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$ Respomible Ref: - E-n-v-1rclnlental Clearance #J.1 0ZJA_ll_dated_ 17.07.2003 Kindly refer altove Environmental Clearance #J.1101117712002_lA.ll dated 1,7.07.2003 to our Unit#1 locatedat Plot no 11711.18, GIDC Estate, Ankleshw.r:SggOOZl'D,;;: Bharuch, Gujarat. i \n/e are sending herewith Lhe compliance report along with various other required informationwith respect to our unit *1 foiyour kind reference and records.The details given are with respect to the periodlanio Jun2012. we hope. that the above is in order. In case you neecl anv additional information, we can provide the same on hearinq from vou. _:oft c.oly 4'tvufo,t it alto favtilAr'r"Cl . Thanking you Yours faithfufy For,United {h\sphgzus Ltd \_i..\( Ut\NV DR P N PARAM"ESWAMN Vice President -Environment United PhosPhorus Limited 117,G.|.D.C., Ankleshwar - 393 002' Guiarat'(lndia) Ph. (02646) 250336, 251223' 251249' 250279 Fax (02646) 250297 Ref: U1/EC-2011112 lL August,2OI2 Unit PIot # 117 I l1B,GIDC, Ankleshwar _ 393 Dr. A Mehrotra, Director (S) Ministry of Environment andForests Western Region Office Kendriya Parvavaran Bhavan Link Road # 3, E - 5, Ravi Shankar Naoar Bhopal - 462 016 (M.p) Dear Sir; S ub: - C o mp Lta r r _e e 1q_eonditian s of E nviro nme nta l_G j ea ranc e e I s s 5 s s s s s s 5 5 S 5 b- 5 s 5 s 5 5 D D !- D D - - Care" #i 00: - ,-rr','tldi f :::". .-.*t B'rrril ?d!ul"t',.li*,.rr ' , .l/' 'e+ono'.{ltoot Encl : a/a \\0' Mumbal Office:'UNIPHOS" House, C. D. Marg, 11th Road, Khar (W)' Mumbai. Phone: (022) 26040464,26041111' Fax: (022)26040467 s S S s ?

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Page 1: NV - upl-ltd.com

$Respomible

Ref: - E-n-v-1rclnlental Clearance #J.1 0ZJA_ll_dated_ 17.07.2003

Kindly refer altove Environmental Clearance #J.1101117712002_lA.ll dated 1,7.07.2003to our Uni t#1 located at Plot no 11711.18, GIDC Estate, Ankleshw.r:SggOOZl 'D,; ; :Bharuch, Gujarat .

i

\n/e are sending herewith Lhe compliance report along with various other requiredinformation with respect to our unit *1 foiyour kind reference and records. Thedetails given are with respect to the periodlanio Jun2012.

we hope. that the above is in order. In case you neecl anv additional information, wecan provide the same on hearinq from vou._:oft

c.oly 4'tvufo,t it alto favtilAr'r"Cl .Thanking you

Yours faithfufyFor, United {h\sphgzus Ltd\_i..\(

Ut\NVDR P N PARAM"ESWAMNVice President -Environment

United PhosPhorus Limited117, G.|.D.C., Ankleshwar - 393 002' Guiarat' (lndia)

Ph. (02646) 250336, 251223' 251249' 250279 Fax (02646) 250297

Ref: U1/EC-2011112lL August,2OI2

UnitPIot # 117 I l1B, GIDC, Ankleshwar _ 393

Dr. A Mehrotra, Director (S)Ministry of Environment and ForestsWestern Region OfficeKendriya Parvavaran BhavanLink Road # 3, E - 5, Ravi Shankar NaoarBhopal - 462 016 (M.p)

Dear S i r ;

S u b : - C o mp Lta r r _e e 1q_eonditian s of E nviro nme n ta l_G j ea ranc e

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Mumbal Office:'UNIPHOS" House, C. D. Marg, 11th Road, Khar (W)' Mumbai.Phone: (022) 26040464,26041111' Fax: (022) 26040467

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Page 2: NV - upl-ltd.com

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Copy l.o: The Zonal OfficerCentral Pol lut ion Control BoardParivesh Bhavan

Opp VMC ward Office_I0Subhanpura, Baroda_39002 3

: Mr..l D Kaiyani - Regional OfficerGujarat Pollution Control BoardPio t No1 501, GIDC,Ank leshwar -393002

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Page 3: NV - upl-ltd.com

UNITED PHOSPHORUS LIMITED; UNIT # 1 Plot # 117/118; G.I.D.C Estate; Ankleshwar

ENVIRONMENTAL CLEARNACE CONDITIONS COMPLIANCE REPORT JAN-JUN 2012

Page 4: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 2 of 73

Condition Compliance Status

No Description

Condition Compliance

* The Environmental Clearance is issued for

the following products

Penoxaline @ 150 MT / Month

Cartap @ 50 MT / Month

Metabromuron @ 50 MT / Month

Phosphamidon @ 150 MT / Month

Dichlorovos @ 200 MT / Month; and

Antracol / Mancozeb @ 500 / 800

MT / Month

Environmental Clearance also contains the

following by-products

Hydrated Sodium Sulphate @ 737

MT / Month

Sodium Sulphite Solution @ 298 MT

/ Month

Sodium Bromide Solution @ 95 MT /

Month

Sodium Sulphite Solids @ 31 MT /

Month

Liquefied Methyl Chloride @ 131

MT / Month; and

30 % HCL @ 138 MT / Month

Complied.

Production details are attached for the period of Jan-Jun 2011.

We have Obtained Consent to Establish (NOC) for Product Mix Change

(No. GPCB/BRCH-CCA-158(7)/ ID-15833/106214) in March 2012 and

applied for consent to operate (CC&A) on 17/03/2012. The Details for

the same are provided in Annexure-1

* The land area of the project is 1,36,777 m2. Project does not involve forest land and displacement of people. Water

requirement is 951.1 kl / day. Solid waste in the form of ETP Sludge (30 MT / Month); Incinerator Ash (4.5 MT /

Month) and Inorganic Solids from Monocrotophos Plant (75.6 MT / Month); Solid Salts (82 MT / Month); and Salt from

RO System will be disposed off in the secured landfill facility. NOC from GPCB was obtained on 29.06.2002. Public

Hearing was held on 16.01.2002

* MOEF accords Environmental Clearance to the project under provisions of EIA Notification dated 27.01.1994 as

amended subsequently subject to compliance of various special and general conditions

** We have Obtained Consent to Establish (NOC) for Product Mix Change (No. GPCB/BRCH-CCA-158(7)/ ID-

15833/106214) in March 2012. The Details for the same are provided in Annexure-1

Page 5: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 3 of 73

No Description Status

A SPECIFIC CONDITIONS

1 Gaseous emissions (SO2, NOX, HCl, HC

and Cl2) and PM from various process units should conform to standards

prescribed by authorities. At no time, emissions to go beyond standards.

During failure of pollution control systems, unit should not be restarted

until measures are rectified to achieve

the efficiency

Complied.

Monitoring done internally and through external agency.

Reports are attached herewith for the period of Jan-Jun 2012

All parameters are within permissible limit. We have also started monitoring PM2.5 parameter for ambient air as per new standards

Flue Gas Stacks Emissions

Parameter Range

SO2 10 -18 mg/nm3

Stack attached to Boilers

NOX 9 – 11 mg/nm3

Stack attached to Boilers

Process Stack Emissions

Parameter Range

HCl 1.8 – 3.1 mg/m3 (PCl3 Plant Stack attached to storage tank)

Cl2 0.5 –1.7 mg/m3 (In PCl3 Plant Stack attached to Storage Tank

SPM 57 - 78 mg/nm3 (SPD of CaCl2 Plant)

NH3 8.4 – 18.3 mg/nm3 (In TMP Plant Stack attached to scrubber)

PM 11.3 mg/nm3 (from Antracol Plant Bag Filter)

Page 6: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 4 of 73

2 Fugitive emissions in workplace

environment, product, raw material storage areas must be monitored. Flue

gas emissions should conform to standards prescribed by GPCB

Complied.

Emission monitoring at various locations are being carried out by our QA Department.

We are also measuring & keeping a check on the level of CS2, Cl2 & NH3 for ambient conditions around the premises.

3 Process emissions (SPM, HCl, SO2, Methyl Chloride and VOC) should be

scrubbed through caustic ventury

scrubber and conform to standards. Efficiency of scrubber to be improved

and maintained as per best practicable technology. VOC data to be monitored

and submitted to MOEF. Additional ventury scrubber for Mancozeb,

Penoxaline, Phosphamidon plant and a

scrubber for Cartap plant to be installed in addition to process scrubbers already

installed in the unit

Complied.

Air pollution control systems are provided.

VOC Monitoring is done through M/S Bharuch Enviro Infrastructure

Ltd.

The monitoring data is attached herewith.

Page 7: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 5 of 73

Condition Compliance Status No Description

4 As reflected in EIA / EMP Report, effluent generation should not exceed

195 m3 / day. The waste streams to be segregated into high and low pollution

load streams. Effluent with high organic load to be incinerated and dilute streams

like from R & D, washing, domestic,

dilute streams from process and scrubber blow down, to be given primary,

secondary and tertiary treatment before discharging into GIDC drain. Treated

effluent to conform to standards. Non toxic effluent to be diverted to RO plant

and re cycled to minimize fresh water

consumption

Complied.

Treated effluent is discharged to GIDC drain to final Effluent treatment

plant, NCTL, Ankleshwar for further treatment & disposal to deep sea. Details of quantity discharged are attached herewith.

The permeate from RO System is taken to cooling tower water make up.

5 Waste stream should be treated before

taking into solar evaporation pond. Solvent from effluent to be recovered

before discharging into solar evaporation

pond. As reflected in EIA / EMP Report, Company to install forced

evaporation system for aqueous waste to avoid discharge of effluent into solar

evaporation pond

Complied.

Company has discontinued Solar Evaporation ponds.

Forced Evaporation System is in operation. Details are attached for the

period Jan-Jun 2012

6 Company to recover Methyl Chloride (CH3CL) by installation of CH3CL

recovery plant. Solvent recovery to be improved and attempts to be made to

achieve at least 90 % recovery wherever

possible. Rest solvent which can’t be recovered, to be incineration. Action to

be submitted to Ministry within 3 months

Complied.

Methyl Chloride Plant is in operation.

We have EDC solvent in Monocrotophos & having recovery of @ 97%

Page 8: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 6 of 73

No Condition Compliance Status

Description

7 Company to up grade existing incinerator for incineration of hazardous

waste. Organic waste, solid waste generated, to be collected and

incinerated for total destruction. As reflected in EIA / EMP Report, solid

waste and ash obtained after incinerator

should be stored in plant premises in a pit with impervious flooring and

leachate collection system. Ash and sludge from ETP to be finally disposed

off in a TSDF of BEIL. Leachate to be sent to ETP for treatment

Complied.

Company has discontinued operation of Incinerator.

Company has taken membership of Common Incinerator at BEIL, Ankleshwar.

Details of incinerable waste send to BEIL, Ankleshwar is attached for

the period Jan-Jun 2012

8 Destruction efficiency of incinerator to be assessed by agency like CPCB and

reported. Company to monitor VOCs

and data submitted t MOEF / CPCB / GPCB regularly

Not Applicable.

Company has discontinued operation of Incinerator. Company has

membership of common facility BEIL, Ankleshwar.

9 As per CREP, bio assay test to be

replaced by Toxicity Factor Test Method developed by CPCB. TF=4 to

be achieved by December 2003 and

TF=2 by July 2006. Action plan to be submitted within 3 months

Complied.

TF factor monitoring results are attached for the period of Jan-Jun 2012

10 Green belt in 0.2 hectors in addition to 3.66 hector to be provided to mitigate

the effect of fugitive emissions in the

plant. Development of green belt along the boundary wall, open space and

avenue roads to be improved in consultation with local DFO as per

CPCB guidelines

Complied.

Green belt area provided approx. 0.5 hector in addition to existing

Green belt area 3.66 hector. This is an on going activity.

During period Jan-Jun 2012 trees planted @ 150 Nos

11 Company to adopt waste minimization / cleaner production techniques to

reduce pollution load and action plan to be submitted to Ministry within 3

months

Complied.

Page 9: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 7 of 73

No Condition Compliance Status

Description

12 Company to undertake rain water harvesting measures as per action plan

submitted to Ministry

Complied.

Rain water harvesting area = 3070 m2

Rain water is being used in cooling tower.

13 Company to comply with Environmental Protection measures and

safeguards recommended in EIA / EMA / RRA reports as well as

recommendations of Public Hearing panel

Complied.

B GENERAL CONDITIONS

1 Company to adhere to stipulations made by GPCB

Complied.

2 No further expansion / modifications in the plant to be carried out without prior

approval of MOEF. In case of deviations / alterations in the project

proposals from those submitted, a fresh reference to be made to Ministry to

assess adequacy of conditions imposed

and add additional environmental protection measures required, if any

Complied

We have Obtained Consent to Establish (NOC) for Product Mix Change

(No. GPCB/BRCH-CCA-158(7)/ ID-15833/106214) in March 2012 and

applied for Consent to operate (CC&A). The Details for the same are

provided in Annexure-1

3 Company to comply with MSIHC Rules 2000. Prior approvals of Chief Inspector

of Factories, Chief Inspector of

Explosives, Fire Safety Inspectorate etc, to be obtained

Complied.

4 Company to comply with HWM Rules

and authorization from GPCB to be obtained

Complied

Company have Consent & Authorization CC&A #31505 dated

05/06/2010 valid up to 16.06.2013

Page 10: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 8 of 73

No. Condition Compliance Status

Description

5 Overall noise levels in and around plant area to be kept within the standards (85

dBA) by providing noise control measures including acoustic hoods,

silencers, enclosures etc, on all sources of noise generation. Ambient noise

levels to conform to standards i.e. 75

dBA (day time) and 70 dBA (night time)

Complied.

Noise level monitoring results at different location around Plants area

are attached.

