old.bartonandloguidice.comold.bartonandloguidice.com/portals/22/assets/ontario county deis... ·...

Upstate Laboratories, Inc. 6034 Corporate Drive East Syracuse, New York 13057-1017

Sample Data Summary Package Case Narrative, Summary of Test Results, Summary of QC Results and Chain of Custody Documentation Volume 1 of 4

SDG No. CAS105

Project:

Ontario Co. LF Phase III (Cont. Wells) Ontario, New York

Prepared for:

Ms. Carta Canjar Casella c/o Ontario Co. Recycling & LF Mgmt. 1879 State Route 5 and 20 Stanley, New York 14561

Samples Collected:

July 9, 2009

New York Lab Code 10170

-1

NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION

Upstate Laboratories, Inc 6034 Corporate Drive East Syracuse, New York 13057

SAMPLE IDENTIFICATION AND ANALYTICAL REQUIREMENT SUMMARY

Customer Sample Code

MW-28 MW-29 MW-29 MS MW-29 MSD MW-29 DUPE DUPE HOLDING BLANK ULI TRIP BLANK

Laboratory Sample Code

U0907195-001 U0907195-002

U0907195-002MS U0907195-002MSD U0907195-002DP

U0907195-003 U0907195-004 U0907195-005

Analytical Requirements VOA

GC/MS Method

# 8260 8260 8260 8260

-8260 8260 8260

BNA GC/MS Method

# --------

Pest PCBs Method

# --------

Herb GC/MS Method

# . -------

Metals

Baseline + Dissolved Baseline + Dissolved Baseline + Dissolved

_ Baseline + Dissolved Baseline + Dissolved

_ «

Wet Chemistry and

Other

Baseline Baseline Baseline

Baseline Baseline

_. _.

B-212

-2-

Narrative

1.0 Summary This report presents the sample test results and quality control results for two water locations collected from the Ontario Co. LF Phase III (Cont. Wells) project, Ontario, New York. The samples were analyzed for the parameters listed in Section 3.0, below.

This report is divided into two packages and four volumes. The Sample Data Summary Package (Volume 1) presents a summary ofthe test results and quality control data. This abbreviated format is useful to engineers and environmental scientists. The Sample Data Package (Volumes 2-4) is a comprehensive report containing instrument raw data. It is formatted for validation by an independent third party.

2.0 Chain of Custody The samples were collected by Barton and Loguidice, PC personnel on July 9, 2009, and were delivered to Upstate Laboratories, Inc., Syracuse, New York. The Chain of Custody Documentation is presented in Volumes 1 and 2.

3.0 Methodology The analyses were performed using test methods developed by the USEPA. The specific method numbers are:

Parameter Volatile Organics

Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Selenium Potassium Silver Sodium Thallium Vanadium Zinc

Method 8260

200.7 200.7 200.7 200.7 200.7 200.7 200.7 200.7 200.7 200.7 200.7 200.7 200.7 200.7 200.7 245.2 200.7 200.7 200.7 200.7 200.7 200.7 200.7 200.7

Reference (1)

(1) (1) (1) 0) (1) (1) (1) (1) (1) (1) (1) (1) (1) (1) (1) (1) (1) (1) (1) (1) (1) (1) 0) 0)

The total number of pages in this Data Package is:

- 3 -

Total Alkalinity Ammonia-Nitrogen BOD Bromide Chloride COD Color Cyanide Hexavalent Chromium Nitrate-Nitrogen Phenols Sulfate TDS TKN TOC

310.2 350.1 405.1 300.1 325.2 410.4 110.2 335.4 SM3500 353.2 420.4 375.4 160.1 351.2 415.1

(1) (1) 0) (1) (1) (1) (1) (1) (1) (1) (1) (1) (1) (1) (1)

(1) New York State Department of Environmental Conservation Analytical Services Protocol (ASP), 7/05 revision.

4.0 Quality Control Quality control data includes method blanks, reference samples, matrix spikes, matrix spike duplicates, duplicates and surrogate recoveries. For wet chemistry, the association of QC data with sample data is made through the use ofthe "File No." found on both the final report pages and the QC summary pages.

5.0 Internal Validation The following observations are offered:

Volatiles by GC/MS Holding Time : Criteria were satisfied.

Calibration

Method Blanks

MSB

MS/MSD

Surrogates

Inter. Stds.

: Several target compounds were manually integrated in the IC and CC. All other criteria were satisfied.

: Criteria were satisfied.





Trace Metals (Total and Dissolved) and Cyanides Data Holding Time : Criteria were satisfied.

Calibration

Method Blanks

: The ICV recovery for Potassium was slightly below QC acceptance limits. The CCV1 and CCV2 recoveries for Arsenic and Selenium were above QC acceptance limits. The initial CRDL Standard recovery for Selenium was above QC acceptance limits. The final CRDL Standard recovery for Arsenic was above QC acceptance limits. All other criteria were satisfied.

: Antimony, Arsenic and Selenium were detected in several ICBs and CCBs for several analytical sequences. All associated samples ran ND for Antimony, Arsenic and Selenium; thus the data should be considered valid. All other criteria were satisfied.

- 4 -

Reference Sample

Matrix Spikes

Duplicates

: The LCS recoveries for Antimony and Arsenic were above QC acceptance limits. All associated samples ran ND for Antimony, Arsenic and Selenium; thus the data should be considered valid. All other criteria were satisfied.

: The MS recoveries for Antimony and Arsenic were above QC acceptance limits for the MS performed on sample location MW-29. The MS recoveries for Antimony, Arsenic and Silver were outside QC acceptance limits for the MS performed on sample location MW-29DISS. All other criteria were satisfied.

: The Duplicate %RPD for Thallium was outside QC acceptance limits for the Duplicate performed on sample location MW-29DISS. The concentration of Thallium in sample location MW-29DISS was less than 5X the PQL; therefore, the data should be considered valid. The Duplicate %RPDs for Antimony and Thallium were outside QC acceptance limits for the Duplicate performed on sample location MW-29. The concentrations of Antimony and Thallium were less than 5X the PQL; therefore, the data should be considered valid. All other criteria were satisfied.

Wet Chemistry Data

Holding Time

Calibration

Method Blanks

Reference Samples

Matrix Spikes

Duplicates

Other


: The CCV12 and CCV22 recoveries for Total Alkalinity were above QC acceptance limits for analytical sequence R43750. The CCV3 recovery for COD was slightly below QC acceptance limits for analytical sequence R44133. The CCV5 recovery for TOC was above QC acceptance limits for analytical sequence R43902. All other criteria were satisfied.

: Total Phenols were detected at a concentration above the CRDL in CCB10 for analytical sequence R43939. Ammonia was detected at a concentration above the CRDL in CCB1 for analytical sequence R43900. All other criteria were satisfied.




: Sample location MW-2 8 and DUPE were reanalyzed for Total Alkalinity in analytical sequence R43751 within ASP holding time due to inconsistent sample results when compared with past data.

I certify that this data package is in compliance with the terms and conditions ofthe Contract, both technically and for completeness, for other than the conditions detailed above. Release ofthe data contained in this hardcopy data package and/or in the computer-readable data submitted on floppy diskette has been authorized by the Laboratory Manager or his designee, as verified by the following signature.

APPr°ved (^7>V57^Z gTS/rtfa^

Anthony J. Scala, Director

QCCAS105B

- 5 -

Sample Data

Upstate Laboratories, Inc.

- 6 -

\tt~\l 1A

A-rii rr /->c_/-> A M I / - » O A M A I » m i n <-.A-»-A ».. • •_.•_._>. »WLMI !_.__ V_T\V3A.INIUO rtlNrtLTDIO UM 1 A O M t t 1

Lab Name: Upstate Labs Inc. Contract: Casella

Lab Code: 10170

Mat

San

Lev

%lv

GC

Soil

Case No.: SAS No.: SDC

rix: (soil/water) WATER Lab Sample ID: IJ

iple wt/vol: 5.0 (g/ml) ML Lab File ID: C.

el: (low/med) LOW Date Received: 7,

loisture: not dec. Date Anal vzed: 7/

Column: RTX-VO

Extract Volume:

CAS NO.

