kemz Resibond Private Limited. is a proposed unit located at Survey No:84/1,84/2,Village: Fofadiya, Tal: Dabhoi, Dist: Vadodara-391210.
Salient features of the Project:
Sr. No Contents Details1 Name of the Project: M/s. Kemz Resibond Private Limited
Survey No:84/1,84/2,Village:Fofadiya, Tal:Dabhoi,Dist:Vadodara-391210
2 Details of Applicant Ms. Ankita Agrawal(Director)3 Status Kemz Resibond Pvt. Ltd. is a proposed unit intend to
manufacture various resins at Survey No:84/1,84/2, Village: Fofadiya, Tal: Dabhoi, Dist: Vadodara-391210.
For this the unit has applied for obtaining Environment Clearance from SEIAA-Gujarat.
CTE is also granted for the same from GPCB.4 Total Plot area
( sq. meter)Proposed: 7551.00 Sq. m.
5 Capital Investment of theProject, Rs. in Crores
Proposed: 4.7238 crores
6 Capital cost for EMP, Rs. in Lakhs
14.1 Lacs
7Recurring cost for EMP,Rs. in Lakhs
12.25 Lacs
8 Employment opportunity Proposed: 20
9 Green belt Development Proposed: 1667 .Sq. m.
10 Pollution control measures adoptedEffluent disposal Domestic Wastewater is 1.2 KL/day will be
disposed off through Soak Pit/Septic Tank System.Total Industrial Effluent of 3.5 KL/day will be collected neutralized in the ETP and then evaporated.
Flue gas emission control Adequate stack height will be provide.
Stack monitoring facilities for the periodic monitoring of the stack to verify the compliance of the stipulated norms.
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Process gas emissioncontrol
Scrubber will provide with Reactors & Blenders.
Fugitive emissioncontrol We will provide the scrubber with blender due to any rarely circumstances if acid fumes will generate.
Hazardouswaste management
All the hazardous waste will be collected, stored, handled, transported and disposed as per the Hazardous Waste (Management, Handling and Transboundary Movement) Rules, 2016, amended time to time etc. are major Act/rules/notification applicable to industry.
11Expenditure for CSR & CERactivities
Rs. 9.5 Lacs
Conclusion:
Negligible impact will occur on air quality & all the required air pollution control system will be provided.There will be no ecological damage.No adverse impact will occur on water environment.Local employment opportunities will increase.Various other environment parameters like Forest/National Park/Sanctuary and Historical/Religious place will not be affected.Environment Management Plant has been formulated to control all the pollutant parameters and Environment Management Cell has been set-up to ensure that these parameters do not exceed the norms set out by the concerned authorities.After commissioning of the proposed project, the Environment Management Cell will take care of all the pollution control measures.
Thus It is concluded on a positive note that due to the adequate provision and efficient operation of proposed environmental management systems and after the implementation of the proposed mitigation measures and environmental management plans, the project activities during the operation phase would have manageable & largely have minor impacts on the environment, and on balance the project would be beneficial to surrounding communities and the region.
12. DISCLOSURE OF CONSULTANT:
Details of the Environmental Consultant and its experts details and NABL Accredited laboratories are addressed in EIA report.
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CHAPTER 1
INTRODUCTION
1.1 PREAMBLE
M/s. Kemz Resibond Private Limited is a proposed unit located at Survey No: 84/1,84/2,Village: Fofadiya, Tal: Dabhoi, Dist:Vadodara-391210.The unit intends to manufacture Synthetic organic Resins viz. Unsaturated Polyester Resin, Alkyd Resin, Epoxy Resin,Saturated Polyester Resin, Vinyl Ester Resin.
The proposed site is well connected with National highway-48 whereas nearest city isVadodara located at a distance of @ 30Km.The nearest Village is Nana Fofadiya at distanceof @ 900m. There is no National park, Sanctuary or Forest land in surrounding 10Km radius.The project doesn’t fall under CRZ boundaries.
The proposed project fall under Project/ Activity No.- 5(f) Synthetic Organic Chemicals- and fall under “Category-B” as stated in Environmental Impact Assessment Notification dated 14/ 09/ 2006 and hence Environmental Clearance is mandatory and required to be obtained as “Category-B” project from SEAC, Gujarat.
In order to assess the Environmental Impacts of the proposed project, Kemz Resibond Private Limited entrusted Entech Laboratory, Ahmedabad to undertake Draft Environmental Impact Assessment Study for various components of the Environment viz., Air, Water, Noise, Land and Socio-economics. This Report presents base line data collected for March – April – May 2019 for Air, Water, Noise, Land etc., for identification and assessment of the impacts.
1.2 PURPOSE OF EIA
Environmental Impact Assessment (EIA) is the process of evaluating likely environmental impacts, both positive and negative, of a new or expansion project by taking into account natural, social and economic aspects. It also comprises of suggesting mitigation measures, for the possible negative impacts, before implementation of the project.
The purpose of the EIA study is to identify existing environmental condition in the study area, predicting and assessing environmental impacts due to the proposed project and suggesting measures to mitigate the adverse impacts and to delineate a comprehensive environment management plan along with recommendations and suggestions. The different activities that are likely to take place in the proposed project have been identified and mitigation measures have been proposed.
On 27th January 1994, the Union Ministry of Environment and Forests (MoEF), Government of India, under the Environmental (Protection) Act 1986, promulgated EIA Notification making Environmental Clearance (EC) mandatory for expansion or modernization of any activity or for setting up new projects listed in Schedule of the notification and its subsequent amendments.
On 14 th September 2006, a new legislation was passed, which has objectives such as “To formulate a transparent, decentralized and efficient regulatory mechanism; to incorporate necessary environmental safeguards at planning stage; to involve stakeholders in the public consultation process and to identify developmental projects based on impact potential instead of the investment criteria”
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As per the provisions of the new re-engineered EIA Notification of 2006, the company requires to obtain prior Environmental Clearance from the State Level Environmental Appraisal Authority or from the Ministry of Environment & Forests, New Delhi as stated in the said Notification.
This Proposed project falls under Synthetic organic Chemical Industry which is listed in Schedule and falls under Clause No. 5 (f) of Category “B” (Located outside notified Industrial area) of Schedule as stated in Environmental Impact Assessment Notification published on 14th September 2006 and its vide amendment.
For this the industry is required to submit an Environmental Impact Assessment Study report to State Pollution Control Board. As the unit is located in outside the notified area it does require the Process of Public Hearing.
As a part of Environmental Clearance process for proposed new project, Kemz ResibondPrivate Limited has uploaded and submitted relevant documents, namely Form - 1 (as per the EIA Notification, 2006, as amended), along with a Pre-Feasibility Report and proposed Terms of Reference (ToRs) for carrying out environmental studies, to the State Expert Appraisal Committee (SEAC) vide letter no. SEIAA/GUJ/TOR/5(f)/1093/2019 dated 30 July 2019. Proposal was accepted on 17/04/2019 by SEIAA. Based on the information contained in the documents submitted, the project has been awarded file no. SIA/GJ/IND2/34668/2019. Presentation was made during the 508th State Expert Appraisal Committee (Industry) meeting held on 24th May 2019 at Gandhinagar, Gujarat. ToR were finalized to conduct the Environmental Impact Assessment (EIA) & Environmental Management Plan (EMP) studies, vide its letter dated 30 July 2019
This report is prepared based on Generic Structure of EIA Document’s given in Appendix III and IIIA to EIA Notification dated 14th September 2006.
1.3 OBJECTIVES OF EIA STUDY
The Environmental study undertaken is aimed at identifying existing Environmental conditions; predicting Environmental impacts associated with the proposed new project and suggesting mitigation measures to mitigate the adverse Environmental impacts. The different activities that are likely to take place have been analyzed and proposed mitigation measures are assessed for their adequacy. Proposed mitigation measures have been considered where necessary.
The study also aims at reflecting the acceptability of the project to different stockholders and at incorporating the concerns raised by them into impact assessment and of the subsequent comprehensive Environmental management Plan and suggest the preventive and mitigative measures to minimize the adverse impacts on the environment and to maximize the beneficial impacts.
1.4 PROJECT PROPONENT
M/s. Kemz Resibond Private Limited is a Small scale proposed unit intend to manufacturing various types Resin. Now, looking at prospective market scenario and considering the large market demand of the Products, the company is keen to manufacture proposed product.
M/s. Kemz Resibond Private Limited is promoted by a team of directors. List of directors is given in TABLE 1.1.
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TABLE NO. 1.1 LIST OF DIRECTORS
Sr.No.
Name Designation Residential Address
1 Mr. Kushank Agrawal Director I-203, Shivabhi Luxuria, Near Jijimata Temple, Makarpura Road,Maneja, Vadodara.
2 Dr. Ankita Agrawal Director I-203,Shivabhi Luxuria,Near Jijimata Temple,Makarpura Road, Maneja,Vadodara.
3 Mr. Brij Vallabh Das Agrawal Director I-203,Shivabhi Luxuria, Near Jijimata Temple,Makarpura Road, Maneja, Vadodara.
IMPORTANCE OF THE PROJECT TO THE COUNTRY, REGION:
The UPR are widely used in the building & construction industry. The growth of the construction industry is an important indicator of a country’s development, as it createsinvestment opportunities across various related sectors. This growth in the constructionindustry is projected to propel the demand for FRP (Fiber glass reinforced plastic) products.This would lead to growth in demand for UPRs in diverse applications. They are widely usedas thermo setting resins with better product performance then another resins such as epoxy,vinyl ester, acrylics, amides and alkyd resins. They are easy to manufacture, cost-effective,easy to processing for conversion into a finished product and readily modified for specific use. Buildings & construction, pipes & tanks and automotive industries make extensive use of various UPRs for making FRP fuel storage tanks, cooling tower components, artificial marble quartz, beams, ladder rails, boat hulls, decks and small automobile parts (both interior andexterior).
Vinyl ester is another variety of resin, whose important property is resistance to moisture andoffers commercial barrier coating. These resins are costlier than UPR. But, their corrosionresistance, mechanical and thermal properties are much better than that of UPR. Therefore,the acceptance of epoxy, vinyl ester, acrylic and poly urethane resins are becoming are whichis strait impact in the growth of the UPR market.
Demand and Supply Gap:Rising global demand for paints & coatings in various industrial applications is one of themajor drivers for growth of there in a market. Unsaturated polyester resins (UPR) are knownfor their commercial usage in fibreglass reinforced plastics (FRP) which are utilized inbuilding & constructions, marine, wind energy, electrical & electronics, pipes & tanks and automotive/transportation. The unsaturated polyester resin market in India is suspended togrow substantially in the next five years. The market is mainly driven by domesticconsumption basically by government, NGOs and civic bodies. The Indian unsaturatedpolyester resin market showed strong growth in the last couple of years due to strong GDPgrowth, increased manufacturing activity and core-sector growth.
Imports v/s Indigenous Production:
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The state and pattern of growth of the economy determine there is in requirement. The requirements of resin may be fulfilled either through indigenous production and/or throughimports. It is not possible for a developing country to import huge quantities of resin becauseof foreign exchange constraints whereas it is better for a country to be self-sufficient in itsresin requirements. The products manufactured will substitute the imports, saving foreignexchange to India.
Export Possibility:There may be large opportunities to become a global supplier of quality resin. Also there exists abundant market opportunities in the neighbouring regions of Asia, Africa and the Middle East.
Domestic/Exports Markets:The finished goods will be sold in domestic market and would be largely exported to theRegulated International Market as per demand.
Employment generation (Direct & Indirect) due to the project:
The proposed project will generate direct employment to 20 personnel initially.
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1.5 LOCATION
M/s. Kemz Resibond Private Limited is located at Survey No: 84/1, 84/2, Village:Fofadiya, Tal:Dabhoi, Dist:Vadodara-391210.
The co-ordinates of site are given below:
Latitude Longitude
A 22 5’08.47” N 73 12’47.77” EB 22 05’08.30” N 73 2’49.33” EC 22 5’03.41” N 73 2’49.43” ED 22 5’03.37” N 73 12’47.80”E
Please refer Figure No. 1.1 for Map of Gujarat State and project location.Please refer Figure No. 1.2for Google Image of Kemz Resibond Private LimitedPlease refer Figure No. 1.3 for 5 km & 10 km radius map of project site.Please refer Figure No. 1.4 for Plant Layout.Please refer Figure No.1.5for Topography Map of Kemz Resibond Private Limited
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FIGURE NO.1.1 MAP OF GUJARAT STATE.
FIGURE NO.1.2 GOOGLE IMAGE OF KEMZ RESIBOND PRIVATE LIMITED
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FIGURE NO. 1.3 5 & 10 KM RADIOUS MAP OF THE PROJECT SITE
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FIGURE NO.1.4LAYOUT PLAN
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FIGURE NO.1.5Topography Map of Kemz Resibond Private Limited
Project Site,M/s. Kemz Resibond Private Limited
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1.6 STUDY AREA
To decide whether proposed action is likely to cause significant adverse environmental effects; the concept of EIA is practiced. Before proceeding the baseline Environmental status, it is important to know the boundary limits and framework where data can be effectively utilized in impact assessment.
In keeping with the nature and size of the industry, based on submitted TOR and additional terms of Reference Issued by State Level environment impact Assessment Authority, Gujarat the study area for detailed studies is an area within a radius of 10 Kms with the Project Site at the centre. A Map of the Study Area is presented in Figure No. 1.3
1.7 NEAREST LOCATION FROM THE SITE
TABLE NO: 1.2NEAREST LOCATIONS FROM THE SITE
Sr.No.
Features Description Distance(Km)
1 Nearest village/City/Industrial Area
Nana Fofadiya 0.9
2 Nearest town Vadodara 22N3 Water Body Creek / Nalah /
lake /Pond /reservoir /canal/ Rivers / Stream / Estuary / Sea
Kayavarohan Lake 3.6 Km
4 Highway SH 161NH 48
2.73 Km2.86 Km
5 Railway Station Karjan 12 Km SW6 Airport Vadodara 30 Km N7 National park / wild life
sanctuary / Reserve Forest landNo National park / wild life sanctuary / Reserve Forest land within 10 km radius.
--
8 CRZ applicability Not Applicable --
Note: All the above mention distances are aerial distances from the project site.
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TABLE NO. 1.3NEAREST INDUSTRIES FROM THE PROJECT SITE
Sr. No.
Name of industries Type of product/Industry Address Approx Distance from the project site (Km)
1. Orbit fabrics Private Limited
Wearing apparel Manglej 4
2. Brooks lab Pharmaceutical Manglej 4
3. KYB Conmat Machinery production Manglej 4
4. Jct electronic Private Limited
Electronic Kandari 4.5
5. Agni Private Limited Fire fighting solutions Kandari 7
6. Patel fibre & cellulose Cellulose fibre Karjan 6
7. Shivam pipes Cement pipes Karjan 8
8. Dwarikadhish steel Steel items Karjan 6
9. Act agro chem Private Limited
Agro chemicals Sadhli road 7
10. Electrotherm (i) Ltd Ductile iron pipe making Karjan 9
11. Standard belex Private Limited
Customized structures Por 6
12. Clad metal technology Private Limited
Metal tubes Raman gamdi 2
13. Nandinee Private Limited Fibre tanks Fofaliya 0.2
14. Conmat oil & gas Private Limited
Oil & gas services Fofaliya 1.5
15. Brent wood Various construction items Fofaliya 2
16. Invac cast Ltd Mining & metals company Fofaliya 2.25
17. Flexathermenpanllow Private Limited
Axial expansion joint Bamangam 3
18. Adheshwar metal Private Limited
Steel pipe manufacturing Raman gamdi 6
19. Delts engineers Pneumatic valve manufacturers
Raman gamdi 5
20. KCM Technologies Private Limited
Hydraulic equipment Por 6.5
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1.8 SCOPE & METHODOLOGY OF EIA:
An attempt has been made to carry out a Draft Environmental Impact AssessmentStudy for M/s.Kemz Resibond Private Limited. The Scope of EIA adopted for KemzResibond Private Limited is based on the TOR approved by SEIAA, Gujarat . The copy of the same is attached here with.
Under the scope of EIA, it covers:
A brief description of project site, its surrounding environment and proposed project facilities.To endow with detail description of the raw materials and manufacturing process for proposed products.Collection and Assessment of existing environmental baseline status based on the project information, field survey relating to air quality, meteorology, water quality, socio-economic aspects, flora & fauna, existing land use pattern etc. within study area.Identification of Impacts due to the proposed project. Prediction and evaluation of the environmental impacts that may result from project development.Outline the Environmental Management Plan (EMP) to mitigate the adverse impacts due to the proposed project.Preparation of Risk Assessment Report.
METHODOLOGY FOR EIA:
The methodology adopted for carrying out the Environmental Impact Assessment for the proposed project has been based on the Guidelines issued by Ministry of Environment and Forest (MOEF). An effective EIA calls for identification of environmental parameters likely to be impacted, depending on the activities to be carried out during construction and operation phase of the project.
Generation and collection of baseline data for valued Environmental components as per approved TOR.
Identification and quantification of significant Environmental impacts due to the project and associated activities.
Evaluation of impacts due to proposed activities and preparation of an Environmental impact statement.
Preparation of appropriate Environmental Management Plan (EMP) surrounding strategies for minimizing identified adverse impacts along with budgetary provisions to be made by the project authorities for implementation of mitigation measures.
Delineation of post Environmental Quality Monitoring Programme (EQMP) along with organizational setup required for monitoring the effectiveness of mitigation measures.
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1.9 REGULATORY FRAMEWORK:
Prior to implementation of proposed expansion project, it will be necessary to acquire all the necessary clearance from the Government of India, as per the applicable national regulations. With respect to prevention and control of environmental pollution, thefollowing Acts and Rules of MoEF govern the proposed project activity:
The Water (Prevention & Control of Pollution) Act, 1974.The Water (Prevention & Control of Pollution) Cess Act, 1977.The Air (Prevention & Control of Pollution) Act, 1981.The Environment (Protection) Rules, 1986 and its amendments from time to timeThe Hazardous Waste (Management, Handling and Transboundary Movement) Rules, 2008.The MSIHC (Manufacture, Storage and Import of Hazardous Chemicals) Rules, 1989.The Noise Pollution (Regulation and Control) Rules, 2000 and its Amendments.The Batteries (Management and Handling) Rules, 2001The Energy Conservation Act, 2001.The National Environment Appellate Authority Act, 1997.The Public Liability Insurance Rules, 1991.The Factories Act, 1948.The Petroleum Act, 1934 and the Petroleum Rules, 2002.Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996The Gas Cylinder Rules, 2004The Static and Mobile Pressure Vessels (unfired) Rules, 1981The Motor Vehicle act, 1988 and The Central Motor Vehicle Rules, 1989Environment Impact Assessment Notification S. O. No. 1533 (E) dated 14th September, 2006 and subsequent Amendments.
STANDARDS:
NAAQS by CPCB, 18th November 2009Drinking water: IS: 10500
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1.10 STRUCTURE OF EIA:
This EIA report has been prepared on the basis of available on-site primary data (survey/ monitoring) and secondary/literature data. The EIA report contains project features, baseline environmental setup, assessment of environmental impacts, and formulation of mitigation measures, environmental management and monitoring plan with risk & assessment Report.
The report includes 12 Chapters. The structure of the EIA Report with necessary tables, drawings and annexure is as follows:
Chapter 1: Introduction
This chapter provides background information on need of project, need of EIA study and brief of the project. The scope and EIA methodology adopted in Preparations of EIA report have also been described in this Chapter. It also covers the identification of project & project proponent, brief description of nature, size, location of the project and its importance to the country and the region. Scope of the study details about the regulatory scoping carried out as per the generic structure given in the EIA Notification, 2006.
Chapter 2: Project Description
This chapter deals with the project details of the proposed products, with type of project, need for the project, location, size & magnitude of operation including associated activities required by and for the project, proposed schedule for approval and implementation, including technical details of raw material, quality and quantity etc.
Chapter 3: Description of the Environment
This chapter presents the existing environmental status of the study area around the proposed project including topography, drainage pattern, water environment, geological, climate, transport system, land use, flora & fauna, socio-economic aspects, basic amenities etc. Environmental assessment of the project site in regard to its capability to receive the proposed project is also discussed in this Chapter.
Chapter 4: Anticipated Environmental Impacts and Mitigation Measures
This chapter describes the overall impacts of the proposed project activities and underscores the areas of concern, which need mitigation measures. It predicts the overall impact of the proposed project on different components of the environment viz. air, water, land, noise, biological, and socio-economic.
Chapter 5: Analysis of Alternatives (Technology & site)
This chapter describes the site selection criteria and analysis of proposed alternative technologies.
Chapter 6: Environmental Monitoring Program
Technical aspects of monitoring the effectiveness of mitigation measures have been given in this Chapter.
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Chapter 7: Additional Studies
This chapter deals with the Public consultation & Risk assessment carried out for the proposed manufacturing plant. Unit is not located in notified area so, public consultation is required.
Chapter 8: Project Benefits
This chapter deals with the benefits to the local surrounding people due to proposed project.
Chapter 9: Environment cost benefit Analysis
During the scoping stage; no recommendation of environmental cost benefit analysis is suggested by the appraisal committee.
Chapter 10: Environmental Management Plan
This chapter details the inferences drawn from the environmental impact assessment exercise. It describes the overall impacts of the proposed activities during construction and operation phases and underscores the areas of concern, which need mitigation measures. It also provides mitigation and control measures for environmental management plan (EMP) for minimizing the negative environmental impacts and to strengthen the positive environmental impacts of the proposed project.
Chapter 11: Summary & Conclusion
This chapter provides the summary and conclusions of the EIA study of the Proposed project with overall justification for implementation of the project and also explanation of how, adverse effects will be mitigated.
Chapter 12: Disclosure of Consultants Engaged
This chapter provides the disclosure of consultants engaged to carry out the EIA study along with other additional studies.
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1.11 PHOTOGRAPHS OF THE PROJECT SITE.
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CHAPTER 2
PROJECT DESCRIPTION
2.1 INTRODUCTION
M/s. Kemz Resibond Private Limited. is a proposed unit located at SurveyNo:84/1,84/2, Village: Fofadiya, Tal: Dabhoi, Dist:Vadodara-391210. The unit intends to manufacture Synthetic Resins viz. Unsaturated Polyester Resin, Alkyd Resin, Epoxy Resin, Saturated Polyester Resin, Vinyl Ester Resins total to the tune of 1270MT/ Month.
2.2 LOCATION
The location of the project is as shown here in Table No. 2.1.
TABLE NO. 2.1 LOCATION OF THE PROJECT SITE
Sr. No.
Description Information
1 Geographical Location Latitude : 22°05’05.35”Longitude : 22°05’05.35”
2 Survey. No. 84/1,84/23 Village Fofadiya4 Taluka Dabhoi5 District Vadodara6 State Gujarat
2.3 JUSTIFICATION OF PROPOSED ACTIVITY
Looking at prospective market scenario and considering the large market demand of the Resins in the domestic as well as global market, the company is keen to set up industrial unit for Resin manufacturing.
To meet the current market requirement Kemz Resibond Private Limited. has intended to set up proposed Resin manufacturing unit at SurveyNo:84/1,84/2, Village: Fofadiya, Tal: Dabhoi, Dist: Vadodara-391210.
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2.4 PROMOTERS & THEIR BACKGROUND
Sr.
No.Name Designation Address
1 Mr. Kushank Agrawal Director I-203, Shivabhi Luxuria, NearJijimata Temple, Makarpura Road, Maneja, Vadodara.
2 Dr. Ankita Agrawal Director I-203, Shivabhi Luxuria, NearJijimata Temple, Makarpura Road, Maneja, Vadodara.
3 Mr. Brij Vallabh Das Agrawal
Director I-203, Shivabhi Luxuria, NearJijimata Temple, Makarpura Road, Maneja, Vadodara.
2.5 INFRASTRUCTURE FACILITIES
The project site is surrounded by industrial units. Indigenous raw materials & Chemicals are available from local market. Due to Developed location, proposed resin activity will be facilitated with good infrastructure and other facilities such as availability of skilled as well as unskilled workforce, contractors, superior communication facilities, transportation facilities etc.
Availability of basic facilities like water, fuel, power, man power and raw materials in nearby areas.There is no rehabilitation and re-settlement involved.Nearest city Vadodara is 22 km away from the location, which is having connectivity with other parts of the country by road, rail& air.The unit is well connected with National Highway (NH-48). Karjan Railway station is 12.0 Km away from the site.No national park or wildlife habitat falls within 10 km radial distance from the project site.Availability of good communication and transportation facilities.
The details of resources are mentioned in Table No. 2.2.
TABLE NO. 2.2DETAILS OF SOURCES
Sr. no.
Project Requirements
Total Source/Remarks
1 Land 7551.74 m2 --2 Total Fresh Water 5.5 KL/Day Borewell3 Power 125 KW Madhya Gujarat Vij
Company Limited4 Fuel Requirement
A LDO 44 Lit/Hr TraderB HSD 10 Lit/Hr Trader
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TABLE NO. 2.3LIST OF PLANT MACHINERIES FOR PROPOSED PRODUCTION ACTIVITY
Sr. No. Name of equipment Size Quantity1 Thermic Oil Heater 4 Lac Kcal/Hr 1 Nos.2 D.G Set 100 KVA 1 Nos.3 Reactors 6 KL 3 Nos.4 Blenders 10 KL 3 Nos.5 Pumps -- As per requirement6 Vacuum pump -- 1 set7 Air Compressor -- 1 no.8 Nitrogen plant -- 1 no.9 Oil extractors with filters -- 1 set10 ETP with evaporator -- 1 set11 Cooling system with pump -- 3 set12 Drier and pulverizer -- 1 set
2.6 LAND USE BREAK-UP FOR TOTAL PLOT AREA
The proposed land area break-up w.r.t. plant machineries, EMS, Green Belt, safety aspect, raw material & product storage is shown at Figure No. 1.4 and listed in Table No. 2.4.
TABLE NO. 2.4LAND USE BREAK-UP FOR TOTAL PLOT AREA
Sr. No. Particulars LAND AREA(Sq. m.)
% of Land Use
1 Built up area 1604 21.242 Parking Area 995 13.183 Garden/green belt area 1667 22.074 Worker Hosing Colony 3000 39.735 Internal Roads 285.74 3.78
Total 7551.74 100.00
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2.7 PRODUCT DETAIL
List of products & capacity are given in the Table No. 2.5
TABLE NO. 2.5LIST OF PRODUCTS
Sr. No.
Product Name CAS No. Total Quantity (MT/Month)
1. Unsaturated Polyester Resin 26123-45-5 10002. Alkyd Resin 63148-69-6 120
3. Epoxy Resin 24969-06-0 50
4. Saturated Polyester Resin 61926-16-7 50
5. Vinyl Ester Resin 68002-44-8 50
TOTAL 1270
2.8 PACKING AND FINAL APPLICATION OF PRODUCTS
TABLE NO. 2.6PACKING AND FINAL APPLICATION OF PRODUCTS
Sr. No.
Name of Product Type of Packing Final Application of Product
1 Unsaturated PolyesterResin
Drums/carboys
Artificial Quartz Stone & Marble Stone
2 Alkyd Resin Drums/carboys3 Epoxy Resin Drums/carboys
4Saturated Polyester Resin Drums/carboys/syn
thetic bags5 Vinyl Ester Resin Drums/carboys
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2.9 RAW MATERIALS REQUIREMENT
List of Raw Materials, with consumption for manufacturing of proposed products, is given in Table No. 2.7.
TABLE NO.2.7DETAILS OF RAW MATERIALS
Sr. No. Product name Name of Raw material
Quantity Total
(MT/Month)
1UNSATURATED POLYESTER RESIN (1000MT/Month)
Glycol(MEG/DEG/PG/NPG)
271
Acid Anhydride(PA/IPA/PTA/AA) 264MaleaicAnhydride(MA) 156Styrene Monomer 400
2 ALKYD RESIN(120MT/Month)
CastorOil/Linseed Oil/Soya bean Oil
34.32
Glycerin/MEG/Pentaerithritol/NPG/ TrimethalolPropane
23.28
AcidAnhydride(PA/MA/AA/Rosin)
37.8
Xylene 30
3SATURATEDPOLYESTER RESIN (50MT/Month)
AcidAnhydride(IPA/PTA) 24.55Sodium Di Methyl SulfoIsopthate(DMSSalt)
13.5
Glycol( MEG/DEG/PG/NPG) 23Di ButylTinOxide 0.5
4 EPOXYRESIN(50MT/Month)
EpoxyResin 30Bisphenol-A 7.5CausticSoda 0.005Xylene 12.5
5VINYLESTERRESIN(50MT/Month
EpoxyResin 15Bisphenol A 7MethacrylicAcid 5.5StyreneMonomer 22.5
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Draft EIA report of M/s. Kemz Resibond Private Limited 27
2.11.3 TRANSPORTATION DETAILS OF RAW MATERIAL & PRODUCT:
All raw materials &
products
State Means of Transportation
Source
Liquid/Solid Tankers/Drums/Sealed Containers/Synthetic bags
From Local vendors/Selling to local vendors
2.11.4 PROJECT COST
Total project cost is 4.7238 Crore. Breakup of investment is given as below:
Sr. No. Name of Assets Total Estimated Investment (Rs. In Lakhs)
1 Land 63.022 Factory Building 161.543 Plant & Machinery 247.82
Grand Total 472.38
2.11.5 PROJECT IMPLEMENTATION SCHEDULE
Implementation of project within a pre-determined time frame is an important factor for the success of a project. Timely implementation may save on various costs like interest, administrative overheads and helps to realize the goals as per pre-determined objectives.
The implementation of the project will involve major activities like preparation of specification / drawings, issue of tenders, receipt of quotations, scrutiny of tenders, placing of orders, construction, delivery & erection, test trial runs of various items. Completion of the project will take place after getting the necessary clearances from concerned authorities.
TABLE 2.7.1: PROJECT IMPLEMENTATION SCHEDULE
Sr.No.
Particulars Expected date of commencement
Expected date of completion
1 Land Already acquired -2 Civil Works 15 days from EC Within 90 days from EC
Plant & Machinery & Other fixed assets3 Placement of orders As soon as EC receive4 Equipment Delivery 75 days from EC 90 days from EC5 Erection & installation 75 days from EC 120 days from EC6 Trial Production 120 days from EC 135 days from EC7 Start of commercial production 135th day from EC onwards
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Draft EIA report of M/s. Kemz Resibond Private Limited 28
2.12 MANUFACTURING PROCESS DETAILS, CHEMICAL REACTION AND MASS BALANCE
1. UNSATURATED POLYESTER RESIN
Process Description:
In SS reactor charge Dihydroxy glycol and Dicarboxylic acids. Raise Temperature up to 160
°C with continuous agitation. Reflux at 160 °C in about 2 hours (approx). Remove the
reaction water continuously to allow temperature to rise to 220°C. Check the sample for acid
value.
Start vacuum distillation for removing access water/volatiles from reactor. Stop
vacuumdistraction and start cooling. Add inhibitor. Further cool to 160 °C.
Discharge liquid resin from reactor into blender containing styrene monomer. During
discharge resin temperature in blender should not increase 70°C. Circulate the water in jacket
of blender to reduce blender temperature. Cool to room temperature. Testing like viscosity,
gel time etc is carried out. Adjust if necessary.
Weighted & packed in drums or carboys
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Chemical Reaction:
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Mass Balance:
2. ALKYD RESIN:
Process Description:
Charge Caster oil/ Linseed oil/ Soya bean oil and Glycerin/ MEG/ pentaerithritol/ Neo penta
glycol/ trimethalol, along with Pthaliec anhydride/ Maliec anhydride/adipic acid/rosin into the
Reactor.
Raise Temperature up to 160°C with continuous agitation. Reflux at 16°C in about 2
hours(approx). Remove the reaction water continuously to allow temperature to rise to 260°C.
Check the sample for acid value.
Start vacuum distillation for removing access water/volatiles from reactor.
Stopvacuum distraction and start cooling. Add inhibitor. Further cool to 160°C.
Discharge solid resin from reactor into blender containing xylene. Circulate the water in
jacket of blender to reduce blender temperature. Cool to room temperature.
Weighted & packed in drums or carboys.
REACTION VESSEL(160 °C To 200 °C)(Approx 2 Hr)
GLYCOL: 261.5 MT/MonthACID ANHYDRIDE: 264 MT/MonthMALEIC ANHYDRIDE: 156 MT/Month
BLENDERSTYRENE MONOMER:400 MT/Month
WATER91.5 KL/Month Dryer
EVAPORATION LOSS:91.5 KL/Month
GLYCOL RECOVERED9 MT/Month
UNSATURATED POLYESTER RESIN: 1000 MT/Month
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Draft EIA report of M/s. Kemz Resibond Private Limited 31
Chemical Reaction:
Material Balance:
REACTION VESSEL(160 °C To 260 °C)(Approx 2 Hr)
CASTOR OIL/LINSEED OIL/SOYA BEAN OIL: 34.32 MT/Month
GLYCERIN/MEG/PENTAERITHRITOL/NPG/ TRIMETHALOL PROPANE: 22.8MT/Month
ACID ANHYDRIDE: 37.8 MT/Month
BLENDERXYLENE: 30 MT/Month
WATER5.4 KL/Month Dryer
EVAPORATION LOSS:4.92 KL/Month
GLYCERIN/ MEG/ PENTAERITHRITOL/ NPG/ TRIMETHALOL PROPANERECOVERED0.48 MT/Month
ALKYD RESIN: 120 MT/Month
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Draft EIA report of M/s. Kemz Resibond Private Limited 32
3. EPOXYRESIN
Process Description:
Charge Epoxy resin and Bisphenol A in reactor. Heat to 170°C and maintaintemperature for
2-4 hours. Check epoxy equivalent weight. Cool it to 80°C. Dilute it in xylene and cool to
room temperature. Testing will be carried out and packedin drums and carboys.
Chemical Reaction:
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Draft EIA report of M/s. Kemz Resibond Private Limited 33
Material Balance
4. Saturated Polyester Resin
Process Description:
Charge Isophthalic acid/purified terephthalic acid and 5 sodium dimethylisophthalate, along
with di-ethylene glycol/polyethylene glycol and mono ethyleneglycol with di butyl tin oxide
in reactor.
The mass will be heated to 165°C where methanol/water will start coming out andmass
viscosity will be start increasing. The methanol/water will be condensedand removed. The
mass heated up to 200°C and vacuum is applied and excessglycols and water will be
removed. The polymer will be discharged in trays.
Crushed, pulverized and packed in bags
REACTION VESSEL(170 °C)(Approx 2 -4Hr)
EPOXY RESIN: 30 MT/Month
BISPHENOL A: 7.5 MT/Month
CAUSTIC SODA: 0.005 MT/Month
BLENDERXYLENE: 12.5 MT/Month
EPOXY RESIN: 50 MT/Month
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Draft EIA report of M/s. Kemz Resibond Private Limited 34
Chemical Reaction:
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Material Balance
IPA/PTA: 24.25 MT/MonthDMS Salt: 13.25 MT/MonthDEG/PG: 11.25 MT/MonthMEG/NPG: 11.25 MT/Month
Methanol : 10.5 MT/Month
SATURATED POLYESTER RESIN (50 MT/Month)
REACTION VESSEL(165 °C)
TRANS ESTERIFICATIONREACTOR
TRAYS
CRUSHING
PULVERIZING
PACKING
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Draft EIA report of M/s. Kemz Resibond Private Limited 36
5. VINYL ESTER RESIN
Process Description:
Charge Epoxy resin and Bisphenol A in reactor. Heat to 170 °C and maintain temperature for
2-4 hours. Check epoxy equivalent weight. Cool it to 100 °C. Add Methacrylic acid and
additives in reactor. Maintain the temperature for 4-6 hours. Cool to 80 °C.
Discharge solid resin from reactor into blender containing styrene monomer. During
discharge resin temperature in blender should not increase 70 °C.Circulate the water in jacket
of blender to reduce blender temperature. Cool to room temperature. Testing like viscosity,
gel time etc is carried out. Adjust if necessary.
Weighted & packed in drums or carboys
ReactionChemistryReaction Chemistry
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Draft EIA report of M/s. Kemz Resibond Private Limited 37
Material Balance:
REACTION VESSEL(170 °C)(Approx 2 -4Hr)
EPOXY RESIN: 15.13 MT/Month
BISPHENOL A: 6.89 MT/Month
METHACRYLIC ACID: 5.25 MT/Month
BLENDERSTYRENE MONOMER: 22.5 MT/Month
VINYL ESTER RESIN: 50 MT/Month
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Draft EIA report of M/s. Kemz Resibond Private Limited 38
2.13 WATER REQUIREMENT & WASTEWATER GENERATION
M/s Kemz Resibond Private Limited. is proposed unit and the source of water for proposed activity will be Bore-well.Water Balance Diagram is shown at Figure No. 2.1
TABLE NO. 2.8DETAILS OF WATER CONSUMPTION & EFFLUENT GENERATION
Sr.No.
Category Water consumption
(KL/Day)
Wastewater Generation (KL/Day)
Mode of Disposal
1 Domestic 2 1.2 To soak pit
2 Gardening 3 Nil
2 Process
a Process NIL 3.5 To ETPFollowed byEvaporation
b Cooling 0.5 0.05
Total 5.5 4.75
1. Total water requirement for the project:5.5KLD2. Domestic water Consumption will be around 2 KLPD and sewage generated will be
disposed to soak pit @1.2 KLPD.3. Gardening water consumption will be 3.0 KLPD.4. Industrial effluent generation will be 3.55 KLPD which will be treated in ETP having
treatment units like collection cum neutralization tank and finally evaporated in evaporator. Unit will achieve Zero Liquid Discharge by evaporated in evaporator.
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Draft EIA report of M/s. Kemz Resibond Private Limited 40
2.13.1 WASTEWATER MANAGEMENT
Domestic Wastewater @ 1.2KL/day will be disposed off through Soak Pit System.
Industrial Effluent generation @ 3.55 KL/day will be sent to ETP for Primary treatment and then it will be evaporated in Evaporated System.
So, unit will achieve Zero Liquid Discharge.
2.13.2 CHARACTERISTICS OF EFFLUENT:
The characteristics of wastewater & final outlet would be as follows:
TABLE NO. 2.9CHARACTERISTICS OF INDUSTRIAL EFFLUENT
Sr.No
EffluentParameters Results
ETP Inlet ETP Outlet(Before Evaporation)
1. pH <5 7-7.52. SS (mg/L) 350 1523. TDS (mg/L) 3645 14184. COD (mg/L) 2300 422.55. BOD (mg/L) 1011 525
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Draft EIA report of M/s. Kemz Resibond Private Limited 41
2.14 DETAILS OF EFFLUENT TREATMENT PLANT:
Industrial effluent will be treated in an Effluent Treatment Plant (ETP) having evaporation system. Industrial effluent generated due to various industrial process/activity will be collected in collection cum neutralization tank for the collection of effluent & neutralize the effluent. pH which is generally 7 will be checked. From holding tank, the effluent will be pumped into evaporation system to evaporate the effluent. The sludge/Residue remaining after evaporation will be collected in plastic (HDPE) bags and stored. This will ultimately sent to the landfill (TSDF) site for the ultimate disposal.
TABLE NO.2.10DETAILS OF PROPOSED EFFLUENT TREATMENT PLANT UNITS
Sr. No.
Name of Unit Nos.Size (m)
1 Collection cumNeautrilization Tank
1 1.5X1.5x 2.0(+0.5FB)
2 Evaporation system 1 Capacity: 300liter/hour
FIGURE NO. 2.2EFFLUENT TREATMENT PLANT DIAGRAM
1
2
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Draft EIA report of M/s. Kemz Resibond Private Limited 42
2.15 FLUE GAS EMISSION :
LDO will be used as a fuel in Thermic Oil Heater.
Stand by DG set will be intermittent source of flue gas emission with use of HSD (10Lit/Hr) & operated only during power failure.
The details regarding flue gas emission are given at Table No. 2.11
TABLE NO.2.11FLUE GAS STACKDETAILS
Sr. No.
Name of Unit Stack height
(m)
Type Of Fuel
Quantity of Fuel
Parameter Air Pollution Control System
01 Thermic Oil Heater(4 Lac
Kcal/Hr)
12 LDO 44Lit/Hr
PMSOxNOx
N.A.As we are
using LDO as a fuel
02D.G. Set
(100 KVA)(Standby Use)
6 HSD 10 Lit. /Hr Acoustic Enclosure
TABLE 2.12EMISSION RATE OF THE POLLUTANTS
Sr.No.
Stack attached to Type of Fuel
Dia.(m)
Height (m)
Exit Velocity (m/sec)
Emission Rates (gm/s)SPM
(*)SO2(**)
NOX(***)
1 Thermic Fluid Heater (2 Lac Kcal/Hr)
LDO 0.3 12 8.0 0.058 0.110 0.037
2 D.G. set-I (100 KVA)
HSD 0.15 6 6.0 0.010 0.018 0.006
Note: (*) Based on maximum expected concentration of SPM-150 mg/Nm3 in Flue gas stack
(**) Based on maximum expected concentration of SO2-100 ppm in Flue gas stack
(***) Based on maximum expected concentration of NOx- 50 ppm in Flue gas stack
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Draft EIA report of M/s. Kemz Resibond Private Limited 43
2.16 PROCESS GAS EMISSION:
Electricity will be used as fuel in Reactors & Blenders. There will be no any process gas emissions from unit as reactors and blenders will be in closed vessels with closed circuit system.
Sr. No.
Name of Unit Stack height
(m)
Parameter Air Pollution Control System
01 Reactors (Sealed Vessels)
3 Nos.
Close Circuit System VOCs
Scrubber
02Blenders3 Nos.
2.17 FUEL REQUIREMENT
The details of fuels used for the project are given in Table No. 2.13 .
TABLE 2.13FUEL DETAILS
Sr. No Name of Fuel Qty.01 LDO 44Lit/Hr02 Diesel 10 Lit. /Hr
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Draft EIA report of M/s. Kemz Resibond Private Limited 44
2.18 FUGITIVE EMISSION CONTROL:
Fugitive emission could occur from the vehicle movement, storage yard of raw materials and finished products.
The storage quantity is low since only 7 days inventory will be maintained at site and proper handling methods will be adopted.
Emissions from transport of vehicles would occur to a certain extent. The emissions from traffic movements is controlled by proper planning of the transport of raw materials and finished products to and from the factory premises. All the roads inside the plant is concreted to reduce any dust emissions.
During the production, the industry will carry out regular monitoring of fugitive emissions as per the factories Act.
Measures taken for fugitive emission control:
Proper storage of raw materials, products and fuels.Scrubber will provide with blenders.Ensuring closed feeding and sampling.Establishing SOPs for start-up, shut down and maintenance operational procedures.Regular work place monitoring and ambient air quality monitoring as per post project monitoring plan.Various types of solvents are used in the manufacturing process. These are handled in closed conditions. Good ventilation will be provided to reduce the concentration at the work place/room.
2.18.1 VOC MANAGEMENT PLAN
The VOC emission in unit may occur at different stages of solvent handling such as solvent storage, loading, unloading etc. The fugitive emissions of organic chemicals and VOCs mainly occur due to tank breathing losses, Leaking pipe fitting and valves, during maintenance operations. Following measures will be adopted to ensure compliance and further reduction.
The fugitive emissions in terms of handling losses are reduced by proper storage and handling.Hazardous chemicals will be stored as per standard criteria.Periodically monitoring will be carried out.Proper ventilation in storage & production area will be provided and all materials will be stored inSuitable packing to prevent contamination of air due to particulates & volatile emissions from storage container & area.Enclosed system & efficient procedures for materials charging will be provided.SOP’s for start-up, shut down, operation & maintenance will be established & maintained in all relevant area of works.
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Draft EIA report of M/s. Kemz Resibond Private Limited 45
2.18.2 ODOUR CONTROL ACTION PLAN
Causes of odour during handling and storage, are various raw materials. To control odour following precautions will be taken
Chemicals will be stored in leak free container.Avoiding the solid/hazardous waste storage inventory.Spraying of chemicals wherever required to avoid odour.During ETP operation, due to acidic water some minor odour will be generate. To avoid this scenario, quality of influent waste water (COD, temperature, pH etc.) is maintained within desired limit.
2.19 HAZARDOUS WASTE MANAGEMENT
The hazardous wastes generated by the industry & Method of Management and Handling is given in Table No. 2.14.
TABLE NO. 2.14DETAILS OF HAZARDOUS WASTES
Sr. No.
Type of Hazardous
Waste
Source Cat. No. Quantity(MT/Year)
Management
01 ProcessWaste/Residue
Process 21.1 35 Collection, Storage and Reuse and Non-Reusable disposed to CHWIF Site.
02 ETP Sludge/ ETP Plant 35.3 4 Collection, Storage and Disposal atTSDF Site.
03 EvaporationResidue
From Evaporator
37.3 3 Collection, Storage and disposal at CHWIF Site.
04 Used Oil Lubrication/D.G.set
5.1 0.05 Collection, Storage and reuse as Lubricant withinPremises.
05 Discardeddrums/bags
MaterialHandling
33.1 5 Collection, Storage and Sold to Recycler
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Draft EIA report of M/s. Kemz Resibond Private Limited 46
2.20 NOISE POLLUTION
The typical Noise levels of equipment. As indicated by the Equipment manufacturers are given in Table No. 2.15
TABLE NO. 2.15TYPICAL NOISE LEVELS OF EQUIPMENT
Sr. No.
Name of Machinery/Unit Noise level in dB
1. Pumps 60-652. Compressor 65-75
The following measures have been taken to reduce the noise levels to acceptable limits:
i) Sound producing equipment are enclosed in the sound proofing enclosure to give residual sound pressure level of 85 dB(A) and
ii) Providing suitable ear protecting devices for working personnel.
Details of measures proposed for noise pollution abatement & its monitoring.
Noise levels will be monitored and records of same will be maintained, at day and night at 4-6 locations, fortnightly internally and monthly by third party (GPCB recognized Env. Agency). Also periodically workers will be examined for their hearing ability and accordingly corrective actions will also made if required. Good working conditions will be developed to avoid chances of Noise Pollution. Regular maintenance of machineries, machine guarding and enclosures for the Noisy machines will be done to avoid Noise Pollution. Even though Noisy machines will be strictly be operated in day time only.Effective green belt will be developed to minimize effect of Noise Pollution to surroundings. Required PPEs will be given to workers.
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Draft EIA report of M/s. Kemz Resibond Private Limited 47
2.21 LIST OF HAZARDOUS CHEMICALS
The Raw Materials, which are termed as Hazardous Chemicals as per the "Manufacturing, Storage and Import of Hazardous Chemicals Rules, 1989”, are as listed in Table No. 2.16
TABLE NO. 2.16LIST OF HAZARDOUS CHEMICALS
Name of Hazardous Chemical
Quantity will be stored at a
time (MT)
Threshold Quantity in (MT)
Description
Diethylene Glycol 12 197 (Sch-1, Part-II) Colorless clear viscous liquid with sweet taste and no odor,
easily soluble in water, methanol, diethyl ether.
Monoethylene Glycol 12 267 (Sch-1, Part-II) Colourless, odourless liquid at 20ºC
Propylene Glycol 12 540 (Sch-1, Part-II) Clear colorless oily liquid with no odor and taste,
soluble in water and acetone.Styrene Monomer 10 583 (Sch-1, Part-II) Colorless clear viscous liquid
with sweetish, aromatic odor, very slightly soluble in cold
water.Phthalic Anhydride 15 508 (Sch-1, Part-II) White colored crystals with
acrid and choking odor, very slightly soluble in cold water
and diethyl ether.Maleic Anhydride 15 352 (Sch-1, Part-II) White colored crystals,
soluble in water, while veryslightly soluble in methanol.
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2.22 SAFETY & OCCUPATIONAL MEASURE FOR STORAGE & HANDLING OF THE RAW MATERIAL & PRODUCT:
Use of proper PPE
Dyke wall will be provided to all above ground storage tank.
Fire hydrant system will be installed.
Safety shower and eye washer will be installed near storage area.
Flame proof Electrical fittings will be provided at flammable storage area.
Proper selection of MOC for chemicals storage tank.
Earthing/bonding will be provided for static charges.
Flame arrestor will be provided on flammable material storage tank vent.
Level gauge and level measurement instrument will be provided on material storage tank.
Safety permit system followed for loading, unloading of hazardous chemical.
Authorized person will only be permitted in storage tank area.
NFPA label, capacity and content will be displayed on storage tank.
Good ventilation will be provided.
MOC of pumps, valves, pipes etc. will be acid/corrosion proof.
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Draft EIA report of M/s. Kemz Resibond Private Limited 49
2.23 ACTION PLAN FOR TRANSPORTATION OF RAW MATERIALS AND PRODUCTS INCLUDING HAZARDOUS CHEMICALS:
Following safety precautions are suggested during transportation of hazardous chemicals in tankers / or other vehicles, while unloading, transportation and meeting the emergencies arising out of leakages and spillages of hazardous materials:
Safety Instructions for Transportation of Hazardous Materials:
The name of the chemical along with pictorial sign denoting the dangerous goods should be marked on the vehicle and the packing material.The name of the transporter, his address and telephone number should be clearly written on the road tanker and on the vehicle.The tanker or vehicle should not be used to transport any material other than what is written on it.Only trained drivers and cleaners should transport hazardous chemicals.The transporter and the manufacturer must ensure the safe transportation of the material.The Tanker / Vehicle should be checked for its fitness and safe condition before loading.During loading and unloading, the tanker/vehicle should be braked and isolated against any movement, while loading/unloading, use safety appliances.The tanker / vehicle should not be overloaded beyond the weight permitted by Transport authorities.Check for leakages from the line connections / containers before starting and Stopping the filling operations.Drive the vehicles carefully, especially in crowded localities and on Bumpy roads.Do not apply sudden break.The tanker / vehicle should not be parked for long time on the way and especially in crowded places. Park the vehicle away from residential areas
Tankers:
The tankers are checked for its fitness and safe condition before loading.During loading and unloading, the tanker should be braked and isolated against any movement, while loading/unloading, use safety appliances.Check for leakages from the line connections before starting and stopping the filling operations.Drive the vehicles carefully, especially in crowded localities and on bumpy Roads.Do not apply sudden break.The tanker should not be parked for long time on the way and especially in Crowded Places. Park the vehicle away from residential areas.
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Draft EIA report of M/s. Kemz Resibond Private Limited 50
2.24 COST OF THE PROJECT
The total project cost will be 4.7238 cr including Land ,Building, Plant machinery & Others. Total capital and recurring cost towards Environmental protection Measures per annum will be 14.1 lacs & 12.28 lacs respectively.
Table No.–2.17CAPITAL COST & RECURRING COST OF THE PROJECT
Sr.No
System Approximate recurring cost per annum
(in Lacs)
Approximate capital cost
(Rs. In Lacs)
Basis for cost estimates
1 Air pollution control 0.36 2 The capital cost would include cost of providing adequate height of the stack, ladder and platform, Air Pollution Control Systems and recurring cost would include cost of monitoring of air environment.
2 Water pollution control -- 8 Capital cost would include cost of ETP, Evaporation cost of Spray Drying etc. In capital cost civil work, mechanical work, Electrical work and piping work is included. Recurring cost is for operational phase.
3 Noise pollution monitoring
0.06 -- The recurring cost would include cost of noise monitoring.
4 Solid and hazardous waste management
0.18 3 Capital cost would include cost of providing storage space for hazardous waste and membership of TSDF Fee. Recurring cost would include cost of land filling and transportation.
5 Environment monitoring and management
0.6 -- The recurring cost would be incurred on hiring of consultants and payment of various statutory fees to regulatory agencies.
6 Green belt 1.44 1.10 Development of Greenbelt including Gardening and Plantation
7 Occupational health (OHC)
0.64 -- Occupational health check up of Employees and workers
Total 3.28 14.1
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2.25 POWER REQUIREMENT
TABLE 2.18POWER REQUIREMENT
Electricity DG Set(KVA)
Required Proposed Connected Load (KVA)
Source 100
125 Madhaya Gujarat Vij Company Ltd.
2.26 MAN POWER
The requirement of personnel for the Plant is met with keeping in view the following:Technical support of Plant, including Process Control and InstrumentationSmooth and efficient operation of PlantEffective co-ordination between the various Departments within the Plant Optimum organization with well-defined and judicious job distributionOptimum utilization of different grades of workmen and supervisory staff and Maximum capacity utilization of facilities.
