multifunctional nanoparticle systems— coupled...

Multifunctional Nanoparticle Systems—Coupled Behavior and Applications

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Cambridge University Press978-1-107-40797-8 - Multifunctional Nanoparticle Systems—Coupled Behavior andApplications: Materials Research Society Symposium Proceedings: Volume 1257Editors: Joseph B. Tracy, Yuping Bao, Andrew M. Dattelbaum, Yadong Yin, Alain Pignolet,Hariharan Srikanth, Lionel Vayssieres and Anke WeidenkaffFrontmatterMore information

http://www.cambridge.org/9781107407978

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MATERIALS RESEARCH SOCIETYSYMPOSIUM PROCEEDINGS VOLUME 1257

Multifunctional NanoparticleSystems—Coupled Behavior

and ApplicationsSpring 2010, April 5-9, San Francisco, California, U.S.A.

EDITORS:

Joseph B. TracyNorth Carolina State UniversityRaleigh, North Carolina, U.S.A.

Yuping BaoUniversity of Alabama

Tuscaloosa, Alabama, U.S.A.

Andrew M. DattelbaumLos Alamos National Laboratory

Los Alamos, New Mexico, U.S.A.

Yadong YinUniversity of California - Riverside

Riverside, California, U.S.A.

Symposium N Organizers:

Alain PignoletInstitut National de la Recherche Scientifique

(INRS) Centre - Energie Mat6riauxTelecommunications

Varennes/Montrdal, Quebec, Canada

Hariharan SrikanthUniversity of South Florida

Tampa, Florida, U.S.A.

Lionel VayssieresNational Institute for Materials Science,

International Center for MaterialsNanoArchitectonics

Tsukuba, Japan

Anke WeidenkaffEmpa, Swiss Federal Laboratories for Materials

Science and Technology, Laboratory forSolid State Chemistry & Catalysis

Duebendorf, Switzerland

IMIRIS1Materials Research Society

Warrendale, Pennsylvania






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CONTENTS

Preface xiii

Materials Research Society Symposium Proceedings xiv

ENERGY APPLICA TIONS

Silver/Gold Heterometallic Nanostructures and Their SurfacePlasmon-Related Behaviors 3

Hyunjoon Song

POSTER SESSION I

Optimization of Light Emission from Silicon NanocrystalsGrown by PECVD 11

Satoshi Ishikawa, Szu-Lin Cheng, Yiyang Gong,Jelena Vuckovic, and Yoshio Nishi

Novel Solid Nanohybrids that Stabilize Oil/Water Emulsionsand Catalyze Reactions at the Interface 17

Jimmy A. Faria, Min Shen, and Daniel E. Resasco

Emission Inhomogeneity in InAs Quantum Dot DWELLStructures 23

Alejandro Vivas Hernandez, Georgiy Polupan,Eric Velazquez Lozada, Ingri J. Guerrero Moreno,and Ye S. Shcherbyna

Structural and Magnetic Properties of Pure and Cobalt DopedGallium Nitride Nanocrystals 29

V. Ganesh, S. Suresh, and K. Baskar

Fabrication of Transparent, Conductive Phase-SegregatedITO/PC Composites 35

Celeste Mason and Rosario A. Gerhardt

Percolation Conduction of Nanocluster Films for Nano-Devices 41Il-Suk Kang and Chi Won Ahn






FUNDAMENTALS FOR MEDICAL APPLICA TIONS

Polymeric/Inorganic Multifunctional Nanoparticlesfor Simultaneous Drug Delivery and Visualization 49

Andrea Fornara, Alberto Recalenda, Jian Qin,Abhilash Sugunan, Fei Ye, Sophie Laurent,Robert N. Muller, Jing Zou, Abo-Ramadan Usama,Muhammet S. Toprak, and Mamoun Muhammed

MAGNETIC NANOPARTICLES FOR MEDICAL APPLICATIONS

High Transversal Relaxivities of Silica Coated Multicore IronOxide Nanoparticles Suitable for Magnetic Resonance Imaging 57

Elena Taboada, Elisenda Rodriguez, and Anna Roig

POSTER SESSION II

Synthesis of Fe3O4/ZnO Core-Shell Nanoparticlesfor Photodynamic Therapy Applications 67

Juan C. Beltran-Huarac, Surinder P. Singh,Maharaj S. Tomar, Sandra Pefta, Luis Rivera,and Oscar J. Perales-P^rez

Distance Controlled and Electrically DrivenPhotoluminescence Quenching from QuantumDot-Au Complexes 73

