msds chesterton 274

© A.W. Chesterton Company, 2010 All Rights Reserved. ¹Classified according to: * 29 CFR 1910.1200, 1915, 1916, 1917 ® Reg. US Patent and TM Office * Mass. Right-to-Know Law (ch. 40, M.G.L..O. 111F)

* California Proposition 65

* Controlled Products Regulations

* 67/548/EEC, 1272/2008/EC (ATP01) 99/45/EC and 75/324/EEC * Worksafe Australia [NOHSC: 1008 (2004)]

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MATERIAL SAFETY DATA SHEET

in accordance with 1907/2006/EC (REACH) 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING

Product Name: 274 Industrial Degreaser (Aerosol)

Revision: 5 August 2010 Date of issue: 6 July 2007

MSDS No. 207A-14

Not classified as hazardous according to criteria of Safe Work Australia.

Company: A.W. CHESTERTON COMPANY 860 Salem Street Groveland, MA 01834-1507, USA Tel.: +1 978-469-6446 Fax: +1 978-469-6785 (Mon. - Fri. 8:30 - 5:00 PM EST) E-mail (MSDS questions): [email protected] E-mail: [email protected] MSDS requests: www.chesterton.com

Supplier:

For Chemical Emergency: 24 hours per day, 7 days per week Call Infotrac: 1-800-535-5053 Outside N. America: +1 352-323-3500 (collect)

Use: Petroleum base cleaner. Dissolves grease, oil, tar and other similar water insoluble soils generally encountered in the industrial and marine environments.

2. HAZARDS IDENTIFICATION Highly flammable. Contents under pressure. Repeated exposure may cause skin dryness or cracking. As with any organic solvent based product, care should be taken to avoid excessive inhalation of vapors. This is especially important in enclosed areas or areas with poor ventilation.

3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Ingredients¹ % Wt. CAS No. EC No. Symbol R-phrases Naphtha (Petroleum), Hydrotreated Heavy* 85-95 64742-48-9 265-150-3 Xn 65-66 Petroleum Gases, Liquefied, Sweetened** 10-20 68476-86-8 270-705-8 F+ 12 See section 15 for text of risk phrases on the label and section 16 for others. *Contains less than 0.1 % w/w Benzene. **Contains less than 0.1 % w/w 1,3-Butadiene.

Product: 274 Industrial Degreaser (Aerosol) Date: 5 August 2010 MSDS No.: 207A-14

A.W. Chesterton Company, 2010 All Rights Reserved. Reg. US Patent and TM Office of 5

4. FIRST AID MEASURES Inhalation: Remove to fresh air. If not breathing, administer artificial respiration. Contact physician immediately.

Skin Contact: Wash skin with soap and water. Contact physician if irritation persists.

Eye Contact: Flush eyes for at least 15 minutes with large amounts of water. Contact physician if irritation persists.

Ingestion: Do not induce vomiting. Contact physician immediately.

Advice to Physician: Treat symptoms.

5. FIRE-FIGHTING MEASURES Extinguishing Methods: Carbon Dioxide, dry chemical, foam or water spray

Unusual Fire and Explosion Hazards:

Pressurized containers, when heated, are a potential explosive hazard.

Special Fire Fighting Measures: Cool exposed containers with water. Recommend Firefighters wear self-contained breathing apparatus.

Flammability Classification: NFPA: Storage Level III; 16CFR 1500.3 Extremely flammable aerosol

HAZCHEM Emergency Action Code: 2 Y

6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Utilize exposure controls and personal protection as specified in Section 8.

Environmental Precautions: Keep out of sewers, streams and waterways.

Methods of Clean Up: Evacuate area. Provide adequate ventilation. Contain spill to a small area. Keep away from sources of ignition - No smoking. If removal of ignition sources is not possible, then flush material away with water. Pick up with absorbent material (sand, sawdust, clay, etc.) and place in a suitable container for disposal. Refer to section 13 for disposal advice.

7. HANDLING AND STORAGE Handling: Shake well before using. Keep away from sources of ignition - No smoking. After handling, wash before eating,

drinking or smoking. Vapors are heavier than air and will collect in low areas. Vapor accumulations could flash and/or explode if ignited. Utilize exposure controls and personal protection as specified in Section 8.

Storage: Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C (120°F). Do not pierce or burn, even after use.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION Hazardous Ingredients OSHA ACGIH TLV AUSTRALIA ppm mg/m3 ppm mg/m3 ppm mg/m3 Naphtha (Petroleum), Hydrotreated Heavy* – – – – – – Petroleum Gases, Liquefied, Sweetened 1000 – 1000 – 1000 – *Chesterton recommended limit: 171 ppm (1200 mg/m3).



Respiratory Protection: Not normally needed. If exposure limits are exceeded, use approved organic vapor respirator.

Ventilation: Use only in well-ventilated areas. If exposure limits are exceeded, provide adequate ventilation. Vapors are heavier than air and will collect in low areas.

Protective Gloves: Chemical resistant gloves (e.g. Viton*, neoprene, nitrile). *DuPont's registered trademark.

Eye Protection: Safety glasses

Other: Impervious clothing (e.g. Viton*, neoprene or nitrile) as necessary to prevent skin contact. *DuPont's registered trademark.