Range

Daytime (Limit: 75 dBA): 57.5 ---- 70.1

Nighttime (Limit: 70 dBA) : 38.7 ---69.2

6 Occupational health surveillance

program to be undertaken as regular exercise for all employees, specifically

for those engaged in handling hazardous

substances. First aid facilities in OHC to be strengthened and medical records of

each employees to be maintained

Regular medical check up of each employee has been conducted.

Premedical employment medical check up was done for 10 new joinees

for the period of Jan-Jun 2012

7 A separate Environment Management Cell with full fledged laboratory to be set

up to carry out the environmental management and monitoring functions

Complied.

Water, Stack Monitoring, Bio Assay Test, Tf Factor Test, Ambient Air

Monitoring, voc monitoring, Solid Waste Analysis, Noise Level Monitoring are carried out. Also, Environmental Audit is being carried

out regularly.

8 Company to provide adequate funds for

recurring and non-recurring expenses to implement the conditions stipulated by

MOEF as well as state government along with implementation schedule for

all conditions stipulated. The funds should not be diverted for any other

purposes

Complied.

The funds are already provided as part of manufacturing activities and operation of ETP, incineration of waste etc. Separate cost codes are

also available.

9 Implementation of the project and Environmental Action Plan to be

monitored by MOEF, Regional Office at Bhopal, GPCB / CPCB. A six monthly

compliance report to be submitted to

monitoring agencies

Complied.

Half yearly reports are being sent during first week of February and

August every year to Ministry of Environment and Forests Regional Office, Western Region, Bhopal.

Page 11: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 9 of 73

10 Company to inform that public that

project has been accorded Environmental Clearance by Ministry

and copies are available with GPCB and may be seen at MOEF’s web site. This

should be advertised within 7 days in

two local news papers and copies to be submitted to RO

Complied.

Published in Gujarati and English news papers; and copies submitted to GPCB and MOEF

11 Company to inform RO as well as Ministry, date of financial closure and

final approval of the project by

concerned authorities and date of commencing the land development

work, if any

Complied.

- Ministry may revoke or suspend the

clearance, if implementation of any of

the conditions is not satisfactory

Noted

- Ministry reserves the right to stipulate

additional conditions if required. Company, in a time bound manner, will

implement the same

Noted

- The above conditions will be enforced inter-alia under provisions of various

acts and rules

Noted

Page 12: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 10 of 73

STACK MONITORING REPORT

(INTERNAL LAB ANALYSIS REPORT)

Page 13: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 11 of 73

STACK MONITORING REPORT

MONTH: JAN 2012

PESTICIDES AND PESTICIDE INTERMEDIATES PLANT :

Sr. AREA IDENTIFICATION DATE OF HCL CHLORINE NH3 NOX SPM SO2

No. (STACK) SAMPLING

20

mg/Nm3 5 mg/Nm3

30

mg/Nm3

50

mg/Nm3

20

mg/Nm3

100

mg/Nm3

TMP PLANT VENT OF 10.01.12 ------ BDL 6.30 ------ ------ ------

1 SCRUBBER ATTACHED

TO R-901 AND R-902 23.01.12 ------ BDL 8.10 ------ ------ ------

MANCOZEB

PLANT(OLD) 01.01.12 TO 31.01.12 ------ ------ ------ ------ ------ ------

2 WET SCRUBBER SPRAY Not in operation

DRIER ------ ------ ------ ------ ------ ------

MANCOZEB

PLANT(NEW) 01.01.12 TO 31.01.12 ------ ------ ------ ------ ------ ------

3 SPD WET SCRUBBER Not in operation

OUTLET ------ ------ ------ ------ ------ ------

SPRAY DRIER SYSTEM 08.01.12 ------ ------ ------ ------ 15.00 ------

4 OF ANTRACOL PLANT

22.01.12 ------ ------ ------ ------ 17.00 ------

OTHER CHEMICAL PLANT :

Sr. AREA IDENTIFICATION DATE OF HCL CHLORINE NH3 NOX SPM SO2

No. (STACK) SAMPLING 20 mg/m3 9 mg/m3

175

mg/m3

50

mg/Nm3

150

mg/m3

100

mg/Nm3

IN PCL3 PLANT STACK 10.01.12 1.50 0.70 ------ ------ ------ ------

5 ATTACHED TO

STORAGE SCRUBBER 23.01.12 1.80 0.50 ------ ------ ------ ------

Page 14: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 12 of 73

SPRAY DRIER SYSTEM 01.01.12 TO 14.01.12 ------ ------ ------ ------ ------ ------

6 OF CACL2 PLANT Not in operation

26.01.12 ------ ------ ------ ------ 62.00 ------

STACK ATTACHED TO

7 BOILER B5 GT-3138 13.01.12 ------ ------ ------ 10.00 22.00 17.00

8 BOILER B6 GT-3476 22.01.12 ------ ------ ------ 11.00 24.00 13.00

9 BOILER B7 GT-3515 10.01.12 ------ ------ ------ 9.00 28.00 15.00

ALL THE PARAMETERS ARE WITHIN THE LIMITS

(Analyzed by)

Sr.Executive –QA

(Approved by )

HOD -QA

Page 15: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 13 of 73

STACK MONITORING REPORT

MONTH: FEB 2012

PESTICIDES AND PESTICIDE INTERMEDIATES PLANT :

Sr. AREA IDENTIFICATION DATE OF HCL CHLORINE NH3 NOX SPM SO2

No. (STACK) SAMPLING

20

mg/Nm3 5 mg/Nm3

30

mg/Nm3

50

mg/Nm3

20

mg/Nm3

100

mg/Nm3

TMP PLANT VENT OF 09.02.12 ------ BDL 4.30 ------ ------ ------

1 SCRUBBER ATTACHED

TO R-901 AND R-902 20.02.12 ------ BDL 7.20 ------ ------ ------

MANCOZEB PLANT(OLD) 01.02.12 TO 29.02.12 ------ ------ ------ ------ ------ ------

2 WET SCRUBBER SPRAY Not in operation

DRIER ------ ------ ------ ------ ------ ------

MANCOZEB

PLANT(NEW) 01.02.12 TO 29.02.12 ------ ------ ------ ------ ------ ------

3 SPD WET SCRUBBER Not in operation

OUTLET ------ ------ ------ ------ ------ ------

SPRAY DRIER SYSTEM 01.02.12 TO 29.02.12 ------ ------ ------ ------ ------ ------

4 OF ANTRACOL PLANT Not in operation

------ ------ ------ ------ ------ ------

OTHER CHEMICAL PLANT :

Sr. AREA IDENTIFICATION DATE OF HCL CHLORINE NH3 NOX SPM SO2

No. (STACK) SAMPLING 20 mg/m3 9 mg/m3 175 mg/m3

50

mg/Nm3 150 mg/m3

100

mg/Nm3

IN PCL3 PLANT STACK 09.02.12 1.90 1.10 ------ ------ ------ ------

5 ATTACHED TO

STORAGE SCRUBBER 20.02.12 2.30 0.70 ------ ------ ------ ------

Page 16: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 14 of 73

SPRAY DRIER SYSTEM 10.02.12 ------ ------ ------ ------ 73.00 ------

6 OF CACL2 PLANT

21.02.12 ------ ------ ------ ------ 59.00 ------

STACK ATTACHED TO

7 BOILER B5 GT-3138 01.02.12 TO 29.02.12 ------ ------ ------ ------ ------ ------

Not in operation

8 BOILER B6 GT-3476 16.02.12 ------ ------ ------ 9.00 28.00 11.00

9 BOILER B7 GT-3515 18.02.12 ------ ------ ------ 7.00 22.00 14.00

ALL THE PARAMETERS ARE WITHIN THE LIMITS

(Analyzed by)

Sr.Executive –QA

(Approved by )

HOD -QA

STACK MONITORING REPORT

Page 17: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 15 of 73

MONTH: MARCH 2012

PESTICIDES AND PESTICIDE INTERMEDIATES PLANT :

Sr. AREA IDENTIFICATION DATE OF HCL CHLORINE NH3 NOX SPM SO2

No. (STACK) SAMPLING 20 mg/Nm3 5 mg/Nm3 30 mg/Nm3 50 mg/Nm3 20 mg/Nm3 100 mg/Nm3

TMP PLANT VENT OF 11.03.12 ------ BDL 9.60 ------ ------ ------

1 SCRUBBER ATTACHED

TO R-901 AND R-902 23.03.12 ------ BDL 12.80 ------ ------ ------

MANCOZEB PLANT(OLD) 01.03.12 TO 31.03.12 ------ ------ ------ ------ ------ ------

2 WET SCRUBBER SPRAY Not in operation

DRIER ------ ------ ------ ------ ------ ------

MANCOZEB PLANT(NEW) 01.03.12 TO 31.03.12 ------ ------ ------ ------ ------ ------

3 SPD WET SCRUBBER Not in operation

OUTLET ------ ------ ------ ------ ------ ------

SPRAY DRIER SYSTEM 17.03.12 ------ ------ ------ ------ 14.00 ------

4 OF ANTRACOL PLANT

20.03.12 ------ ------ ------ ------ 17.00 ------

OTHER CHEMICAL PLANT :

Sr. AREA IDENTIFICATION DATE OF HCL CHLORINE NH3 NOX SPM SO2

No. (STACK) SAMPLING 20 mg/m3 9 mg/m3 175 mg/m3 50 mg/Nm3 150 mg/m3 100 mg/Nm3

IN PCL3 PLANT STACK 11.03.12 2.90 0.80 ------ ------ ------ ------

5 ATTACHED TO

STORAGE SCRUBBER 23.03.12 2.20 1.10 ------ ------ ------ ------

SPRAY DRIER SYSTEM 12.03.12 ------ ------ ------ ------ 57.00 ------

6 OF CACL2 PLANT

Page 18: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 16 of 73

24.03.12 ------ ------ ------ ------ 64.00 ------

STACK ATTACHED TO

7 BOILER B5 GT-3138 06.03.12 ------ ------ ------ 8.00 18.00 14.00

8 BOILER B6 GT-3476 23.03.12 ------ ------ ------ 10.00 22.00 18.00

9 BOILER B7 GT-3515 23.03.12 ------ ------ ------ 8.00 26.00 15.00

ALL THE PARAMETERS ARE WITHIN THE LIMITS

(Analyzed by)

Sr.Executive –QA

(Approved by )

HOD -QA

STACK MONITORING REPORT

Page 19: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 17 of 73

MONTH: APRIL 2012

PESTICIDES AND PESTICIDE INTERMEDIATES PLANT :

Sr. AREA IDENTIFICATION DATE OF HCL CHLORINE NH3 NOX SPM SO2

No. (STACK) SAMPLING 20 mg/Nm3 5 mg/Nm3 30 mg/Nm3 50 mg/Nm3 20 mg/Nm3 100 mg/Nm3

TMP PLANT VENT OF 08.04.12 ------ BDL 7.30 ------ ------ ------

1 SCRUBBER ATTACHED

TO R-901 AND R-902 24.04.12 ------ BDL 15.60 ------ ------ ------

MANCOZEB

PLANT(OLD) 13.04.12 ------ ------ ------ ------ 19.00 ------

2 WET SCRUBBER SPRAY

DRIER (Mojj) 27.04.12 ------ ------ ------ ------ 18.00 ------

MANCOZEB

PLANT(NEW) 01.04.12 TO 30.04.12 ------ ------ ------ ------ ------ ------

3 SPD WET SCRUBBER Not in operation

OUTLET ( L&T) ------ ------ ------ ------ ------ ------

SPRAY DRIER SYSTEM 01.04.12 TO 30.04.12 ------ ------ ------ ------ ------ ------

4 OF ANTRACOL PLANT Not in operation

------ ------ ------ ------ ------ ------

OTHER CHEMICAL PLANT :

Sr. AREA IDENTIFICATION DATE OF HCL CHLORINE NH3 NOX SPM SO2

No. (STACK) SAMPLING 20 mg/m3 9 mg/m3 175 mg/m3 50 mg/Nm3 150 mg/m3 100 mg/Nm3

IN PCL3 PLANT STACK 08.04.12 2.10 1.30 ------ ------ ------ ------

5 ATTACHED TO

STORAGE SCRUBBER 24.04.12 1.80 1.70 ------ ------ ------ ------

SPRAY DRIER SYSTEM 12.04.12 ------ ------ ------ ------ 61.00 ------

Page 20: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 18 of 73

6 OF CACL2 PLANT

27.04.12 ------ ------ ------ ------ 73.00 ------

STACK ATTACHED TO

7 BOILER B5 GT-3138 06.04.12 ------ ------ ------ 6.00 15.00 12.00

8 BOILER B6 GT-3476 16.04.12 ------ ------ ------ 8.00 20.00 14.00

9 BOILER B7 GT-3515 16.04.12 ------ ------ ------ 9.00 22.00 15.00

ALL THE PARAMETERS ARE WITHIN THE LIMITS

(Analyzed by)

Sr.Executive –QA

(Approved by )

HOD -QA

Page 21: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 19 of 73

STACK MONITORING REPORT

MONTH: MAY 2012

PESTICIDES AND PESTICIDE INTERMEDIATES PLANT :

Sr. AREA IDENTIFICATION DATE OF HCL CHLORINE NH3 NOX SPM SO2

No. (STACK) SAMPLING 20 mg/Nm3 5 mg/Nm3 30 mg/Nm3 50 mg/Nm3 20 mg/Nm3 100 mg/Nm3

TMP PLANT VENT OF 09.05.12 ------ BDL 12.30 ------ ------ ------

1 SCRUBBER ATTACHED

TO R-901 AND R-902 23.05.12 ------ BDL 9.80 ------ ------ ------

MANCOZEB PLANT(OLD) 02.05.12 TO 18.05.12 ------ ------ ------ ------ 15.00 ------

2 WET SCRUBBER SPRAY Not in operation

DRIER (Mojj) 24.05.12 ------ ------ ------ ------ 17.00 ------

MANCOZEB PLANT(NEW) 01.05.12 TO 31.05.12 ------ ------ ------ ------ ------ ------

3 SPD WET SCRUBBER Not in operation

OUTLET ( L&T) ------ ------ ------ ------ ------ ------

SPRAY DRIER SYSTEM 01.05.12 TO 21.05.12 ------ ------ ------ ------ ------ ------

4 OF ANTRACOL PLANT Not in operation

26.05.12 ------ ------ ------ ------ 17.00 ------

OTHER CHEMICAL PLANT :