74-87-3 75-1-4 74-83-9 75-00-3 75-69-4 67-64-1 75-35-4 74-88-4 75-15-0 75-09-2 107-13-1 156-60-5 75-34-33 108-5-4 78-93-3 156-59-2 67-66-3 74-97-5 71-55-6 56-23-5 71-43-2 107-06-2 97-01-6 78-87-5 75-27-4 74-95-3 108-10-1 10061-1-5 108-88-3 10061-2-6 79-00-5 591-78-6 127-18-4 124-48-1 106-93-4 108-90-7 630-20-6 100-41-4 108-38-3

EPA SAMPLE NO.

MW-28

3 No.: CAS105

0907195-001H

29000.D

9/2009

18/2009

ID: 0.53 (mm) Dilution Factor: i.n

(uL) Soil Aliauot Volume: .ul

CONCENTRATION UNITS: COMPOUND (ug/L or ug/Kg) UG/L Q

Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane Acetone 1,1-Dichloroethene lodomethane Carbon Disulfide Methylene Chloride Acrylonitrile trans-1,2-Dichloroethene 1,1-Dichloroethane Vinyl Acetate 2-Butanone cis-1,2-Dichloroethene Chloroform Bromochloromethane 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene 1,2-Dichloropropane Bromodichloromethane Dibromomethane 4-Methyl-2-pentanone cis-1,3-Dichloroprooene Toluene trans-1,3-Dichloroprooene 1,1,2-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene 1,1,1,2-Tetrachloroethane Ethylbenzene m,p-Xylene

FORM I VOA

- 7 -

5 5 5 5 5

10 5 5 5 5

100 5 5

50 10 5 5 5 5 5 5 5 5 5 5 5

10 5 5 5 5

10 5 5 5 5 5 5 5

U u u u u u u u u u u u u

_**r u u u u u u u u u u u u u u u u u u

J^" u u u u u u

3/9

._

u

0

ULT~

M

Lab Name: Upstate Labs Inc.

Lab Code: 10170 Case No.:

Matrix: (soil/water) WATER

Sample wt/vol:

Level: (low/med)

% Moisture: not dec.

GC Column: RTX-VO ID: 0.53

1A

VOLATILE ORGANICS ANALYSIS DATA SHEET

Contract: Casella

EPA SAMPLE NO.

MW-28

SAS No.: SDG No.: CAS105

5.0

LOW

(g/ml) ML

Lab Sample ID: U0907195-001H

Lab File ID: C29000.D

Date Received: 7/9/2009

Soil Extract Volume:

CAS NO.

95-47-6 100-42-5 75-25-2 79-34-5 96-18-4 541-73-1 106-46-7 95-50-1 96-12-8

(mm)

Date Analyzed: 7/18/2009

Dilution Factor: 1.0

(uL)

COMPOUND

Soil Aliquot Volume:

CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L

o-Xylene Styrene Bromoform 1,1,2,2-Tetrachloroethane 1,2,3-Trichloropropane 1,3-Dichlor obenzene 1,4-Dichlor obenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-chloro-propane

_5_ 5

10

Q

U U U U U U U U U

(uL)

FORM IVOA

- 8 -

3/90

1E VOLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDS EPA SAMPLE NO.

Lab Name:

Lab Code:

Upstate Labs Inc.

10170

Contract: Casella MW-28

Case No.: SAS No.:

5.0

LOW


Sample wt/vol:

Level: (low/med)




SDG No.: CAS105

(g/ml) ML




(mm)



(uL)

Number TICs found:



(uL)

CAS NO. COMPOUND NAME RT EST. CONC. Q

FORM I VOA-TIC

- 9 -

3/90

U.S. EPA CLP

CLIENT SAMP ID INORGANIC ANALYSIS DATA SHEET

Lab Name: Upstate Laboratories, Inc.

Lab Code: 10170 Case No.

Matrix (soil/water): WATER

Level (low/med): LOW

% Solids: 0.0

MW-28

Contract: 448355


Lab Sample ID: U0907195-001


Concentration Units (ug/L or mg/kg dry weight): UG/L

A

CAS No.

7429-90-5 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-42-8 7440-43-9 7440-70-2 7440-47-3 7440-48-4 7440-50-8 57-12-5 471-34-1 7439-89-6 7439-92-1 7439-95-4 7439-96-5 7439-97-6 7440-02-0 7440-09-7 7782-49-2 7440-22-4 7440-23-5 7440-28-0 7440-62-2 7440-66-6

Analyte

Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Cyanide Hardness, T Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

Concentration

4730 ss^iiMiSpBisJ

10.0 137 3.0 500 5.0

225000 10.0 20.0 11.9 10.0

790000 5280 3.0

55500 785

0.20 30.0 4080 5.0 10.0

50700 20.9 30.0 102

C

till -B.

U U U

U U __§*

u

u

u u

X u u

u

Q

. .„__ _ ^9__f-

N

**___

E se**

N

M

P P P P P P P P P P P C P P P P P

cv p p p p p p p p

Color Before: BROWN

Color After: YELLOW

Clarity Before:

Clarity After:

T~

sy™

•J

Texture:

Artifacts: YES

Comments: Light Brown Sediment /y[<

FORM I •

- 1 0 -IN I L M 0 4 . 1

U.S. EPA - CLP

CLIENT SAMP ID INORGANIC ANALYSIS DATA SHEET





% Solids: 0.0

MW-28[Diss]

Contract: 448355





CAS No.

7429-90-5 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-43-9 7440-70-2 7440-47-3 7440-48-4 7440-50-8 7439-89-6 7439-92-1 7439-95-4 7439-96-5 7439-97-6 7440-02-0 7440-09-7 7782-49-2 7440-22-4 7440-23-5 7440-28-0 7440-62-2 7440-66-6

Analyte

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

Concentration

4150 30.0 10.0 134 3.0 5.0

221000 10.0 20.0 12.6 5250 3.0

55100 785 0.20 30.0 3810 5.0 10.0

50600 18.2 30.0 103

C

U U «***-

U

u

u u

^Pt&£8

u

D U

X u

XT

u

Q

N* N

E

E

#>_-* jae"

N

M

P P P P P P P P P P P P P P CV P P P P P P P P

Color Before:

Color After: COLORLESS

COLORLESS

Clarity Before:

Clarity After:

cl*a|«^i^"

Texture:

Artifacts:

Comments: /f" "j

FORM I - IN

-11-ILM04.1

Upstate Laboratories, Inc. Analytical Report Date: 12-Aug-09

CLIENT: Casella

Lab Order: U0907195

Proj eet: Ontario Co. LF Phase III (Cont. Wells)

Lab ID: U0907195-001

Analyses Result

COLOR Color

RESIDUE, DISSOLVED (TDS) Residue, Dissolved (TDS)

6.00

940

ALKALINITY ON AQUEOUS SAMPLES BY LACHAT Alkalinity, Total (As CaC03) 570

CHLORIDE WATERS BY LACHAT Chloride 71.1

NITROGEN, AMMONIA (AS NH3 BY LACHAT) Nitrogen, Ammonia (As NH3) ND

NITROGEN, TOTAL KJELDAHL (TKN) BY LACHAT Nitrogen, Kjeldahl, Total 0.718

NITROGEN, NITRATE (AS N) Nitrogen, Nitrate (as N)

SULFATE Sulfate

ND

94.2

BIOCHEMICAL OXYGEN DEMAND (5 DAY BOD) Biochemical Oxygen Demand ND

CHEMICAL OXYGEN DEMAND (COD) Chemical Oxygen Demand 28 T

•mm

TOTAL ORGANIC CARBON (TOC) Organic Carbon, Total 3.9

PHENOLICS, TOTAL REC. FOR WATERS Phenolics, Total Recoverable ND

HEXAVALENT CHROMIUM BY ASP 2005 Hexavalent chromium ND

Client Sample ID: MW-28

Collection Date: 7/9/2009 1:03:00 PM

Matrix: GROUNDWATER

Limit Qual Units DF

INORGANIC ANIONS BY IC FOR WATERS Bromide ND

NOTES: The reporting limits were raised due to matrix interference.

