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  • 7/27/2019 MSDS Vanadium Nikel

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    Material Safetv Data Sheet Page I of5Trading name: Vanadium concentrateProduct-number:Producer: Nickelhue Aue GmbH

    Date: m0U06Actualised: 2004106

    1. Chemical Product and Company Identification1.1. Trading name: Vanadium concentrate1.2. Synonyms: Vanadium pentoxide1.2. Companyldentification:

    Company.Emergency tele,

    Nickelhtte Aue GmbH, 08280 Aue, Germany; Phone: 0049 I 3771505-0No.: Phone: 0049 1 3771 505-0, Fax: 0049 I 3771 505-229

    Composition / Information on ingredientsChemical identity:Concentration:

    Chemical formula:CAS Number:EC Number:EC Index Number:

    Vanadium compound n.o.s.approx. 30 ... 40 YoYanadium pentoxidebalance Na, Fe, S

    v20513r4-62-Inot availablenot available

    3. Physical and Chemical propertiesform:colour:odour:pH:Sp ecific Gravity/D ensify :Vapor Pressure:Vapor Density:Melting Point:Boiling Point (oC):Solubility:Molecular Formula:Molecular Weight:

    solidyellow-brownodourlessnot availableapprox. 6 - 7not availablenot availablenot availablenot availablenot availablenot availablenot available

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    Material Safetv Data Sheet Page 2 of 5Trading name: Vanadium concentrateProduct-number:Producer: Nickelhtte Aue GmbH

    Date: 2004/06Actualised: 2004106

    Hazards identificationHarmful by inhalation and if swallowed. Danger! Causes respiratory tract irritation. Toxic: danger ofserious damage to health by prolonged exposure through inhalation. May cause eye and skin irritation.Toxic to aquatic organisms (WGK 3: extremely water-hazardous) and clarification plant, may causelong-term adverse effects in the aquatic environment. Possible risk of harm to the unborn child. Possiblerisk of irreversible effects. Can be of corrosive, self-heating or oxidizing nature. Possible decomposingand producing of toxic or harmful gases under fire. Reactions with acids or oxidizing substances maycause explosions.

    5 First aid measuresAfter inhalation: move to fresh air immediately, give oxygen, call in physicianIngestion: if victim is conscious and alert, give 2-4 cupfuls of milk or water. Never giveanything by mouth to an unconscious person. Wash mouth out with water. Call inphysician immediately.After eye contact: immediately flush eyes with plenty of water for at least 15 minutes with theEyelids held wide open respectively until no rests of chemicals are visible,call in physicianAfter skin contact: remove contaminated clothing, flush skin with plenty of water for at least 15minutes resoectively until no rests of chemicals are visible, get medical aidAfter swallowing: make victim drink plenty of water, induce vomiting, call in physician

    6 Fire-fighting measuresGeneral information: As in any fire, wear self-contained breathing apparatus in pressure-demand

    and full protective gear. Substance is non-combustible. Danger of dustexplosion.Extinguishing media: in adaption to materials stored in the immediate neighbourhoodFlashpoint: not availableAutoignition Temperature: not availableOther information: prevent fire-fighting water from entering surface water or groundwater,Fire extinguishing only at early stages of a fire

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    Material Safetv Data Sheet Page 3 of5Trading name: Vanadium concentrateProduct-number:Producer: Nickelhtte Aue GmbH

    Date: 2004106Actualised: 2004106

    7 Accidental release measuresPerson-related precautionary measures: Avoid substance contact. Avoid generation of dusts, do not

    inhale dusts. Ensure supply of fresh air in enclosed rooms,Environmental-protection measures: Do not allow to enter sewerage system.Fprocedures for cleaning/absorption: Carefully take up dry. Do not use water for cleaning streets.Forward for ciisposai. Clean up affected area. Avoidseneration of dust.

    8 Handling and storageHandling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse.Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Do not breathe dust orfumes. Use only with adequate ventilation, work under hood. Prevent the product fromentering surface water or groundwater.Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away fromincompatible or tlammable substances. Porsr-rn room locked and accessible only forauthorized persons.