Sr. AREA IDENTIFICATION DATE OF HCL CHLORINE NH3 NOX SPM SO2

No. (STACK) SAMPLING 20 mg/m3 9 mg/m3 175 mg/m3 50 mg/Nm3 150 mg/m3 100 mg/Nm3

IN PCL3 PLANT STACK 09.05.12 2.80 1.60 ------ ------ ------ ------

5 ATTACHED TO

Page 22: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 20 of 73

STORAGE SCRUBBER 23.05.12 2.30 1.20 ------ ------ ------ ------

SPRAY DRIER SYSTEM 11.05.12 ------ ------ ------ ------ 78.00 ------

6 OF CACL2 PLANT

20.05.12 ------ ------ ------ ------ 63.00 ------

STACK ATTACHED TO

7 BOILER B5 GT-3138 10.05.12 ------ ------ ------ 7.00 17.00 10.00

8 BOILER B6 GT-3476 24.05.12 ------ ------ ------ 8.00 24.00 14.00

9 BOILER B7 GT-3515 24.05.12 ------ ------ ------ 10.00 21.00 16.00

ALL THE PARAMETERS ARE WITHIN THE LIMITS

(Analyzed by)

Sr.Executive –QA

(Approved by )

HOD -QA

Page 23: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 21 of 73

STACK MONITORING REPORT

MONTH: JUNE 2012

PESTICIDES AND PESTICIDE INTERMEDIATES PLANT :

Sr. AREA IDENTIFICATION DATE OF HCL CHLORINE NH3 NOX SPM SO2

No. (STACK) SAMPLING 20 mg/Nm3 5 mg/Nm3 30 mg/Nm3 50 mg/Nm3 20 mg/Nm3 100 mg/Nm3

TMP PLANT VENT OF 08.06.12 ------ BDL 18.40 ------ ------ ------

1 SCRUBBER ATTACHED

TO R-901 AND R-902 23.06.12 ------ BDL 14.20 ------ ------ ------

MANCOZEB PLANT(New) 11.06.12 ------ ------ ------ ------ 18.00 ------

2 WET SCRUBBER SPRAY

DRIER (Mojj) 12.06.12 TO 30.06.12 ------ ------ ------ ------ ------ ------

Not in operation

MANCOZEB PLANT(Old) ------ ------ ------ ------ ------ ------

3 SPD WET SCRUBBER Not in operation

OUTLET ( L&T) ------ ------ ------ ------ ------ ------

SPRAY DRIER SYSTEM 10.06.12 ------ ------ ------ ------ 15.00 ------

4 OF ANTRACOL PLANT

25.06.12 ------ ------ ------ ------ 17.00 ------

OTHER CHEMICAL PLANT :

Sr. AREA IDENTIFICATION DATE OF HCL CHLORINE NH3 NOX SPM SO2

No. (STACK) SAMPLING 20 mg/m3 9 mg/m3 175 mg/m3 50 mg/Nm3 150 mg/m3 100 mg/Nm3

IN PCL3 PLANT STACK 08.06.12 3.10 0.80 ------ ------ ------ ------

5 ATTACHED TO

STORAGE SCRUBBER 23.06.12 2.60 1.20 ------ ------ ------ ------

Page 24: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 22 of 73

SPRAY DRIER SYSTEM 09.06.12 ------ ------ ------ ------ 65.00 ------

6 OF CACL2 PLANT

23.06.12 ------ ------ ------ ------ 78.00 ------

STACK ATTACHED TO

7 BOILER B5 GT-3138 11.06.12 ------ ------ ------ 9.00 17.00 13.00

8 BOILER B6 GT-3476 22.06.12 ------ ------ ------ 11.00 21.00 17.00

9 BOILER B7 GT-3515 22.06.12 ------ ------ ------ 9.00 24.00 15.00

ALL THE PARAMETERS ARE WITHIN THE LIMITS

(Analyzed by)

Sr.Executive –QA

(Approved by )

HOD -QA

Page 25: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 23 of 73

STACK MONITORING REPORT

(MAHABAL ENVIROENGINEERS ANALYSIS REPORT)

Page 26: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 24 of 73

STACK MONITORING REPORT: (By MAHABAL ENVIRO ENGINEERS LIMITED)

MONTH: JANUARY 2012

PESTICIDES AND PESTICIDES INTERMEDIATES PLANT:

Sr. AREA IDENTIFICATION DATE OF HCL CHLORINE NH3 NOx SPM SO2

No. (STACK) SAMPLING 20 mg/m3 5 mg/m3 30 mg/m3 50

mg/m3 20 mg/m3 100

mg/m3

TMP PLANT VENT OF

1 SCRUBBER ATTACHED 10.01.2012 …. ….. …. …. …. ….

TO R-901 AND R-902

MANCOZEB PLANT(OLD) …. ….. …. …. …. ….

2 WET SCRUBBER SPRAY 10.01.2012

DRIER …. ….. …. …. …. ….

MANCOZEB PLANT(NEW)

3 SPD WET SCRUBBER 10.01.2012 …. ….. …. …. …. ….

OUTLET

ANTRACOLPLANT (BAG FILTER) …. ….. …. …. …. ….

4 10.01.2012

ANTRACOL PLANT (HOT AIR GENERATOR)

OTHER CHEMICAL PLANT

Sr. AREA IDENTIFICATION DATE OF PCL3 CHLORINE NH3 NOX SPM SO2

No. (STACK) SAMPLING 09 mg/m3 9 mg/m3 175 mg/m3 50 PPM 150 mg/m3 100 PPM

STACK ATTACHED TO

BOILER B5 GT-3138 10.01.2012 ---- ------ ----- ----- ----- -----

5

BOILER B6 GT-3476 10.012012 …. …… ….. …… …… …..

BOILER B7 GT-3515 10.01.2012 …. ….. …… 12.8 BDL BDL

SPRAY DRIER SYSTEM OF CACL2 PLANT

…. …. …. …. …. …. 6 10.01.2012

IN PCL3 PLANT STACK ATTACHED TO STORAGE SCRUBBER

7 10.01.2012 …. …. …. …. …. ….

ALL THE PARAMETERS ARE WITHIN THE LIMITS

Page 27: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 25 of 73

STACK MONITORING REPORT: (BY MAHABAL ENVIRO ENGINEERS PVT. LTD.)

MONTH: FEBRUARY 2012

PESTICIDES AND PESTICIDES INTERMEDIATES PLANT:

Sr. AREA IDENTIFICATION DATE OF HCL CHLORINE NH3 NOx SPM SO2

No. (STACK) SAMPLING 20 mg/m3 5 mg/m3 30 mg/m3 50

mg/m3 20 mg/m3 100

mg/m3

TMP PLANT VENT OF

1 SCRUBBER ATTACHED 21.02.2012 …. BDL 18.3 ….. ….. ….

TO R-901 AND R-902

MANCOZEB PLANT(OLD)

2 WET SCRUBBER SPRAY 21.02.2012 ….. …… ….. …… ….. ……

DRIER

MANCOZEB PLANT(NEW)

3 SPD WET SCRUBBER 21.02.2012 ….. ….. ….. ….. ….. ……

OUTLET

ANTRACOLPLANT (BAG FILTER)

4 21.02.2012 …. ….. ….. ….. ….. …..

ANTRACOL PLANT (HOT AIR GENERATOR)

OTHER CHEMICAL PLANT

Sr. AREA IDENTIFICATION DATE OF PCL3 CHLORINE NH3 NOX SPM SO2

No. (STACK) SAMPLING 09 mg/m3 9 mg/m3 175 mg/m3 50 PPM 150 mg/m3 100 PPM

STACK ATTACHED TO

BOILER B5 GT-3138 21.02.2012 …. …. ….. ….. ….. …..

5

BOILER B6 GT-3476 21.02.2012 …. ….. ….. 11.4 BDL BDL

BOILER B7 GT-3515 21.02.2012 …. …. ….. 10.3 BDL BDL

SPRAY DRIER SYSTEM OF CACL2 PLANT

… …. …. …. 55.6 …. 6 21.02.2012

IN PCL3 PLANT STACK ATTACHED TO STORAGE SCRUBBER

7 21.02.2012 0.7 BDL … …. …. …..

ALL THE PARAMETERS ARE WITHIN THE LIMITS

Page 28: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 26 of 73

STACK MONITORING REPORT :(BY MAHABAL ENVIRO ENGINEERS PVT. LTD.)

MONTH: MARCH 2012

PESTICIDES AND PESTICIDES INTERMEDIATES PLANT:

Sr. AREA IDENTIFICATION DATE OF HCL CHLORINE NH3 NOx SPM SO2

No. (STACK) SAMPLING 20 mg/m3 5 mg/m3 30 mg/m3 50

mg/m3 20 mg/m3 100

mg/m3

TMP PLANT VENT OF

1 SCRUBBER ATTACHED 15.03.2012 ….. BDL 9.8 …. …. ….

TO R-901 AND R-902

MANCOZEB PLANT(OLD)

2 WET SCRUBBER SPRAY 15.03.2012 …. ….. ….. ….. ….. ……

DRIER

MANCOZEB PLANT(NEW)

3 SPD WET SCRUBBER 15.03.2012 …. ….. ….. ….. …. …..

OUTLET

ANTRACOLPLANT (BAG FILTER) 15.03.2012 ….. … …. …. …. …..

4

ANTRACOL PLANT (HOT AIR GENERATOR)

OTHER CHEMICAL PLANT

Sr. AREA IDENTIFICATION DATE OF PCL3 CHLORINE NH3 NOX SPM SO2

No. (STACK) SAMPLING 09 mg/m3 9 mg/m3 175 mg/m3 50 PPM 150 mg/m3 100 PPM

STACK ATTACHED TO

BOILER B5 GT-3138 15.03.2012 …. …. …. ….. ….. …..

5

BOILER B6 GT-3476 15.03.2012 …. …. ….. 10.8 BDL BDL

BOILER B7 GT-3515 15.03.2012 …. …. ….. 11.5 BDL BDL

SPRAY DRIER SYSTEM OF CACL2 PLANT

…. …. ….. ….. 73.1 …. 6 15.03.2012

IN PCL3 PLANT STACK ATTACHED TO STORAGE SCRUBBER

7 15.03.2012 0.9 BDL …. …. …. ….

ALL THE PARAMETERS ARE WITHIN THE LIMITS

Page 29: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 27 of 73

STACK MONITORING REPORT: (BY MAHABAL ENVIRO ENGINEERS PVT. LTD.)

MONTH: APRIL 2012

PESTICIDES AND PESTICIDES INTERMEDIATES PLANT:

Sr. AREA IDENTIFICATION DATE OF HCL CHLORINE NH3 NOx SPM SO2

No. (STACK) SAMPLING 20 mg/m3 5 mg/m3 30 mg/m3 50

mg/m3 20 mg/m3 100

mg/m3

TMP PLANT VENT OF 20.04.2012 … BDL 12.7 … … …

1 SCRUBBER ATTACHED

TO R-901 AND R-902

MANCOZEB PLANT(OLD)

2 WET SCRUBBER SPRAY 20.04.2012 …. ….. ….. ….. ….. …...

DRIER

MANCOZEB PLANT(NEW)

3 SPD WET SCRUBBER 20.04.2012 …. ….. ….. ….. ….. …..

OUTLET

ANTRACOLPLANT (BAG FILTER)

4 20.04.2012 ….. ….. …… ….. …. ….

ANTRACOL PLANT (HOT AIR GENERATOR)

OTHER CHEMICAL PLANT

Sr. AREA IDENTIFICATION DATE OF PCL3 CHLORINE NH3 NOX SPM SO2

No. (STACK) SAMPLING 09 mg/m3 9 mg/m3 175 mg/m3 50 PPM 150 mg/m3 100 PPM

STACK ATTACHED TO

BOILER B5 GT-3138 20.04.2012 …. ….. …. ….. ….. …..

5

BOILER B6 GT-3476 20.04.2012 …. ….. …. 10.7 BDL BDL

BOILER B7 GT-3523 20.04.2012 …. ….. …… 12.1 BDL BDL

SPRAY DRIER SYSTEM OF CACL2 PLANT

20.04.2012

…. …. …. …. 69.3 … 6

IN PCL3 PLANT STACK ATTACHED TO STORAGE SCRUBBER

7 20.04.2012 0.5 BDL …. …. ….

ALL THE PARAMETERS ARE WITHIN THE LIMITS

Page 30: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 28 of 73

STACK MONITORING REPORT: (BY MAHABAL ENVIRO ENGINEERS PVT. LTD.)

MONTH: MAY 2012

PESTICIDES AND PESTICIDES INTERMEDIATES PLANT:

Sr. AREA IDENTIFICATION DATE OF HCL CHLORINE NH3 NOx SPM SO2

No. (STACK) SAMPLING 20 mg/m3 5 mg/m3 30 mg/m3 50

mg/m3 20 mg/m3 100

mg/m3

TMP PLANT VENT OF

1 SCRUBBER ATTACHED 11.05.2012 …. BDL 18.6 ….. …. ….

TO R-901 AND R-902

MANCOZEB PLANT(OLD)

2 WET SCRUBBER SPRAY 11.05.2012 …. ….. ….. ….. ….. …..

DRIER

MANCOZEB PLANT(NEW)

3 SPD WET SCRUBBER 11.05.2012 ….. ….. ….. ….. … ….

OUTLET

ANTRACOLPLANT (BAG FILTER)

4 11.05.2012 …. ….. …. …. ….. …..

ANTRACOL PLANT (HOT AIR GENERATOR)

OTHER CHEMICAL PLANT

Sr. AREA IDENTIFICATION DATE OF PCL3 CHLORINE NH3 NOX SPM SO2

No. (STACK) SAMPLING 09 mg/m3 9 mg/m3 175 mg/m3 50 PPM 150 mg/m3 100 PPM

STACK ATTACHED TO

BOILER B5 GT-3138 11.05.2012 ….. ….. ….. 13.4 BDL BDL

5

BOILER B6 GT-3476 11.05.2012 ….. ….. …… ….. …. …..