Total Manpower at Kemz Resibond Private Limited will be summarized in Table No. 2.19
TABLE NO. 2.19DETAILS OF MAN POWER
Total Workers in all Shifts
Male Female Total
20 -- 20
2.27 GREEN BELT DEVELOPMENT
The development of Green Belt is an important aspect for any plant because:It acts as a 'Heat Sink'It improves the Ambient Air Quality by controlling SPM in airIt helps in noise abatement for the surrounding areaIt helps in settlement of new birds and insects within itself It increases the aesthetic value of Site.Total plot area is 7551.74 Sq. meter. From that they had planning for gardening and plantation for 1667 Sq. Meter.
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Draft EIA report of M/s. Kemz Resibond Private Limited 52
Unit will develop 10 trees in 1st year, 9 trees in 2nd year, 4 trees in 3rd year, 1 trees in 4th year, 1 trees in 5th year.The tree species selected for the plantation will be pollutant tolerant ,fast growing, wing firm, deep rooted and ever green. The company will select pollutant tolerant plant species. For example, Asopalav, Neem Tree, Ambo, Bamboo etc.They will also develop plantation as per the MoEF guidelines all along the periphery of plant so that these trees perform as natural barrier and bring down the fugitive emission and stop carryover of dust along with wind current.The tree species selected for the plantation will be pollutant tolerant, fast growing, wing firm, deep rooted, and ever green. The company will select pollutant tolerant plant species.
They will also develop plantation as per the MoEF guidelines all along the periphery of plant so that these trees perform as natural barrier and bring down the fugitive emission and stop carryover of dust along with wind current.
Trees to be planted:
Scientific Name Common Name Habit No. Of trees planted
Mangifera indica L. Ambo Tree 2Chamaedorea sifrizii Bamboo Tree 5Alstoniascholaris. Saptaparni Tree 2Roystonea regia Bottle palm Tree 5Bougainvillea Bougainvel Shrub ClumpsAzadirachta indicaA.Juss Neem Tree Tree 3Duranta repensvariegata
Duranta repens -- 3
Dypsis lutescens Butterfly palm -- ClumpsPlumeriarubra L. Champo Tree 2Terminaliacatappa L. Badam Tree 1divaricata jasmine -- ClumpsPolyalthia longifolia Asopalav Tree 2
Five Years greenbelt development plan:
Plantation Period in year 1st 2nd 3rd 4th 5th Total No. of Plants to be Planted 70 70 40 10 10 200Yearly tree plantation (%) 35 35 20 5 5 100%
Capital cost (Rs.) 38500 38500 22000 5500 5500 1,10,000
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Draft EIA report of M/s. Kemz Resibond Private Limited 53
2.28 SCHEME FOR RAIN WATER HARVESTING
For rainwater harvesting calculations, areas like process and storage, Go-down, scrap yard etc. are excluded due tohaving chances of contamination.
Runoff water generated from Roof Top (admin block), Road area and green belt area can be used to store rain water for reuse. As per IMD data average rainfall of Vadodara is 855 mm/annum (0.855 m). The estimated runoff quantum using different run off coefficient applicable for roof top, Green belt and Roads is given below
TABLE NO. 2.20LAND AREA BREAKUP AND ESTIMATION OF RUNOFF
Sr.
No.
Title Area, m2
Rainfall intensity
(m)
Runoff coefficient
Runoff generated
(m3)1 Roof top
(office building)
420 0.855 0.8 287.28
2 Road 3.78 0.855 0.5 1.6163 Greenbelt 1667 0.855 0.2 285.06
Total 574
From the above it is inferred that ~574 m3 effective run off water may likely to be available that can be stored in the proposed tank for reuse. Average rainwater available per day = 574 m3/365 days =1.57 m3/day. The likely storing capacity of proposed pond/tank will be 1 m× 1 m× 2 m i.e. to store ~1.57 m3/day
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Draft EIA report of M/s. Kemz Resibond Private Limited 54
2.29 SOLVENT MANAGEMENT SYSTEM
In the manufacturing process Styrene and Xylene are used as solvents to dissolve solid resin and to make finished product in form of liquid solution and all process occur in blender in air tight container and below evaporation point. i.e 70 °C. However, for accidently leakages the solvent from blender goes recovery through scrubber and reuse.
The solvent consumption is shown at Table No. 2.21
TABLE NO. 2.21DETAILS OF SOLVENT
Sr.No.
Name of the
product
SolventName
SolventUsed (t/t)
Production Capacity (t/Month)
SolventUsed (t/Month)
1 Unsaturated Polyester
Resin
Styrene Monomer
0.4 1000 400
2 Alkyd Resin
Xylene 0.25 120 30
3 Epoxy
Resin
Xylene 0.25 50 12.5
4 Vinyl Ester Resin
Styrene Monomer
0.45 50 22.5
TOTAL 1220 465
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CHAPTER: 3
BASE LINE ENVIRONMENT QUALITY
3.1. INTRODUCTION
Preparation of EIA study needs a datum on which the evaluation can be done. It is necessary to collect data about different environmental attributes that are being affected by the development of the region which, in turn, defines an existing environmental quality of the region to serve as the datum.
Base line data requirement is also necessary to identify environmentally significant issues as well as to enumerate the critical environmental changes that are occurred due to the industrial development of the region.
Here an attempt has been made to collect the information about an existing environment on the below mentioned eight major environmental attributes:
I - Air EnvironmentII - Meteorology III - Water EnvironmentIV - Hydro-geomorphologyV - NoiseVI - Land EnvironmentVII - Ecology VIII - Socio-economic
3.2. STUDY AREA
The study area for Baseline Environmental Quality is the area with a radius of 10 Kms keeping project site as a centre. The same is shown in Figure No. 3.3 and the villages falls under the same is listed in Table No. 3.1.
SCOPE OF THE STUDY AREA
Sr.No.
Environmental Attributes
Description
1 Land use 10 km radius buffer area from the project site as per the EIA requirements
2 Geology & Soils Once during study period3 Geo-Hydrology Once during study period4 Site specific
Hourly Meteorological data
For the following parameters :Temperature (inWind speed (kmph)Wind direction (deg)Relative HumidiyRainfall (mm)Mixing Height
5 Ambient Air Quality Monitoring
For the following parameters :PM10PM2.5NOx
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SO2VOC
Monitoring Duration : Twice in a weekMonitoring Station : Total 8 locations within study including Project site
Location: Project Site, Puniyad, Menpur, Raman Gamdi, Kyavarohan, Dhanora, Karjan, Gandhar
6 Ground Water sampling For ground water samples: Max. 8 sampling locations as mentioned Below – once during the period from March 2019 to May 2019 Parameters: pH, Temperature, Turbidity, Total Solid (TS), Total Suspended Solids (TSS), Total Dissolved Solids (TDS), Electrical Conductivity (EC), Dissolved Oxygen (DO), Total Hardness (as CaCO3), Calcium Hardness, Magnesium Hardness, Total Alkalinity ( as CaCO3), Calcium (as Ca), Magnesium (as Mg), Chloride (as Cl), Sulphate (as SO4), Chemical Oxygen Demand (COD), Biological Oxygen Demand (BOD), Fluoride as F, Colour, Odor, Taste, Sodium as Na, Potassium as K, Iron as Fe & Copper as CuLocation: Project Site, Puniyad, Menpur, Raman Gamdi, Kyavarohan, Dhanora, Karjan, Gandhar
7 Surface Water sampling For surface water samples: Max.1 sampling locations asmentioned Below – once during the period from March 2019 to May 2019 Parameters: pH, Temperature, Turbidity, Total Solid (TS), Total Suspended Solids (TSS), Total Dissolved Solids (TDS), Electrical Conductivity (EC), Dissolved Oxygen (DO), Total Hardness (as CaCO3), Calcium Hardness, Magnesium Hardness, Total Alkalinity ( as CaCO3), Calcium (as Ca), Magnesium (as Mg), Chloride (as Cl), Sulphate (as SO4), Chemical Oxygen Demand (COD), Biological Oxygen Demand (BOD), Fluoride as F, Colour, Odor, Taste, Sodium as Na, Potassium as K, Iron as Fe & Copper as CuLocation: Kayavarohan Lake
8 Soil sampling For soil samples: Total 8 locations within study area including Project siteParameter : Particle size Distribution, Sand, Silt, Clay, Texture, Porosity, Water holding capacity, Organic carbon (OC), Calcium as Ca, Magnesium as Mg, Sodium as Na, Cation Exchange Capacity, Electrical Conductivity, Available Nitrogen, Available Potassium, Available PhosphorusLocation: Project Site, Puniyad, Menpur, Raman Gamdi, Kyavarohan, Dhanora, Karjan, Gandhar
9 Leq Noise levelmeasurement readings
Daytime and nighttime readings at max.7 sampling locations as mentioned above - once during the periodLocation: Project Site, Puniyad, Menpur, Raman Gamdi, Kyavarohan, Dhanora, Nr. Highway
10 Ecology & Biodiversity Once during study period of terrestrial and aquatic life.11 Socioeconomic Study Once during study period12 Risk and Hazard
AnalysisPhysical verification of site once during study period
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TABLE NO. 3.1NAME OF VILLAGES IN STUDY AREA.
Sr. No. Name of Village Distance from Project Site
1. NANA FOFADIYA 0.9 Km2. POR 6.56 Km3. PUNIYAD 2.75 Km4. MENPUR 2.05 Km5. RAMAN GAMDI 6.69 Km6. KAYAVAROHAN 3.8 Km7. BAMANGAM 2.90 Km8. CHHATTRAL 9.22 Km9. RUVAD 6.60 Km10. KANDRI 6.52 Km11. KASHIPURA 6.59 Km12. KARJAN 9.91 Km13. VEMAR 9.16 Km14. NANA FOFADIYA 0.9 Km15. POR 6.56 Km16. PUNIYAD 2.08 Km17. MENPUR 2.03 Km18. RAMAN GAMDI 6.67 Km19. KAYAVAROHAN 4.00 Km20. BAMANGAM 2.90 Km21. DHANORA 4.92 Km22. RUVAD 6.60 Km23. KANDRI 6.52 Km24. KASHIPURA 6.59 Km25. KARJAN 9.42 Km26. VEMAR 9.16 Km
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FIGURE NO. 3.1STUDY AREA MAP OF BASE LINE STUDY FOR 5 KM AND 10 KM RADIUS
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FIGURE NO. 3.2
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3.3. ENVIRONMENTAL STANDARDS OF THE REGION
NATIONAL AMBIENT AIR QUALITY STANDARDSTable 3.2 : National Ambient Air Quality Standards
Pollutants Time-weighted average
Concentration in ambient airIndustrial, Residential, Rural and others area
Ecologically Sensitive area (Notified by CentralGovernment)
Method of Measurement
Sulphur Dioxide (SO2) µg/m3
Annual Average*
50 20 Improved west and GaekeUltraviolet fluorescence
24 hours** 80 80Oxides of Nitrogen as (NO2) µg/m3
AnnualAverage*
40 30 Modified Jacob &Hochheiser (Na-Arsenate)Chemiluminescence24 hours** 80 80
Particulate Matter (Size less than 10 µm or PM10) µg/m3
Annual Average*
60 60 GravimetricTOEMBeta attenuation24 hours** 100 100
Particulate Matter (Size less than 2.5µm or PM2.5) µg/m3
Annual Average*
40 40 GravimetricTOEMBeta attenuation24 hours** 60 60
Ozone (O3)µg/m3
8 hours ** 100 100 UV photometricChemiluminescenceChemical Method
1hours** 180 180
Lead (Pb)µg/m3
Annual Average*
0.50 0.50 AAS/ICP method after sampling on EPM 2000 or equivalent filter paperED-XRF using Teflon filter
24 hours** 1.0 1.0
Carbon Monoxide (CO) mg/m3
8 hours** 02 02 Non Dispersive Infra Red (NDIR) spectroscopy1 hour** 04 04
Ammonia(NH3)µg/m3
Annual Average*
100 100 ChemiluminescenceIndophenol Blue Method
24 hours** 400 400Benzene (C6H6)µg/m3
Annual* 05 05 Gas chromatography based continuous analyzerAdsorption and desorption followed by GC analysis
Benzo(a)Pyrine (BaP)-particulate phase only,µg/m3
Annual* 01 01 Solvent extraction followed by HPLC/GC analysis
Arsenic (As),µg/m3
Annual* 06 06 AAS/ICP method after sampling on EPM 2000 or equivalent filter paper
Nickel (Ni)µg/m3
Annual* 20 20 AAS/ICP method after sampling on EPM 2000 or equivalent filter paper
*Annual Arithmetic mean of minimum 104 measurements in a year taken twice a week 24 hourly at uniform interval.
**24 hourly/8 hourly or 01 hourly values, as applicable, shall be complied with 98% of the time in a year. 2% of the time the time, they may exceed the limits but not two consecutive days of monitoring.
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WATER QUALITY STANDARDS
Table 3.3: Indian Standard Specification for Drinking water
Sr.No.
Parameters Desirable Limit Permissible Limit in the Absence of
Alternate SourceI Essential Characteristics1. Colour, Hazen Units, Max. 5 252. Odour Unobjectionable -3. Taste Agreeable -4. Turbidity, NTU, Max. 5 105. pH value 6.5-8.5 No Relaxation6. Total Hardness (as CaCO3) mg/l, Max. 300 6007. Iron (as Fe) mg/ l, Max. 0.3 1.08. Chlorides (as Cl) mg/l, Max. 250 10009. Residual Free Chlorine, mg/l, Min. 0.2* -II Desirable Characteristics10. Dissolved Solids, mg/l, Max. 500 200011. Alkalinity (as CaCO3), mg/l, Max. 200 60012. Sulphate (as SO4) mg/l, Max. 200 40013. Nitrate (as NO3) 50 No Relaxation14. Fluoride (as F) mg/l, Max. 1.0 1.515. Calcium (as Ca) mg/l, Max. 75 20016. Magnesium (as Mg) mg/l, Max. 30 10017. Copper (as Cu) mg/l, Max. 0.05 1.518. Manganese (as Mn) mg/l, Max. 0.1 0.319. Mercury (as Hg) mg/l, Max. 0.001 No Relaxation20. Cadmium (as Cd) mg/l, Max. 0.01 No Relaxation21. Selenium (as Se) mg/l, Max. 0.01 No Relaxation22. Arsenic (As As) mg/l, Max. 0.05 No Relaxation23. Lead (as Pb) mg/l, Max. 0.05 No Relaxation24. Zinc (as Zn) mg/l, Max. 5 1525. Aluminium (as Al) mg/l, Max. 0.03 0.226. Boron (as B) mg/l, Max. 1 527. Chromium (as Cr) mg/l, Max. 0.05 No Relaxation28. Cyanide (as CN) mg/l, Max. 0.05 No Relaxation29. Phenolic Compounds (as C6H5OH) mg/l,
Max.0.001 0.002
30. Anionic Detergents (as MBAS) mg/l, Max. mg/l, Max.
0.2 1.0
31. Mineral Oil mg/l, Max. 0.01 0.0332. Pesticides Absent 0.00133. Radioactive Materials
a. Alpha Emitters, Bq/I, Max.b. Beta Emitters, Pci/I, Max
--
0.10.037
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AMBIENT NOISE QUALITY STANDARDS
Table 3.4: Ambient Air Quality Standards with respect to noise
Category of Area Limits Leq, dB(A)
Day Time Night Time
Industrial 75 70
Commercial 65 55
Residential 55 45
Silence 50 40
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3.4. AIR ENVIRONMENT3.4.1. AMBIENT AIR QUALITY (AAQ) IN THE STUDY AREA
The collection of base line information for Air Environment includes identification of specific air pollutants being released into the atmosphere having significant impact on neighbourhood. The Ambient Air Quality status, with respect to the identified air pollutants, has been studied at eight major locations including project site. This has been done through Air Quality surveillance program and based on TOR.
The back-ground air quality for PM10, PM2.5, Sulphur Dioxide (SO2)and Oxides of Nitrogen (NOx) was monitored. The monitoring for these parameters has been done at sites located in different directions and situated within the suspected impact zone, in and around the existing project site. We had considered minimum one monitoring station in the upwind direction and minimum one monitoring station in the pre dominant downwind direction at a location where maximum ground level concentration is likely to occur.
3.4.1.1. THE LOCATION OF AAQ STATIONS
The locations of the AAQ stations are based on prevailing meteorology, pollution source and available infrastructure facilities. One station has been particulary set-up in down winddirection.
Thus, monitoring has been done at eight sampling stations located in different directions and situated within the suspected impact zone in and around the existing project site.
The locations map of the AAQ monitoring station is shown in Figure No. 3.3 and tabulated in Table No. 3.5.
TABLE NO. 3.5.LOCATIONS OF AMBIENT AIR QUALITY MONITORING STATIONS
Sr. No. Locations Direction Distance in KM
1 Project Site -- --2 Puniyad NWW 2.083 Menpur N 2.034 Raman Gamdi NW 6.675 Kayavarohan E 4.06 Dhanora SWW 4.927 Karjan SWW 9.918 Gandhara S 3.13
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FIGURE NO. 3.3LOCATIONS MAP OF THE AAQ MONITORING STATION
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3.4.1.2. BASE LINE DATA
At every sampling station, important parameters namely PM10, PM2.5, Sulphur Dioxide (SO2) and Oxides of Nitrogen (NOx) were monitored. The results are given in Table No.3.7. The minimum, mximum, Average and 98 % of PM10, PM2.5, SO2 and NOx are as shown in Table No 3.6
TABLE NO.3.6Ambient Air Quality Analysis Results
(Minimum, Maximum, Average And 98 %) For Individual Location
Sr. no.
Sampling Location
Distance &
Direction
PM10 PM2.5 SO2 NOX VOC
01 Project Site -- Max. 80.6 41.9 24 38.5 BDLMin 69.2 30.4 18.2 29.3 BDLAvg. 75.6 35.8 20.6 33.9 BDL98 % 80.2 40.79 23.5 38.2 BDL
02 Puniyad 2.08 km in NWW
Max. 68.9 32.5 15.1 28.9 BDLMin 54.6 22.3 9.8 20.2 BDLAvg. 61.7 27.8 13.4 25.8 BDL98 % 67.5 31.8 14.8 28.3 BDL
03 Menpur 2.03 km in N
Max. 70.2 30.5 14.5 32.2 BDLMin 56.6 21.1 9.1 24.1 BDLAvg. 63.5 25.7 12.0 28.7 BDL98 % 68.8 29.9 14.2 31.5 BDL
04 Raman Gamdi
6.67 km in NW
Max. 60.2 21.5 16.3 28.9 BDLMin 50.2 14.1 11.2 21.2 BDLAvg. 54.2 17.7 13.6 24.6 BDL98 % 59.0 21.0 15.8 28.3 BDL
05 Kayavarohan 4.0 km in E
Max. 70.6 33.7 20.2 39.5 BDLMin 59.9 22.1 15.5 30.2 BDLAvg. 64.7 28.2 18.2 35.3 BDL98 % 70.4 32.7 19.8 38.7 BDL
06 Dhanora 4.92 km in SWW
Max. 76.6 36.7 21.2 38.5 BDLMin 56.3 24.2 12.2 24.2 BDLAvg. 67.6 28.8 16.7 32.7 BDL98 % 75.49 34.86 20.74 38.22 BDL
07 Karjan 9.91 km in SWW
Max. 64.2 25.9 16.2 30.9 BDLMin 40.2 17.7 11.3 20.2 BDLAvg. 50.1 21.9 13.3 27.1 BDL98 % 62.22 25.57 15.69 30.71 BDL
08 Gandhara 3.13 km in S
Max. 60.9 19.2 13.9 25.1 BDLMin 50.6 11.9 9.3 14.9 BDLAvg. 55.8 16.3 11.4 21.6 BDL98 % 60.9 19.1 13.7 25.0 BDL
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Table No.3.7Ambient Air Quality Analysis Report for the Month of March to May 2019
Name & Address of Client :
ENTECH LABORATORIES.33,34, Kushal Estate, Saket Industrial Estate, Village: Moraiya, Ta: Sanand, Dist: Ahmedabad, Gujarat.
Name of Project :
EIA Study for M/S Kemz Resibond Private Limited. Survey No.: 84/1, 84/2, Village: Fofadiya, Tal: Dabhoi, dist: Vadodara-391210
Location : Project site(A1) Method Of Sampling : IS 5182/USEPA GuidelinesType of Sampling : Grab Sampling Sampling Done By : Entech TeamDescription Of Sample : Ambient Air
Average Wind Speed : 10.8 m/sec
Sampling Duration : 24 Hour Relative Humidity : 26%Test Method for PM10 : IS 5182(P-23) 2012
Test Method for PM2.5 : Lab SOP NO.28 2014 (Based on USEPA)
Test Method for SO2 : IS 5182(P-2) 2012
Test Method for NO2 : IS 5182(P-6)2012
Sr.No
Date ofSampling
ParametersPM10
(µg/m3)PM2.5(µg/m3)
SO2(µg/m3)
NOx(µg/m3)
VOC(PPM)
1 04-03-2019 77.3 36.3 20.6 36.8 BDL2 07-03-2019 77.4 39.5 18.5 32.9 BDL3 11-03-2019 79.4 30.4 19.2 30.2 BDL4 14-03-2019 76.3 34.9 21.8 36.7 BDL5 18-03-2019 76.2 33.7 19.2 31.6 BDL6 21-03-2019 79.1 36.3 22.1 31.1 BDL7 25-03-2019 73.8 38.4 21.2 33.1 BDL8 28-03-2019 73.5 33.2 19.4 29.6 BDL9 01-04-2019 71.6 34.3 22.3 37.2 BDL10 04-04-2019 75.3 34.4 18.7 29.9 BDL11 08-04-2019 71.8 32.9 20.4 31.8 BDL12 11-04-2019 76.5 34.2 19.8 34.7 BDL13 15-04-2019 76.2 33.5 24.0 35.6 BDL14 18-04-2019 80.6 41.9 19.5 36.7 BDL15 22-04-2019 79.3 38.8 21.1 33.1 BDL16 25-04-2019 72.2 32.1 20.3 36.9 BDL17 29-04-2019 74.5 34.4 18.2 29.3 BDL18 02-05-2019 77.9 39.4 23.1 38.5 BDL19 06-05-2019 79.7 36.7 22.3 37.9 BDL20 09-05-2019 73.3 32.4 19.5 33.4 BDL21 13-05-2019 70.6 38.8 20.8 34.5 BDL22 16-05-2019 79.6 37.4 22.9 34.6 BDL23 20-05-2019 69.2 39.0 19.8 36.4 BDL24 23-05-2019 76.8 35.6 20.3 32.8 BDL
Max. 80.6 41.9 24 38.5 -Min. 69.2 30.4 18.2 29.3 -
Average 75.6 35.8 20.6 33.9 -98th Percentile 80.2 40.79 23.5 38.2 -
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TEST REPORT
Name & Address of Client :
ENTECH LABORATORIES.33,34, Kushal Estate, Saket Industrial Estate, Village: Moraiya, Ta: Sanand, Dist: Ahmedabad, Gujarat.
Name of Project :EIA Study for M/S Kemz Resibond Private Limited.Survey No.: 84/1, 84/2, Village: Fofadiya, Tal: Dabhoi, dist: Vadodara-391210
Location : Puniyad (A2) Method Of Sampling : IS 5182/USEPA GuidelinesType of Sampling : Grab Sampling Sampling Done By : Entech TeamDescription Of Sample : Ambient Air
Average Wind Speed : 12.0 m/sec
Sampling Duration : 24 Hour Relative Humidity : 26%Test Method for PM10 : IS 5182(P-23) 2012
Test Method for PM2.5 : Lab SOP NO.28 2014 (Based on USEPA)
Test Method for SO2 : IS 5182(P-2) 2012
Test Method for NO2 : IS 5182(P-6)2012
Sr.No
Date ofSampling
ParametersPM10
(µg/m3)PM2.5(µg/m3)
SO2(µg/m3)
NOx(µg/m3)
VOC(PPM)
1 04-03-2019 66.3 30.2 9.8 25.6 BDL2 07-03-2019 62.2 28.9 11.5 24.9 BDL3 11-03-2019 68.9 32.5 13.2 28.2 BDL4 14-03-2019 58.2 30.7 14.1 27.2 BDL5 18-03-2019 66.9 28.2 13.2 26.5 BDL6 21-03-2019 64.3 28.9 12.5 22.1 BDL7 25-03-2019 63.8 27.1 11.1 26.6 BDL8 28-03-2019 65.2 28.6 13.8 24.8 BDL9 01-04-2019 60.3 26.3 12.8 20.2 BDL10 04-04-2019 59.2 23.9 13.5 26.3 BDL11 08-04-2019 54.6 22.3 13.9 27.4 BDL12 11-04-2019 62.5 27.2 14.3 28.9 BDL13 15-04-2019 61.2 27.5 14.9 28.1 BDL14 18-04-2019 60.6 24.9 13.2 26.2 BDL15 22-04-2019 68.8 29.7 15.1 28.1 BDL16 25-04-2019 62.2 27.1 14.3 27.5 BDL17 29-04-2019 59.6 25.1 14.7 25.9 BDL18 02-05-2019 60.9 23.7 13.8 28.1 BDL19 06-05-2019 64.9 29.9 13.3 24.5 BDL20 09-05-2019 60.3 26.4 14.5 22.1 BDL21 13-05-2019 66.6 30.8 14.8 26.9 BDL22 16-05-2019 64.2 30.2 13.5 25.6 BDL23 20-05-2019 60.4 29.7 14.2 26.2 BDL24 23-05-2019 65.2 30.6 14.6 23.9 BDL
Max. 68.9 32.5 15.1 28.9 -Min. 54.6 22.3 9.8 20.2 -
Average 61.7 27.8 13.4 25.8 -98th Percentile 67.5 31.8 14.8 28.3 -
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TEST REPORT
Name & Address of Client :
ENTECH LABORATORIES.33,34, Kushal Estate, Saket Industrial Estate, Village: Moraiya, Ta: Sanand, Dist: Ahmedabad, Gujarat.
Name of Project :EIA Study for M/S. Kemz Resibond Private Limited.Survey No.: 84/1, 84/2, Village: Fofadiya, Tal: Dabhoi, dist: Vadodara-391210
Location : Menpur (A3) Method Of Sampling : IS 5182/USEPA GuidelinesType of Sampling : Grab Sampling Sampling Done By : Entech TeamDescription Of Sample : Ambient Air
Average Wind Speed : 10.5 m/sec
Sampling Duration : 24 Hour Relative Humidity : 26%Test Method for PM10 : IS 5182(P-23) 2012
Test Method for PM2.5 : Lab SOP NO.28 2014 (Based on USEPA)
Test Method for SO2 : IS 5182(P-2) 2012
Test Method for NO2 : IS 5182(P-6)2012
Sr.No
Date ofSampling
ParametersPM10
(µg/m3)PM2.5(µg/m3)
SO2(µg/m3)
NOx(µg/m3)
VOC(PPM)
1 05-03-2019 65.8 27.2 13.2 28.5 BDL2 08-03-2019 62.2 22.9 14.5 31.9 BDL3 12-03-2019 69.9 27.5 10.2 32.2 BDL4 15-03-2019 65.2 24.7 9.1 26.2 BDL5 19-03-2019 60.9 22.2 9.2 28.5 BDL6 22-03-2019 66.3 26.9 10.5 25.1 BDL7 26-03-2019 68.8 22.1 11.1 30.6 BDL8 29-03-2019 70.2 30.2 13.8 29.8 BDL9 02-04-2019 66.3 29.3 14.3 28.2 BDL10 05-04-2019 62.2 23.4 14.5 26.3 BDL11 09-04-2019 65.6 28.9 10.9 28.4 BDL12 12-04-2019 59.5 25.2 11.3 30.9 BDL13 16-04-2019 62.2 30.5 10.9 30.1 BDL14 19-04-2019 58.6 21.9 12.2 31.2 BDL15 23-04-2019 60.8 27.7 14.1 28.1 BDL16 26-04-2019 66.2 24.1 9.3 29.5 BDL17 30-04-2019 66.5 21.1 11.2 31.9 BDL18 03-05-2019 64.9 26.7 13.8 31.1 BDL19 07-05-2019 60.9 23.9 14.3 29.5 BDL20 10-05-2019 65.3 26.4 12.5 24.1 BDL21 14-05-2019 56.6 26.8 13.8 28.9 BDL22 17-05-2019 60.2 24.2 12.5 24.6 BDL23 21-05-2019 58.2 28.7 11.2 28.2 BDL24 24-05-2019 62.2 24.6 12.2 27.9 BDL
Max. 70.2 30.5 14.5 32.2 -Min. 56.6 21.1 9.1 24.1 -
Average 63.5 25.7 12.0 28.7 -98th Percentile 68.8 29.9 14.2 31.5 -
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TEST REPORT
Name & Address of Client :
ENTECH LABORATORIES.33,34, Kushal Estate, Saket Industrial Estate, Village: Moraiya, Ta: Sanand, Dist: Ahmedabad, Gujarat.
Name of Project :EIA Study for M/S. Kemz Resibond Private Limited.Survey No.: 84/1, 84/2, Village: Fofadiya, Tal: Dabhoi, dist: Vadodara-391210
Location : Raman Gamdi (A4)
Method Of Sampling : IS 5182/USEPA Guidelines
Type of Sampling : Grab Sampling Sampling Done By : Entech TeamDescription Of Sample : Ambient Air
Average Wind Speed : 10.7 m/sec
Sampling Duration : 24 Hour Relative Humidity : 26%Test Method for PM10 : IS 5182(P-23) 2012
Test Method for PM2.5 : Lab SOP NO.28 2014 (Based on USEPA)
Test Method for SO2 : IS 5182(P-2) 2012
Test Method for NO2 : IS 5182(P-6)2012
Sr.No
Date ofSampling
ParametersPM10
(µg/m3)PM2.5(µg/m3)
SO2(µg/m3)
NOx(µg/m3)
VOC(PPM)
1 05-03-2019 54.3 18.2 12.2 26.5 BDL2 08-03-2019 59.2 20.4 11.5 28.9 BDL3 12-03-2019 54.9 21.5 14.2 24.2 BDL4 15-03-2019 60.2 20.7 14.1 21.2 BDL5 19-03-2019 55.9 17.2 12.2 21.5 BDL6 22-03-2019 50.3 17.9 13.5 23.1 BDL7 26-03-2019 55.8 18.1 14.1 23.6 BDL8 29-03-2019 50.2 18.2 15.8 22.8 BDL9 02-04-2019 56.3 19.3 12.3 23.2 BDL10 05-04-2019 52.2 18.4 13.5 21.3 BDL11 09-04-2019 55.6 16.9 11.9 23.4 BDL12 12-04-2019 50.5 17.2 12.3 26.9 BDL13 16-04-2019 56.2 15.5 14.9 25.1 BDL14 19-04-2019 52.6 14.9 15.2 23.2 BDL15 23-04-2019 57.8 16.7 14.1 23.1 BDL16 26-04-2019 52.2 14.1 16.3 21.5 BDL17 30-04-2019 52.5 17.1 11.2 24.9 BDL18 03-05-2019 50.9 18.7 13.8 26.1 BDL19 07-05-2019 54.9 15.9 14.3 28.5 BDL20 10-05-2019 58.3 19.4 15.5 22.1 BDL21 14-05-2019 52.6 16.8 14.8 26.9 BDL22 17-05-2019 50.2 17.2 13.5 28.6 BDL23 21-05-2019 56.2 16.7 12.2 25.2 BDL24 24-05-2019 50.2 18.6 12.2 28.9 BDL
Max. 60.2 21.5 16.3 28.9 -Min. 50.2 14.1 11.2 21.2 -
Average 54.2 17.7 13.6 24.6 -98th Percentile 59.0 21.0 15.8 28.3 -
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TEST REPORT
Name & Address of Client :
ENTECH LABORATORIES.33,34, Kushal Estate, Saket Industrial Estate, Village: Moraiya, Ta: Sanand, Dist: Ahmedabad, Gujarat.
Name of Project :EIA Study for M/S Kemz Resibond Private Limited..Survey No.: 84/1, 84/2, Village: Fofadiya, Tal: Dabhoi, dist: Vadodara-391210.
Location : Kayavarohan (A5)
Method Of Sampling : IS 5182/USEPA Guidelines
Type of Sampling : Grab Sampling Sampling Done By : Entech TeamDescription Of Sample : Ambient Air
Average Wind Speed : 11.1 m/sec
Sampling Duration : 24 Hour Relative Humidity : 26%Test Method for PM10 : IS 5182(P-23) 2012
Test Method for PM2.5 : Lab SOP NO.28 2014 (Based on USEPA)
Test Method for SO2 : IS 5182(P-2) 2012
Test Method for NO2 : IS 5182(P-6)2012
Sr.No
Date ofSampling
ParametersPM10
(µg/m3)PM2.5(µg/m3)
SO2(µg/m3)
NOx(µg/m3)
VOC(PPM)
1 06-03-2019 62.3 30.2 18.2 34.5 BDL2 09-03-2019 65.2 30.9 15.5 36.9 BDL3 13-03-2019 60.9 31.5 19.2 34.2 BDL4 16-03-2019 66.2 33.7 18.1 37.2 BDL5 20-03-2019 65.9 31.2 20.2 39.5 BDL6 23-03-2019 60.3 30.9 19.5 36.1 BDL7 27-03-2019 64.8 27.1 18.1 34.6 BDL8 30-03-2019 69.2 28.2 17.8 36.8 BDL9 03-04-2019 65.3 26.3 19.3 39.2 BDL10 06-04-2019 63.2 25.4 18.5 37.3 BDL11 10-04-2019 62.6 26.9 17.9 34.4 BDL12 13-04-2019 68.5 27.2 17.3 36.9 BDL13 17-04-2019 70.2 28.5 18.9 32.1 BDL14 20-04-2019 70.6 24.9 19.2 30.2 BDL15 24-04-2019 63.8 26.7 19.1 36.1 BDL16 27-04-2019 68.2 27.1 18.3 38.5 BDL17 01-05-2019 61.5 22.1 18.2 30.9 BDL18 04-05-2019 59.9 24.7 16.8 34.1 BDL19 08-05-2019 64.9 26.9 16.3 36.5 BDL20 11-05-2019 64.3 27.4 18.5 38.1 BDL21 15-05-2019 69.6 28.8 19.8 30.9 BDL22 18-05-2019 64.2 30.2 18.5 35.6 BDL23 22-05-2019 62.4 31.7 18.2 30.2 BDL24 25-05-2019 60.2 28.6 17.2 36.9 BDL
Max. 70.6 33.7 20.2 39.5 -Min. 59.9 22.1 15.5 30.2 -
Average 64.7 28.2 18.2 35.3 -98th Percentile 70.4 32.7 19.8 38.7 -
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TEST REPORT
Name & Address of Client :
ENTECH LABORATORIES.33,34, Kushal Estate, Saket Industrial Estate, Village: Moraiya, Ta: Sanand, Dist: Ahmedabad, Gujarat.
Name of Project :EIA Study for Kemz Resibond Private Limited.Survey No.: 84/1, 84/2, Village: Fofadiya, Tal: Dabhoi, dist: Vadodara-391210
Location : Dhanora (A6) Method Of Sampling : IS 5182/USEPA GuidelinesType of Sampling : Grab Sampling Sampling Done By : Entech TeamDescription Of Sample : Ambient Air
Average Wind Speed : 11.8 m/sec
Sampling Duration : 24 Hour Relative Humidity : 26%Test Method for PM10 : IS 5182(P-23) 2012
Test Method for PM2.5 : Lab SOP NO.28 2014 (Based on USEPA)
Test Method for SO2 : IS 5182(P-2) 2012
Test Method for NO2 : IS 5182(P-6)2012
Sr.No
Date ofSampling
ParametersPM10
(µg/m3)PM2.5(µg/m3)
SO2(µg/m3)
NOx(µg/m3)
VOC(PPM)
1 06-03-2019 56.3 25.2 12.2 34.5 BDL2 09-03-2019 70.2 28.9 16.5 37.9 BDL3 13-03-2019 64.9 26.5 14.2 32.2 BDL4 16-03-2019 73.2 32.7 18.1 36.2 BDL5 20-03-2019 65.9 30.2 15.2 34.5 BDL6 23-03-2019 60.3 26.9 13.5 32.1 BDL7 27-03-2019 64.8 28.1 14.1 36.6 BDL8 30-03-2019 70.2 29.2 18.8 28.8 BDL9 03-04-2019 65.3 25.3 16.3 24.2 BDL10 06-04-2019 69.2 28.4 18.5 28.3 BDL11 10-04-2019 70.6 26.9 19.9 30.4 BDL12 13-04-2019 65.5 24.2 14.3 34.9 BDL13 17-04-2019 70.2 27.5 15.9 28.1 BDL14 20-04-2019 76.6 30.9 20.2 30.2 BDL15 24-04-2019 71.8 31.7 19.1 28.1 BDL16 27-04-2019 64.2 28.1 16.3 36.5 BDL17 01-05-2019 60.5 26.1 14.2 34.9 BDL18 04-05-2019 68.9 27.7 16.8 35.1 BDL19 08-05-2019 71.9 30.9 19.3 38.5 BDL20 11-05-2019 70.3 31.4 17.5 29.8 BDL21 15-05-2019 65.6 26.8 15.8 35.9 BDL22 18-05-2019 70.2 28.2 18.5 34.6 BDL23 22-05-2019 74.2 36.7 21.2 30.2 BDL24 25-05-2019 64.2 29.6 15.2 36.9 BDL
Max. 76.6 36.7 21.2 38.5 -Min. 56.3 24.2 12.2 24.2 -
Average 67.6 28.8 16.7 32.7 -98th Percentile 75.49 34.86 20.74 38.22 -
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TEST REPORT
Name & Address of Client :
ENTECH LABORATORIES.33,34, Kushal Estate, Saket Industrial Estate, Village: Moraiya, Ta: Sanand, Dist: Ahmedabad, Gujarat.
Name of Project :EIA Study for M/S Kemz Resibond Private Limited.Survey No.: 84/1, 84/2, Village: Fofadiya, Tal: Dabhoi, dist: Vadodara-391210
Location : Karjan (A7) Method Of Sampling : IS 5182/USEPA GuidelinesType of Sampling : Grab Sampling Sampling Done By : Entech TeamDescription Of Sample : Ambient Air
Average Wind Speed : 13.2 m/sec
Sampling Duration : 24 Hour Relative Humidity : 26%Test Method for PM10 : IS 5182(P-23) 2012
Test Method for PM2.5 : Lab SOP NO.28 2014 (Based on USEPA)
Test Method for SO2 : IS 5182(P-2) 2012
Test Method for NO2 : IS 5182(P-6)2012
Sr.No
Date ofSampling
ParametersPM10
(µg/m3)PM2.5(µg/m3)
SO2(µg/m3)
NOx(µg/m3)
VOC(PPM)
1 05-03-2019 46.3 25.2 12.2 28.5 BDL2 08-03-2019 40.2 22.9 14.5 26.9 BDL3 12-03-2019 54.9 23.5 12.2 24.2 BDL4 15-03-2019 53.2 21.7 15.1 27.2 BDL5 19-03-2019 59.9 21.2 16.2 26.5 BDL6 22-03-2019 54.3 24.9 14.5 27.1 BDL7 26-03-2019 50.8 21.1 13.1 25.6 BDL8 29-03-2019 54.2 25.2 13.8 24.8 BDL9 02-04-2019 58.3 22.3 12.3 20.2 BDL10 05-04-2019 53.2 24.4 14.5 28.3 BDL11 09-04-2019 50.6 21.9 12.9 27.4 BDL12 12-04-2019 59.5 20.2 11.3 25.9 BDL13 16-04-2019 42.2 24.5 12.9 29.1 BDL14 19-04-2019 40.6 18.9 13.2 30.2 BDL15 23-04-2019 45.8 23.7 14.1 26.1 BDL16 26-04-2019 40.2 21.1 12.3 24.5 BDL17 30-04-2019 44.5 20.1 13.2 28.9 BDL18 03-05-2019 48.9 22.7 11.8 26.1 BDL19 07-05-2019 44.9 25.9 14.3 30.5 BDL20 10-05-2019 40.3 19.4 13.5 28.1 BDL21 14-05-2019 47.6 19.8 12.8 26.9 BDL22 17-05-2019 50.2 19.2 11.5 28.6 BDL23 21-05-2019 52.2 17.7 12.2 30.2 BDL24 24-05-2019 64.2 18.6 14.2 30.9 BDL
Max. 64.2 25.9 16.2 30.9 -Min. 40.2 17.7 11.3 20.2 -
Average 50.1 21.9 13.3 27.1 -98th Percentile 62.22 25.57 15.69 30.71 -
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TEST REPORT
Name & Address of Client :
ENTECH LABORATORIES.33,34, Kushal Estate, Saket Industrial Estate, Village: Moraiya, Ta: Sanand, Dist: Ahmedabad, Gujarat.
Name of Project :EIA Study for M/S. Kemz Resibond Private Limited.Survey No.: 84/1, 84/2, Village: Fofadiya, Tal: Dabhoi, dist: Vadodara-391210
Location : Gandhra (A8) Method Of Sampling : IS 5182/USEPA GuidelinesType of Sampling : Grab Sampling Sampling Done By : Entech TeamDescription Of Sample : Ambient Air
Average Wind Speed : 11.1 m/sec
Sampling Duration : 24 Hour Relative Humidity : 26%Test Method for PM10 : IS 5182(P-23) 2012
Test Method for PM2.5 : Lab SOP NO.28 2014 (Based on USEPA)
Test Method for SO2 : IS 5182(P-2) 2012
Test Method for NO2 : IS 5182(P-6)2012
Sr.No
Date ofSampling
ParametersPM10
(µg/m3)PM2.5(µg/m3)
SO2(µg/m3)
NOx(µg/m3)
VOC(PPM)
1 04-03-2019 56.3 18.2 10.2 16.5 BDL2 07-03-2019 60.2 15.9 9.5 14.9 BDL3 11-03-2019 60.9 18.5 11.2 19.2 BDL4 14-03-2019 54.2 13.7 10.1 21.2 BDL5 18-03-2019 60.9 15.2 10.2 20.5 BDL6 21-03-2019 54.3 16.9 12.5 23.1 BDL7 25-03-2019 60.8 17.1 11.1 20.6 BDL8 28-03-2019 54.2 16.2 10.8 22.8 BDL9 01-04-2019 60.3 15.3 12.3 21.2 BDL10 04-04-2019 56.2 16.4 12.5 24.3 BDL11 08-04-2019 51.6 11.9 13.9 23.4 BDL12 11-04-2019 55.5 17.2 11.3 24.9 BDL13 15-04-2019 59.2 18.5 10.9 21.1 BDL14 18-04-2019 50.6 15.9 11.2 20.2 BDL15 22-04-2019 55.8 17.7 10.1 22.1 BDL16 25-04-2019 52.2 15.1 9.3 22.5 BDL17 29-04-2019 58.5 18.1 12.2 23.9 BDL18 02-05-2019 55.9 15.7 11.8 25.1 BDL19 06-05-2019 50.9 18.9 11.3 21.5 BDL20 09-05-2019 53.3 17.4 11.5 23.1 BDL21 13-05-2019 56.6 16.8 12.8 21.9 BDL22 16-05-2019 58.2 19.2 13.5 23.6 BDL23 20-05-2019 52.2 12.7 13.2 20.2 BDL24 23-05-2019 51.2 13.6 10.2 22.9 BDL
Max. 60.9 19.2 13.9 25.1 -Min. 50.6 11.9 9.3 14.9 -
Average 55.8 16.3 11.4 21.6 -98th Percentile 60.9 19.1 13.7 25.0 -
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PHOTOGRAPHS SHWOING AAQ MONITORING
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3.4.1.3. SAMPLE ANALYSIS
Monitoring and testing of ambient air quality were carried out for various parameters namely PM10,PM2.5, SO2 and NOx by using Respirable Dust Sampler (RDS). Twenty four-hourly samples were collected for PM10 ,PM2.5 and for SO2 & NOx 8 hourly samples were collected for the month of March – April – May -2019.
The sampling and testing of Ambient Air Quality Parameters were carried out as per relevant parts of IS: 5182. The brief details of testing procedures adopted are given in Table No.3.8.
TABLE NO. 3.8
DETAILS OF AMBIENT AIR QUALITY MONITORING & ANALYSIS PROCEDURES
Parameter Ambient Air Quality Monitoring & Analysis Procedure
PM10 Gravimatric Method, IS:5182, 11255 & Operational Manual of Instrument
PM2.5 Gravimatric Method & Operational Manual of InstrumentNOx Jacob & Hochheiser Method.
Absorption in dilute NaOH and then estimating colorimetric with Sulphanilamide N(1-Nepthyl) Ethylene Diamine Dihydrochloride and Hydrogen Peroxide (IS : 5182 Part II : 1975)
SO2 Improved West & Gaeke Method.Absorption in Mercury Sodium Tetra Chloride followed by colorimetric estimation using P-Rosaniline Hydrochloride and Formaldehyde(IS : 5182 Part II : 1969)
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3.5. METEOROLOGY
Meteorological conditions, of the site, regulates the transport and diffusion of air-pollutants released into the atmosphere. Ambient temperature, wind speed, wind direction and atmospheric stability are called primary or basic Meteorological Parameters because the dispersion and diffusion of pollutants depend mainly on these Parameters. Humidity, precipitation, pressure and visibility are secondary Meteorological Parameters as this control the dispersion of the pollutants indirectly by affecting primary Parameters.
3.6. BASELINE DATA
Meteorological data were obtained from our own meteorological station kept at project site.for the parameters namely ambient temperature, wind speed, wind direction, relative humidity for the period March, April and May 2019. The Wind Rose diagram for the month of March, April and May 2019 is shown in FIGURE NO. 3.4.
3.6.1. Ambient Temperature
The monthly variations of monthly highest and monthly lowest temperatures recorded are as follows:
Location –Project site Temperature, oCMarch 2019 April 2019 May 2019
Maximum 37.10 40.20 40.90Minimum 18.40 22.90 26.50
3.6.2. Wind Speed
Wind speed determines the rate of diffusion and travel time of air pollutants. The results of monitoring are as follows:
Location –Project Site Wind Velocity, Km/hrMarch 2019 April 2019 May 2019
Maximum 10.1 7.80 33.3Minimum Calm Calm Calm
3.6.3. Wind Direction
This is important in air pollution since it determines the direction of transport of air pollutants. The mean wind direction will be indicative of the direction of travel of the pollutants.
The meteorological parameters namely: ambient temperature, wind speed, wind direction and stability class were obtained from our own meteorological station kept at Project Site for the Period of March – April – May - 2019.As specific mixing heights were not available, mixing height based on CPCB publication “Spatial Distribution of Hourly Mixing Depth over Indian Region”, PROBES/88/2002-03 has been used.
The windrose diagram is shown in Figure No. 3.4
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FIGURE NO. 3.4
WINDROSE DIAGRAM FOR THE MONTH OF March– April – May 2019
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TABLE NO.3.9WIND ROSE (FREQUENCY DISTRIBUTION DATA)
Directions / Wind Classes (m/s)
Wind Speed (m/s)0.50 -2.10
2.10 - 3.60 3.60 - 5.70 5.70 -8.80
8.80 -11.10
>= 11.1 Total
348.75 - 11.25 52 40 4 0 0 0 9611.25 - 33.75 52 40 4 0 0 0 9633.75 - 56.25 19 16 2 0 0 0 3756.25 - 78.75 14 10 0 0 0 0 2478.75 - 101.25 16 11 3 0 0 0 30101.25 - 123.75 79 12 2 0 0 0 93123.75 - 146.25 121 13 5 0 0 0 139146.25 - 168.75 50 1 0 0 0 0 51168.75 - 191.25 42 11 0 0 0 0 53191.25 - 213.75 86 137 49 5 0 0 277213.75 - 236.25 187 286 142 8 0 0 623236.25 - 258.75 99 122 19 2 0 0 242258.75 - 281.25 115 70 7 1 0 0 193281.25 - 303.75 34 12 0 1 0 0 47303.75 - 326.25 25 34 4 0 0 0 63326.25 - 348.75 50 43 4 0 0 0 97
Sub-Total 1041 858 245 17 0 0 2161Calms 46
Missing/Incomplete 1Total 2208
3.6.4. Relative Humidiy (RH)
Mean Monthly Relative Humidity for Meteorological station kept at project site. is given in Table No.3.10
TABLE NO.3.10RELATIVE HUMIDITY
Month Relative Humidity ( % )Minimum Maximum
March 2019 2.4 61.5April 2019 2.0 75.5May 2019 6.3 93.0
3.6.5. Rain FallTABLE NO.3.11
RAINFALL PATTERN AT VADODARA RAIN GAUGE STATIONYears Rainfall (mm)
2013 8392014 9172015 4832016 8552017 1183
Average 856
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3.6.6. Mixing Height
As specific mixing heights were not available, mixing height based on CPCB publication “SPATIAL DISTRIBUTION OF HOURLY MIXING DEPTH OVER INDIAN REGION”, PROBES/88/2002-03 has been tabulated in Table No.3.12.
TABLE NO.3.12HOURLY MIXING DEPTH OVER INDIAN REGION
Hour of the Day Mixing Height(mts.)
5 506 507 1008 4009 50010 50011 100012 100013 100014 100015 100016 100017 100018 50019 500
3.7. ATMOSPHERIC STABILITY
The hourly occurrence of various stability classes at project site is determined by wind direction fluctuation method by employing on-line instrument.
The stability classification system based on wind direction fluctuation method is as follows.
Relationship between and stability class as suggested by Slade (1965) is given in Table No.3.13
TABLE NO. 3.13STABILITY CLASSIFICATION
Stability Class (degrees)A > 22.5B 22.4 - 17.5C 17.4 - 12.5D 12.4 - 7.5E 7.4 - 3.5F < 3.5
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3.8. NOISE ENVIRONMENT
Noise, often defined as unwanted sound, interferes with speech communication, causes annoyance, distracts from work and disturbs sleep thus deteriorating quality of human environment.
The noise is generated from multiple sources such as medium and heavy industries, urban activities in the commercial and human settlements, and vehicular traffic in the region.
The noise level in the study area has been measured through Leutron sound level meter for a period of one day for 30 minutes interwal at each monitoring station.
In the study area noise levels were monitored in eight locations at different locations for day and night time and are given Table No.3.14
TABLE NO.3.14MAXIMUM AMBIENT NOISE LEVELS WITHIN STUDYAREA
Sr.No
Name of the Location
Categoryof Area/zone
DayTime in Leq dB (A)
CPCBStandard DayTime
Night Time in Leq dB
(A)
CPCBStandard
Night time1. Project Site Industrial 53.2 75dB(A) 48.1 70dB(A)2. Puniyad Residential 49.4 55dB(A) 43.5 45dB(A)3. Menpur Residential 48.1 55dB(A) 42.3 45dB(A)4. Raman gamdi Residential 47.6 55dB(A) 42.7 45dB(A)5. Kayavarohan Residential 48.7 55dB(A) 43.6 45dB(A)6. Dhanora Residential 49.3 55dB(A) 42.1 45dB(A)
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In order to assess the noise levels in the study area, monitoring was carried out at eight different locations within 10 km radius of the study area. The noise monitoring locations are shown in Figure No. 3.3 and monitoring location mentioned in Table 3.14. Noise levels were recorded and computed for equivalent noise levels for day-equivalent, night-equivalent & day-night equivalent.
Sound Pressure Levels (SPL) measurements were recorded at eight locations. The readings were taken for every hour for 24-hrs. The day noise levels have been monitored during 6 am to 10 pm and night noise levels during 10 pm to 6 am at all the locations covered in the study area.
Day time Noise Levels (Lday)
The day time noise level were between 44-60 dB(A), which is well below the permissible limit.
Night time Noise Levels (Lnight)
Industrial Zone:The night time noise level in the Project site was observed between 38-51dB(A), which is well below the permissible limits).
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TABLE NO.3.15
AMBIENT NOISE ANALYSIS IN THE STUDY AREA
Name & Address of Client :
ENTECH LABORATORIES.33,34, Kushal Estate, Saket Industrial Estate, Village: Moraiya, Ta: Sanand, Dist: Ahmedabad, Gujarat.
