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NCOFIS - 2012 NATIONAL CONFERENCE ON FRONTIERS IN SPECTROSCOPY (NCOFIS-2012) APRIL 2 nd and 3 rd , 2012 ORGANISED BY PG & RESEARCH DEPARTMENT OF CHEMISTRY GOVERNMENT ARTS COLLEGE TIRUVANNAMALAI, TAMIL NADU (NAAC Accredited B-grade College) In Collaboration with DEPARTMENT OF CHEMISTRY THIRUVALLUVAR UNIVERSITY VELLORE, TAMIL NADU Sponsored By UNIVERSITY GRANTS COMMISSION SOUTH-EASTERN REGIONAL OFFICE, HYDERABAD

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Page 1: NATIONAL CONFERENCE ON FRONTIERS IN SPECTROSCOPY filencofis - 2012 national conference on frontiers in spectroscopy (ncofis-2012) april 2nd and 3rd, 2012 organised by pg & research

NCOFIS - 2012

NATIONAL CONFERENCE ON FRONTIERS IN SPECTROSCOPY

(NCOFIS-2012)

APRIL 2nd

and 3rd

, 2012

ORGANISED BY

PG & RESEARCH DEPARTMENT OF CHEMISTRY

GOVERNMENT ARTS COLLEGE

TIRUVANNAMALAI, TAMIL NADU

(NAAC Accredited B-grade College)

In Collaboration with

DEPARTMENT OF CHEMISTRY

THIRUVALLUVAR UNIVERSITY

VELLORE, TAMIL NADU

Sponsored By

UNIVERSITY GRANTS COMMISSION

SOUTH-EASTERN REGIONAL OFFICE, HYDERABAD

Page 2: NATIONAL CONFERENCE ON FRONTIERS IN SPECTROSCOPY filencofis - 2012 national conference on frontiers in spectroscopy (ncofis-2012) april 2nd and 3rd, 2012 organised by pg & research

NCOFIS - 2012

Page 3: NATIONAL CONFERENCE ON FRONTIERS IN SPECTROSCOPY filencofis - 2012 national conference on frontiers in spectroscopy (ncofis-2012) april 2nd and 3rd, 2012 organised by pg & research

NCOFIS - 2012

Dr. G. Elango M.Sc., M.Phil., Ph.D.,

Convenor - NCOFIS-2012

Assistant professor, Department of Chemistry

Government Arts College, Tiruvannamalai.

PREFACE

This NATIONAL CONFERENCE ON FRONTIERS IN SPECTROSCOPY (NCOFIS-

2012) has been organized on April 2nd

and 3rd

, 2012 under the joint auspices of the UGC,

Hyderabad in Collaboration with Thiruvalluvar University, Vellore by PG & Research

Department of Chemistry, Government Arts College, Tiruvannamalai.

This conference aims to introduce spectroscopy to students and research scholars who

will have a wide spectrum of backgrounds and generate their enthusiasm for a deeper

understanding of spectroscopy. It also brings together scientists working on various aspects of

spectroscopy form all over the country to enable stimulating discussion and exchange of

information.

In this century not only the chemists but also the scientists, in every discipline like

physics, mathematics and informatics are at hand to share the responsibilities. Therefore this

conference will be a platform to cater the above needs and interests of the students and research

scholars of various disciplines.

With the help of the Delegates and Scientists of high caliber who will preside the

conference will give wide knowledge to the students, and research scholars of various

disciplines.

I extend my sincere thank to eminent personalities for their acceptance to deliver the

keynote address to shape this National Conference.

This first National Conference of this magnitude and its proceedings could not have been

possible without the support of UGC.

I hope that the scientific deliberations and discussion of the gathering during a two day

Conference would help to stimulate better scientific understanding and technical innovations for

the growth of polymer research and development.