BOILER B7 GT-3515 11.05.2012 …. …. ….. 11.8 BDL BDL

SPRAY DRIER SYSTEM OF CACL2 PLANT

…. …. ….. …. 76.1 ….. 6 11.05.2012

IN PCL3 PLANT STACK ATTACHED TO STORAGE SCRUBBER

7 11.05.2012 0.7 BDL … … …. ….

ALL THE PARAMETERS ARE WITHIN THE LIMITS

Page 31: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 29 of 73

STACK MONITORING REPORT: (BY MAHABAL ENVIRO ENGINEERS PVT. LTD.)

MONTH: JUNE 2012

PESTICIDES AND PESTICIDES INTERMEDIATES PLANT:

Sr. AREA IDENTIFICATION DATE OF HCL CHLORINE NH3 NOx PM SO2

No. (STACK) SAMPLING 20 mg/m3 5 mg/m3 30 mg/m3 50 mg/m3 20 mg/m3 100

mg/m3

TMP PLANT VENT OF

1 SCRUBBER ATTACHED 13.06.2012 ….. BDL 8.4 …… ….. …..

TO R-901 AND R-902

MANCOZEB PLANT(OLD)

2 WET SCRUBBER SPRAY 13.06.2012 …. …. ….. ….. ….. …..

DRIER

MANCOZEB PLANT(NEW)

3 SPD WET SCRUBBER 13.06.2012 …. ….. ….. …… ….. …..

OUTLET

ANTRACOLPLANT (BAG FILTER)

4 13.06.2012 ….. ….. …… ….. 11.3 ….

ANTRACOL PLANT (HOT AIR GENERATOR)

OTHER CHEMICAL PLANT

Sr. AREA IDENTIFICATION DATE OF PCL3 CHLORINE NH3 NOX SPM SO2

No. (STACK) SAMPLING 09 mg/m3 9 mg/m3 175 mg/m3 50 PPM 150 mg/m3 100 PPM

STACK ATTACHED TO

BOILER B5 GT-3138 13.06.2012 ……. …… …… …… …… ……

5

BOILER B6 GT-3476 13.06.2012 ….. ….. …… 12.3 BDL BDL

BOILER B7 GT-3515 13.06.2012 ….. …… …… 10.2 BDL BDL

SPRAY DRIER SYSTEM

6 OF CACL2 PLANT 13.06.2012

…… ……. ……. ….. 62.4 ……

IN PCL3 PLANT STACK

7 ATTACHED TO 13.06.2012 0.9 BDL …. ….. ….. …..

STORAGE SCRUBBER

ALL THE PARAMETERS ARE WITHIN THE LIMITS

Page 32: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 30 of 73

AMBIENT AIR MONITORING

(OUR INTERNAL LAB ANALYSIS REPORTS)

Page 33: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 31 of 73

MONTH: JANUARY 2012

AMBIENT AIR MONITORING REPORT

MONTH : JAN-2012

PM 2.5 PM 10 AMMONIA CL2 HCL NOX SO2

LIMITS --> 60 100 400 100 200 80 80

Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3

LOCATION DATE

NEAR MAIN GATE 02.01.12 78 4.0 BDL 2.31 3.00

NEAR MAIN GATE 05.01.12 46 86 6.0 BDL 3.30 4.00

NEAR MAIN GATE 08.01.12 90 4.0 BDL 3.63 4.00

NEAR MAIN GATE 11.01.12 72 2.0 BDL 2.31 5.00

NEAR MAIN GATE 14.01.12 55 69 6.0 BDL 2.64 6.00

NEAR MAIN GATE 17.01.12 76 3.0 BDL 3.63 5.00

NEAR MAIN GATE 20.01.12 83 4.0 BDL 1.65 4.00

NEAR MAIN GATE 23.01.12 52 67 4.0 BDL 2.31 3.00

NEAR MAIN GATE 26.01.12 80 5.0 BDL 2.31 5.00

NEAR MAIN GATE 29.01.12 84 3.0 BDL 3.63 5.00

Maximum 55 90 6 BDL 3.63 6 5

Minimum 46 67 2 BDL 1.65 3 3

Average 51.00 78.50 4.10 BDL 2.77 4.40 4.40

%Deviation Nil Nil Nil Nil Nil Nil Nil

All the parameters are within the limits

( Analyzed by ) Sr.Executive –QA

(Approved by ) HOD -QA

AMBIENT AIR MONITORING REPORT

MONTH : JAN-2012

PM 10 AMMONIA CL2 HCL NOX SO2 LIMITS --> 100 400 100 200 80 80 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3

LOCATION DATE B/H CACL2 PLANT 02.01.12 82 83.0 BDL 12.54 12.00 B/H CACL2 PLANT 05.01.12 89 78.0 BDL 14.19 10.00 B/H CACL2 PLANT 08.01.12 79 81.0 BDL 14.52 9.00 B/H CACL2 PLANT 11.01.12 93 75.0 BDL 13.53 12.00

B/H CACL2 PLANT 14.01.12 85 78.0 BDL 15.84 10.00

B/H CACL2 PLANT 17.01.12 68 56.0 BDL 11.22 9.00

Page 34: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 32 of 73

B/H CACL2 PLANT 20.01.12 61 49.0 BDL 9.24 12.00

B/H CACL2 PLANT 23.01.12 73 55.0 BDL 10.23 10.00

B/H CACL2 PLANT 26.01.12 71 57.0 BDL 11.84 8.00 B/H CACL2 PLANT 29.01.12 65 52.0 BDL 12.54 9.00 Maximum 93 83 BDL 15.84 12 12 Minimum 61 49 BDL 9.24 8 9 Average 76.60 66.40 0 12.57 10.20 10.00

%Deviation Nil Nil Nil Nil Nil Nil

All the parameters are within the limits

( Analyzed by )

Sr.Executive –QA (Approved by )

HOD -QA

AMBIENT AIR MONITORING REPORT

MONTH : JAN-2012

SPM AMMONIA CL2 HCL NOX SO2

LIMITS --> 500 400 100 200 80 80

Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3

LOCATION DATE

B/H BREQUATING PLANT 02.01.12 172 61.0 BDL 12.87 11.00

B/H BREQUATING PLANT 05.01.12 156 55.0 BDL 15.18 9.00

B/H BREQUATING PLANT 08.01.12 195 32.0 BDL 14.19 10.00

B/H BREQUATING PLANT 11.01.12 183 43.0 BDL 11.88 8.00

B/H BREQUATING PLANT 14.01.12 189 48.0 BDL 9.90 9.00

B/H BREQUATING PLANT 17.01.12 190 37.0 BDL 10.23 12.00

B/H BREQUATING PLANT 20.01.12 138 45.0 BDL 12.87 11.00 B/H BREQUATING PLANT 23.01.12 146 56.0 BDL 10.56 10.00 B/H BREQUATING PLANT 26.01.12 152 49.0 BDL 12.54 9.00

B/H BREQUATING PLANT 29.01.12 172 42.0 BDL 9.90 8.00 Maximum 195 61 BDL 15.18 11 12

Minimum 138 32 BDL 9.9 9 8

Average: 169.30 46.80 0 12.01 10.00 9.40

%Deviation Nil Nil Nil Nil Nil Nil

All the parameters are within the limits

( Analyzed by )

Sr.Executive –QA

(Approved by )

HOD -QA

Page 35: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 33 of 73

MONTH: FEBRUARY 2012

AMBIENT AIR MONITORING REPORT

MONTH : FEB-2012

PM 2.5 PM 10 AMMONIA CL2 HCL NOX SO2

LIMITS --> 60 100 400 100 200 80 80

Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3

LOCATION DATE

NEAR MAIN GATE 02.02.12 78 4.0 BDL 3.63 4.00

NEAR MAIN GATE 05.02.12 51 90 6.0 BDL 2.31 2.00

NEAR MAIN GATE 09.02.12 83 2.0 BDL 1.65 5.00

NEAR MAIN GATE 12.02.12 47 73 3.0 BDL 4.29 3.00

NEAR MAIN GATE 15.02.12 93 3.0 BDL 2.97 3.00

NEAR MAIN GATE 19.02.12 85 5.0 BDL 3.63 4.00

NEAR MAIN GATE 22.02.12 81 3.0 BDL 3.30 4.00

NEAR MAIN GATE 24.02.12 54 79 2.0 BDL 2.31 3.00

NEAR MAIN GATE 26.02.12 88 4.0 BDL 3.96 5.00

NEAR MAIN GATE 28.02.12 76 5.0 BDL 3.30 4.00

Maximum 54 93 6 BDL 4.29 5 4

Minimum 47 73 2 BDL 1.65 3 2

Average 50.67 82.60 3.70 BDL 3.14 4.20 3.20

%Deviation Nil Nil Nil Nil Nil Nil Nil

All the parameters are within the limits

( Analyzed by )

Sr.Executive –QA

(Approved by )

HOD -QA

AMBIENT AIR MONITORING REPORT

MONTH : FEB-2012

PM 10 AMMONIA CL2 HCL NOX SO2

LIMITS --> 100 400 100 200 80 80

Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3

LOCATION DATE

B/H CACL2 PLANT 02.02.12 76 72.0 BDL 10.23 11.00

B/H CACL2 PLANT 05.02.12 81 58.0 BDL 8.58 7.00

B/H CACL2 PLANT 09.02.12 79 83.0 BDL 12.21 14.00 B/H CACL2 PLANT 12.02.12 88 64.0 BDL 13.20 12.00 B/H CACL2 PLANT 15.02.12 86 70.0 BDL 7.59 9.00 B/H CACL2 PLANT 19.02.12 63 58.0 BDL 10.89 10.00

Page 36: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 34 of 73

B/H CACL2 PLANT 22.02.12 78 53.0 BDL 15.84 11.00

B/H CACL2 PLANT 24.02.12 85 71.0 BDL 11.88 13.00

B/H CACL2 PLANT 26.02.12 82 66.0 BDL 14.52 13.00 B/H CACL2 PLANT 28.02.12 73 79.0 BDL 13.20 11.00

Maximum 88 83 BDL 15.84 14 13

Minimum 63 53 BDL 7.59 9 7

Average 79.10 67.40 0 11.81 11.60 10.60

%Deviation Nil Nil Nil Nil Nil Nil

All the parameters are within the limits

( Analyzed by ) Sr.Executive –QA

(Approved by ) HOD -QA

AMBIENT AIR MONITORING REPORT

MONTH : FEB-2012

SPM AMMONIA CL2 HCL NOX SO2 LIMITS --> 500 400 100 200 80 80

Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3

LOCATION DATE

B/H BREQUATING PLANT 02.02.12 158 42.0 BDL 10.56 10.00 B/H BREQUATING PLANT 05.02.12 163 35.0 BDL 14.19 11.00

B/H BREQUATING PLANT 09.02.12 176 28.0 BDL 16.17 12.00

B/H BREQUATING PLANT 12.02.12 180 40.0 BDL 8.25 9.00

B/H BREQUATING PLANT 15.02.12 168 31.0 BDL 9.57 9.00

B/H BREQUATING PLANT 19.02.12 178 26.0 BDL 12.87 13.00

B/H BREQUATING PLANT 22.02.12 132 38.0 BDL 10.56 10.00

B/H BREQUATING PLANT 24.02.12 141 41.0 BDL 7.59 10.00

B/H BREQUATING PLANT

26.02.12 160 33.0 BDL 11.55 8.00

B/H BREQUATING PLANT 28.02.12 178 29.0 BDL 12.21 9.00

Maximum 180 42 BDL 16.17 12 13

Minimum 132 26 BDL 7.59 8 9

Average: 163.40 34.30 0 11.35 9.80 10.40

%Deviation Nil Nil Nil Nil Nil Nil

All the parameters are within the limits

( Analyzed by )

Sr.Executive –QA

(Approved by )

HOD -QA

Page 37: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 35 of 73

MONTH: MARCH 2012

AMBIENT AIR MONITORING REPORT

MONTH : MAR-2012

PM 2.5 PM 10 AMMONIA CL2 HCL NOX SO2

LIMITS --> 60 100 400 100 200 80 80

Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3

LOCATION DATE

NEAR MAIN GATE 02.03.12 84 5.0 BDL 3.30 3.00

NEAR MAIN GATE 05.03.12 55 78 3.0 BDL 2.97 4.00

NEAR MAIN GATE 08.03.12 89 7.0 BDL 2.31 5.00

NEAR MAIN GATE 10.03.12 91 4.0 BDL 3.96 4.00

NEAR MAIN GATE 12.03.12 49 75 6.0 BDL 1.98 2.00

NEAR MAIN GATE 15.03.12 83 3.0 BDL 2.31 3.00

NEAR MAIN GATE 18.03.12 76 8.0 BDL 2.64 4.00

NEAR MAIN GATE 21.03.12 89 5.0 BDL 3.30 2.00

NEAR MAIN GATE 25.03.12 43 81 4.0 BDL 2.64 3.00

NEAR MAIN GATE 28.03.12 76 3.0 BDL 2.31 3.00

Maximum 55 91 8 BDL 3.96 5 4

Minimum 43 75 3 BDL 1.98 2 2

Average 49.00 82.20 4.80 BDL 2.77 3.40 3.20

%Deviation Nil Nil Nil Nil Nil Nil Nil

All the parameters are within the limits

( Analyzed by ) Sr.Executive –QA

(Approved by ) HOD -QA

AMBIENT AIR MONITORING REPORT

MONTH : MAR-2012

PM 10 AMMONIA CL2 HCL NOX SO2

LIMITS --> 100 400 100 200 80 80

Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3

LOCATION DATE

B/H CACL2 PLANT 02.03.12 85 61.0 BDL 11.88 13.00

B/H CACL2 PLANT 05.03.12 72 57.0 BDL 7.59 9.00

B/H CACL2 PLANT 08.03.12 90 70.0 BDL 14.52 15.00

B/H CACL2 PLANT 10.03.12 83 65.0 BDL 13.20 11.00

B/H CACL2 PLANT 12.03.12 92 51.0 BDL 8.58 8.00

Page 38: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 36 of 73

B/H CACL2 PLANT 15.03.12 87 58.0 BDL 11.55 10.00

B/H CACL2 PLANT 18.03.12 90 71.0 BDL 13.86 11.00

B/H CACL2 PLANT 21.03.12 78 81.0 BDL 9.57 12.00 B/H CACL2 PLANT 25.03.12 83 68.0 BDL 10.89 13.00 B/H CACL2 PLANT 28.03.12 90 70.0 BDL 10.23 10.00