    9 Exposure controls/personal protectionSpecific control parameter: TRGS 900

    Mass concentration: 3,6 or 10 mg/m3Peak limit: 4Remark: TRGS 901-96MAK values (USA)TLV-TWA: 10 (E,i)/3 @,R) ms/m3TLV-STEL: -Remarks:Health hazard: lung

    Ventilation is normally required when handling or using this product to keep exposure to airbornecontaminants below the exposure limit. Use adequate general or local exhaust ventilation to keepairborne concentrations below the permissible exposure limits. Use only under a chemical fume hood.Personal protective equipment:Eyes: Wear appropriate protective eyeglasses or chemical safety goggles and face protection.Skin: Wear appropriate protective rubber gloves to prevenl skin rxposure.Respiratory protection: required when dusts are generated. Filtei P 3 ( acc. to DIN 3181) for solid andliquid particles of toxic and very toxic substances. High efficiency particle respirator

    necessary.

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    Material Safetv Data Sheet Page 4 of5Trading name: Vanadium concentrateProduct-number:Producer: Nickelhtte Aue GmbH

    Date: 2004106Actualised: 2004106

    Clothing: Wear appropriate protective clothing to prevent skin exposure and closed shoes. Protectiveclothing should be selected specifically for the working place, depending on concentrationand quantity of the hazardous substances handled. The resistance of the protective clothingto chemicals should be ascertained with the respective supplier.Industrial hygiene: Immediately change centaminated clothing. Apply skin-protective barrier cream.Wash hands and face after working with substance. Under no circumstances eat ordrink at workplace. Work under hood. Do not inhale substance.

    10 Stabilify and reactivityChemical stability: stable under normal temperatures and pressuresConditions to be avoided: Exposure to airSubstances to be avoided: strong acids, oxidizing mattersHazardousdecompositionproducts: notavailableFurther information: fire-promoting substance, dust explosion possible, catalltic

    11 ToxicologicalinformationAcute tocxity: LCso (inhalation, rat):

    LD5s (dermal,rat):LD5s (oral. rat):Carcinogenicity: not availableFurther toxicological information: Vanadium and its compounds generally cause irritations after eye

    and skin contact and mucosal irritations, coughing, and dyspnoeaafter inhalation. After absorption of toxic quantities changes inthe blood picture, loss of weight, cardiovascular complaints.Irreversible damage possible.Further data: The product should be handled with the care usual when dealins with chemicals.

    12 Ecological informationEcotoxic information: not availableBiological information: Toxic for aquatic organisms, may cause long-term adverse effects in theaquatic environment.Further ecologic data: The following applies to vanadium compounds in general: toxic for

    Aquatic organisms: LD50 from 4.8 mg/l up in soft water, froms 30 mg/l in hard water.Do not allow to enter waters, waste water or soil!!

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    Material Safetv Data Sheet Page 5 of5Trading name: Vanadium concentrateProduct-number:Producer: Nickelhtte Aue GmbH

    Date: 2Q04/06Actualised z 2004/06

    13 Disposal considerationsProduct: Chemicals must be disposed of in compliance with the respective national regulations.Waste Disposal: product back to the producerPackaging: Nickelhtte Aue product packaging must be disposed of in compliance with the country-Specific regulations or must be passed to a packaging return system .

    14 Transport informationLand transport: ADR, LrN 3285 Vanadium compound n.o.s., 6.1, IVT5Transport by sea: IMDG, GGVSee, tIN 3285 Vanadium compound n.o.s., 6.1,II|T5Transport by air: CAO, PAX, LIN 3285 Vanadium compound n.o.s., 6.1, IVT5The transport regulations are cited according to international regulations and in the form applicable inGermany (GGVSE). Possible national deviations in other countries are not considered.

    t5 Regulatory informationLabelling according to EC DirectivesSymbol: T ToxicN Danserous for the environment

    16 CommentsEmployers should use this information only as a supplement gathered by them, and should makeindependent judgement of suitability of this informdtion to ensure proper use and protect the health andsafety of the employers. This information is furnished without wansnty, ond use of the product not inconformance with this material safety data sheet or in combination witit arty other product or process,is in the responsibility ofthe user.written in 2003