Dr. G. Elango

(Convener – NCOFIS-2012)

Page 4: NATIONAL CONFERENCE ON FRONTIERS IN SPECTROSCOPY filencofis - 2012 national conference on frontiers in spectroscopy (ncofis-2012) april 2nd and 3rd, 2012 organised by pg & research

NCOFIS - 2012

NCOFIS – 2012

PROGRAMME

Day 1: 02-04-2012, Monday

09:00am to 10:00am Registration

10:00am to 11:00am Inauguration

11:00am to 11:15am Tea

11:15am to 01:00pm

Technical Session - I

Chairperson

Bhatnagar Dr. N. Jayaraman

Professor

Department of Organic Chemistry

Indian Institute of Science

Bangalore.

Oral Presentation by 10 Candidates

01:00pm to 02:00pm Lunch

02:00pm to 05:00pm

Technical Session - II

Chairperson

Dr.K.P.Elango

Associate Professor of Chemistry

Gandhigram Rural Institute

Deemed University

Gandhigram.

Oral Presentation by 12 Candidates

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NCOFIS - 2012

Day 2: 03-04-2012, Tuesday

10:00am to 01:00pm

Technical Session - III

Chairperson

Dr. Vishnu Priya Bakthavachalam

Deputy General Manager

Head, Analytical Division

Aditya Birla Science & Technology Centre

Mumbai.

Oral Presentation by 12 Candidates

01:00pm to 02:00pm Lunch

02:00pm to 04:00pm

Technical Session - IV

Chairperson-I

Dr.K.Suresh

Deputy General Manager

New Materials-Ultratech Cement Ltd.

Aditya Birla Group

Raigad District, Maharastra.

Chairperson-II

Dr.A.Pandurangan

Director

Institute of Catalysis & Petroleum

Technology

Anna University

Chennai

Oral Presentation by 12 Candidates

04:00pm to 04:30pm Poster Presentation

04:30pm to 05:00pm Valedictory function

Page 6: NATIONAL CONFERENCE ON FRONTIERS IN SPECTROSCOPY filencofis - 2012 national conference on frontiers in spectroscopy (ncofis-2012) april 2nd and 3rd, 2012 organised by pg & research

NCOFIS - 2012

CONTENTS

TITLE PAGE NO.