Maximum 92 81 BDL 14.52 15 12

Minimum 72 51 BDL 7.59 8 9

Average 85.00 65.20 0 11.19 12.00 10.40 %Deviation Nil Nil Nil Nil Nil Nil

All the parameters are within the limits

( Analyzed by )

Sr.Executive -QA

(Approved by )

HOD -QA

AMBIENT AIR MONITORING REPORT

MONTH : MAR-2012

SPM AMMONIA CL2 HCL NOX SO2

LIMITS --> 500 400 100 200 80 80

Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3

LOCATION DATE

B/H BREQUATING PLANT 02.03.12 131 38.0 BDL 9.57 10.00

B/H BREQUATING PLANT 05.03.12 140 26.0 BDL 12.87 8.00

B/H BREQUATING PLANT 08.03.12 152 31.0 BDL 11.55 11.00

B/H BREQUATING PLANT 10.03.12 170 42.0 BDL 10.56 10.00

B/H BREQUATING PLANT 12.03.12 178 21.0 BDL 7.92 7.00

B/H BREQUATING PLANT 15.03.12 122 24.0 BDL 8.91 12.00

B/H BREQUATING PLANT 18.03.12 145 31.0 BDL 13.86 9.00

B/H BREQUATING PLANT 21.03.12 152 29.0 BDL 6.27 7.00

B/H BREQUATING PLANT 25.03.12 160 35.0 BDL 9.57 11.00

B/H BREQUATING PLANT 28.03.12 148 40.0 BDL 10.56 8.00

Maximum 178 42 BDL 13.86 11 12

Minimum 122 21 BDL 6.27 7 7

Average: 149.80 31.70 0 10.16 9.60 9.00

%Deviation Nil Nil Nil Nil Nil Nil

All the parameters are within the limits

( Analyzed by )

Sr.Executive -QA

(Approved by )

HOD -QA

Page 39: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 37 of 73

MONTH: APRIL 2012

AMBIENT AIR MONITORING REPORT

MONTH : APR-2012

PM 2.5 PM 10 AMMONIA CL2 HCL NOX SO2

LIMITS --> 60 100 400 100 200 80 80

Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3

LOCATION DATE

NEAR MAIN GATE 02.04.12 77 4.0 BDL 2.31 4.00

NEAR MAIN GATE 05.04.12 51 81 6.0 BDL 3.30 3.00

NEAR MAIN GATE 09.04.12 72 3.0 BDL 3.30 3.00

NEAR MAIN GATE 13.04.12 86 3.0 BDL 2.31 4.00

NEAR MAIN GATE 16.04.12 46 92 5.0 BDL 2.64 5.00

NEAR MAIN GATE 19.04.12 85 7.0 BDL 3.63 5.00

NEAR MAIN GATE 22.04.12 71 4.0 BDL 1.65 2.00

NEAR MAIN GATE 24.04.12 76 3.0 BDL 3.63 4.00

NEAR MAIN GATE 27.04.12 49 73 4.0 BDL 2.31 5.00

NEAR MAIN GATE 30.04.12 91 4.0 BDL 3.63 5.00

Maximum 51 92 7 BDL 3.63 5 5

Minimum 46 71 3 BDL 1.65 2 3

Average 48.67 80.40 4.30 BDL 2.87 3.80 4.20

%Deviation Nil Nil Nil Nil Nil Nil Nil

All the parameters are within the limits

( Analyzed by )

Sr.Executive –QA

(Approved by )

HOD -QA

AMBIENT AIR MONITORING REPORT

MONTH : APR-2012

PM 10 AMMONIA CL2 HCL NOX SO2 LIMITS --> 100 400 100 200 80 80

Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3

LOCATION DATE

B/H CACL2 PLANT 02.04.12 68 57.0 BDL 9.57 12.00

B/H CACL2 PLANT 05.04.12 70 54.0 BDL 10.89 8.00

B/H CACL2 PLANT 09.04.12 84 68.0 BDL 13.20 14.00

B/H CACL2 PLANT 13.04.12 89 61.0 BDL 9.57 11.00

B/H CACL2 PLANT 16.04.12 94 49.0 BDL 8.58 9.00

B/H CACL2 PLANT 19.04.12 85 56.0 BDL 13.86 8.00

B/H CACL2 PLANT 22.04.12 65 74.0 BDL 11.55 10.00

Page 40: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 38 of 73

B/H CACL2 PLANT 24.04.12 72 83.0 BDL 9.57 10.00

B/H CACL2 PLANT 27.04.12 81 70.0 BDL 10.23 12.00

B/H CACL2 PLANT 30.04.12 76 78.0 BDL 8.58 11.00

Maximum 94 83 BDL 13.86 14 11

Minimum 65 49 BDL 8.58 9 8

Average 78.40 65.00 0 10.56 11.40 9.60

%Deviation Nil Nil Nil Nil Nil Nil

All the parameters are within the limits

( Analyzed by )

Sr.Executive –QA

(Approved by )

HOD -QA

AMBIENT AIR MONITORING REPORT

MONTH : APR-2012

SPM AMMONIA CL2 HCL NOX SO2

LIMITS --> 500 400 100 200 80 80

Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3

LOCATION DATE

B/H BREQUATING PLANT 02.04.12 134 23.0 BDL 8.91 8.00

B/H BREQUATING PLANT 05.04.12 158 30.0 BDL 10.56 11.00

B/H BREQUATING PLANT 09.04.12 147 29.0 BDL 9.57 10.00 B/H BREQUATING PLANT 13.04.12 172 18.0 BDL 10.56 9.00 B/H BREQUATING PLANT 16.04.12 165 24.0 BDL 7.92 7.00 B/H BREQUATING PLANT 19.04.12 117 26.0 BDL 6.27 10.00 B/H BREQUATING PLANT 22.04.12 132 29.0 BDL 10.56 8.00

B/H BREQUATING PLANT 24.04.12 140 23.0 BDL 8.91 8.00

B/H BREQUATING PLANT 27.04.12 163 31.0 BDL 10.89 7.00

B/H BREQUATING PLANT 30.04.12 143 27.0 BDL 11.22 10.00

Maximum 172 31 BDL 11.22 10 11 Minimum 117 18 BDL 6.27 7 8

Average: 147.10 26.00 0 9.54 8.00 9.60

%Deviation Nil Nil Nil Nil Nil Nil

All the parameters are within the limits

( Analyzed by ) Sr.Executive –QA

(Approved by ) HOD -QA

Page 41: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 39 of 73

MONTH: MAY 2012

AMBIENT AIR MONITORING REPORT

MONTH : MAY-2012

PM 2.5 PM 10 AMMONIA CL2 HCL NOX SO2

LIMITS --> 60 100 400 100 200 80 80

Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3

LOCATION DATE

NEAR MAIN GATE 03.05.12 83 4.0 BDL 2.31 4.00

NEAR MAIN GATE 05.05.12 48 71 6.0 BDL 3.30 3.00

NEAR MAIN GATE 08.05.12 78 3.0 BDL 3.30 3.00

NEAR MAIN GATE 12.05.12 80 3.0 BDL 2.31 4.00

NEAR MAIN GATE 14.05.12 42 94 5.0 BDL 2.64 5.00

NEAR MAIN GATE 17.05.12 84 7.0 BDL 3.63 5.00

NEAR MAIN GATE 20.05.12 91 4.0 BDL 1.65 2.00

NEAR MAIN GATE 22.05.12 89 3.0 BDL 3.63 4.00

NEAR MAIN GATE 25.05.12 52 92 4.0 BDL 2.31 5.00

NEAR MAIN GATE 27.05.12 84 4.0 BDL 3.63 5.00

Maximum 52 94 7 BDL 3.63 5 5

Minimum 42 71 3 BDL 1.65 2 3

Average 47.33 84.60 4.30 BDL 2.87 3.80 4.20

%Deviation Nil Nil Nil Nil Nil Nil Nil

All the parameters are within the limits

( Analyzed by )

Sr.Executive –QA

(Approved by )

HOD -QA

AMBIENT AIR MONITORING REPORT

MONTH : MAY-2012

PM 10 AMMONIA CL2 HCL NOX SO2

LIMITS --> 100 400 100 200 80 80 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3

LOCATION DATE

B/H CACL2 PLANT 03.05.12 68 57.0 BDL 9.57 12.00

B/H CACL2 PLANT 05.05.12 70 54.0 BDL 10.89 8.00

B/H CACL2 PLANT 08.05.12 84 68.0 BDL 13.20 14.00

Page 42: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 40 of 73

B/H CACL2 PLANT 12.05.12 89 61.0 BDL 9.57 11.00

B/H CACL2 PLANT 14.05.12 94 49.0 BDL 8.58 9.00

B/H CACL2 PLANT 17.05.12 85 56.0 BDL 13.86 8.00

B/H CACL2 PLANT 20.05.12 65 74.0 BDL 11.55 10.00

B/H CACL2 PLANT 22.05.12 72 83.0 BDL 9.57 10.00

B/H CACL2 PLANT 25.05.12 81 70.0 BDL 10.23 12.00

B/H CACL2 PLANT 27.05.12 76 78.0 BDL 8.58 11.00

Maximum 94 83 BDL 13.86 14 11

Minimum 65 49 BDL 8.58 9 8

Average 78.40 65.00 0 10.56 11.40 9.60

%Deviation Nil Nil Nil Nil Nil Nil

All the parameters are within the limits

AMBIENT AIR MONITORING REPORT

MONTH : MAY-2012

SPM AMMONIA CL2 HCL NOX SO2

LIMITS --> 500 400 100 200 80 80

Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3

LOCATION DATE

B/H BREQUATING PLANT 03.05.12 134 23.0 BDL 8.91 8.00

B/H BREQUATING PLANT 05.05.12 158 30.0 BDL 10.56 11.00

B/H BREQUATING PLANT 08.05.12 147 29.0 BDL 9.57 10.00

B/H BREQUATING PLANT 12.05.12 172 18.0 BDL 10.56 9.00

B/H BREQUATING PLANT 14.05.12 165 24.0 BDL 7.92 7.00

B/H BREQUATING PLANT 17.05.12 117 26.0 BDL 6.27 10.00

B/H BREQUATING PLANT 20.05.12 132 29.0 BDL 10.56 8.00

B/H BREQUATING PLANT 22.05.12 140 23.0 BDL 8.91 8.00

B/H BREQUATING PLANT 25.05.12 163 31.0 BDL 10.89 7.00

B/H BREQUATING PLANT 27.05.12 143 27.0 BDL 11.22 10.00

Maximum 172 31 BDL 11.22 10 11

Minimum 117 18 BDL 6.27 7 8

Average: 147.10 26.00 0 9.54 8.00 9.60

%Deviation Nil Nil Nil Nil Nil Nil

All the parameters are within the limits

( Analyzed by )

Sr.Executive –QA

(Approved by )

HOD -QA

Page 43: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 41 of 73

MONTH: JUNE 2012

AMBIENT AIR MONITORING REPORT

MONTH : JUN-2012

PM 2.5 PM 10 AMMONIA CL2 HCL NOX SO2

LIMITS --> 60 100 400 100 200 80 80

Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3

LOCATION DATE

NEAR MAIN GATE 02.06.12 81 5.0 BDL 3.30 3.00

NEAR MAIN GATE 07.06.12 44 74 4.0 BDL 2.31 4.00

NEAR MAIN GATE 10.06.12 89 4.0 BDL 3.30 4.00

NEAR MAIN GATE 13.06.12 79 5.0 BDL 2.31 2.00

NEAR MAIN GATE 16.06.12 51 83 3.0 BDL 2.31 2.00

NEAR MAIN GATE 19.06.12 76 4.0 BDL 2.64 4.00

NEAR MAIN GATE 22.06.12 85 3.0 BDL 3.63 3.00

NEAR MAIN GATE 25.06.12 48 72 5.0 BDL 1.65 2.00

NEAR MAIN GATE 27.06.12 81 4.0 BDL 3.30 2.00

NEAR MAIN GATE 29.06.12 75 5.0 BDL 2.97 3.00

Maximum 51 89 5 BDL 3.63 4 4

Minimum 44 72 3 BDL 1.65 2 2

Average 47.67 79.50 4.20 BDL 2.77 2.80 3.00

%Deviation Nil Nil Nil Nil Nil Nil Nil

All the parameters are within the limits

( Analyzed by ) Sr.Executive –QA

(Approved by ) HOD -QA

AMBIENT AIR MONITORING REPORT

MONTH : JUN-2012

PM 10 AMMONIA CL2 HCL NOX SO2

LIMITS --> 100 400 100 200 80 80

Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3

LOCATION DATE

B/H CACL2 PLANT 02.06.12 85 56.0 BDL 13.86 10.00

B/H CACL2 PLANT 07.06.12 65 74.0 BDL 11.55 8.00

B/H CACL2 PLANT 10.06.12 94 49.0 BDL 8.58 9.00 B/H CACL2 PLANT 13.06.12 81 70.0 BDL 9.57 10.00

B/H CACL2 PLANT 16.06.12 78 62.0 BDL 11.55 12.00 B/H CACL2 PLANT 19.06.12 87 58.0 BDL 10.23 11.00 B/H CACL2 PLANT 22.06.12 90 64.0 BDL 9.57 9.00

Page 44: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 42 of 73

B/H CACL2 PLANT 25.06.12 83 53.0 BDL 10.23 10.00

B/H CACL2 PLANT 27.06.12 79 57.0 BDL 7.92 7.00

B/H CACL2 PLANT 29.06.12 75 61.0 BDL 8.91 9.00

Maximum 94 74 BDL 13.86 12 11

Minimum 65 49 BDL 7.92 7 8

Average 81.70 60.40 0 10.20 9.40 9.60

%Deviation Nil Nil Nil Nil Nil Nil

All the parameters are within the limits

( Analyzed by )

