msds training
TRANSCRIPT
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MSDSMATERIAL SAFETY DATA SHEET
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It is an important component of workplace safety, and
intended to provide procedures for handling or
working with that substance in a safe manner, storage,
disposal, protective equipment, and spill handling
procedures.
16 point (section) EU format conforming to 29CFR
1910.1200
CFR (code of Federal Regulation)
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INTRODUCTION
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Gives the product name, description, manufacturer, and
emergency numbers. Manufacturer/ supplier name & address
Product trade name
CAS no.
Synonyms
Generic chemical name
Product type
Preparation/ revision date
Transportation emergency phone number MSDS number
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1- Chemical Product & Company Identification
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Hazardous ingredients
Components
CAS no.
Percentage (by wt)
Carcinogen
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2- Chemical composition and common name
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Lists the main hazards
Appearance
Odor
Principal hazards
Target organs
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3- Hazard identification
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Action to be taken if a person is affected
Eyes
Skin
Inhalation
Oral
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4- First aid measures
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Details required in case of fires
Flash point
Extinguishing media
Fire fighting procedures
Unusual fire & explosion hazards
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5- Fire fighting measures
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Steps to be taken in case of spillage/ leakage
Spill control procedures
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6- Accidental release measures
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Pumping temperature
Maximum handling temperature
Handling procedures
Maximum storage temperature
Storage procedures
Loading temperature
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7- Handling and storage information
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Mainly deals with personal protective equipments
Exposure limits
Other exposure limits
Engineering controls
Gloves protection
Eyes protection
Respiratory protection
Clothing recommendation
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8- Exposure control and personal protection
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Flash point
Specific gravity/ density
Solubility
ViscosityPour point
And others
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9- Physical and chemical properties
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Stability
Decomposition temperature
Incompatibility
Polymerization
Thermal decomposition
Conditions to avoid
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10- Stability and reactivity
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Related to acute & chronic exposure
ACUTEo Eye irritation
o Skin irritation
o Respiratory irritation
o Dermal toxicity
o Inhalation toxicity
o Oral toxicity
o Dermal sensitization
o Inhalation sensitization
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11- Toxicological information
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CHRONIC
Chronic toxicity
Carcinogenicity
Mutagenicity
Reproductive toxicity
teratogenicity
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11- Toxicological information
contd
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Details regarding environmental toxicity & fate
ENVIRONMENTAL TOXICITYFreshwater fish toxicity
Freshwater invertebrates toxicity
Algal inhibition
Saltwater fish toxicity
Saltwater invertebrates toxicity
Bacterial toxicity
Miscellaneous
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12- Ecological information
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ENVIRONMENTAL FATEBiodegradation
Bioaccumulation
Soil mobility
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12- Ecological information
contd.
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Details required for waste disposal
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13- Disposal information
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ICAO/ IATA
IMDG EMS
MARPOL
USCG
U.S. DOT
DOT NAERG
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14- Transport information
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Global chemical inventories
US federal regulations
State regulations
Product registrations
Local statutory
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15- Regulatory information
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NFPA codes
o Health
o Fire
o Reactivity
HMIS codes
o Healtho Fire
o Reactivity
Precautionary labels
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16- Information not covered in the other sections
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QUESTIONS ?
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CAS registry numbers are unique numerical identifiers
for chemical, element, compound, polymer, alloys,mixtures
As of Sep 2009, there are 50 million organic/ inorganic
substances in CAS registry
e.g. 7732-18-5
Last digit is single, a checksum
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PPE Personal Protective Equipment
DOT Department of Transportation
CERCLA Comprehensive Environmental Response,
Compensation, and Liability Actof 1980 (USA)
OSHA Occupational Safety and Health
Administration
NIOSH National Institute for Occupational Safety
and Health
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LC50 (Lethal Concentration 50) is the concentration of achemical which kills 50% of a sample population.
This measure is generally used when exposure to a
chemical is through the animal breathing it in.
LD50 (Lethal Dose 50) is the dose of a chemical whichkills 50% of a sample population. It is used when
exposure is by swallowing, skin contact, injection.
EC50 (half maximal effective concentration) , ED50 (effective dose 50), IC50 (half maximal inhibitory concentration)
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PEL permissible exposure limit in ppm or mg/m3
TWA time weighted average
STEL short term exposure limit, usually for 8 h period
ACGIH American Conference of Industrial Hygienists
MSHA Mine Safety and Health Administration
IARC International Agency for Research on Cancer(WHO)
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OECD Organization for economic co-operation and
development
RCRA Resource Conservation and Recovery Act (RCRA),enacted in 1976, is the principal Federal law in the
United States governing the disposal of solid waste.
ICAO International Civil Aviation Organization
IATA International Air Transport Association
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IMDG International Maritime Dangerous Goods
IMDG EmS IMDG emergency schedule
MFAG Medical First Aid Guide
MARPOL International Convention for the Prevention ofPollution From Ships
USCG United States Coast Guard
NAERG North American Emergency Response Guidebook
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TSCA Toxic Substances Control Act
EU/ EEC European Union/ European Economic Committee
SARA Superfund Amendments and Reauthorization Act
consolidated list of chemicals subject to emergencyplanning
NFPA National Fire Protection Association
HMIS Health Management Information System
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