Zhitao Kang, Jie Xu, Dinal Andreasen,and Brent Wagner

MEDICAL APPLICA TIONS

* Multifunctional Nanoparticles for Targeted Imagingand Therapy of Cancer 81

Yong-Eun Koo Lee and Raoul Kopelman

Silicon Quantum Dots Functionalized for siRNA Delivery 93Stefanie Klein, Oliver Zolk, Falk Schrodl,and Carola Kryschi

* Invited Paper






Multivalent Biomimetic Glyconanoparticle Platforms as QCMAmplifiers for Lectin-Carbohydrate Interactions 99

Eugene Mahon, Teodor Aastrup, and Mihail Barboiu

MULTIFUNCTIONAL POLYMERS

* Why Structure Matters - Controlling the Propertiesof Nanopartide Hybrid Materials 107

Jihoon Choi, Hongchen Dong,Krzysztof Matyjaszewski,and Michael R. Bockstaller

Electron Microscopy (TEM) and X-ray Spectromicroscopy(STXM) of PP/MMT/PP-g-MA and PP/MMT/SEBSNanocomposites 113

Zulima Martin, M. Angeles Gomez,and Ignacio Jimenez

MULTIFUNCTIONAL OXIDES

Active Nanostructures at Interfaces for PhotocatalyticReactors and Low-Power Consumption Sensors 123

James L. Gole, Serdar Ozdemir, Sharka M. Prokes,and David A. Dixon

APPENDIX

THIN FILM TRANSISTORS AND MATERIALS

Local Electromechanical Properties of ZnO Thin Filmsand Microcrystals 133

I.K. Bdikin, M. Silibin, R. Ayouchi, R. Schwarz,S. Gavrilov, J. Gracio, and A.L. Kholkin

Annealing Effects on Electrical Properties and Defects ofCaCu3Ti4O,2 Thin Films Deposited by Pulsed Laser Deposition 139

Guochu Deng and Paul Muralt

•Invited Paper






CHARACTERIZATION

Study of Tunability of BST with Different Structuresfor Microwave Applications 147

Heba B. El-Shaarawy, Sebastien Pacchini,Badreddine Ouagague, Sandrine Payan,Anthony Rousseau, Mario Maglione,and Robert Plana

DEFECTS AND METASTABILITY

* Giant AC Electrical Response of La0.7Sr0.3MnO3in Sub-Kilogauss Magnetic Fields 155

A. Rebello, V.B. Naik, S.K. Barik, M.C. Lam,and R. Mahendiran

Evidence for Magnetic Polarons in Hole-Doped CobaltPerovskites 165

A. Podlesnyak, A. Furrer, Th. Strassle,E. Pomjakushina, K. Conder, and D.I. Khomskii

CARRIER TRANSPORT

Ultra Wideband AC Permittivity and Permeability ofNanometer and Micron Size Iron and Magnetite Particulatesand Their Composites 173

Rick L. Moore and John Schultz

Surface Spin-Glass Freezing and Blocking in Nickel FerriteNanoparticles 179

K. Nadeem and H. Krenn

Synthesis and Magnetic Properties of Pure and Cobalt-DopedNanocrystalline Bismuth Ferrite 187

Gina Montes, Oscar Perales-P£rez, Boris Renteria,and Marco Galvez

Thermal Conductivity of Nickel Oxide NanoparticlesSynthesized by Combustion Method 193

Pranati Sahoo, Dinesh K. Misra, Girija S. Chaubey,Jim Salvador, Nathan Takas, and Pierre F.P. Poudeu

•Invited Paper






Structure and Transport Properties ofSro.75-xCaxYo.25Coo.25Mno.7503-8 (0 < x < 6) 199

A. Galeeva, Ph. Napolsky, S. Istomin, A. Gippius,and D. Khokhlov

Synthesis of Biocompatible Magnetic Iron Oxide(y-Fe2O3 and Fe3O4) Nanoparticles by a ModifiedPolyol Process for Biomedical Applications 205

Georgia Basina, Ioannis Panagiotopoulos,Eamonn Devlin, George Hadjipanayis,Levent Colak, Costas Hadjipanayis, Hui Mao,Georgios Diamantopoulos, Michael Fardis,Georgios Papavassiliou, Dimitris Niarchos,and Vasilis Tzitzios