Sr.Executive –QA

(Approved by )

HOD -QA

AMBIENT AIR MONITORING REPORT

MONTH : JUN-2012

SPM AMMONIA CL2 HCL NOX SO2

LIMITS --> 500 400 100 200 80 80

Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3 Microg/m3

LOCATION DATE

B/H BREQUATING PLANT 02.06.12 117 26.0 BDL 6.27 9.00

B/H BREQUATING PLANT 07.06.12 140 23.0 BDL 8.91 11.00

B/H BREQUATING PLANT 10.06.12 163 31.0 BDL 10.89 7.00

B/H BREQUATING PLANT 13.06.12 160 29.0 BDL 6.27 9.00

B/H BREQUATING PLANT 16.06.12 171 22.0 BDL 10.56 9.00

B/H BREQUATING PLANT 19.06.12 160 27.0 BDL 7.92 12.00 B/H BREQUATING PLANT 22.06.12 188 32.0 BDL 6.27 8.00 B/H BREQUATING PLANT 25.06.12 145 30.0 BDL 10.56 11.00 B/H BREQUATING PLANT 27.06.12 171 21.0 BDL 7.59 6.00

B/H BREQUATING PLANT 29.06.12 168 18.0 BDL 8.25 10.00 Maximum 188 32 BDL 10.89 9 12 Minimum 117 18 BDL 6.27 6 9 Average: 158.30 25.90 0 8.35 7.80 10.60 %Deviation Nil Nil Nil Nil Nil Nil

All the parameters are within the limits

( Analyzed by ) Sr.Executive –QA

(Approved by ) HOD -QA

Page 45: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 43 of 73

AMBIENT AIR ANALYSIS REPORT

(BY MAHABAL ENVIRO ENGINEERS PVT. LTD)

JAN-JUN 2012

MONTH

LOCATION DATE OF RSPM SOx NOx HCL NH3 H.C. CHLORI

NE H2S P2O5 CO

SAMPLING 100 µg

/m3

120

µg

/m3

120

µg

/m3

200

µg

/m3

850

µg

/m3

160

µg

/m3

100 µg

/m3

400 µg

/m3

30

µg

/m3

5000

µg

/m3

JAN

Near

TMP/Boile

r area

10.01.2012 79.4 19.4 21.6 27.2 32.8 BDL BDL BDL BDL 1145

FEB

Near

TMP/Boile

r area

21.02.2012 84.7 20.5 24.7 37.6 27.5 BDL BDL BDL BDL 1031

MAR

Near

TMP/Boile

r area

15.03.2012 74.2 17.3 20.4 25.2 24.6 BDL BDL BDL BDL 1145

APR

Near

TMP/Boile

r area

19.04.2012 69.3 19.8 20.6 27.2 29.4 BDL BDL BDL BDL 1145

MAY

Near

TMP/Boile

r area

11.05.2012 79.4 18.7 22.4 34.6 46.8 BDL BDL BDL BDL 1031

JUN

Near

TMP/Boile

r area

13.06.2012 86.9 12.5 15.9 19.3 92.2 BDL BDL BDL BDL 916

AMBIENT AIR POLLUTION MONITORING REPORT

Page 46: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 44 of 73

(MAHABAL ENVIROENGINEERS LIMITED)

JAN TO JUNE 2012

Sr. LOCATION MONTH DATE OF TIME OF PARAMETER RESULTS

No. SAMPLING SAMPLING

AT

MANCOZEB

PLANT JAN 10.01.2012

9.30 to 13.30

(4 hrs) 0.144 mg/m3

1 CS2

13.35 to 17.35

(4 hrs) 0.183 mg/m3

AT

MANCOZEB

PLANT FEB 21.02.2012

9.30 to 13.30

(4 hrs) 0.138 mg/m3

2 CS2

13.35 to 17.35

(4 hrs) 0.173 mg/m3

AT

MANCOZEB

PLANT MAR 15.03.2012

9.30 to 13.30

(4 hrs) 0.060 mg/m3

3 CS2

13.35 to 17.35

(4 hrs) 0.071 mg/m3

AT

MANCOZEB

PLANT APR 19.04.2012

9.30 to 13.30

(4 hrs) 0.102 mg/m3

4 CS2

13.35 to 17.35

(4 hrs) 0.074 mg/m3

AT

MANCOZEB

PLANT MAY 11.05.2012

9.30 to 13.30

(4 hrs) 0.137 mg/m3

5 CS2

13.35 to 17.35

(4 hrs) 0.129 mg/m3

AT

MANCOZEB

PLANT JUN 13.06.2012

9.30 to 13.30

(4 hrs) 0.112 mg/m3

6 CS2

13.35 to 17.35

(4 hrs) 0.119 mg/m3

Page 47: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 45 of 73

TOXICITY FACTOR

(OUR INTERNAL LAB ANALYSIS REPORTS)

Page 48: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 46 of 73

TOXICITY FACTOR

MONTH: JANUARY 2012

DATE Parts of Ratio of Dilution FISH FISH ANALYSIS OF FIISH

AFTER HRS. TOXICITY

OF Dilution Waste

Factor

(T) TYPE NO. FINAL OUTLET 2 HRS 6 HRS 24 HRS 48 HRS FACTOR

EXP. Water Water Tf

Tobe To test PH COD

Added Water PPM

To one (by

Part of Volume)

Waste

Water

(by

volume)

02.01.12 3 1:4 4 ZEBRA 5 7.45 80 5 5 5 5 Tf =4

05.01.12 1 1:2 2 ZEBRA 5 7.90 88 5 5 5 5 Tf =2

08.01.12 3 1:4 4 ZEBRA 5 7.55 92 5 5 5 5 Tf =4

11.01.12 1 1:2 2 ZEBRA 5 7.69 72 5 5 5 5 Tf =2

15.01.12 3 1:4 4 ZEBRA 5 7.35 92 5 5 5 5 Tf =4

18.01.12 3 1:4 4 ZEBRA 5 7.37 80 5 5 5 5 Tf =4

21.01.12 1 1:2 2 ZEBRA 5 7.72 84 5 5 5 5 Tf =2

24.01.12 3 1:4 4 ZEBRA 5 7.55 88 5 5 5 5 Tf =4

26.01.12 1 1:2 2 ZEBRA 5 7.40 84 5 5 5 5 Tf =2

29.01.12 3 1:4 4 ZEBRA 5 7.67 84 5 5 5 5 Tf =4

Remark : All parameter passes as per requirement.

( Analyzed by )

Sr. Executive

(Approved by)

HOD - QA

Page 49: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 47 of 73

TOXICITY FACTOR

MONTH: FEBRUARY 2012

DATE Parts of Ratio of Dilution FISH FISH ANALYSIS OF

FIISH AFTER HRS.

TOXICITY

OF Dilution Waste Factor (T) TYPE NO. FINAL OUTLET 2 HRS 6 HRS 24 HRS 48 HRS FACTOR

EXP. Water Water Tf

Tobe To test PH COD

Added Water PPM

To one (by

Part of Volume)

Waste

Water

(by volume)

01.02.12 1 1:2 2 ZEBRA 5 7.47 81 5 5 5 5 Tf =2

04.02.12 1 1:2 2 ZEBRA 5 7.38 81 5 5 5 5 Tf =2

07.02.12 3 1:4 4 ZEBRA 5 7.37 68 5 5 5 5 Tf =4

10.02.12 3 1:4 4 ZEBRA 5 7.01 96 5 5 5 5 Tf =4

13.02.12 3 1:4 4 ZEBRA 5 7.10 92 5 5 5 5 Tf =4

17.02.12 1 1:2 2 ZEBRA 5 7.43 64 5 5 5 5 Tf =2

19.02.12 1 1:2 2 ZEBRA 5 7.46 64 5 5 5 5 Tf =2

23.02.12 3 1:4 4 ZEBRA 5 7.38 80 5 5 5 5 Tf =4

25.02.12 1 1:2 2 ZEBRA 5 7.50 48 5 5 5 5 Tf =2

27.02.12 3 1:4 4 ZEBRA 5 8.03 48 5 5 5 5 Tf =4

Remark : All parameter passes as per requirement.

( Analyzed by )

Sr. Executive

(Approved by)

HOD - QA

Page 50: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 48 of 73

TOXICITY FACTOR

MONTH: MARCH 2012

DATE Parts of Ratio of Dilution FISH FISH ANALYSIS OF

FIISH AFTER

HRS. TOXICITY

OF Dilution Waste

Factor

(T) TYPE NO. FINAL OUTLET 2 HRS 6 HRS 24 HRS 48 HRS FACTOR

EXP. Water Water Tf

Tobe To test PH COD

Added Water PPM

To one (by

Part of Volume)

Waste

Water

(by volume)

02.03.12 3 1:4 4 ZEBRA 5 7.70 64 5 5 5 5 Tf =4

05.03.12 1 1:2 2 ZEBRA 5 7.45 64 5 5 5 5 Tf =2

08.03.12 3 1:4 4 ZEBRA 5 7.42 80 5 5 5 5 Tf =4

11.03.12 1 1:2 2 ZEBRA 5 7.17 80 5 5 5 5 Tf =2

14.03.12 3 1:4 4 ZEBRA 5 7.10 80 5 5 5 5 Tf =4

16.03.12 1 1:2 2 ZEBRA 5 7.08 96 5 5 5 5 Tf =2

19.03.12 1 1:2 2 ZEBRA 5 7.10 48 5 5 5 5 Tf =2

24.03.12 3 1:4 4 ZEBRA 5 7.00 48 5 5 5 5 Tf =4

27.03.12 1 1:2 2 ZEBRA 5 7.04 80 5 5 5 5 Tf =2

29.03.12 3 1:4 4 ZEBRA 5 7.17 82 5 5 5 5 Tf =4

Remark : All parameter passes as per requirement.

( Analyzed by ) Sr. Executive

(Approved by) HOD - QA

Page 51: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 49 of 73

TOXICITY FACTOR

MONTH: APRIL 2012

DATE Parts of Ratio of Dilution FISH FISH ANALYSIS OF

FIISH AFTER HRS.

TOXICITY

OF Dilution Waste

Factor

(T) TYPE NO. FINAL OUTLET 2 HRS 6 HRS 24 HRS 48 HRS FACTOR

EXP. Water Water Tf

Tobe To test PH COD

Added Water PPM

To one (by

Part of Volume)

Waste

Water

(by volume)

02.04.12 1 1:2 2 ZEBRA 5 7.40 80 5 5 5 5 Tf =2

05.04.12 1 1:2 2 ZEBRA 5 6.85 64 5 5 5 5 Tf =2

08.04.12 3 1:4 4 ZEBRA 5 7.20 80 5 5 5 5 Tf =4

11.04.12 3 1:4 4 ZEBRA 5 7.24 64 5 5 5 5 Tf =4

15.04.12 3 1:4 4 ZEBRA 5 7.60 64 5 5 5 5 Tf =4

18.04.12 1 1:2 2 ZEBRA 5 7.32 64 5 5 5 5 Tf =2

21.04.12 1 1:2 2 ZEBRA 5 6.92 96 5 5 5 5 Tf =2

25.04.12 3 1:4 4 ZEBRA 5 7.00 80 5 5 5 5 Tf =4

27.04.12 1 1:2 2 ZEBRA 5 7.05 80 5 5 5 5 Tf =2

29.04.12 3 1:4 4 ZEBRA 5 7.04 64 5 5 5 5 Tf =4

Remark : All parameter passes as per requirement.

( Analyzed by ) Sr. Executive

(Approved by) HOD - QA

Page 52: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 50 of 73

TOXICITY FACTOR

MONTH: MAY 2012

DATE Parts of Ratio of Dilution FISH FISH ANALYSIS OF FIISH AFTER HRS. TOXICITY

OF Dilution Waste

Factor

(T) TYPE NO. FINAL OUTLET 2 HRS 6 HRS 24 HRS 48 HRS FACTOR

EXP. Water Water Tf

Tobe To test PH COD

Added Water PPM

To one (by

Part of Volume)

Waste

Water

(by

volume)

02.05.12 1 1:2 2 ZEBRA 5 7.03 48 5 5 5 5 Tf =2

05.05.12 1 1:2 2 ZEBRA 5 7.03 32 5 5 5 5 Tf =2

07.05.12 1 1:2 2 ZEBRA 5 7.20 48 5 5 5 5 Tf =2

10.05.12 1 1:2 2 ZEBRA 5 6.80 32 5 5 5 5 Tf =2

13.05.12 1 1:2 2 ZEBRA 5 7.55 32 5 5 5 5 Tf =2

17.05.12 1 1:2 2 ZEBRA 5 7.17 32 5 5 5 5 Tf =2

19.05.12 1 1:2 2 ZEBRA 5 7.08 48 5 5 5 5 Tf =2

22.05.12 1 1:2 2 ZEBRA 5 7.20 48 5 5 5 5 Tf =2

25.05.12 1 1:2 2 ZEBRA 5 7.65 64 5 5 5 5 Tf =2

28.05.12 1 1:2 2 ZEBRA 5 7.88 64 5 5 5 5 Tf =2

Remark : All parameter passes as per requirement.

( Analyzed by ) Sr. Executive

(Approved by) HOD - QA

Page 53: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 51 of 73

TOXICITY FACTOR

MONTH: JUNE 2012

DATE Parts of Ratio of Dilution FISH FISH ANALYSIS OF FIISH AFTER HRS. TOXICITY

OF Dilution Waste Factor (T) TYPE NO. FINAL OUTLET 2 HRS 6 HRS 24 HRS 48 HRS FACTOR

EXP. Water Water Tf

Tobe To test PH COD

Added Water PPM

To one (by

Part of Volume)

Waste

Water

(by volume)

03.06.12 1 1:2 2 ZEBRA 5 7.80 64 5 5 5 5 Tf =2

06.06.12 1 1:2 2 ZEBRA 5 7.45 64 5 5 5 5 Tf =2

09.06.12 1 1:2 2 ZEBRA 5 7.34 64 5 5 5 5 Tf =2

11.06.12 1 1:2 2 ZEBRA 5 7.33 32 5 5 5 5 Tf =2

14.06.12 1 1:2 2 ZEBRA 5 7.42 64 5 5 5 5 Tf =2

17.06.12 1 1:2 2 ZEBRA 5 7.00 64 5 5 5 5 Tf =2

20.06.12 1 1:2 2 ZEBRA 5 7.25 64 5 5 5 5 Tf =2

23.06.12 1 1:2 2 ZEBRA 5 7.46 80 5 5 5 5 Tf =2

26.06.12 1 1:2 2 ZEBRA 5 7.52 64 5 5 5 5 Tf =2

28.06.12 1 1:2 2 ZEBRA 5 7.62 68 5 5 5 5 Tf =2

Remark : All parameter passes as per requirement.

