notio sn presentation.pdf

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Confidential Confidential

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New New Syndiotactic Syndiotactic Elastomer Elastomer with Crystallinewith Crystalline

Structure controlled inStructure controlled in NanoNano Order Order

Mitsui Chemicals, Inc.Mitsui Chemicals, Inc.Elastomer Elastomer Div.Div.

SELLER WARRANTS TO THE BESTOF ITS KNOWLEDGE THAT THE USEOR SALE OF NOTIO TMSN WILL NOTINFRINGE UPON ANY PATENTCOVERING THE PRODUCT ITSELF,BUT DOES NOT WARRANT AGAINSTINFRINGEMENT BY REASON OF THEUSE THEREOF IN COMBINATIONWITH ANY OTHER PRODUCTS OR INTHE OPERATION OF ANY PROCESS.

SNSN


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1.1. What is NotioWhat is Notio TMTM--SNSN ??

2.2. Adapting for Adapting for calenderingcalendering of Notioof NotioTMTM

--SNSN

3.3. Features of NotioFeatures of Notio TMTM--SN leather SN leather

ContentsContents


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2013.02.2013.02. 2525Structure of NotioStructure of Notio TM TM - - SN SN

1. What is Notio1. What is Notio TM TM - - SN? SN?

NotioNotio TM TM - - SN is aSN is a Syndiotactic Syndiotactic New OlefinNew Olefin Elastomer Elastomer withwithCrystalline/Amorphous Structure Controlled inCrystalline/Amorphous Structure Controlled in NanoNano Order Order

50nm50nm

crystalline blockscrystalline blocksheat resistanceheat resistanceresistance to Scratch and Abrasionresistance to Scratch and Abrasion

NanoNano network of network of crystallinecrystalline / /amorphousamorphous segmentssegmentsTransparency, Solubility, Resistance to Scratch and AbrasionTransparency, Solubility, Resistance to Scratch and Abrasion

AFM ImageAFM Image

amorphous chainamorphous chainrubber elasticity/flexibilityrubber elasticity/flexibilityhigh melt tensionhigh melt tensionresistance to Scratch and Abrasionresistance to Scratch and Abrasion

TEMTEM ImageImage10001000 nmnm


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densitydensity / /

Light WeightLight Weight

NotioNotio

PVCPVCPUPU

00

500500

10001000

15001500

TransparencyTransparency

Heat ResistanceHeat Resistance / /Elasticity BalanceElasticity Balance

GoodGoodElasticityElasticityPermanent set after 150%Permanent set after 150% ExtesionExtesion (%)(%)

4040 3030 2020 1010 00

6060

100100

140140

2020

T M A

T M A

( ( ) )

180180

NotioNotio TMTM

C2 basedC2 based elastmer elastmer SEBSSEBS

GoodGood

H

e a

t R e s

i s t a n c e

H

e a

t R e s

i s t a n c e

FlexibilityFlexibility

PP /PP / NotioNotio TMTM = 80 / 20wt%= 80 / 20wt%

TEMTEM ImageImage

Compatibility with PPCompatibility with PP

1 m

FeatureFeature s of Notios of Notio TM TM - - SN(1)SN(1)1. What is Notio1. What is Notio TM TM - - SN? SN?


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AbrasionAbrasion ResistanceResistance

Amount of Amount of Weight LossWeight Loss

GoodGood

NotioNotio --00

2020

4040

6060

8080

100100

PVCPVC

Taber Abrasion Wear testingTaber Abrasion Wear testingWeel;Weel; HH--3838 Load;9.8N(1kg)Load;9.8N(1kg) 770rpm,0rpm, 11000cycles000cycles

Scratch ResistanceScratch Resistance

NotioNotio TMTM--SNSN

Ethylene basedEthylene basedelastomer elastomer

EthyleneEthylene vinylacetatevinylacetatecopolymer copolymer

Frictional wear testFrictional wear test JIS L 0849 compliant,JIS L 0849 compliant,Load=Load= 10001000 gf, reciprocating times=10(33times/min.),gf, reciprocating times=10(33times/min.),rubbed by cotton duckrubbed by cotton duck

PU coatedPU coatedOlefin Leather Olefin Leather


FeatureFeature s of Notios of Notio TM TM - - SN(2)SN(2)

NotioNotio TM TM - - SN has high abrasion resistance and scratchSN has high abrasion resistance and scratchresistance same as PU.resistance same as PU.