Ferroelectric and Ferromagnetic Properties of Co DopedBiFeO3 Thin Films 213

D. Barrionuevo, S.P. Singh, M.S. Tomar,and R.S. Katiyar

Phenomena and Mechanism on Phase TransformationTwinning in Nanocrystalline BaTiO3 219

Sujata Mazumder and Jiten Ghosh

POSTER SESSION: FILMS AND GROWTH

* Synthesis of Complex-Oxide Nanorods via Pulsed-LaserDeposition 227

John E. Mathis, Gyula Eres, Claudia Cantoni,Kyunghoon Kim, and Hans M. Christen

CuO Nanowire-Co304 Nanoparticle Heterostructuresand Their Vertically Aligned and Horizontally SuspendedArchitectures 233

Wenwu Shi and Nitin Chopra

•Invited Paper






POSTER SESSION: CHARACTERIZATION

The Path Towards Woven Thin-Film Transistors 241Kunigunde Cherenack and Gerhard TrGster

Antireflective Optical Properties of Colloidal SubwavelengthNanostructured Surfaces 247

Bo-Tau Liu and Sheng-Jie Tang

Effect Co-, and Sc- Doping on the Functional Propertiesof Nanocrystailine Powders and Thin Films of ZnO 253

Marco Galvez, Oscar Perales-Perez, and S.P. Singh

Tailoring Sol-Gel Transition Processes for the Designof Novel Shape Metal Oxide Materials 259

Martin Jarvekulg, Raul Valbe, Kathriin Utt,Martin Timusk, and Tanel TStte

The Role of Sputter Pressure in Influencing Electricaland Optical Properties of ITO on Glass 265

S. Elhalawaty, K. Sivaramakrishnan,N.D. Theodore, and T.L. Alford

The Properties of Silica and Hybrid Nanostructures 277Avi Shalav, Taehyun Kim, and Robert G. Elliman

Effects of He-Irradiation on the Metal-to-Insulator Transitionof Vanadium Dioxide Nanoclusters 283

H. Karl, J. Peng, and B. Stritzker

POSTER SESSION: NOVEL DEVICES

Tuning the Magnetic Domain Structure of Spin-PolarizedComplex Oxide Nanostructures 293

Joanna S. Bettinger, Rajesh V. Chopdekar,Brooke L. Mesler, Douglas Chain, Andrew Doran,Erik Anderson, Andreas Scholl, and Yuri Suzuki

POSTER SESSION: THIN FILM TRANSISTORS

ZnO-CdZnS Core-Shell Nanocable Arrays for Highly EfficientPhotoelectrochemical Hydrogen Generation. 301

Yoon Myung, Dong Myung Jang, Yong Jei Sohn,Tae Kwang Sung, Gyeong Bok Jung, Yong Jae Cho,Han Sung Kim, and Jeunghee Park






Silicon-Based Microplatforms for Characterizationof Nanostructured Layers with Application in IntermediateTemperature Micro Solid Oxide Fuel Cells 307

I. Garbayo, A. Taranc6n, J. Santiso, A. Cavallaro,I. Gracia, C. Cane, andN. Sabate

Structure/Property Relations in Bulk Versus Solution DerivedProton Conducting Ceramics of the Form SrCeo.95Ybo.o503-5with Applications in Membrane Separations 315

Kyle S. Brinkman, Elise B. Fox, Paul Korinko,Rob Lascola, Qiang Liu, and Frank Chen

Synthesis and Characterization of Ag/CeO2Nanocomposites 323

Antonella Glisenti, Andrea Frasson,Alessandro Galenda, Matteo Ferroni,Isabella Concina, and Marta Maria Natile

Antimony Doped ZnO Nanorods—A Changefrom n to p Type? 329

Joe Briscoe, Diego E. Gallardo, and Steve Dunn

Synthesis and Thermal Stability of HfO2 Nanoparticles 335Girija S. Chaubey, Yuan Yao, Julien P.A. Makongo,Pranati Sahoo, Pierre F.P. Poudeu,and John B. Wiley

Proton Conduction through Interface Phase of CPAA/KDPComposites 341

Dmitry A. Zakharyevich and Aleksey S. Neustroev

Electrolyte and Cathode Studies for Micro-Solid OxideFuel Cell 347

Yan Yan, Janine Conde, and Paul Muralt

Effect of Substrate Type on the Electrical and OpticalProperties of Cold-Sputtered Indium Tin Oxide Filmsas a Function of Post-Deposition Heat Treatment 353

Salil M. Joshi, Gregory W. Book,and Rosario A. Gerhardt

Author Index 359

Subject Index 363






PREFACE

Symposium O, "Multifunctional Nanoparticle Systems - Coupled Behavior andApplications" was held April 5-9 as part of the 2010 MRS Spring Meeting in SanFrancisco, California. The symposium was opened with a half-day tutorial given by BingXu, entitled "Multifunctional Nanoparticles for Biomedical Applications." The tutorialwas followed by four days of oral and poster presentations on optical and magneticprobes for biomedical applications, energy applications, multifunctional polymers, andmultifunctional oxides. More than 140 talks and posters were presented, including 29invited talks.