2.0

5.00

25

100

1.00

0.500

0.500

0.200

10.0

4.00

20

3.0

0.005

0.010

E300.1 mg/L

E110.2 UNITS

E160.1 mg/L

E310.2 mg/LCaC03

E325.2 mg/L

E350.1 mg/L

E351.2 mg/L

E353.2 mg/L

E375.4 mg/L

E405.1 mg/L

E410.4 mg/L

E415.1 mg/L

E420.4 mg/L

SM3500 mg/L

Date Analyzed

Analyst: NJS 10 7/13/2009

Analyst: NKA 1 7/9/2009 3:45:00 PM

Analyst: KAM 1 7/14/2009

Analyst: VAW 10 7/11/2009


Analyst: BY 1 7/16/2009

Analyst: KAM 1 7/14/2009

Analyst: VAW 1 7/10/2009 9:45:00 AM

Analyst: KEL 2 7/23/2009

Analyst: KAF 1 7/10/2009 7:30:00 AM

Analyst: KAF 1 7/23/2009


(E420.4) Analyst: BY 1 7/17/2009

Analyst: KAF 1 7/10/2009 9:00:00 AM

Approved By:

Qualifiers: * Low Level

B Analyte detected in the associated Method Blank

H Holding times for preparation or analysis exceeded

ND Not Detected at the Reporting Limit

Date: Page 1 of 3

** Value exceeds Maximum Contaminant Value £f <J^

E Value above quantitation range

J Analyte detected below quantitation limits

S Spike Recovery outside accepted recovery limits

• 1 2 -

1A



EPA SAMPLE NO.

Lab Code: 10170

MW-29

Case No. SAS No.: SDG No.: CAS105 Matrix: (soil/water) WATER

Sample wt/vol: 5.0

Level: (low/med) LOW


GC Column:

(g/ml) ML




RTX-VO ID: 0.53 (mm)


CAS NO.

74-87-3 75-1-4 74-83-9 75-00-3 75-69-4 67-64-1 75-35-4 74-88-4 75-15-0 75-09-2 107-13-1 156-60-5 75-34-33 108-5-4 78-93-3 156-59-2 67-66-3 74-97-5 71-55-6 56-23-5 71-43-2 107-06-2 97-01-6 78-87-5 75-27-4 74-95-3 108-10-1 10061-1-5 108-88-3 10061-2-6 79-00-5 591-78-6 127-18-4 124-48-1 106-93-4 108-90-7 630-20-6 100-41-4 108-38-3



(uL)

COMPOUND



Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane Acetone 1,1-Dichloroethene lodomethane Carbon Disulfide Methylene Chloride Acrylonitrile trans-1,2-Dichloroethene 1,1-Dichloroethane Vinyl Acetate 2-Butanone cis-1,2-Dichloroethene Chloroform Bromochloromethane 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene 1,2-Dichlor opropane Bromodichloromethane Dibromomethane 4-Methyl-2-pentanone cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene 1,1,1,2-Tetrachloroethane Ethylbenzene m,p-Xylene

FORM IVOA

-13-

10

100

50 10

10

10

u u u u

u

u u u u u u u u u u u u u u u

u u u u

u u u u u u u

(uL)

Q

u u

u 3/90

1A



EPA SAMPLE NO.

MW-29

Lab Code: 10170 Case No.: SAS No.:

5.0

LOW


Sample wt/vol:

Level: (low/med)




SDG No.: CAS105

(g/ml) ML




CAS NO.

95-47-6 100-42-5 75-25-2 79-34-5 96-18-4 541-73-1 106-46-7 95-50-1 96-12-8

(mm)



(uL)

COMPOUND



o-Xylene Styrene Bromoform 1,1,2,2-Tetrachloroethane 1,2,3-Tr ichloropropane 1,3-Dichlorobenzene 1,4-Dichlor obenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-chloro-propane

_5_ 5

10

(uL)

Q

U U U U U

U U U

FORM IVOA

- 1 4 -3/90




Lab Code: 10170

Contract: Casella MW-29

Case No.: SAS No.: SDG No.: CAS105

5.0

LOW


Sample wt/vol:

Level: (low/med)




(g/ml) ML




(mm)



(uL)

Number TICs found:



(uL)


FORM I VOA-TIC

- 1 5 -3/90

U.S. EPA - CLP

1 INORGANIC ANALYSIS DATA SHEET

CLIENT SAMP ID





% Solids: 0.0

MW-29

Contract: 448355





r< ij

CAS No.

7429-90-5 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-42-8 7440-43-9 7440-70-2 7440-47-3 7440-48-4 7440-50-8 57-12-5 471-34-1 7439-89-6 7439-92-1 7439-95-4 7439-96-5 7439-97-6 7440-02-0 7440-09-7 7782-49-2 7440-22-4 7440-23-5 7440-28-0 7440-62-2 7440-66-6

Analyte


Concentration

1210

10.0 76.5 3.0 500 5.0

235000 10.0 20.0 10.0 10.0

866000 1990 3.0

67600 170

0.20 30.0 3820 5.0 10.0

26400 18.7 30.0 45.1

C

U _5@*

u u u

u u u u

u

D U

X u u

u

Q

-_^KS^g#_;P«~-_K^

N

X

JS

E ____-*

N

M


cv p p p p p p p p

Color Before:

Color After:

COLORLESS

COLORLESS

Clarity Before:

Clarity After:

"!%f

T e x t u r e :

A r t i f a c t s : YES

Comments: Light Brown Sediment

FORM I

- 1 6 -

IN ILM04.1

U.S. EPA CLP


CLIENT SAMP ID





% Solids: 0.0

MW-29[Diss] Contract: 448355





CAS No.

7429-7440-7440-7440-7440-7440-7440-7440-7440-7440-7439-7439-7439-7439-7439-7440-7440-7782-7440-7440-7440-7440-7440-

-90-5 -36-0 •38-2 -39-3 •41-7 •43-9 •70-2 •47-3 •48-4 •50-8 89-6 92-1 95-4 96-5 97-6 02-0 09-7 49-2 22-4 23-5 28-0 62-2 66-6

Analyte


Concentration

1190 30.0 10.0

.1

.0

.0

76 3 5

232000 10.0 20.0 10.0 1960 3.0

67400 173 0.20 30.0 3820 5.0 10.0L*f 26500 14.4 30.0 50.9

N* N

U

E

#_T

Color Before:

Color After:

COLORLESS

COLORLESS

Clarity Before:

Clarity After:

M

P P P P P P P P P P P P P P cv p p p p p p p p

4

Texture:

Artifacts:

Comments:

M7

FORM I - IN

-17-ILM04.1

Upstate Laboratories, Inc. Analytical Report

CLIENT: Lab Order: Project: Lab ID:

Date: 12-Aug-09

Casella

U0907195

Ontario Co. LF Phase III (Cont. Wells) U0907195-002

Client Sample ID: MW-29

Collection Date: 7/9/2009

Analyses Result

INORGANIC ANIONS BY IC FOR WATERS Bromide ND NOTES: The reporting limits were raised due to matrix interference.