( Analyzed by ) Sr. Executive

(Approved by) HOD - QA

Page 54: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 52 of 73

NOISE MONITORING REPORT

(OUR INTERNAL LAB ANALYSIS REPORTS)

SOUND LEVEL MONITORING REPORT : JAN-2012

SR.NO. LOCATIONS OF MONITORING SOUND LEVEL SOUND LEVEL

DAY TIME NIGHT TIME

Page 55: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 53 of 73

Day Time : 6 AM to 10 PM Day Time : 10 PM to 6 AM

Limit : 75 DBA Limit : 70 DBA

Date : 11.01.12 Date : 22.01.12

Time : 12.00 hrs Time : 02.00 hrs

1 MAIN GATE 63.1 45.3

2 WORK SHOP (ENGG.) 68.2 40.1

3 MANCOZEB SOLID (SPD CONTROL ROOM) Not in operation Not in operation

4 NEAR BOILER B5 Not in operation 67.5

5 NEAR BOILER B6 73.2 68.9

6 NEAR BOILER B7 72.5 69.1

7 TMP PLANT (Gr..FLOOR) 66.3 64.5

8 TMP PLANT ( UTILITY) 72.9 68.8

9 MCP PLANT (SCREW COMPRESSOR) 73.0 68.4

10 MCP PLANT (COMPRESSOR HOUSE) 73.9 68.8

11 MCP PLANT ( UTILITY KC 93 D&E) 71.9 68.1

12 AMMONIA PLANT( AIR COMPRESSOR) 72.8 Not in operation

13 MANCOZEB LIQ.( UTILITY) Not in operation Not in operation

14 DG SET- 125O KVA ( EDG-1001) 73.9 68.6

15 DG SET- 500 KVA ( EDG-1002) 73.2 68.0

Remarks : All Parameters passes as per requirements.

( Analyzed by ) (Approved by)

(Sr.Executive) (HOD -Q.A.)

SOUND LEVEL MONITORING REPORT : FEB-2012

SR.NO. LOCATIONS OF MONITORING SOUND LEVEL SOUND LEVEL

DAY TIME NIGHT TIME

Day Time : 6 AM to 10 PM Day Time : 10 PM to 6 AM

Limit : 75 DBA Limit : 70 DBA

Page 56: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 54 of 73

Date : 06.02.12 Date : 18.02.12

Time : 10.00 hrs Time : 01.00 hrs

1 MAIN GATE 68.3 41.6

2 WORK SHOP (ENGG.) 65.2 38.7

3 MANCOZEB SOLID (SPD CONTROL ROOM) Not in operation Not in operation

4 NEAR BOILER B5 Not in operation Not in operation

5 NEAR BOILER B6 Not in operation 68.2

6 NEAR BOILER B7 73.2 69.3

7 TMP PLANT (Gr..FLOOR) Not in operation 65.3

8 TMP PLANT ( UTILITY) Not in operation 68.1

9 MCP PLANT (SCREW COMPRESSOR) 72.8 68.2

10 MCP PLANT (COMPRESSOR HOUSE) 73.6 68.5

11 MCP PLANT ( UTILITY KC 93 D&E) 71.5 67.8

12 AMMONIA PLANT( AIR COMPRESSOR) Not in operation 66.9

13 MANCOZEB LIQ.( UTILITY) Not in operation Not in operation

14 DG SET- 125O KVA ( EDG-1001) 73.5 68.4

15 DG SET- 500 KVA ( EDG-1002) 73.7 69.0

Remarks : All Parameters passes as per requirements.

( Analyzed by ) (Approved by)

(Sr.Executive) (HOD -Q.A.)

SOUND LEVEL MONITORING REPORT : MAR-2012

SR.NO. LOCATIONS OF MONITORING SOUND LEVEL SOUND LEVEL

DAY TIME NIGHT TIME

Day Time : 6 AM to 10 PM Day Time : 10 PM to 6 AM

Limit : 75 DBA Limit : 70 DBA

Date : 08.03.12 Date : 03.03.12

Time : 15.00 hrs Time : 02.00 hrs

Page 57: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 55 of 73

1 MAIN GATE 65.4 39.8

2 WORK SHOP (ENGG.) 61.3 40.2

3 MANCOZEB SOLID (SPD CONTROL ROOM) Not in operation Not in operation

4 NEAR BOILER B5 Not in operation Not in operation

5 NEAR BOILER B6 73.1 69.2

6 NEAR BOILER B7 73.5 69.5

7 TMP PLANT (Gr..FLOOR) 65.2 64.1

8 TMP PLANT ( UTILITY) 71.6 68.5

9 MCP PLANT (SCREW COMPRESSOR) 73.0 68.7

10 MCP PLANT (COMPRESSOR HOUSE) 73.8 69.0

11 MCP PLANT ( UTILITY KC 93 D&E) 70.3 67.2

12 AMMONIA PLANT( AIR COMPRESSOR) 72.6 68.7

13 MANCOZEB LIQ.( UTILITY) Not in operation Not in operation

14 DG SET- 125O KVA ( EDG-1001) 73.9 68.5

15 DG SET- 500 KVA ( EDG-1002) 73.5 69.4

Remarks : All Parameters passes as per requirements.

( Analyzed by ) (Approved by)

(Sr.Executive) (HOD -Q.A.)

SOUND LEVEL MONITORING REPORT : APR-2012

SR.NO. LOCATIONS OF MONITORING SOUND LEVEL SOUND LEVEL

DAY TIME NIGHT TIME

Day Time : 6 AM to 10 PM Day Time : 10 PM to 6 AM

Limit : 75 DBA Limit : 70 DBA

Date : 15.04.12 Date : 03.04.12

Time : 16.00 hrs Time : 00.30 hrs

1 MAIN GATE 69.3 46.8

Page 58: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 56 of 73

2 WORK SHOP (ENGG.) 63.2 41.2

3 MANCOZEB SOLID (SPD CONTROL ROOM) Not in operation Not in operation

4 NEAR BOILER B5 Not in operation 68.8

5 NEAR BOILER B6 72.1 68.0

6 NEAR BOILER B7 72.5 68.4

7 TMP PLANT (Gr..FLOOR) 67.2 65.1

8 TMP PLANT ( UTILITY) 72.8 68.9

9 MCP PLANT (SCREW COMPRESSOR) Not in operation Not in operation

10 MCP PLANT (COMPRESSOR HOUSE) Not in operation Not in operation

11 MCP PLANT ( UTILITY KC 93 D&E) Not in operation Not in operation

12 AMMONIA PLANT( AIR COMPRESSOR) 73.1 67.3

13 MANCOZEB LIQ.( UTILITY) 70.9 66.9

14 DG SET- 125O KVA ( EDG-1001) 74.0 68.3

15 DG SET- 500 KVA ( EDG-1002) 73.2 69.1

Remarks : All Parameters passes as per requirements.

( Analyzed by ) (Approved by)

(Sr.Executive) (HOD -Q.A.)

SOUND LEVEL MONITORING REPORT : MAY-2012

SR.NO. LOCATIONS OF MONITORING SOUND LEVEL SOUND LEVEL

DAY TIME NIGHT TIME

Day Time : 6 AM to 10 PM Day Time : 10 PM to 6 AM

Limit : 75 DBA Limit : 70 DBA

Date : 23.05.12 Date : 03.05.12

Time : 10.00 hrs Time : 02.30 hrs

1 MAIN GATE 65.1 46.8

2 WORK SHOP (ENGG.) 58.9 41.2

3 MANCOZEB SOLID (SPD CONTROL ROOM) 71.8 Not in operation

4 NEAR BOILER B5 73.8 Not in operation

5 NEAR BOILER B6 72.9 68.8

Page 59: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 57 of 73

6 NEAR BOILER B7 73.2 69.1

7 TMP PLANT (Gr..FLOOR) 67.9 65.3

8 TMP PLANT ( UTILITY) 72.5 69.0

9 MCP PLANT (SCREW COMPRESSOR) 73.5 68.6

10 MCP PLANT (COMPRESSOR HOUSE) 71.8 68.2

11 MCP PLANT ( UTILITY KC 93 D&E) 71.5 68.5

12 AMMONIA PLANT( AIR COMPRESSOR) 72.9 69.1

13 MANCOZEB LIQ.( UTILITY) 70.6 66.3

14 DG SET- 125O KVA ( EDG-1001) 73.8 68.5

15 DG SET- 500 KVA ( EDG-1002) 73.1 68.8

Remarks : All Parameters passes as per requirements.

( Analyzed by ) (Approved by)

(Sr.Executive) (HOD -Q.A.)

SOUND LEVEL MONITORING REPORT : JUN-2012

SR.NO. LOCATIONS OF MONITORING SOUND LEVEL SOUND LEVEL

DAY TIME NIGHT TIME

Day Time : 6 AM to 10 PM Day Time : 10 PM to 6 AM

Limit : 75 DBA Limit : 70 DBA

Date : 18.06.12 Date : 22.06.12

Time : 12.00 hrs Time : 00.45 hrs

1 MAIN GATE 67.9 48.3

2 WORK SHOP (ENGG.) 62.1 45.2

3 MANCOZEB SOLID (SPD CONTROL ROOM) Not in operation Not in operation

4 NEAR BOILER B5 73.6 69.3

5 NEAR BOILER B6 74.0 68.9

6 NEAR BOILER B7 73.7 69.1

Page 60: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 58 of 73

7 TMP PLANT (Gr..FLOOR) 67.5 65.6

8 TMP PLANT ( UTILITY) 72.2 68.3

9 MCP PLANT (SCREW COMPRESSOR) 73.3 68.8

10 MCP PLANT (COMPRESSOR HOUSE) 72.1 68.5

11 MCP PLANT ( UTILITY KC 93 D&E) 71.8 67.7

12 AMMONIA PLANT( AIR COMPRESSOR) 72.6 68.8

13 MANCOZEB LIQ.( UTILITY) 69.5 67.3

14 DG SET- 125O KVA ( EDG-1001) 73.6 68.4

15 DG SET- 500 KVA ( EDG-1002) 72.9 68.7

Remarks : All Parameters passes as per requirements.

( Analyzed by ) (Approved by)

(Sr.Executive) (HOD -Q.A.)

Page 61: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 59 of 73

FUGITIVE EMISSIONS REPORT

(OUR INTERNAL LAB ANALYSIS REPORTS)

FUGITIVE EMISSIONS REPORT

Date : 08.01.2012

MONTH : JAN-2012 Time : 15.15 hrs

SR. AREA CHLORINE

CARBON

DISULPHIDE AMMONIA

NO. IDENTIFICATION TLV-0.5 PPM TLV-10 PPM TLV-25 PPM

1 MCP Plant

A. Near Chlorine Tonner Area BDL -- --

2 NH3 Plant

A. RVDF Gfloor Area -- -- 2.00

Page 62: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 60 of 73

B. High way side(Near boundry) -- -- BDL

C. Behind Cacl2 plant -- -- 2.00

3 Mancozeb Plant

A. During Cs2 Tanker unloading -- Plant under shut down --

B. Near ST-702A -- Plant under shut down --

C. Near D-14 Tank -- BDL --

D. Near P-14 Tank -- BDL --

E. Mancozeb Packing Area -- BDL --

F. Mancozeb Storage Godown -- BDL --

Remark : All parameter passes as per requirement.

( Analyzed by ) (Approved by)

(Sr.Executive) (HOD -Q.A.)

FUGITIVE EMISSIONS REPORT

Date : 08.02.2012

MONTH : FEB-2012 Time : 11.15 hrs

SR. AREA CHLORINE

CARBON

DISULPHIDE AMMONIA

NO. IDENTIFICATION TLV-0.5 PPM TLV-10 PPM TLV-25 PPM

1 MCP Plant

A. Near Chlorine Tonner Area BDL -- --

2 NH3 Plant

Page 63: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 61 of 73

A. RVDF Gfloor Area -- -- 3.00

B.

High way side(Near boundry) -- -- BDL

C. Behind Cacl2 plant -- -- 2.00

3 Mancozeb Plant

A. During Cs2 Tanker unloading -- Plant under shut down --

B. Near ST-702A -- Plant under shut down --

C. Near D-14 Tank -- Plant under shut down --

D. Near P-14 Tank -- Plant under shut down --

E. Mancozeb Packing Area -- BDL --

F. Mancozeb Storage Godown -- BDL --

Remark : All parameter passes as per requirement.

( Analyzed by ) (Approved by)

(Sr.Executive) (HOD -Q.A.)

FUGITIVE EMISSIONS REPORT

Date : 13.03.12

MONTH : MAR-2012 Time : 15.10 hrs

SR. AREA CHLORINE

CARBON

DISULPHIDE AMMONIA

NO. IDENTIFICATION TLV-0.5 PPM TLV-10 PPM TLV-25 PPM

1 MCP Plant

A. Near Chlorine Tonner Area BDL -- --

Page 64: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 62 of 73

2 NH3 Plant

A. RVDF Gfloor Area -- -- 8.00

B. High way side(Near boundry) -- -- 1.00

C. Behind Cacl2 plant -- -- 3.00

3 Mancozeb Plant

A. During Cs2 Tanker unloading -- Plant under shut down --

B. Near ST-702A -- Plant under shut down --

C. Near D-14 Tank -- Plant under shut down --

D. Near P-14 Tank -- Plant under shut down --

E. Mancozeb Packing Area -- BDL --

F. Mancozeb Storage Godown -- BDL --

Remark : All parameter passes as per requirement.