Name of Project :EIA Study for M/S Kemz Resibond Private Limited. Survey No.: 84/1, 84/2, Village: Fofadiya, Tal: Dabhoi, dist: Vadodara-391210
Description Of Sample : Ambient Noise Sample Done By: Entech TeamDate of Sampling : As Mention Below Sample Duration: 24 HoursReference Method: IS 9989: 2016Details of Sampling : -
Sr.No
Date ofSampling Location Category
Noise Level, dB(A)Day Time Night Time
Recorded level dB (A)
Leq
Limits in
dB(A)
Recorded level dB(A)
Leq
Limits in
dB(A)
1 04/03/2019 Project Site(N1) Industrial 53.2 75 48.1 65
2 07/03/2019 Puniyad (N2) Residential 49.4 55 43.5 45
3 12/03/2019 Menpur (N3) Residential 48.1 55 42.3 45
4 15/03/2019 Raman Gamdi(N4) Residential 47.6 55 42.7 45
5 20/03/2019Kayavarohan
(N5)Residential
48.7 55 43.6 45
6 23/03/2019 Dhanora (N6) Residential 49.3 55 42.1 45
Sample Code
Sampling Location Date Time
Noise Level in dBA10 m from
Edge of The Road
20 m From Edge of The Road
TN1 Nr. Highway 19-03-2019Day 78.6 73.2
Night 72.1 68.4
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3.9. WATER QUALITY
Water is the most vital resource for all kinds of life. It should not only be available in sufficient quantity but should be of good quality as well. Defilement of water, as a result of human activities, industrial activities and consequent pollution of water, cause deterioration of the water environment.
3.9.1 BASELINE DATA COLLECTION OF GROUND WATER & SURFACE WATER
Physico-chemical Parameters have been used for assessing the base line quality of ground water environment and identification of impacts due to the proposed project.
Methodology for Water Quality Monitoring
The Samples, under all categories, were analysed for various Parameters specified by the Department of Environment. For the collection, preservation and analysis, APHA/IS methods were followed. The requisite Procedures, laid down in APHA/IS methods, were adopted for preserving the Samples with suitable preservative chemicals. The Samples were analysed within the time limits prescribed for each Parameter.
Ground water sources covering 10-km radial distance were examined for physico-chemical, heavy metals and bacteriological parameters in order to assess the effect of industrial and other activities on ground water and surface water. The samples were analyzed as per the procedures specified in 'Standard Methods for the Examination of Water and Wastewater' published by American Public Health Association (APHA).
Samples for chemical analysis were collected in polyethylene carboys. Samples for bacteriological analysis were collected in sterilized glass bottles. Selected physicochemical and bacteriological parameters have been analyzed for projecting the existing water quality status in the study area. Parameters like pH and temperature were analyzed at the time of sample collection.
The details of ground water sampling locations are given in Table No. 3.16 and sampling locations of ground water quality monitoring are shown in Figure 3.3. The physico - chemical characteristics of the ground water samples are presented in the Table No. 3.17.
The monitoring has been done at eight sampling stations located in different directions andsituated within the suspected impact zone in and around the project site.
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TABLE NO. 3.16
LOCATIONS OF WATER QUALITY MONITORING STATIONS
Sr. No.
Type of sample Water sample location
1 Ground Water Project Site2 Ground Water Puniyad3 Ground Water Menpur4 Ground Water Raman gamdi5 Ground Water Kayavarohan6 Ground Water Dhanora7 Ground Water Karjan8 Ground Water Gandhar9 Surface Water Kayavarohan Lake
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TABLE NO.3.17WATER QUALITY ANALYSIS REPORTS
Name & Address of Client :
ENTECH LABORATORIES.33,34, Kushal Estate, Saket Industrial Estate, Village: Moraiya, Ta: Sanand, Dist: Ahmedabad, Gujarat.
Name of Project : EIA Study for M/S. Kemz Resibond Private Limited.Survey No.: 84/1, 84/2, Village: Fofadiya,Tal: Dabhoi, Dist: Vadodara-391210
Monitoring done by: Entech Team Sample Packing/Seal: Satisfactory.Mode of Sampling: Grab Sampling Quantity of Sample: 5 ltr In Plastic CarboyType of Sample: Water SampleDetails of Sample:
Sample Code Description of Sample Date of
SamplingDate of Sample
ReceiptAnalysis
Start DateAnalysis End
DateGW1 Ground Water Of Project Site 25/05/2019 26/05/2019 27/05/2019 03/06/2019GW2 Ground Water Of Puniyad 25/05/2019 26/05/2019 27/05/2019 03/06/2019GW3 Ground Water Of Menpur 25/05/2019 26/05/2019 27/05/2019 03/06/2019GW4 Ground Water Of Raman
Gamdi25/05/2019 26/05/2019 27/05/2019 03/06/2019
Sr.No. Parameters Unit GW1 GW2 GW3 GW4
1. pH - 7.3 8.0 7.9 7.72. Temperature °C 25.4 25.3 25.2 25.83. Turbidity NTU 2.0 2.0 2.1 2.24. Total Solid (TS) mg/L 1414 934 1014 3775. Total Suspended Solids (TSS) mg/L 20 12 8.0 7.06. Total Dissolved Solids (TDS) mg/L 1394 922 1006 3707. Electrical Conductivity (EC) µmhos/cm 2706 1889 2010 7638. Dissolved Oxygen (DO) mg/L 5.3 5.2 5.1 5.49. Total Hardness (as CaCO3) mg/L 240 246 250 89
10. Calcium Hardness mg/L 170 168 179 6811. Magnesium Hardness mg/L 70 78 71 2112. Total Alkalinity ( as CaCO3) mg/L 282 281 275 7213. Calcium (as Ca) mg/L 68 67 71 2714. Magnesium (as Mg) mg/L 17 18 18 5.815. Chloride (as Cl) mg/L 328 256 269 9316. Sulphate (as SO4) mg/L 266 235 226 31
17. Chemical Oxygen Demand (COD) mg/L 18 12 18 8
18. Biological Oxygen Demand (BOD) mg/L 6.0 5.0 6.0 BDL
19. Fluoride as F mg/L 0.52 0.38 0.48 0.2320. Colour Hazen Colorless Colorless Colorless Colorless21. Odor -- Odorless Odorless Odorless Odorless22. Taste -- Agreeable Agreeable Agreeable Agreeable23. Sodium as Na mg/L 120 110 120 4824. Potassium as K mg/L 3.2 3.3 3.0 1.225. Iron as Fe mg/L N.D. N.D. N.D. N.D.26. Copper as Cu mg/L N.D. N.D. N.D. N.D.
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Name & Address of Client :
ENTECH LABORATORIES.33,34, Kushal Estate, Saket Industrial Estate, Village: Moraiya, Ta: Sanand, Dist: Ahmedabad, Gujarat.
Name of Project : EIA Study for M/S. Kemz Resibond Private Limited.Survey No.: 84/1, 84/2, Village: Fofadiya,Tal: Dabhoi, Dist: Vadodara-391210.
Monitoring done by: Entech Team Sample Packing/Seal: Satisfactory.Mode of Sampling: Grab Sampling Quantity of Sample: 5 ltr In Plastic CarboyType of Sample: Water SampleDetails of Sample:
Sample Code Description of Sample Date of
SamplingDate of Sample
ReceiptAnalysis
Start DateAnalysis End
DateGW5 Ground Water Of
Kayavarohan25/05/2019 26/05/2019 27/05/2019 03/06/2019
GW6 Ground Water Of Dhanora 25/05/2019 26/05/2019 27/05/2019 03/06/2019GW7 Ground Water Of Karjan 25/05/2019 26/05/2019 27/05/2019 03/06/2019GW8 Ground Water Of Gandhra 25/05/2019 26/05/2019 27/05/2019 03/06/2019
Sr.No. Parameters Unit GW5 GW6 GW7 GW8
1. pH - 8.0 7.5 7.7 7.72. Temperature °C 25.4 25.5 25.3 25.53. Turbidity NTU BDL BDL 2.0 BDL4. Total Solid (TS) mg/L 736 2445 2212 7665. Total Suspended Solids (TSS) mg/L BDL 25 18 BDL6. Total Dissolved Solids (TDS) mg/L 736 2420 2194 7667. Electrical Conductivity (EC) µmhos/cm 1437 2624 3835 15768. Dissolved Oxygen (DO) mg/L 5.0 4.9 5.1 5.09. Total Hardness (as CaCO3) mg/L 115 335 294 12510. Calcium Hardness mg/L 77 168 149 8011. Magnesium Hardness mg/L 38 167 145 4512. Total Alkalinity ( as CaCO3) mg/L 98 286 264 9813. Calcium (as Ca) mg/L 30 90 59 3214. Magnesium (as Mg) mg/L 9.2 96 35 1015. Chloride (as Cl) mg/L 289 823 712 26216. Sulphate (as SO4) mg/L 156 413 372 160
17. Chemical Oxygen Demand (COD) mg/L 8 20 20 8
18. Biological Oxygen Demand (BOD) mg/L BDL 6.3 86.3 BDL
19. Fluoride as F mg/L 0.35 0.55 0.56 0.4020. Colour Hazen Colorless Colorless Colorless Colorless21. Odor -- Odorless Odorless Odorless Odorless22. Taste -- Agreeable Agreeable Agreeable Agreeable23. Sodium as Na mg/L 86 116 102 8924. Potassium as K mg/L 1.6 3.8 3.1 1.925. Iron as Fe mg/L N.D. N.D. N.D. N.D.26. Copper as Cu mg/L N.D. N.D. N.D. N.D.
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Name & Address of Client :
ENTECH LABORATORIES.33,34, Kushal Estate, Saket Industrial Estate, Village: Moraiya, Ta: Sanand, Dist: Ahmedabad, Gujrat.
Name of Project : EIA Study for M/S. Kemz Resibond Private Limited.Survey No.: 84/1, 84/2, Village: Fofadiya,Tal: Dabhoi, Dist: Vadodara-391210.
Monitoring done by: Entech Team Sample Packing/Seal: Satisfactory.Mode of Sampling: Grab Sampling Quantity of Sample: 5 ltr In Plastic CarboyType of Sample: Water SampleDetails of Sample:
Sample Code Description of Sample Date of
SamplingDate of Sample
ReceiptAnalysis
Start DateAnalysis End
DateSW1 Surface water Of
Kayavarohan Lake20/03/2019 21/03/2019 21/03/2019 28/03/2019
Sr.No. Parameters Unit SW11. pH - 7.92. Temperature °C 28.23. Colour Hazen BDL4. Odor -- Unobjectionable5. Taste - Agreeable6. Turbidity NTU 7.67. Total Solid (TS) mg/L 10388. Total Suspended Solids (TSS) mg/L 629. Total Dissolved Solids (TDS) mg/L 976
10. Electrical Conductivity (EC) µS/cm 178911. Dissolved Oxygen (DO) mg/L 7.612. Biological Oxygen Demand (BOD) mg/L 8.213. Chemical Oxygen Demand (COD) mg/L 24.014. E. Coli MPN / 100 ml 27.115. Total Hardness (as CaCO3) mg/L 14216. Calcium Hardness mg/L 4317. Magnesium Hardness mg/L 9918. Total Alkalinity ( as CaCO3) mg/L 19819. Carbonate mg/L BDL20. Bi-Carbonate mg/L 19621. Sodium (as Na) mg/L 13022. Potassium (as K) mg/L 1923. Magnesium (as Mg) mg/L 39.624. Calcium (as Ca) mg/L 17.225. Chloride (as Cl) mg/L 27926. Sulphates (as SO4) mg/L 36.327. Total Phosphorous (as P) mg/L 12.228. Phosphate (as PO4) mg/L 3.229. Nitrate (as NO3) mg/L 12.230. Nitrite (as NO2) mg/L 1.431. Fluoride (as F) mg/L 0.41
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PHOTOGRAPHS OF WATER SAMPLING
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3.10. LAND ENVIRONMENT
3.10.1 GEOLOGY & HYDROGEOLOGY:
Probable sources of ground water pollution are percolation of treated & untreated effluent; hazardous waste (from storage area/generation source); and spillage of chemicals & fuel. The source of water is ground water hence increase in water demand during expansion will lead to depletion in ground water levels.The study area is a part of flat alluvial plain with an average elevation of 38m from Mean Sea Level of Village: Fofaliya Taluka: Dabhoi District: Vadodara, showing rugged to flat topography.The area is covered by quaternary alluvium which is made up of alternate layers of clay and sand. The alluvium formation is underlain by basalt of Deccan trap of upper Cretaceous to lower Eocene.It is observed that sediments at shallow depths up to 65 to 95 m. In general are uniform in character and composed of medium to fine sand, silt with minor clay lenses.Geohydrologically the area is suitable for the construction of shallow tube wells. The investigation area is characterized by variable groundwater conditions. The groundwater in the multi aquifer system occurs under unconfined to semi-confined conditions. Aquifer upto 75.00 depth is considered to be under unconfined condition.On the basis of survey carried out in the area, it is observed that permeable water bearing zones are expected to occur below a depth of 50m. Static Water level (SWL) in the tube wells varies from 35 to 40 m. b.g.l. Due to the medium scale pumping imposed on the aquifer system in and around the area, water level is more or less stable i.e not declining. At present, the drawdown is about 2.0 – 3.0 m annually. A study was carried out to see the impact on groundwater due to small and short duration pumping after constructing proposed Industry.Drawdown of pumping tube-well is about 1.88m at a pumping rate of 120LPM. Thetotal dissolved salts in ground water around investigated area varies from 950 ppm to 1250ppm.
Due to, for ground water balancing rain Water harvesting structures should be continuous pumping of ground water as well as in the absence of surface water sources and scary rainfallimplemented in the proposed area.
GEOLOGICAL FEATURES OF GUJARAT
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Existing Tube Well of the Study and surrounding area
SrNo.
Location Depth Drilled(m)
SWL(m)
PWL(M.)
Discharge(LPM)
ESP(HP)
TDS(ppm)
1 Nana Fofaliya (Opposite
proposed area)
76 35 37 110 02 1200
2 Kayavaran 86 38 42 350 20 1000
3 Menpura 92 40 44 400 20 950
4 Puniyad 76 37 39 120 02 1250
5 Proposed area tube-well
76 35 39 120 02 1200
Geologically, entire area is covered with recent age deposits of fluvial and marine origin.Major part of the study area is covered with dark alluvial deposits which consist thickness of more than 200 m in the study area.The Narmada and the Mahi are the chief rivers of the district, flow along the north western and southern boundary respectively. The study area is drained by the Narmada river and it's tributaries.Ground water flow is found to be westerly towards river Mahi under confined conditions & so tube wells drilled in north-western or in south-western part, yield more ground water as compared to those drilled in eastern or in South eastern parts of the study area.Underground piping for effluent transfer is avoided as far as possible. Pucca flooring is done in ETP area to avoid any type of leakage that can be percolated into ground water. Hazardous waste is segregated at source and stored in hazardous waste storage area with impervious flooring.Unit will install rain water harvesting system within premises to collect and recharge rainwater. Rain water from proposed construction and paved area shall be recharged.
Source: Water Resources Dept from http://guj-nwrws.gujarat.gov.in/
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TYPE OF SOILS
The soils are medium black soil to deep black soil.in nature. In general the soils are poor to medium in fertility and water retention capacity. Soils are characterized by black to dark black loamy and clay loams of adequate to poor permeability.
pH value is found to be moderately alkaline.Organic Carbon is found to be medium to high which indicates soil of the some area is poor in fertility and some of them are fertile soil. Available potassium is medium to high and available phosphorous is found to be very low to high. Soil is salt-free.During operation activity the impact of air, water and solid & hazardous waste pollution on soil causes direct/ indirect effect on soil.Storage and handling of chemicals and hazardous waste may contaminate the soil. All the necessary control measures are provided for handling, storage and disposal, like designated storage area, leachate collection system etc. Thus, there will not be any significant impact of solid/hazardous waste on the soil environment. The effluent generated from domestic is disposed through soak pit; but soak pit is cleaned regularly to avoid soil pollution.
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3.10.2 CHARACTERISTICS OF SOILS
BASE LINE DATA
The soil samples were collected from different places in the study area. The soil samples are taken from eight villages.
The present study on soil quality establishes the baseline characteristics in the study area surrounding the project site. The study has been addressed with the following objectives.
To determine the baseline characteristicsTo determine the soil characteristics of plant site and surrounding areas with in 10 km radius.To determine the impact of industrialization/Urbanization on soil characteristics.To determine the impacts on soils from agricultural productivity point of view.At each sampling site, the samples were collected at random at a depth of 15 cms and mixed together to form a composite sample. Large stones, gravels and plant roots were removed from soil.
The homogenized soil samples collected at different locations were packed in a polyethylene plastic bag and sealed. The sealed samples were sent to laboratory for analysis. The important physical, chemical parameter concentrations were determined from all samples. The soil was then crushed and water suspension was prepared. The supernatant liquid was then subjected to Physico-Chemical analysis.
Standard Procedures were followed for analysis. The results of soil analysis are tabulated in Table No. 3. 18
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TABLE NO.3.18ANALYSIS RESULTS OF SOIL SAMPLES
Name & Address of Client :
ENTECH LABORATORIES.33,34, Kushal Estate, Saket Industrial Estate, Village: Moraiya, Ta: Sanand, Dist: Ahmedabad, Gujarat.
Name of Project : EIA Study for M/S. Kemz Resibond Private Limited.Survey No.: 84/1, 84/2, village: Fofadiya, Tal: Dabhoi, Dist: Vadodara-391210
Monitoring done by: Entech Team Packing/Seal: Satisfactory.Quantity of Sample: 1Kg In Plastic BagType of Sample: Soil SampleDetails of Sample:
SampleCode Description of Sample Date of Sampling
Date of Sample Receipt
Analysis Start Date
Analysis End Date
S1 Soil Sample Of Project Site
25/05/2019 26/05/2019 27/05/2019 03/06/2019
S2 Soil Sample Of Puniyad 25/05/2019 26/05/2019 27/05/2019 03/06/2019S3 Soil Sample Of Menpur 25/05/2019 26/05/2019 27/05/2019 03/06/2019S4 Soil Sample Of Raman
Gamdi25/05/2019 26/05/2019 27/05/2019 03/06/2019
S5 Soil Sample Of Kayavarohan
25/05/2019 26/05/2019 27/05/2019 03/06/2019
S6 Soil Sample Of Dhanora 25/05/2019 26/05/2019 27/05/2019 03/06/2019S7 Soil Sample Of Karjan 25/05/2019 26/05/2019 27/05/2019 03/06/2019S8 Soil Sample Of Gandhra 25/05/2019 26/05/2019 27/05/2019 03/06/2019
Sr. No. Parameters Unit S1 S2 S3 S4 S5 S6 S7 S8
1. Particle size Distribution
Qualitative
a. Sand 42 41.0 43.0 42 50 46 47.0 49b. Silt 20 31.0 25.6 21.0 30 21 25.0 24.8c. Clay 32 29 28 29 36 30 28 34
2. Texture Clay Sand Clay
Sandy Clay
Clay Loam
Sandy Clay
Sandy Clay Clay Clay
3. Porosity % 30 33 31 32 44 39 30 42
4. Water holding capacity % 53 49 44 46 40 47 45 50
5. Organic carbon (OC) % 1.1 1.3 0.9 1.2 1.0 1.2 0.9 1.0
6. Calcium as Ca mg/kg 35 28 25 29 41 26 30 327. Magnesium as Mg mg/kg 14 13 14 08 18 11 19 188. Sodium as Na mg/kg 45 43 33 31 40 28 23 24
9. Cat ion Exchange Capacity
meq/100g 36 28 30 35 31 22 28 30
10. Electrical Conductivity µS/cm 164 86 118 132 123 98 112 120
11. Available Nitrogen mg/kg 49 43 38 36 47 39 38 48
12. Available Potassium mg/kg 36 30 29 29 36 29 28 36
13. Available Phosphorus mg/kg 8.7 7.6 5.8 6.9 8.1 7.4 6.6 6.3
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PHOTOGRAPHS OF SOIL SAMPLING
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Analysis of the samples collected show that:
Porosity of soil samples were in the range of 32% (Project Site) to 46% (Kayavarohan Village) and Water Holding Capacity (WHC) of Soil samples were in the range of 40% (Kayavarohan Village) to 53% (Project Site).
Cation Exchange Capacity (CEC) of Soil samples were in range of 28meq/100gm (DhanoraVillage) to 36meq/100gm (Kayavarohan Village)
Electrical Conductivity of Soil samples were in range of 54dS/m (Karjan Village) to 164dS/m (Kayavarohan).
Percentage of total Organic Carbon is observed in between 0.8 to 1.0 indicating that On an avg. sufficient in nature.
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3.11 LAND USE PATTERN
Remote Sensing is a process of identification and demarcation of various earths’ objects from a distance without directly coming into contact with them. Remote sensing is largely concerned with the measurement of electromagnetic radiation from the sun, which is reflected, scattered, and emitted by the objects on the surface of the earth. Different objects on the surface of the earth reflect different amounts of the electromagnetic spectrum. The potential of remote sensing in natural resources mapping basically depends on spatial, radiometric and temporal resolution of the sensor. Thus the satellite remote sensing with its capability of repetitive coverage, multi-spectral imaging, synoptic view and low cost can play an important role in the delineation of various landuse landcover classes.
The Study Area up to 10 kms radius from the proposed project Site is considered. The locations is shown in Figure No. 3.1.
The important land uses, as classified by the Census Records, are the Grass land, Crop land, Fallow land, scrub land, barren land, trees, waterbody, settlements and industrial area.
Landuse and landcover distribution in the study area has been estimated using the satellite imagery of generated from Landsat ETM+ scene of October 2006 (Refer: Figure 3.7). The landuse and landcover pattern of the study area (10 km radial zone) has been studied by the same. The land use distribution in the study area (10 km radial zone) is presented in Table 3.19.
Table 3.19:
Land Use Distribution in Study Area (10 km Radial Zone)
Land Use/Land Cover Area sq km %Grass Land 42.08 13.39Crop Land 154.97 49.33
Fallow Land 43.94 13.99Scrub Land 23.90 7.61Barren Land 5.80 1.85
Trees 28.08 8.94Waterbody 1.51 0.48Settlement 12.37 3.94Industry 1.52 0.48
Total 314.16 100
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FIGURE NO. 3.5LAND USE / LAND COVER MAP OF 10 KM RADIUS AREA AROUND
PROJECT SITE
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3.12 HYDROLOGY
Ground water occurs in alluvium formation. Though ground water occurs in all types of formation but most productive aquifer is quaternary sediments (alluvium). The main aquifer are alluvium and blown sand ones. Alluvium is an important formation with regards to the development of ground water in view of occurrence of highly permeable granular beds. Ground water occurs under both unconfined and confined conditions. The yield of the tube well varies from 120 lpm to 400 lpm.
The unconfined aquifer occurs in the upper horizons down to a maximum depth of 95mtr consisting of medium to coarse grained sand. The thickness of aquifer varies between 24m and 36m in general.
Geo-hydrologically study area is a part of Village: Fofaliya, Taluka: Dabhoi, District: Vadodara is suitable for the construction of shallow tube-well and recharge wells for artificial recharge/rain water harvesting structure. Construction of rain water harvesting structure will be helpful to maintain the Static Water level.
Level of groundwater development
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Vulnerability of Industrialization & Urbanization
Vulnerability of Salinity Ingress
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The Vadodara district has main three hydrogeological provinces, Aravalli terrains, Deccan trap & associated Cretaceous sediments terrains and Alluvium areas.
Unit has installed rain water harvesting system within premises to collect and recharge rainwater. Rain water from proposed construction and paved area shall be recharged.
The depth to water is greater in upland areas whereas in valley portion and shallow grounds, the levels are very close to surface. In hilly terrain of eastern, north- east and south-east part of the district, spring zones are seen in stream river section; also along the section of the Mahi, the Narmada and the Orsang rivers. The piezometric surface, mainly in alluvium areas of western half the district also follows the gentle gradient corresponding to subsurface configuration of deep aquifer zones.
Inferences drawn from the data collected by the analysis and investigation carried out in the area are listed below.
Geomorphologically, the study area is flat in nature.Geologically, the area is underlain by Quaternary/Tertiary continental sediments alluvium and older formations. These sediments are mainly consisted by coarse Sand, gravel, clay .The occurrence and movement of groundwater is mainly controlled by intergranular pore space.Sub-surface geology of the area shows permeable and fully developed aquifer system.The quaternary aquifers are generally coarse to fine grained Sand with occasional gravel bed.Un-confined to Semi-confined ground Water level in the study area ranges around from 35 to 40 m. The yield of Tube-wells varies from 120 to 400 lpm.The depth of production tube wells in general varies from78 to 90 m. The study area falls under safe category.
RECOMMENDATIONS:-
Based on the geological & geohydrological study the following recommendations are drawn
for augmenting ground water and balancing ground water by means of rain water harvesting
structure.
Existing one tube-well is capable to fulfil present per annum fresh groundwater requirement.
The area is suitable for rain water harvesting by constructing recharge well, water bodies
like ponds, check dams, nalla bund, gully plug in nearby villages.
The aquifer are un-confined to semi-confined/confined having intake capacity of clear water
approximate 4LPS i.e. 14.4 m^3 per hour. One recharge bore-well can store approximate
10368 m^3 clear rain water in 30days.
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Suggested for constructing one recharge tube well having depth 60m to 70m and pipe Dia
200mm.
The available gross rain fall recharge is 5762 m3 which is three times of the Water to be
recharged .
The study area falls under SAFE category as per GWRE report 2009 approved by CGWA
Delhi if the study area lies under safe category as per CGWA guidelines (w.e.f 15/12/2010)
for evaluating of proposal for ground water balance in such areas, ground water
development is permitted only 100% of recharge quantity or recharge to ground water
should be 50% of the ground water pumped through tube-well.
Presently it seems no impact on groundwater level due to small pumping of 5500 liters per
day.
3.13 ECOLOGY
Environmental Impact Assessments is necessary for industrial projects for new, expansion or for modernization activities. Proper assessment of biological environment and compilation of its taxonomical data is essential for the impact prediction.
The climatic, edaphic and biotic variations with their complex interrelationship and composition of the species, which are adapted to these variations, have resulted in different vegetation cover, characteristic of each region. The ecology of the study area is briefly discussed in this subsection. The study is mostly surrounded by the rural area. The land usepattern used to show the major portion covered by irrigated land.
A base line Survey has been carried out to appraise the terrestrial flora and fauna within study areas of 10 km radius around the site of the industry. The study area includes villages as shown in the following table.
3.13.1 PERIOD OF THE STUDY AREA:
The base line study for identification of floral and faunal biodiversity of the terrestrial environment of the study area was conducted in the Month of March, 2019.
3.13.2 METHODOLOGY:
The methodology adopted for the evaluation of biodiversity status of the study region is as given below. The sampling plots for the survey were selected randomly in the suitable habitats within the study area.
Table 3.20: Methodology adopted for the evaluation of biodiversity status of the study region
Plants Tree 10 meter radius circular plot
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Shrubs 10 meter radius circular plotHerbs 1 meter x 1 meter square plot
BirdsTerrestrial Point centered quadrate in 10 meter radius Aquatic Total count & Folk count
HerpetofaunaTerrestrial / Aquatic 10 meter radius circular plot Indirect evidence Survey in the village with the help of pictorial
representation Mammals Direct Count Line transect and Round transect
Indirect evidence Surveys in the villages with the help of pictorial representation
3.13.3 TOPOGRAPHY OF THE STUDY AREA:
Topography of the region was characterized by fields. Most of the land were planted with different plants and for agriculture as well as utilized for industries. No natural forest area was observed in the study area. (Please refer Figure: 3.6 Land use pattern showing the Project site and surrounding area)
3.13.4 FLORAL DIVERSITY:
The trees, herbs, shrubs and major crops, observed during the biological survey conducted within study area. During study 88 flora observed belongs to 48 Family are enumerated from the study area. Wheat (Triticum aestivum L.), cotton (Gossypium arboreum L.) & Castor (Ricinus communis L.) etc. mainly crops found in the study area.Among the enumerated flora in the study area, no rare and endangered flora was observed
The agriculture is major land use of the study area. During the study period (March, 2019), the cultivable lands of different area were observed with different crops.
Table 3.21: FLORA IN THE STUDY AREA
Scientific Name Family Local nameRanunculus sceleratus L. Ranunculaceae JaldhanaNymphea stellata Wild. Nympheaceae Lal poynaNymphoides peltatum
Nelumbo nucifera Gaertn. Nelumbonaceae Vado Kamalful
Polygala erioptera DC. Polygalaceae PatsanPortulaca olearacea L. Portulacaceae Moti LuniPortulaca quadrifida L. Zini Luni
Polycarpaea corymbosa (L.) Lam.Caryophyllaceae
Jangli soaSpergula arvensis L. Corn spurrey
Bergia odorata Edgew. Elatinaceae OkhradCorchorus aestuans L. Tiliaceae ChunchCorchorus olitorius L. ChunchOxalis corniculata L. Oxalidaceae ChangeriTribulus terrestris L. Zygophyllaceae Bethu Gokhru
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Cayratia carnosa (Lam.) Gagnep. Vitaceae Kath katumboCissus quadrangularie L. Hadsakal
Alyscirpus monilifer (L.) DC.Fabaceae
JhuhighasDesmodium triflorum L. Zino Pandadio
Sesbania bispinosa Jacq)W.F.Wight IkadAmmannia baccifera L. Lythraceae Agio
Ammannia multiflora Roxb. Zino agioLudwigia parviflora Roxb. Onagraceae Panlavang
Trapa bi-spinosa Roxb. TrapaceaeGlinus lotoides L.
MolluginaceaeMitho okhrad
Mollugo pentaphylla L. JhrasOldenlandia corymbosa L. Rubiaceae Parpat
Borreria aricularis L. GanthiyuAcanthospermum hispidum DC.
Astreceae
Zinku gadriyou
Amberboa ramosa (Roxb.) Jeffry. MankadmariAgeratum conzoides L. Dholi sadodi
Echinops echinatus Roxb. Ut kantoEclipta prostrata (L.) L. Manf. Jal bhangro
Grangea mederaspatana (L) Poir. ZinkimundiLaunaea procumbens (Roxb.) Ramayya Moti
bhoypattriParthenium hysterosporus L. Gajargas
Dyerophytum indicum (Gib. Ex Wt.) O. Plumbaginaceae Rato chitrakPlumbago zeylanica L. ChitrakAnagallis arvensis L.
Primulaceae
Khet fuliLeptadenia reticulata (Retz.) W & A. Dodi
Pergularia daemia (Forsk.) Chiov. Chamar dudhali
Enicostema littorale Bl. Gentianaceae MamejvoConscora diffusa (Vahl.) R. Zinkukariatu
Coldenia procumbens L. Boraginaceae OkhradHeliotropium indicum L. Hathi sundha
Convorvulus microphyllus (Roth.)Sieb.ex.Spr. Convolvulaceae
Sankhavali
Evolvulus alsinoides L. Kali sankhavoli
Datura innoxa Mill. Solanaceae Kalo dhanturoBacopa monnieri (L) Pennell.
Scrophulariaceae
JalnaveriBonaya veronicaefolia Spr. Parpati
Kixia ramossisima (Wall.) Janch. Bhit gilodiLindergia urticaefolia Lehm. Bhit chattiOrobanche aegyptica Pers. Orobanchaceae VakubmbhoAndrographis ehioides L. Acanthaceae Kariyatu
Andrographis paniculata Wall. Lilu kariyatuPhyla nodiflora (L) Greene. Verbenaceae Rathvelio
Anisomeles indica (L) O. Ktze. Lamiaceae Chodharo
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Leucas cephalotes (Roxb. Ex Roth.) Spr. KuboOcimum gratissimum L. Avchi bavchi
Ocimum sanctum L. TulsiBoerhavia diffusa L.
NyctaginaceaeSatodi
Polygonum glabrum Willd. ShrrulPolygonum plebeium R. Br. Zinko okhrad
Acalypha indica L. Euphorbiaceae KappiHydrilla verticillata (L.f.) Royal. Hydrocharitaceae Kureli
Ceretophyllam demersum L. CeretophyllaceaeEichhornia crassipes Mart.
PontederiaceaeVallisnaria spirallis L. JalsarpolianAsparagus recemosus Willd. Liliaceae SatavariAsphodelus tenuifolius Cav. DungaroCommelina benghalensis L. Commelinaceae Motu
sismuliyuLemna verticellata Hegelm. Lemnaceae
Thypha angustata Bory. Thyphaceae Gha bajariuSegittaria segitifolia L. Alismataceae -
Potamogeton nodosus Poir. Potamogetonaceae -Eriocaulon sp. Ericulaceae -
Cyperus difformis L. Cent.
Cyperaceae
ChiyoCyperus rotundus L.Scirpus ciliaris L. -
Scirpus littoralis Auct. -Apluda mutica L.
PoaceaeBhangoru
Aristida adscensionis L. LapduAristida funiculate Trin. & Rupr. Laso lampdo
Cajanus cajan (L.) Millsp. Leguminosae TuvarTriticum aestivum L. Poaceae Wheat
Gossypium herbaceum L. Malvaceae KapaasRicinus communis L. Euphorbiaceae CastorFicus benghalensis Moraceae vad
Fauna:
During the survey, a total of 67 species belonging to 41 families were noted in the study area. Most of the species are of common occurrence. List of fauna observed during study period are given in Table 3.21.
Table 3.21: FAUNA IN THE STUDY AREA
Scientific Name Family Local nameAnas clypeata Anatidae Northern Shoveler
Anas poecilorhyncha Spot billed duckAnas querquedula GarganeyArdea purpurea Ardeidae Purple heronArdeolagrayii Pond heron
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Egrettagarzetta Little egretMesophoyxintermedia Median Egret
Elanuscaeruleus Accipitridae Black winged kiteMilvusmigrans Black kite
Pernis ptilorhyncus Oriental Honey Buzzard
Acridium sp. Tetrigidae Pigmy locustDelias eucharis Pieridae Common JezebelColotis amata Small Salmon Arab
Belenois aurota PioneerMycterialeucocephala Ciconiidae Painted StorkOrthotomussutorius Cisticolidae Tailor bird
Priniasocialis Ashy priniaColumba livia
Columbidae
Blue rock pigeonStreptopeliadecaocto Eurasian Collard
DoveSpilopeliasenegalensis Laughing Dove
Streptopeliatranquebari ca Red Turtle-doveCentropussinensis Cuculidae Crow- pheasant
Eudynamysscolopaceus Indian koelCorvus macrorhynchos Corvidae Jungle Crow
Corvussplendens Common crowLonchuramalabarica Estrildidae Indian silverbilDicrurus macrocercus Discruidae Black drongo
Turdoidesstriatus Leiothrichidae Jungle babblerHirundosmithii Hirundinidae Wire tailed
SwallowMeropsorientalis Meropidae Green bee- eater
Nectarinia asiatica Nectariniidae Purple sunbirdFrancolinus pondicerianus Phasianidae Grey francolin
Tachybaptus ruficollis Podicipedidae Little GrebePycnonotuscafer Pycnonotidae Red vented bulbul
Pycnonotus leucotis White-eared bulbulActitishypoleucos Scolopacidae Common sandpiper
Tringa glareola Wood SandpiperAcridotheresginginianus Sturnidae Bank myna
Acridotherestristis Common mynaSturnuspagodarum Brahminy StarlingPseudibispapillosa Threskiornithidae Red-naped Ibis
Threskiornismelanoceph alus Oriental White IbisConocephalus sp. Tettigoniidae GrasshopperBelenois aurota Pieridae PioneerDelias eucharis Common Jezebel
Catopsilia pomona Common emigrantDanauschrysippus Nymphalidae Plain tigerMuscadomestica Muscidae House fly
Catochrysops strabo Lycaenidae Forget-me-not
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Prosotas dubiosa Tailless LineblueOrthetrum sp. Libellulidae Skimmer dragonfly
Gryllusbimaculatus Gryllidae Field cricketGryllusdomecticus House cricket
Camponotuscompressus Formicidae Black antOecophyllasmaragdina Red ant
Anopheles sp. Culicidae MosquitoApisdorsata Apidae Honey beeApisflorea Honey bee
Boselaphustragocamelus Bovidae Blue bullSimia entellus Cercopithecidae Hanuman Langur
Felischaus Felidae Jungle catHerpestesedwardsi Herpestidae Common
mongooseCalotesversicolar Agamidae Garden lizard
Ptyas mucosa Colubridae Indian Rat SnakeNajanaja Elapidae Common cobra
Lissemyspunctata Trionychidae Indian Flapshell Turtle
Varanusbengalensis Varanidae Common Indian Monitor Lizard
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3.14 SOCIO-ECONOMIC ENVIRONMENT
Existing baseline status of the socio-economic profile of the study area with
reference to demographic structure, provision of basic amenities, health status
incorporating economic pattern in the nearby rural areas (10 km radius) were
undertaken, it was used in assessing the impact of the project on socio-economic
environment.
Basic infrastructures are available within area like Schools, Colleges, Hospitals &
a community facility even nearby area of the project site is also developed.
Findings of study area based on Census 2011 and field survey:
Total population : 49815
Males: 25908
Females: 23907
Sex ratio : 927
Average literacy rate: 81%
Economical profile of the area depends on Industrial job and agricultural
activities.
Infrastructure facility like roads, transportation, electricity connection, bank, post-
office, school etc available in village.
Education facility like anganwadi and primary school available in village and for
further education facility getting from Kayavarohan and Karjan.
Main source of the drinking water is bore well and some villages are having
Narmada canal as water source and ground water as a domestic purpose uses.
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3.15 Traffic Survey
To determine current traffic volumes on the road, the traffic studies have been accomplished. This study gives an idea about expected future traffic volumes as a part of overall impact assessment forthe project. The traffic densities may vary based on working days and time, and also may vary in day and night times. This survey was conducted during normal working day to get details of traffic density. NH-48 is 2.86 km from project site, hence traffic density study was conducted at said location. The vehicles moving in both the directions were counted continuously for 24 hours at one location. The vehicles were counted every hour and recorded under respective category. The maximum traffic count in an hour is termed as peak hour traffic. The vehicles were categorized under various heads like heavy motor vehicles such as buses, trucks and tankers, light motor vehicles (cars, jeeps), three wheelers (auto rickshaws, tempo etc.) two wheelers (scooters, motor cycles) etc. The summary of daily traffic density in terms of PCU for the locations were monitored during the study period is summarized below. It was observed that the cars/jeeps and trucks/buses forms the major volume of the traffic. The overall total traffic PCU of this road is minimal. The present level of traffic in terms of Passenger Car Units (PCU) at these locations as per the conversion factors stipulated by Indian Road Congress (IRC) is presented below:
Table 3.23: Traffic Counts
Type of Vehicles
Peak hr. traffic on NH-48 Near FofadiyaBamangam to Manglej
Manglej to Bamangam
Vehicle Nos. PCU Vehicle Nos. PCUHeavy (Bus, Truck, etc) 165 495 165 496Light (Car, Jeep, Pickup Van etc.) 205 205 203 2033 Wheeler (Rickshaw) 107 107 108 1082 Wheeler (Scooter, motorcycle, cycle etc) 152 76 156 78Total 629 883 632 885
Table: 3.24 Existing Traffic Scenario and Level of Services
Particular Existing Traffic Scenario and Level of ServicesBamangam to Manglej Manglej to Bamangam
Road type 6 lane with dividerCapacity as per IRC 4300 (PCU’s /h)Existing total volume during peak hr (PCU) 883 885Existing volume / capacity ratio 0.2 0.2Level of Service “A” Very Good “A” Very Good
DiscussionThe above traffic reveals the LOS (Levels of Service) as “A” Very Good for the NH-48, which is a 6 lane road with divider. Increase in traffic due to proposed expansion in facility will be taken care by the six lane road.
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CHAPTER 4
ANTICIPATED ENVIRONMENTAL IMPACTS & MITIGATION MEASURES
4.1 INTRODUCTION
Environmental Impact Assessment (EIA) is an activity or an attempt to identify, predict, evaluate and communicate the likely environmental impacts of the proposed project on the surrounding environment.
The major element involved in the process of Environmental Impact Assessment is the Identification of impacts as it forms the basis for quantification and evaluation of impacts. In this section, the impacts on the environment, either beneficial or deleterious due to the proposed project have been identified. The aspects of the environment, which are likely to be disturbed or damaged due to the proposed project, are represented as parameters.
Prediction of impacts is the most important component in the Environmental Impact Assessment studies for quantification and evaluation of impacts. Several scientific techniques and methodologies are available to predict impacts of developmental activities on physical, ecological and socio-economic environments. Such predictions are superimposed over the baseline (pre-project) status of environmental quality to derive the ultimate (post-project) scenario of environmental conditions. The prediction of impacts helps in minimizing the impacts on environmental quality during the post project execution.
The identified impacts for various components of environment viz. air, noise, water, land, socio-economy etc. are presented herewith. EIA is an activity or an attempt to identify, predict, evaluate and communicate the likely environmental impacts of the activity/project on the environment.
ENVIRONMENTAL IMPACT ASSESSMENT STUDY INCLUDES:
Identification of all the probable impacts (be it positive or negative) of the various activities involved in the completion of the project.
Classification of the probable impacts i.e. positive or negative, reversible or irreversible, short term or long term.
Evaluation of the probable impacts i.e. qualitative and quantitative assessment of the likely impacts.
Communication to the general public, interested parties, controlling authorities (Government or Municipality) through a Public Hearing process, revealing all the probable impacts, which are likely to occur due to the Proposed project, on the environment. It also includes the mitigation measures of those impacts, which are inevitable.
This chapter presents the identification, prediction and evaluation of impacts with mitigation measures of the proposed expansion project of M/s. Kemz Resibond Private Limited on the identified parameters in the baseline environmental status.
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4.2 IMPACT IDENTIFICATION
Considering that identification of significant environmental impact is essential in the preparation of EIA report, an attempt has been made here through the use of “Activity Effect” Matrix.
IDENTIFICATION MATRIXThe impact identification matrix is shown in the Table No. 4.1. For simplicity the entire project has been divided into two phases:
1. Construction Phase
2. Operation Phase
Various activities belonging to each phase have been grouped separately and arranged in Columns. The environmental Factor or Parameter, which are anticipated to be impacted, has been arranged in Rows. A preliminary scrutiny has been done and the cells, which fall at the junction of the ‘Activity’ and ‘Factor’, that have possible interaction with each other, have been ‘marked’.
The matrix thus establishes the possible ‘cause-effect’ relationship and identifies the environmental factors likely to be impacted and activities responsible for the same. The impact identified may be positive and negative, short term and long term, reversible and irreversible, minor and major. This determination will be done at prediction stage.
A. Construction Phase
Unit will carry out construction activity for manufacturing area, internal roads, housing colony etc. will be done. The various activities involved in construction phase of a proposed project are listed below:Transportation of construction materials required for modification of existing structure ExcavationMaterial handlingMinor civil construction/Modification of existing civil structure.Erection/Installations of equipment and machineryEmployment of labourGreen belt development
B. Operational Phase
The activities involved in the operation phase of the proposed project are listed below:Raw material handling and StorageProduct Manufacturing Utility ConsumptionProduct Handling & StorageTransportationEffluent GenerationGaseous EmissionsHazardous Waste Generation EmploymentGreen belt development
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4.3 IMPACT PREDICTION AND ASSESSMENT WITH MITIGATIVE MEASURES:
This section is devoted to the prediction and assessment of impacts, which are the most important components of EIA. Such predictions are superimposed over the base-line status of the environmental quality to derive the ultimate environmental scenario.
Prediction involves determination of the nature and extent of the probable impacts due to the proposed Project. Here it is determined, whether the likely environmental impacts are:
1. Positive or Negative2. Long term or Short term
Prediction of impacts during the construction and operational phase is as Shown in Table No 4.2.
Unit will establish full infrastructure for the proposed plant. However, there will be short term negligible impacts during this phase and mitigation measures for the same are proposed as under.
Based on Environmental Impact Analysis, the Environmental Impacts under this step are quantitatively and qualitatively assessed.
Quantitative assessment with the help of a mathematical model has been done wherever possible. In other cases, the impact assessment has been qualitative which is based on available scientific knowledge and judgment.
The mathematical model used for prediction in the present study includes “Aermod view” model for ambient air quality. For other cases i.e. Water, Noise, Land/Soil, Ecology, Socioeconomic etc., the available scientific knowledge and judgments have been used.
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4.4 IMPACT ON AIR ENVIRONMENT
A. Impact during Construction Phase:-
The impacts during construction phase will be short-term impacts as they will be limited to the period of construction.
These activities may result in temporary increase in SPM levels, primarily, in the working environment.
Main Impacts during construction period is dusting and Air Pollution from vehicles.
There will be impact on Air Environment during construction phase and also during operation phase. The impact during construction phase will be short term and reversible.
The main sources of emission during the construction period are the movement of equipment at site and dust emitted during handling, grading, earthwork, and exhaust emissions from vehicles and equipment deployed during the construction phase is also likely to result in marginal increase in the levels of SO2 , NOx, SPM and CO.
B. Mitigation measures during Construction Phase :-
The activities like site development, construction and vehicular traffic contribute to increase in SPM and NOx concentrations. The mitigation measures recommended to minimize the impacts are:
Water sprinkling in construction area. Proper maintenance of vehicles and construction equipment.Proper traffic management to be follow during loading and unloading of construction
material.The heights, from which materials will be dropped, will be the minimum practical height to
limit fugitive dust generation.Tree plantation in the area earmarked for greenbelt development.
Hence, the impacts on ambient air quality during construction phase will be marginal temporarily and reversible in nature (for short duration) and restricted to small plant area only.
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C. Impact during Operational Phase:-
The impacts on air quality from project depend on various factors like design capacity, configuration, process technology, raw material, fuel to be used, air pollution control measures, operation and maintenance. Apart from the above, other activities associated with transportation of fuel, raw materials and finished products, storage facilities and material handling within the plant premises may also contribute to air pollution.
1. Source of Air Pollution
The operational phase activities are expected to have long - term impacts on the air quality. The main sources from project are Flue gas emission, Process gas emission, Fugitive emission etc.
i. Flue gas Emissions
Thermic Fluid Heater will be the main sources of emissions from the Plant. The unit is going to use LDO as a fuel in TFH.
Further, it may be noted that the impacts due to utility operations would be negligible as the LDO will be used as fuel.
PM, SO2 and NOx are the main air pollutants generated from the TFH. The emissions TFH Stack is given in Table No. 4.3.
For control of flue gas emissions below permissible limit, the unit will provide adequate stack height.
Based on the above stated facts, predictions related to the Ground Level Concentrations (GLCs) have taken into account the flue gas emissions from the proposed flue gas stack.
ii. Process/Fugitive Emissions
Reactors & Blenders will be the minor source of process emission from the plant. VOCs are the air pollutants generated from the blender during loading of material and for the same scrubber will be provided.
Scrubber will be provide with the reactors & blenders to control of VOCs.
Fugitive emission details with its mitigation measures:Entire process will be carried out in the closed reactors with proper maintenance of
pressure and temperature. No any type of major process gas emission from proposed unit. In proposed resin manufacturing process, First the raw materials will be mixed in the closed reactor vessel. Once the desired parameters will be achieved, the product will be cooled and transferred to blender with very slow rate. In blender equipped with water jacket, unit willmaintain temperature less than 70°C means below the vaporization point of Styrene Monomer / Xylene. However, unit has proposed to provide the scrubber with blender due to any rarely circumstances if acid fumes will generate.
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TABLE NO.4.3BASIS OF EMISSION RATE CULATIONS
Sr.No.
Stack attached to
Type of Fuel
Dia.(m)
Height (m)
Exit Temp. ( C)
Exit Velocity (m/sec)
Emission Rates (gm/s)PM
(*)SO2(**)
NOX(***)
1 Thermic Fluid Heater
LDO 0.3 12 160 8.0 0.058 0.110 0.037
2 D G Set- 1 (500 kVA)
HSD 0.15 6 210 6.0 0.010 0.018 0.006
Note: (*) Based on maximum expected concentration of PM-150 mg/Nm3in Flue gas stack
(**) Based on maximum expected concentration of SO2-100 ppm in Flue gas stack
(***) Based on maximum expected concentration of NOx-50 ppm in Flue gas stack
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iii. Prediction of Impacts on Air Environment
The concentration of pollutants at the ground level has been computed using computer model viz. AERMOD to assess the impact of source emissions from the proposed stack which will be installed. Mathematical modeling is an established and accepted technique to predict the air quality.
In this study, impact on environment due to the proposed plant has been assessed with the help of Mathematical modeling following the Central Pollution Control Boards Guidelines. The mathematical model used for conducting the study is the latest version of AERMOD developed by the Lakes Environmental Software, which is entirely in line with the requirements of Central Pollution Control Board, New Delhi.
A mathematical model developed by the Environmental Protection Agency (EPA) is used for calculating GLCs. This is based, on the original Gaussian Plume Model equation but is defined in terms related to atmospheric phenomenon. The average and maximum Ground Level Concentrations (GLCs) have been determined for SPM, SO2 ,and NOx, . The average 24hrs. concentrations have been determined in polar grid of 100 up to 3600 for a distance of 500m, 1000m, 2000m, 2500m, 3000m, 3100 m, 3400m, 4000m, 5000m, 7500m, and 10000 m. has been calculated based on the micro-meteorological data collected from the meteorological station kept at the project site of M/s. Kemz Resibond Private Limited
Methodology :
Prediction of GLC values are made by using AERMOD software approved by U.S. Environmental Protection Agency (USEPA) and has adopted it as its regulatory model since 2005. In point source emissions, the stacks are subjected to plume rise which again is dependent on force of buoyancy and momentum. The higher is the plume rise or stack, the lesser will be ground level concentrations (GLC’s).The emissions when released into the atmosphere are subjected to transportation, dispersion, transformation, and fall out and wash out and finally reach the ground level at a particular distance and concentrations. The relationship between the source of emissions and its magnitude with the ground level concentrations (GLC’s) at receptor points is governed by air dispersion models which take into the account by the source strength, plume rise, atmospheric stability, mixing height, wind velocity, terrain and other meteorological conditions. The comparison between the predicted and field sampled downwind concentrations for SPM, SO2 ,and NOx (µg/m3) will be carried out in this study to predict the average downwind ground level concentrations (GLC’s)
Data Used for Computation
Stack emissions data have been used for prediction of short-term incremental GLC values of PM, SO2 & NOx, using the meteorological data collected during the March – April – May 2019. Details of the data used for computations are given below
Meteorological Data
The meteorological data recorded continuously during the month of March 2019 to May 2019, on hourly basis. AERMOD model requires hourly surface data values for wind speed, wind direction, temperature, relative humidity and cloud cover. Both data files for the surface and profile files were then used to generate the meteorological file required by the AERMOD dispersion model using the AERMET meteorological pre-processor. This AERMET has three
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stages to process the data. The first stage extracts meteorological data and assesses data quality through a series of quality assessment checks. The second stage merges all data available for 24-hour periods and writes these data together in a single intermediate file. The third and final stage reads the merged meteorological data and estimates the necessary boundary layer parameters for dispersion calculations by AERMOD.
Dispersion Modeling Results
The 24 hourly average ground level concentration (GLC) values from plant have been computed for PM, SO2 & NOx, considering topographical features around the plant and applicable stability classes. The maximum 24 hourly average GLC values for PM, SO2 & NOx, from plant are given in Table No. 4.4. Corresponding isopleths plotted are shown in Figure 4.1 to Figure No. 4.3 for of PM, SO2 & NOx.
iv. Predicted 24-hourly short term incremental ground level concentration
The results of the GLCs are given in the Table No. 4.4
When the above stated GLCs results are added in to the average ambient air parameters it gives overall AAQ of the surrounding study area.
Air quality contours are shown in the Figure No. 4.1 to 4.3
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TABLE NO.4.4
MAXIMUM COMPUTED GROUND LEVEL CONCENTRATION AT
PROJECT SITE
Sr.No.
Description ValueConcn *( µg/m3)
Co-ordinatesX (m) Y (m)
A PM1 1st Highest 24 hr. Result 1.35560 321.39 383.022 2nd Highest 24 hr. Result 1.33896 383.02 321.39
B SO21 1st Highest 24 hr. Result 2.54827 321.39 383.022 2nd Highest 24 hr. Result 2.51574 383.02 321.39
C NOx1 1st Highest 24 hr. Result 0.85586 321.39 383.022 2nd Highest 24 hr. Result 0.84487 383.02 321.39
Note :-(*) This predicted maximum Ground Level Concentration (GLC) is based on worst case scenario, considering maximum stack emission limit of SPM-150 mg/Nm3, SO2 100 PPM and NOx-50 PPM. As the actual emissions will be well below this predicted GLCs.
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TABLENO. 4.5CUMULATIVE CONCENTRATIONS DUE TO INCREMENTAL GLC's
Pollutant
MaximumBaseline
Conn
( g/m3)
IncrementalConn due to Proposed
Project ( g/m3)
Resultant Conn
( g/m3)
NAAQStandards( g/m3)
PM 88.66 1.35560 90.0156 100
SO2 33.62 2.54827 36.16827 80
NOx 48.7 0.85586 49.55586 80
With this marginal contribution due to the proposal of the project, the levels of PM, SO2 & NOx will remain below the 24 –hourly ambient air quality standards for SO2 & NOx (80
3) and PM103) prescribed by CPCB. The operation of plant is not likely to
cause any significant impact on the ambient air quality of the study area.