COLOR Color


10.0

1000




NITROGEN, TOTAL KJELDAHL (TKN) BY LACHAT Nitrogen, Kjeldahl, Total ND


SULFATE Sulfate

ND

331


CHEMICAL OXYGEN DEMAND (COD) Chemical Oxygen Demand 26 I j * ~

TOTAL ORGANIC CARBON (TOC) Organic Carbon, Total ND



Matrix: GROUNDWATER

Limit Qual Units DF Date Analyzed

E300.1 Analyst: NJS 2.0 mg/L 10 7/13/2009

E110.2 Analyst: NKA 5.00 UNITS 1 7/9/2009 3:45:00 PM

E160.1 Analyst: KAM 25 mg/L 1 7/14/2009

E310.2 Analyst: VAW 10 mg/LCaC03 1 7/10/2009

E325.2 Analyst: VAW 1.00 mg/L 1 7/10/2009

E350.1 Analyst: KAM 0.500 mg/L 1 7/14/2009

E351.2 Analyst: KAM 0.500 mg/L 1 7/14/2009

E353.2 Analyst: VAW 0.200 mg/L 1 7/10/2009 9:45:00 AM

E375.4 Analyst: KEL 50.0 mg/L 10 7/23/2009

E405.1 Analyst: KAF 4.00 mg/L 1 7/10/2009 7:30:00 AM

E410.4 Analyst: KAF 20 mg/L 1 7/23/2009

E415.1 Analyst: VAW 3.0 mg/L 1 7/16/2009

E420.4 (E420.4) Analyst: BY 0.005 mg/L 1 7/17/2009

SM3500 Analyst: KAF 0.010 mg/L 1 7/10/2009 9:00:00 AM

Approved By:

Qualifiers: * Low Level




Date: Page 2 of 3

** Value exceeds Maximum Contaminant Value __/<^f




• 18 -

1A VOLATILE ORGANICS ANALYSIS DATA SHEET


EPA SAMPLE NO.

DUPE

Lab Code: 10170 Case NC SAS No.: SDG No.: CAS105 Matrix: (soil/water) WATER

Sample wt/vol:

Level: (low/med)



5,0

LOW

(g/ml) ML





CAS NO.

74-87-3 75-1-4 74-83-9 75-00-3 75-69-4 67-64-1 75-35-4 74-88-4 75-15-0 75-09-2 107-13-1 156-60-5 75-34-33 108-5-4 78-93-3 156-59-2 67-66-3 74-97-5 71-55-6 56-23-5 71-43-2 107-06-2 97-01-6 78-87-5 75-27-4 74-95-3 108-10-1 10061-1-5 108-88-3 10061-2-6 79-00-5 591-78-6 127-18-4 124-48-1 106-93-4 108-90-7 630-20-6 100-41-4 108-38-3

(mm)

(uL)


Dilution Factor: 10


COMPOUND CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L

Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane Acetone 1,1-Dichloroethene lodomethane Carbon Disulfide Methylene Chloride Acrylonitrile trans-1,2-Dichloroethene 1,1-Dichloroethane Vinyl Acetate 2-Butanone cis-1,2-Dichloroethene Chloroform Bromochloromethane 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene 1,2-Dichloropropane Bromodichloromethane Dibromomethane 4-Methyl-2-pentanone cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene 1,1,1,2-Tetrachloroethane Ethylbenzene m.p-Xylene

FORM IVOA

- 1 9 -

10

100

50 10

10

10

Q

U U U U U U U U U U

u u u

u u u u u u u u u u u u u u u u u u

ifV*

u u u u u u

(uL)

"7*T~ Li

L4

3/90 2H

1A



EPA SAMPLE NO.

DUPE

Lab Code: 10170 Case No.: SAS No.: SDG No.: CAS105

5.0

LOW


Sample wt/vol:

Level: (low/med)




(g/ml) ML




(mm)



CAS NO.

(uL)

COMPOUND


CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L Q

(uL)

95-47-6 100-42-5 75-25-2 79-34-5 96-18-4 541-73-1 106-46-7 95-50-1 96-12-8

o-Xylene Styrene Bromoform 1,1,2,2-Tetrachloroethane 1,2,3-Trichloropropane 1,3-Dichlor obenzene 1,4-Dichlorobenzene 1,2-Dichlor obenzene 1,2-Dibromo-3-chloro-propane

5 5 5 5 5 5

I _

5 10

U u U U u u U U U

FORM IVOA

-20-3/90





Contract: Casella

SAS No.:

DUPE

SDG No.: CAS105


Sample wt/vol:

Level: (low/med)



5.0

LOW

(g/ml) ML



Date Received:

(mm)

Date Analyzed

Dilution Factor

7/9/2009

7/18/2009

1.0 Soil Extract Volume:

Number TICs found:

(uL) Soil Aliquot Volume:


(uL)


FORM I VOA-TIC

- 2 1 -3/90

U.S. EPA CLP


CLIENT SAMP ID





% Solids: 0.0

Dupe[Diss]

Contract: 448355





CAS No.

7429-90-5 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-43-9 7440-70-2 7440-47-3 7440-48-4 7440-50-8 7439-89-6 7439-92-1 7439-95-4 7439-96-5 7439-97-6 7440-02-0 7440-09-7 7782-49-2 7440-22-4 7440-23-5 7440-28-0 7440-62-2 7440-66-6

Analyte


Concentration

100 30.0 10.0 108 3.0 5.0

207000 10.0 20.0 10.0 262 3.0

51400 637 0.20 30.0 2570 5.0 10.0 50600 30.0 30.0 53.5

C

U U U

S-&B

u U

U U U

0

U U

X u ^r

u

Q

N* N

E

E

Jg B_f

N

M

P P P P P P P P P P P P P P

cv p p p p p p p p

Color Before:

Color After:

COLORLESS

COLORLESS

Clarity Before:

Clarity After: Texture:

Artifacts:

Comments: /fj

FORM I

- 2 2 -IN I L M 0 4 . 1

U.S. EPA - CLP


CLIENT SAMP ID





% Solids: 0.0

Dupe

Contract: 448355





CAS No.

7429-90-5 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-42-8 7440-43-9 7440-70-2 7440-47-3 7440-48-4 7440-50-8 57-12-5 471-34-1 7439-89-6 7439-92-1 7439-95-4 7439-96-5 7439-97-6 7440-02-0 7440-09-7 7782-49-2 7440-22-4 7440-23-5 7440-28-0 7440-62-2 7440-66-6

Analyte


Concentration

4760 _J0T_9.

10.0

138 3.0 500 5.0

227000

10.0

20.0

11.0

10.0

796000

6180

3.0 55700

811 0.20

30.0

3870

5.0 10.0

50600

34.9

30.0

51.8

C

U -ffiffi,

u u u

u u *@»

u

u

u u

ss@»

u u

u

Q

N

X"

X E Pf*

N

M


cv p p p p p p p p

Color Before: BROWN

Color After: YELLOW

Clarity Before:

Clarity After:

ifM-J**

Texture:

Artifacts: YES

Comments: Light Brown Sediment M-< " •

FORM I

-23-IN ILM04.1

Upstate Laboratories, Inc. Analytical Report Date: 12-Aug-09

CLIENT: Casella

Lab Order: U0907195

Project: Ontario Co. LF Phase III (Cont. Wells)

Lab ID: U0907195-003

Client Sample ID: Dupe

Collection Date: 7/9/2009

Analyses Result

INORGANIC ANIONS BY IC FOR WATERS Bromide ND NOTES: The reporting limits were raised due to matrix interference.