TECHNICAL SESSION DETAILS i - iv

MESSAGES

CHANCELLOR – VIT UNIVERSITY, VELLORE v

REGISTRAR, THIRUVALLUVAR UNIVERSITY, VELLORE vi

PRINCIPAL, GOVERNMENT ARTS COLLEGE, TIRUVANNAMALAI vii

RESEARCH OFFICER – TANSCHE, CHENNAI viii

HEAD OF THE DEPARTMENT - CHEMISTRY ix

HEAD OF THE DEPARTMENT – CHEMISTRY, THIRUVALLUVAR

UNIVERSITY, VELLORE x

CONVENER – NCOFIS-2012 xi

STATE TREASURER – TNGCTA xii

EDITOR-IN-CHIEF xiii

EXECUTIVE EDITOR xiv

CONTROLLER OF EXPLOSIVES xv

CHAIRPERSONS DETAILS Xvi - xxi

ORAL PRESENTATION 1 - 394

POSTER PRESENTATION 395 - 526

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i NCOFIS-2012

Technical Session – I

Chairperson : Bhatnagar Dr. N. Jayaraman

Paper Title Time Page

No

Tir Spectral Study On Biodegradable Hydrogels: A Review

D.S.Franklin , and S.Guhanathan

Bet

wee

n 1

0:0

0a

m a

nd

01:0

0p

m

2

Gc-Ms Analysis Of The Ethanolic Extract Of Phallusia Nigra Savigny, 1816

V.K. Meenakshi, M. Paripooranaselvi, S. Gomathy, K.P. Chamundeswari 12

Growth And Spectroscopic Studies Of Kdp Crystals Doped With L-Aspartic

Acid

R.Krishnamurthy, R.Rajasekaran and Bincy Susan Samuel

21

Synthesis And Charcterisation Of Novel Biodegradable Aliphatic Co

Polyesters

L Sowbagyalakshmiprabha, R Nanthini , K Prabhu

30

Phytoconstituents Analysis By Gc-Ms & Therapeutic Efficacy Of Mahonia

Leschenaultia Takeda On Acetaminophen Induced Hepatotoxicity In Rats

P.Monisha, M.Ramya, J.Perumal raj and *S. Palani,

48

Adsorption Of Commassie Navy Blue, Acid Dye By Low Cost Adsorbents

Such As Wood And Bentonite

V.Manivannan

63

Ftir Spectral Studies On Random Block Co-Polyester

G.Elango, T. Venkataraman, T.Sivaramakrishnan and S. Guhanathan 68

Investigation On Glycerol Based Hydrogels –Synthesis And

Characterisation

D.S. Franklina, And S. Guhanathanb

77

Removal Of Pb(Ii) By A Low Cost Adsorbent Prepared From

Nanocomposites Of Chitosan With Methylcellulose And Clay

V. Kanchana and P.N.Sudha

91

Room Temperature Green Synthesis Of Silver Nanoparticles By Single Step

Method

M. Balaji, M. Janaki Vembu, T. Somanathan* and N. Gokulakrishnan*

100

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ii NCOFIS-2012

Technical Session – II

Chairperson : Dr.K.P.Elango

Paper Title Time Page

No

Growth And Spectroscopic Studies Of Pure And L-Glutamic Acid Doped

Zinc Tris (Thiourea) Sulphate (Zts) Single Crystals

Bincy Susan Samuel, R.Krishnamurthy, R.Rajasekaran

Bet

wee

n 0

2:0

0p

m a

nd

05:0

0p

m

105

Ftir And Xrd Studies Of Microcrystalline Cellulose Extracted From Sisal

Fibers By Steam Explosion.

M.S. Sivakami and P.N.Sudh

114

Spectrophotometric And Spectrofluorimetric Studies On The Interaction Of

Atenolol With P-Chloranil

C. Balraj, K. Ganesh, A. Satheshkumar, K. P. Elango 123

Synthesis Of 5-Methoxydibenzo [B,G][1,8]Naphthyridines And Evaluation

Of Their Biological Activity

G. Arulprakasha, and N. Krithik

131

The Study Of Morbidity And Mortality Of Air Pollution From Tanneries In

Vellore District In Reference To The Respiratory Syndromes

A.Thaminum Ansari And K. Subramani 136

Synthesis, Growth And Spectroscopic Studies On New Nonlinear Optical

Single Crystal: L-Lysinium Trifluoroacetate

G.Nathiya And S.M. Ravi Kumar

152

Wound Healing Applications Of Chitosan Containing Biodegradable Polymer Blends I.Yuvarani , P.N.Sudha

160

Synthesis ,Growth ,And Characterisation Of 2-Aminopyridine Complex

R.Srineevasan ,R.Udhayarekha , R.Rajasekaran 172

Synthesis And Characterisation Of General Purpose Unsaturated

Polyester/Clay Nano Composites

N. Prabu, G. Elango, Mansur Ahmed, T. Sivaramakrishnan And

S. Guhanathan

178

Synthesis, Characterisation And Antibacterial Activity Of Some Novel

Schiff Base Complexes Of Co(Ii) And Cu(Ii) Metal Ions

A.K. Ibrahim Sheriff, S.Syed Shafi, E.Rajini, D.Sathis Kumar

185

Heme Protein Immobilized Large Pore Three Dimensional Nanoporous

Silica: A Characterisation Study By FT-IR And N2 Physisorption

Measurement

M. Harikrishnan. V. Kannan, N. Gokulakrishnan, T.Somanathan

194

Heavy Metal Chelation Using Natural Biopolymer

Saravanan D And Sudha P N 202

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iii NCOFIS-2012

Technical Session – III

Chairperson : Dr. Vishnu Priya Bakthavachalam

Paper Title Time Page

No

A Study On Synthesis, Characterization And Biological Activities Of 1-

((Dicyclohexylamino) (Phenyl)Methyl) Pyrrolidine- 2,5-Dione And Its Mnii,

Znii And Cdii Metal Complexes

S.Rajeswaria*, M.Vijaya Chandrasekara And G.Venkatesa Prabhu

Bet

wee

n 1

0:0

0a

m a

nd

01:0

0p

m

208

Amperometric Determination Of Ascorbic Acid Using Sol Gel Derived

Copperhexacyanoferrate Nano Particles Carbon Ceramic Composite

Modified Electrode

J.Pandidurai, 1 N.Suresh, 1 M.Rajeshkumar, 1 R.A. Kalaivani1 And

S. Sriman Narayanan

214

Bimetallic Oxides Nanoparticles For The Synthesis Of Carbon Nanotubes By Chemical Vapour Deposition Technique A. Thondaimaana, Stalin Josepha, T. Somanathanb, And N. Gokulakrishnan

