observing changes to equilibrium forestville central school regents chemistry

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Observing Observing Changes to Changes to Equilibrium Equilibrium Forestville Central Forestville Central School School Regents Chemistry Regents Chemistry

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Page 1: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

Observing Observing Changes to Changes to EquilibriumEquilibrium

Forestville Central SchoolForestville Central School

Regents ChemistryRegents Chemistry

Page 2: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

IntroductionIntroduction In this experiment you will be introduced to In this experiment you will be introduced to

chemical equilibrium. chemical equilibrium. You will then be presented with a number of You will then be presented with a number of

systems at equilibrium and will be asked to systems at equilibrium and will be asked to "stress" these systems by changing the "stress" these systems by changing the concentration of one of the reactants or products concentration of one of the reactants or products or by changing the temperature of the system. or by changing the temperature of the system.

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Page 3: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

ExperimentsExperiments Complete each one of the experiments below and Complete each one of the experiments below and

answer the questions on your worksheet. answer the questions on your worksheet. Click Click on the pictures to guide you.on the pictures to guide you.

Cobalt System

Ammonium System

Iron Thiocyanate System

Chromate System

Copper SulfateSystem

Page 4: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

Cobalt SystemCobalt System

NOTES: - Silver ions react with chloride ions to form the insoluble compound silver chloride.

1)

2)

3)

4)

5) Hint: read the note belowCoCl4

2-

Hint: Think aboutThe Cl- ion

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Page 5: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

Cobalt SystemCobalt System

1) Answer:1) Answer: Equilibrium shifts to the leftEquilibrium shifts to the left

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Page 6: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

Cobalt SystemCobalt System

2) Answer:2) Answer: Equilibrium shifts to the rightEquilibrium shifts to the right

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Page 7: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

Cobalt SystemCobalt System

3) Answer:3) Answer: Equilibrium shifts to the RightEquilibrium shifts to the Right

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Page 8: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

Cobalt SystemCobalt System

4) Answer:4) Answer: Equilibrium shifts to the leftEquilibrium shifts to the left

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Page 9: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

Cobalt SystemCobalt System

5) Answer:5) Answer: Equilibrium shifts to the right due to Equilibrium shifts to the right due to

the precipitation out of the Clthe precipitation out of the Cl-- ions in ions in AgCl.AgCl.

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Page 10: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

Ammonium SystemAmmonium System

NOTES: - The purplish color is due to phenolphthalein. The darker the purple color, the larger the hydroxide ion concentration in solution.

1)

2)

pink Colorless

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Page 11: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

Ammonium SystemAmmonium System

1) Answer:1) Answer: Equilibrium shifts to the right (see Equilibrium shifts to the right (see

notes regarding color)notes regarding color)

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Page 12: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

Ammonium SystemAmmonium System

2) Answer:2) Answer: Increase in temperature shifts the Increase in temperature shifts the

equilibrium to the RIGHTequilibrium to the RIGHT

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Page 13: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

Iron Thiocyanate Iron Thiocyanate

NOTES: - the HPO4-2 ion forms a complex with the Fe+3 ion.

1)

2)

3)

4)

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Hint: See notes

Page 14: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

1) Answer:1) Answer: Equilibrium shifts to the RightEquilibrium shifts to the Right

Iron Thiocyanate Iron Thiocyanate

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Page 15: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

2) Answer:2) Answer: Equilibrium shifts to the rightEquilibrium shifts to the right

Iron Thiocyanate Iron Thiocyanate

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Page 16: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

3) Answer3) Answer Equilibrium shifts to the leftEquilibrium shifts to the left

Iron Thiocyanate Iron Thiocyanate

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Page 17: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

4) Answer4) Answer Due to the removal of FeDue to the removal of Fe+3+3, equilibrium , equilibrium

shifts to the leftshifts to the left

Iron Thiocyanate Iron Thiocyanate

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Page 18: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

Chromate SystemChromate System

Na2CrO4

1)

Na2Cr2O7

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2)

Page 19: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

Chromate SystemChromate System

1) Answer:1) Answer: Equilibrium shifts to the rightEquilibrium shifts to the right

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Page 20: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

Chromate SystemChromate System

2) Answer:2) Answer: Equilibrium shifts to the leftEquilibrium shifts to the left

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Page 21: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

Copper Sulfate SystemCopper Sulfate System

Page 22: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

Answer:Answer: Equilibrium shifts to the right as water Equilibrium shifts to the right as water

is heated offis heated off

Copper Sulfate SystemCopper Sulfate System

Question:What if you add water Back to the dish?

Page 23: Observing Changes to Equilibrium Forestville Central School Regents Chemistry

Copper Sulfate SystemCopper Sulfate System

Answer:Answer: Equilibrium shifts back to the left as Equilibrium shifts back to the left as

water is added back to the unhydrated water is added back to the unhydrated crystalcrystal

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