COLOR Color


15.0

1200




NITROGEN, TOTAL KJELDAHL (TKN) BY LACHAT Nitrogen, Kjeldahl, Total 0.643


SULFATE Sulfate

ND

92.8


CHEMICAL OXYGEN DEMAND (COD) Chemical Oxygen Demand 26 T

TOTAL ORGANIC CARBON (TOC) Organic Carbon, Total 4.1



Matrix: GROUNDWATER

Limit Qual Units DF Date Analyzed

2.0

5.00

25

100

1.00

0.500

0.500

0.200

10.0

4.00

20

3.0

0.005

0.010

E300.1 mg/L

E110.2 UNITS

E160.1 mg/L

E310.2 mg/LCaC03

E325.2 mg/L

E350.1 mg/L

E351.2 mg/L

E353.2 mg/L

E375.4 mg/L

E405.1 mg/L

E410.4 mg/L

E415.1 mg/L

E420.4 mg/L

SM3500 mg/L

10

1

1

10

1

1

1

1

2

1

1

1

(E420.4) 1

1

Analyst: NJS 7/13/2009

Analyst: NKA 7/9/2009 3:45:00 PM

Analyst: KAM 7/14/2009

Analyst: VAW 7/11/2009


Analyst: BY 7/16/2009

Analyst: KAM 7/14/2009

Analyst: VAW 7/10/2009 9:45:00 AM

Analyst: KEL 7/23/2009

Analyst: KAF 7/10/2009 7:30:00 AM

Analyst: KAF 7/23/2009


Analyst: BY 7/17/2009

Analyst: KAF 7/10/2009 9:00:00 AM

Approved By:

Qualifiers: * * Low Level




Date Page 3 of3

** Value exceeds Maximum Contaminant Value




c *

- 2 4 -

1A



EPA SAMPLE NO.

Lab Code: 10170

HOLD BLANK

Case No.: SAS No.:

5.0

LOW


Sample wt/vol:

Level: (low/med)




SDG No.: CAS105

(g/ml) ML

Lab Sample ID: U0907195-004A


Date Received:

CAS NO.

74-87-3 75-1-4 74-83-9 75-00-3 75-69-4 67-64-1 75-35-4 74-88-4 75-15-0 75-09-2 107-13-1 156-60-5 75-34-33 108-5-4 78-93-3 156-59-2 67-66-3 74-97-5 71-55-6 56-23-5 71-43-2 107-06-2 97-01-6 78-87-5 75-27-4 74-95-3 108-10-1 10061-1-5 108-88-3 10061-2-6 79-00-5 591-78-6 127-18-4 124-48-1 106-93-4 108-90-7 630-20-6 100-41-4 108-38-3

(mm)

Date Analyzed

Dilution Factor

7/9/2009

7/19/2009

1.0 (uL)

COMPOUND



Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane Acetone 1,1-Dichloroethene lodomethane Carbon Disulfide Methylene Chloride Acrvlonitrile trans-1,2-Dichloroethene 1,1-Dichloroethane Vinyl Acetate 2-Butanone cis-1,2-Dichloroethene Chloroform Bromochloromethane 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene 1,2-Dichloropropane Bromodichloromethane Dibromomethane 4-Methyl-2-pentanone cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene 1,1,1,2-Tetrachloroethane Ethylbenzene m.p-Xylene

FORM IVOA

- 2 5 -

10

100

50 10

10

10

(uL)

Q

U U U U U U U U U U U U U U

u u u u u u u u u u u u u u u u u u u u u u u u u

3/90

1A



EPA SAMPLE NO.

Lab Code: 10170

HOLD BLANK

Case No.: SAS No.: SDG No.: CAS105 Matrix: (soil/water) WATER

Sample wt/vol: 5.0



GC Column:

(g/ml) ML






CAS NO.

95-47-6 100-42-5 75-25-2 79-34-5 96-18-4 541-73-1 106-46-7 95-50-1 96-12-8



(uL)

COMPOUND



o-Xylene Styrene Bromoform 1,1,2,2-Tetrachloroethane 1,2,3-Trichloropropane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-chloro-propane

_____ 10

Q

U J__ U

U U

U U

(uL)

FORM IVOA

- 2 6 -3/90



Lab Name:

Lab Code:

Upstate Labs Inc.

10170 Case No.:

Contract: Casella

SAS No.:

HOLD BLANK

SDG No.: CAS105

5.0

LOW


Sample wt/vol:

Level: (low/med)


GC Column: RTX-VO ID: 0_53


(g/ml) ML




(mm)



(uL)

Number TICs found:



(uL)


FORM I VOA-TIC

- 2 7 -3/90



EPA SAMPLE NO.

Lab Code: 10170

ULI TRIP BLANK


5.0

LOW


Sample wt/vol:

Level: (low/med)


GC Column: RTX-VO ID: 053


(g/ml) ML




CAS NO.

74-87-3 75-1-4 74-83-9 75-00-3 75-69-4 67-64-1 75-35-4 74-88-4 75-15-0 75-09-2 107-13-1 156-60-5 75-34-33 108-5-4 78-93-3 156-59-2 67-66-3 74-97-5 71-55-6 56-23-5 71-43-2 107-06-2 97-01-6 78-87-5 75-27-4 74-95-3 108-10-1 10061-1-5 108-88-3 10061-2-6 79-00-5 591-78-6 127-18-4 124-48-1 106-93-4 108-90-7 630-20-6 100-41-4 108-38-3

(mm)



(uL)

COMPOUND



Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane Acetone 1,1-Dichloroethene lodomethane Carbon Disulfide Methylene Chloride Acrylonitrile trans-1,2-Dichloroethene 1,1-Dichloroethane Vinyl Acetate 2-Butanone cis-1,2-Dichloroethene Chloroform Bromochloromethane 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene 1,2-Dichloropropane Bromodichloromethane Dibromomethane 4-Methyl-2-pentanone cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene 1,1,1,2-Tetrachloroethane Ethylbenzene m,p-Xylene

FORM I VOA

- 2 8 -

10

100

50 10

10

10

Q

U U U U U U U U U

u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u

(uL)

3/90

1A




EPA SAMPLE NO.

ULI TRIP BLANK

SAS No.: SDG No.: CAS105 Matrix: (soil/water) WATER

Sample wt/vol: 5.0



GC Column:

(g/ml) ML






CAS NO.

95-47-6 100-42-5 75-25-2 79-34-5 96-18-4 541-73-1 106-46-7 95-50-1 96-12-8



(uL)

COMPOUND



o-Xylene Styrene Bromoform 1,1,2,2-Tetrachloroethane 1,2,3-Trichloropropane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-chloro-propane 10

(uL)

Q

U U U U U U U U U

FORM IVOA

-29-3/90


TENTATIVELY IDENTIFIED COMPOUNDS



EPA SAMPLE NO.

Contract: Casella

SAS No.:

ULI TRIP BLANK


Sample wt/vol: 5.0



GC Column:

SDG No.: CAS105

(g/ml) ML Lab Sample ID: U0907195-005A



RTX-VO ID: 0.53 (mm) Date Analyzed: 7/19/2009

Dilution Factor: 1.0 Soil Extract Volume:

Number TICs found:

(uL) Soil Aliquot Volume:


(uL)


FORM I VOA-TIC

- 3 0 -3/90

Quality Control Summary


- 3 1 -

2A WATER VOLATILE SYSTEM MONITORING COMPOUND RECOVERY


Lab Code: 10170 Case No.: SAS No.:

01 02 03 04 05 06 07 08 09 10 11

EPA

SAMPLE NO.

VMBS01 VBLK01 MW-28 DUPE VMBS02 VBLK02 MW-29 MW-29MS MW-29MSD HOLD BLANK ULI TRIP BLAN

SMC1

#

109 107 113 112 110 109 109 112 _____

110 111

SMC2

#

103 103 102 101 102 102 102 102 103 101 101

SMC3

#

102 100 101 102 101

! _____ 102 101 102 102 103

TOT

OUT

0 0 0 0 0 0 0 0 0 0 0

SMC1 SMC2 SMC3

= 1,2-Dichloroethane-d4 = Toluene-d8 = Bromofluorobenzene

QC LIMITS (76-114) (88-110) (86-115)

# Column to be used to flag recovery values * Values outside of contract required QC limits D System Monitoring Compound diluted out

SDG No.: CAS105

page 1 of 1 FORM II VOA-1 3/90

• 3 2 -

3A WATER VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY



Matrix Spike- EPA Sample No MW-29

SAS No. SDG No.: CAS105

COMPOUND

1,1-Dichloroethene

Benzene

Trichloroethene

Toluene

Chlorobenzene

SPIKE

ADDED

(ug/L)

50

50

50

50

50

SAMPLE

CONCENTRATION

(ug/L)

0.0

0.0

0.0

0.0

0.0

MS

CONCENTRATION

(ug/L)

60

52

56

52

54

MS

%

REC#

120

104

112

104

108

QC

LIMITS

REC.