Multifunctional nanoparticle systems integrate multiple functional inorganic ororganic building blocks, thus providing improved or new material properties unavailablefrom single components. They exhibit rich physics and provide new opportunities forproperty engineering and self-assembly. Hybrid inorganic-organic and purely inorganicmultifunctional nanoparticle systems are potentially useful in diverse fields, includingmedical diagnostics and therapy and biological/environmental sensing, catalysis, andresponsive materials. It is also crucial to further develop synthetic approaches formultifunctional nanoparticles and to investigate their coupled properties and collectivebehaviors.

We gratefully acknowledge all of the invited speakers and session chairs for helpingto make this symposium possible. Each proceedings paper was peer-reviewed, and wethank the reviewers for their time and energy invested in their reviews. We also thankthe Army Research Office, the Journal of Materials Chemistry, and MRS for theirfinancial support of this symposium.

Joseph B. TracyYuping BaoAndrew M. DattelbaumYadong Yin

July 2010






MATERIALS RESEARCH SOCIETY SYMPOSIUM PROCEEDINGS

Volume 1245 — Amorphous and Polycrystalline Thin-Film Silicon Science and Technology—2010,Q. Wang, B. Yan, C.C. Tsai, S. Higashi, A. Flewitt, 2010, ISBN 978-1-60511-222-0

Volume 1246 — Silicon Carbide 2010—Materials, Processing and Devices, S.E. Saddow, E.K. Sanchez,F. Zhao, M. Dudley, 2010, ISBN 978-1-60511-223-7

Volume 1247E —Solution Processing of Inorganic and Hybrid Materials for Electronics and Photonics,2010, ISBN 978-1-60511-224-4

Volume 1248E —Plasmonic Materials and Metamaterials, J.A. Dionne, L.A. Sweatlock, G. Shvets, L.P. Lee,2010, ISBN 978-1-60511-225-1

Volume 1249 — Advanced Interconnects and Chemical Mechanical Planarization for Micro- andNanoelectronics, J.W. Bartha, C.L. Borst, D. DeNardis, H. Kim, A. Naeemi, A. Nelson,S.S. Papa Rao, H.W. Ro, D. Toma, 2010, ISBN 978-1-60511-226-8

Volume 1250 — Materials and Physics for Nonvolatile Memories II, C. Bonafos, Y. Fujisaki, P. Dimitrakis,E. Tokumitsu, 2010, ISBN 978-1-60511-227-5

Volume 125 IE —Phase-Change Materials for Memory and Reconfigurable Electronics Applications,P. Fons, K. Campbell, B. Cheong, S. Raoux, M. Wuttig, 2010, ISBN 978-1-60511-228-2

Volume 1252— Materials and Devices for End-of-Roadmap and Beyond CMOS Scaling, A.C. Kummel,P. Majhi, I. Thayne, H. Watanabe, S. Ramanathan, S. Guha, J. Mannhart, 2010,ISBN 978-1-60511-229-9

Volume 1253 — Functional Materials and Nanostructures for Chemical and Biochemical Sensing, E. Comini,P. Gouma, G. Malliaras, L. Torsi, 2010, ISBN 978-1-60511-230-5

Volume 1254E —Recent Advances and New Discoveries in High-Temperature Superconductivity, S.H. Wee,V. Selvamanickam, Q. Jia, H. Hosono, H-H. Wen, 2010, ISBN 978-1-60511-231-2

Volume 1255E —Structure-Function Relations at Perovskite Surfaces and Interfaces, A.P. Baddorf,U. Diebold, D. Hesse, A. Rappe, N. Shibata, 2010, ISBN 978-1-60511-232-9

Volume 1256E —Functional Oxide Nanostructures and Heterostructures, 2010, ISBN 978-1-60511-233-6Volume 1257 — Multifunctional Nanoparticle Systems—Coupled Behavior and Applications, Y. Bao,

A.M. Dattelbaum, J.B. Tracy, Y. Yin, 2010, ISBN 978-1-60511-234-3Volume 1258— Low-Dimensional Functional Nanostructures—Fabrication, Characterization and

Applications, H. Riel, W. Lee, M. Zacharias, M. McAlpine, T. Mayer, H. Fan, M. Knez,S. Wong, 2010, ISBN 978-1-60511-235-0

Volume 1259E —Graphene Materials and Devices, M. Chhowalla, 2010, ISBN 978-1-60511-236-7Volume 1260 — Photovoltaics and Optoelectronics from Nanoparticles, M. Winterer, W.L. Gladfelter, D.R.

