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    The University of Western Ontario Department of Chemical & Biochemical Engineering

    Oil refining and Processing

    CBE 432b

    Jan. 2010

    Oil History and Origin

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    Crude Oil History

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    q For the first t ime, it was used around 4000B.C.as

    q caulking for ships

    qadhesive to secure weapon handles

    q Egyptian used it for embalming and to heldframed pyramids together

    q The Roman orator Cicero carr ied a crude-oillamp

    q Senecas and Iroquois used it for bodypainting and fireworks.

    q In 18th century, people who dug wells to findwater became disappointed when they struckoil

    Crude Oil History

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    q Kerosene lamp, invented in 1854, createdthe first large scale demand for petroleum.

    The first successful well was dril led by Col.

    Edwin Drake in 1859.q In early 20th century (1920s), the real valueof crude oil was recognized as an energy

    source

    q Due to the increasing demand for energyand other by products from crude oil, it is

    considered as an strategic industryinfluencing many political decisions all over

    the world

    Crude Oil History

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    http://www.oilhistory.com/pages/drake/derrick.html

    Crude Oil History

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    Spindletop, Texas 1901The fi rst major oil discovery

    q The Cerro Azul # 4flow ed 850, 000barrels of oil betw eenFebruary 15-19before it w as cappedand cont rolled.

    q The w ell producedover 57 mill ionbarrels in it s lifet ime.

    Crude Oil History

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    Origin of crude oil

    q Crude oil moves through the pores of the source rockupon formation and its properties may change with time.q There are many theories about the origin of crude oil,however it is generally accepted that:

    Crude oil, or petroleum, is derived from the remains ofprehistoric plants and animals matter.

    Fish Fossil Plant fossil

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    The Formation of Oil

    Millions of years ago, rains washedprehistoric plant and animal

    remains into the seas along with

    sand and silt, and layer upon layerpiled up on the sea bottom. Theselayers were compressed under the

    weight of these sediments, and theincreasing pressure and

    temperature changed the mud,sand and silt into rock and the

    organic matter into petroleum. Thisrock is known as source rock.

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    The Formation of Oil

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    Since oil and gas are less densecompared to water, they float on top of

    water. Oil and gas that formed in thesource rock deep within the earth

    floated up through tiny pore spaces inthe rock.

    The Formation of Oil

    Some seeped out at the surface of the earth.

    Some was trapped by dense, non-porous rock,called shale. These underground traps of oil andgas are called reservoirs. Reservoirs contain

    porous rocks, which allow fluids to flow throughthe pore spaces.

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    Generation Migrat ionAccumulation

    andPreservation

    Processes:

    Elements: SourceRock

    Reservoirand Seal

    Trap Must Be Available Before/ Duri ngMigration

    The Formation of Oil

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    Oil f ills the pore-space betw een grains

    Reservoir : Oil is st ored in reservoir rock

    The Formation of Oil

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    Porosity = 26% , permeabili ty = 2434 md

    Reservoir Rock

    Sand

    Pore

    space

    The Formation of Oil

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    Reservoir Rock

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    qIf migrating oil encountereda reservoir rock it

    preferentially f lowed through

    this conduit

    qIf it led straight to the

    surface, the petroleumescaped

    qIf the reservoir was folded

    or faulted, the oil may havebeen trapped.

    Oil Migrat ion

    oil & gas seeps

    trappedoil & gas

    Reservo

    ir

    Rock

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    Ant iclines are folds in t he eart h

    GasGas

    OilOil

    WaterWater

    Cap rock

    Reservoirrock

    Oil Reservoir

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    Oil and gas migrates from source rock,through reservoir r ock t o trap

    Oil Reservoir

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    Spill PointSpill Point

    Seal Rock(Mudstone)Reservoir Rock

    (Sandstone)Migration fromKitchen

    Early Generation

    Late Generation

    Gas displaces

    all oil

    Gas beginning

    to displace oil

    Displaced oilaccumulates

    Pet roleum system, A Dynamic Ent it y

    Oil Reservoir

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    Huston Geological society, Academic Liaison committee

    Oil and Gas Reservoirs

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    Largest North American field before Prudhoe BayMore than 5 bil lion barrels recoverable, East Texas OilField (1930)

    Huston Geological society, Academic Liaison committee

    Oil and Gas Reservoirs

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    Oil and Gas Reservoirs

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    Reservoir rock sampling

    When oil wells are drilled, sometimes a coringtool is used to obtain samples of the reservoir

    rock for study. Geologists study these core

    samples to learn about the reservoir and helpdecide how to produce the oil and gasefficiently.

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    Reservoir rock sampling

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    Reservoir rock sampling

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    Oil Seepage

    Typical large-scale onshore oil

    seep, Qaiyarah, Iraq

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    Gas (and oil-coated) bubble plume in watercolumn (right), Surfacingoil pancakes(gas

    bubbles burst and lost to atmosphere)

    Oil Seepage

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    Titas seepage, BGFCL estimates, Bangladesh

    07.27.2009, www.energybangla.com

    Gas Seepage