230

Characterisation Of Hydrophobic Inorganic-Organic Hybrid Nanoporous

Silica By 29si Mas-Nmr Technique

V. Saravanana, V. Sivashankara, G. Navaneetha Krishnana,

N. Gokulakrishnanb*, T.Somanathan

238

Characterization Of Chemically Functionalized Carbon Nanotubes Using

Spectroscopic Techniques

D. Balajia, N. Surendarraja, T. Somanathanb,* And N. Gokulakrishnanb,*

246

Characterization Of Chitosan Blended Vermiculite- Adsorbent By Analytical Techniques M. Soundarrajan, T. Gomathi And P.N. Sudha

253

Chitosan And Starch Based Biodegradable Polymer Material For Food

Packaging Applications

K.Nasreen, K.Vijayalakshmi And P.N.Sudha

259

Corrosion Behavior Of Solvent Free Echanochemically Synthesized

Polyaniline/ Clay Nanocomposites

N.Kalaivasan And S. Syed Shafi

266

Determination of optical constants of Al doped ZnO thin films from UV-

Vis-NIR spectra

T. Ganesh, S. Rajesh, Francis P. Xavier

276

Chararecterisation Of An NLO Semi Organic Crystal Using Spectroscopic

Techniques

S.Gopinath, S.Barathan, R.Rajasekaran

283

Enhancement of zinc chloride on the growth and spectroscopical properties

of L-PCCM crystals

S .Vetrivel, K.Kanagasabapathy and R. Rajasekaran

289

Gadolinium Nanoparticles as a Potential Magnetic Resonance Imaging

Contrast Agent

A. Abilarasu, G. Vijayasarathi, M. Shanmugam, N. Gokulakrishnan and T.

Somanathanb,

299

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iv NCOFIS-2012

Technical Session – IV

Chairpersons : Dr.K.Suresh and Dr.A.Pandurangan

Paper Title Time Page

No

GC-MS Studies On Methanolic Leaves Extract Of Limonia Crenulata

L. Suresh Kumar, J. And G. Manikandan

Bet

wee

n 0

2:0

0p

m a

nd

05:0

0p

m

304

General Spectroscopy: A Review

K.Rajeshwari And P.N. Sudha 317

Growth And Opticial Studies Of 2-Aminopyridine, Potassium Chloride And

Glycine (2-Apkcg) Single Crystals For Nlo Applications

R.Srineevasan, R.Rajaskaran

328

Heavy Metal Chelation Using Natural Biopolymer

Saravanan D And Sudha P N 334

Kinetics And Mechanism Of The Oxidation Of Α –Hydroxy Acid By

Pyridinium Fluorochromate In Aqueous Acetic Medium.

S. Zaheer Ahmed , S Syed Shafi And S. Sheik Mansoor

339

Measurement Of Natural Radioactivity In Building Material From Chengam,

Tiruvannamalai District, Tamilnadu Using Gamma-Ray Spectrometer

R.Ravisankar, K.Vanasundari, M.Suganya, R.Kavitha And M.Karthikeyan

346

Characterization Of Intelligent Polymer Hydrogels By NMR Spectroscopy

D.S.Franklin, G. Elango And S.Guhanathan 356

Synthesis And Characterization Of Copper Nanoparticles By Chemical

Reduction Method

Arunachalam Dinesh Karthik And Kannappan Geetha

363

Synthesis And Characterization Of Certain Biodegradable Aliphatic

Polyesters

Ravi.A, Nanthini. R. And Karunanidhi.M

370

Synthesis And Characterization Of Polyaniline-Exchanged Bentonite

Nanocomposites

S Tharani, S. David Amalraj And G Harichandran

376

Applications Of Ftir Spectroscopy In Corrosion Monitoring Technique

Nirmala Baby, P.Manjula, Mrs.S.Manimegalai, K.N.Manonmani 386

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v NCOFIS-2012

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vi NCOFIS-2012

Dr. B. KRISHNAMURTHY M.A., Ph.D.,

Registrar

MESSAGE

I am extremely happy to know that the Department of Chemistry, Government Arts

College, Tiruvannamalai organising an UGC sponsored National conference on frontiers in