The Dispersion modeling assumptions are considered as follows:
1. The receptor locations for 36 wind directions starting with 10 degrees and incrementing with 100 up to 3600 for a distance of 500m, 1000m, 2000m, 2500m, 3000m, 3100 m, 3400m, 4000m, 5000m, 7500m, and 10000 m. has been taken for the Air Quality Modelling.
2. The impacts of the pollutants were identified up to 10000 meters.3. The terrain of the study area was considered as FLAT.4. Stability Class was evaluated based on Temperature Profile and Cloud Cover.5. The mathematical equations used for the dispersion modelling assumes that the earth surface
acts as a perfect reflector of plume and physic-chemical process, such as dry and wet deposition, and chemical transformation of pollutants are negligible.
6. The micro-meteorological data viz. Temperature, Wind Speed and Wind Direction has been collected from the meteorological station kept at the project site of M/s. Kemz Resibond Private Limited.
RESULTS OF THE AERMOD MODEL
The overlapped Isopleths on Google Image of the same is shown as at Figure No. 4.1 to 4.3. & concentration values are shown in Table No. 4.6 to 4.10.
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TABLE NO. 4.6 1ST HIGHEST 24-HR AVERAGE
CONCENTRATION VALUES OF PM (µg/m3)
Direction O Distance (meters)500 1000 2000 2500 3000
360 0.19029 0.14099 0.19405 0.17227 0.1509710 0.39735 0.19875 0.14942 0.13241 0.11602 20 0.87795 0.32521 0.22071 0.18729 0.17080 30 1.16630 0.74150 0.57292 0.47304 0.39586 40 1.35560 0.63256 0.58814 0.53243 0.47474 50 1.33896 0.82010 0.76795 0.68113 0.59622 60 0.45878 0.36950 0.34714 0.30060 0.26014 70 0.35171 0.23956 0.33087 0.29055 0.2520880 0.39086 0.27775 0.45045 0.42837 0.3963390 0.32988 0.21704 0.18688 0.16059 0.13770 100 0.14317 0.15440 0.21597 0.18857 0.16284110 0.12336 0.06809 0.03714 0.03036 0.02567120 0.14366 0.17985 0.14829 0.12358 0.11901130 0.19207 0.07154 0.02980 0.03342 0.03449 140 0.19288 0.14388 0.07249 0.05560 0.04576 150 0.14037 0.23347 0.18955 0.15238 0.12379 160 0.16293 0.09552 0.13931 0.12484 0.11010 170 0.17700 0.21447 0.35712 0.36240 0.35040180 0.16342 0.14826 0.12571 0.11144 0.10036190 0.16075 0.16660 0.19961 0.18835 0.17409200 0.16692 0.22634 0.29768 0.25736 0.22027 210 0.14188 0.05623 0.07128 0.07983 0.08146220 0.08314 0.03732 0.01992 0.01843 0.02142 230 0.05876 0.01578 0.02862 0.03464 0.04057 240 0.07437 0.01937 0.00750 0.00704 0.00665 250 0.09340 0.12138 0.13800 0.12113 0.10587 260 0.10019 0.05535 0.05517 0.04294 0.03347 270 0.18116 0.10130 0.05556 0.03788 0.02649 280 0.40993 0.48304 0.51620 0.46427 0.40885 290 0.27315 0.12696 0.11633 0.10193 0.08836 300 0.20557 0.13837 0.15458 0.15867 0.16917310 0.16208 0.22598 0.24364 0.21344 0.22672320 0.18111 0.10321 0.08282 0.09515 0.09853 330 0.17708 0.12576 0.07900 0.08341 0.08706 340 0.15312 0.11669 0.08113 0.09677 0.10303 350 0.14528 0.07739 0.04469 0.04385 0.03866
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1ST HIGHEST 24-HR AVERAGE CONCENTRATION VALUES OF PM (µg/m3)
Direction O Distance (meters)3500 4000 5000 7500 10000
360 0.13238 0.11667 0.09247 0.05755 0.0398210 0.10873 0.10173 0.08788 0.06149 0.0451720 0.15353 0.13964 0.11926 0.08097 0.0580030 0.33586 0.28852 0.22080 0.13162 0.08984 40 0.41820 0.37034 0.29559 0.18543 0.12862 50 0.52051 0.45776 0.36217 0.22506 0.15581 60 0.22650 0.19881 0.15695 0.09763 0.06776 70 0.21902 0.19148 0.14974 0.09139 0.0683980 0.35733 0.32132 0.26182 0.17352 0.1297990 0.13021 0.12281 0.10725 0.07606 0.05644 100 0.14098 0.12494 0.09956 0.06243 0.04357110 0.02423 0.02498 0.02435 0.02408 0.02572120 0.11286 0.10550 0.09065 0.06217 0.04475130 0.03057 0.02682 0.02053 0.01786 0.01900140 0.03847 0.03247 0.02404 0.02356 0.02477150 0.10210 0.08548 0.06232 0.04270 0.03657160 0.09698 0.08577 0.06831 0.05247 0.05600170 0.32122 0.29224 0.24110 0.15753 0.11181180 0.08467 0.07197 0.05345 0.03008 0.02057190 0.15461 0.13772 0.11053 0.07476 0.05929200 0.18906 0.16341 0.13474 0.10192 0.09145 210 0.07557 0.06933 0.05772 0.03728 0.03109220 0.02250 0.02249 0.02263 0.02482 0.02719 230 0.04583 0.04997 0.05267 0.04443 0.03583 240 0.00641 0.00632 0.00600 0.00325 0.00438250 0.09272 0.08121 0.06382 0.03938 0.02739 260 0.02998 0.02720 0.02348 0.01995 0.01917 270 0.01899 0.01398 0.00812 0.00478 0.00521280 0.35899 0.31691 0.25177 0.15666 0.10807 290 0.07503 0.06394 0.04717 0.02547 0.01948300 0.15831 0.14609 0.12246 0.07968 0.06389 310 0.21925 0.20835 0.18179 0.13189 0.11547320 0.09342 0.08726 0.07398 0.04991 0.04101 330 0.08294 0.07783 0.06723 0.05807 0.04700340 0.09949 0.09450 0.08347 0.06036 0.04519 350 0.03358 0.02983 0.02915 0.02782 0.02775
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FIGURE NO. 4.1ISOPLATHES OF PM CONCENTRATION FOR 24HRS
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TABLE NO. 4.71ST HIGHEST 24-HR AVERAGE
CONCENTRATION VALUES OF SO2 (µg/m3)
Direction O Distance (meters)500 1000 2000 2500 3000
360 0.35822 0.26203 0.36406 0.32348 0.2836410 0.74830 0.37342 0.28035 0.24865 0.21799 20 1.65139 0.61196 0.41390 0.35154 0.31965 30 2.19159 1.38937 1.07646 0.88903 0.74406 40 2.54827 1.18235 1.10218 0.99890 0.89130 50 2.51574 1.53194 1.43988 1.27836 1.11969 60 0.86319 0.69319 0.65168 0.56469 0.48890 70 0.66149 0.44581 0.62121 0.54592 0.4738480 0.73212 0.51564 0.84308 0.80230 0.7424990 0.62029 0.40848 0.35101 0.30181 0.25811 100 0.26914 0.28753 0.40561 0.35437 0.30614110 0.23171 0.12791 0.06976 0.05702 0.04820120 0.26859 0.33649 0.27857 0.23227 0.22262130 0.36104 0.13455 0.05547 0.06250 0.06470 140 0.36347 0.26948 0.13607 0.10430 0.08566 150 0.26408 0.43681 0.35615 0.28645 0.23279 160 0.30632 0.17783 0.26164 0.23462 0.20702 170 0.33302 0.39775 0.66759 0.67872 0.65694180 0.30711 0.27622 0.23504 0.20734 0.18691190 0.30182 0.31076 0.37293 0.35174 0.32499200 0.31431 0.42050 0.55870 0.48342 0.41395 210 0.26719 0.10576 0.13258 0.14917 0.15258220 0.15658 0.07022 0.03748 0.03330 0.03870 230 0.11070 0.02970 0.05212 0.06358 0.07497 240 0.14004 0.03646 0.01357 0.01281 0.01217 250 0.17518 0.22670 0.25911 0.22746 0.19878 260 0.18880 0.10234 0.10330 0.08048 0.06278 270 0.34149 0.19022 0.10457 0.07132 0.04988 280 0.76839 0.90017 0.96752 0.87119 0.76770 290 0.51313 0.23851 0.21845 0.19154 0.16609 300 0.38560 0.25970 0.28993 0.29600 0.31663310 0.30421 0.42194 0.45743 0.40099 0.42398320 0.34017 0.19381 0.15352 0.17726 0.18402 330 0.33227 0.23612 0.14835 0.15598 0.16317 340 0.28748 0.21894 0.15076 0.18072 0.19291 350 0.27265 0.14525 0.08362 0.08222 0.07256
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1ST HIGHEST 24-HR AVERAGE CONCENTRATION VALUES OF SO2 (µg/m3)
Direction O Distance (meters)3500 4000 5000 7500 10000
360 0.24879 0.21934 0.17389 0.10828 0.0749410 0.20386 0.19087 0.16504 0.11561 0.0849720 0.28764 0.26191 0.22392 0.15222 0.1091030 0.63132 0.54240 0.41516 0.24755 0.16900 40 0.78547 0.69579 0.55563 0.34878 0.24201 50 0.97787 0.86025 0.68087 0.42332 0.29315 60 0.42581 0.37385 0.29522 0.18371 0.12753 70 0.41182 0.36010 0.28168 0.17195 0.1283380 0.66935 0.60187 0.49043 0.32513 0.2433590 0.24403 0.23035 0.20138 0.14298 0.10571100 0.26510 0.23443 0.18686 0.11725 0.08186110 0.04369 0.04508 0.04408 0.04408 0.04766120 0.21137 0.19775 0.17012 0.11684 0.08415130 0.05739 0.05038 0.03859 0.03273 0.03517140 0.07187 0.06056 0.04350 0.04312 0.04578150 0.19204 0.16080 0.11726 0.07991 0.06860160 0.18240 0.16135 0.12853 0.09623 0.10367170 0.60240 0.54822 0.45251 0.29588 0.21010180 0.15775 0.13413 0.09966 0.05618 0.03847190 0.28849 0.25688 0.20619 0.13962 0.11089200 0.35541 0.30727 0.24957 0.18888 0.17002 210 0.14171 0.13009 0.10841 0.07010 0.05790220 0.04068 0.04074 0.04119 0.04578 0.05060 230 0.08510 0.09312 0.09853 0.08337 0.06733 240 0.01180 0.01170 0.01118 0.00608 0.00813250 0.17406 0.15248 0.11985 0.07399 0.05148 260 0.05499 0.04986 0.04305 0.03683 0.03564 270 0.03575 0.02632 0.01529 0.00872 0.00964280 0.67436 0.59551 0.47332 0.29470 0.20335 290 0.14100 0.12017 0.08866 0.04785 0.03601300 0.29663 0.27395 0.22989 0.14975 0.11934 310 0.41027 0.39001 0.34060 0.24513 0.21527320 0.17461 0.16320 0.13853 0.09363 0.07610 330 0.15558 0.14608 0.12629 0.10872 0.08816340 0.18649 0.17728 0.15674 0.11349 0.08502 350 0.06307 0.05538 0.05442 0.05210 0.05169
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FIGURE NO. 4.2ISOPLATHES OF SO2 CONCENTRATION FOR 24HRS
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TABLE NO. 4.81ST HIGHEST 24-HR AVERAGE
CONCENTRATION VALUES OF NOX (µg/m3)
Direction O Distance (meters)500 1000 2000 2500 3000
360 0.12034 0.08783 0.12223 0.10862 0.0952510 0.25140 0.12541 0.09413 0.08350 0.07321 20 0.55469 0.20557 0.13895 0.11804 0.10728 30 0.73602 0.46638 0.36151 0.29858 0.24990 40 0.85586 0.39672 0.36998 0.33538 0.29929 50 0.84487 0.51397 0.48339 0.42923 0.37600 60 0.28995 0.23273 0.21882 0.18964 0.16420 70 0.22219 0.14947 0.20859 0.18334 0.1591480 0.24574 0.17281 0.28295 0.26929 0.2492390 0.20834 0.13722 0.11787 0.10136 0.08665 100 0.09039 0.09642 0.13621 0.11901 0.10282110 0.07781 0.04295 0.02343 0.01915 0.01619120 0.09013 0.11292 0.09355 0.07801 0.07471130 0.12126 0.04519 0.01860 0.02097 0.02172 140 0.12213 0.09045 0.04569 0.03502 0.02875 150 0.08870 0.14659 0.11961 0.09621 0.07819 160 0.10288 0.05963 0.08786 0.07880 0.06953 170 0.11186 0.13328 0.22401 0.22781 0.22054180 0.10314 0.09263 0.07887 0.06951 0.06268190 0.10135 0.10424 0.12512 0.11800 0.10902200 0.10560 0.14095 0.18759 0.16234 0.13902 210 0.08977 0.03552 0.04445 0.05005 0.05122220 0.05260 0.02359 0.01259 0.01111 0.01291 230 0.03719 0.00997 0.01741 0.02127 0.02510 240 0.04705 0.01225 0.00453 0.00428 0.00407 250 0.05881 0.07606 0.08701 0.07638 0.06675 260 0.06344 0.03427 0.03467 0.02702 0.02108 270 0.11475 0.06388 0.03513 0.02396 0.01676 280 0.25795 0.30188 0.32479 0.29251 0.25779 290 0.17232 0.08010 0.07336 0.06433 0.05578 300 0.12946 0.08720 0.09734 0.09929 0.10626310 0.10215 0.14155 0.15360 0.13466 0.14227320 0.11423 0.06508 0.05144 0.05944 0.06173 330 0.11156 0.07929 0.04981 0.05234 0.05477 340 0.09653 0.07351 0.05053 0.06063 0.06475 350 0.09155 0.04877 0.02806 0.02760 0.02436
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1ST HIGHEST 24-HR AVERAGE CONCENTRATION VALUES OF NOx (µg/m3)
Direction O Distance (meters)3500 4000 5000 7500 10000
360 0.08356 0.07367 0.05841 0.03637 0.0251710 0.06844 0.06408 0.05542 0.03883 0.0285420 0.09655 0.08793 0.07519 0.05113 0.0366530 0.21203 0.18217 0.13944 0.08315 0.05677 40 0.26377 0.23367 0.18661 0.11715 0.08129 50 0.32840 0.28891 0.22868 0.14219 0.09847 60 0.14302 0.12557 0.09916 0.06171 0.04284 70 0.13832 0.12095 0.09461 0.05776 0.0430980 0.22467 0.20202 0.16462 0.10914 0.0817090 0.08192 0.07734 0.06762 0.04802 0.03551100 0.08904 0.07871 0.06274 0.03937 0.02749110 0.01457 0.01503 0.01471 0.01474 0.01597120 0.07094 0.06639 0.05712 0.03924 0.02827130 0.01927 0.01692 0.01296 0.01095 0.01178140 0.02411 0.02031 0.01452 0.01441 0.01533150 0.06450 0.05401 0.03939 0.02682 0.02303160 0.06127 0.05420 0.04318 0.03218 0.03473170 0.20224 0.18406 0.15194 0.09936 0.07056180 0.05290 0.04498 0.03343 0.01885 0.01291190 0.09677 0.08616 0.06916 0.04684 0.03721200 0.11937 0.10320 0.08361 0.06328 0.05700 210 0.04757 0.04368 0.03640 0.02354 0.01942220 0.01357 0.01359 0.01376 0.01533 0.01697 230 0.02852 0.03123 0.03306 0.02799 0.02261 240 0.00395 0.00392 0.00375 0.00204 0.00273250 0.05845 0.05120 0.04024 0.02485 0.01729 260 0.01839 0.01667 0.01440 0.01233 0.01195 270 0.01201 0.00884 0.00514 0.00291 0.00323280 0.22646 0.20000 0.15897 0.09899 0.06831 290 0.04736 0.04036 0.02978 0.01607 0.01206300 0.09957 0.09197 0.07719 0.05030 0.04004 310 0.13769 0.13090 0.11433 0.08217 0.07220320 0.05859 0.05476 0.04650 0.03144 0.02550 330 0.05224 0.04905 0.04241 0.03649 0.02960340 0.06260 0.05952 0.05263 0.03812 0.02856 350 0.02118 0.01856 0.01826 0.01749 0.01733
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FIGURE NO. 4.3ISOPLATHES OF NOx CONCENTRATION FOR 24HRS.
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v. Assessment of Impact on Air Quality
Base line study reveals that the levels of various pollutants like PM, SO2 and NOx etc. in the ambient air of surrounding study area are well within the limits stipulated by National Ambient Air Quality (NAAQ) Standard for Residential, Rural and other areas.
It can be seen from Table No. 4.4 that the maximum predicted 24 hours GLC(s) of all the pollutants i.e., PM, SO2 and NOx and its incremental concentrations on baseline value is below the NAAQS.
Thus, it can be concluded that, with proposed emissions from the Plant, the Ambient Air Quality within the industrial premises as well as in the surrounding study area will not exceed the NAAQ standards and hence there is no significant adverse impact on Ambient Air Quality.
D. Mitigation Measures for Air Environment during Operational Phase
The industry will take measures for reduction of fugitive emissions emanating out of process reactions by providing vent condensers.
Good ventilation will be provided to reduce the work room concentrations.
Fugitive emissions will be reduced by providing vent condensers to all the reactors.
Adequate stack height of 12 m will be provided to the TFH.
Stack monitoring facilities for t he periodic monitoring of the stack to verify the compliance of the stipulated norms.
For control of process gas emissions scrubbing system will be provided with suitable scrubbing media.
In order to minimize the air pollution, unit will develop greenbelt in and around its premises.
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4.5 WATER ENVIRONMENT
A. Impact During Construction Phase
Impact on water quality during construction phase / foundation work will be marginal and confined to use of water by workers only.
The existing sewer facility will be utilized by the temporary construction workforce or mobile toilets will get arranged for workers and proper site management will minimize the surface water runoff and soil erosion.
The water required for construction will be met by Water Tanker at site.
The quality of both surface and groundwater may also deteriorate in regard to the labour camps likely to be developed during the construction phase if proper solid waste management practices are not adopted. Good housekeeping should be practiced like handling and disposing of solid waste i.e. debris to enter from drainage column.
The baseline status of water quality in the core and buffer zone area has been established through sampling and analysis of various water quality parameters as part of the baseline environmental monitoring. Water samples collected from 14 locations in the core and the buffer zone of 10 km radius of the project area during the study period. The prime objective of the baseline water quality study was to establish the existing water quality in the study area and to evaluate the anticipated impact of the proposed project activity on water quality and to suggest appropriate mitigation measures for implementation. This will also be useful for assessing the conformity to the standards of water quality during the construction and implementation/ operational phase of the project. The contamination of groundwater might occur due to the irrational disposal of liquid wastes.
Mitigation measures :
Adequate sanitation facilities will be provided to the workers.
The existing sewer facility will be utilized by the temporary construction workforce or mobile toilets will get arranged for workers.
Proper site management will minimize the surface water runoff and soil erosion.
Good housekeeping should be practiced like handling and disposing of solid waste
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B. Impact During Operation Phase
The unit will segregate the waste streams for effective treatment.
Domestic Wastewater @ 1.2 KL/day will be disposed off through Soak Pit/Septic Tank System.
Industrial Effluent generation @ 3.5 KL/day will be sent to ETP for Primary treatment and then it will be evaporated in Evaporated System.
So, unit will achieve Zero Liquid Discharge.
Thus, it can be concluded that negligible impact on surrounding water environment is caused. Further, it is emphasized that all precautionary measures have to be strictly adhered as mentioned in the Environmental Management Plan given in Chapter 10, to maintain ground water quality within norms in the future.
C. Mitigation Measures for Water Environment during Operational Phase :-
Skilled manpower will be deployed for continuous and efficient operation of ETP.
Domestic wastewater will be disposed of through soak pit system via septic tank.
Minimization of water use providing drip system for gardening.
Use of high-pressure hoses for cleaning the floor and process equipment to reduce the amount of wastewater generated during washings.
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4.6 SOLID/ HAZARDOUS WASTE :
A. Impact of Solid / hazardous waste during Construction Phase:-
Improper disposal of debris, used oil, faulty and replaced spares, tyres and tubes and diesel for DG sets will result in surface and groundwater contamination and in turn affects the drainage of the area. As such proper housekeeping programme needs to be formulated for proper disposal of solid and liquid wastes.
B. Impact of Solid / hazardous waste during Operation Phase:-
The details of hazardous waste to be generated from the proposed project, is mentioned at Chapter -2. The proposed practice of storage of generated hazardous waste, in a closed room having an impervious bottom, and disposed of as per the prescribed guidelines will be continued for the generation of hazardous waste. Hence, the impact due to the same will be negligible as the handling of hazardous waste to be generated will be disposed as per guidelines. The details of solid/Hazardous waste details are shown in below Table No.4.9.
TABLE 4.9SOLID/HAZARDOUS WASTE GENERATION AND DISPOSAL MODE
Sr. No.
Type of Hazardous
Waste
Source Cat. No. Quantity (MT/Year)
Management
01 ProcessWaste/Residue
Process 21.1 35 Reuse and Non-Reusable disposed to CHWIF Site
02 ETP Sludge ETP Plant 35.3 4 Collection, Storage and Disposal at TSDF Site
03 Evaporation Residue
From Evaporator
37.3 3 Collection, Storage and Disposal at CHWIF Site
03 Used Oil Lubrication/D.G. set
5.1 0.05 Collection, Storage and reuse as Lubricant withinpremises.
04 Discardeddrums/bags
MaterialHandling
33.1 5 MT Collection, Storage and Sold To Recycler
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C. Measures for hazardous/solid waste during Operational phase :-
To reduce the quantity of solid/hazardous waste generation as well as possible contamination of land(soil) due to spillages/leakages from the plant operations, following Mitigationmeasures will be implemented:
There will not be any leakages/spillage from the raw-materials storage and from the storage of generated effluent from the project.
The generated Hazardous waste will be stored on floor with suitable packing and this dedicated area will be covered with the roof.
There cordson quantity of hazardous waste generation and disposal will be maintained for each category and possibilities will be explored for minimization and reuse.
Classification of waste
Collection, Storage, Transportation & disposed/sale to authorized recycler or re-user.
Data Management and Reporting
Personnel Training to the workers and employees.
The leakages of oil spills from machinery shall be collected in leak proof barrels and then disposed of to SPCB authorized dealers.
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4.7 NOISE ENVIRONMENT :-
A. Impact during Construction Phase
There will be slightly increase in noise level during construction phase due to construction activity and movement of vehicles. But it is restricted to construction phase only and it will occur during daytime, when construction activities will be in progress.
B. Mitigation measures during Construction Phase :-
Recommended mitigation measures are:
Good maintenance of vehicles and construction equipment.
Restriction of construction activities to day time only.
All vehicles entering the project site will be informed to maintain speed limits and not blow horns unless it is required.
The noise generated from construction machinery will be kept low by keeping the moving parts serviced and properly lubricated.
Plantation of trees around the plant boundary to attenuate the noise.
C. Impact during Operational Phase :-
As per observations, the Ambient Noise Level is within norms of Industrial Area. With the implementation of the mitigation measures proposed, the noise levels at plant boundaries will be well below the limits specified for industrial areas.
The major sources contributing to Noise pollution during the plant operation will be Compressor, TFH, Pumps etc. The operation of the equipment will generate noise ranging between 70-80 dB (A). The occasional noise is being attenuated by the development of green belt in and around the industry, which will be taken up right from the construction phase. Also ear protecting devices will be provided for personnel working in high noise generating zone.
The main sources of noise pollution in the plant are TFH, Reactors, DG Set, and other Noise generating units. Vehicular movements during operation phase for loading/unloading of raw materials and finished products and transporting activity may also increase noise level. Noise levels in the ambient air are well within the permissible limits given by the National Ambient Noise level standards as confirmed during baseline study. Leq values of the noise levels within the plant premises will be kept less than 75db [A] [during day time] and 70db[B] [during night time] which will be within the permissible limit.
Thus, there is practically no impact on surrounding environment.
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D. Mitigation Measures for Noise level during Operational Phase :
To minimize the noise pollution the unit proposes the following noise control measures:
Noise suppression measures such as enclosures, buffer sand or protective measures will be provided if required (wherever noise level is more than 90 dB(A)).
Employees will be provided with earplugs or earmuffs where exposure is 85 dB (A) or more.
Vehicles will be regularly maintained and optimum use of the same will be made.
Extensive oiling, lubrication and preventive maintenance is be carried out for the machineries and equipment to reduce noise generation and will be adopted for proposed expansion.
For DG Set and other high noise generating equipment acoustic enclosures shall be provided and also will be provide sufficient Green Belt Development area.
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4.8 LAND/SOIL ENVIRONMENT :
A. Impact during Construction Phase:-
In proposed unit needs to do Excavation for plant activity. Unit will do construction activity for proposed foundation work. Hence there will be minor impact on the surrounding soil environment and there will be only change in Land Use Pattern for the project site.
Present Land use of the site is open land. Proposed production activity will be done in premises of the unit. Hence, there will be change of existing land use pattern only for the project site.
The activities of proposed products will be confined within the plant site premises. During construction works, top soil generated from various activities like excavation etc. will be stored and preserved to use it during restoration period as far as possible. There will be no disposal of wastewater on land. Hazardous wastes will be stored at earmarked area with impervious flooring, shed and spillage/ leakage collection system to eliminate rainwater contamination, chances of overflow / spillages going on to the land and thus land/ soil contamination.
B. Mitigation measures during Construction Phase :-:
The earthen material generated during excavations and site grading periods, will be properly dumped and slope stabilization shall be taken. The topsoil generated during construction shall be preserved and reused for plantations.
Hence, no significant negative impact is envisaged on the surrounding soil quality due to presence of solid / hazardous waste within the plant premises.
C. Impact during Operation Phase
Source emission, wastewater and hazardous waste generation from any project activity affects the soil environment.
The impact due to air causes direct/indirect effect on soil. The emissions of SPM during operation will be effectively controlled. There will be practically no effect on the soil quality due to air emissions.
Domestic effluent will be discharged to soak pit and septic tank system. Wastewater generated from the Industrial activity will be treated in Effluent Treatment Plant and finally it will be evaporated in the Evaporation System
As per the Hazardous Waste (Management & Handling) Amendment Rules, 2016, all necessary control steps for each type of Hazardous Wastes generated will be taken for the proposed project activity.
Hence, due to the proposed project the land use pattern; land cover and topography of the area will be changed only for the project premises.
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D. Mitigation Measures during Operational Phase :
The unit will use LDO as a fuel for TFH and ha ve a stack height of 12 m respectively. There will be no process gas emissions from the proposed product manufacturing.
Effluent water generated from all streams of the proposed project will be treated in Primary Treatment plant and finally treated effluent will be evaporated in the Evaporation System.
Solid / hazardous waste generated is being stored separately in Hazardous Waste storage area within the factory premises and disposed as per guidelines.
The hazardous waste storage area has non-percolating RCC floor and covered roof.
Any spillage of raw material, water and waste water resulting in local contamination of soil, such soil will be recovered from ground and will be sent as hazardous waste for final disposal to TSDF site. All possible recyclable/reusable wastes shall be reused/ recycled within the premises itself.
Greenbelt development shall be taken in and around the premises so as to avoid soil erosion.
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4.9 ECOLOGY:
A. Impact during Construction Phase
Any construction activity brings changes in some components of the local Terrestrial ecosystem. These adverse impacts are restricted to the project Construction site and to some extent it's immediate surroundings.
The proposed project will not involve removal of any vegetation from the soil and loosening of the topsoil generally causes soil erosion as it is. However, such impacts will be confined to the plant site and will be minimized through paving and water sprinkling and greenbelt development. Thus, there will no major adverse impacts are envisaged on ecological environment due to project activities.
B. Mitigation measures during construction phase :
During construction, small shrubs in the plant premises are required to be cleared. The measures required to be undertaken to minimize the impact on the ecology are:
The felling of trees will be kept at minimum.Adequate Greenbelt will be developed.
C. Impact during Operation Phase :-
Impacts on terrestrial ecosystem can occur due to operation of the any industrial project mainly from air emissions, liquid effluents as well as hazardous wastes generation, which can interfere with the biotic and abiotic components of the ecosystem and may induce injurious effects when concentrations exceed permissible standards.
The proposed project will be carried out on land within M/s. Kemz Resibond Private Limitedwithout cutting of any trees. The proposed project does not alter the crop pattern and natural vegetation of the surrounding area.
Due to the safe control technology of air pollutants, liquid effluents and hazardous wastes disposal, no impact on the surrounding ecology is anticipated.
Development of additional greenbelt/green area will improve the ecological Environment of the surrounding areas.
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Prediction of impacts is based both on the direct and indirect; short-term as well as long-term; reversible and irreversible impacts that are most likely to occur owing to the industrial activity during establishment and operation. The ecological factors that are considered most significant as far as the impact on flora and fauna are concerned:
1. Whether there shall be any reduction in species diversity.
2. Whether there shall be any habitat loss or fragmentation.
3. Whether there shall be any risk or threat to the rare or endangered or endemic or threatened (REET) species.
4. Whether there shall be any impairment of ecological functions such as (i) disruption of food chains (ii) decline in species population and/or (iii) alterations inpredator-prey relationships.
Negative Impacts:
As there is change in the land use and land cover on account of the proposed project, the proposed action is not going to have any direct and significant negative impacts of flora and fauna or biodiversity.
Most probable Scenario:
As stated earlier, it is a new project there will be change in the land use and land cover within the project site. No damage is going to be done to the existing green cover within the project site. Except for a few weeds, there are only cultivated plants and no RET species in the core area. No species is going to be lost on account of the proposed project. No direct or indirect damage is expected to the flora and fauna of the buffer zone. Further, as there are no rare or endangered or endemic or threatened (REET) species, the project does not pose any threat to the flora and fauna of the study area. As the industry is required to operate and maintain the emissions and effluents within the limits specified by the CPCB / SPCB, the effects of the industry on the flora and fauna of the buffer zone may be negligible. Neither the storm water nor the effluent water nor any other kind of rain or waste water from the industry shall get in to the drinking water resources.
D. Mitigation Measures during Operational Phase :-
The measures required to be undertaken to minimize the impact on the ecology are:
The felling of trees will be kept at minimum.Adequate Greenbelt will be developed.
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4.10 SOCIO ECONOMIC ENVIRONMENT:
Like any other project, the proposed project is also expected to have certain positive and negative impacts on socio-economic environment.
A. Impact during Construction Phase
Local people involved as contract labors will have benefits of getting employment. Proposed project will generate temporary employment for personnel during operational phase.
Impact on Socio-Economic Environment
Due to proposed project there is no major negative impact on socio economic environment.
The proposed Project will require workforce of 20 persons during plant operations. Thus industrial activity will boost up the commercial and economical status of the locality to some extent and the overall impacts on socio- economic environment due to the proposed expansion are positive in nature and accrue to the community on the long-terms basis.
B. Impact during Operational Phase :-
The proposed project will generate direct employment. The indirect employment will be generated by way of transportation, shopkeepers and other casual employment. Implementation of this plant will also reduce production loss due to shortage of power.
Thus, the Proposed project will have significant positive impacts on the employment pattern of the study area.
During the erection phase short term direct or indirect employment will be generated. Project Proponent shall give first preference to the Local people wherever found suitable for all the jobsin the plant operations. Economic status of the local people will improve due to the increased employment & business opportunities, thereby making a positive impact to the Local Economy, educational, medical and housing facilities in the study area will considerably improve. Thus, the proposed project will have significant positive impact on the socio-economic environment.
C. Mitigation Measures for Socio-Economy :-
Due to proposed project the employment generation will be around 20 persons including skilled, semi-skilled & unskilled labour and office staff. Local qualified personnel can be employed.Under CSR Budget, the proponent has allotted 9.5 lacs to take up welfare activities.
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4.11 HEALTH & SAFETY :
A. Impact during Construction Phase
Health problems are also likely to be experienced in the area as a result of Immigrant labor being careless about personal hygiene and also mosquito and fly-borne infections usually prevalent in the rural areas. Such Problems will be minimized by provision of adequate sanitary and health services.
B. Impact during Operational Phase :-
The impact on health and safety hazard is due to Fire, handling of raw material and products. The company will provide sufficient fire fighting system. Therefore, no adverse impact is anticipated.
C. Mitigation measures for Health & Safety :-
1. Provision of periodic medical checkup with first aid facilities for all the employees is necessary.
2. Protective equipment will be regularly checked and will be kept easily accessible and easilyworkable during emergency.
3. Various types of fire extinguishers such as (Foam type, DCP, water, CO2 type) will be providing inside the factory premises.
4. Provide sufficient fire fighting system.
5. Health Problems will be minimized by provision of adequate sanitary and health services.
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CHAPTER 5
ANALYSIS OF ALTERNATIVES
5.1 SITE ALTERNATIVES
The alternatives analysis plays a key role for evaluation of the proposed technologies. M/s. Kemz Resibond Private Limited. is a proposed unit located at Survey No: 84/1, 84/2, Village: Fofadiya, Tal: Dabhoi, Dist: Vadodara-391210. The unit intends to manufacture Synthetic Organic Res ins.
During search of land by the unit for proposed Project, one land at survey no. 672, ParikhaVillage, Dabhoi Taluka, but there was GOUCHAR land between survey no. 672 and road,So it was left by the unit and after that the unit had found another land at survey no. 627, Parikha Village, Dabhoi Taluka. It was found that during the year 1951, the land was given by some trust by their ancestors, so it was again dropped.
Finally, the unit has selected this land which is fulfilling all criteria for setting up the proposed project. The proposed unit is in an area of 7551 Sq. meter and will have al l the infrastructure facilities very near by the plant. Land, water sources, material transportation and power etc.are available without any difficulty and the site is also well connected to NH - 48 (Chennai –Delhi).
The supporting factors for site selection:
1. There is no protected area notified under the Wild Life (Protect ion) Act (1972) & Eco-sensitive area notified under Section 3 of the Environment (Protection) Act- 1986 exists within 10 Km radius areas from the Plant Site.
2. The raw materials required for the production of all the proposed products is easily available in the vicinity of the project site because of the proximity to the industrial chemical markets at Bharuch, Ankleshwar, Vadodara and Padra . This will reduce both the cost of raw material transportation and the associated risk.
3. Plant is well connected to NH-48 (Mumbai – Delhi).
4. Availability of trained and skilled manpower nearby because of the proximity to various industrial areas and city/town.
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5.2 ALTERNATIVES FOR TECHNOLOGIES :
The technology proposed by M/s. Kemz Resibond Private Limited. for manufacturing of proposed products is based on latest and best available technology with automated machinery over manual machineries so far in the market to achieve maximum yield with minimum pollution generation and fugitive emission.
The unit is conscious about product quality and equally about the environmental aspects and resource conservations. The unit has adopt concept of 3R for waste reduction and will replace/upgrade their existing plant and machineries from time to time with the Best Available Technology.
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CHAPTER 6
ENVIRONMENTAL MONITORING PROGRAMME
6.1 INTRODUCTION
Based on the findings of the Environmental Impact Assessment study, various mitigation measures have been proposed, which have been detailed out in Environmental Management Plan (EMP). In order to monitor the impacts and efficacy of these plans monitoring of various environmental attributes have been proposed during and after the completion of the management plans.
A well-defined environmental monitoring programme would be employed with trained and qualified staff of Environmental Management Cell of the proposed project to monitor the environmental attributes of the area with respect to EMP as well as the guidelines of the GPCB/CPCB. Environmental monitoring schedule proposed to be adopted by the project.
Environmental monitoring program covers various areas like:
Ambient air qualityProcess /Flue Gas StacksWater quantity and qualityEffluent qualityNoiseSoil characteristicsEcology, etc.
6.2 OBJECTIVES OF ENV. MONITORING PROGRAM
The objective of the monitoring will be as follows:
To confirm the statutory compliance
To verify the results of the impact assessment study with respect to the proposedproject.
To study the trend of concentration values of the parameters, which have been, identified as critical and planning the mitigate measures.
To check and assess the efficacy of pollution control equipment.
To implement the EMP, a structured Environment Management Cell (EMC) interwovenwith the management system will be created.
EMC will undertake regular monitoring of the proposed pollution control system andconduct yearly audit of the environmental performance of the system. It will also checkthat the stipulated measures are being satisfactory implemented and operated.
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6.3 POST PROJECT ENV. MONITORING PROGRAM
Details of Environmental Monitoring Program are provided at Table No. 6.1.
TABLE NO. 6.1
ENVIRONMENTAL MONITORING PLAN
Sr. No. Aspect Source of Impact
Monitoring Method and it’s
ParametersFrequency Executing
AgencyMonitoring
Agency
1.0 CONSTRUCTION PHASE 1.1 Local
Manpower Absorption
Construction Work
Contractor’s report
Daily Contractor Kemz Resibond
1.2 Air Quality Transportation of construction materials and Construction activity
Monitoring of PM, SO2 and NOx
Weekly Kemz Resibond
GPCB/ Recognized Env. Agency
1.3 Public Health Dust, Noise, Movement of labours
Regular medical checkup
Monthly Contractors Kemz Resibond
2.0 OPERATION PHASE 2.1 Water
Quality & Quantity
Raw water & Ground water quality within the Project Area
As per IS:10500 Quarterly Kemz Resibond
GPCB/ Recognized Env. Agency
2.2 Effluent Quality
Quality of Treated effluent Send to Evaporation System to achieve Zero Liquid discharge.
ETP sample collection & quality analysis
Daily (Internal); Monthly (Third Party)
Kemz Resibond
GPCB/ Recognized Env. Agency
2.3 Ambient Air Quality
3 within premises PM10, PM2.5, SO2, NOx and as specified by SPCB
Quarterly Kemz Resibond
GPCB/ Recognized Env. Agency
2.4 Flue Gas Stack
Thermic Fluid Heater PM, SO2, NOx Quarterly Kemz Resibond
GPCB/ Recognized Env. Agency
2.5 Work Area 3 within plant area VOC and as specified by Factory Inspectorate
Quarterly Kemz Resibond
GPCB/ Recognized Env. Agency
2.6 Noise Level All prominent locations Noise levels Noise levels Kemz GPCB/
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within the premises Quarterly Quarterly Resibond Recognized Env. Agency
2.7 Hazardous Waste Management
ETP sludge &Evaporation Residue
General parameters Quarterly
General parameters Quarterly
Kemz Resibond
GPCB/ Recognized Env. Agency
Generation of used drums, bags and records of their dispatch to approved vendors.
Maintain Records Daily Kemz Resibond
GPCB/ Recognized Env. Agency
Generation of waste oil and theirtreatment
Maintain Records Daily Kemz Resibond
GPCB/ Recognized Env. Agency
2.8 OccupationalHealth
Pre-employmentcheck-up
Vision, Audiometry,Spirometry, Urine,Complete blood count,etc.
Once at the time of appointment
Kemz Resibond
Factory Inspector
Periodical check up Vision, Audiometry,Spirometry, Urine, RBS,Liver function tests(LFT),Complete blood count,Anemia, etc.
Age <30 yrs: once in5 years; 31-40 yrs,once in 4years;41-50 yrs: once in 2years; above >50 yrs, once in a year
Post-employmentcheck-up
Vision, Audiometry,Spirometry, ChestSkiagram, Urine,Complete blood count,etc.
Once at the time of relieving
2.9 Safety Whole unit Safety Audit Yearly Kemz Resibond
Factory Inspector
2.10 Greenbeltdevelopment
Within the premisesand in plant vicinity
Plant growth andsurvival rate
Periodic Kemz Resibond
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6.4 ADMINISTRATIVE ACTIONS & DOCUMENTATION
Records of the monitoring program shall be kept on regular basis for all aspects of the monitoring. Separate records for water, wastewater, solid waste, air, emission, soil & manure shall be prepared and preserved regularly.
Immediately upon the completion of monitoring as per the planned schedule, report shall be done & necessary documents shall be forwarded to the concern person. Methodology of monitoring (sampling & analysis) shall be prepared as separate documents as SOP (Standard Operating Procedure) wherever required.
Environmental statements &/or performance report/compliance report/audit report as per conditions of EC and CC&A shall be prepared and submitted to the concern authority as per the guidelines provided by the authorities within the stipulated timeframe. CC&A and other statutory permission/consents must be obtained & renewed timely as per legal provision & guidelines. Similarly, all necessary report & forms shall be prepared and submitted to the concern authority as per the statutory requirement of Environmental Acts/rules, Factory Act & MSIHC rules.
Reporting of accident & other requirements shall be made in prescribed format well within stipulated time frame as per statutory requirements & guidelines.
6.5 BUDGETARY PROVISIONS
The budget for Environmental Monitoring shall be Rs.1,12,800 Per Year and detailed break-up is provided in Table No. 6.2.
TABLE NO. 6.2BREAK UP OF BUDGET FOR ENVIRONMENTAL MONITORING
PLANSr.No.
Activity Quantity peryear
Budget perQuantity
(Rs)
Total Budget
(Rs)1 Ambient Air Monitoring 8 1500 120002 Stack Gas Monitoring 8 2000 160003 Haz. Waste Sample 4 1200 48004 Soil Sample 4 2500 100005 Ground Water Sample 4 1000 40006 Health Monitoring 20 3200 640007 Noise monitoring 4 500 2000
TOTAL 11900 112800
The industry will engage recognized laboratories to carry out all necessary monitoring parameters. Qualified staff has been appointed for the purpose of Operation and maintenanceof the pollution control facilities. Stand-by facilities are provided to all the facilities so as toensure fail proof treatment.
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CHAPTER-7
ADDITIONAL STUDIES
7.1 PUBLIC CONSULTATION
The proposed project M/s. Kemz Resibond Private Limited. falls under the Project/Activity No. 5(f) of Category ‘B’ as stated in the Environmental Impact Assessment Notification dated 14/09/2006 and therefore Environmental Clearance for these products is required to be obtained. The Application in Form-1 was made to State Level Environment Impact Assessment Authority (SEIAA), Gujarat for obtaining the related Environmental Clearance. The proposal was considered by State Expert Appraisal Committee (SEAC) in its meeting held on 24th May 2019 and has issued the recommendations to SEIAA. SEIAA has issued Terms of Refrences (TORs) for carrying out Environmental Impact Assessment study vide letter No. SEIAA/ GUJ/ TOR/5(f)/1093/2019, Dated: 30/07/2019.
All the aspects of the TORs are incorporated in the draft EIA/EMP report, the same may be submitted to the Gujarat Pollution Control Board (GPCB) for conducting public hearing/public consultation as per EIA Notification, 2006 as well as MoEF&CC’s O.M. J-11011/321/2016-IA .II (I), 27-04-2018.
7.2 RISK ASSESSMENT
7.2.1 INTRODUCTION
Industrial activities including production, storage, handling, transportation and operational practices presents levels of hazards to workforce, population and environment at large due to accidents, spills, leaks etc. These accidents results in personal and financial loss. The assessment of the threat posed, its control and prevention through good design, management and operational controls is of primal importance.
The QRA report signifies that trained & skilled employees and supporting services can achieve improved safety & productivity levels. Together they can also achieve low maintenance cost, optimized use of Raw materials and negligible rejections/ wastes.
The project is advised to equip with a well-planned Disaster Management Plan as an essential Mitigation Control Measure.
Substantial information is given in the chapter preventive measures of QRA, for choosing Plant and Equipment which will ensure PRODUCT SAFETY.
A good Legal & Regulatory Compliance Register shall be planned and be in place. All the Rules and Regulations of the land shall be strictly followed to achieve a hindrance free operation of the plant from the statutory point of view.
A good Safety Manual shall be planned and be in place. All the requirements of Safety & Health of the operating plant shall be an essential part of the manual. The Safety manual will serve as a good communication medium to the employees of the plant. The systems to be
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complied by the operating level employees as part of their responsibilities and the operational requirements of the system will be readily available in the manual at their disposal.
Risk Assessment study includes predictions of the Worst Case Scenario (catastrophic failure) and Maximum Credible Accident Scenario along with damage distances and preparedness plan for effectively combating such situations. The report also discusses and demarcates the vulnerable zones and a detailed fire control plan for flammable substances.
No plan is complete or total of its requirements and its scope of improvement is a continuous process. Hence, the Risk Assessment Report is to be reviewed and updated as and when:
any expansion, alteration, or extension of the plant is planned / implementedan incident has occurred and been dealt with, based on feedback gathered on any shortcomings in the handling of the situationany feedback is received from the users of the report
Risk Assessment is therefore defined as a continuous and integrated process of identification, evaluation, and measurement of risks, along with their potential impact on the organization.
Objectives of Risk Assessment:
Risk analysis follows an extensive hazard analysis. It involves the identification and assessments of risks to the neighbouring population is exposed to as a result of hazards present. This requires a thorough knowledge of failure probability, credible accident scenario, vulnerability of population etc. Much of this information is difficult to get or generate. Consequently, the risk analysis is often confined to maximum credible accident studies.
Risk assessment is carried out for the following objectives:1. To identify hazard and risk resulting from the hazards2. To study and foresee the effects of such risks on the workers, public, property and environment and to find out necessary control measures to prevent or minimize risk.3. To comply the legal requirement by various safety and environment laws of the country like.
The Factories Act, 1948 / The Gujarat Factories Act, 1963The Environment Protection Act and Rules, 1986Hazardous waste (Management & Handling) Rules, 1989Public Liability Insurance Act & Rules,1991Chemical Accident, (Emergency, planning, preparedness and response) Rules, 1996.
4. To get the necessary information for Emergency planning and evacuation.
The benefits of risk assessment include the following:
Mitigation or reduction of the risk of an incident.Mitigation of the severity and/or consequences by way of improved process techniques, fire protection systems, arrangements of storage, inventory monitoring to fit production requirements.Confidence building in employees by improving competency.Preparedness and prompt response to deal with any accident
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7.2.2. STORAGE AND HANDLING
All raw materials are stored in the designated storage location. List of Product along with its details of properties and storage are presented herewith in Table 7.1 to Table 7.3
Table 7.1: STORAGE DETAILS OF RAW MATERIAL & PRODUCTS:
Sr. No. Chemical State Means ofStorage
Total Capacity
(MT)22. Unsaturated Polyester Resin Liquid Drums/Tank 22
23. Alkyd Resin Liquid Drums 1124. Epoxy Resin Liquid Drums 1125. Saturated Polyester Resin Liquid/
solidDrums/Bags 11
26. Vinyl EsterResin Liquid Drums 1127. MEG Liquid Drums/Tank 1228. DEG Liquid Drums/Tank 1229. PG Liquid Drums 1230. Phthalic/Isothalic Anhydride Solid Bags 1531. Maleaic Anhydride Solid Bags 1532. Styrene Monomer Liquid Drums 1033. Castor Oil Liquid Drums 4.534. Linseed Oil Liquid Drums 4.535. Soya bean Oil Liquid Drums 4.536. Glycerin/Pentaerithritol/NPG/
Trimethalol PropaneLiquid Drums 4.5
37. Xylene Liquid Drums 1038. 5 Sodium Di Methyl SulfoIsopthate
(DMS Salt)Liquid Drums 4.5
39. Di Butyl Tin Oxide Soild Bags 0.25040. Bisphenol-A Liquid Drums 1041. Caustic Soda Solid Bags 0.25042. Methacrylic Acid Liqiud Drums 4.5
Table 7.2: STORAGE AND DISPOSAL OF SOLID / HAZARDOUS WASTE
Sr. No.
Name of Solid Waste
Category No.
QuantityMT/Year
Storage of Waste
Method of Disposal
1 Process Waste / Residue
21.1 35 Bags Collection, Storage and Reuse and Non-
reusable disposed to CHWIF site.
2. ETP Sludge 35.3 4 Bags Collection, Storage and Disposal at TSDF Site
3. Evaporation Residue
37.3 3 Bags Collection, Storage and Disposal at CHWIF
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Site4. Used Oil 5.1 0.05 Drums Collection, Storage and
Reuse as Lubricant within Premises.
5. Discarded Drums/Bags
33.1 5 Hazardous waste storage
area
Collection, Storage and sold to recycler.
7.2.3 RISK RATING
The consequences on various environmental receptors have been ranked into 5 levels ranging from insignificant to catastrophic consequence and are given in table below:
Table 7.3: OVERALL SEVERITY/CONSEQUENCE
ConsequenceCategory
Magnitude Ranking
ExtremelyMild
The activities and their environmental impacts are judged to be very short term & reversible change
±1
Mild The activities and their environmental impacts are judged to be short term & reversible change
±2
Moderate The activities and their environmental impacts are judged to be long term & reversible change
±3
Severe The activities and their environmental impacts are judged to be long term & irreversible change
±4
Most Severe The activities and their environmental impacts are judged to be permanent & irreversible change
±5
After identifying the consequence severity, the probability of occurrence also needs to be estimated to arrive at a complete picture of environmental impact risk. Table below provide probability/likelihood ratings on a scale of 1 to 5. These ratings are used for estimating the likelihood of each occurrence.
Table 7.4: OCCURRENCE FREQUENCY/PROBABILITY
Category Ranking Occurrence FrequencyVery Likely 5 Has happened more than once per year at the location
Likely 4 Has happened at the locationSomewhat
Likely3 Has happened once in organization or more than one per
year in industryUnlikely 2 Heard of in the industryHighly
Unlikely1 Never heard of in the industry
The level of risk is calculated by multiplying the consequence score and the probability of occurrence together. Thus Risk Rating = Consequence Score × Probability of Occurrence
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Table 7.5: RISK RATING
Sr. No.
Source Scenarios Failure Mechanism
Risk Consequence
Probability Severity Risk Rating
1 Leakages of Hazardous chemicals
During charging of raw materials, during unloading of product and from storage area
Fire 2 3 6
2 Spillage of Acid / Alkali
During charging of raw materials, during unloading of product and from storage area
Fire 2 2 4
3 Risk during transfer of Chemicals
Spillages and leakages
Fire 3 2 6
4 Risk due to electrical spark in solvent storage area
Electrical fault Fire 1 4 4
LEGEND
PROBABILITY: SEVERITY: RISK RATING:(PROBABILITY x SEVERITY)
1 – HIGHLY UNLIKELY 1 – EXTREMELY MILD2 – UNLIKELY 2 – MILD3 – SOMEWHAT LIKELY 3 – MODERATE4 – LIKELY 4 – SEVERE5 – VERY LIKELY 5 – MOST SEVERE
Fire protection/ control / mitigation measures are incorporated (under execution).Hence, M/s. Kemz Resibond Private Limited. can be categorized as a medium hazard industry who can manage their risks through invoking on-site emergency plan. The scope for Off-site emergency is visualized as a remote possibility.
During the navigation of above sequence of activities, it is drawn to the understanding that the storage & handling are to be closely associated. This will ensure, the associated preventive / mitigating facilities planned and installed for managing the projected risk scenarios will be serving the desired objectives.
The in-house regulatory measures for implanting safety shall be appropriate to the risks, and to be handled by trained persons for the purpose. SOPs are to be documented and identified people are to be trained. Regular mock drills shall be planned and executed, as a preparation/ precaution for dealing with emergency operations.
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7.2.4 PROCEDURE FOR TREATMENT OF WORKERS AFFECTED DURING ACCIDENT
Like:Gas Leakages / Breathing of Solvent/Acidic Fumes Skin Burning due to chemical contactAccident due to chemical spillage Fire hazardous Electric Shock
Special Safety Precaution:Provide proper fire extraction & fire hose at risk area. Wear safety glasses or a face shield if splashing may occurSkin contact requires immediate washing of the affected area with soap and waterRegular work zone monitoringPeriodic health checkup programs have to be Organized and records maintained
Treatment of worker after fire accident :
Burn of skin requires immediate flushing of the contaminated area with soap and water at a sink or emergency shower for a good fifteen minutes. Remove clothing. In case of eye burn, promptly flush eye with copious amount of water for 15 minutes (lifting upper and lower lids occasionally) and obtain medical attention. Company should have tie up with nearest hospital for emergency treatment. It is recommended to provide the safety shower and eyewash station in plant.
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7.3 HAZARDS AND THEIR CONTROL MEASURES
While hazards of other type along with safety measures, flood control measures and earthquake control measures are given in Table 7.6 Table 7.7 & Table 7.8 respectively.
Table 7.6: HAZARDS AND ITS CONTROL MEASURE
Sr. No.