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2013.02.2013.02. 2525Physical properties of NotioPhysical properties of Notio TM TM - - SN SN

0mgmgWeight lossWeight lossAbrasion ResistanceAbrasion Resistance

3cmcmFalling Ball TestFalling Ball TestStressStress --AbsorbingAbsorbingPropertyProperty

8%%

ININ

--HazeHaze

Optical PropertyOptical Property

61%%@70@70 CC

25%%@23@23 CCCompression SetCompression Set

15%%Permanent SetPermanent Set34MPaMPa Young Modulus Young Modulus

>700%%Elongation of BreakElongation of Break

15MpaMpaTensile StrengthTensile Strength

Mechanical PropertiesMechanical Properties

116 CCSofteningSofteningTemperatureTemperatureThermal Property

Thermal Property84Shore A HardnessShore A Hardness

865Kg/m3Kg/m3DensityDensity

1.4g/10min.g/10min.@230@230 CCMFRMFR

Basic PropertiesBasic Properties

Notio TM

SN-0285UnitUnitConditionConditionItemItem


The above figures are just representative value, but not specification values.

Low Low - - MFR and High abrasion resistance is features of NotioMFR and High abrasion resistance is features of Notio TM TM - - SN.SN.


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NotioNotio TMTM--SN PelletSN Pellet

Formability of NotioFormability of Notio TM TM - - SN SN 1. What is Notio1. What is Notio TM TM - - SN? SN?

NotioNotio TM TM - - SN is supplied as pellets and can be formed by SN is supplied as pellets and can be formed by

extrusion or extrusion or calendering calendering process. process.


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Soft SheetsSoft Sheets

Car InteriorsCar Interiors StationeryStationery

BagBag ShoeShoe ss

Applications Applications1. What is Notio1. What is Notio TM TM - - SN? SN?


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Through this collaboration, HUNTING WORLDwanted to express strong will, as symbolized byRyo Ishikawas strong resolve and ardentpassion, as well as the attitude of doggedlypursuing a dream. The theme color is red acolor that Ryo Ishikawa also likes to wear canbe said to be the most appropriate color for representing this will. As for attitude, this hasbeen expressed using a single, straight line.The inner lining is a deep red base materialembossed with Ryo Ishikawas brand logo, aswell as an albatross and eagle motifs, two birdsthat are used as golf terms to indicate scores.The lineup includes five items: a messenger

bag, a tote bag, a small tote bag, a duffle bag,and a pouch. Everything from the design andstyle down to the smallest details has beendeveloped in collaboration with Ryo Ishikawa.

For the main material, these products useNOTIONOTIO SN leather SN leather , a new material thatbrings several Japanese technologies together.NOTIONOTIO SN leather SN leather is a revolutionary materialwith excellent heat resistance, wear resistance,and scratch resistance, but none of the harmfulsubstances that are often included in thematerials normally used for bag applications.But the best thing about this material is that it isextremely light. In fact, the material used inthese bags is 30% to 40% lighter than theplastics that are normally used, such as PVC(vinyl chloride).

http://www.honda.co.jp/FREEDSPIKE/

NotioNotioTMTM-- SN is usedSN is usedfor surface leather.for surface leather.

(1)Honda Freed Spike (2)Hunting world

http://www.itochu.co.jp/ja/news/2012/121114.html

Adaption examples Adaption examples


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--SNSN


ContentsContents


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melting & mixingmelting & mixing

CalenderingCalendering

LaminatingLaminating

CoolingCoolingwindingwinding

less than 35less than 35(sheet temperature)(sheet temperature)

115115 130130(sheet temperature)(sheet temperature)

160160 1818 55

(resin temperature)(resin temperature)

160160 1818 55(resin temperature)(resin temperature)

TemperatureTemperature

more than 10m/min.more than 10m/min.