Gamelin, S. Oda, 2010, ISBN 978-1-60511-237-4Volume 126IE —Scanning Probe Microscopy—Frontiers in NanoBio Science, C. Durkan, 2010,

ISBN 978-1-60511-238-1Volume 1262 — In-Situ and Operando Probing of Energy Materials at Multiscale Down to Single Atomic

Column—The Power of X-Rays, Neutrons and Electron Microscopy, CM. Wang,N. de Jonge, R.E. Dunin-Borkowski, A. Braun, J-H. Guo, H. Schober, R.E. Winans, 2010,ISBN 978-1-60511-239-8

Volume 1263E —Computational Approaches to Materials for Energy, K. Kim, M. van Shilfgaarde, V. Ozolins,G. Ceder, V. Tomar, 2010, ISBN 978-1-60511-240-4

Volume 1264 — Basic Actinide Science and Materials for Nuclear Applications, J.K. Gibson, S.K. McCall,E.D. Bauer, L. Soderholm, T. Fanghaenel, R. Devanathan, A. Misra, C. Trautmann,B.D. Wirth, 2010, ISBN 978-1-60511-241-1

Volume 1265 — Scientific Basis for Nuclear Waste Management XXXIV, K.L. Smith, S. Kroeker,B. Uberuaga, K.R. Whittle, 2010, ISBN 978-1-60511-242-8

Volume 1266E —Solid-State Batteries, S-H. Lee, A. Hayashi, N. Dudney, K. Takada, 2010,ISBN 978-1-60511-243-5

Volume 1267 — Thermoelectric Materials 2010—Growth, Properties, Novel Characterization Methods andApplications, H.L. Tuller, J.D. Baniecki, G.J. Snyder, J.A. Malen, 2010,ISBN 978-1-60511-244-2

Volume 1268 •— Defects in Inorganic Photovoltaic Materials, D. Friedman, M. Stavola, W. Walukiewicz,S. Zhang, 2010, ISBN 978-1-60511-245-9

Volume 1269E —Polymer Materials and Membranes for Energy Devices, A.M. Herring, J.B. Kerr,S.J. Hamrock, T.A. Zawodzinski, 2010, ISBN 978-1-60511-246-6






MATERIALS RESEARCH SOCIETY SYMPOSIUM PROCEEDINGS

Volume 1270 — Organic Photovoltaics and Related Electronics—From Excitons to Devices,V.R. Bommisetty, N.S. Sariciftci, K. Narayan, G. Rumbles, P. Peumans, J. van de Lagemaat,G. Dennler, S.E. Shaheen, 2010, ISBN 978-1-60511-247-3

Volume 127IE —Stretchable Electronics and Conformal Biointerfaces, S.P. Lacour, S. Bauer, J. Rogers,B. Morrison, 2010, ISBN 978-1-60511-248-0

Volume 1272 — Integrated Miniaturized Materials—From Self-Assembly to Device Integration,C.J. Martinez, J. Cabral, A. Fernandez-Nieves, S. Grego, A. Goyal, Q. Lin, JJ. Urban,J.J. Watkins, A. Saiani, R. Callens, J.H. Collier, A. Donald, W. Murphy, D.H. Gracias,B.A. Grzybowski, P.W.K. Rothemund, O.G. Schmidt, R.R. Naik, P.B. Messersmith,M.M. Stevens, R.V. Ulijn, 2010, ISBN 978-1-60511-249-7

Volume 1273E —Evaporative Self Assembly of Polymers, Nanoparticles and DNA, B.A. Korgel, 2010,ISBN 978-1-60511-250-3

Volume 1274 — Biological Materials and Structures in Physiologically Extreme Conditions and Disease,M.J. Buehler, D. Kaplan, C.T. Lim, J. Spatz, 2010, ISBN 978-1-60511-251-0

Prior Materials Research Society Symposium Proceedings available by contacting Materials Research Society






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