Name of the Possible Hazards & Emergency
It’s Source & Reasons
Its Effect on persons property & environment
Control Measures Provided
1. Gas Leakages / Breathing of Solvent/Acidic Fumes
From Reaction vessel, From storage tank, During loading & unloading of material
Lungs, Eye, Skin irritation, Corrosion of wall & roof, Leaves damage
SOP for loading & unloading of materials, closed containers, suction system with pump
2. Skin Burning due to chemical contact
Due to leakages in tank, During loading of material
Skin irritation Provision of body shower, first aid facility
3. Accident due to chemical spillage
Due to improper loading & unloading of materials
Lungs, Eye, Skin irritation
Provision of eyeshower, Provision of spill kit at process area
4. Fire hazardous Due to solvent leakages
Burning of any body parts
Provision of fire extinguisher, sand buckets
5. Electric Shock Due to short circuit, open electric connection
Difficulty in breathing &heartbeat, In major effect person can dye
Provision of flame proof electric fitting
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Table 7.7: EARTHQUAKE CONTROL MEASURES
Sr. No.
Hazard Safety Precautions Emergency Control
1 Electric shock
All electric line cut off / switch off from main supplyHand siren use to declare emergencyShock proof hand gloves should be used if needed
Stop electric powerInform site main controllerfor outside help
2 Fire Minimum stock of Hazardous chemicalEarthquake proof building
Stop the leakageInform site main controller for outside help
Table 7.8: FLOOD CONTROL MEASURES
Sr. No.
Hazard Safety Precautions Emergency Control
2 Slippery Surface Clean the working placeKeep away all persons at safe assembly points Evacuate all persons through emergency exit door immediately
Start the emergency water tapping
7.4 RISK IDENTIFICATION
Identification of risks is done qualitatively and quantitatively through the selection of hazardous substances and by studying the manufacturing process, to arrive at possible failures and their inherent causes. Probability of risk occurrence is also ascertained in order to determine the MAXIMUM CREDIBLE ACCIDENT SCENARIO and the WORST CASE SCENARIO.The risks are then analyzed quantitatively in terms of probability, and severity. The risks have also been rated according to the matrix R = Probability x Severity.
7.4.1 MAXIMUM CREDIBLE LOSS ACCIDENT SCENARIOS
A Maximum Credible Accident (MCA) can be characterized as the worst credible accident. In other words: an accident in an activity, resulting in the maximum consequence distance that is still believed to be possible. AMCA-analysis does not include a quantification of the probability of occurrence of the accident. Another aspect, in which the pessimistic approach of MCA studies appears, is the atmospheric condition that is used for dispersion calculations. As per the reference of the study, weather conditions having an average wind speed of 3.0 m/s have been chosen.
The Maximum Credible Loss (MCL) scenarios have been developed for the Facility. The MCL cases considered, attempt to include the worst “Credible” incidents- what constitutes a credible incident is always subjective. Nevertheless, guidelines have evolved over the years and based on basic engineering judgment, the cases have been found to be credible and modeling for assessing vulnerability zones is prepared accordingly. Only catastrophic cases have been considered and not partial or small failures (as is the case in Quantitative Risk Assessment where contributions from low frequency - high outcome effect as well as high frequency - low outcome events are distinguished). The objective of the study is emergency planning, hence only holistic & conservative assumptions are used for obvious reasons.
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Hence though the outcomes may look pessimistic, the planning for emergency concept should be borne in mind whilst interpreting the results.
7.4.2 DAMAGE CRITERIA
In consequence analysis, use is made of a number of calculation models to estimate the physical effects of an accident (spill of hazardous material) and to predict the damage (lethality, injury, material destruction) of the effects. The calculations can roughly be divided in three major groups:
1. Determination of the source strength parameters;2. Determination of the consequential effects;3. Determination of the damage or damage distances.
7.5 RISK ASSESSMENT AND CONSEQUENCE ANALYSIS
7.5.1 SOFTWARE USED FOR CALCULATIONS
ALOHA (Areal Locations of Hazardous Atmospheres):Aloha is a computer program designed especially for use by people responding to chemical accidents, as well as for emergency planning and training. ALOHA can predict the rates at which chemical vapors may escape into the atmosphere from broken gas pipes, leaking tanks, and evaporating puddles. It can then predict how a hazardous gas cloud might disperse in the atmosphere after an accidental chemical release.
ALOHA is an air dispersion model, which you can use as a tool for predicting the movement and dispersion of gases. It predicts pollutant concentrations downwind from the source of a spill, taking into consideration the physical characteristics of the spilled material. ALOHA also accounts for some of the physical characteristics of the release site, weather conditions, and the circumstances of the release. Like many computer programs, it can solve problems rapidly and provide results in a graphic, easy-to-use format. This can be helpful during an emergency response or planning for such a response.
ALOHA provides output as amount of chemical discharged from the source as well as its concentration in air it takes in to account different levels of concentrations for a specified chemical. Different concentration levels are given below:
ERPG 1: is the maximum airborne concentration below which it is believed that nearly all individuals could be exposed for up to 1 hour without experiencing other than mild transient adverse health effects or perceiving a clearly defined, objectionable odor.
ERPG 2: is the maximum airborne concentration below which it is believed that nearly all individuals could be exposed for up to 1 hour without experiencing or developing irreversible or other serious health effects or symptoms which could impair an individual's ability to take protective action.
ERPG 3: is the maximum airborne concentration below which it is believed that nearly all individuals could be exposed for up to 1 hour without experiencing or developing life-threatening health effects.
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IDLH: The Immediately Dangerous to Life or Health (IDLH) level. A chemical's IDLH is an estimate of the maximum concentration in the air to which a healthy worker could be exposed without suffering permanent or escape-impairing health effects.
7.6 PREVENTIVE MEASURES
The 4 E of hazards and prevent accidents are as follows:Engineering and technological innovation to improve reliabilityExperience in the study of hazards and operations- Risk analysisEnforcement of decisions on study results – Preventive mechanismsEducation, awareness, and practice in prevention of accidents (Training & drills)
Various measures will be adopted at each stage of the project for ensuring safety of people, environment, and property.
These measures include the following:Site selectionChoice of technologyEquipment design incorporating domestic and international safety codesPlant layout with utmost consideration given to operational safety aspectsIncorporation of interlocks and protection systems in plant designSafety awareness for key management personsSafety training of all operational, maintenance staffRegular safety monitoring - Audits and inspections
7.6.1 SITE SELECTION
The plant is located near State high way No. 161. The site soil conditions are rigid and safe, complying with the requirements of the load bearing capacity of various installations.
7.6.2 CHOICE OF TECHNOLOGY
The process is carefully chosen for reducing wastes, reducing the risk to human beings and the environment. It is the proven one and acknowledged internationally.
7.6.3 EQUIPMENT DESIGN
Electrical
1. Plant areas are segregated into zone areas as per the hazards present, with adequate distances to separate the two zones vide Petroleum Rules.
2. Areas designated as Zone - 0, 1 areas will have all electrical fixtures including lighting fixtures, switches, junction boxes, cable glands, etc. of approved make and flame proof type.
3. For standby power diesel generator of adequate capacity will be installed with auto-start facility in case of power trip/failure. This DG set will be located far away from the processing area.
4. All tanks, pumps, tankers and pipelines are properly earthed and bonded for electrical continuity and prevention of static electric charges. Double earthing will be provided to drain electrical charge to two independent earth pits.
5. All incomers to the electrical panels including MCCs and PCCs will have air circuit breakers of adequate capacity for electrical protection of equipment’s connected to the outgoing feeders.
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6. All feeders in MCCs and PCCs will have user point identification at both termination ends for easy tracking of faults and rectification.
7. Adequate ventilation fans will be provided in electrical panels for effective heat dissipation.8. Earthing pits locations and requirements with looping grids shall be provided as per the legal
and regulatory requirements.9. Overhead cable routing will take into account safe distances from buildings and facilities.
Underground cabling shall be marked with metal markers as per the regulatory requirements.10. All panels will have incomer earth fault relay.11. Lightning arrestors will be provided on top of all structures.12. All cables running on trays at elevation shall be properly dressed up and tied with clamps for
rigidity.13. All areas of plant and machinery and roads including all open operating areas are illuminated
sufficiently to carry out operations round the clock.
7.6.4 PLANT LAYOUT
1. Administrative office is located away from process plants and storage tanks.2. Security office is located close to gate and away from process plants and storage area.3. Canteen is located close to administrative office and away from process plants.4. Adequate number of safety showers and eye wash fountains are provided in areas close to
storage facilities and process plants and on each floor wherever necessary5. A separate area has been provided on site in the upwind direction for emergency evacuation-
Assembly Points.6. Interconnecting roads within the plot are made circular so that more than one get-away is
available at any point.7. Flame proof areas have been isolated from the non-flame proof areas.8. DG room and electrical transformer located away from administrative office, process plant
and storage area.9. Fire hydrant system covers the entire operating area of the plant.10. Warning boards will be put up in areas where entry is restricted11. No Smoking boards will be put up at the entrance and at other locations throughout the plant12. Boards showing the numbers and contact details of government / district officials as well as
fire department, police department, district commissioner, etc. will be installed at security gate as well as in the operational area.
13. Battery-cum-electrically operated emergency alarms will be made available.14. Speed breakers and speed limit signs will be displayed as required
7.6.5 SAFETY AWARENESS FOR KEY MANAGEMENT
1. Key management personnel will be made aware from the beginning of the project of the key issues regarding the safety in design and operation of the plant.
2. Discussions on safe handling of hazchems have been carried out with various safety experts, technical collaborators and with overseas suppliers through conference calls.
7.6.6 SAFETY TRAINING FOR ALL OPERATIONAL STAFF
1. All operational staff will be given safety training as a compulsory part of their induction program.
2. Safety training will include, among other things, the following important aspects:a. awareness of hazards of individual chemicals through study of MSDSb. correct usage of Personal Protective Equipment (PPE)
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c. explanation of the hazards and risks present in the premises, as well as their analysisd. impact on safety, health, and environment due to improper handling of hazardous chemicalse. guidelines for safety in operationsf. Checklist of Do’s and Don’t’s
7.6.7 SAFETY AUDITS AND INSPECTIONS
1. Regular safety audit will be conducted to ascertain the safety levels followed in the plant and suggestions for improvement
2. Special safety audits will be conducted whenever there are process-related equipment / operational changes made in the plant
3. Testing and inspection of high pressure equipment with periodical hydro testing and thickness testing will be carried out during maintenance shutdown.
4. Testing of pressure safety valves and setting will be carried out regularly during maintenance shutdown
5. Calibration of control valves, instruments as and when required, but at least once in a year during maintenance shutdown
6. Testing of electrical measurements, such as earthing resistance, will be carried as per requirement.
7. Testing of all fire hydrant installations, fire extinguishers, fire pumps, fire water level monitors will be carried regularly.
7.7 MITIGATION MEASURES
Risk mitigation involves the reduction of the likelihood of a loss occurring due to an accident and the reduction of the severity of such a loss.
Several risk mitigation measures have been taken into consideration in the planning of this project:
Personal Protective EquipmentMedical facilitiesHandling of leakages and spillsFirefighting systemEngineering controlsEmergency Control CentreDisaster Management Plan
7.7.1 PERSONAL PROTECTIVE EQUIPMENT
Personal protective equipment (PPE) are needed to protect individuals from injury. Several types of PPE are necessary for providing the optimum protection to individuals from the various risks. In addition to the PPE which will be used for regular plant operation, the following PPE has been selected for preservation at the plant’s Emergency Control Centre room for use in case of emergency:
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Table 7.9: LIST OF PROPOSED PERSONAL PROTECTIVE EQUIPMENTS
Sr. No. Equipment Quantity1. Self-contained Breathing Apparatus (SCBA) 2 set2. Face masks/Dust Mask 20 sets3. Fire Fighting suits 2 sets4. Helmets 20 pieces5. Gloves 40 pairs6. Eyes Goggles 10 sets
A. Training
i. Induction Trainingii. Special Trainingiii. On Job trainingiv. Training for Self Contained Breathing Apparatus and Emergency Life Saving
Apparatus
B. Body Protection (Non Respiratory)
v. Protecting Clothingvi. Head Protection (Safety Helmet)vii. Face & Eye Protectionviii. Ear Protectionix. Hand Protection
x. Foot Protection
C. General Protection
1. Safety Belt: double harness full body safety belt is compulsory for work at height.2. Safety Net: used for work at height.3. Safety Shower: for first aid treatment in case of chemical exposure on body4. Eye Washer Fountains: for first aid treatment in case of eye exposure.
D. Care of PPE’s
Each and every personal protective equipment will be visual checked by the user for its integrity before its use and, if any defects are observed, the concerned supervisor should be promptly informed and the defects corrected or PPE replaced.Self contained breathing apparatus will be inspected and details of the inspection and maintenance recorded.All employees should familiarize themselves with different types of PPEs available in the company.When not in use, PPE should be carefully stored in a designated place. Do not put it in tool box where it is likely to be damaged or allow it to lie in an open place where it may collect dust. Store PPE in a safe place well covered, away from sunlight and dust.Do not use the PPE’s other than its purpose or don’t temper with any PPE’s.
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7.7.2 MEDICAL FACILITIES
Medical facilities are needed to provide immediate medical attention to people who may be exposed to certain health risks during an accident.
1. First Aid Centre will be located at the Workers Facility near the administrative building and canteen.
2. A doctor will visit the plant periodically.3. First Aid Centre will be equipped with a safety shower, eye wash centre and oxygen-
administering facility, etc.4. Medicines and antidotes for relevant hazardous chemicals will be stored for 5 persons.5. The contact numbers of all nearby hospitals and medical facilities will be kept and put up
on a board in the First Aid Centre.6. A general agreement for immediate treatment will be made between the nearest hospital
and the plant.
7.7.3 FIREFIGHTING SYSTEMS
Due to the handling of various chemicals in the plant, it is necessary to provide an effective and efficient fire fighting system. A map of the fire fighting installations is given in the plant site layout. Unit will provide two types of fire extinguisher one is foam type and one is Co2 .
M/s. Kemz Resibond Private Limited. management shall take into consideration fire prevention measures at the project planning and during plant commissioning stage to avoid any outbreak of fire. But looking to the hazardous nature of manufacturing operation shall be handled and processed, the chances of outbreak of fire is however less but cannot be refuted. Hence to avoid such a scenario, a well laid fire protection system will be provided in the factory. List of proposed fire fighting equipment’s are given in table below:
TABLE 7.10: LIST OF PROPOSED FIRE FIGHTING EQUIPMENT’S
Sr. No. Name of Equipment Type Quantity(Nos.)
1. Foam type fire extinguishers 5 kg 12. Co2 type fire extinguishers 10 kg 13. Fire Sand Bucket Stand of Six
Bucket1
7.7.4 EMERGENCY CONTROL CENTRE
The Emergency Control Centre is a designated room that shall be occupied by the Incident Controller, the final authority to give directives, coordinate with various teams, communicate with district government agencies, and to deal with an emergency inside the plant. The following documents and equipment shall be kept here for the use of the Incident Controller during an emergency:
Updated drawings and P&I diagrams of plantSite layout plan showing raw materials and finished products storage area, security gates, assembly points, process plants, utility building and other areas of the plantDisaster Management PlanList of key plant operating personnel
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Telephone numbers and contact details of key plant operating personnelTelephone numbers and contact details of district government officials and emergency officesPersonal Protective Equipment for emergency useFire extinguishers (Co2 & Foam filled)
7.8 CHECKLIST OF DO’S AND DON’TS
Suitable notices / boards displayed at several locations indicating appropriate hazards warning as well as Do’s and Don’ts for ensuring operational and personal Safety for information of workers / staff and visitors.
Do’s Don’tsFor good physical condition, check the vessels expected to be used in the process.
Don’t use the vessels expected to be used in the process without checking.
Check the availability of utilities required till the end of the batch / job.
Don’t fail to check the availability of utilities required till the end of the batch / job
Check for proper manpower available till the entire operation in over.
Don’t work without enough and proper man power.
Time schedule should prepare for material flow on basis of the process.
Don’t use the material without Prepare time schedule of material flow on basis of the process.
Monitor the temperature and pressure if possible
Don’t perform without Monitoring the temperature and pressure during process.
Familiarize the worker about what is the job on hand.
Don’t keep the workers under wraps about what is the job on hand.
The worker or operator should have sufficient Knowledge of the materials handling.
Don’t let the worker / operator do the work having lack of sufficient knowledge of the materials handled.
Visual instructions should properly display for Characteristics of the chemicals.
Don’t use the chemical with unknown characteristics or having unreadable label.
Ensure proper training of personnel. Don’t let the personnel do the work without giving proper training.
Ensure sufficient numbers of safety devices are available.
Don’t work without sufficient numbers of safety devices.
Ensure the workers wear proper PPE of adequate grade.
Don’t let the workers do work without wearing proper PPE of adequate grade.
Demarcation of the chemical storage area for chemical in test.
Don’t use material that is under testing for production.
Ensure removal of used containers from workspaces.
Don’t store used containers at workspaces.
Prepare and follow the safe work instruction.
Don’t breach the safe work instruction.
Record every incident that led to an accident irrespective of the seriousness of the accident and analyze the same to improvise the system continuously.
Don’t try to conceal information regarding missed accidents or small injuries.Remember every and any mishap can be fatal if not for yourself for others.
Never work bare foot or without safety shoes.
Don’t work bare foot or without safety shoes.
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Never use mobile phones in work zones. Don’t use mobile phones in work zones.operational aspect that has been identified.
Open or use containers only on written instruction.
Don’t open or use containers on which instruction are not written.
Verify the label with the instruction before use.
Don’t work without Verifying the label with the instruction before use.
Participate wholeheartedly in all safety related exercises an keep yourself updated.
Don’t ever even thinking of evading safety instructions.
Reactors must be closed tightly during time of reaction
Don’t open reactor while reaction is ongoing
Keep material safety data sheet in locations where chemicals are being handledand study it.
Don’t mix waste chemicals in the same storage containers because mixing twoOr more waste chemicals in the one container can cause violent reactions.
Segregate toxic, flammable chemicals and keep them under control
Don’t store acetic acid or acetic anhydride, which are highly flammable, with acids.
Be sure to store chemicals and hazardous materials away from heat or flames,and take steps to eliminate ignition sources nearby.
Don’t allow spillages of the chemicals from drum while transferring
7.9 DISASTER MANAGEMENT PLAN
7.9.1 OBJECTIVES OF EMERGENCY PROCEDURES
Measures those are required to be taken during emergency are co-ordination of activities with many departments/ services and outside resources.
The objective of the procedure is to define role of key personnel of different services during major emergency to be effectively utilized to:
1. Safeguard lives2. Contains of incident and bring it under control3. Minimize damage to property & neighboring environment4. Rescue & treatment of casualties & evacuation of persons to safe areas5. Identification of affected persons, information to relatives and extending necessary assistance.6. Preservation of information, records etc. which will help in investigation7. Welfare assistance to casualties8. Providing relevant information to police, district authorities and news media9. Mobilizing inside resources10. Initiating and organizing evacuation of affected persons
Collecting latest status, other information and requirement
7.9.2 BASIS OF PLAN AND HANDLING OF EMERGENCY
1. It is not possible to envisage and detail every action, which should be taken during an emergency. The basic philosophy is to get key personnel of necessary discipline who have the knowledge and background to assess the situation and give directions as per the objectives as quickly as possible.
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2. The plan identifies the services/departments required to combat emergencies and also identifies the key persons to discharge the duties.
3. Key personnel have been identified for emergencies and are responsible for providing necessary assistance.
4. Any outside assistance, which company shall get, shall be co-ordinate by the main site controller on duty.
5. Messages via telephones are restricted to key personnel only. This is required to keep the telephones free for key personnel to contact for necessary feed-back.
6. Senior person who arrives on scene is automatically in charge for the service group. He should not leave the site without entrusting the charge to his deputy. All the key personnel should be available at the main control room. All key personnel of other services will report to main site controller, who will co- ordinate between various departments and outside agencies.
7.9.3 INFORMATION ABOUT EMERGENCY AND SUBSEQUENT ACTIONS
1. Any person noticing fire/explosion/release of hazardous gases should shout FIRE, FIRE or HELP, HELP and will activate the emergency bell
2. Inform respective control rooms3. The Executive in-charge along with the concerned Dept. Head will immediately rush to the
incidence site to assess and take immediate action required to control the source of incidence. They will also inform Security and Safety personnel to come to the place of disaster/emergency and assist them.
4. If he feels that the situation is likely to escalate and may lead to emergency will communicate following minimum information to all senior persons.
Brief description of incident.Status & seriousness of the situationActions immediately taken.Immediate assistance required.All key personnel of respective services, depending on nature of emergency will arrive at site to take charge of positions.
7.9.4 INSTRUCTIONS TO EMPLOYEES
The plan assumes certain discipline at site during emergency as given below;
1. Do not get panick2. Do not approach the scene of disaster as a spectator3. Do not engage phones/ P.A. system unnecessarily4. Non-essential personnel to gather at security gate after receiving instructions5. Do not move here & there unnecessarily6. Do not approach unnecessarily to get information or more inquiry7. Remain at your working place unless called and be attentive to instructions8. Ensure that all contract laborers working in the premises are immediately sent to main security gate. They will receive further instructions from main site controller
All non - essential staff members should gather at safe assembly point after assessing the wind direction (from the wind sock, stack of boiler chimney) and wait for further instructions which will be communicated through PA system or by other available means.
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7.9.5 INSTRUCTIONS TO CONTRACTORS
The plan assumes certain discipline at site during emergencies as given below;
1. Do not get panick2. Do not approach the scene of disaster as a spectator3. Do not engage phones/ P.A. system unnecessarily4. Non-essential personnel to gather at security gate after receiving instructions5. Do not move here & there unnecessarily.6. Do not approach unnecessarily for information or more inquiry.7. Remain at your working place unless called and be attentive to instructions8. Ensure that all contract laborers working in the premises are immediately sent to main
security gate. They will receive further instructions from main controller. All should gather at safe assembly points after assessing the wind direction (from the wind sock, stack of boiler chimney) and wait for further instructions which will be communicated through PA system or by other available means.
9. All fabricator contractors should ensure that all welding machines are switched off and all cylinders are closed before leaving the working area.
10. All civil contractors should be gathered at assembly points after declared emergency.
7.9.6 MITIGATION OF CONSEQUENCES DURING MAJOR ACCIDENT
No major hazard installation can ever be absolutely safe. Even if a hazard assessment has been carried out, if the hazards have been detected and appropriate measures have been taken, the possibility of an accident cannot be completely ruled out. So safely systems provide measures, which can mitigate the consequences of accident or emergency situation. In order to be able to initiate counter measures in the event of an accident, company shall install various safety systems to mitigate the consequences during Major Accident are as under:
1. Emergency Control members available in the plant2. ECC room with full equipped with Fire Fighting Equipment3. Alarm System and method of reporting / declaring emergency4. Regular rehearsal of emergency preparedness5. Training to all employees regarding emergency preparedness6. MSDS of all hazardous chemicals are available in safety department and in concerned
department.
7.10 EMERGENCY CONTROL CENTRE WITH LIST OF EQUIPMENT AND ACCESSORIES
Safety Office in front of Operation Building will act as Emergency Control Center. It is equipped with all necessary accessories as mentioned below.
7.10.1 DOCUMENTS
Site PlanDisaster Control Plan copyList of essential telephone numbersList firefighting equipmentShift Schedule of Emergency Control members
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7.10.2. PERSONAL PROTECTIVE EQUIPMENT
A. Sets (Breathing Apparatus)Face MasksHand glovesGum bootsGogglesHelmetsSafety beltsApronsFire proximity suit
7.10.3. EQUIPMENT LIST
Internal / External TelephonePortable alarmTorchesEmergency Cupboard with necessary PPEArtificial RespiratorRacer watches (STOP WATCH)Gas Detector TubeStatic Charge MeterGas Mask
7.11 INFORMATION REGARDING KEY PERSONS AND THEIR RESPONSIBILITIES DURING EMERGENCY
7.11.1 SITE MAIN CONTROLLER
After getting information of emergency, the site main controller will rushed to the Emergency Control Center immediately.
1. On reaching he will assess the magnitude of the situation in consultation with Incident Controller and decide whether inside or outside help are to be called (i.e. Fire Service, Police, and Ambulance etc.).
2. Ensure that key persons are called in.3. Give guidance and direction in vital and important activities to control the emergency
situation.4. Direct to close down and evacuation of the plants in consultation with Incident controller and
key personnel.5. If necessary arrange for evacuation of neighboring population.6. Inform the Government authorities such as Collector, MC, Factory Inspector, Health Officer
& medical Officer and request them for their help as situation demands.7. Give prime importance to human life and guidance in organizing the rescue operations as
well as ensure whether injured people getting proper medical attention in time.8. Always be in touch with the Incident Controller to get further progress and decide further
plan.9. On completion of emergency situation declare the normalcy through Administrative Officer.10. Control the re-occupation of the affected areas on discontinuation of emergency.11. Do not permit to re-start the plant unless it is safe.12. Give authentic statement of the incident to News Media & Government Authorities.
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7.11.2 INCIDENT CONTROLLER
1. Take the charge of situation and assess the magnitude of the event2. Control and guide all the operations with priorities to the Safety of Personnel, minimize
pollution, loss of material and loss to the plant equipment and property.3. Provide advice and guide to the Fire Fighting and Rescuing squad and Fire Brigade while
they arrive.4. Establish communication with emergency control center.5. Report on all significant developments to the emergency control center through
phone/Messenger.6. Ensure that evacuation of the areas in the factory getting affected is complete.7. After the emergency situation is brought under control, assure that the necessary evidence for
further investigation in the incident is preserved and inform Site Controller regarding control of emergency.
7.11.3 TECHNICAL STAFF / DEPARTMENT HEAD
1. As soon as informed, rush to the spot and take charge of the situation till senior group arrives.
2. Ensure that emergency siren is raised which gives information to Security, Safety, Administration Staff and Technical Staff.
3. On arrival of Incident Controller, inform him about the gravity of the situation and then to work under his guidance to control the situation.
4. Ensure that only experienced and essential people remains at the location for controlling, while others to be evacuated from the scene.
7.11.4 EMPLOYEES NEAR THE SPOT (INCIDENT AREA)
The employees near affected area, under the guidance of the Incident Controller shall1. Tackle the emergency as per laid down procedures for the area bearing in mind the
requirements of the situation called for by the progress of the emergency.2. Remove all non-essential employees (who are not assigned any emergency duty) shall
evacuate the area and gather at the specified assembly points.3. Stop the operations as per the information of the Incident Controller.
7.11.5 PERSONNEL OFFICER
1. When emergency declared immediately rushed to emergency control center.2. Basically he will work as a Liaison Officer and will stationed at emergency control center
during emergency. He will work under the direction of Site Controller.3. To ensure that the casualty receives adequate attention at first aid center, also ensure
additional help if require from Government authorities or outside agencies.4. Arrange transport facility for injured personnel to get timely medical help.5. He will also arrange for head count at assembly points and will inform Site Controller.6. Also be in touch with the Security and Other Departments for help.7. Will check the Roll call from Time Office for availability of trained personnel during
emergency situation at the site.8. Determine the need to inform statutory authorities of the accident and fill the necessary
forms for submission with consultation of the Site Controller.9. When emergency is prolonged, arrange for the relief of personnel as well as inform the
families of injured persons and organize refreshments / catering facility.
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7.11.6 ENGINEERING SERVICES KEY PERSONNEL
1. When emergency declared, immediately proceed to Emergency Control Center.2. Ensure the availability of electrical wiremen, utility, maintenance employees and drivers.3. Ensure the water supply & electric power generator in case of power failure.4. Be in touch with the Site controller / Incident Controller to extend help as and when
required.5. Ensure availability of Light Motor Vehicles as well as Fork Lifts, JCBs etc.6. Arrange the vehicle as per required by Administrative / Personnel Officer.
7.11.7 SECURITY & FIRE IN-CHARGE
1. When emergency declared, ensure that the Fire man in the fire station and Security guards at the maingate are sufficient.
2. On getting instruction from Site Controller/Incident controller, cordon the affected area to maintain lawand order.
3. As per instruction from Site Controller/ Incident controller, arrange to start the fire hydrant pump.
4. Ensure the following duties by Security Guards;Stop all vehicles and visitors entering into the factory, except any Government authorities such as FireBrigade, Police, Factory Inspector, Medical Staff and inform the Administrative Officer on their arrival.If any press reporter and local Leader comes at the main gate, take them to the Administration Office.Do not allow any vehicle to park at the main gate or nearby at main road.Assure that the entrance of the gate is clear for thorough fare. In Similar way control/ guide internaltraffic for smooth operations.Act according instructions given by Personnel and Administrative Officer.Ensure that all essential personnel evacuated and assembled at Assembly points.Arrange effective security nearby the incident place.
7.11.8 FIRST AID ATTENDANTS
1. As per the instructions given by the Incident Controller, arrange the supply of additional emergency related equipment to the incident place. Give necessary First Aid treatment to the affected persons immediately.
2. Inform the Personnel and Administration Officer regarding the severity of injury and advise for furthermedical help if necessary.
3. Ask for additional trained First-Aider, if required.4. On arrival of Doctor, assist him to give medical treatment to the affected people.
7.11.9 SAFETY OFFICER
1. On hearing emergency siren rush to the spot and assume the position of incident controller and take care of the situation till a senior personnel arrives and on their arrival work with them in team, extending their own expertise.
2. Give instructions and guideline to the people involved in control measures. As well as help in providing required PPE.
3. Give instructions to the safety attendants.4. Brief the Site Main Controller about the progress of control measures.5. Advise site controller regarding type of help required from outside.
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6. Give instructions to other department through internal phones /Communication Officer.7. Make arrangement to carry out monitoring whenever necessary and appraise results to the
concerned seniors.
7.11.10 EMERGENCY ORGANIZATION FOR IDLE HOURS
7.11.10.1 SECURITY
1. After getting information through emergency hooter inform at least two senior persons at their residence by telephone/messenger.
Site controllerSafety OfficerIncident controller.Technical Staff/Senior Staff
2. Assure that the front side of the gate is clear for thoroughfare.3. Act according to the instructions of Incident Controller/Senior Officers4. Inform Emergency Control Center for emergency.
7.11.11 LIST OF IMPORTANT AUTHORITIES WITH THEIR ROLE IN EMERGENCY AND TELEPHONE NUMBERS
List of important authorities with their role in emergency and telephone numbers will be prepared and placed wherever required.
7.11.12 INFORMATION ABOUT EXTERNAL COMMUNICATION SYSTEM
1. Communication will be through Emergency Central Alarm System.2. Telephones: An EPABX unit will be installed to connect all departments internally.
Company will also provide mobile connections to all important personnel at site.3. STD Phone & Fax/Telex: Will be provided at important places4. In the event of failure of telephone system: Communication officer will arrange special
messengers for communication Minimum one vehicle with driver/trained security personnel are available in the company premises round the clock.
Unit will communicate through our Administration department by unit’s vehicle to nearby community.
7.11.13 ANNOUNCEMENT SYSTEM DETAILS
During emergency it is necessary that the alarm should be heard by all employees wherever they work, for that speakers will be placed at various locations within plant.
7.11.14 OUT SIDE IMPORTANT ADDRESSES AND PHONE NUMBERS
List of important addresses in the nearby area such as hospitals, ambulance services, fire fighting services, Government personnel (District Helpline, District EOCRescue & Relief, district collector, zilla panchayat, police station and emergency control services and their telephone numbers will be prepared and will be displayed outside emergency control room.
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7.11.15 REHEARSAL AND UPDATION OF PLAN
1. Regular mock drills will be organized. Shortfalls in actions observed during drill will be explained to participants and will be corrected accordingly.
2. Any shortcomings regarding On–Site Emergency Plan observed during such drills will be corrected and incorporated in On-Site Emergency Plan and same will be communicated to all.
3. The On-Site Emergency Plan will be updated after any significant development in factory or change in the law.
7.12 OCCUPATIONAL HEALTH AND SAFETY PROGRAM FOR THE PROJECT
The factory will take all reasonably practicable measures to minimize the risk of such accident incompliance with the legal obligation under the relevant safety.All building plans and installations are as per relevant acts and duly approved by competent government authorities.Process and Equipment will be designed by qualified and experienced professionals and fabricated to applicable national / international codes with stage wise inspection.Safety features such as fire extinguisher and suitable Personal Protective Equipment (PPE) shall be provided. Regular operations and testing of fire extinguishers shall be carried out.Periodic inspection and testing of pressure vessels, equipment, machineries and equipment handling substances.Training of workers and Staff for fire fighting, work permit system, first aid, safe handling of materials and integrating safety, in all activities.Accident / Incident reporting system and information of employees about the same for better awareness.Suitable notices / boards displayed at several locations indicating appropriate hazardswarning as well as DOs and DON’T for ensuring operational and personal Safety for information of workers / staff and visitors.
For the safety of the workers, personal protective equipments like hand gloves, helmets, safety shoes, goggles, aprons etc. & Ear protecting devices like earplugs/earmuffs will be provided. Nose mask will be provided at places, where there is possibility of dust generation.
List of Personnel Protective Equipment
1. Face Masks2. Ear Plunge3. Hand Gloves4. Gum Boots5. Goggles6. Helmets7. Aprons8. Fire Proximity Suit
Company shall adequately install fire-fighting system in different sections of the plant.
Some of the safeties precautionary measures shall be taken for manufacturing process are listed below:
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1. Safety Relief Valve, Rupture disk, temperature scanner, pressure indicator, and flow meter will be installed to vessel wherever required.
2. Cooling / Chilling water circulation arrangement will be provided to avoid abrupt increase of pressure and control heat and high temperature.
3. Auto control system (ACS) to Monitor & Control.4. Vent will be connected with scrubber as per the requirement.5. PPE will be provided to workers during charging of various raw materials and exhaust
ventilation lines will be provided as per requirement.6. Necessary interlocking and alarm system will be installed wherever required.
7.12.1 MEDICAL AID SCHEME
For outside help, company authority will make a mutual understanding with the following authorities to extend their help whenever an emergency occurs;
1. Doctors from Civil Hospital2. Police Station3. Fire Brigade
Time to time company shall inform/impart training to concerned employees for awareness about chemicals and its hazards and the precautionary measures on their part. An emergency guide will be provided to each employee, which gives guidance to him or her during an emergency.
7.13 LEAK DETECTION AND REPAIR (LDAR)
Leak Detection and Repair (LDAR) is a program implemented to comply with environmentalregulations for reducing the fugitive emissions of targeted chemicals into the environment. Inaddition to control fugitive emissions, LDAR Program also helps the industries to reduceunwanted losses of chemicals and thereby conserving energy & increasing their profitability.
Following steps are followed for effective implementation of LDAR Program:
1. Identification of volatile chemicals which may contribute in VOCs:
In existing plant, following are the list of chemicals which may contribute in VOCs.STYRENE MONOMERXYLENEEPOXYN RESIN
2. Identification of all the probable sources of leakage; such as valves, pumps, andConnectors.
List of the sources of probable leakage is as follows:Valves/FlangesPump glands handling above chemicalsPump sealsLPDs (Low Point Drains)HPVs (High Point Vents)
A list of all such items shall be made and same shall be incorporated in the checklist for LDAR.
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3. Selection of appropriate method for leak detection:Considering the nature of the chemical; only visual check is required for leak detection of individual chemicals.
4. Scheduling and checklist for Leak Detection:- Daily visual inspection of complete pipelines and equipment for abnormality and leakages.- Planned maintenance of all the equipment will be incorporated for reducing breakdowns and leakages.- Anti-splash tapes will be place on flanges to avoid heavy leaks due to rupture of gaskets.-Procurement and installation of pipelines and pumps will be such that their design pressure will be higher than working pressure.These liquids will be transfer in close system using appropriate pipes and pumps.After transfer of these liquids, will be empty their pipelines and drain down into their home tank, so that in case of pipeline failure, there is no leak of liquid to atmosphere.Seamless pipelines will be procure and install for handling such liquids.No container containing such the liquids will be store with lid left open.These liquids will be store in well ventilated space and in cool conditions.Leakless valves will be use to handle the liquids.SOP and training will be establish for handling, transfer operation and bleeding of system if any.Routing of pipeline to be such that pipelines will have minimum bends and low points where there are chances of creating vapor packets.Duration and capacity of storing all such material will be as minimum as possible so that there will be reduction of chances of emissions.Temporary repair and containment of any leaks will be done as soon as it occur.
5. Methods for rectification of identified leaks:For all identified leaks, closure shall be ensured with the help of maintenance department and records for the same shall be maintained.
7.14 DETAILS OF VARIOUS SOP’S PREPARED:
Procedure/ guideline for effective and efficient handling, treatment and disposal of liquid effluent & Hazardous waste
Procedure/ guideline for effective and efficient operation of air pollution control equipments
Procedure/ guideline for proper inspection and maintenance of safety equipments in thepremises
Procedure for safe handling of fire extinguisher guidelines for working at height or on fragileroof or false ceiling
Procedure for safe handling of liquid chemical at site
Guidelines & procedure for handling and storage of hazardous chemicals
Guideline/ procedure for spillage control of liquid chemicals
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7.15 FIRE CONTROL PLAN
M/s. Kemz Resibond Private Limited. has considered fire prevention measures at the project planning stage for its upcoming new facility to avoid any outbreak of fire By looking to the hazardous nature of process and the chemicals that are handled and processed, the chances of outbreak of fire cannot be totally ignored. Hence to tackle such a situation, company has developed proposed, well-resourced and adequate fire protection system/fire fighting network.
The company has planned to keep the different types of fire extinguishers at variousconspicuous locations.
Other Fire fighting Measures to be updated for the new facilities shall be:
Flame detectors, smoke / temperature actuated heat detectors with alarms, automaticsprinkler system, shall be installed at conspicuous locations as per the requirements.Company shall have Fire Water Tank of adequate capacity to combat the emergency, if arise.Working staff will be trained to operate CO2 and foam extinguishers.DG set shall be made available as a separate power backup for fire network, in case ofemergency or power failure.Factory Layout shall be designed in such a way, that it will have a provision for separate entry and exist with adequate margin all around the periphery for unobstructed easy movement of the emergency vehicle / fire tenders without reversing back.
Ways To Minimize The Manual Handling Of The Hazardous Chemicals:
1. Fork lifts are used for unloading chemical barrels/carboys, their movements within plant,handling carboys, bulk chemical bags, etc.2 Cranes, hoists, pallet trucks, conveyors, etc. are used as per the requirement, to eliminatemanual handling.3 Lifting tools & tackles are used, wherever required.4 SOPs, work instructions are prepared and followed.5 Trainings are provided to relevant staff, operators, workers for the risk associated withmanual handling of hazardous chemicals, ways to overcome those risk, etc.
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CHAPTER - 8
PROJECT BENIFITS
The proposed project activities will become beneficial to the surrounding area or community in terms of infrastructure, employment, social development and other benefits as described here under;
8.1 IMPROVEMENTS IN INFRASTRUCTURE
There will be increase in some small scale businesses like tea stall, catering services/hotels, grocery, sweet marts, cycle shop etc. in the study area.
8.2 EMPLOYMENT POTENTIAL
Due to proposed project direct employment of about 20 and indirect about 70 will be generated. Thus, the activities of proposed project will require considerable manpower which will be beneficial to employment structure of local area as maximum recruitments will be done from local area on merit basis. Local people will be given preference for almost all the jobs in the Plant, direct as well as indirect.
Economic status of the local people will be improved due to the increased business opportunities, thereby, making a positive impact. Educational, medical and housing facilities in the study area will considerably improve. Therefore, social infrastructure of the study area will be improved.
8.3 CORPORATE SOCIAL RESPONSIBILITY (CSR) & SOCIO-ECONOMIC DEVELOPMENT
Due to the proposed Project, facilities are likely to grow with the development. There is a positive effect due to improved communication and health services, which have lead to economic prosperity, better educational opportunities and access to better health and family welfare facilities. There will be beneficial effect on human settlement due to employment opportunities from the industry.
Local quality of life will be improved. This factor combined with all other mitigation measures like proper treatment and disposal of wastewater, hazardous waste and gaseous emission has minimized the adverse impact on ecology and had a beneficial impact on human settlement and employment opportunities. There has been a beneficial impact on the local socio-economic environment.
The increasing industrial activity will boost the commercial and economical status of the locality up to some extent.
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8.4 DIRECT REVENUE EARNING TO THE NATIONAL AND STATE EXCHEQUER
This project will contribute additional revenue to the Central & State exchequer in the form of Central GST & State GST. Thus, the project will help the Government by paying taxes from time to time, which is a part of revenue and thus, will help in developing the area. Demand of the proposed products in foreign market is also significant, which will boost the export potential of the company as well as country. Export oriented units plays vitalrole in development of economy as well as local physical infrastructure for further boostingof industrial development with sustainable approach as the industries need to maintain good environment & safety condition to get better foreign market.
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CHAPTER - 9
ENVIRONMENT COST BENIFIT ANALYSIS
9.1 COST BENEFIT ANALYSIS
As per EIA Notification 14-09-2006, this Chapter of the ‘Environmental Cost Benefit Analysis’ is applicable only if it is recommended at the Scoping stage. However, as per the TOR points issued by SEAC, vide their letter Ref. No.: SEIAA/ GUJ/TOR/5(f)/1093/2019, Dated: 30/07/19, Environmental Cost Benefit Analysis is not applicable and therefore the same has not been carried out.
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CHAPTER 10
ENVIRONMENTAL MANAGEMENT PLAN
10.1 INTRODUCTION
Environmental Management Plan is considered to be an Integral component of EIA process. EMP is essentially a road map that describes how the impact mitigation measures suggested in earlier chapters, will be implemented along with other measures concerned during different life cycle phases of project
Any industrial development is associated with certain positive impacts as well as some negative impacts on the environment. However, the negative or adverse impacts cannot possibly rule out scientific development. At the same time, adverse impacts cannot be neglected.
The Environmental Management Plan describes, in brief, the management's plan for proper and adequate implementation of treatment and control system for air and liquid pollutants and for maintaining the environment. It also includes development of green belts around the plant, proper safety of the workers, noise control, fire protection systems and measures.
10.2 THE ENVIRONMENTAL MANAGEMENT PLAN (EMP)
The Environmental Management Plan (EMP) consists of a set of mitigation, monitoring and institutional measures to be taken during the design, construction and operation (post construction) stages of the project. The plan also includes the actions needed for implementation of these measures. Overall objective of EMP:
Prevention: Measures aimed at impeding the occurrence of negative environmental impacts and/or preventing such an occurrence having harmful environmental impacts.Reduction at Source: Reduction at source by adopting Best Available Technology.Minimization: Limiting or reducing the degree, extent, magnitude, or duration of adverse impacts.
The major components of the Environmental Management Plan are:Mitigation of potentially adverse impacts.Monitoring during project implementation and operation.Implementation schedule and environmental cost estimates.Integration of EMP with project planning, design, construction and operation.
The EMP has been designed keeping in view the regulatory and other requirements to ensure the following:Minimum disturbance to the native flora and fauna.Compliance with the air, water, soil and noise quality norms.Conservation of water to the extent possible.Encourage the socio-economic development.
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10.3 SCOPE & OBJECTIVES OF EMP
The main objective of Environmental Management Plan is to warrant that the industrial development in an identified particular study area needs to be entangled with judicious utilization of non-renewable resources and to ensure that the stress/load on the ecosystem is within its permissible assimilative capacity.
The main objectives in formulating this environmental management plan are:
To comply with all regulations stipulated by the Central / State Pollution Control Boards related to air emissions and liquid effluents discharges as per air and water pollution control laws.
To treat all the pollutants viz., liquid and gaseous which contribute to the degradation of the environment with appropriate technology.
To handle hazardous wastes as per the Hazardous Waste (Management and Handling & Transboundary Rules, 2016 of the Environment (Protection) Act, 1986.
To promote further afforestation in the surrounding areas of the Plant.
To create good working conditions (devoid of air and noise pollution) for employees.
To reduce fire and accident hazards.
Perspective budgeting and allocation of funds for environment management expenditure.
Continuous development and search for innovative technologies for a cleaner and better environment.
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10.4 ADMINISTRATIVE ACTIONS:
10.4.1. OPERATIONAL PHILOSOPHY
Philosophy behind designing the Environment Management Plan for a particular project is that all the activities being undertaken at the plant should be in complete compliance with all applicable laws, regulations, standards and guidelines. In order to achieve this, the management of the KEMZ RESIBOND has been established a resource base for the management of health, safety, environment and social issues at operation phase of the project. Technically qualified and experienced staff is in-charge of this activity and has planning to hire more qualified staff if needed in future expansion. Success of the Environment Management Plan is due to following aspects:
1. Management Support;
2. Efficiency of Environment Management Cell;
3. Acceptability of resulting environmental quality.
10.4.2 MANAGEMENT SUPPORT –ENVIRONMENT POLICY
To implement and facilitate the Environment Management System for any project, one of the most important aspects is management support. An Environmental Policy covering following aspects shall be laid down prior to commencement of proposed project:
The corporate policy for Environmental Management is to create sound and eco-friendly environment for sustainable development at all production projects, plan new projects with environment-friendly considerations, plan regulative, ameliorative and mitigative measures to protect environment and fully merge into the overall corporate policy for achieving the targeted business goals of the Corporation.
Objectives: The environmental policy is framed specifically to fulfill the following objectives:
Create a work environment which enhances/motivates production and productivity. Create a residing environment for the enjoyment and peace of employee. Encourage safe and scientific operations and other well-established engineering practices.
Promoting awareness amongst the employees and the neighborhood population for adopting environmentally friendly acceptable procedures and restricting environmental degradation and pollution to the barest minimum.
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10.4.3 ENVIRONMENTAL MANAGEMENT CELL
Kemz Resibond will formulate an Environmental Management Cell for its proposed unit. All the project activities will be monitored to ensure the appropriate implementation of all environmental mitigation activities and to identify areas where environmental management plan compliance is not satisfied. For effective implementation of the monitoring program, it is also necessary to have a permanent organizational set-up.
Unit will set-up permanent environmental management cell (EMC) for the effective implementation and monitoring of environmental management system. The unit will assign responsibility to officer from various disciplines and cadres to perform and co- ordinate the activities concerned with management and implementation of environmental control measures. The environmental management cell (EMC) propose to set-up by unit is given here below in Figure No. 10.1
FIGURE NO. 10.1ENVIRONMENTAL MANAGEMENT CELL
Director
EHS Manager
Executive EHS
Supervisor & Operators
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10.5 MITIGATIVE MEASURES
The probable impacts identified & the mitigation measures envisaged for protection of Environmental Components during the construction and operational phase are as tabulated in the table below:
Activity Environme-ntal
Impacts
Mitigation measures Remarks
Construction Phase:Erection of Plant Machineries
AirNoiseSocio Economic
Well maintained vehicles will be used.Metalled Road for Vehicle MovementWell maintained equipment will be utilized to prevent noise generation.Local labour will be hired for the work so that housing arrangement will be avoided.
Implementationresponsibility:Kemz Resibond
Operation Phase:Manufacturingof Products
AirLandWaterNoise
Ensure proper handling of all chemical by introducing spill control procedures.Ensure usages of PPE’s by workers.Strictly following the appropriate spill control procedures.The charging of the hazardous chemical will be done through very carefully. MSDS of Raw material & products will be displayed at storage & handling area.Water usage will be strictly by putting water meter plant wise. Monitored data will be analyzed and reviewed time to time.Contaminated solid waste will be sent to approve TSDF Facilities.Storage area will be designed in line with the factory Act requirement.
Implementationresponsibility:Kemz Resibond
Operation ofThermic Fluid Heater
• Air• Noise• Water
Ensure proper preventive maintenance of fuel firing system and optimization of air fuel ratio.Ensure proper maintenance of machinery to reduce noise levelAfter clean up of spillage ensure that disposed it properly.Provision of Adequate Stack Height. Ensure usage of Personal Protective Equipments.
Implementationresponsibility:Kemz Resibond
Operation ofCooling Tower
Air• Water
Ensure proper maintenance of machinery to reduce noise level
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• Noise Blow down is being sent in ETP provided within premises
Storage, Handling & Transportation of Raw materials and Products
Air• Water• Land
Chemical to be stored in accordance with the rules and regulations of the Safety Department. Separate storage area for solid/liquid raw materials. Install proper facilities to prevent rain/storm water contamination during the storage of solid raw materials.Ensure disposal of used drums, bags as per the rules/regulations.
Implementationresponsibility:Kemz Resibond
Transportation of all the raw materials,Finished products &Hazardous wastes.
AirWaterLand
Work will be given to Trained/Approved Transports for the transportation of the raw materials/products.
Ensure availability of MSDS of all the raw materials and finished products to the Off-site Emergency team.
Implementationresponsibility:Kemz Resibond
Development and maintenance of green belt
• Air• Land
Ensure development and maintenance of proper green belt as proposed.
Direct / Indirect Employment
• Socio Economicissue
Continue policy of local employment according to the skill and availability of the manpower
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10.6 IN-HOUSE LABORATORY
KEMZ RESIBOND has proposed to develop an in-house laboratory facility for plant performance and continuous up gradation and optimization of plant operation. List of major instruments available in laboratory are given below.
TABLE NO.10.1LIST OF MAJOR LABORATORY INSTRUMENTS
Sr.No.
Name of Equipment Quantity
1. Ford cup for viscosity testing in process 1 Nos.
2. Chilling bath lab scale for viscosity checking 1 Set
3. Mettler toledo microweighing balance for solid %, acid value & Other testing requirements
1 Set
4. Heating oven for checking solid content. 1 Set
5. Gelation timer for peak exotherm & geltime determination ofResin
1 Set
10.7 GREENBELT DEVELOPMENT
The unit is proposing green belt area of 1667 Sq.m. The purpose of a green belt around the plant site is to capture the fugitive emissions emanating from Plant operations, attenuate the noise generated and improve the aesthetics.
SELECTION OF TREES
The choice of trees species, suitable for plantation at the Industry Site, has been governed by the following guiding factors:
1. As per guidelines issued by Ministry of environment & Forests for greenbelt development.
2. As per the study carried out by our FAE in Ecological & Biodiversity.
3. The tree must be tolerant to all the pollutants present in the area.
4. The tree should be able to grow and thrive on soil of the areas, be evergreen, in habitat, having minimum of leaf fall.
5. The tree must be tall in peripheral curtain plantation and with large and spreading canopy in the primary and secondary attenuation zones.
6. The tree should possess extensive foliar area to provide maximum impinge surface for continued efficient adsorption and absorption of pollutants.
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7. The tree should be fast growing and indigenous.
8. The tree should maintain ecological, land and hydrological balance of the region.
Total plot area is 7551 Sq. meter. From that they had done planning for gardening and plantation for 1667 Sq. Meter.
The tree species selected for the plantation will be pollutant tolerant ,fast growing, wing firm, deep rooted and ever green.
The company will select pollutant tolerant plant species. For example, Asopalav, Neem Tree etc.
Budgetary expenditure for the greenbelt development has been depicted in the Table No. 10.2
TABLE NO. 10.2BUDGETARY EXPENDITURE FOR GBD
Sr.
No.
Parameter Capital Cost in
Rs.
Annual
recurring
Amount in Rs.
1 Site Development &
Plant/Seeds
1,10,000 --
2 Plant Care -- 1,44,000
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10.8 OCCUPATIONAL HEALTH AND SAFETY
Following measures will be adopted in the plant:
Inspection and maintenance of pollution control systems regularly.All safety measures such as safety appliances, training, safety awards, posters, slogans related to safety.The workers exposed to noisy sources area will be provided with ear muffs/plugs.Adequate facilities for drinking water and toilets in insufficient numbers will be provided to the employees.Fire proof aprons and necessary personnel protective appliances and equipment will be provided to the concerned personnel.Pre-medical examination and periodical examination will be carried out once in a year and records are maintained in Form No-32 & 33 as per GFR. PFT, LFT, Cardiac as well as Haematological & Urine test will be carried out during pre-placement and periodical examination.Isolation of drinking water & refreshment area including canteen etc. from the area of hazardous materials storage & handling Chemical Safety Booklet/Documents for all hazardous chemicals will be prepared and safety Booklet/Documents thus prepared has been made available well before commissioning of the project to all employees working with chemicals.Chemical safety booklet includes all necessary details like permissible exposure level/limit, Health effect, symptoms of toxic effects on human health, on-site first aid and necessary medical treatment guidelines etc.All required & necessary health manual & procedures for all activities will be developed and implemented. Such Manual & Procedures shall be made available to all concern employees.Preparation & implementation of Emergency action plan including on-site & off-site emergency management plan. Strict Prohibition of match box, lighters, clothes having potential of static charges as well as smoking in plant & storage area.Regular safety audit will be planned and necessary improvement will be taken as suggested by auditor.Properly designed & designated storage area and provision of good handling equipment and procedures will be ensured before commissioning plant. Mechanical handling system & arrangement wherever possible to avoid manual handling & so to avoid issues of MSDS. Wherever, automatic system is not possible, adequate manual handling facilities like trolley & Crain to reduce the stress of pulling -pushing and lifting to prevent or minimize the chances of issues related with MSDS.Provision of ergonomic design of all facilities wherever possible (e.g. chairs, tables, working platforms, self and position & height of display screens & panel etc.) to prevent or minimize the chances of issues related with MSDS Management will provide all necessary PPEs, safety equipment/materials to ensure healthy & safe work conditions. Regular inspection for the safety procedures and use of PPEs & Safety equipment/material will be done by the management/safety officer. Necessary training programs & audit will be done on regular basis to prevent impacts of the operational activities on human health as well as to improve workplace condition & safe work system.