Mixing timeMixing time ;;less than 30min.less than 30min.

Line speedLine speed

More than the softeningMore than the softeningtemperaturetemperature

Temperature should be set toTemperature should be set tomore than the melting pointmore than the melting pointof the polymer of the polymer

PointsPointsProcessProcess

Calendering Calendering conditionsconditions2. Adapting for 2. Adapting for calendering calendering of Notioof Notio TM TM - - SN SN


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2. Adapting for 2. Adapting for calendering calendering of Notioof Notio TM TM - - SN SN

Formulation examples for leather Formulation examples for leather

ShoreShore --A HardnessA Hardness 90906060

T a

b e r

A b r a s i o n

R e s

i s t a n c e

T a

b e r

A b r a s i o n

R e s

i s t a n c e

goodgood

NotioNotio TMTM--SN/PPSN/PP

NotioNotio TMTM--SN/PESN/PE

NotioNotio TMTM--SN/PP and/or SN/PP and/or

Tafmer Tafmer TMTM

--PN, ML, etcPN, ML, etc

NotioNotio TMTM--SN/EVA and/or SN/EVA and/or Tafmer Tafmer TMTM / /

Tafmer Tafmer TMTM--PN, ML, etcPN, ML, etc

NotioNotio TMTM--SN and/or SN and/or

Tafmer Tafmer TMTM

--PN, ML, etcPN, ML, etc

Car interiorsCar interiors

Bag/CaseBag/CaseUltrasonic Welder Ultrasonic Welder

Nonslip goodsNonslip goods

Shoes / FurnitureShoes / Furniture

Building MaterialsBuilding MaterialsFlexing ResistanceFlexing Resistance

Heat ResistanceHeat Resistance

Scent FreeScent Free

StationaryStationary

We recommend the Notio TM-SN base compound as your request spec.


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2. Adapting for 2. Adapting for calendering calendering of Notioof Notio TM TM - - SN SN

Ruck

Embossing

FoamingWorkability

Physical

property

Calendering

Flex resistance

(with filler)(with filler)(with filler)Flame resistance

CH-18SN-0285

(55)(55) (84)Flexibility (Shore-A)

Abrasion resistance

Notio TM-SNbase compound

Notio TM-SNItems

Formulation examples for leather Formulation examples for leather

CH-18 is the softest formulation which we have already developed.


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--SNSN


ContentsContents


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2013.02.2013.02. 2525Compared PVC leather Compared PVC leather to Notioto Notio TM TM - - SN leather SN leather

3. Features of 3. Features of NotioNotio - - SN leather SN leather

conditionitem

No changeNo changeCrackCrack-100,000times-10

206226NwrapTear strength

1238858Nweft

50,000times

50,000times

CS-10, 9.8N,60rpm, 1000times

445050mg23 Abrasion resistance

(weight loss)

0.50.5mmCloth

Flexion resistance

No changeNo change-23

1263788NwrapTensile Strength

170126Nweft

-10

Total 1.11.1mm

Thickness

-

unit

No changeNo change

Notio TM-SN leather LV leather Measurement

Especially, abrasion resistance and flexion resistanceEspecially, abrasion resistance and flexion resistancein low temperature of NotioTM in low temperature of NotioTM - - SN leather are better SN leather are better

than those of LV leather.than those of LV leather.