( Analyzed by ) (Approved by)

(Sr.Executive) (HOD -Q.A.)

FUGITIVE EMISSIONS REPORT

Date : 09.04.12

MONTH : APR-2012 Time : 11.30 hrs

SR. AREA CHLORINE

CARBON

DISULPHIDE AMMONIA

NO. IDENTIFICATION TLV-0.5 PPM TLV-10 PPM TLV-25 PPM

1 MCP Plant

A. Near Chlorine Tonner Area BDL -- --

Page 65: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 63 of 73

2 NH3 Plant

A. RVDF Gfloor Area -- -- 6.00

B. High way side(Near boundry) -- -- 1.00

C. Behind Cacl2 plant -- -- 4.00

3 Mancozeb Plant

A. During Cs2 Tanker unloading -- 1.00 --

B. Near ST-702A -- 1.00 --

C. Near D-14 Tank -- BDL --

D. Near P-14 Tank -- Plant under shut down --

E. Mancozeb Packing Area -- BDL --

F. Mancozeb Storage Godown -- BDL --

Remark : All parameter passes as per requirement.

( Analyzed by ) (Approved by)

(Sr.Executive) (HOD -Q.A.)

FUGITIVE EMISSIONS REPORT

Date : 13.05.12

MONTH : MAY-2012 Time : 14.30 HRS

SR. AREA CHLORINE

CARBON

DISULPHIDE AMMONIA

NO. IDENTIFICATION TLV-0.5 PPM TLV-10 PPM TLV-25 PPM

1 MCP Plant

Page 66: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 64 of 73

A. Near Chlorine Tonner Area BDL -- --

2 NH3 Plant

A.

RVDF Gfloor Area -- -- 5.00

B. High way side(Near boundry) -- -- BDL

C. Behind Cacl2 plant -- -- 3.00

3 Mancozeb Plant

A. During Cs2 Tanker unloading -- BDL --

B. Near ST-702A -- BDL --

C. Near D-14 Tank -- BDL --

D. Near P-14 Tank -- Plant under shut down --

E. Mancozeb Packing Area -- BDL --

F. Mancozeb Storage Godown -- BDL --

Remark : All parameter passes as per requirement.

( Analyzed by ) (Approved by)

(Sr.Executive) (HOD -Q.A.)

FUGITIVE EMISSIONS REPORT

Date : 10.06.2012

MONTH : JUN-2012 Time : 10.00 HRS

SR. AREA CHLORINE

CARBON

DISULPHIDE AMMONIA

NO. IDENTIFICATION TLV-0.5 PPM TLV-10 PPM TLV-25 PPM

Page 67: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 65 of 73

1 MCP Plant

A. Near Chlorine Tonner Area BDL -- --

2 NH3 Plant

A. RVDF Gfloor Area -- -- 5.00

B. High way side(Near boundry) -- -- BDL

C. Behind CaCl2 plant -- -- 3.00

3 Mancozeb Plant

A. During Cs2 Tanker unloading -- BDL --

B. Near ST-702A -- BDL --

C. Near D-14 Tank -- BDL --

D. Near P-14 Tank -- BDL --

E. Mancozeb Packing Area -- BDL --

F. Mancozeb Storage Godown -- BDL --

Remark : All parameter passes as per requirement.

( Analyzed by ) (Approved by)

(Sr.Executive) (HOD -Q.A.)

Page 68: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 66 of 73

VOC MONITORING DATA

Sub: Total VOC monitoring analysis data.

Date of Monotoring 13.02.2012

Time 14.00 to 15.15 hrs.

Location Different Plant & Locaton at UPL-1

Instrument used On line digital VOC monitoring Instrument of BEIL

Instrument operation Operated by Mr. Nitin (BEIL) / H.J.Patel (Q.A)

Sr.No. Location Parameter Findings

1 TMP Plant - Drum Filling Area Total VOC BDL

2 TMP Plant - Ground Floor area Total VOC BDL

3 TMP Plant - First Floor area Total VOC BDL

4 TMP Plant - Near Solvent storage tank Total VOC BDL

5 MCP Plant - Entrance, Near Drum filling area Total VOC BDL

6 MCP Plant - Ground floor , Centre Total VOC BDL

7 MCP Plant - First floor , Centre Total VOC BDL

8 MCP Plant - Second floor , Centre Total VOC BDL

9 ETP Plant - Near Aer-2 & Aer-3 area Total VOC BDL

10 ETP Plant - Haz.Drum storage area Total VOC BDL

11 Drum storage area, Behind ETP Plant Total VOC BDL

12 Raw material Drum storage area - Pond site Total VOC BDL

13 Pilot plant - Ground floor area Total VOC BDL

14 Pilot plant - First floor area Total VOC BDL

15 Pilot plant - Second floor area, Methanol reflux area Total VOC BDL

16 Pilot plant - Ground floor area, Methanol Feeding pump Total VOC BDL

17 FG storage godown Total VOC BDL

18 Drum storage area- Opposite FG godown, near parking Total VOC BDL

19 Main gate Total VOC BDL

20 On Road, Near Boiler Total VOC BDL

21 On Road, Between Antracol plant & Electrical Dept. Total VOC BDL

22 R & D Lab Total VOC BDL

23 Q.A.Lab Total VOC BDL

Page 69: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 67 of 73

PRODUCTION DETAILS

MONTH

MONOCROTOPHOS

TRI-METHYL

PHOSPHITE

MANCOZEB

ANTRACOL

DICHLOROVOS

TRI-ETHYL PHOSPHITE

Quantity in MT

JAN.’12 0 541.345 9.967 318.3 136 0.337

FEB' 12 146.05 652.75 3.323 2.51 115.08 0

MAR' 12 0 938.83 0 165.5 194.5 0

APR’ 12 203.029 781.094 0 0 151.98 0

MAY’ 12 592.25 1105.62 1.651 49 163.001 0

JUN’ 12 614.1 1058.1 174 137.6 142 0

MONTH

PRODUCTION (MT)

PHOSPHAMIDON

CARTAP

PENOXALINE

METABROMURON

IKI (Flocinamide)

JAN.’12 28.8 0 140 0

0

FEB' 12 36.78 0.45 15.6 0

0

MAR' 12 0 0 0 0

0

APR’ 12 0 0 0 0 0

MAY’ 12 0 0 0 0 1.149

JUN’ 12 0 0 0 0 11.688

Page 70: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 68 of 73

DETAILS OF WATER CONSUMPTION/ WASTE WATER DISPOSAL (INDUSTRIAL + DOMESTIC)

MONTH

WATER

CONSUMPTION

TREATED

EFFLUENT

DISCHARGE

QUANTITY TO

FETP,NCTL

KL/MONTH

JAN.’12 24219

6710

FEB' 12

21519

5404

MAR' 12

26332

5479

APR’ 12 29252

3879

MAY’ 12 29159

4069

JUN’ 12 21115

4678

TOTAL 151596 30219

KL/DAY 837.54 165.6

Page 71: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 69 of 73

DETAILS OF TREATMENT FOR HIGH TDS EFFLUENT WASTE WATER IN EVAPORATION SYSTEM

MONTH

FORCED EVAPORATION SYSTEM:

High TDS (NaCl) from Plants and from

RO system in KL

(Feed Qty)

REUSABLE PERMEATE

GENERATED

(RO Plant) –KL

JAN’ 12 856.0 251.25

FEB’ 12 930.7 371.25

MAR’ 12 809.4 429.75

APR’ 12 460.9 48.0

MAY’ 12 990.7 0.0

JUN’12 1022.0 175.0

TOTAL

5069.7 1275.25

DETAILS OF INCINERABLE WASTE - MT

MONTH

OPENING

STOCK (MT)

GENERATION

CONTAMINATED

PLASTIC &

OTHER WASTE

DISPOSAL

(Total Sent

to BEIL)

CLOSING

STOCK

ORGANIC AQUEOUS

JAN’ 12 7.84 85.39 271.1 9.52

369.51 4.34

FEB’ 12 4.34 44.79 117.74 2.25 159.78 9.34

MAR’ 12 9.34 13.99 90.83 3.4 113.62 3.94

APR’ 12 3.94 31.09 48.08 0.46 79.63 3.94

MAY’ 12

3.94

55.41

7.23

3.57

66.21

3.94 4.98

Page 72: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 70 of 73

JUN’12 3.94 27.99 0 2.27 29.22

HAZARDOUS WASTE TO LANDFILL DETAILS

MONTH

OPENING

STOCK

GENERATION

SOLID

DISPOSAL

TO BEIL

(ETP

SLUDE +

SALT)*

CLOSING

STOCK

ETP

SALT

TOTAL

(ETP

SLUDGE+

SALT)

ALL FIGURES IN MT

JAN’ 12 10.44 18.99 68 86.99 88.74 8.69

FEB’ 12 8.69 20.2 59.22 79.42 84.42 3.69

MAR’ 12 3.69 14.12 80.93 95.05 95.05 3.69

APR’ 12 3.69 12.26 76.4 88.66 88.66 3.69

MAY’ 12 3.69 29.52 139.42 168.94 168.94 3.69

JUN’12 3.69 21.50 139.45 160.95 159.45 5.19

TOTAL LANDFILL WASTE DETAILS –MT

MONTH

(ETP SLUDGE +

SALT)*

DCP

SLUDGE**

NON-RECYCLABLE

PLASTIC

WASTE/INSULATION

WASTE

TOTAL

JAN’ 12 88.74 171.75 4.89 265.38 FEB’ 12 84.42 122.53 4.56 211.51 MAR’ 12 95.05 310.96 10.75 416.76 APR’ 12 88.66 122.5 7.26 218.42 MAY’ 12 168.94 154.08 5.43 328.45 JUN’ 12 159.45 178.24 9.86 347.55

Page 73: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 71 of 73

DETAILS OF DCP SLUDGE (BY-PRODUCT / SOLD AS SOIL CONDITIONER)

MONTH

OPENING

STOCK (MT)

GENERATION

(MT)

DISPATCH (MT)

CLOSING

STOCK

(MT)

PARTY*

BEIL**

JAN’ 12 0.246 300 110.46 171.75 18.036 FEB’ 12 18.036 300 76.37 122.53 119.14 MAR’ 12 119.136 555 260.21 310.96 102.97 APR’ 12 102.966 955* 752.74 122.5 182.726 MAY’ 12 182.726 420.12 243.62 154.08 205.146 JUN’ 12 205.146 470.00 423.18 178.24 73.726

* Clarifier, Pit cleaned & accumulated sludge taken out resulted in higher generation for the month of April

(*) Sold as Soil Conditioner to end user M/S U S Fertilizer (Dhan Varsha Fertilizer), Behind High School, At post

Poicha, Vaya Nandesari Chokadi, Dist : Vadodara, Gujarat

(2) Ambic Organic ,Plot No 17,Nalia Kharkhana compound,Dhulia Charrasta ,At and post Isorli,

Ta : Bardoli,Dist –Surat, Gujarat

Page 74: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 72 of 73

Annexure-1:

Consent to Establish (NOC) for Product Mix Change (No. GPCB/BRCH-CCA-158(7)/ ID-15833/106214) and

applied for consent to operate (CC&A) on 17.03.2012.

PRODUCT DETAILS – Existing and After product mix change

Sr. No.

Existing Quantity As per Consent After Product Mix Change

Existing Products Capacity, (MT/M)

Proposed Products

Capacity, (MT/M)

Pesticide products

1 Penoxaline 150 Penoxaline .

NIL,

2 Phosphamidon 150 Phosphamidon NIL

3 Cartap 50 Cartap NIL

4 Metabromuron 50 Metabromuron NIL

5 Mancozeb OR Antracol (Combine capacity)

750 OR 750

Mancozeb OR Antracol OR Maneb OR Zineb OR Ziram (combined capacity)

650 OR 650 OR 650 OR 650 OR 650

6 Monocrotophos 270 Monocrotophos OR Dichlorovos (DDVP) (combined)

760 OR 760 7

Dichlorovos (DDVP)

200

8 -- -- Flonicamide (IK) 50

9 -- --

Tebuconazole OR Fen 04 OR Sulfosulfuran (Combined

60 OR 60

OR 60

Page 75: NV - upl-ltd.com

Compliance Report for the conditions in the Environmental Clearance # J.11011/117/2002-IA.II dated 17.07.2003

issued by Ministry of Environment and Forests, New Delhi

for expansion of pesticide unit by United Phosphorus Ltd., Unit # 1, Ankleshwar, Gujarat

Period Jan-Jun 2012

Page 73 of 73

capacity)

TOTAL 1620 TOTAL 1520

Intermediates products –no change –MT/M

10 Tri Methyl

Phosphite /Tri Ethyl Phosphite

1120/1000 Tri Methyl

Phosphite /Tri Ethyl Phosphite

1120/1000

By-products details –MT/M

1 Fuesed/Anhydrous

Calcium Chloride

1800 Fused/Anhydrous

Calcium Chloride

1800

2 Di- Calcium

phosphate sludge

600 Di- Calcium

phosphate sludge

600

3 An hydrous

Ammonia

425 An hydrous

Ammonia

425

4 30% Calcium

Chloride

5000 30% Calcium

Chloride

5000

5 Methyl Chloride 131 Methyl Chloride 175

6 Ammonium

Chloride

873 Ammonium

Chloride 873

7

Hydrated sodium

Sulphate(Na2SO4,H

2O)

737 Hydrated sodium

Sulphate(Na2SO4,H

2O) 737

8 30% HCL 138 30% HCL 138

9 Sodium Sulphite

liquid (Na2SO3)

298 Sodium Sulphite

liquid (Na2SO3) NIL

10 Sodium Bromide

Liquid

95 Sodium Bromide

Liquid NIL

11 Sodium

Sulphate(100%)

31 Sodium

Sulphate(100%) 31

12 Ethanol Nil Ethanol 11.5

13 NaSH NIL NaSH 3.5

14 Sodium Bi Sulpite NIL Sodium Bi Sulpite 9

15 MeOH NIL MeOH 11