spectroscopy (NCOFIS-2012) in collaboration with our University chemistry department for

two days 2nd and 3rd April 2012. I am sure, this conference, will be a source of great

enrichment and it would contribute to the ongoing research in various fields of chemistry.

I am sure that the seminar will enlighten and motivate many people of this area.

I wish the conference will be a successful one.

(B. KRISHNAMURTHY)

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vii NCOFIS-2012

Government Arts College Tiruvannamalai – 606601, Tamil Nadu, India

(NAAC Accredited B-Grade College)

Office: 04175 – 236298

Fax : 04175 – 236553

Dr. R.RAJASEKARAN.M.Sc., M.Phil., Ph.D.,

Principal, Government Arts college

Tiruvannamalai

MESSAGE

I am delighted to know that the Department of Chemistry, Government Arts College,

Tiruvannamalai will host a two day conference on 2nd

and 3rd

April 2012, to explore

groundbreaking discoveries made through the use of spectroscopy. The event features

presentations by four distinguished scientists on how they applied spectroscopy to study the

three-dimensional arrangement of atoms in complex bio-molecules and the motions and

interactions that are important to their functioning.

“Understanding the nature of biomolecular interactions in space and time in atomic detail is

essential to shed light on these communication networks and to design alternatives when they

are compromised by disease. Nuclear magnetic resonance (NMR) spectroscopy has evolved

as the premier technique for studying the structure and functionality of these complex bio-

molecules.”

I encourage convenor, organizing committee and various faculty members of this college to

formulate the delegate, a frequent visitor to our Government Arts College, Tiruvannamalai

for their various research updates.

I wish each and everyone worked for this great success of the conference.

(R.RAJASEKARAN)

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viii NCOFIS-2012

___________________________________________________________________________

Date: 05-03-2012

MESSAGE

It is a matter of immense pleasure that the PG Department of

Chemistry,Government Arts College, Tiruvannamalai, Tamilnadu is organising a

National Conference on “Frontiers in Spectroscopy” on 2nd and 3rd April 2012.

I hope that this conference will give wide exposure to the students, research

and academicians.

I congratulate the organizers of the conference to this venture and extend my

best wishes for the success of the event.

(V. VASANTHAKUMARI)

RESEARCH OFFICER

website: www.tnuniv.ac.in

e-mail: [email protected]

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ix NCOFIS-2012

Government Arts College Tiruvannamalai – 606601, Tamil Nadu, India

(NAAC Accredited B-Grade College)

Office: 04175 – 236298

Fax : 04175 – 236553

DR. V. MANNIVANNAN, M.SC., Ph.D.

HEAD, DEPARTMENT OF CHEMISTRY

GOVERNMENT ARTS COLLEGE, TIRUVANNAMALAI.

(NCOFIS-2012)

MESSAGE

The conference entitled “Frontiers in spectroscopy” consists of invited lectures by 6

eminent scientists of our Country working in different areas, oral presentations and poster

presentations by Research Scholars. The topics include different areas of spectroscopy. This

conference will provide a unique platform to the fresher’s in this field.

Our excursions into this area has lead to the developments of novel approaches in

identifying and to interpret the various materials while at the same time to led to a greater

understanding of the role of the spacer segment that links the branch points in governing their

solution conformation and their bulk properties of compounds.

I hope this conference will be a bridge for various research scholars. I convey my

heartfelt appreciation to one and all.

(V. MANNIVANNAN)

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x NCOFIS-2012

Dr. S. Syed Shafi

Professor and Head, Department of Chemistry

Thiruvalluvar University, Vellore.