9. PHYSICAL AND CHEMICAL PROPERTIES Physical state low viscosity liquid Odour mild odor Colour clear Vapour pressure @ 20C not applicable Initial boiling point 188°C (370°F), product

only % Aromatics by weight ≤ 0.01%, product only

Melting point not determined pH not applicable % Volatile (by volume) 100% Density 0,77 kg/l Flash point 61°C (142°F), product

only Weight per volume 6.4 lbs/gal.

Method Closed Cup Coefficient (water/oil) < 1 Viscosity not determined Vapour density (air=1) > 1 Autoignition temp. 227°C (440°F), product

only Rate of evaporation (ether=1) < 1

Explosion limits LEL 1.2; UEL 9.9 Solubility in water negligible Other none

10. STABILITY AND REACTIVITY Stability: Stable

Hazardous Polymerization: Will not occur.

Hazardous Decomposition Products:

Carbon Monoxide, aldehydes and other toxic fumes.

Conditions to Avoid: Open flames, heat, sparks and red hot surfaces.

Materials to Avoid: Reactive metals and strong oxidizers like liquid Chlorine and concentrated Oxygen.

11. TOXICOLOGICAL INFORMATION Primary Route of Exposure Under Normal Use:

Inhalation, skin and eye contact. Personnel with pre-existing dermatitis may be aggravated by exposure.

Acute Effects: Direct eye contact may result in eye irritation. Inhalation of vapor concentrations in excess of 1000 ppm will cause eye and respiratory tract irritation, dizziness, headache and other central nervous system effects.

Chronic Effects: Prolonged or repeated skin contact may defat the skin and cause skin irritation.

Other Information: As per 29 CFR 1910.1200 (Hazard Communication), this product contains no carcinogens as listed in the National Toxicology Program (NTP), the International Agency for Research on Cancer (IARC) or the Occupational Safety and Health Administration (OSHA).



12. ECOLOGICAL INFORMATION Ecotoxicological data have not been determined specifically for this product. The information given below is based on a knowledge of the components and the ecotoxicology of similar substances.

Mobility: Liquid. Insoluble in water. Floats on water. In determining environmental mobility, consider the product's physical and chemical properties (see Section 9). The hazardous ingredients will rapidly evaporate to the air if released into the water.

Degradability: Naphtha (Petroleum), Hydrotreated Heavy: can degrade in air; may biodegrade. This substance is expected to be removed in a wastewater treatment facility.

Accumulation: not determined

Ecotoxicity: not determined

13. DISPOSAL CONSIDERATIONS Incinerate absorbed material with a properly licensed facility. Incinerate pressurized or sealed containers in an approved facility. Check local, state and national/federal regulations and comply with the most stringent requirement. This product is classified as a hazardous waste according to 91/689/EEC.

EWC-code: 15 01 10

14. TRANSPORT INFORMATION TDG: UN1950, AEROSOLS, FLAMMABLE, CLASS 2.1, U.S. DOT :

Shipping Name: 1 AEROSOLS, FLAMMABLE Hazard Class: 2.1 UN/NA #: UN1950 Packaging Group #: Not Applicable Emergency Response Guide Book No 126 1 NOTE: Shipped as Consumer Commodity ORM-D in packaging having a rated capacity gross weight of 66 lb. or less (49 CFR 173.306(h)).

IMDG: UN1950, AEROSOLS, CLASS 2.1, UN1950, EmS F-D, S-U, ERG No 126 LIMITED QUANTITY

IATA/ICAO: UN1950, AEROSOLS, FLAMMABLE, CLASS 2.1,

ADR/RID: UN1950 AEROSOLS, 2, 5F, ADR

15. REGULATORY INFORMATION European Classification¹: F+ - Extremely flammable

R-Phrase(s): R66 Repeated exposure may cause skin dryness or cracking. *

S-Phrase(s): S23A Do not breathe spray. S24 Avoid contact with skin. S51 Use only in well-ventilated areas.

Name of the substances on the label:

none

Other information: Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C (120°F). Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No Smoking.

Canadian Classification¹: B5: Flammable aerosols; A: Compressed gases

Risk Phrase(s): Flammable aerosol. Repeated exposure may cause skin dryness or cracking.

Precautionary and First Aid Measure(s):

Do not breathe spray. Avoid contact with skin. Use only in well-ventilated areas. If affected by vapor, move to fresh air. In case of contact with eyes, rinse with plenty of water and seek medical advice. Wash skin with soap and water.

Other Information: Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C (120°F). Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No Smoking.



16. OTHER INFORMATION

US EPA SARA TITLE III Hazardous Materials Identification System (HMIS) 312 Hazards : 313 Chemicals : 4 = Severe Hazard

3 = Serious Hazard 2 = Moderate Hazard1 = Slight Hazard 0 = Minimal Hazard * = See Section 8

HEALTH 1

Immediate none FLAMMABILITY 3Fire REACTIVITY 1Pressure Release TSCA: All chemical components are

listed in the TSCA inventory. Personal Protection *

JAPAN PRTR Class I Chemicals : Class II Chemicals :

none none

Risk phrases in section 3: R12 Extremely flammable. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking.

Changes to the MSDS in this revision: Sections

*R65: not applicable according to criteria (aerosol).

This information is based solely on data provided by suppliers of the materials used, not on the mixture itself. No warranty is expressed or implied regarding the suitability of the product for the user’s particular purpose. The user must make their own determination as to suitability.

msds chesterton 274

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