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10.9 EXPENDITURE ON ENVIRONMENTAL MATTERS
The Table No. 10.3 table gives the expenditure to be incurred by M/s. Kemz Resibond on environmental matters.
TABLE NO.10.3EXPENDITURE ON ENVIRONMENTAL MATTERS
Sr.No
System Approximate recurring cost
per annum(in Lacs)
Approximate capital cost
(Rs. In Lacs)
Basis for cost estimates
1 Air pollution control
0.36 2 The capital cost would include cost of providing adequate height of the stack, ladder and platform, Air Pollution Control Systems and recurring cost would include cost of monitoring of air environment.
2 Water pollution control
-- 8 Capital cost would include cost of ETP, Evaporation cost of Spray Drying etc. In capital cost civil work, mechanical work, Electrical work and piping work is included. Recurring cost is for operational phase.
3 Noise pollution monitoring
0.06 -- The recurring cost would include cost of noise monitoring.
4 Solid and hazardous waste management
0.18 3 Capital cost would include cost of providing storage space for hazardous waste and membership of TSDF Fee. Recurring cost would include cost of land filling and transportation.
5 Environment monitoring and management
0.6 -- The recurring cost would be incurred on hiring of consultants and payment of various statutory fees to regulatory agencies.
6 Green belt 1.44 1.10 Development of Greenbelt including Gardening and Plantation.
7 Occupational health (OHC)
0.64 -- Occupational health check up of Employees and workers
Total 3.28 14.10
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10.10 CONCEPT OF WASTE MINIMIZATION, RECYCLE / REUSE / RECOVER TECHNIQUES, ENERGY CONSERVATION AND NATURAL RESOURCES CONSERVATION.
WASTE MINIMIZATION, RECYCLE /REUSE / RECOVER TECHNIQUES:
Unit shall to do moping in their unit instead of washing of water.Unit should try to minimize the excess raw material in batch, so it will reduces the unreacted raw material in effluent generation. Ultimately, it will reduce the concentration of effluent.Unit shall provide fix pipeline in their unit to minimize the leakages.Good House Keeping: Proper housekeeping practices make the system easier and less costly.Roof water harvesting system shall be adopted to reduce the fresh water requirement.Cleaner production technology may be adopted for the resource conservation and pollution control.
Cleaner production practices Process vessels:
Liquid raw material will be charged by pumping and closed loops and dosing will be done by metering system to avoid odour.Double mechanical seals will be provided to the process vessels having agitator for reduction of odour and leakages.
Storage tanks
Storage tanks for products as well as raw materials will be fitted with appropriate control devices to avoid possible odours / leakages.
House keeping:
Keep work areas clean.Keep exits and entrances clear.Use proper waste collection containers.Cleanup spills and leaks off’s any type quickly and properly.Follow up preventive predictive maintenance.
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ENERGY CONSERVATION:
Energy Conservation and Energy Efficiency are separate, but related concepts. Energy conservation is achieved when growth of energy consumption is reduced, measured in physical terms. Energy Conservation can, therefore, be the result of several processes or developments, such as productivity increase or technological progress. On the other hand Energy efficiency is achieved when energy intensity in a specific product, process or area of production or consumption is reduced without affecting output, consumption or comfort levels. Promotion of energy efficiency will contribute to energy conservation and is therefore an integral part of energy conservation promotional policies.
Energy efficiency means using less energy to perform the same function. Various measures taken will be as follows:
First step to conserve energy is to identify source of energy utilization.
Variable frequency drives (VFD) in pumps, whenever required is provided to save energy.
Use of low loss transformer instead of conventional transformer.
As far as possible the unit is planning to use solar street lights in the factory premises which is the renewable energy.
Proper air to fuel ratio is maintained for the maximum efficiency of thermic fluid heater.
Good insulation practice has been adopted to prevent heat losses.
Regular cleaning to the lamps and fixtures is done to get better illumination in the plant.
To avoid loss of precious quantum of energy, regular maintenance/ servicing is provided to all the equipments.
Unit is planning to conduct energy audit regularly as a tool for monitoring purpose.
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REUSE / RECYCLE:
Used oil from the plant & machineries is reused as a lubricant within plant and excess, if any is sold to authorize recyclers.
GOOD HOUSEKEEPING:
Good housekeeping means changing existing practices or introducing new ways of operating and maintaining equipment. Proper good housekeeping can prevent accidents, spillages and leakages, raw material & product loses. For Good housekeeping following practices are adopted.
All the materials are stored in compatible group.
All pits, sumps are properly covered or securely fenced.
Appropriate tools are provided for handling of all the materials.
Regular training is given to all workforces.
All the passages, floors and stairways are maintained in good condition. The systemis made available to deal with any spillage at the plant. Sufficient disposable bins are clearly marked and these are suitably located in the plant.
In the plant, precaution and instructions are displayed at strategic locations. Proper working instructions are given to all the workers in factory.
Roads/walkway within the plant is maintained neat and clean. Walkways are clearly marked and free from obstructions.
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CHAPTER 11
SUMMARY OF ENV. IMPACTS & CONCLUSION
11.1 INTRODUCTION
The environmental impacts of projects or actions generally encompass a broad range of impact from Air and Noise pollution to affect on employment and neighborhood as well as on social structure. All of these impacts vary in magnitude as well as in their beneficial or adverse classification. As a result, a natural question arises as to what is the “collective” or “overall” environmental impact of the project or action taken. Is the project beneficial or is it adverse? To answer such a question requires a comparison of these impacts and to some extent subjective evaluation of those impacts which are more important than others.
Kemz Resibond Private Limited.is a proposed unit intend to manufacture various resins Survey No:84/1,84/2,Village: Fofadiya, Tal: Dabhoi, Dist: Vadodara-391210.
The unit intends to manufacture Synthetic Organic Resins viz. Unsaturated Polyester Resin, AlkydResin, Epoxy Resin, Saturated Polyester Resin, VinylEster Resins, total to the tune of 1250 MT/ Month.
In order to assess the potential environmental impacts arising due to proposed project, the promoter has assigned the work of EIA to M/s. Entech Laboratories, Ahmedabad (for collecting the information on existing environmental conditions and assess the impacts on environment due to proposed project expansion and suggest the environmental safeguards and mitigation measures).
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11.2 SALIENT FEATURES OF THE PROJECT
Sr. No Contents Details1 Name of the Project: M/s. Kemz Resibond Private Limited
SurveyNo:84/1,84/2,Village:Fofadiya, Tal:Dabhoi,Dist:Vadodara-391210
2 Details of Applicant Ms. Ankita Agrawal(Director)
3 Status Kemz Resibond Private Limited. is a proposed unit intend to manufacture various resins at Survey No:84/1,84/2, Village: Fofadiya, Tal: Dabhoi, Dist: Vadodara-391210.
For this the unit has applied for obtaining Environment Clearance from SEIAA-Gujarat.
CTE is also granted for the same from GPCB.4 Total Plot area
( sq. meter)Proposed: 7551.00 Sq. m.
5 Capital Investment of theProject, Rs. in Crores
Proposed: 4.7238 crores
6 Capital cost for EMP, Rs.in Lakhs 14.1 Lacs
7Recurring cost for EMP,Rs. in Lakhs 12.25 Lacs
8 Employment opportunity Proposed: 20
9 Green belt Development Proposed: 1667 Sq. m.
10 Pollution control measures adoptedEffluent disposal Domestic Wastewater is 1.2 KL/day will be
disposed off through Soak Pit/Septic Tank System.Total Industrial Effluent of 3.5 KL/day will be collected neutralized in the ETP and then evaporated.
Flue gas emission control Adequate stack height will be provide.
Stack monitoring facilities for the periodic monitoring of the stack to verify the compliance of the stipulated norms.
Process gas emissioncontrol
There will be no process gas emission from the process as all process will be done in closed vessels with close circuit system.
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Fugitive emission control Unit will provide the scrubber with blender due to any rarely circumstances if acid fumes will generate.
Hazardous waste management
All the hazardous waste will be collected, stored, handled, transported and disposed as per the Hazardous Waste (Management, Handling and Transboundary Movement) Rules, 2016, amended time to time etc. are major Act/rules/notification applicable to industry.
11Expenditure for CSR & CERactivities
Rs. 9.5 Lacs
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Environment Impact Assessment as detailed in previous chapter can now be concise to impact statement given below.
11.3 AIR ENVIRONMENT
Meteorological data collected during the study period March–April–May 2019 confirms that climatic Status of the study area is consistent with the regional meteorology.
Average concentration of ambient air quality parameters such as PM10, PM 2.5, SO2, NOxin the surrounding study area are well within the permissible limits as prescribed in the National Ambient Air Quality (NAAQ) Standards for respective residential rural areas and industrial areas.
Further, it has may be noted that the impacts due to utility operations would be negligible as the LDO will be used as fuel. Hence, there would not be any major impacts due to emission. Adequate stack height with stack monitoring facilities will be provided. There are no any type of major process gas emissions.
Evaluated GLCs due to the proposed air pollution load. When added to the monitored existing ambient air quality, provides the expected ambient air quality when the fuel quantity will increase in proposed utility and the same indicates that expected AAQ are well within the permissible limit of National Ambient Air Quality Standards for residential rural areas as well as industrial areas.
It is concluded from the above that there will be a minor impact on the AAQ of the surrounding environment due to operation of the proposed expansion project.
11.4 WATER ENVIRONMENT
M/s. Kemz Resibond is a proposed unit and the source of water for proposed project will be from Bore-well.
The quality of the water was tested at eight locations in the study area. The ground water norms were compared to IS: 10500 (1991) for evaluation. The Industry generates process effluent apart from, Cooling Tower blow down and domestic effluent.
Wastewater Generation & Disposal:
Total wastewater generation will be 4.7 KLPD. Domestic Wastewater is 1.2 KL/day will be disposed of through Soak Pit/Septic Tank System.Total Industrial Effluent to the tune of 3.5 KL/day will be collected neutralized in the ETP and then evaporated.
Thus, it can be concluded that negligible impact on surrounding water environment is caused. Further, it is emphasized that all precautionary measures have to be strictly adhered as mentioned in the Environmental Management Plan given in Chapter 10, to maintain ground water quality within norms in the future.
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11.5 NOISE ENVIRONMENT
Base line data indicates that noise levels in the study area are not on higher sides. Noise level in and around plant site were measured. Measured noise levels within premises indicate that overall noise levels are within the Damage Risk Criteria. The company will provide ear-protecting devices/ earplugs for working personnel exposed to high noise level. It can be concluded that there will be no impact on the noise level of the surrounding environment.
11.6 HAZARDOUS WASTES
As per the Hazardous Waste (Management & Handling) Amendment Rules, 2016, all necessary control steps for each type of Hazardous Wastes generated from the proposed project will be taken. Therefore, no impact of hazardous wastes generation on surrounding soil environment is anticipated.
11.7 ECOLOGY
The proposed project will be carried out on land without cutting of any trees. Also, the project site is located in non-agricultural land devoid of any permanent eco-system. So, it does not alter the crop pattern and natural vegetation of the surrounding area. Due to the safe control technology of air pollutants, liquid effluents and solid/hazardous wastes disposal, no impact on the surrounding ecology is anticipated.
11.8 SOCIO - ECONOMIC ENVIRONMENT
The proposed project will generate direct employment 20 persons. The indirect employment will be generated by way of transportation, shopkeepers and other casual employment. Implementation of this plant will also reduce production loss due to shortage of power.
Thus, the proposed project will have significant positive impacts on the employment pattern of the study area.
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11.9 LAND USE
Source emission, wastewater and hazardous waste generation from any project activity affects the soil environment.
Soil samples have been collected from 8 locations to ascertain its physical and chemical characteristics within study area. Physical parameter suggested that type of soil within study area is black cotton.
The plot is non a gricultural land and industrial activity will be c ar r ie d out for resin manufacturing. There are no ecosensitive areas such as forest, national park, wildlife sanctuary, biosphere reserves and wildlife corridors etc. located within 10km radius of project area.
The impact due to air causes direct/indirect effect on soil. The emissions of Particulate Matter during operation will be effectively controlled. There will be practically no effect on the soil quality due to air emissions.
Domestic effluent will be discharged to soak pit and septic tank system. Wastewater generated from the Industrial activity will be treated in Effluent Treatment Plant and then evaporated. The Hazardous Solid Waste will be disposed to TSDF site.
As per the Hazardous Waste (Management & Handling) Amendment Rules, 2016, all necessary control steps for each type of Hazardous Wastes generated will be taken for the proposed project.
Hence, due to the proposed project the, land use pattern; land cover and topography of the area will not be changed
11.10 CONCLUSION
It can be concluded on a positive note that due to the adequate provision and efficient operation of Environmental Management Systems and after the implementation of the proposed mitigation measures and environmental management plans, the proposed project activities during the construction and operation phase would have manageable & largely have reversible impacts on the environment, and on balance the project would be beneficial to surrounding communities and the region.
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CHAPTER 12
DISCLOSURE OF CONSULTANT
Declaration By Consultant Organization Preparing EIA Report:
Project proponent M/s. Kemz Resibond Private Limited.Project Site Survey No. 84/1, 84/2, Vill. Fofadiya,
Taluka: Dabhoi, Dist: Vadodara Gujarat.Type of project Resin manufacturing unit
Category of project as perEIA notification
5(f) – B- Synthetic Organic Chemicals
EIA Consultant Organization
Entech Laboratories
Contact Information Office: 202, Trade Square, Opp. Torrent Power House,Dharmnagar, Sabarmati, Ahmedabad-380005, Gujarat, India, Phone: 079-2757 2758
Phone 9824012121E-mail [email protected] Court Order SCA No. 2728 of 2018 (Please see Annexure A)
Laboratory engaged in the EIA Project:Laboratory Organization
Entech LaboratoriesNABL Accredited Laboratory33,34 Kushal Estate, Sanket Industrial Estate, Village -Moraiya, Taluka Sanand, Ahmedabad 382213 Gujarat, India
Declaration by the head of the Consultant Organization
I, Prakash Vaghela, hereby confirm that the experts prepared the EIA of “Kemz Resibond Private Limited.” I also confirm that I shall be fully accountable for any misleading information mentioned in this statement.
Name:Mr. Prakash VaghelaDesignation:CEOConsulting Organization Name:Entech LaboratoriesAddress: 202, Trade Square, Opp. Torrent Power House, Dharmnagar, Sabarmati,Ahmedabad-380005Date: 28-11-2019
Declaration by NABL Approved Laboratory for Analysis(1) NABL Accreditation certificate by En-Tech Laboratories, Sanand Ahmedabad annexed as Annexure-B.
Entech Laboratories
Draft EIA report of M/s. Kemz Resibond Private Limited 204
Disclosures of Consultants
I, hereby, certify that I was part of the EIA team in the following expertise that developed the EIAof M/s. Kemz Resibond Private Limited
EIA Co-Ordinator:
The name of EIA co-ordinator is Mr. Prakash Vaghela. In support Team Members along with their role in the project is given as per following:
EIA Team Member
Qualification with Experience
in Area
Sign Involvement in the Work of EIA
Mr. Prakash Vaghela
B.E. (Environment), PGDIS, LLB
Risk Assessment, Site visit and prediction of impact on land use pattern, identified source of generation of Hazardous Waste and its disposal methods, Mitigation measures for management of hazardous waste, identified waste generation sources and preparing environmental management plan, identification of impact & mitigation measures and EIA report preparation
Mr. Dipak Jadav
B. Sc. Chemistry Water pollution prevention, control and prediction of impacts- Identification of surface water sampling stations, water requirement/demand calculation, identification of impacts and relevant mitigation measures, assisting in preparation of management plan and report writing
Mr. Joshua Anand
Master of Technology in Geomatics, Bachelor of Technology in Civil (Water Resource Engineering)
Development of land use map of study area, prepare land use classification and prediction of impact on land use pattern
Mr. Haresh Makwana
B.Sc. PDIS Meteorology, air quality modelling and prediction- Data collection, assistance in report preparation for AAQM modelling and water sample monitoring for EIA with help of external agency
Entech Laboratories
Draft EIA report of M/s. Kemz Resibond Private Limited 205
Mr. MaksoodMansoori
B.E. (Mechanical)
Site visit, understanding and representing ground water conditions, identification of impacts, suggestion of mitigation measures and contribution of EIA documentation
Mr. Mahesh Solanki
B.E. (Chemical) Risk assessment and hazard management - Assistance in identification of impacts & mitigation measures, safety during construction and operational phase and report writing.
Mr. Anant Patel MSC (Environment Biotechnology)
Identification of impacts & mitigation measures for Ecology and biodiversity, flora and fauna and contribution in EIA documentation with help of external agency
Mr. Jigar H Joshi
B.E Electrical, PDIS, PDIETM
Identified potential hazards of proposed activities; Consequence analysis and Suggestion of mitigative and safety measures for Hazards identified.
Ms. Riddhi Soni B.E Environment Monitoring and identification of sampling location and evaluation of results and EIA report preparation with help of external agency.
Mrs. Viral Chauhan
B.A. , M.A. Sociology
Site visit, evaluation of socieo-economic status of study area, social economic issues arise due to proposed project and contribution in EIA documentation with help of external agency
ANNEXURE-1
CTE FROM GPCB
NET Payment Receipt
Address : , Survey No:84/1, 84/2, Vill: Fofaliya, Tal: Dabhoi, Dist: Vadodara, Fofaliya, Vadodara Pin : 391210
Bank Details
Transaction No
Application: 163817(ECC)-dd/MM/yyyy
ICO-1782188177
QICO7900735609
PCB ID: 72906-Kemz Resibond Pvt. Ltd
Payment Id 231798
Payment Date 23/08/2019
Date : 26/08/2019
Paid Amount 15000
Status Success
Remarks Success
Type
Referance No
MIS Date
163817 (Environment Clearance)
EC -ECC-CCA
-
ANNEXURE-2
NA CERTIFICATE
ANNEXURE-3Undertaking for complying the three conditions, Water
consumption <25 m3/Day, Fuel Consumption < 25 TPD, not covered under category of MAH
ANNEXURE-4
LAND POSSESSION DOCUMENTS (LPD)
ANNEXURE-5
CGWA APPLICATION COPY
ANNEXURE-6Undertaking for underground drainage connection will not be taken and will be
achieve Zero Liquid Discharge
ANNEXURE-7
NOC LETTER FROM BEIL INFRASTRUCTURE LIMITED (FOR
TSDF & CHWIF)
ANNEXURE-8
MSDS OF RAW MATERIALS & PRODUCTS
File
No:
PLC
/329
28 O
ctob
er 20
02
NA
TIO
NA
L IN
DU
STR
IAL
CH
EM
ICA
LS
NO
TIF
ICA
TIO
N A
ND
ASS
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(NIC
NA
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FULL
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4949
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sion
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and
A
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989
(Cw
lth)
(th
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and
Reg
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his
legi
slat
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is a
n A
ct o
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of A
ustr
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he N
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dm
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lic h
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occ
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and
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he E
nvir
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For
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78(1
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Act
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ull P
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Occ
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Com
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or +
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.
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and
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m th
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web
site
or
avai
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req
uest
, fre
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by
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or r
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and
enq
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leas
e co
nta
ct th
e N
ICN
AS
Ad
min
istr
atio
n C
oor
dina
tor
at:
Str
eet
Ad
dres
s:
3
34 -
336
Ill
awar
ra R
oad
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RR
ICK
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LE
NSW
22
04, A
UST
RA
LIA
. P
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ddre
ss:
G
PO
Box
58
, SY
DN
EY
NSW
200
1, A
US
TR
AL
IA.
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+
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AX
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88
88.
Web
site
:
w
ww
.nic
nas.
gov
.au
Dire
ctor
C
hem
icals
Not
ifica
tion
and
Ass
essm
ent
TABL
E O
F C
ONT
ENT
S
FU
LL
PU
BL
IC R
EPO
RT
.....
......
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41.
APP
LIC
AN
T A
ND
NO
TIF
ICA
TIO
N D
ET
AIL
S..
......
.....
......
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.....
......
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......
.....
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......
.....
......
.....
.....
.42.
IDE
NT
ITY
OF
CH
EM
ICA
L...
......
.....
......
.....
......
.....
.....
......
.....
......
.....
.....
......
.....
......
.....
.....
......
.....
.....
....4
3.C
OM
POS
ITIO
N..
.....
......
.....
......
.....
.....
......
.....
......
.....
.....
......
.....
......
.....
.....
......
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......
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......
....
44.
INT
RO
DU
CT
ION
AN
D U
SE I
NFO
RM
AT
ION
......
......
.....
.....
......
.....
......
.....
.....
......
.....
.....
......
.....
......
...4
5.P
RO
CE
SS A
ND
RE
LE
ASE
IN
FOR
MA
TIO
N...
......
......
.....
.....
......
.....
......
.....
.....
......
.....
......
.....
.....
......
...5
5.1.
Dis
trib
utio
n, T
rans
port
and
Sto
rage
.....
.....
......
.....
......
.....
.....
......
.....
......
.....
.....
......
.....
......
.....
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.....
55.
2.O
pera
tion
Des
crip
tion.
......
.....
......
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......
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.....
......
.....
......
.....
.....
......
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......
.....
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......
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......
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..5
5.3.
Occ
upa
tiona
l exp
osu
re...
......
.....
.....
......
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......
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......
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......
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......
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......
......
....5
5.4.
Rel
ease
......
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......
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......
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......
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.....
......
.....
65.
5.D
ispo
sal.
.....
......
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..6
5.6.
Pub
lic
exp
osur
e...
......
.....
.....
......
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......
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......
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...6
6.P
HY
SIC
AL
AN
D C
HE
MIC
AL
PR
OP
ER
TIE
S...
.....
......
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......
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...6
7.T
OX
ICO
LO
GIC
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INV
EST
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TIO
NS
......
......
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...8
8.E
NV
IRO
NM
EN
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..8
9.1.
Env
iro
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t.....
......
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1.1.
Env
iro
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ent.
......
......
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......
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......
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......
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1.2.
Env
iro
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ffec
ts a
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......
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....8
9.1.
3.E
nvir
onm
ent –
ris
k c
hara
cter
isat
ion
......
.....
......
.....
......
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......
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......
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......
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....8
9.2.
Hum
an h
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......
......
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......
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......
89.
2.1.
Occ
upa
tiona
l hea
lth
and
safe
ty –
exp
osu
re a
sses
smen
t....
.....
......
.....
......
.....
.....
......
.....
......
.....
....8
9.2.
2.P
ubli
c he
alth
– e
xpo
sure
ass
essm
ent.
......
......
.....
......
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.....
......
.....
......
.....
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......
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......
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2.3.
Hum
an h
ealt
h -
effe
cts
asse
ssm
ent.
......
......
......
.....
......
.....
.....
......
.....
......
.....
.....
......
.....
.....
......
....9
9.2.
4.O
ccu
patio
nal h
ealt
h an
d sa
fety
– r
isk
char
acte
risa
tion
.....
......
.....
.....
......
.....
.....
......
.....
......
.....
....9
9.2.
5.P
ubli
c he
alth
– r
isk
char
acte
risa
tion
......
......
.....
.....
......
.....
......
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......
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......
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......
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....9
10.
CO
NC
LUS
ION
S .
.....
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.....
......
.....
......
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......
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....9
10.1
.H
azar
d c
lass
ific
atio
n...
......
.....
......
.....
......
.....
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......
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......
.....
.....
......
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......
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......
.910
.2.
Env
iro
nmen
tal
risk
ass
essm
ent.
.....
......
.....
......
.....
.....
......
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......
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......
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.....
......
.....
......
.....
.....
.....
910
.3.
Hum
an h
ealt
h ri
sk a
sses
smen
t.....
......
......
.....
.....
......
.....
......
.....
.....
......
.....
......
.....
.....
......
.....
......
.....
..9
10.3
.1.
Occ
upa
tiona
l hea
lth
and
safe
ty...
......
......
.....
......
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......
.....
.....
......
.....
......
.....
.....
......
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....9
10.3
.2.
Pub
lic
heal
th..
......
.....
......
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......
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......
.....
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.....
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.911
. M
AT
ER
IAL
SA
FET
Y D
AT
A S
HE
ET
.....
.....
......
.....
......
.....
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......
.....
......
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.....
......
.....
......
.....
.....
...9
11.1
.M
ater
ial
Safe
ty D
ata
She
et..
.....
......
.....
......
.....
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......
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.....
......
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.....
......
.....
.....
......
......
....9
11.2
.L
abel
......
.....
......
.....
.....
......
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1012
. R
EC
OM
ME
ND
AT
ION
S...
.....
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......
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......
.....
.....
......
.....
......
.....
.....
......
.....
......
.....
.....
......
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......
...10
12.1
.S
eco
ndar
y no
tifi
catio
n...
......
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......
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..10
13.
BIB
LIO
GR
APH
Y...
......
......
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......
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.....
.11
Oct
obe
r 20
02
NIC
NA
S
FU
LL P
UB
LIC
RE
PO
RT
: P
LC/3
29
Pag
e 3
of 1
0
FULL
PU
BLIC
RE
POR
T
4949
892
Satu
rate
d Po
lyes
ter R
esin
1.
AP
PL
ICA
NT
AN
D N
OT
IFIC
AT
ION
DE
TA
ILS
APP
LIC
ANT
(S)
T
he V
alsp
ar (A
ustr
alia
) C
orpo
rati
on P
ty L
imit
ed o
f 20
3 P
ower
Str
eet,
Gle
nden
nin
g, N
SW 2
761
.
NO
TIFI
CATI
ON C
ATE
GOR
Y
The
not
ifie
d p
oly
mer
mee
ts t
he P
LC
crit
eria
.
EX
EMPT
INFO
RM
ATI
ON (
SEC
TIO
N 7
5O
F TH
E A
CT)
D
ata
item
s an
d de
tails
cla
imed
ex
emp
t fro
m p
ubl
icat
ion:
C
hem
ical
na
me
and
sy
nony
ms,
m
olec
ular
for
mul
a,
poly
mer
co
nst
itue
nts,
w
eigh
t pe
rcen
tage
of
po
lym
er c
onst
ituen
ts a
nd re
sidu
al m
ono
mer
s.
VA
RIAT
ION
OF
DA
TA R
EQU
IREM
ENT
S (S
ECTI
ON
24
OF
THE
ACT
)
No
var
iati
on t
o th
e sc
hed
ule
of d
ata
requ
irem
ents
is
clai
med
.
PRE
VIO
US N
OTI
FICA
TION
IN A
UST
RALI
A B
Y A
PPLI
CAN
T(S)
N
one
NO
TIFI
CATI
ON IN
OTH
ER C
OUN
TRIE
S
No
ne
2.
IDE
NT
ITY
OF
CH
EM
ICA
L
MA
RKET
ING
NA
ME
(S)
49
498
92 S
atu
rate
d P
olye
ster
Res
in
MET
HO
DS O
F D
ETEC
TION
AN
D D
ETER
MIN
ATI
ON
AN
ALY
TICA
LM
ETH
OD
IR
Rem
arks
T
he n
otif
ier
has
pro
vide
d an
IR
spe
ctru
m f
or t
he n
otif
ied
poly
mer
.
3.
CO
MP
OS
ITIO
N
PURI
TY
Hig
h
HA
ZAR
DOU
S IM
PUR
ITIE
SN
one
RES
IDU
AL
MO
NOM
ERS
All
resi
dual
mo
nom
ers
are
bel
ow t
he r
elev
ant
cut-
offs
for
cla
ssifi
cati
on o
f th
e n
otif
ied
poly
mer
as
a ha
zard
ous
sub
stan
ce (
NO
HSC
, 19
99a)
.
4.
INT
RO
DU
CT
ION
AN
D U
SE I
NF
OR
MA
TIO
N
MO
DE O
F IN
TRO
DU
CTIO
N O
F N
OTI
FIED
PO
LYM
ER (1
00%
) O
VER
NEX
T 5
YEA
RS
Oct
obe
r 20
02
NIC
NA
S
FU
LL P
UB
LIC
RE
PO
RT
: P
LC/3
29
Pag
e 4
of 1
0
T
he p
olym
er w
ill b
e m
anuf
actu
red
at t
he n
otif
ier’
s pl
ant i
n D
and
enon
g, V
ic.
MA
XIM
UM I
NTR
OD
UCT
ION
VO
LUM
E OF
NO
TIFI
ED P
OLY
MER
(10
0%)
OV
ER N
EXT
5 Y
EARS
Yea
r 1
2 3
4
5 T
onne
s21
2
1 21
21
2
1
USE
T
he n
otif
ied
po
lym
er is
a c
ompo
nent
of
indu
stri
al P
VC
pro
duct
s fo
r fl
oori
ng.
5.
PR
OC
ES
S A
ND
RE
LE
AS
E I
NF
OR
MA
TIO
N
5.1.
D
istr
ibut
ion
, Tra
nspo
rt a
nd S
tora
ge
IDEN
TITY
OF
MA
NUFA
CTU
RER/
REC
IPIE
NTS
The
no
tifie
d ch
emic
al
wil
l be
m
anuf
actu
red
at
the
not
ifie
r’s
plan
t in
D
ande
nong
, V
IC,
and
refo
rmu
late
d in
to P
VC
flo
orin
g at
Arm
stro
ng W
orld
Ind
ustr
ies,
in B
raes
ide,
VIC
.
TRA
NSP
ORTA
TIO
N A
ND P
ACK
AGIN
G
The
not
ifie
d po
lym
er w
ill
be p
acke
d in
itial
ly in
200
kg
stee
l co
ntai
ner
s. A
fter
cru
shin
g, i
t is
rep
ack
ed
into
25
kg h
essi
an b
ags
and
stor
ed a
t th
e m
anuf
actu
rer’
s si
te u
ntil
req
uire
d by
the
cust
om
er.
5.2.
O
per
atio
n D
escr
iptio
n
Poly
mer
Man
ufac
ture
The
pol
ymer
is
man
ufa
ctur
ed i
n a
bat
ch p
roce
ssin
g o
pera
tion
in a
n en
clo
sed
hea
ted
reac
tion
ves
sel
fitte
d w
ith
stir
ring
and
an
ove
rhea
d co
nden
ser
syst
em u
nder
neg
ativ
e pr
essu
re.
Whe
n th
e re
acti
on i
sco
mpl
ete,
th
e re
actio
n ve
ssel
is
cool
ed t
o a
roun
d 1
50-1
80º
C a
nd
the
liqu
id p
olye
ster
is
dis
char
ged
into
20
5 li
tre
open
hea
ded
dru
ms
and
allo
wed
to
coo
l. D
urin
g co
olin
g th
e po
lyes
ter
soli
difi
es (
200
kg
). A
bat
ch o
f res
in is
app
roxi
mat
ely
7 to
nnes
. C
rush
ing
Pro
cess
Afte
r m
anuf
actu
re,
the
notif
ied
poly
mer
is
tran
spor
ted
as 2
00 k
g so
lid
lum
ps i
n op
en h
eade
d st
eel
dru
ms
to a
cru
shin
g c
ontr
acto
r’s
site
. T
he
poly
mer
res
in i
s cr
ush
ed i
nto
lum
ps o
f 25
to
10
0 m
m
diam
eter
and
pac
ked
into
25
kg h
essi
an s
acks
. P
rodu
ct M
anuf
actu
reT
he n
otif
ied
poly
mer
is
wei
ghe
d in
to a
co
ntai
ner
and
ad
ded
to t
he m
ixer
with
oth
er in
gre
dien
ts.
The
ingr
edie
nts
are
blen
ded
in a
Ban
bury
typ
e cl
ose
d m
ixer
the
n fo
rmed
via
cal
ende
r ro
lls.
The
no
tifie
dpo
lym
er c
ompr
ises
abo
ut 1
0% o
f th
e fi
nish
ed p
rodu
ct.
5.3.
O
ccu
patio
nal e
xpos
ure
Nu
mbe
r a
nd C
ateg
ory
of W
ork
ers
Ca
tego
ry o
f Wor
ker
Num
ber
Exp
osur
e D
ura
tion
E
xpos
ure
Fre
quen
cy
O
per
ato
r –
bat
ch p
roce
ssin
g
4
1-2
hou
rs
3 pe
r ye
ar
Q
C T
estin
g 1
1
-2 h
ours
3
per
year
Supe
rvis
ion
1
1
-2 h
ours
3
per
year
Dri
ver
s –
Tru
ck d
eliv
erie
s 1
Cru
shin
g pl
ant o
pera
tors
4-6
hou
rs
3 pe
r ye
ar
Exp
osur
e D
eta
ils
Poly
mer
Man
ufac
ture
Dur
ing
load
ing
of
ingr
edie
nts,
the
mix
er v
esse
l is
un
der
nega
tive
pre
ssur
e to
min
imis
e ex
posu
re t
o th
e po
lym
er i
ngre
dien
ts.
The
not
ifie
d p
oly
mer
is s
olid
at
the
conc
lusi
on o
f th
e m
anuf
actu
ring
pro
cess
. N
o cl
ean
ing
of
the
reac
tor
vess
el o
r fe
ed l
ines
occ
urs
as t
he r
esid
ual
is i
ncor
pora
ted
into
the
fol
low
ing
batc
h. D
erm
al e
xpos
ure
to th
e no
tifi
ed p
olym
er d
ue to
spi
lls o
r spl
ash
es m
ay o
ccur
du
ring
dis
char
ge o
f th
e p
olym
er f
rom
the
reac
tor
vess
el.
Cru
shin
g P
roce
ssA
s th
e p
olym
er i
s so
lid,
exp
osur
e w
ill b
e li
mit
ed.
Som
e ex
pos
ure
may
occ
ur t
o du
sts
crea
ted
dur
ing
crus
hing
.
Oct
obe
r 20
02
NIC
NA
S
FU
LL P
UB
LIC
RE
PO
RT
: P
LC/3
29
Pag
e 5
of 1
0
Pro
duct
Man
ufac
ture
The
not
ifie
d po
lym
er i
s so
lid
whe
n ad
ded
to
the
mix
er,
and
is e
xtru
ded
bou
nd i
n s
heet
s of
vin
yl
floo
rin
g.
Som
e po
tent
ial e
xist
s fo
r ex
posu
re to
du
st.
5.4.
R
elea
se
REL
EASE
OF
CH
EMIC
AL A
T S
ITE
Pol
ymer
Pro
duc
tion
Sit
eT
he p
rodu
ctio
n ve
ssel
s h
ave
ove
rhea
d co
nden
sers
ins
tall
ed. I
t is
esti
mat
ed t
hat
appr
oxi
mat
ely
348
kg
of d
istil
late
wil
l be
colle
cted
per
pro
duct
ion
batc
h (7
ton
nes
of
resi
n), t
his
dist
illa
te m
ay c
onta
in tr
ace
amou
nts
of t
he n
otif
ied
pol
ymer
and
its
mon
om
ers.
Th
e co
nden
sers
will
als
o co
llec
t an
y du
st g
ener
ated
in
the
mix
ing
proc
ess
thus
gen
erat
ing
a sm
all
amou
nt o
f so
lid
was
te.
Sin
ce t
he n
otif
ied
poly
mer
wil
l be
com
pat
ible
wit
h th
e n
ext b
atch
of
mat
eria
l pr
odu
ced,
the
equi
pmen
t is
not
cle
aned
aft
er t
he p
oly
mer
is
pro
duce
d. S
ome
was
te n
otif
ied
poly
mer
may
be
gene
rate
d d
ue t
o sp
ills
dur
ing
the
prod
ucti
on p
roce
ss,
part
icul
arly
dur
ing
dru
m fi
llin
g.
Cru
shin
g S
iteT
he e
mpt
y d
rum
s, w
hich
con
tain
ed th
e po
lym
er r
esin
, m
ay c
onta
in t
race
am
ount
s o
f po
lym
er.
Dur
ing
the
crus
hing
pro
cess
(o
ff-s
ite)
ther
e is
the
pos
sibi
lity
of
the
gene
ratio
n of
pol
ymer
du
st o
r fi
ne
poly
mer
sha
rds.
N
o in
dica
tion
has
bee
n gi
ven
as t
o th
e w
aste
man
agem
ent
at t
he c
rush
ing
sit
e, b
ut
pres
umab
ly t
here
wil
l be
a d
ust
su
ppre
ssio
n sy
stem
in-
pla
ce,
whi
ch m
ay o
nly
be
fine
wat
er s
pray
s. I
fth
is i
s so
, the
n th
e du
st/s
hard
s w
ill
be p
reve
nted
fro
m l
eavi
ng t
he s
ite
and
wil
l th
en b
e co
llec
ted
and
st
ore
d fo
r di
spo
sal.
REL
EASE
OF
CH
EMIC
AL F
RO
M U
SE
Gen
eral
ly a
ny s
pilt
po
lym
er r
esin
will
be
swep
t up
an
d, i
f n
ot c
onta
min
ated
, ad
ded
to t
he p
roce
ss.
Dur
ing
the
pro
duct
ion
of
the
floo
ring
, th
e no
tifi
ed p
olym
er w
ill o
nly
be
pres
ent
in s
olid
was
tes
(ie
floo
rin
g o
ff-c
uts)
.
The
em
pty
hess
ian
bags
may
hav
e tr
ace
amo
unts
of
pol
ymer
res
in i
n th
e fo
rm o
f du
st.
5.5.
D
isp
osal
Poly
mer
Pro
duc
tion
Site
The
dis
tilla
te a
nd
othe
r aq
ueou
s w
aste
s w
ill
be
sent
to
a th
erm
al o
xidi
ser
wh
ere
they
wil
l be
bur
nt
pro
duci
ng o
xide
s o
f car
bon
and
wat
er v
apou
r.
Any
so
lid w
aste
s ge
nera
ted
duri
ng
pro
duct
ion
wil
l be
col
lect
ed a
nd s
ent
to l
andf
ill.
Ann
ual
ly t
his
will
eq
uate
to a
ppro
xim
atel
y 24
kg.
Cru
shin
g S
iteT
he e
mpt
y dr
um
s, a
nd
any
trac
e p
olym
er,
will
eith
er b
e re
fille
d w
ith p
oly
mer
res
in o
r w
ill g
o to
la
ndfi
ll.
Any
co
llect
ed d
ust
or s
har
ds a
re li
kely
to
be
sent
to l
andf
ill.
Flo
orin
g M
anuf
actu
rer
Any
con
tam
inat
ed s
plit
resi
n an
d f
loor
ing
off-
cuts
will
be
sen
t to
lan
dfil
l. T
he
emp
ty h
essi
an w
ill b
e se
nt t
o la
ndf
ill.
5.6.
P
ubl
ic e
xpo
sure
Publ
ic e
xpo
sure
to
the
noti
fied
che
mic
al i
s o
nly
likel
y to
occ
ur
if th
ere
is a
sp
ill o
f th
e so
lid
mat
eria
l du
rin
g tr
ansp
ort
to a
nd f
rom
the
cru
shin
g pl
ant,
or
duri
ng
tran
spor
t to
the
cus
tom
er s
ite.
T
he p
ublic
m
ay h
ave
low
-lev
el c
onta
ct w
ith p
rodu
cts
mad
e fr
om t
he re
sin.
6.
PH
YS
ICA
L A
ND
CH
EM
ICA
L P
RO
PE
RT
IES
Oct
obe
r 20
02
NIC
NA
S
FU
LL P
UB
LIC
RE
PO
RT
: P
LC/3
29
Pag
e 6
of 1
0
App
eara
nce
at
20o C
and
101
.3 k
Pa
Cle
ar, m
oder
atel
y ye
llow
gra
nule
s
Mel
ting
Po
int
> 9
0o C
Den
sity
13
60 k
g/m
3
Sol
utio
n/E
xtra
ctio
n B
ehav
iou
r 7.
9 g/
L a
t 20
o C
R
emar
ks
One
(1
) g
of
the
gro
und
pol
ymer
res
in w
as a
dde
d to
10
0 m
L o
f d
eio
nise
d w
ater
an
d st
irre
d w
ith
a m
agne
tic
stir
rer f
or 2
4 ho
urs
. A
fter
thi
s th
e m
ixtu
re w
as f
ilter
ed
to r
emov
e an
y so
lid
mat
eria
l an
d th
e re
sult
ant f
iltra
te w
as d
ried
and
the
res
ulta
nt
mat
eria
l (t
he d
isso
lved
pol
ymer
resi
n) w
as w
eigh
ed.
Onl
y br
ief
det
ails
are
ava
ilab
le a
nd t
his
wo
uld
see
m t
o b
e a
very
hig
h s
olu
bilit
y fo
r a
larg
ely
hyd
roph
obi
c po
lym
er d
espi
te t
he p
rese
nce
of s
ome
carb
oxyl
ic a
cid
gro
ups.
Par
ticl
e S
ize
20-1
00 m
m d
iam
eter
R
emar
ks
P
arti
cle
size
ha
s be
en
dete
rmin
ed f
or
the
poly
mer
fo
llow
ing
crus
hin
g.
T
he
part
icle
s ar
e la
rge
and
not
insp
irab
le,
how
ever
, a
smal
l qu
antit
y o
f fi
ne p
artic
les
may
be
pro
duce
d.
Fla
mm
abi
lity
N
ot fl
amm
able
Exp
losi
ve
Pro
per
ties
N
ot e
xplo
sive
Hyd
roly
sis
as
a F
unct
ion
of p
H
Not
det
erm
ined
R
emar
ks
T
he
noti
fied
po
lym
er
cont
ains
es
ter
func
tion
alit
ies
that
co
uld
be e
xpec
ted
to
und
ergo
hyd
roly
sis
und
er e
xtre
me
pH
con
diti
ons.
How
ever
, in
the
env
iron
men
tal
pH r
ange
of 4
–9, s
igni
fica
nt h
ydro
lysi
s is
un
likel
y to
occ
ur.
Par
titi
on C
oeff
icie
nt (
n-o
ctan
ol/w
ater
) N
ot d
eter
min
ed
R
emar
ks
T
he
noti
fied
pol
ymer
is
rela
tive
ly s
olub
le,
thus
ind
icat
ing
it w
ill
part
itio
n in
to t
he
wat
er p
hase
(how
ever
see
com
men
ts a
bove
).
Ads
orpt
ion/
Des
orp
tion
N
ot d
eter
min
ed
R
emar
ks
T
he
notif
ied
poly
mer
is
like
ly t
o h
ave
som
e m
obil
ity i
n so
il du
e to
its
rel
ativ
e so
lubi
lity.
Dis
soci
ati
on C
onst
ant
Not
det
erm
ined
R
emar
ks
T
he
notif
ied
pol
ymer
co
ntai
ns c
arbo
xyli
c fu
ncti
onal
ities
, w
hich
are
exp
ecte
d to
ha
ve t
ypic
al a
cid
ity.
Oct
obe
r 20
02
NIC
NA
S
FU
LL P
UB
LIC
RE
PO
RT
: P
LC/3
29
Pag
e 7
of 1
0
7.
TO
XIC
OL
OG
ICA
L I
NV
EST
IGA
TIO
NS
No
Tox
icol
ogic
al d
ata
wer
e su
bmitt
ed.
Acc
ord
ing
to t
he M
SD
S, t
he a
cute
exp
osu
re t
o th
e po
lym
er m
ay c
ause
m
ild t
o m
oder
ate
irri
tati
on o
f th
e ey
es a
nd m
ild
irri
tatio
n of
the
sk
in.
Der
mat
itic
eff
ects
may
res
ult
from
pr
olo
nged
ex
posu
re.
Vap
ours
fro
m t
he h
eate
d re
sin
may
be
irri
tatin
g to
the
res
pira
tory
tra
ct.
Ing
estio
n m
ay
caus
e ga
stro
-int
esti
nal d
istu
rban
ces
and
be s
ligh
tly
irri
tati
ng to
the
muc
ous
mem
bran
es.
8.
EN
VIR
ON
ME
NT
No
eco
toxi
colo
gica
l da
ta w
ere
subm
itte
d.
9.
RIS
K A
SSE
SSM
EN
T
9.1.
E
nvir
onm
ent
9.1.
1.
Env
iron
men
t – e
xpos
ure
asse
ssm
ent
Rel
ease
It i
s an
ticip
ated
tha
t ve
ry l
ittle
of
the
not
ifie
d po
lym
er w
ill
be r
elea
sed
to t
he e
nvir
onm
ent (
see
sect
ion
5.4
). T
he m
ajo
rity
of
the
notif
ied
poly
mer
will
be
inco
rpor
ated
int
o flo
orin
g m
ater
ials
, w
hich
at
the
end
of t
hei
r us
eful
liv
es w
ill
be d
ispo
sed
of
to l
andf
ill.
Onc
e in
corp
ora
ted
in t
he
floo
rin
g m
ater
ial t
he n
otif
ied
po
lym
er w
ill b
e co
ntai
ned
in a
n in
ert
mat
rix
.
Fat
e
In l
andf
ill,
it i
s ex
pect
ed t
hat
the
was
te n
eat
pol
ymer
fro
m t
he t
wo
pro
duct
ion
stag
es m
ay b
e m
obil
e, d
ue it
s re
lati
vely
hig
h w
ater
sol
ubil
ity,
bu
t at
very
low
con
cent
ratio
ns.
The
pol
ymer
wil
l ev
entu
ally
deg
rade
thr
oug
h bi
otic
and
abi
otic
pro
cess
es t
o gi
ve w
ater
vap
our
and
oxi
des
of
carb
on.
The
po
lym
er w
ill n
ot b
e re
leas
ed f
rom
th
e fl
oori
ng m
ater
ials
, bu
t ov
er t
ime
the
floo
ring
m
ater
ials
will
slo
wly
deg
rade
due
to b
ioti
c an
d a
bio
tic p
roce
sses
.
9.1.
2.
Env
iron
men
t – e
ffec
ts a
sses
smen
t
S
ome
of t
he le
acha
te fr
om th
e la
ndfi
ll m
ay r
each
the
aqua
tic
com
par
tmen
t bu
t th
is w
ill
be a
t ve
ry
low
con
cent
rati
ons
and
in a
ver
y di
ffus
e m
anne
r. T
her
e ar
e no
eco
toxi
city
dat
a, h
owev
er, i
t is
un
like
ly th
at t
he p
olym
er w
ill b
e to
xic
to a
quat
ic o
rgan
ism
s at
the
lev
els
at w
hich
it m
ay e
nte
r th
ew
ater
bod
ies.
The
pol
ymer
is
not
expe
cted
to c
ross
bio
logi
cal
mem
bra
nes
due
to i
ts h
igh
mo
lecu
lar
wei
ght,
an
d as
su
ch s
houl
d no
t bio
accu
mul
ate
(Co
nnel
l, 19
90)
.
9.1.
3.
Env
iron
men
t – r
isk
ch
arac
teri
sati
on
T
akin
g in
to a
ccou
nt th
e us
e an
d re
leas
e p
atte
rns,
as
spec
ifie
d in
the
not
ific
atio
n, t
he r
isk
pose
d by
the
not
ifie
d p
oly
mer
is e
xpec
ted
to b
e lo
w.
9.2.
H
um
an h
ealt
h
9.2.
1.
Occ
upa
tio
nal h
ealt
h an
d sa
fety
– e
xpo
sure
ass
essm
ent
D
erm
al a
nd o
cula
r ex
pos
ure
can
occ
ur d
uri
ng c
erta
in f
orm
ulat
ion
and
man
ufac
turi
ng
proc
esse
s.
How
ever
, ex
posu
re t
o si
gnif
ican
t am
oun
ts o
f th
e no
tifie
d p
olym
er i
s li
mite
d be
caus
e of
the
en
gine
erin
g co
ntro
ls (
clos
ed r
eact
ion
vess
el,
extr
acti
on
vent
ilati
on)
and
pers
ona
l pr
ote
ctiv
e eq
uipm
ent
wor
n by
wor
ker
s.
Safe
ty b
oots
, co
vera
lls a
nd s
afet
y gl
asse
s ar
e re
quir
ed in
all
are
as,
and
addi
tiona
l eq
uipm
ent
such
as
dus
t m
ask
, air
sup
plie
d ho
od,
chro
me
leat
her
or P
VC
glo
ves,
fa
ce s
hiel
ds o
r ha
rd h
ats
are
requ
ired
dur
ing
reac
tor
oper
atio
ns a
nd b
atch
pro
cess
ing
pro
cedu
res.
Oct
obe
r 20
02
NIC
NA
S
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LL P
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LIC
RE
PO
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: P
LC/3
29
Pag
e 8
of 1
0
Dur
ing
tran
spor
t an
d st
orag
e, w
ork
ers
are
unl
ikel
y to
be
expo
sed
to t
he n
otif
ied
pol
ymer
exc
ept
whe
n pa
ckag
ing
is a
ccid
enta
lly b
reac
hed.
F
orkl
ift
driv
ers
will
wea
r sa
fety
gla
sses
and
ch
rom
e le
ath
er g
lov
es.
Wor
kers
at
the
crus
hing
pla
nt
may
be
exp
osed
to
dus
ts g
ener
ated
in
the
crus
hin
g pr
oces
s, a
nd
shou
ld w
ear
prot
ecti
ve c
loth
ing,
incl
udi
ng d
ust
mas
ks, g
ogg
les
and
cove
ralls
.
9.2.
2.
Pu
blic
hea
lth
– e
xpos
ure
asse
ssm
ent
T
he
notif
ied
poly
mer
will
no
t be
avai
labl
e to
the
pub
lic.
Mem
bers
of
the
pub
lic
may
com
e in
to
cont
act w
ith p
rodu
cts
cont
aini
ng t
he n
otif
ied
poly
mer
.
9.2.
3.
Hu
man
hea
lth
- e
ffec
ts a
sses
smen
t
T
he
notif
ied
poly
mer
mee
ts t
he P
LC
cri
teri
a an
d th
eref
ore
low
haz
ard
is e
xpec
ted
due
to t
he la
ck
of r
eact
ive
gro
ups
and
the
inab
ilit
y of
the
pol
ymer
to p
enet
rate
bio
logi
cal m
embr
anes
. D
ust
may
be
gen
erat
ed d
urin
g th
e cr
ush
ing
pro
cess
.
9.2.
4.
Occ
upa
tio
nal h
ealt
h an
d sa
fety
– r
isk
cha
ract
eris
atio
n
T
he
OH
S ris
k pr
esen
ted
by t
he n
otif
ied
pol
ymer
is
expe
cted
to
be l
ow, h
owev
er,
ther
e is
a r
isk
of e
xpo
sure
to
mec
hani
cally
-gen
erat
ed d
usts
dur
ing
the
crus
hin
g pr
oces
s. T
he n
otif
ied
pol
ymer
m
ay b
e pr
esen
t in
for
mul
atio
ns c
onta
inin
g h
azar
dou
s in
gre
dien
ts.
If
thes
e fo
rmu
lati
ons
are
clas
sifi
ed
as
haza
rdou
s to
hea
lth
in
acco
rdan
ce
wit
h th
e N
OH
SC
A
ppro
ved
Cri
teri
a fo
r C
lass
ifyi
ng H
azar
dou
s S
ubst
ance
s, w
ork
plac
e pr
acti
ces
and
con
trol
pro
cedu
res
con
sist
ent
with
pr
ovi
sion
s o
f Sta
te a
nd T
erri
tory
haz
ardo
us
sub
stan
ces
legi
slat
ion
mus
t be
in o
pera
tion
.
9.2.
5.
Pu
blic
hea
lth
– r
isk
ch
arac
teri
sati
on
T
he
notif
ied
poly
mer
wil
l no
t b
e av
aila
ble
to t
he p
ubli
c.
Mem
bers
of
the
publ
ic m
ay m
ake
derm
al c
onta
ct w
ith
pro
duct
s co
ntai
nin
g th
e no
tifi
ed p
oly
mer
at l
ow c
once
ntra
tion
s.
How
ever
, th
e ri
sk t
o pu
blic
hea
lth w
ill b
e ne
glig
ible
bec
ause
the
notif
ied
poly
mer
is
bou
nd w
ithin
a m
atri
x
and
unli
kely
to b
e bi
oava
ilab
le.