MESSAGE

I am happy to learn that the Post Graduate Department of Chemistry, Government

Arts College, Tiruvannamalai is adding another feather to its cap of achievement by

conducting a UGC sponsored National conference on Frontiers in Spectroscopy (NCOFIS-

2012) in collaboration with our department for two days 2nd

and 3rd

April 2012.

Spectroscopy plays a vital role in the discovery of new technologies and materials,

from nanomaterials to more efficient synthesis of pharmaceuticals.

Spectroscopy can be used to discover the energies of electrons within atoms or

molecules. It can help us to find out how the atoms are arranged in the molecule and also

solve the problem of identification of the structure of organic compounds.

I hope that the response will be good and the research temperament of the students

and other participants will get enhanced.

I wish the national conference the grand success.

(S. Syed Shafi)

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xi NCOFIS-2012

Government Arts College Tiruvannamalai – 606601, Tamil Nadu, India

(NAAC Accredited B-Grade College)

Office: 04175 – 236298

Fax : 04175 – 236553

Dr. G. Elango M.Sc., M.Phil., Ph.D.,

Convenor - NCOFIS-2012

Assistant professor, Department of Chemistry

Government Arts College, Tiruvannamalai.

Date: 27/03/2012

MESSAGE

I am extremely happy to welcome every one for the UGC sponsored National Level

Conference on Frontiers in spectroscopy (NCOFIS-2012). This conference consists of

valuable key note addresses from eminent scientists from various parts of the India. This will

be really useful to the budding research scholars.

Spectroscopy is an instrumental tool to identify, to detect and to confirm the various

stages of the compounds. A spectroscopic technique satisfies all interdisciplinary area

research in fulfilling their need. This conference wills really a boon to the scientific

community in transforming their views and ideas. I convey my sincere thanks for all

committee members for uplifting the conference in various stages of angles.

I wish the conference be a grand success.

(G.ELANGO)

Convener, NCOFIS- 2012

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xii NCOFIS-2012

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xiii NCOFIS-2012

Dr. S. GUHANATHAN, M.Sc., Ph.D.,

(EDITOR IN CHIEF – NCOFIS -2012)

PRINCIPAL INVESTIGATOR (UGC PROJECT)

PG & RESEARCH DEPARTMENT OF CHEMISTRY

MUTHURANGAM GOVERNMENT ARTS COLLEGE

(AUTONOMOUS)

Date: 23/03/2012

MESSAGE

I am happy to hear that the Department of Chemistry is conducting UGC sponsored

National Level Conference on “Frontiers in Spectroscopy” during 2nd

and 3rd

April 2012 in

collaboration with Department of Chemistry, Thiruvalluvar University, Vellore

In this occasion, I extend my heartiest greetings and felicitations to the faculty of

chemistry. I am confident that the department will be able to convert challenges into

opportunities and reach greater heights of performance. Very soon this department will

become research department. The Conference activities carried out by the department will be

for the benefit of the Post Graduate students & Research Scholars and would carry interesting

and valuable articles from the faculty, staff and students of various Universities and colleges

showcasing their talents and innovative skills latent in them.

I convey my heartfelt appreciation for arranging this valuable conference. I wish the

conference to be a splendid success.

(Dr. S.GUHANATHAN)

Editor in Chief, NCOFIS- 2012

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xiv NCOFIS-2012

EXECUTIVE EDITOR – NCOFIS -2012

Date: 27/03/2012

MESSAGE

I am happy to convey my warm greetings for the success of this conference “Frontiers

in Spectroscopy” and I congratulate the convener for hosting. This conference is addressing

many issues on Spectroscopy. I am confident that your deliberations and the outcome of your

efforts will raise an awareness to the students and research scholars.

“A positive thinker sees an opportunity in every difficulty”

I wish you every success in the accomplishment of objectives of this conference.

Dr.N.J

(EXECUTIVE EDITOR – NCOFIS -2012)

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xv NCOFIS-2012

Date: 14/03/2012

MESSAGE

I extend my best wishes and congratulations to the Conference Committee for a most

successful “National Conference on Frontiers in Spectroscopy - 2012” on 2nd & 3rd April

2012.NCOFIS-2012 will be a major milestone in the history of PG Department of Chemistry,

Government Arts College, Thiruvannamalai hosting such a great scientific event.