61 - 145

76 - 127

71 - 120

76 - 125

75 - 130

COMPOUND

1,1-Dichloroethene

Benzene

Trichloroethene

Toluene

Chlorobenzene

SPIKE

ADDED

(ug/L)

50

50

50

50

50

MSD

CONCENTRATION

(ug/L)

60

53

56

53

53

MSD

%

REC#

120

106 | ________

106

106

%

RPD#

0

2

0

2

2

QC LIMITS

RPD REC.

14

11 ___

13

13

61 - 145

76 - 127

71 - 120 _̂~--_-___-_____

75 - 130

# Column to be used to flag recovery and RPD values with an asterisk * Values outside of QC limits

RPD: 0 out of 5 outside limits

Spike Recovery: 0 out of 10 outside limits

COMMENTS:

FORM III VOA-1

- 3 3 -3/90

U.S. EPA - CLP

5A SPIKE SAMPLE RECOVERY

Lab Name: Upstate Laboratories, Inc. Contract: 448355

Lab Code: 10170 Case No. SAS No.:

CLIENT SAMP ID

MW-29S

SDG No.


% Solids for Sample: 0.0

CAS105


Concentration Units (ug/L or mg/kg dry weight) UG/L

Analyte

Antimony Arsenic Barium Beryllium Boron Cadmium Chromium Cobalt Copper Iron Lead Manganese Nickel Selenium Silver Thallium Vanadium Zinc

Control Limit %R

75-125 75-125 75-125 75-125 75-125 75-125 75-125 75-125 75-125 75-125 75-125 75-125 75-125 75-125 75-125 75-125 75-125 75-125

Spiked Sample Result (SSR) C

702.9025 2534.8636 2243.9938 53.8455

5564.1047 47.1990 209.0947 452.1801 255.2903 2877.5377 460.8179 667.9034 471.5315 2273.7974 37.7766

1846.2971 527.7317 489.2851

Sample Result (SR)

30.0000 10.0000 76.4906 3.0000

500.0000 5.0000 10.0000 20.0000 10.0000

1986.6603 3.0000

170.2584 30.0000 5.0000 10.0000 18.6580 30.0000 45.1430

C

U U B U U U U U U

U

U U U

U

Spike Added (SA)

500.00 2000.00 2000.00 50.00

5000.00 50.00 200.00 500.00 250.00 1000.00 500.00 500.00 500.00 2000.00 50.00

2000.00 500.00 500.00

%R

140.6 126.7 108.4 107.7 111.3 94.4 104.5 90.4 102.1 89.1 92.2 99.5 94.3 113.7 75.6 91.4 105.5 88.8

Q N N

M

P P P P P P P P P P P P P P P P P P

Comments:

FORM V (Part 1) - IN ILM04.1

-34-

U.S. EPA CLP




CLIENT SAMP ID

MW-29[Diss]S


% Solids for Sample: 0 . 0

SDG No.: CAS105


Concentration Units (ug/L or mg/kg dry weight) UG/L

Analyte

Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Iron Lead Manganese Nickel Selenium Silver Thallium Vanadium Zinc

Control Limit

%R

75-125 75-125 75-125 75-125 75-125 75-125 75-125 75-125 75-125 75-125 75-125 75-125 75-125 75-125 75-125 75-125 75-125


687.2646 2595.2778 2247.0082 54.1740 47.3674

209.9321 458.9565 253.4051

2751.6927 464.5259 701.5858 478.7060

2402.6772 37.2223

1887.5141 526.1100 514.7296

Sample Result (SR)

30.0000 10.0000 76.0772 3.0000 5.0000 10.0000 20.0000 10.0000

1963.0323 3.0000

172.5367 30.0000 5.0000 10.0000 14.3922 30.0000 50.8773

C

U U B U U U U U

U

U U U

U

Spike Added (SA)

500.00 2000.00 2000.00

50.00 50.00 200.00 500.00 250.00 1000.00 500.00 500.00 500.00

2000.00 50.00

2000.00 500.00 500.00

%R

137.5 129.8 108.5 108.3 94.7

105.0 91.8

101.4 78.9 92.9

105.8 95.7

120.1 74.4 93.7

105.2 92.8

Q

N N

N

M

P P P P P P P P P P P P P P P P P

Comments:


-35-

U.S. EPA - CLP

5B POST DIGEST SPIKE SAMPLE RECOVERY


Lab Code: 10170 Case No. SAS No.


CLIENT SAMP ID

MW-2 9A

SDG No. CAS105


Concentration Units: ug/L

Analyte

-__-__-&_-_-_____

I^CSMV.C

Control Limit %R


zzzz_3__Q__Mr:

Sample Result (SR) C

5)010 \€).0 H

Spike Added (SA)

(>bcOft.

%R

IQ̂ J a

Comments:


•36-

U.S. EPA - CLP

5B POST DIGEST SPIKE SAMPLE RECOVERY




CLIENT SAMP ID

MW-29[Diss]A

SDG No. : CAS105



Analyte

Antimony Arsenic

Control Limit %R


230.80 2046.60


30.00 10.00

U U

Spike Added (SA)

500.0 2000.0

%R

46.2 102.3

Q M

P P

Comments:


•37-

U.S. EPA CLP





CLIENT SAMP ID

MW-29S

SDG No.: CAS105




Analyte

Cyanide

Control Limit %R

75-125


72.8000


10.0000 U

Spike Added (SA)

80.00

%R

91.0 Q M

C

Comments:


-38-

U.S. EPA - CLP

DUPLICATES



Matrix (soil/water): WATER DISSOLVED

CLIENT SAMP ID

MW-29[Diss]

SDG No. : CAS105



% Solids for Duplicate: 0.0


Analyte


Control Limit

10

20

Sample (S) C

1186.7211 0.0000 0.0000 76.0772 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

1963.0323 0.0000

67381.7638 172.5367 0.0000 0.0000

3817.5812 0.0000 0.0000

26542.1961 14.3922 0.0000 50.8773

U U B U U

U U U

U

U U B U U

U

Duplicate (D) C

1142.8024 0.0000 0.0000 72.8524 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

1893.4835 0.0000

65404.8438 171.8157 0.0000 0.0000 0.0000 0.0000 0.0000

25573.8562 18.9014 0.0000 50.3015

U U B U U

U U U

U

U U u u u

u

RPD

3.8

4.3

2.2

3.6

3.0 0.4

0.0

3.7 27.1

1.1

Q M

P P P P P P P P P P P P P P CV P P P P P P P P

FORM VI IN ILM04.1

•39-

U.S. EPA - CLP

DUPLICATES



TOTAL

CLIENT SAMP ID

MW-2 9

SDG No.: CAS105




% Solids for Duplicate: 0.0


Analyte

Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Cyanide Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

Control Limit

60

Sample (S)

10

20

1212 0 0

76 0 0 0 0 0 0 0 0

1986 0

67627 170 0 0.

3817. 0. 0.

26368. 18. 0.

45.

.7267

.0000

.0000

.4906

.0000

.0000

.0000

.0000 0000 oooo oooo oooo 6603 0000 3220 2584 0000 0000 7173 0000 0000 7046 6580 0000 1430

Duplicate (D)

1113 90 0

73 0 0 0 0 0 0 0 0

1891 0

66291 174 0. 0. 0. 0. 0.

25843. 11. 0.

52.