10.
C
ON
CL
USI
ON
S –
ASS
ES
SME
NT
LE
VE
L O
F C
ON
CE
RN
FO
R T
HE
EN
VIR
ON
ME
NT
A
ND
H
UM
AN
S
10.1
. H
aza
rd c
lass
ific
ati
on
B
ased
on
the
av
aila
ble
dat
a th
e no
tifi
ed p
olym
er i
s no
t cl
assi
fied
as
haza
rdou
s un
der
the
App
rove
d C
rite
ria
for
Cla
ssify
ing
Haz
ard
ous
Su
bsta
nce
s (N
OH
SC. ,
19
99b)
10.2
. E
nvir
onm
enta
l ris
k as
sess
men
t
Th
e po
lym
er i
s no
t co
nsid
ered
to p
ose
a r
isk
to t
he e
nvi
ronm
ent
base
d on
its
rep
orte
d us
e p
atte
rn.
10.3
. H
um
an h
ealt
h r
isk
asse
ssm
ent
10.3
.1.
Occ
upa
tiona
l hea
lth
and
safe
ty
T
her
e is
L
ow
C
once
rn
to
occu
pati
onal
he
alth
an
d sa
fety
un
der
th
e co
nditi
ons
of
the
occu
pati
onal
set
tings
des
crib
ed.
10.3
.2.
Pu
blic
hea
lth
Th
ere
is N
eglig
ible
Con
cern
to p
ublic
hea
lth w
hen
use
d as
des
crib
ed.
11.
M
AT
ER
IAL
SA
FE
TY
DA
TA
SH
EE
T
11.1
. M
ater
ial S
afet
y D
ata
She
et
T
he
MS
DS
of
the
noti
fied
pol
ymer
pro
vide
d by
the
not
ifie
r w
as in
acc
ord
ance
with
the
NO
HS
C
Na
tion
al C
ode
of P
ract
ice
for
the
Pre
para
tion
of
Mat
eria
l Sa
fety
Da
ta S
heet
s (N
OH
SC, 1
994
a).
It i
s p
ubli
shed
her
e as
a m
atte
r of
pub
lic r
ecor
d. T
he
accu
racy
of
the
info
rmat
ion
on t
he M
SD
S
rem
ains
the
res
pon
sibi
lity
of
the
appl
ican
t.
Oct
obe
r 20
02
NIC
NA
S
FU
LL P
UB
LIC
RE
PO
RT
: P
LC/3
29
Pag
e 9
of 1
0
11.2
. L
abel
Th
e la
bel
for
the
noti
fied
pol
ymer
pro
vide
d b
y th
e no
tifi
er w
as i
n ac
cord
ance
wit
h th
e N
OH
SC
N
atio
nal
Cod
e o
f P
ract
ice
for
the
Lab
elli
ng o
f W
orkp
lace
Sub
stan
ces
(NO
HSC
, 19
94b)
. T
he
accu
racy
of t
he i
nfor
mat
ion
on t
he la
bel
rem
ains
the
resp
onsi
bili
ty o
f th
e ap
plic
ant.
12.
R
EC
OM
ME
ND
AT
ION
S
C
ONT
ROL
MEA
SUR
ESO
ccu
patio
nal H
ealt
h an
d Sa
fety
N
o sp
ecifi
c en
gine
erin
g co
ntro
ls,
wor
k p
ract
ices
or
pers
onal
pro
tect
ive
equi
pmen
t ar
e re
quir
ed f
or t
he s
afe
use
of t
he n
otif
ied
pol
ymer
its
elf,
how
ever
, th
ese
shou
ld b
e se
lect
ed o
n th
e ba
sis
of a
ll in
gred
ient
s in
the
form
ula
tion
.
Em
ploy
ers
shou
ld e
nsu
re t
hat
the
foll
owin
g p
erso
nal
pro
tect
ive
equi
pmen
t is
use
d b
y w
orke
rs t
o m
inim
ise
occ
upat
ion
al e
xpo
sure
to
the
dus
ts g
ener
ated
dur
ing
the
cru
shin
g pr
oce
ss n
otif
ied
chem
ical
D
ust
mas
ks, g
oggl
es, c
over
alls
.
Gui
danc
e in
se
lect
ion
of
per
son
al
pro
tect
ive
equ
ipm
ent
can
be
obta
ined
fr
om
A
ustr
alia
n, A
ustr
alia
n/N
ew Z
eala
nd
or o
ther
ap
prov
ed s
tan
dard
s.
A c
opy
of t
he M
SDS
shou
ld b
e ea
sily
acc
essi
ble
to
emp
loye
es.
If p
rodu
cts
and
mix
ture
s co
ntai
nin
g t
he n
otif
ied
poly
mer
are
cla
ssif
ied
as
haza
rdo
us t
o he
alth
in
acco
rdan
ce w
ith
the
NO
HS
C A
ppro
ved
Cri
teri
a f
or C
lass
ifyin
g H
azar
dou
s Su
bsta
nce
s, w
orkp
lace
pra
ctic
es a
nd c
ontr
ol p
roce
dur
es c
onsi
sten
t w
ith p
rovi
sion
s o
f S
tate
an
d T
erri
tory
haz
ardo
us s
ubst
ance
s le
gisl
atio
n m
ust
be in
op
erat
ion
.
Env
iro
nmen
t
The
fol
low
ing
cont
rol
mea
sure
s sh
ould
be
impl
emen
ted
by t
he o
pera
tor
to m
inim
ise
envi
ron
men
tal
expo
sure
dur
ing
(man
ufac
ture
and
use
) of
the
not
ifie
d p
oly
mer
: M
inim
ise
dust
pro
duct
ion
du
ring
cru
shin
g v
ia t
he u
se o
f fin
e w
ater
sp
rays
, C
ont
ain
and
swee
p up
any
spi
lt m
ater
ial,
D
o no
t all
ow it
to e
nter
any
sto
rmw
ater
dra
ins
or n
atur
al w
ater
bod
ies.
Dis
posa
l The
not
ifie
d p
olym
er s
houl
d b
e di
spos
ed o
f by
land
fill
or
inci
nera
tion
.
Em
erge
ncy
proc
edu
res
Spi
lls/r
elea
se o
f th
e no
tifie
d po
lym
er s
hou
ld b
e h
andl
ed b
y co
ntai
nmen
t an
d th
en s
wep
t up
, pl
aced
in s
eala
ble
con
tain
er,
and
disp
ose
d of
to
land
fill,
or r
ecyc
led
if p
ossi
ble.
12.1
. S
econ
dar
y n
otif
icat
ion
Th
e D
irec
tor
of C
hem
ical
s N
otif
icat
ion
and
Ass
essm
ent
mu
st b
e no
tifi
ed i
n w
riti
ng w
ithi
n 28
da
ys b
y th
e no
tifi
er, o
ther
im
port
er o
r m
anuf
actu
rer:
(1)
Und
er S
ecti
on 6
4(1
) of
the
Act
; if
th
e no
tifi
ed p
oly
mer
is
intr
oduc
ed i
n a
chem
ical
for
m t
hat
does
not
mee
t th
e P
LC
cr
iter
ia.
or
Oct
obe
r 20
02
NIC
NA
S
FU
LL P
UB
LIC
RE
PO
RT
: P
LC/3
29
Pag
e 10
of 1
0
(2)
Und
er S
ecti
on 6
4(2
) of
the
Act
:-
if a
ny o
f th
e ci
rcum
stan
ces
list
ed i
n th
e su
bsec
tion
ari
se.
The
Dir
ecto
r w
ill t
hen
deci
de w
heth
er s
econ
dary
not
ific
atio
n is
req
uire
d.
No
addi
tiona
l sec
ond
ary
noti
fica
tion
con
diti
ons
are
stip
ula
ted.
13.
B
IBL
IOG
RA
PH
Y
Co
nnel
l D.
W.
(199
0)
Gen
eral
cha
ract
eris
tics
of
orga
nic
com
poun
ds w
hich
exh
ibit
bio
accu
mul
atio
n. I
n C
onn
ell
D. W
., (E
d)
Bio
accu
mul
atio
n o
f Xen
obio
tic C
ompo
unds
. CR
C P
ress
, B
oca
Rat
on,
USA
.
Nat
ion
al O
ccup
atio
nal
Hea
lth
and
Safe
ty C
omm
issi
on (
1994
a) N
atio
nal
Cod
e o
f Pr
acti
ce f
or t
he P
repa
rati
on o
f M
ater
ial
Safe
ty D
ata
She
ets
[NO
HS
C:2
011
(199
4)]
. Aus
trali
an G
ove
rnm
ent P
ubli
shin
g S
ervi
ce, C
anb
erra
.
Nat
ion
al O
ccup
atio
nal
Hea
lth
and
Safe
ty C
omm
issi
on
(199
4b)
Nat
iona
l C
ode
of P
ract
ice
for
the
Lab
ellin
g of
W
orkp
lace
Sub
stan
ces
[NO
HS
C:2
012
(19
94)]
. Au
stra
lian
Gov
ernm
ent
Pub
lish
ing
Ser
vice
, C
anbe
rra.
Nat
ion
al
Occ
upa
tiona
l H
ealth
an
d S
afet
y C
om
mis
sion
(1
999a
) L
ist
of
Des
igna
ted
Haz
ardo
us
Subs
tanc
es
[NO
HS
C:1
0005
(19
99)]
. Au
stra
lian
Gov
ernm
ent
Pub
lish
ing
Ser
vice
, C
anbe
rra.
Nat
ion
al O
ccup
atio
nal
Hea
lth
and
Safe
ty C
omm
issi
on (
199
9b)
App
rove
d C
rite
ria
for
Cla
ssif
ying
Haz
ard
ous
Sub
stan
ces
[NO
HS
C:1
008
(19
99)]
. A
ustr
alia
n G
over
nmen
t Pu
blis
hing
Ser
vice
, C
anbe
rra.
MA
TE
RIA
L S
AFE
TY
DA
TA
SH
EE
TW
est S
yste
m In
c.
MSD
S #1
05-1
3aLa
st R
evis
ed:
26A
PR13
1.CH
EMIC
AL P
RO
DUC
T AN
D C
OMP
ANY
IDEN
TIFI
CATI
ON
PROD
UCT
NAM
E:..
......
......
......
......
......
......
......
.WES
T SY
STEM
®10
5 Ep
oxy
Resin
PROD
UCT
CODE
:....
......
......
......
......
......
......
.....1
05CH
EMIC
AL F
AMI
LY:..
......
......
......
......
......
......
...Ep
oxy R
esin.
CHEM
ICAL
NAM
E:...
......
......
......
......
.......
......
....B
isph
enol
A b
ased
epo
xy re
sin.
FORM
ULA
:.....
......
......
......
......
......
......
......
......
...No
t app
licab
le.
MAN
UFAC
TUR
ER:
EMER
GENC
Y TE
LEPH
ONE
NU
MBE
RS:
Wes
t Sys
tem
Inc.
Tran
spor
tatio
n10
2 Pa
tters
on A
ve.
CHEM
TREC
:.....
......
......
...80
0-42
4-93
00 (U
.S.)
Bay
City
, MI 4
8706
, U.S
.A.
703-
527-
3887
(Int
erna
tiona
l)Ph
one:
866
-937
-879
7 or
989
-684
-728
6No
n-tra
nspo
rtatio
nww
w.we
stsys
tem
.com
Poiso
n Ho
tline:
......
......
.....
800-
222-
1222
2.HA
ZAR
DS ID
ENTI
FICA
TION
EMER
GENC
Y OV
ERVI
EW
WAR
NING
May
cau
se s
kin
irrita
tion.
May
cau
se e
ye ir
ritat
ion.
May
caus
e al
lergic
reac
tion.
Cle
ar,v
isco
usliq
uid w
ith m
ild o
dor.
PRIM
ARY
ROU
TE(S
) OF
ENTR
Y:...
......
......
......
......
......
......
......
......
...Sk
in co
ntact
.
POTE
NTIA
L HE
ALTH
EFF
ECT
S:
ACUT
E IN
HAL
ATIO
N:..
......
......
......
......
......
......
......
......
......
......
......
....If
pro
duct
is h
eate
d, va
pors
gen
erat
ed c
an c
ause
hea
dach
e, n
ause
a,
dizz
ines
s an
d po
ssib
le re
spira
tory
irrit
ation
if in
haled
in h
igh
conc
entra
tions
.
CHRO
NIC
INHA
LATI
ON:
......
......
......
......
......
.......
......
......
......
......
......
Repe
ated
exp
osur
e to
high
vapo
r con
cent
ratio
ns m
ay c
ause
irrit
ation
of
pre-
exist
ing lu
ng a
llerg
ies a
nd in
crea
se th
e ch
ance
of d
evel
oping
alle
rgy
sym
ptom
s to
this
prod
uct.
ACUT
E SK
IN C
ONTA
CT:.
......
......
......
......
......
......
......
......
......
......
......
May
cau
se a
llerg
ic sk
in re
spon
se in
cer
tain
indi
vidua
ls. M
ay c
ause
m
oder
ate
irrita
tion
to th
e skin
suc
h as
redn
ess
and
itchin
g.
CHR
ONIC
SKI
N CO
NTAC
T:...
......
......
......
......
......
......
......
......
......
......
May
cau
se s
ensit
izatio
n in
susc
eptib
le in
divid
uals.
May
cau
se m
oder
ate
irrita
tion
to th
e sk
in.
EYE
CONT
ACT
:....
......
......
......
......
......
......
......
......
......
......
......
......
.....
May
cau
se ir
ritat
ion.
INGE
STIO
N:...
......
......
......
......
......
......
......
......
......
......
......
......
......
......
Low
acu
te o
ral to
xicity
.
SYM
PTO
MS
OF
OVE
REX
POSU
RE:
......
......
......
......
......
.......
......
......
.Pos
sible
sen
sitiza
tion a
nd s
ubse
quen
t alle
rgic
reac
tions
usu
ally
seen
as
redn
ess
and
rash
es.
MED
ICA
L CO
NDIT
IONS
AG
GRA
VATE
D BY
EXP
OSU
RE:
......
......
....P
re-e
xistin
g sk
in a
nd re
spira
tory
disor
ders
may
be
aggr
avat
ed b
y exp
osur
e to
this
pro
duct
. Pr
e-ex
isting
lung
and
skin
alle
rgie
s may
incr
ease
the c
hanc
e of
dev
elop
ing
aller
gic s
ympt
oms
to th
is pr
oduc
t.
3.CO
MPO
SITI
ON
/INFO
RM
ATIO
N O
N H
AZA
RDOU
S IN
GRE
DIE
NTS
INGR
EDIE
NT N
AME
CAS
#CO
NCEN
TRAT
ION
(%)
Prop
ane,
2,2
-bis[
p-(2
,3-e
poxy
prop
oxy)
phen
yl]-,
pol
ymer
s25
085-9
9-8
60-1
00Be
nzyl
alco
hol
100-
51-6
10-3
0Ph
enol
-form
alde
hyde
pol
ymer
glyc
idyl
ethe
r28
064-1
4-4
1-10
4.FI
RST
AID
ME
ASUR
ES
FIR
ST A
ID F
OR
EYES
......
......
......
......
......
.......
......
......
......
......
......
.....
Flus
h im
med
iate
ly w
ith w
ater
for a
t lea
st 1
5 m
inute
s. C
onsu
lt a p
hysic
ian.
FIR
ST A
ID F
OR
SKIN
......
......
......
......
......
......
......
......
......
......
......
......
.Rem
ove
cont
amin
ated
clo
thing
. W
ipe
exce
ss fr
om s
kin. A
pply
wate
rless
sk
in cle
aner
and
then
was
h wi
th s
oap
and
wate
r. C
onsu
lt a
phys
ician
if e
ffect
s occ
ur.
FIR
ST A
ID F
OR
INH
ALAT
ION
......
......
......
......
......
......
......
......
......
......
Rem
ove
to fr
esh
air i
f effe
cts o
ccur
.
FIR
ST A
ID F
OR
ING
ESTI
ON...
......
......
......
......
......
......
......
......
......
.....
No a
cute
adv
erse
hea
lth e
ffect
s exp
ecte
d fro
m a
mou
nts
inge
sted
und
er
norm
al co
nditio
ns o
f use
. Se
ek m
edica
l atte
ntio
n if a
sign
ifican
t am
ount
is in
gest
ed.
Wes
t Sys
tem
Inc.
Page
2of
4W
EST
SYST
EM®
105 R
esin
MSD
S #1
05-1
3aLa
st R
evis
ed:
26A
PR13
5.FI
RE
FIG
HTIN
G M
EAS
URE
S
FLAS
H P
OIN
T:...
......
......
......
......
.......
......
......
......
......
......
......
......
......
.>20
0°F
(Tag
Clo
sed
Cup)
EXTI
NGUI
SHI
NG
MEDI
A:.
......
......
......
......
......
......
......
......
......
......
.....
Foam
, car
bon d
ioxid
e (C
O 2),
dry
chem
ical.
SPE
CIA
L FI
RE F
IGHT
ING
PRO
CED
URES
:....
......
......
......
......
......
.....
Wea
r a s
elf-c
onta
ined
bre
athi
ng a
ppar
atus
and
com
plete
full-b
ody
pers
onal
pr
otec
tive
equi
pmen
t. C
lose
d co
ntain
ers
may
rupt
ure
(due
to b
uildu
p of
pre
ssur
e) w
hen
expo
sed
to e
xtre
me
heat
.
FIR
E A
ND E
XPLO
SIO
N HA
ZARD
S:.
......
......
......
......
......
......
......
......
.Dur
ing a
fire
, sm
oke
may
cont
ain th
e or
igin
al m
ater
ials
in a
dditio
n to
co
mbu
stio
n pro
ducts
of v
aryin
g co
mpo
sition
whi
ch m
ay b
e to
xic a
nd/o
r irri
tatin
g. C
ombu
stion
pro
duct
s may
incl
ude,
but
are
not
lim
ited
to:
phen
olics
, car
bon
mon
oxide
, car
bon
diox
ide.
6.AC
CIDE
NTA
L RE
LEAS
E M
EASU
RES
SPIL
L OR
LEA
K PR
OCE
DURE
S:..
......
......
......
......
......
......
......
......
....S
top
leak
with
out a
dditi
onal
risk.
Dik
e an
d ab
sorb
with
iner
t mat
eria
l (e.g.
, sa
nd) a
nd c
ollec
t in
a su
itabl
e, clo
sed
cont
ainer
. W
arm
, soa
py w
ater
or n
on-fla
mm
able
, saf
e so
lvent
may
be
used
to c
lean
resi
dual.
7.HA
NDLI
NG A
ND S
TOR
AGE
STO
RAGE
TEM
PERA
TURE
(min
./max
.):...
......
......
......
......
.......
......
..40
°F (4
°C) /
120
°F (4
9°C)
STO
RAGE
:....
......
......
......
......
......
......
......
......
......
......
......
......
......
......
.Sto
re in
coo
l, dr
y pla
ce.
Stor
e in
tight
ly se
aled
con
tain
ers t
o pr
even
t m
oistu
re a
bsor
ptio
n an
d lo
ss o
f vol
atile
s. E
xces
sive
heat
over
long
per
iods
of t
ime
will
degr
ade
the
resi
n.
HAND
LING
PR
ECA
UTIO
NS:.
......
......
......
......
......
......
......
......
......
......
Avoid
pro
long
ed o
r rep
eate
d sk
in co
ntac
t. W
ash
thor
ough
ly af
ter h
andl
ing.
Laun
der c
onta
min
ated
clot
hing
befo
re re
use.
Avo
id in
hala
tion
of v
apor
s fro
m h
eate
d pr
oduc
t. P
reca
utio
nary
step
s sh
ould
be
take
n wh
en cu
ring
prod
uct i
n la
rge
quan
titie
s. W
hen
mix
ed w
ith e
poxy
cur
ing a
gent
s th
is pr
oduc
t cau
ses
an e
xoth
erm
ic, w
hich
in la
rge
mas
ses,
can
prod
uce
enou
gh
heat
to d
amag
e or
igni
te s
urro
undi
ng m
ater
ials
and
emit f
umes
and
vap
ors
that
var
y wi
dely
in co
mpo
sition
and
toxic
ity.
8.EX
POS
URE
CO
NTRO
LS/P
ERS
ONA
L PR
OTE
CTI
ON
EYE
PRO
TECT
ION
GUI
DEL
INES
:....
......
......
......
......
......
......
......
......
.Saf
ety
glass
es w
ith s
ide
shiel
ds o
r che
mica
l spla
sh g
oggl
es.
SKIN
PRO
TECT
ION
GUI
DEL
INE
S:...
......
......
......
......
.......
......
......
......
Wea
r liqu
id-pr
oof,
chem
ical r
esist
ant g
love
s (ni
trile-
buty
l rub
ber,
neop
rene
, bu
tyl r
ubbe
r or n
atur
al ru
bber
) and
full
body
-cov
ering
clot
hing.
RESP
IRAT
ORY
/VEN
TILA
TION
GUI
DELI
NES
:.....
......
......
......
......
......
Goo
d ro
om ve
ntila
tion
is us
ually
ade
quat
e fo
r mos
t ope
ratio
ns. W
ear a
NI
OSH/
MSH
A ap
prov
ed re
spira
tor w
ith a
n or
gani
c vap
or c
artri
dge
whe
neve
r exp
osur
e to
vapo
r in
conc
entra
tions
abo
ve a
pplic
able
limits
is li
kely.
Note
: W
est S
yste
m, I
nc. h
as c
ondu
cted
an
air s
ampl
ing
study
usin
g th
is pr
oduc
t or s
imila
rly fo
rmula
ted
prod
ucts
. Th
e re
sults
indi
cate
that
the
com
pone
nts
sam
pled
for (
epich
loroh
ydrin
, ben
zyl a
lcoho
l)wer
e ei
ther
so
low
that
they
wer
e no
t det
ecte
d at
all o
r the
y we
re si
gnific
antly
belo
w
ADDI
TION
AL P
ROTE
CTIV
E M
EASU
RES
:.....
......
......
......
......
......
......
Prac
tice
good
cau
tion
and
pers
onal
clea
nline
ss to
avo
id sk
in a
nd e
ye
cont
act.
Avoi
d sk
in co
ntac
t whe
n re
mov
ing
glove
s and
oth
er p
rote
ctive
equ
ipm
ent.
Was
h th
orou
ghly
afte
r han
dling
. Gen
eral
ly sp
eakin
g, w
orkin
g cle
anly
and
follo
wing
bas
ic pr
ecau
tiona
ry m
easu
res
will
grea
tly m
inim
ize th
e po
tent
ial f
or h
arm
ful e
xpos
ure
to th
is pr
oduc
t und
er n
orm
al us
e co
nditi
ons.
OCC
UPA
TION
AL E
XPO
SUR
E L
IMIT
S:...
......
......
......
......
......
......
......
Not e
Expo
sure
Lev
el (P
EL) o
r the
ACG
IH G
uidel
ines f
or in
form
atio
n on
spe
cific
ingre
dien
ts.
9.PH
YSI
CAL
AND
CHEM
ICA
L PR
OPE
RTI
ES
PHYS
ICAL
FO
RM:.
......
......
......
......
......
......
......
......
......
......
......
......
....L
iquid
.CO
LOR:
......
......
......
......
......
......
......
......
......
......
......
......
......
......
......
...Cl
ear.
ODO
R:...
......
......
......
......
......
......
......
......
......
......
......
......
......
......
......
...M
ild.
BOIL
ING
PO
INT:
......
......
......
......
......
.......
......
......
......
......
......
......
......
.> 4
00°F
MEL
TIN
G PO
INT/
FREE
ZE P
OIN
T:...
......
......
......
......
.......
......
......
......
.No
data
.VI
SCO
SITY
:.....
......
......
......
......
......
......
......
......
......
.......
......
......
......
....1
000
(cP)
pH:.
......
......
......
......
......
......
......
......
......
......
......
......
......
......
......
......
....N
o da
ta.
SOLU
BIL
ITY
IN W
ATER
:....
......
......
......
......
......
......
......
......
......
......
...Sl
ight
.SP
ECI
FIC
GRA
VITY
:.....
......
......
......
......
......
......
......
......
......
.......
......
..1.
15BU
LK D
ENS
ITY:
......
......
......
......
......
.......
......
......
......
......
......
......
......
.9.6
(pou
nds/
gallo
n)VA
POR
PR
ESSU
RE:..
......
......
......
......
......
......
......
......
......
......
.......
.....
< 1
mm
Hg @
20°
C.VA
POR
DEN
SITY
:.....
......
......
......
......
......
......
......
......
......
......
......
......
.Hea
vier t
han
air.
% V
OLA
TILE
BY
WEI
GHT
:....
......
......
......
......
......
......
......
......
......
......
ASTM
D 2
369-
07wa
s us
ed to
det
erm
ine
the
Vola
tile C
onte
nt o
f mix
ed
epox
y re
sin
and
hard
ener
. Re
fer t
o the
har
dene
r's M
SDS
for i
nfor
mat
ion a
bout
the
tota
l vola
tile c
onte
nt o
f the
resin
/har
dene
r sys
tem
.
10.
STAB
ILIT
Y AN
D RE
ACTI
VITY
STAB
ILIT
Y:...
......
......
......
......
......
......
......
......
......
......
......
......
......
......
.Sta
ble.
Wes
t Sys
tem
Inc.
Page
3of
4W
EST
SYST
EM®
105 R
esin
MSD
S #1
05-1
3aLa
st R
evis
ed:
26A
PR13
HAZA
RDO
US P
OLYM
ERIZ
ATIO
N:..
......
......
......
......
......
......
......
......
..W
ill no
t occ
ur b
y its
elf, b
ut a
mas
s of
mor
e th
an o
ne p
ound
of p
rodu
ct p
lus
an a
lipha
tic a
mine
will
caus
e irr
ever
sibl
e pol
ymer
izat
ion w
ith si
gnific
ant h
eat b
uild
up.
INCO
MPA
TIBI
LITI
ES:.
......
......
......
......
......
......
......
......
......
......
......
.....
Stro
ng a
cids,
bas
es, a
mine
s an
d m
erca
ptan
s ca
n ca
use
polym
eriz
ation
.
DECO
MPO
SIT
ION
PRO
DUC
TS:.
......
......
......
......
......
......
......
......
......
.Car
bon
mon
oxid
e, ca
rbon
dio
xide
and
phe
nolic
smay
be
prod
uced
dur
ing
unco
ntro
lled
exot
herm
ic re
actio
ns o
r whe
noth
erwi
sehe
ated
to d
ecom
posi
tion.
11.
TOXI
COLO
GICA
L IN
FORM
ATI
ON
No s
pecif
ic or
al, in
halat
ion o
r der
mal
toxic
olog
y da
ta is
kno
wn fo
r thi
s pr
oduc
t. S
pecif
ic to
xicolo
gy in
form
ation
for a
bisp
heno
l-A b
ased
ep
oxy
resi
n pr
esen
t in t
his p
rodu
ct is
indic
ated
belo
w:
Ora
l:....
......
......
......
......
......
......
......
......
......
......
...LD
50
>500
0 mg
/kg
(rat
s)In
hala
tion:
......
......
......
......
......
.......
......
......
......
...No
Dat
a.De
rmal:
......
......
......
......
......
.......
......
......
......
......
.LD 5
0=
20,0
00 m
g/kg
(sk
in ab
sorp
tion
in ra
bbits
)
TERA
TOLO
GY:
......
......
......
......
......
......
......
......
.-A
(DG
EBP
A) d
id n
ot ca
use
birth
def
ects
or o
ther
adv
erse
ef
fect
s on
the
fetu
s whe
n pr
egna
nt ra
bbits
wer
e ex
pose
d by
skin
cont
act,
the
most
likel
y ro
ute
of e
xpos
ure,
or w
hen
preg
nant
rats
or r
abbit
s we
re
expo
sed
oral
ly.
REPR
ODU
CTIV
E E
FFEC
TS:..
......
......
......
......
...
MUT
AGEN
ICIT
Y:...
......
......
......
......
.......
......
......
.DG
EBPA
in a
nima
l mut
agen
icity
stu
dies
were
neg
ative
. In
vitro
mut
agen
icity
te
sts w
ere
nega
tive
in so
me
case
s an
d po
sitiv
e in
oth
ers.
CARC
INO
GEN
ICIT
Y:NT
P...
......
......
......
......
.......
......
......
......
......
......
......
......
......
......
....P
rodu
ct no
t list
ed.
IARC
......
......
......
......
......
.......
......
......
......
......
......
......
......
......
......
Prod
uct n
ot li
sted.
OSH
A...
......
......
......
......
.......
......
......
......
......
......
......
......
......
......
.Pro
duct
not l
isted
.
No in
gred
ient o
f thi
s pro
duct
pre
sent
at l
evels
gre
ater
than
or e
qual
to 0
.1%
is id
entif
ied a
s a
carci
noge
n or
pot
entia
l car
cinog
en b
y OS
HA,
NTP
or IA
RC.
Man
y st
udies
hav
e be
en c
ondu
cted
to a
sses
s th
e po
tent
ial c
arci
noge
nicit
y of d
iglyc
idyl e
ther
of b
isphe
nol-A
. Al
thou
gh so
me
weak
evid
ence
of
car
cinog
enic
ity h
as b
een
repo
rted
in a
nim
als, w
hen
all o
f the
dat
a ar
e co
nside
red,
the
weig
ht o
f evid
ence
doe
s no
t sho
w th
at D
GEBP
A is
carc
inog
enic.
Ind
eed,
the
mos
t rec
ent r
evie
w of
the
avai
lable
dat
a by
the
Inte
rnat
iona
l Age
ncy f
or R
esea
rch
on C
ance
r (IA
RC)h
as
conc
lude
d th
at D
GEB
PA
is no
t cla
ssifi
ed a
s a
carc
inog
en.
Epich
loro
hydr
in, a
n im
purit
y in
this
prod
uct (
<5 p
pm) h
as b
een
repo
rted t
o pr
oduc
e ca
ncer
in la
bora
tory
anim
als a
nd to
pro
duce
mut
agen
ic ch
ange
s in
bac
teria
and
cult
ured
hum
an c
ells.
It h
as b
een
esta
blish
ed b
y th
e Int
erna
tiona
l Age
ncy
for R
esea
rch
on C
ance
r (IA
RC) a
s a
prob
able
hum
an ca
rcin
ogen
(Gro
up 2
A) b
ased
on
the
follo
wing
con
clusio
ns:
hum
an e
vide
nce
inad
equa
te; a
nimal
evid
ence
su
fficie
nt.
It ha
s be
en c
lass
ified a
s an
ant
icipa
ted h
uman
car
cinog
en b
y th
e Na
tiona
l Tox
icolo
gy P
rogr
am (N
TP).
Note
: It
is un
likel
y tha
t nor
mal
use
of
this
prod
uct w
ould
resu
lt in
mea
sura
ble e
xpos
ure
conc
entra
tions
to th
is su
bsta
nce.
12.
ECOL
OGI
CAL
INFO
RMA
TIO
N
In th
e no
n-cu
red
liqui
d for
m th
is pr
oduc
t may
cau
se lo
ng-te
rm h
arm
if re
leas
ed to
the
envi
ronm
ent.
Prev
ent e
ntry
into
sew
ers
and
natu
ral w
ater
s.
Mov
emen
t and
Par
tition
ing:
Bioc
once
ntra
tion
pote
ntial
is m
oder
ate
(BC
F be
twee
n 10
0 an
d 30
00 o
r Log
Kow
bet
ween
3 a
nd 5
).
Degr
adati
on a
nd T
rans
form
ation
:Th
eore
tical
oxyg
en d
eman
d is
calc
ulate
d to
be
2.35
p/p
. 20
-day
bioc
hem
ical o
xyge
n de
man
d is
<2.5
%.
Ecot
oxic
olog
y:M
ater
ial is
mod
erat
ely t
oxic
to a
quat
ic or
ganis
ms o
n an
acu
te b
asis.
LC5
0/EC
50 b
etwe
en 1
and
10
mg/
L in
mos
t sen
sitive
sp
ecie
s.
13.
DISP
OSA
L CO
NSID
ERA
TIO
NS
WAS
TE D
ISPO
SAL
MET
HOD:
......
......
......
......
......
......
......
......
......
.....
Evalu
ation
of t
his p
rodu
ct u
sing
RCRA
crit
eria
show
s th
at it
is n
ot a
ha
zard
ous w
aste
, eith
er b
y lis
ting
or c
hara
cter
istic
s, in
its p
urch
ased
form
. It
is th
e re
spon
sibilit
y of
the
user
to d
eterm
ine
prop
er d
ispo
sal
met
hods
.
Incin
erat
e, re
cycl
e (fu
el b
lendi
ng) o
r rec
laim
may
be
pref
erre
d m
etho
ds w
hen
cond
ucte
d in
acco
rdan
ce w
ith fe
dera
l, sta
te an
d lo
cal r
egul
ation
s.
14.
TRA
NSPO
RTA
TIO
N IN
FORM
ATIO
N
DOT
Non-
Bulk
SHIP
PING
NAM
E:..
......
......
......
......
......
......
......
......
......
......
.......
......
....N
ot re
gula
ted.
TECH
NICA
L SH
IPPI
NG N
AME
:.....
......
......
......
......
......
......
......
......
.....
Not a
pplic
able
.
Wes
t Sys
tem
Inc.
Page
4of
4W
EST
SYST
EM®
105 R
esin
MSD
S #1
05-1
3aLa
st R
evis
ed:
26A
PR13
HAZA
RD C
LASS
:.....
......
......
......
......
......
......
......
......
......
......
......
......
...No
t app
licab
le.
U.N.
/N.A
. NUM
BER
:.....
......
......
......
......
......
......
......
......
......
.......
......
....N
ot a
pplic
able
.PA
CKI
NG
GROU
P:...
......
......
......
......
.......
......
......
......
......
......
......
......
.Not
app
licab
le.
IMD
GSH
IPPI
NG N
AME
:.....
......
......
......
......
......
......
......
......
......
.......
......
......
.Env
ironm
enta
lly h
azar
dous
sub
stanc
e, liq
uid,
n.o.
s.TE
CHNI
CAL
SHIP
PING
NAM
E:..
......
......
......
......
......
......
......
......
......
..Ep
oxy R
esin.
HAZA
RD C
LASS
:.....
......
......
......
......
......
......
......
......
......
......
......
......
...Cl
ass
9.U.
N. N
UM
BER:
......
......
......
......
......
.......
......
......
......
......
......
......
......
....U
N30
82.
PAC
KIN
G GR
OUP:
......
......
......
......
......
.......
......
......
......
......
......
......
....P
G II
I.Em
S Nu
mbe
r: ...
......
......
......
......
......
......
......
......
......
......
......
......
......
...F-
A, S
-FM
ARIN
E PO
LLUT
ANT
......
......
......
......
......
.......
......
......
......
......
......
.....
Yes
ICAO
/IATA
SHIP
PIN
G NA
ME:
......
......
......
......
......
......
......
......
......
......
......
......
......
.Env
ironm
enta
lly h
azar
dous
sub
stanc
e, liq
uid,
n.o.
s.TE
CHNI
CAL
SHIP
PING
NAM
E:..
......
......
......
......
......
......
......
......
......
..Ep
oxy R
esin.
HAZA
RD C
LASS
:.....
......
......
......
......
......
......
......
......
......
......
......
......
...Cl
ass
9.U.
N. N
UM
BER:
......
......
......
......
......
.......
......
......
......
......
......
......
......
....U
N30
82.
PAC
KIN
G GR
OUP:
......
......
......
......
......
.......
......
......
......
......
......
......
....P
G II
I.M
ARIN
E PO
LLUT
ANT:
......
......
......
......
......
......
......
......
......
......
......
.....
Yes
15.
REGU
LATO
RY
INFO
RMAT
ION
OSH
A S
TATU
S:...
......
......
......
......
.......
......
......
......
......
......
......
......
.....
Irrita
nt.
TSCA
STA
TUS:
......
......
......
......
......
......
......
......
......
......
......
......
......
....A
ll com
pone
nts a
re li
sted
on T
SCA
inve
ntor
yor
oth
erw
ise co
mpl
y with
TS
CA re
quire
men
ts.
Cana
da W
HM
IS C
lass
ifica
tion:
......
......
......
......
......
......
......
......
......
...D2
B-T
oxic
mate
rial c
ausi
ng o
ther
toxi
c effe
cts.
CEPA
Che
mic
alIn
vent
ory
Stat
us:..
......
......
......
......
......
......
......
......
..Al
l com
pone
nts
are
liste
d or
are
oth
erw
ise c
ompl
iant w
ith C
EPA
re
quire
men
ts.
SARA
TIT
LE II
I:SE
CTI
ON
313
TOXI
C C
HEM
ICAL
S...
......
......
......
......
......
......
....N
one
(dem
inim
us).
STAT
E RE
GUL
ATO
RY
INFO
RM
ATIO
N:Th
e foll
owin
g ch
emica
ls ar
e sp
ecific
ally
liste
d or
oth
erw
ise re
gula
ted
by in
divid
ual s
tates
. Fo
r det
ails
on y
our r
egul
ator
y re
quire
men
ts yo
u sh
ould
co
ntac
t the
app
ropr
iate
agen
cy in
your
sta
te.
COM
PONE
NT
NAM
E/C
AS N
UMB
ERCO
NCEN
TRAT
ION
STAT
E CO
DEEp
ichlo
rohy
drin
106-
89-8
< 5p
pm1 CA
Benz
yl al
coho
l10
0-51
-6M
A, P
A, N
J
1.
Thes
e su
bsta
nces
are
kno
wn
to th
e sta
te o
f Cal
iforn
ia to
caus
e ca
ncer
or re
prod
uctiv
e ha
rm, o
r bot
h.
16.
OTH
ER IN
FOR
MAT
ION
REAS
ON
FOR
ISSU
E:...
......
......
......
......
.......
......
......
......
......
......
......
..Ch
ange
s mad
e in
Secti
on14
and
15.
PREP
ARED
BY:
......
......
......
......
......
.......
......
......
......
......
......
......
......
..G
. M. H
ouse
APPR
OVE
D BY
:....
......
......
......
......
......
......
......
......
......
......
......
......
.....
G. M
. Hou
seTI
TLE:
......
......
......
......
......
......
......
......
......
......
......
......
......
......
......
......
Heal
th, S
afet
y &
Env
ironm
enta
l Man
ager
APPR
OVA
L DA
TE:.
......
......
......
......
......
......
......
......
......
......
......
......
...Ap
ril 26
, 201
3SU
PERS
EDE
S DA
TE:.
......
......
......
......
......
......
......
......
......
......
......
.....
Mar
ch 9,
201
2M
SDS
NUM
BER
:.....
......
......
......
......
......
......
......
......
......
......
......
......
...10
5-13
a
This
info
rmat
ion
is fu
rnish
ed w
ithou
t war
rant
y, e
xpre
ssed
or i
mpl
ied, e
xcep
t tha
t it is
acc
urat
e to
the
best
know
ledg
e of
Wes
t Sys
tem
Inc.
The
dat
a on
th
is sh
eet i
s rel
ated
only
to th
e sp
ecific
mat
eria
l des
igna
ted
here
in.
Wes
t Sys
tem
Inc.
ass
umes
no
lega
l res
pons
ibilit
y fo
r use
or r
elia
nce
upon
thes
e da
ta.
p. 1
10
0
He
alt
h
Fir
e
Re
ac
tiv
ity
Pe
rso
na
lP
rote
cti
on
2 1 0 H
Mat
eria
l Saf
ety
Dat
a Sh
eet
Pro
pyle
ne g
lyco
l MSD
S
Sect
ion
1: C
hem
ical
Pro
duct
and
Com
pany
Iden
tific
atio
n
Prod
uct N
ame:
Pro
pyle
ne
glyc
ol
Cat
alog
Cod
es:
SLP
1162
, SL
P2
974
CAS
#: 5
7-5
5-6
RTE
CS:
TY
2000
000
TSC
A: T
SC
A 8
(b)
inve
ntor
y: P
rop
yle
ne g
lyco
l
CI#
: No
t app
licab
le.
Syno
nym
: 1
,2,-
pro
pane
diol
, 1,2
-dih
ydr
oxy
prop
ane
Che
mic
al N
ame:
Pro
pyle
ne
Gly
col
Che
mic
al F
orm
ula:
CH
3CH
OH
CH
2OH
Con
tact
Info
rmat
ion:
Scie
ncel
ab.c
om, I
nc.
1402
5 S
mith
Rd.
Hou
sto
n, T
exa
s 77
396
US
Sal
es:
1-80
0-90
1-72
47In
tern
atio
nal
Sal
es:
1-2
81-4
41-4
400
Ord
er
Onl
ine:
Sci
ence
Lab
.com
CHE
MTR
EC (2
4HR
Em
erge
ncy
Tele
phon
e), c
all:
1-80
0-4
24-9
300
Inte
rnat
iona
l CH
EMTR
EC,
cal
l: 1-
703
-52
7-38
87
For n
on-e
mer
genc
y as
sist
ance
, cal
l: 1-
281
-44
1-44
00
Sect
ion
2: C
ompo
sitio
n an
d In
form
atio
n on
Ingr
edie
nts
Com
posi
tion:
Nam
eC
AS #
% b
y W
eigh
t
Pro
pyle
ne
gly
col
57-5
5-6
100
Toxi
colo
gica
l Dat
a on
Ingr
edie
nts:
Pro
pyle
ne
glyc
ol:
OR
AL
(LD
50)
: A
cute
: 20
000
mg
/kg
[Rat
]. 2
2000
mg/
kg [M
ouse
].D
ER
MA
L (L
D5
0):
Acu
te: 2
0800
mg/
kg [R
abbi
t].
Sect
ion
3: H
azar
ds Id
entif
icat
ion
Pote
ntia
l Acu
te H
ealth
Effe
cts:
Haz
ard
ous
in
cas
e of
inge
stio
n. S
light
ly h
aza
rdou
s in
ca
se o
f sk
in c
ont
act
(irr
itant
, per
mea
tor)
, of
eye
con
tact
(irr
itant
), o
fin
hala
tion
.
Pote
ntia
l Chr
onic
Hea
lth E
ffect
s:S
ligh
tly h
aza
rdo
us i
n ca
se
of s
kin
con
tact
(se
nsiti
zer)
. CA
RC
INO
GE
NIC
EF
FE
CT
S:
No
t ava
ilabl
e. M
UTA
GE
NIC
EF
FE
CT
S:
Not
ava
ilabl
e. T
ER
ATO
GE
NIC
EF
FE
CT
S: N
ot a
vaila
ble
. DE
VE
LO
PM
EN
TA
L T
OX
ICIT
Y:
No
t ava
ilabl
e. T
he
subs
tanc
e m
ay b
eto
xic
to c
entr
al n
erv
ous
sys
tem
(C
NS
). R
epea
ted
or p
rolo
nge
d e
xpo
sure
to
the
su
bsta
nce
can
pro
duce
tar
get
org
ans
dam
age
.
Sect
ion
4: F
irst A
id M
easu
res
Eye
Cont
act:
p. 2
Che
ck fo
r an
d re
mov
e a
ny
con
tact
len
ses.
Im
me
diat
ely
flu
sh e
yes
wit
h ru
nni
ng w
ate
r fo
r at
leas
t 15
min
utes
, ke
epin
g ey
elid
sop
en. C
old
wat
er m
ay b
e u
sed.
Get
med
ica
l atte
ntio
n.
Skin
Con
tact
:In
ca
se o
f co
ntac
t, im
med
iate
ly f
lush
ski
n w
ith p
len
ty o
f w
ate
r. C
over
the
irrit
ate
d sk
in w
ith a
n em
ollie
nt. R
emov
e c
onta
min
ate
dcl
othi
ng a
nd s
hoes
. C
old
wa
ter
ma
y b
e u
sed
.Wa
sh c
loth
ing
befo
re re
use.
Th
orou
ghly
cle
an s
hoes
bef
ore
reu
se.
Get
me
dic
alat
ten
tion.
Serio
us S
kin
Cont
act:
Was
h w
ith
a d
isin
fect
ant
soa
p an
d co
ver
the
con
tam
ina
ted
sk
in w
ith a
n an
ti-b
acte
rial c
rea
m.
See
k im
med
iate
med
ica
lat
ten
tion.
Inha
latio
n:If
inh
aled
, re
mov
e to
fres
h a
ir. I
f not
bre
ath
ing
, giv
e a
rtifi
cia
l res
pira
tion.
If b
reat
hin
g is
diff
icu
lt, g
ive
oxy
gen
. Ge
t me
dica
lat
ten
tion.
Serio
us In
hala
tion:
No
t ava
ilabl
e.
Inge
stio
n:D
o N
OT
indu
ce v
om
iting
unl
ess
dire
cted
to d
o so
by
me
dic
al p
ers
onn
el. N
ever
giv
e a
nyth
ing
by
mo
uth
to a
n u
nco
nsc
iou
spe
rso
n. If
larg
e q
uan
titie
s o
f th
is m
ate
rial a
re s
wal
low
ed, c
all
a ph
ysic
ian
imm
edia
tely
. Lo
ose
n tig
ht c
loth
ing
su
ch a
s a
colla
r,tie
, bel
t or w
aist
band
.
Serio
us In
gest
ion:
No
t ava
ilabl
e.
Sect
ion
5: F
ire a
nd E
xplo
sion
Dat
a
Flam
mab
ility
of t
he P
rodu
ct: M
ay b
e co
mb
ustib
le a
t hig
h te
mpe
ratu
re.
Aut
o-Ig
nitio
n Te
mpe
ratu
re: 3
71°
C (
699
.8°F
)
Flas
h Po
ints
: C
LO
SE
D C
UP
: 99°
C (
210
.2°F
). O
PE
N C
UP
: 107
°C (2
24.6
°F) (
Cle
vela
nd)
.
Flam
mab
le L
imits
: LO
WE
R: 2
.6%
UP
PE
R:
12.5
%
Prod
ucts
of C
ombu
stio
n: T
hese
pro
duc
ts a
re c
arb
on o
xide
s (C
O,
CO
2).
Fire
Haz
ards
in P
rese
nce
of V
ario
us S
ubst
ance
s: S
ligh
tly f
lam
mab
le to
flam
mab
le in
pre
senc
e o
f he
at.
Expl
osio
n Ha
zard
s in
Pre
senc
e of
Var
ious
Sub
stan
ces:
Ris
ks o
f exp
losi
on o
f th
e pr
oduc
t in
pre
sen
ce o
f m
ech
ani
cal i
mp
act:
No
t ava
ilab
le. R
isk
s o
f exp
losi
on
of t
he p
rod
uct i
npr
ese
nce
of
stat
ic d
isch
arg
e: N
ot a
vaila
ble.
Fire
Fig
htin
g M
edia
and
Inst
ruct
ions
:S
MA
LL F
IRE
: Use
DR
Y c
hem
ica
l po
wd
er.
LAR
GE
FIR
E:
Use
wa
ter
spra
y, fo
g o
r fo
am. D
o no
t use
wat
er je
t.
Spec
ial R
emar
ks o
n Fi
re H
azar
ds:
Whe
n he
ate
d to
de
com
posi
tion
it e
mits
ac
rid s
mok
e a
nd
irrit
atin
g fu
me
s.
Spec
ial R
emar
ks o
n Ex
plos
ion
Haz
ards
: No
t ava
ilabl
e.
Sect
ion
6: A
ccid
enta
l Rel
ease
Mea
sure
s
Smal
l Spi
ll:D
ilute
wit
h w
ate
r an
d m
op
up,
or
abso
rb w
ith
an in
ert
dry
ma
teri
al a
nd p
lace
in
an a
ppr
opr
iate
was
te d
isp
osal
co
nta
ine
r.F
inis
h c
lean
ing
by
spre
adi
ng w
ate
r on
the
con
tam
ina
ted
su
rfac
e a
nd
disp
ose
of a
cco
rdin
g to
loca
l and
regi
onal
aut
hor
ityre
quire
men
ts.
Larg
e Sp
ill:
Ab
sorb
with
an
ine
rt m
ater
ial a
nd p
ut t
he s
pille
d m
ater
ial i
n a
n ap
pro
pria
te w
aste
dis
posa
l. F
inis
h c
lean
ing
by s
pre
adi
ng w
ate
ron
the
cont
am
inat
ed
surf
ace
and
allo
w to
eva
cua
te th
roug
h th
e s
ani
tary
sys
tem
. Be
care
ful
that
the
pro
duc
t is
not
pre
sent
at
aco
nce
ntra
tion
lev
el a
bove
TLV
. Che
ck T
LV o
n th
e M
SD
S a
nd w
ith lo
cal a
uth
orit
ies.
Sect
ion
7: H
andl
ing
and
Stor
age
p. 3
Prec
autio
ns:
Ke
ep a
wa
y fr
om h
eat.
Ke
ep a
wa
y fr
om s
our
ces
of
igni
tion
. Em
pty
cont
aine
rs p
ose
a fi
re r
isk
, eva
por
ate
the
resi
due
un
der
afu
me
ho
od. G
roun
d al
l eq
uipm
ent c
ont
aini
ng m
ate
rial.
Do
not
inge
st.
Do
not b
rea
the
gas
/fum
es/
vap
or/s
pra
y. W
ear
su
itab
lepr
otec
tive
clo
thin
g. I
n ca
se o
f ins
uffi
cie
nt v
entil
atio
n, w
ear
su
itab
le re
spira
tory
eq
uipm
ent
. If
inge
sted
, se
ek m
edi
cal
advi
ceim
med
iate
ly a
nd s
how
the
con
tain
er o
r th
e la
bel.
Avo
id c
ont
act
with
ski
n a
nd e
yes
. Ke
ep a
way
fro
m in
com
pat
ible
s su
ch a
sox
idiz
ing
age
nts,
red
ucin
g a
gent
s, a
cid
s, a
lka
lis, m
ois
ture
.
Stor
age:
Hyg
rosc
opi
c. K
eep
con
tain
er t
ight
ly c
los
ed. K
eep
con
tain
er in
a c
ool
, wel
l-ve
ntila
ted
are
a. D
o n
ot s
tore
ab
ove
23
°C (7
3.4
°F).
Sect
ion
8: E
xpos
ure
Cont
rols
/Per
sona
l Pro
tect
ion
Engi
neer
ing
Con
trol
s:P
rovi
de
exh
aus
t ve
ntil
atio
n or
oth
er e
ngin
eerin
g co
ntro
ls to
kee
p th
e a
irbo
rne
con
cen
trat
ions
of v
apo
rs b
elo
w t
heir
res
pect
ive
thre
sho
ld li
mit
valu
e. E
nsu
re t
hat e
yew
ash
sta
tions
and
sa
fety
sho
we
rs a
re p
roxi
mal
to th
e w
ork
-sta
tion
loca
tion.
Pers
onal
Pro
tect
ion:
Sp
lash
go
ggle
s. L
ab
coa
t. V
apo
r re
spira
tor.
Be
sure
to
use
an
appr
ove
d/ce
rtifi
ed r
esp
irato
r or
equ
iva
lent
. Glo
ves.
Pers
onal
Pro
tect
ion
in C
ase
of a
Lar
ge S
pill:
Sp
lash
go
ggle
s. F
ull
sui
t. V
apor
re
spir
ato
r. B
oot
s. G
love
s. A
se
lf c
onta
ined
bre
athi
ng a
ppar
atus
sh
ould
be
use
d to
avo
idin
hala
tion
of
the
pro
duc
t. S
ugge
sted
pro
tect
ive
clo
thin
g m
igh
t not
be
su
ffici
ent
; co
nsu
lt a
spe
cia
list B
EFO
RE
ha
ndlin
g th
ispr
oduc
t.
Expo
sure
Lim
its:
TW
A: 1
0 (m
g/m
3) f
rom
AIH
A C
onsu
lt lo
cal a
uth
orit
ies
for
acc
epta
ble
expo
sure
lim
its.
Sect
ion
9: P
hysi
cal a
nd C
hem
ical
Pro
pert
ies
Phys
ical
sta
te a
nd a
ppea
ranc
e: L
iqu
id. (
Oily
liq
uid.
)
Odo
r: P
ract
ical
ly O
dor
less
.
Tast
e: P
ract
ical
ly T
aste
less
.
Mol
ecul
ar W
eigh
t: 7
6.1
g/m
ole
Col
or:
Co
lorle
ss. C
lear
pH (1
% s
oln/
wat
er):
No
t ava
ilabl
e.
Boi
ling
Poin
t: 18
8°C
(3
70.4
°F)
Mel
ting
Poin
t: -
59°C
(-7
4.2
°F)
Crit
ical
Tem
pera
ture
: N
ot a
vaila
ble.