I am sure that NCOFIS-2012 will bring together all researchers and academicians

working on various spectroscopic techniques from all disciplines and strengthen their

networks.

I once again wish NCOFIS-2012 for every success.

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xvi NCOFIS-2012

N. Jayaraman

Professor

Department of Organic Chemistry,

Indian Institute of Science,

Bangalore 560 012, India

E-mail: [email protected];

Fax: +91 80 2360 0529; Tel: +91 80 2293 2578

DETAILS

Education

B.Sc., University of Madras (1984)

M.Sc., Annamalai University (1988)

Ph.D. Indian Institute of Technology, Kanpur, in 1994, under the supervision of

Professor S. Ranganathan

Postdoctoral fellow in the research group of Professor Sir J. F. Stoddart at the

University of Birmingham, UK, and at the University of California, Los Angeles,

USA (1994-1999)

Faculty at the Department of Organic Chemistry, IISc., Bangalore, since 1999

Major areas of research

Carbohydrate chemistry and dendrimer chemistry

Honors and awards

Shanti Swarup Bhatnagar Prize (2009)

Fellow of Indian Academy of Sciences (2011)

Chemical Research Society of India Medal (2007)

Diamond Jubilee Distinguished Fellow, University Institute of Chemical Technology,

Mumbai (2008-2009)

Professor Swaminathan Endowment Lecture, University of Madras, Chennai (2007)

Rajib Goyal Prize for Chemical Sciences (2011)

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xvii NCOFIS-2012

K. P. ELANGO

Associate Professor,

Department of Chemistry,

Gandhigram Rural Institute (Deemed University),

Gandhigram 624 302 TN,

E-mail: [email protected]

Key Note Address

Spectroscopic Studies on the Charge Transfer Complexes of Drugs with

Biologically Significant Acceptors

Drugs are organic compounds, and as a result, their activity, their solubility in plasma

and their distribution to various tissues is dependent on their physicochemical properties.

Even the interaction of a drug with a receptor or an enzyme is dependent on characteristics of

a drug molecule, such as ionization, electron distribution, polarity and electronegativity. If we

are to understand drug action, we must also understand the physicochemical parameters that

make this action possible. Physicochemical approaches are also being applied increasingly to

the study of drug action. The intent of the application of these approaches is either to

blueprint the information at hand with regard to a given type of drug activity or to provide a

rational guide to the synthesis of new compounds of greater activity. Raman, UV–vis, 1H

NMR, FT-IR, mass and fluorescence spectral techniques were employed to investigate the

mechanism of interaction of drug molecules with biologically significant acceptors such as

quinones and iodine. Equilibrium, thermodynamic and kinetic aspects of these interactions

have been investigated and various physic-chemical parameters related to the charge transfer

interaction have been computed. Such an attempt would definitely shed some on the study of

interaction of drug molecules in real pharmacokinetic study.

1. C.Balraj, K.Ganesh and K.P.Elango, J. Mol. Struc., 998, 110-118, 2011.

2. K.Ganesh, C.Balraj and K.P.Elango, Spectrochimica Acta Part A, 79, 1621-1629, 2011.

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Dr. Vishnupriya B.

Head, Analytical Science & Technology

Aditya Birla Science &Technology Company Ltd.,

Navi Mumbai, 410208

Key Note Address

Compositional Analysis using spectroscopic tools

Vishnupriya Bhakthavatsalam, Scientist in Charge of the Department of Analytical

science & Technology at the Aditya Birla Science & Technology, graduated in 2006 with a

doctorate (PHD Analytical Chemistry) from Auburn University (Auburn, USA), and obtained

a Post Doc in Indiana University in surface analytical chemistry in 2008. She also has couple

of masters in applied chemistry and Polymer science & Engineering from Guindy

Engineering College, Anna University. Dr Vishnupriya B started her career in analytical

research with ABSTCL in September 2008. Prior to that, she held scientific officer positions

at the Spic Science Foundation, Guindy Chennai. She is currently the head of the Department

of Analytical Science &Tech, where she supervises a team of thirteen scientists conducting

developmental activities on analytical methodologies and instrumental techniques supporting

the new products and new processes of Aditya Birla Group. Dr. Vishnupriya’s contributions

include the development of new methods for the aromatics quantification of heavy naphtha

using NIR, compositional analysis of particle impurities generated in the viscose staple fiber

spin line using Infrared and Raman spectroscopy and also on various other topics. Dr.