.7287

.1442

.0000

.1574

.0000

.0000

.0000

.0000 0000 0000 oooo oooo 9059 0000 9027 6430 0000 0000 0000 0000 0000 9373 3566 0000 9832

U B U U U

U U U U

U

U U U U U

U

RPD

8.5 0.0

4.5

1.4

4.9

0.0

2. 48.

16.0

M

P P P P P P P P P P P C P P P P cv p p p p p p p p

FORM VI IN ILM04.1

-40-

F:\DATA\C16272.D

WATER VOLATILE MATRIX SPIKE BLANK RECOVERY

L a b N a m e : Upstate Labs Inc. Contract: Casella

L a b C o d e : 1Q170 Case I SAS No.:

Matrix Spike-EPA Sample No.: VBLKOI

SDG No.: CASI05

Level (low/med): Low

COMPOUND

1,1-Dichloroethene Benzene Trichloroethene Toluene Chlorobenzene

SPIKE ADDED

("9") 50 50 50 50 50

SAMPLE CONCENTRATION (ug/D

_0_ 0

MS CONCENTRATIO (ug/l)

61 53 56 52 53

MS

REC 122 106 112 104 106

QC LIMITS

61-145 76-127 71-120 76-125 75-130

Page 1 of 1 VWMBS60.XLS

- 4 1 -7/23/2009 3:41 PM

F:\DATA\C16272.D

WATER VOLATILE MATRIX SPIKE BLANK RECOVERY

Lab Name: Upstate Labs Inc, Contract: Casella

L a b C o d e : 10170 Case I SAS No.:

Matrix Spike-EPA Sample No.: VBLK02 Level (low/med):

SDG No.:CAS105

Low

COMPOUND

1,1-Dichloroethene Benzene Trichloroethene Toluene Chlorobenzene

SPIKE ADDED (ug/l)

50 50 50 50 50

SAMPLE CONCENTRATION

i__s.ll 0 0

MS CONCENTRATIO (ug/D

60 53 55 53 53

MS % REC

120 106 110 106 106

QC LIMITS

61-145 76-127 71-120 76-125 75-130

Page 1 of 1 VWMBS60.XLS

- 4 2 -7/23/2009 3:41 PM

I -ts. CO I

<*1

o

< M

M

S o

t s i < H - 0)

3 a O BJ

a H-3 3

h-1 M O O O O O O

O O

CD CO CD CO _-. LO

O l-» Ln CJ I

CD CD IX) CO

__. LO

•-3 _r cu M i - 1

h1-

c 3

M

o o o o

CD CT.

o ~ J J - .

CD CTl

I - 1

co o a H -

C 3

PO PO O

o o o

H 1

CD 0 0 - J CJl

cn o

CD

o U )

co H-! - •

«. ro H

PJ

o o O

O

l->

a. CD t o

PO L n

CO

__. CTi

CQ

CD I - 1

CD 3 H-c

I - 1

o o o o

h-» M L n CD

L n Cn

M I - 1

Cn

I O

T ) O r t PJ Co

ca H-C 3

PO O O O O

O

M CD 0 0 PO L n

LO CO

co CD

M

3 H-o

2 PJ 3

?r__ CD h-"

h-» O O O

O

CD to O

I - 1

_-. CD t o

O

0) 3 (D Cn

CD

l->

o o o o

t->

o t o M

cn CD

t-» O t O

PO

s 0--Q 3 CD cn H -c 3

PO M O O O

o

ro o L 0 CO CTl

^ 1 J - .

CD _ J

(-»

f CD PJ

M H

n o O 13

a _ .

h-> O O O

o

CD 0 0 LO

- J CTl

CD 0 0

*_

ro i - 1

o o o o

ro o ___ ~ j ^ j

t o

o

CD - J

cn

(D i-i

M

o o o o

CD a-. *-o to

CD a__

a__

n O cr PJ

!-• rr

M o o o o

CD CD OS,

o O

CO CD

CTl

O o _r QJ t-j

o 3 H -G 3

M O O

o o

CD ^ 1 LO

CJI O

CD ^ 1

L 0

M

o p -

p ^

ro M O O O

O

PO M H-1

Cn • J

CJl ^ 1

M O O

00

o tu p 3 H-r ;

g

l - 1

O

o o o

CD CD L 0

~ J CJl

CO CD

__-

to cu ca a* i- > o n o 3

t o

o o o o

PO

o L 0

o CD o H-» O t-»

CJl

CD H >< I - " h-" H -C 3

I - * O O

o o

CO ^ J ~ J

PO CJI

CO ~ J

_ J

CU H V-c 3

h-» PO

o o o o

H " PO

cn ! - • M

^ 1 CO

M O CJI

M

I . 3 CO r t CD H -3 3 H - O O 3

><

M M O O O O O O

O O

I - 1 M po CA

PO ro - J PO

CO LO H> H»

M l-> PO LO t o PO

CO PO

M C 3 t->-3

g

M t o O O O

O

M h-J CJl 0 0 CD

cn L 0

CO cn

cn

> 3 P) I—'

•< r t (D

H -H C CD

O c 3 a

dp

7>

>-_ i-i C CD

*. O G 3 a

o

t-< H -3 H-r t tn

dP •jo

> C CD

O C_

co

— c _a \ tr1

03

o H -

a _̂̂ 3

i Q

rK 03 •«—-

> 04 C (D O C to

r-1

(. rn

_-o C H n CD

n T ) H

CQ O I - 1

H -0-

t-< o W

m o c H O (D

P_

fS

tr1

PJ

rr o o a CD

..

(-> O t-> - J

o

C3 CU

w CD

2 o

r-< (U

rr z PJ

3 fl> ..

a 15 w r t CU r t (D

P) O O i-s P) r t

o H -CD cn

M 3 O

o o 3 O

n > m o CJl

tn > w 3 o . ••

n o 3 r t h W

o r t

CO L0 CJI CJl

lr1

> w O

fg H_ O ?o K

n O ~J 3 _̂ J0

O f

CQ

U • CQ

M TJ

> I

< J r-* m

•0 tr1

I -ts. -ts. I

o

<: M M

M t"1

s O

C-P -

3 o

P» O

o o o

CD CO

o cn t o

CD CD

P>

< PJ

3 P) a P -

G 3

P> O

o o o

CD _ J M

0 0 CJI

CD ~ J

t o

i-3

tr p i I-1

P-" P -

G 3

M

o o o o

CD CJl

a-. J - .

co

CD CJI

J - .

CQ

o a P-P 3

t o t o

o o o o

P> CO CD LO

o

cn CO

CO

o

cn

w P -H ' <1 CD t-i

t o

o o o o

M

cn cn L n

o _-.

OD LO

LO

CQ CD P-° (D 3 P -G 3

P "

o o o o

(-• p>

cn L n

o - J

p »

h-1

cn U l

TJ o r t PJ OJ

cn P -c 3

t o

o o o o

o

p " CO ~ J

o CJl

4_-0 0

CD 0 0

CJI

3 P -o

s PJ 3

*--_ CD p -

I - 1

o o o

o

CD t o t o

P» M

CD P0

t o

01 3 CD tn CD

P " o o o

o

P*

o P 1

CD

^ J ^ 1

l->

o t o

o

s OJ -3 3 CD CD P -

1

t o I - 1

o o o

o

PO o p>

a. o

cn o

CO cn

o

_-• CD PJ

M

n o

o o TS

a 3 Ti

p 1

o o o

o

CD 0 0 0 0

CJl P>

CD CO

CD

t o p» o o o

o

PO o _-. o CD

I - 1

I - 1

CD ~ J

P0

CD

n

P* o o o

o

CD LO cn

l - J

LO

CD LO

cn

n o cr PJ P ' r t

p « o o o

o

CD CD P 1

CJI _ J

CD CD

t o

o 3" h o 3 P -G 3

P> o o o

o

CD cn cn

- J cn

CO cn

- J

o PJ M o P -r_ g

PO P " o o o

o

PO o - J

__. 0 0

CD _ J

CD 0 0

CO

o OJ

3 P -p £3

p » 0 0 0

0

CO OJ CJl

L 0 t o

CO 0 0

CJI

o_ CD l-j

*< t - 1

P 1

p .