Spec
ific
Gra
vity
: 1.0
36
(Wa
ter
= 1
)
Vapo
r Pr
essu
re:
0 kP
a (@
20°
C)
0.0
8 m
mH
g a
t 20
C 0
.129
mm
Hg
at 2
5 C
Vapo
r De
nsity
: 2.
62 (
Air
= 1
)
Vola
tility
: N
ot a
vaila
ble.
Odo
r Thr
esho
ld:
No
t ava
ilabl
e.
Wat
er/O
il D
ist.
Coef
f.: T
he p
rod
uct i
s m
ore
sol
ubl
e in
wa
ter;
log(
oil/
wat
er) =
-0.
9
Ioni
city
(in
Wat
er):
No
t ava
ilabl
e.
Dis
pers
ion
Prop
ertie
s: S
ee s
olub
ility
in w
ater
, ace
ton
e.
p. 4
Solu
bilit
y: S
olub
le in
co
ld w
ate
r, h
ot w
ate
r, a
ceto
ne.
Sect
ion
10: S
tabi
lity
and
Rea
ctiv
ity D
ata
Stab
ility
: T
he p
rod
uct i
s s
tabl
e.
Inst
abili
ty T
empe
ratu
re:
No
t ava
ilabl
e.
Con
ditio
ns o
f Ins
tabi
lity:
Inco
mpa
tible
ma
teri
als,
exc
ess
hea
t, e
xpo
sure
to
mo
ist
air o
r w
ate
r
Inco
mpa
tibili
ty w
ith v
ario
us s
ubst
ance
s: R
eac
tive
with
ox
idiz
ing
age
nts,
red
ucin
g a
gent
s, a
cids
, al
kalis
.
Cor
rosi
vity
: N
on-
cor
rosi
ve in
pre
sen
ce o
f gl
ass
.
Spec
ial R
emar
ks o
n Re
activ
ity:
Hyg
rosc
opi
c; k
eep
con
tain
er t
ight
ly c
lose
d. I
nco
mp
atib
le w
ith c
hlo
rofo
rma
tes,
stro
ng a
cids
(n
itric
aci
d, h
ydro
flulo
ric a
cid
),ca
ustic
s, a
liph
atic
am
ines
, is
ocy
ana
tes,
str
ong
oxid
izer
s, a
cid
anh
ydri
des,
silv
er n
itrat
e, r
edu
cin
g ag
ents
.
Spec
ial R
emar
ks o
n Co
rros
ivity
: No
t ava
ilabl
e.
Poly
mer
izat
ion:
Will
no
t occ
ur.
Sect
ion
11: T
oxic
olog
ical
Info
rmat
ion
Rou
tes
of E
ntry
: Abs
orb
ed th
rou
gh s
kin
. Ey
e co
nta
ct.
Toxi
city
to A
nim
als:
Acu
te o
ral t
oxic
ity (
LD
50)
: 18
500
mg
/kg
[Ra
bbit]
. Acu
te d
erm
al t
oxic
ity (
LD50
): 2
080
0 m
g/k
g [R
abbi
t].
Chr
onic
Effe
cts
on H
uman
s: M
ay c
ause
da
ma
ge to
the
follo
win
g o
rga
ns:
cen
tral
ner
vou
s sy
stem
(CN
S).
Oth
er T
oxic
Effe
cts
on H
uman
s:H
aza
rdo
us i
n ca
se
of in
gest
ion.
Slig
htly
ha
zard
ous
in c
ase
of s
kin
co
nta
ct (i
rrita
nt, p
erm
eato
r),
of in
hala
tion
.
Spec
ial R
emar
ks o
n To
xici
ty to
Ani
mal
s: N
ot a
vaila
ble.
Spec
ial R
emar
ks o
n Ch
roni
c Ef
fect
s on
Hum
ans:
Ma
y af
fect
ge
netic
ma
teria
l (m
uta
geni
c).
May
ca
use
adve
rse
repr
odu
ctiv
e e
ffect
s an
d bi
rth
defe
cts
(ter
ato
geni
c) b
ase
d on
anim
al te
st d
ata.
Spec
ial R
emar
ks o
n ot
her T
oxic
Eff
ects
on
Hum
ans:
Acu
te P
ote
ntia
l Hea
lth E
ffec
ts:
Ski
n: M
ay c
aus
e m
ild s
kin
irrit
atio
n. It
ma
y be
abs
orb
ed th
rou
gh th
e sk
in a
nd
caus
e s
yste
mic
effe
cts
sim
ilar
to t
hose
of i
nges
tion
. Eye
s: M
ay c
aus
e m
ild e
ye
irrit
atio
n w
ith
som
e im
med
iate
, tra
nsit
ory
stin
ging
, lac
rim
atio
n,
blep
haro
spa
sm,
and
mild
tra
nsi
ent
co
nju
nctiv
al h
yper
em
ia. T
her
e is
no
res
idu
al d
isc
omfo
rt o
r inj
ury
onc
e it
is w
ash
ed
awa
y. I
nhal
atio
n: M
ay
cau
se r
esp
irat
ory
tra
ct ir
rita
tion
. In
gest
ion
: It
may
ca
use
gast
roin
tes
tina
l tra
ct ir
rita
tion.
It m
ay
affe
ctbe
havi
or/c
ent
ral
nerv
ous
syst
em(C
NS
de
pre
ssio
n, g
ene
ral a
nes
thet
ic,
con
vuls
ion
s, s
eiz
ure
s, s
om
nol
enc
e, s
tupo
r, m
usc
leco
ntra
ctio
n o
r sp
astic
ity,
co
ma
), b
rain
(ch
ange
s in
su
rfac
e E
EG
), m
etab
olis
m, b
lood
(in
tra
vasc
ula
r he
mol
ysis
, whi
te b
loo
dce
lls -
dec
reas
ed n
eutr
ophi
l fu
nctio
n),
resp
iratio
n (r
esp
irato
ry s
timu
latio
n, c
hro
nic
pulm
ona
ry e
dem
a, c
yan
osis
), c
ard
iova
scul
ar
syst
em
(hyp
ote
nsio
n, b
rady
card
ia,
arrh
ythm
ias,
ca
rdia
c a
rres
t), e
ndo
crin
e sy
ste
m (
hypo
glyc
emia
), u
rinar
y sy
ste
m (
kid
neys
),an
d liv
er.
Chr
oni
c P
ote
ntia
l He
alth
Eff
ects
: S
kin
: Pro
long
ed o
r re
peat
ed s
kin
con
tact
may
ca
use
alle
rgic
con
tact
der
mat
itis.
Ing
esti
on: P
rolo
nged
or
rep
eate
d in
ges
tion
may
ca
use
hyp
erg
lyce
mia
an
d m
ay
affe
ct b
eha
vio
r/C
NS
(sy
mp
tom
s si
mila
r to
tha
tof
ac
ute
ing
estio
n).
Inh
alat
ion:
Pro
lon
ged
or r
epea
ted
inha
latio
n m
ay a
ffect
beh
avio
r/C
NS
(with
sym
pto
ms
sim
ilar
to in
gest
ion
),an
d sp
leen
Sect
ion
12: E
colo
gica
l Inf
orm
atio
n
Ecot
oxic
ity:
Eco
toxi
city
in w
ate
r (L
C50
): >
5000
mg/
l 24
hou
rs [G
old
fish]
. >1
0000
mg/
l 48
hour
s [g
uppy
]. >
100
00 m
g/l 4
8 ho
urs
[wat
er f
lea]
.
BOD
5 an
d C
OD:
No
t ava
ilabl
e.
p. 5
Prod
ucts
of B
iode
grad
atio
n:P
oss
ibly
haz
ard
ous
sh
ort t
erm
deg
rad
atio
n p
rod
ucts
are
not
like
ly. H
owev
er,
lon
g te
rm d
egra
dat
ion
pro
duc
ts m
ay
aris
e.
Toxi
city
of t
he P
rodu
cts
of B
iode
grad
atio
n: T
he p
rod
ucts
of d
egra
dat
ion
are
less
tox
ic th
an th
e p
rod
uct
itse
lf.
Spec
ial R
emar
ks o
n th
e Pr
oduc
ts o
f Bio
degr
adat
ion:
No
t ava
ilabl
e.
Sect
ion
13: D
ispo
sal C
onsi
dera
tions
Was
te D
ispo
sal:
Sect
ion
14: T
rans
port
Info
rmat
ion
DOT
Cla
ssifi
catio
n: N
ot a
DO
T c
ontr
olle
d m
ate
rial (
Un
ited
Sta
tes
).
Iden
tific
atio
n: N
ot a
pplic
able
.
Spec
ial P
rovi
sion
s fo
r Tra
nspo
rt: N
ot a
pplic
able
.
Sect
ion
15: O
ther
Reg
ulat
ory
Info
rmat
ion
Fede
ral a
nd S
tate
Reg
ulat
ions
:P
enn
sylv
ania
RT
K: P
rop
yle
ne g
lyco
l Min
nes
ota
: P
rop
yle
ne g
lyco
l TS
CA
8(b
) in
vent
ory
: Pro
pyle
ne
gly
col
Oth
er R
egul
atio
ns: E
INE
CS
: T
his
pro
duc
t is
on
the
Eur
ope
an In
ven
tory
of E
xis
ting
Com
me
rcia
l Che
mic
al S
ubs
tanc
es.
Oth
er C
lass
ifica
tions
:
WHM
IS (C
anad
a):
No
t co
ntro
lled
und
er W
HM
IS (
Ca
nada
).
DSC
L (E
EC):
R21
/22-
Har
mfu
l in
con
tact
with
ski
n a
nd if
sw
allo
wed
. S2
4/2
5- A
void
co
nta
ct w
ith s
kin
and
eye
s.
HM
IS (U
.S.A
.):
Hea
lth H
azar
d: 2
Fire
Haz
ard:
1
Rea
ctiv
ity: 0
Pers
onal
Pro
tect
ion:
h
Nat
iona
l Fir
e Pr
otec
tion
Asso
ciat
ion
(U.S
.A.):
Hea
lth: 0
Flam
mab
ility
: 1
Rea
ctiv
ity: 0
Spec
ific
haza
rd:
Prot
ectiv
e Eq
uipm
ent:
Glo
ves
. Lab
co
at.
Vap
or r
esp
irat
or.
Be
sur
e to
use
an
app
rov
ed/c
ert
ifie
d re
spir
ato
r or
equi
vale
nt.
Sp
lash
go
ggle
s.
Sect
ion
16: O
ther
Info
rmat
ion
Ref
eren
ces:
-Haw
ley,
G.G
.. T
he C
ond
ense
d C
hem
ical
Dic
tion
ary,
11
e e
d., N
ew Y
ork
N.Y
., V
an
Nos
tra
nd R
eino
ld, 1
987.
-S
AX
, N
.I.
Dan
gero
us
Pro
per
ties
of
Ind
utria
l Ma
teri
als
. Tor
onto
, Va
n N
ostr
and
Rei
nold
, 6e
ed.
19
84. -
The
Sig
ma
-Ald
rich
Lib
rary
of
Che
mic
al S
afe
ty D
ata
, Edi
tion
II. -
Sup
plie
r M
SD
S -
LO
LI -
RT
EC
S -
HS
DB
p. 6
Oth
er S
peci
al C
onsi
dera
tions
: N
ot a
vaila
ble.
Cre
ated
: 10
/10/
200
5 08
:24
PM
Last
Upd
ated
: 06
/09/
201
2 12
:00
PM
The
info
rmat
ion
abo
ve is
bel
ieve
d t
o be
acc
ura
te a
nd r
epre
sen
ts t
he
best
info
rma
tion
cu
rren
tly a
vaila
ble
to u
s. H
ow
eve
r, w
em
ake
no
war
ran
ty o
f me
rcha
nta
bilit
y or
an
y ot
her w
arra
nty
, exp
ress
or
imp
lied,
with
res
pec
t to
suc
h in
form
atio
n, a
nd
we
ass
um
eno
liab
ility
re
sulti
ng f
rom
its
us
e. U
ser
s sh
ould
ma
ke t
hei
r ow
n in
vest
igat
ions
to
de
term
ine
the
sui
tabi
lity
of
the
info
rma
tion
for
the
ir pa
rtic
ula
r pur
pose
s. I
n no
eve
nt s
hall
Sci
ence
Lab
.com
be
liab
le fo
r a
ny c
laim
s, lo
sse
s, o
r da
ma
ges
of a
ny t
hird
par
ty o
r fo
rlo
st p
rofi
ts o
r a
ny s
peci
al,
indi
rect
, inc
ide
ntal
, co
nse
quen
tial o
r exe
mpl
ary
dam
age
s, h
owso
eve
r aris
ing
, ev
en if
Sci
ence
Lab
.com
has
been
ad
vise
d o
f the
po
ssib
ility
of
such
da
mag
es.
Dim
eth
yl S
ulfid
e (D
MS
)SA
FETY
DAT
A SH
EET
Dat
e of
Pre
para
tion:
Oct
ober
18,
201
7
Page
1of
10
Aeg
is R
egul
ator
y In
c.
Sect
ion
1: ID
ENTI
FIC
ATIO
N
Prod
uct N
ame:
Dim
ethy
l Sul
fide
(DM
S)Sy
nony
ms:
Dim
ethy
l sul
phid
e.Pr
oduc
t Use
:S
ee T
echn
ical D
ata
She
et.
Res
tric
tions
on
Use
:N
ot a
vaila
ble.
M
anuf
actu
rer/
Supp
lier:
Gay
lord
Che
mic
al C
ompa
ny, L
LC18
80 F
airla
wn
Rd
Tusc
aloo
sa, A
L 35
401
Uni
ted
Sta
tes
Emer
genc
y Ph
one:
CH
EM
TR
EC (U
SA
): (8
00) 4
24-9
300
Cus
tom
er S
ervi
ce: G
aylo
rd C
hem
ical C
ompa
ny, L
LC:
(985
) 649
-546
4 (8
:00a
m -
5:00
pm C
ST)
(205
) 342
-065
2 (N
ight
s an
d W
eeke
nds)
Dat
e of
Pre
para
tion
of S
DS:
Oct
ober
18,
201
7
Sect
ion
2: H
AZA
RD(
S) I
DEN
TIFI
CATI
ON
GHS
INFO
RM
ATIO
N
Cla
ssifi
catio
n:Fl
amm
able
Liq
uids
, Cat
egor
y 2
LAB
EL E
LEM
ENTS
Haz
ard
Pict
ogra
m(s
):
Sign
al W
ord:
Dan
ger
Haz
ard
Stat
emen
ts:
Hig
hly
flam
mab
le li
quid
and
vap
or.
Prec
autio
nary
Sta
tem
ents
Prev
entio
n:K
eep
away
from
hea
t, ho
t sur
face
s, s
park
s, o
pen
flam
es a
nd o
ther
igni
tion
sour
ces.
No
smok
ing.
K
eep
cont
aine
r tig
htly
clos
ed.
Gro
und
and
bond
con
tain
er a
nd re
ceiv
ing
equi
pmen
t. U
se e
xplo
sion
-pro
of e
lect
rical
, ven
tilat
ing,
and
ligh
ting
equi
pmen
t. U
se n
on-s
park
ing
tool
s.
Take
act
ion
to p
reve
nt s
tatic
dis
char
ges.
W
ear p
rote
ctiv
e gl
oves
, pro
tect
ive
clot
hing
and
eye
pro
tect
ion.
Res
pons
e:IF
ON
SK
IN (o
r hai
r): T
ake
off i
mm
edia
tely
all
cont
amin
ated
clo
thin
g. R
inse
ski
n w
ith w
ater
or s
how
er.
In c
ase
of fi
re: U
se d
ry c
hem
ical
, CO
2, w
ater
spr
ay o
r re
gula
r foa
mto
ext
ingu
ish.
Stor
age:
Sto
re in
a w
ell-v
entil
ated
pla
ce. K
eep
cool
.
Dis
posa
l:D
ispo
se o
f con
tent
s/co
ntai
ner i
n ac
cord
ance
with
app
licab
le r
egio
nal,
natio
nal
and
loca
l law
s an
d re
gula
tions
.
Dim
eth
yl S
ulfid
e (D
MS
)SA
FETY
DAT
A SH
EET
Dat
e of
Pre
para
tion:
Oct
ober
18,
201
7
Page
2of
10
Aeg
is R
egul
ator
y In
c.
Haz
ards
Not
Oth
erw
ise
Cla
ssifi
ed:
Not
app
licab
le.
Ingr
edie
nts
with
Unk
now
n To
xici
ty:
Non
e.
This
mat
eria
l is
cons
ider
ed h
azar
dous
by
the
OSH
A H
azar
d C
omm
unic
atio
n S
tand
ard,
(29
CFR
19
10.1
200)
.
This
mat
eria
l is
cons
ider
ed h
azar
dous
by
the
Haz
ardo
us P
rodu
cts
Reg
ulat
ions
.
Sect
ion
3: C
OM
POSI
TIO
N / I
NFO
RMAT
ION
ON
ING
RED
IEN
TS
Haz
ardo
us In
gred
ient
(s)
Com
mon
nam
e / S
ynon
yms
CAS
No.
% w
t./w
t.M
etha
ne, 1
,1'-t
hiob
is-
Dim
ethy
l sul
fide;
DM
S75
-18-
310
0Im
purit
ies
/ Sta
biliz
ing
addi
tives
:Non
e kn
own.
Sect
ion
4: F
IRST
-AID
MEA
SUR
ES
Inha
latio
n:If
inha
led:
Rem
ove
pers
on to
fres
h ai
r and
kee
p co
mfo
rtab
le fo
r bre
athi
ng.
Cal
l a p
oiso
n ce
nter
or d
octo
r if y
ou fe
el u
nwel
l. Ac
ute
and
dela
yed
sym
ptom
s an
d ef
fect
s:M
ay c
ause
resp
irato
ry ir
ritat
ion.
S
igns
/sym
ptom
s m
ay in
clud
e co
ugh,
sne
ezin
g, n
asal
dis
char
ge,
head
ache
, hoa
rsen
ess,
and
nos
e an
d th
roat
pai
n. E
xces
sive
inha
latio
n m
ay c
ause
hea
dach
e, d
izzin
ess,
con
fusi
on, l
oss
of a
ppet
ite a
nd/o
r los
s of
co
nsci
ousn
ess.
Vap
or in
hala
tion
may
cau
sem
oder
ate
eye,
nos
e, a
nd
thro
at ir
ritat
ion,
mak
ing
it un
likel
y th
at in
divi
dual
s w
ill to
lera
te m
oder
ate
to
high
con
cent
ratio
ns. H
eada
che
and
decr
ease
d ab
ility
to c
once
ntra
te m
ay
occu
r.Ey
e Co
ntac
t:If
in e
yes:
Rin
se c
autio
usly
with
wat
er fo
r at l
east
20
min
utes
. Rem
ove
cont
act l
ense
s, if
pre
sent
and
eas
y to
do.
Con
tinue
rin
sing
. If e
ye ir
ritat
ion
pers
ists:
Get
med
ical
adv
ice/
atte
ntio
n.
Acut
e an
d de
laye
d sy
mpt
oms
and
effe
cts:
May
cau
se e
ye ir
ritat
ion.
S
igns
/sym
ptom
s m
ay in
clud
e re
dnes
s, s
welli
ng, p
ain,
tear
ing,
and
blu
rred
or
haz
y vi
sion
. Sk
in C
onta
ct:
If on
ski
n (o
r hai
r): T
ake
off i
mm
edia
tely
all
cont
amin
ated
clo
thin
g. R
inse
sk
in w
ith w
ater
or s
howe
r. C
all a
poi
son
cent
er o
r doc
tor i
f you
feel
unw
ell.
Was
hco
ntam
inat
ed c
loth
ing
befo
re re
use.
Acut
e an
d de
laye
d sy
mpt
oms
and
effe
cts:
May
cau
sesk
in ir
ritat
ion.
S
igns
/sym
ptom
s m
ay in
clud
e lo
caliz
ed r
edne
ss, s
wel
ling,
and
itch
ing.
In
gest
ion:
If sw
allo
wed
: Cal
l a p
oiso
n ce
nter
or d
octo
r if y
ou fe
el u
nwel
l. If
vom
iting
oc
curs
nat
ural
ly, h
ave
vict
im le
an fo
rwar
d to
redu
ce th
e ris
k of
asp
iratio
n.
Do
NO
T in
duce
vom
iting
unl
ess
dire
cted
to d
o so
by
med
ical
per
sonn
el.
Nev
er g
ive
anyt
hing
by
mou
th to
an
unco
nsci
ous
pers
on.
Acut
e an
dde
laye
d sy
mpt
oms
and
effe
cts:
May
cau
se g
astro
inte
stin
al
irrita
tion.
Sig
ns/s
ympt
oms
may
incl
ude
abdo
min
al p
ain,
sto
mac
h up
set,
naus
ea, v
omiti
ng a
nd d
iarr
hea.
G
ener
al A
dvic
e:In
cas
e of
acc
iden
t or
if yo
u fe
el u
nwel
l, se
ek m
edic
al a
dvic
e im
med
iate
ly
(sho
w th
e la
bel o
r SD
S w
here
pos
sibl
e).
Dim
eth
yl S
ulfid
e (D
MS
)SA
FETY
DAT
A SH
EET
Dat
e of
Pre
para
tion:
Oct
ober
18,
201
7
Page
3of
10
Aeg
is R
egul
ator
y In
c.
Not
e to
Phy
sici
ans:
Sym
ptom
s m
ay n
ot a
ppea
r im
med
iate
ly.
Sect
ion
5: F
IRE-
FIGH
TING
MEA
SUR
ES
FLAM
MAB
ILIT
Y AN
D EX
PLO
SIO
N IN
FORM
ATIO
NH
ighl
y fla
mm
able
liqu
id a
nd v
apor
. Will
be
easi
ly ig
nite
d by
hea
t, sp
arks
or f
lam
es. V
apor
s m
ay
form
exp
losi
ve m
ixtu
res
with
air.
Vap
ors
may
trav
el to
sou
rce
of ig
nitio
n an
d fla
sh b
ack.
Mos
t va
pors
are
hea
vier
than
air.
The
y wi
ll sp
read
alo
ng g
roun
d an
d co
llect
in lo
w o
r con
fined
are
as
(sew
ers,
bas
emen
ts, t
anks
). V
apor
exp
losi
on h
azar
d in
door
s, o
utdo
ors
or in
sew
ers.
Run
off t
o se
wer
may
cre
ate
fire
or e
xplo
sion
haz
ard.
Con
tain
ers
may
exp
lode
whe
n he
ated
. Man
y liq
uids
ar
e lig
hter
than
wat
er.
If ta
nk, r
ail c
ar o
r tan
k tru
ck is
invo
lved
in a
fire
, ISO
LATE
for 8
00 m
eter
s (1
/2 m
ile) i
n al
l di
rect
ions
; als
o, c
onsi
der i
nitia
l eva
cuat
ion
for 8
00 m
eter
s (1
/2 m
ile) i
n al
l dire
ctio
ns.
Fire
invo
lving
Tan
ks o
r Ca
r/Tr
aile
r Loa
ds: F
ight
fire
from
max
imum
dis
tanc
e or
use
unm
anne
d ho
se h
olde
rs o
r m
onito
r no
zzle
s. C
ool c
onta
iner
s w
ith fl
oodi
ng q
uant
ities
of w
ater
unt
il w
ell a
fter
fire
is o
ut. W
ithdr
aw im
med
iate
ly in
cas
e of
risi
ng s
ound
from
ven
ting
safe
ty d
evic
es o
r di
scol
orat
ion
of ta
nk. A
LWAY
S st
ay a
way
from
tank
s en
gulfe
d in
fire
. For
mas
sive
fire
, use
un
man
ned
hose
hol
ders
or m
onito
r noz
zles
; if t
his
is im
poss
ible
, with
draw
from
are
a an
d le
t fire
bu
rn.
Sens
itivi
ty to
Mec
hani
cal I
mpa
ct:
This
mat
eria
l is
not s
ensi
tive
to m
echa
nica
l im
pact
. Se
nsiti
vity
to S
tatic
Dis
char
ge:
Take
actio
n to
pre
vent
sta
tic d
isch
arge
s. T
his
mat
eria
l is
sens
itive
to s
tatic
dis
char
ge.
ME
ANS
OF
EXTI
NCTI
ONSu
itabl
e Ex
tingu
ishi
ng M
edia
:S
mal
l Fire
: Dry
che
mic
al, C
O2,
wat
er s
pray
or
regu
lar f
oam
.
Larg
e Fi
re: W
ater
spr
ay, f
og o
r reg
ular
foam
. Mov
e co
ntai
ners
from
fire
are
a if
you
can
do it
with
out r
isk.
Uns
uita
ble
Extin
guis
hing
Med
ia:
Do
not u
se s
traig
ht s
trea
ms.
CA
UTI
ON
: Thi
spr
oduc
t has
a ve
ry lo
w fl
ash
poin
t: U
se o
f wat
er s
pray
whe
n fig
htin
g fir
e m
ay b
e in
effic
ient
. Pr
oduc
ts o
f Com
bust
ion:
Oxi
des
of c
arbo
n. O
xides
of s
ulph
ur.
Prot
ectio
n of
Fir
efig
hter
s:Fi
re w
ill pr
oduc
e irr
itatin
g, c
orro
sive
and
/or t
oxic
gas
es.
Vap
ors
may
cau
se d
izzi
ness
or s
uffo
catio
n.R
unof
f fro
m fi
re
cont
rol o
r dilu
tion
wat
er m
ay c
ause
pol
lutio
n. W
ear p
ositi
ve
pres
sure
sel
f-con
tain
ed b
reat
hing
app
arat
us (
SCB
A).
Stru
ctur
al fi
refig
hter
s' p
rote
ctiv
e cl
othi
ng w
ill on
ly p
rovi
de
limite
d pr
otec
tion.
Sect
ion
6: A
CCI
DEN
TAL
REL
EASE
MEA
SUR
ES
Emer
genc
y Pr
oced
ures
: A
s an
imm
edia
te p
reca
utio
nary
mea
sure
, iso
late
spi
ll or
leak
are
a fo
r at l
east
50
met
ers
(150
feet
) in
all d
irect
ions
. Kee
p un
auth
oriz
ed p
erso
nnel
aw
ay. S
tay
upw
ind.
Kee
p ou
t of l
ow
area
s. V
entila
te c
lose
d sp
aces
bef
ore
ente
ring.
ELI
MIN
ATE
all
igni
tion
sour
ces
(no
smok
ing,
flar
es, s
park
s or
flam
es in
im
med
iate
are
a). A
ll eq
uipm
ent u
sed
whe
n ha
ndlin
g th
e pr
oduc
t m
ust b
e gr
ound
ed.
Dim
eth
yl S
ulfid
e (D
MS
)SA
FETY
DAT
A SH
EET
Dat
e of
Pre
para
tion:
Oct
ober
18,
201
7
Page
4of
10
Aeg
is R
egul
ator
y In
c.
Pers
onal
Pre
caut
ions
:D
o no
t tou
ch o
r wal
k th
roug
h sp
illed
mat
eria
l. U
se p
erso
nal
prot
ectio
n re
com
men
ded
in S
ectio
n 8.
En
viro
nmen
tal P
reca
utio
ns:
Pre
vent
ent
ry in
to w
ater
way
s, s
ewer
s, b
asem
ents
or c
onfin
ed
area
s.
Met
hods
for C
onta
inm
ent:
Sto
p le
ak if
you
can
do
it w
ithou
t risk
. A v
apor
sup
pres
sing
foam
m
ay b
e us
ed to
red
uce
vapo
rs.
Met
hods
for C
lean
-Up:
Abs
orb
or c
over
with
dry
ear
th, s
and
or o
ther
non
-com
bust
ible
m
ater
ial a
nd tr
ansf
er to
con
tain
ers.
Use
cle
an n
on-s
park
ing
tool
s to
col
lect
abs
orbe
d m
ater
ial.
Oth
er In
form
atio
n:S
ee S
ectio
n 13
for d
ispo
sal c
onsi
dera
tions
.
Sect
ion
7: H
AND
LIN
G A
ND
STO
RAG
E
Han
dlin
g:D
o no
t sw
allo
w. A
void
bre
athi
ng m
ist,
vapo
urs,
or s
pray
. Kee
p aw
ay fr
om h
eat,
hot s
urfa
ces,
sp
arks
, ope
n fla
mes
and
oth
er ig
nitio
n so
urce
s. N
o sm
okin
g. K
eep
cont
aine
r tig
htly
clo
sed.
G
roun
d an
d bo
nd c
onta
iner
and
rece
ivin
g eq
uipm
ent.
Use
non
-spa
rkin
g to
ols.
Tak
e ac
tion
to
prev
ent s
tatic
dis
char
ges.
Was
h th
orou
ghly
afte
r han
dlin
g. U
se o
nly
outd
oors
or
in a
wel
l-ve
ntila
ted
area
. S
ee S
ectio
n 8
for i
nfor
mat
ion
on P
erso
nal P
rote
ctiv
e Eq
uipm
ent.
Stor
age:
Sto
re in
a w
ell-v
entil
ated
pla
ce.K
eep
cont
aine
r tig
htly
clo
sed.
Kee
p co
ol. S
tore
lock
ed u
p. S
tore
aw
ay fr
om in
com
patib
le m
ater
ials
. See
Sec
tion
10 fo
r inf
orm
atio
n on
Inco
mpa
tible
Mat
eria
ls.
Kee
p ou
t of t
he re
ach
of c
hild
ren.
Se
ctio
n 8:
EXP
OSU
RE
CO
NTR
OLS
/ PE
RSO
NAL
PRO
TEC
TION
Expo
sure
Gui
delin
esC
ompo
nent
Dim
ethy
l sul
fide
(DM
S)[
CA
S N
o.75
-18-
3]AC
GIH
:10
ppm
(TW
A);
(200
1)O
SHA:
No
PEL
esta
blis
hed.
PEL:
Per
mis
sibl
e E
xpos
ure
Lim
itTW
A: T
ime-
Wei
ghte
d Av
erag
e
Engi
neer
ing
Con
trol
s:U
se v
entil
atio
n ad
equa
te to
kee
p ex
posu
res
(airb
orne
leve
ls
of d
ust,
fum
e, v
apou
r, ga
s, e
tc.)
belo
w r
ecom
men
ded
expo
sure
lim
its. U
se e
xplo
sion
-pro
of e
lect
rical
, ven
tilat
ing,
an
d lig
htin
g eq
uipm
ent.
PER
SON
AL P
ROTE
CTI
VE E
QUI
PME
NT (P
PE)
Eye/
Face
Pro
tect
ion:
Wea
r ch
emic
al s
afet
y go
ggle
s. E
nsur
e th
at e
yew
ash
stat
ions
are
clo
se to
the
wor
ksta
tion
loca
tion.
Use
equ
ipm
ent
for e
ye p
rote
ctio
n th
at m
eets
the
stan
dard
s re
fere
nced
by
Dim
eth
yl S
ulfid
e (D
MS
)SA
FETY
DAT
A SH
EET
Dat
e of
Pre
para
tion:
Oct
ober
18,
201
7
Page
5of
10
Aeg
is R
egul
ator
y In
c.
CS
A S
tand
ard
CA
N/C
SA-Z
94.3
-92
and
OSH
A re
gula
tions
in
29 C
FR 1
910.
133
for
Per
sona
l Pro
tect
ive
Equi
pmen
t. H
and
Pro
tect
ion:
Wea
r pro
tect
ive
glov
es.
But
yl o
r nitr
ile ru
bber
glo
ves
are
reco
mm
ende
d.C
onsu
lt m
anuf
actu
rer s
peci
ficat
ions
for
furth
er in
form
atio
n.
Skin
and
Bod
y P
rote
ctio
n:W
ear p
rote
ctiv
e cl
othi
ng. F
lam
e re
sist
ant c
loth
ing
that
mee
ts
the
NFP
A 2
112
and
CAN
/CG
SB 1
55.2
0 st
anda
rds
is
reco
mm
ende
d in
are
as w
here
mat
eria
l is s
tore
d or
han
dled
. R
espi
rato
ry P
rote
ctio
n:If
engi
neer
ing
cont
rols
and
ven
tilat
ion
are
not s
uffic
ient
to
cont
rol e
xpos
ure
to b
elow
the
allo
wabl
e lim
its th
en a
n ap
prop
riate
NIO
SH
/MS
HA
app
rove
d ai
r-pu
rifyi
ng re
spira
tor
that
mee
ts th
e re
quire
men
ts o
f CSA
Sta
ndar
d C
AN/C
SA
-Z9
4.4-
11, w
ith o
rgan
ic v
apor
car
tridg
e, o
r sel
f-con
tain
ed
brea
thin
g ap
para
tus
mus
t be
used
. Sup
plie
d ai
r bre
athi
ng
appa
ratu
s m
ust b
e us
ed w
hen
oxyg
en c
once
ntra
tions
are
lo
w o
r if a
irbor
ne c
once
ntra
tions
exc
eed
the
limits
of t
he a
ir-pu
rifyin
g re
spira
tors
. G
ener
al H
ygie
ne C
onsi
dera
tions
:H
andl
e ac
cord
ing
to e
stab
lishe
d in
dust
rial h
ygie
ne a
nd
safe
ty p
ract
ices
. Con
sult
a co
mpe
tent
indu
stria
l hyg
ieni
st to
de
term
ine
haza
rd p
oten
tial a
nd/o
r the
PPE
man
ufac
ture
rs to
en
sure
ade
quat
e pr
otec
tion.
Sect
ion
9: P
HYSI
CAL
AND
CH
EMIC
AL P
ROPE
RTIE
S
Appe
aran
ce:
Cle
ar, c
olor
less
liqu
id.
Col
our:
Col
orle
ss.
Odo
ur:
Ste
nch.
Odo
ur T
hres
hold
:2.
5pp
mPh
ysic
al S
tate
:Li
quid
. pH
:N
otav
aila
ble.
Mel
ting
Poin
t / F
reez
ing
Poin
t:-9
8 °C
(-1
44.4
°F)
Initi
al B
oilin
g Po
int:
37.3
°C (
99.1
°F)
Boi
ling
Ran
ge:
Not
ava
ilabl
e.Fl
ash
Poin
t:-4
9 °C
(-5
6.2
°F)
Evap
orat
ion
Rat
e:N
ot a
vaila
ble.
Flam
mab
ility
(sol
id, g
as):
Not
app
licab
le.
Low
er F
lam
mab
ility
Lim
it:2.
2 %
Upp
er F
lam
mab
ility
Lim
it:19
.7 %
Vapo
r Pr
essu
re:
53.2
kP
a at
20
°C (
68 °
F)
103.
4 kP
a at
38
°C (1
00 °F
)
Dim
eth
yl S
ulfid
e (D
MS
)SA
FETY
DAT
A SH
EET
Dat
e of
Pre
para
tion:
Oct
ober
18,
201
7
Page
6of
10
Aeg
is R
egul
ator
y In
c.
Vapo
r De
nsity
:2.
1 (A
ir =
1)
Rel
ativ
e De
nsity
:0.
85 (W
ater
= 1
) So
lubi
litie
s:In
solu
ble
in w
ater
.
Parti
tion
Coe
ffici
ent:
n-O
ctan
ol/W
ater
:lo
g P
ow: 0
.84
Auto
-igni
tion
Tem
pera
ture
:20
5 °C
(40
1 °F
)
Dec
ompo
sitio
n Te
mpe
ratu
re:
Not
ava
ilabl
e.
Visc
osity
:N
ot a
vaila
ble.
Perc
ent V
olat
ile, w
t. %
:N
ot a
vaila
ble.
VOC
con
tent
, wt.
%:
Not
ava
ilabl
e.D
ensi
ty:
Not
ava
ilabl
e.C
oeffi
cien
t of W
ater
/Oil
Dis
tribu
tion:
Not
ava
ilabl
e.
Sect
ion
10: S
TABI
LITY
AN
D RE
ACTI
VITY
Rea
ctiv
ity:
Con
tact
with
inco
mpa
tible
mat
eria
ls. S
ourc
es o
f ign
ition
. Exp
osur
e to
he
at.
Che
mic
al S
tabi
lity:
Sta
ble
unde
r nor
mal
sto
rage
con
ditio
ns.
Poss
ibili
ty o
f Haz
ardo
us
Rea
ctio
ns:
Non
e kn
own.
Con
ditio
ns to
Avo
id:
Con
tact
with
inco
mpa
tible
mat
eria
ls. S
ourc
es o
f ign
ition
. Exp
osur
e to
he
at.
Inco
mpa
tible
Mat
eria
ls:
Oxi
dize
rs.
Haz
ardo
us D
ecom
posi
tion
Prod
ucts
:N
ot a
vaila
ble.
Sect
ion
11: T
OXI
COLO
GIC
AL
INFO
RM
ATI
ON
EFFE
CTS
OF
ACUT
E EX
POSU
RE
Prod
uct T
oxic
ity
Ora
l:33
00 m
g/kg
(rat
)D
erm
al:
> 50
00 m
g/kg
(rab
bit)
Inha
latio
n:40
250
mg/
m³ (
rat);
4H
Com
pone
nt T
oxic
ityC
ompo
nent
CAS
No.
LD50
ora
lLD
50 d
erm
alLC
50
Dim
ethy
l sul
fide
75-1
8-3
3300
mg/
kg (r
at)
> 50
00 m
g/kg
(rab
bit)
4025
0 m
g/m
³ (ra
t); 4
H
Like
ly R
oute
s of
Exp
osur
e:E
ye c
onta
ct. S
kin
cont
act.
Inha
latio
n. In
gest
ion.
Ta
rget
Org
ans:
Ski
n. E
yes.
Gas
troin
test
inal
trac
t. R
espi
rato
ry s
yste
m.
Dim
eth
yl S
ulfid
e (D
MS
)SA
FETY
DAT
A SH
EET
Dat
e of
Pre
para
tion:
Oct
ober
18,
201
7
Page
7of
10
Aeg
is R
egul
ator
y In
c.
Sym
ptom
s (in
clud
ing
dela
yed
and
imm
edia
te e
ffect
s)In
hala
tion:
May
cau
se r
espi
rato
ry ir
ritat
ion.
Sig
ns/s
ympt
oms
may
incl
ude
coug
h, s
neez
ing,
na
sal d
isch
arge
, hea
dach
e, h
oars
enes
s, a
nd n
ose
and
thro
at p
ain.
Exc
essi
ve
inha
latio
n m
ay c
ause
hea
dach
e, d
izzi
ness
, con
fusi
on, l
oss
of a
ppet
ite a
nd/o
r los
s of
con
scio
usne
ss. V
apor
inha
latio
n m
ay c
ause
mod
erat
e ey
e, n
ose,
and
thro
at
irrita
tion,
mak
ing
it un
likel
y th
at in
divi
dual
s w
ill to
lera
te m
oder
ate
to h
igh
conc
entr
atio
ns. H
eada
che
and
decr
ease
d ab
ility
to c
once
ntra
te m
ay o
ccur
.Ey
e:M
ay c
ause
eye
irrit
atio
n. S
igns
/sym
ptom
s m
ay in
clud
e re
dnes
s, s
wel
ling,
pai
n,
tear
ing,
and
blu
rred
or h
azy
visi
on.
Skin
:M
ay c
ause
ski
n irr
itatio
n. S
igns
/sym
ptom
s m
ay in
clud
e lo
caliz
ed re
dnes
s, s
wel
ling,
an
d itc
hing
. In
gest
ion:
May
cau
se g
astro
inte
stin
al ir
ritat
ion.
Sig
ns/s
ympt
oms
may
incl
ude
abdo
min
al p
ain,
st
omac
h up
set,
naus
ea, v
omiti
ng a
nd d
iarrh
ea.
Skin
Sen
sitiz
atio
n:N
ot a
vaila
ble.
R
espi
rato
ry S
ensi
tizat
ion:
Not
ava
ilabl
e.
Med
ical
Con
ditio
ns
Aggr
avat
ed B
y Ex
posu
re:
Not
ava
ilabl
e.
EFFE
CTS
OF
CHRO
NIC
EXP
OS
URE
(from
sho
rtan
d lo
ng-te
rm e
xpos
ure)
Targ
et O
rgan
s:S
kin.
Eye
s. G
astro
inte
stin
al tr
act.
Res
pira
tory
sys
tem
. C
hron
ic E
ffect
s:P
rolo
nged
or
repe
ated
con
tact
may
dry
ski
n an
d ca
use
irrita
tion.
C
arci
noge
nici
ty:
This
pro
duct
doe
s no
t con
tain
any
car
cino
gens
or p
oten
tial
carc
inog
ens
as li
sted
by
ACG
IH, I
ARC
, OS
HA
, or N
TP.
M
utag
enic
ity:
Dim
ethy
l sul
fide
was
not
mut
agen
ic to
Sal
mon
ella
typh
imur
ium
or
Esc
heric
hia
coli
(bac
teria
l rev
erse
mut
atio
n as
say)
in v
itro,
with
or
with
out m
etab
olic
act
ivat
ion.
It w
as a
lso
nega
tive
in a
DN
A d
amag
e an
d re
pair
assa
y us
ing
Sal
mon
ella
typh
imur
ium
. Dim
ethy
l sul
fide
was
no
t mut
agen
ic in
an
in v
ivo
mou
se m
icro
nucl
eus
stud
y.R
epro
duct
ive
Effe
cts:
Dim
ethy
l sul
fide
had
no e
ffect
on
mal
e or
fem
ale
repr
oduc
tive
orga
ns
follo
win
g re
peat
ed o
ral d
osin
g in
rat
s fo
r up
to 1
4 we
eks.
Whe
n pr
egna
nt r
ats
wer
e do
sed
with
dim
ethy
l sul
fide
from
ges
tatio
n da
ys 6
to
19
via
gava
ge a
t dos
es a
s hi
gh a
s 10
00 m
g/k
g bw
/day
, no
mat
erna
l to
xici
ty, e
mbr
yo-f
etal
or d
evel
opm
enta
l tox
icity
or t
erat
ogen
icity
was
ob
serv
ed.
Dev
elop
men
tal E
ffect
sTe
rato
geni
city
:N
ot a
vaila
ble.
Embr
yoto
xici
ty:
Not
ava
ilabl
e.
Toxi
colo
gica
lly S
yner
gist
ic M
ater
ials
:N
ot a
vaila
ble.
Dim
eth
yl S
ulfid
e (D
MS
)SA
FETY
DAT
A SH
EET
Dat
e of
Pre
para
tion:
Oct
ober
18,
201
7
Page
8of
10
Aeg
is R
egul
ator
y In
c.
Sect
ion
12: E
CO
LOG
ICAL
INFO
RMAT
ION
Ecot
oxic
ity:
Onc
orhy
nchu
s m
ykis
s(R
ainb
ow tr
out):
LC
50 =
213
mg/
L, 9
6-hr
;D
aphn
ia m
agna
: EC
50 =
29
mg/
L, 4
8-hr
;D
aphn
ia m
agna
: EC
50 =
81
mg/
L, 4
8-hr
;P
seud
okirc
hner
iella
sub
capi
tata
: EC
50 =
23
to >
113
.7 m
g/L,
96-
hr.
Pers
iste
nce
/ D
egra
dabi
lity:
Dim
ethy
l sul
fide
is p
hoto
degr
aded
by
reac
tion
with
hyd
roxy
l rad
ical
s in
the
atm
osph
ere
with
a h
alf-
life
of 2
.8 d
ays
(cal
cula
ted)
. E
xper
imen
tal s
tudi
es s
how
dim
ethy
l sul
fide
is ra
pidl
y de
grad
ed in
su
nlig
ht (n
atur
al a
nd s
imul
ated
) for
min
g a
num
ber o
f bre
akdo
wn
prod
ucts
incl
udin
g su
lfur
diox
ide.
Dim
ethy
l sul
fide
does
not
hyd
roly
ze
with
hyd
rolys
is h
alf-l
ives
of >
1 y
ear
at p
H 4
, 7 a
nd 9
.B
ioac
cum
ulat
ion
/ Ac
cum
ulat
ion:
A lo
w b
ioac
cum
ulat
ion
pote
ntia
l is
expe
cted
bas
ed o
n th
e pa
rtiti
on
coef
ficie
nt L
og K
ow o
f 0.9
19. D
imet
hyls
ulfid
e is
read
ily
biod
egra
dabl
e (6
7.4%
deg
rade
d ov
er 2
8 da
ys; O
ECD
TG
301
D).
Mob
ility
in E
nviro
nmen
t:Fu
gaci
ty m
odel
Lev
el II
I ind
icat
es d
imet
hyl s
ulfid
e w
ill di
strib
ute
in
air,
wat
er a
nd s
edim
ent d
epen
dent
on
the
rout
e of
the
emis
sion
. Fu
gaci
ty m
odel
Lev
el II
I dis
tribu
tion
with
100
% o
f the
dim
ethy
l sul
fide
rele
ased
to a
ir is
: 98.
6% (a
ir), 1
.3%
(wat
er),
0.1%
(soi
l) an
d <0
.01%
(s
edim
ent);
with
100
% o
f the
dim
ethy
l sul
fide
rele
ased
to w
ater
the
dist
ribut
ion
is: 8
.6%
(air)
, 91.
2% (w
ater
), 0.
01%
(soi
l) an
d 0.
2%
(sed
imen
t); w
ith 1
00%
of t
he d
imet
hyl s
ulfid
e re
leas
ed to
soi
l the
di
strib
utio
n is
: 39.
4% (a
ir), 7
.2%
(wat
er),
53.4
% (s
oil)
and
0.01
%
(sed
imen
t).
Fuga
city
mod
el L
evel
III d
istri
butio
n w
ith e
qual
rele
ase
of d
imet
hyl
sulfi
de to
air,
wat
er a
nd s
oil i
s: 2
8.1%
(air)
, 57.
2% (w
ater
), 14
.6%
(s
oil)
and
0.1%
(sed
imen
t).O
ther
Adv
erse
Effe
cts:
Not
ava
ilabl
e.
Sect
ion
13: D
ISPO
SAL
CO
NSID
ERA
TIO
NS
Dis
posa
l Ins
truct
ions
:D
ispo
sal s
houl
d be
in a
ccor
danc
e wi
th a
pplic
able
regi
onal
, nat
iona
l an
d lo
cal l
aws
and
regu
latio
ns. L
ocal
regu
latio
ns m
ay b
e m
ore
strin
gent
than
regi
onal
or n
atio
nal r
equi
rem
ents
.
Sect
ion
14: T
RAN
SPO
RT IN
FOR
MAT
ION
U.S
. Dep
artm
ent o
f Tra
nspo
rtat
ion
(DO
T)Pr
oper
Shi
ppin
g Na
me:
UN
1164
, DIM
ETH
YL S
ULF
IDE,
3, P
G II
Cla
ss:
3U
N Nu
mbe
r:U
N11
64Pa
ckin
g G
roup
:II
Labe
l Cod
e:
Dim
eth
yl S
ulfid
e (D
MS
)SA
FETY
DAT
A SH
EET
Dat
e of
Pre
para
tion:
Oct
ober
18,
201
7
Page
9of
10
Aeg
is R
egul
ator
y In
c.
Can
ada
Tran
spor
tatio
n of
Dan
gero
us G
oods
(TD
G)
Prop
er S
hipp
ing
Nam
e:U
N11
64, D
IMET
HYL
SU
LFID
E, 3
, PG
IIC
lass
:3
UN
Num
ber:
UN
1164
Pack
ing
Gro
up:
IILa
bel C
ode:
IMD
G T
rans
port
Info
rmat
ion
Prop
er S
hipp
ing
Nam
e:U
N11
64, D
IMET
HYL
SU
LFID
E, 3
, PG
IIC
lass
:3
UN
Num
ber:
UN
1164
Pack
ing
Gro
up:
IILa
bel C
ode:
Flas
h po
int:
-49
°C (
-56.
2 °F
) (C
lose
d C
up)
EmS
Num
ber:
F-E
, S-D
ICA
O/IA
TATr
ansp
ort I
nfor
mat
ion
Prop
er S
hipp
ing
Nam
e:U
N11
64, D
IMET
HYL
SU
LFID
E, 3
, PG
IIC
lass
:3
UN
Num
ber:
UN
1164
Pack
ing
Gro
up:
IILa
bel C
ode:
Flas
h po
int:
-49
°C (
-56.
2 °F
) (C
lose
d C
up)
Sect
ion
15: R
EGUL
ATO
RY IN
FOR
MAT
ION
Che
mic
al In
vent
orie
s
US
(TS
CA)
The
com
pone
nts
of th
is p
rodu
ct a
re in
com
plia
nce
with
the
chem
ical
not
ifica
tion
requ
irem
ents
of
TSC
A.C
anad
a (D
SL)
The
com
pone
nts
of th
is p
rodu
ct a
re in
com
plia
nce
with
the
chem
ical
not
ifica
tion
requ
irem
ents
of
the
NSN
Reg
ulat
ions
und
er C
EPA
, 199
9.
Dim
eth
yl S
ulfid
e (D
MS
)SA
FETY
DAT
A SH
EET
Dat
e of
Pre
para
tion:
Oct
ober
18,
201
7
Page
10
of 1
0A
egis
Reg
ulat
ory
Inc.
Fede
ral R
egul
atio
ns
Uni
ted
Stat
esTh
is S
DS
has
been
pre
pare
d to
mee
t the
U.S
. OS
HA
Haz
ard
Com
mun
icat
ion
Stan
dard
, 29
CFR
191
0.12
00.
SARA
Titl
e III
No
com
pone
nts
are
liste
d.
Stat
e R
egul
atio
nsM
assa
chus
etts
US
Mas
sach
uset
ts C
omm
onw
ealth
's R
ight
-to-K
now
Law
(App
endi
x A
to 1
05 C
ode
of
Mas
sach
uset
ts R
egul
atio
ns S
ectio
n 67
0.00
0)C
ompo
nent
CAS
No.
RTK
Lis
tD
imet
hyl s
ulfid
e(D
MS
)75
-18-
3E
Not
e: E
= E
xtra
ordi
nar
ily H
aza
rdou
s S
ubst
anc
e
New
Jer
sey
US
New
Jer
sey
Wor
ker a
nd C
omm
unity
Rig
ht-to
-Kno
w A
ct (
New
Jer
sey
Stat
ute
Ann
otat
ed
Sec
tion
34:5
A-5)
Com
pone
ntC
AS N
o.R
TK L
ist
Dim
ethy
l sul
fide
(DM
S)
75-1
8-3
SH
HS
Not
e: S
HH
S =
Spe
cia
l Hea
lth H
aza
rd S
ubs
tan
ce
Penn
sylv
ania
US
Pen
nsyl
vani
a W
orke
r and
Com
mun
ity R
ight
-to-K
now
Law
(34
Pa. C
ode
Cha
p. 3
01-3
23)
Com
pone
ntC
AS N
o.R
TK L
ist
Dim
ethy
l sul
fide
(DM
S)
75-1
8-3
EN
ote:
E =
Env
iron
men
tal H
aza
rd
Cal
iforn
iaC
alifo
rnia
Pro
p 65
:Th
is p
rodu
ct d
oes
not c
onta
in c
hem
ical
s kn
own
to th
e St
ate
of C
alifo
rnia
to
cau
se c
ance
r, bi
rth d
efec
ts o
r oth
er re
prod
uctiv
e ha
rm.
Sect
ion
16: O
THER
INFO
RM
ATIO
N
Dis
clai
mer
:Th
e in
form
atio
n co
ntai
ned
in th
is d
ocum
ent a
pplie
s to
this
spe
cific
mat
eria
l as
supp
lied.
It m
ay
resp
onsi
bilit
y to
sat
isfy
one
self
as to
the
suita
bilit
y an
d co
mpl
eten
ess
of th
is in
form
atio
n fo
r th
eir
own
part
icul
ar u
se.
Dat
e of
Pre
para
tion
of S
DS:
Oct
ober
18,
201
7Ve
rsio
n:
1.2
GHS
SD
SPr
epar
ed b
y:Ae
gis
Regu
lato
ry In
c.
Phon
e: (5
19) 4
88-0
351
ww
w.a
egis
reg.
com
He
alt
h
Fir
e
Re
ac
tiv
ity
Pe
rso
na
lP
rote
cti
on
3 0 2 J
ANNEXURE-ACONSULTANT’S CERTIFICATE OF
ACCREDITATION (HIGH COURT STAY ORDER)
ANNEXURE A
ANNEXURE-B
NABL ACCREDITATION CERTIFICATE
ANNEXURE-C
EMS ADEQUACY CERTIFICATE
ANNEXURE-D
UNDERTAKING BY THE EIA CONSULTANT
ANNEXURE-E
UNDERTAKING BY THE PROJECT PROPONENT