Cloth>Resin layer Cloth>Resin layer

(Depending on(Depending on

cloth properties)cloth properties)



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2013.02.2013.02. 2525Compared P Compared P U U leather leather to Notioto Notio TM TM - - SN leather SN leather

Pictures aftertesting

26 mg18 mgAmount of weight loss

PU leather NotioTM-SN leather

Taber Abrasion Wear testingTaber Abrasion Wear testing :H22, 1kg, 60rpm, 200times

PUPUPUPUPUPUPUPU leatherleatherleatherleatherleatherleatherleatherleather NotioNotioNotioNotioNotioNotioNotioNotioTMTMTMTMTMTMTMTM-------- SNSNSNSNSNSNSNSN leatherleatherleatherleatherleatherleatherleatherleather


Exposed clothExposed clothExposed clothExposed clothExposed clothExposed clothExposed clothExposed cloth


Abrasion resistance of Notio TM -SN leather is the same as PU.(PU leather has exposed cloth after test, but Notio TM -SN leather dont have it.)


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aromaticaromaticcompoundscompounds

halidehalide

solventsolventplasticizer plasticizer

useuse--freefree

--useusefreefree

useuse--freefree--useusefreefree

PU leather PU leather PVC leather PVC leather NotioNotio TMTM--SN leather SN leather

Environment safety Environment safety

NotioNotio TM TM - - SN leather doesSN leather does NOT NOT include plasticizers, phthalate, halide, and include plasticizers, phthalate, halide, and styrene, and it is lower environmental load than PVC and PU leat styrene, and it is lower environmental load than PVC and PU leat her her ..



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NGNGNGNGgoodgoodWater Water

(100degreeC,(100degreeC,

5min.)5min.)

NGNGNGNGgoodgoodalkalinealkalineaqueous sol.aqueous sol.

NGNGNGNGgoodgoodacidacidaqueous sol.aqueous sol.

NGNGNGNGgoodgoodNaphthaleneNaphthalene(Mothball)(Mothball)

PU leather PU leather PVC leather PVC leather NotioNotio TMTM--SN leather SN leather

Durability ; hydrolysis, SolventsDurability ; hydrolysis, Solvents3. Features of 3. Features of NotioNotio - - SN leather SN leather

NotioNotio TM TM - - SN leather is stable against hydrolysis and Solvents.SN leather is stable against hydrolysis and Solvents.


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**test conditiontest condition JIS ZJIS Z 29112911 --20102010appendix1 test of plasticappendix1 test of plastic methodmethod Durability ; FungusDurability ; Fungus

PVCPVCNotioNotio TMTM--SNSN

Judgment0 ;The growth of mold is not visible under the naked eye and the microscope either.1;The growth of mold is not visible under the naked eye, but visible under the microscope.2; The growth of mold is not visible under the naked eye, the area of the growth part is less than 25%

of the overall product of the sample.3; The growth of mold is not visible under the naked eye, The area of the growth part is less than 50%

of the overall product of the sample.4; The bacterial thread often grows. The area of the growth part is 50% or more of the overall product of the sample.5 ; The growth of the bacterial thread intensely covers the front side of the sample.

PUPU

Result: 1Result: 1 Result: 3Result: 3 Result: 4Result: 4


NotioNotio TM TM - - SN has strong Fungus Resistance.SN has strong Fungus Resistance.


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**test conditiontest condition JIS ZJIS Z 29112911 --20102010appendix1 test of plasticappendix1 test of plastic methodmethod Cold resistanceCold resistance


DroppingDroppingDroppingDroppingDroppingDroppingDroppingDropping

-------- 3030303030303030

Cold resistance testCold resistance testCold resistance testCold resistance testCold resistance testCold resistance testCold resistance testCold resistance testJIS K 6772JIS K 6772JIS K 6772JIS K 6772JIS K 6772JIS K 6772JIS K 6772JIS K 6772

PVCPVCPVCPVCPVCPVCPVCPVC

NotioNotioNotioNotioNotioNotioNotioNotioTMTMTMTMTMTMTMTM-------- SN leatherSN leatherSN leatherSN leatherSN leatherSN leatherSN leatherSN leather

NotioNotio TM TM - - SN leather is superior to PVC leather in Cold resistance,SN leather is superior to PVC leather in Cold resistance,

and it is not broken at and it is not broken at - - 30 30 ..

notio sn presentation.pdf

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