Vishnupriya’s work on Poly phenylene oxides resulted in scientific publications in patents

and articles in journal of new materials, journal of applied polymer science. Reviews of Dr.

Vishnupriya’s work and broader reach articles have appeared in Analyst, Electroanalysis etc.,

Abstract of Keynote Address: Particulate impurities are complex in composition and

technologically challenging to decode. Their appearance and their composition create a

quality performance barrier over time if a careful selection of tools and techniques are not

chosen to decode them. A complete understanding of the chemistry in each step is required;

therefore, characterization of these particle impurities at each step of the process in detail is

carried out. Once decoded, the history of those particles is searched to pin point the right

hypothesis where this could have happened. Then, effective measures are applied to evaluate

a suitable solution. Overall, this helps in enhancing the product appearance and solving

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xix NCOFIS-2012

mysterious inline impurities. Thus, spectroscopic tool’s choices can be interpreted not just in

the classical framework of product appeal, but in a holistic approach encompassing esthetics

and technology. As an analytical scientists working in the viscose fiber and textile field we

are charged with extracting the information hidden within the impurities of the product spin

line. This work is not only an indispensable part of quality efforts, but also, as the first step

toward building a material history of a perfect process. Indeed, a necessary and valuable

complement and their correlation to the availability of materials.

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xx NCOFIS-2012

Dr. K Suresh M.Sc., PhD., (Indian Institute of Science, Bangalore)

Deputy General Manager

New Materials-Ultratech Cement Ltd.

Aditya Birla Group

Raigad District, Maharastra.

Key Note Address

Spectroscopic Applications to New Materials

The lecture will dwell on new materials like Carbon nano-tubes, Zylon and their

applications in chemical, medical and engineering. Preparation and characterization of these

will be presented. Spectroscopic methods like UV, Confocal Raman Spectroscopic image

analysis, Different Fluorescence spectroscopic techniques for hazardous PAH will also be

presented. Application of simple UV visible spectroscopy for effective control and mitigation

of hexa-valent chromium in cement systems will also be briefed.

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xxi NCOFIS-2012

Dr. A. PANDURANGAN

Director

Institute of Catalysis and Petroleum Technology

Anna University, Chennai-600025. India.

Tel: 91-44-22358653 Fax: 91-44-22200660

E-mail: [email protected], [email protected]

DETAILS

Professional recognition, awards, fellowships received

Certificate of Merit- I have secured FIRST RANK in the college in M.Sc., Chemistry

in the University Examination during April 1990.

Jan.1991, Teaching Research Fellow, Anna University, Chennai, India.

TamilNadu Science and Technology –Young Scientist Project Award (1998-1999)

Max-Planck-Institute Post-Doctoral Fellowship, MPI for biochemie, Munich,

Germany. July2002-July2003

Hindustan Platinum Award for the Best Poster Presentation Presented during the 17th

National Symposium on Catalysis held at CSMCRI, Bhavnagar during Jan. 18-20,

2005.

Prestigious Sistla- Kameswari Young Scientist Gold Medal Award of the Catalysis

Society of India-2005- Honored on 18th

Jan-2005 at CSMCRI, Bhavnagar during Jan.

18-20, 2005.

Selected for BOYSCAST (Better Opportunity for Young Scientist in Chosen Area of

Science and Technology) fellowship program for the year 2005-2006 in the field of

Nanotechnology.

Tamilnadu Scientist Award (TANSA) for the year 2005 presented by Dr. M. K. Bhan

on 10.10.2007 under the discipline of Chemical Sciences by Tamilnadu State Council

for Science and Technology, Govt. of. Tamilnadu, Chennai

DARPA Fellowship, US Defence Department, Department of Chemical Engineering,

University of Massachusetts, Amherst, MA, USA, Apr.2009-Sep.2010.