P> 0 0 0

0

CO - J P>

t o 0 0

CD ^ 1

p »

CO D_- D_- 3 -0) H p -p £3

p » ro 0 0 0

0

P* t o CJ1 L 0 t o

CD

_-. p »

0 t C -

a-.

"1 3 cn r t CD P-3 3 p- 0 O 3

•<

P» M 0 0 0 0 0 0

0 0

p» p» PO L0 PO t o 00 CJl

00 cn cn __.

p" p» PO LJ t o PJ

co cn

p *

5

p -3 p

3

p * t o 0 0 0

0

p> P 1

_-_ CO

__. CJI _J

CD CJl

_ J

> 3 OJ P 1

• < r t CD

• _

H c CD

0 c 3 a

oV-

po

i-3 H c CD

•*-0 c 3 a

n

IT1

p -3 p-r t cn

dp •5d

> c CD

0 c w

' — •

c -Q • v .

ir>

CQ 0 P " p -a , ,_ 3 -Q \ ?r i Q

'

> __> c CD 0

c (J)

M 0 rn

rn 0 ci H n CD

n m M

CQ 0 p -p -

a tr* r. cn

CQ 0 c l-i 0 CD

Kf

[5

tr1

PJ

rr n 0 a CD

..

t-> 0 p " - J 0

0 OJ 0) CD

3 0

M QJ t r

3 OJ 3 m ..

a "0 _) r t PJ r t CD

rr1

OJ tr CJ h UJ r t 0

I - . p -CD cn

M

3 0

CQ

o c.

3 o

> CQ P> O CJl

t n

> Ui

3 O • • •

n 0 3 r t H OJ O r t

CO LO CJI CJI

> td o

H3

o 3-K O O - J 3 H_ JO O t"1

CQ

tr1

t?_

a

>

o tr1

f t .

4A VOLATILE METHOD BLANK SUMMARY


EPA SAMPLE NO.

VBLK01

Lab Code:

Lab File ID:

10170 Case No.:

C28988.D



GC Column: RTX-VO ID: 0.53 (mm)

Lab Sample ID: MB-43946

Time Analyzed: 21:01

Heated Purge: (Y/N) N

Instrument ID: 12.0

THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS AND MSD:

01 02 03

EPA

SAMPLE NO.

VMBS01 MW-28 DUPE

LAB

SAMPLE ID

LCS-43946 U0907195-001H U0907195-003H

LAB

FILE ID

C28987.D ^02900075

C29001.D

TIME

ANALYZED

20:22 4:47 5:26

COMMENTS:

page 1 of 1 FORM IV VOA 3/90

-45-

1A



EPA SAMPLE NO.

VBLK01

Lab Code: 10170 Case No.: SAS No.: SDG No.: CAS105 Matrix: (soil/water) WATER

Sample wt/vol: 5.0



GC Column:

(g/ml) ML






CAS NO.

74-87-3 75-1-4 74-83-9 75-00-3 75-69-4 67-64-1 75-35-4 74-88-4 75-15-0 75-09-2 107-13-1 156-60-5 75-34-33 108-5-4 78-93-3 156-59-2 67-66-3 74-97-5 71-55-6 56-23-5 71-43-2 107-06-2 97-01-6 78-87-5 75-27-4 74-95-3 108-10-1 10061-1-5 108-88-3 10061-2-6 79-00-5 591-78-6 127-18-4 124-48-1 106-93-4 108-90-7 630-20-6 100-41-4 108-38-3



(uL)

COMPOUND



Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane Acetone 1,1-Dichloroethene lodomethane Carbon Disulfide Methylene Chloride Acrylonitrile trans-1,2-Dichloroethene 1,1-Dichloroethane Vinyl Acetate 2-Butanone cis-1,2-Dichloroethene Chloroform Bromochioromethane 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene 1,2-Dichloropropane Bromodichloromethane Dibromomethane 4-Methyl-2-pentanone cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene 1,1,1,2-Tetrachloroethane Ethylbenzene m.p-Xylene

FORM I VOA

- 4 6 -

10

100

50 10

10

10

Q

U U U U U U U U U U

u u u u u u u u u u u u u u u u u u u u u u u u u u u u u

(uL)

3/90



EPA SAMPLE NO.

VBLK01

Lab Code: 10170 Case No.: SAS No.: SDG No.: CAS105

5.0

LOW


Sample wt/vol:

Level: (low/med)




(g/ml) ML




CAS NO.

95-47-6 100-42-5 75-25-2 79-34-5 96-18-4 541-73-1 106-46-7 95-50-1 96-12-8

(mm)



(uL)

COMPOUND



o-Xylene Styrene Bromoform 1,1,2,2-Tetrachloroethane 1,2,3-Trichloropropane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-chloro-propane 10

Q

U U U U U

U U

(uL)

FORM IVOA

-47-3/90



Lab Name: Upstate Labs Inc

Lab Code: 10170

Contract: Casella VBLK01


_____

LOW


Sample wt/vol:

Level: (low/med)




(g/ml) ML




(mm)



(uL)

Number TICs found: 0



(uL)


FORM I VOA-TIC

- 4 8 -3/90

4A

VOLATILE METHOD BLANK SUMMARY


EPA SAMPLE NO.

VBLK02

Lab Code: 10170





Lab Sample ID

Time Analyzed

Heated Purge

MB-43964

13:32

(YIN) N

Instrument ID: 12.0

THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS AND MSD:

01 02 03 04 05 06

EPA

SAMPLE NO.

VMBS02 MW-29 MW-29MS MW-29MSD

rT io lD^LANK ULI TRIP BLANK

LAB

SAMPLE ID

LCS-43964 U0907195-002H U0907195-002HMS U0907195-002HMSD U0907195-004A U0907195-005A

LAB

FILE ID

C29005.D C29007.D C29008.D C29009.D C29010.D C29011.D

TIME

ANALYZED

12:52 14:12 14:51 15:29 16:08 16:47 I

COMMENTS:

page 1 of 1 FORM IV VOA 3/90

• 4 9 -

1A



EPA SAMPLE NO.

VBLK02


Sample wt/vol: 5.0 (g/ml) ML_








CAS NO.

74-87-3 75-1-4 74-83-9 75-00-3 75-69-4 67-64-1 75-35-4 74-88-4 75-15-0 75-09-2 107-13-1 156-60-5 75-34-33 108-5-4 78-93-3 156-59-2 67-66-3 74-97-5 71-55-6 56-23-5 71-43-2 107-06-2 97-01-6 78-87-5 75-27-4 74-95-3 108-10-1 10061-1-5 108-88-3 10061-2-6 79-00-5 591-78-6 127-18-4 124-48-1 106-93-4 108-90-7 630-20-6 100-41-4 108-38-3



(uL)

COMPOUND



Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane Acetone 1,1-Dichloroethene lodomethane Carbon Disulfide Methylene Chloride Acrylonitrile trans-1,2-Dichloroethene 1,1-Dichloroethane Vinyl Acetate 2-Butanone cis-1,2-Dichloroethene Chloroform Bromochloromethane 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene 1,2-Dichloropropane Bromodichloromethane Dibromomethane 4-Methyl-2-pentanone cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane 1,2-Dibromoethane Chlorobenzene 1,1,1,2-Tetrachloroethane Ethylbenzene m.p-Xylene

FORM IVOA

- 5 0 -

10

100

50 10

10

10

(uL)

Q

U

U U U U U U U U

U U

U U U

u u

u u u u u u u u u u u u u u u u u u u

3/90



EPA SAMPLE NO.

VBLK02


Sample wt/vol: 5J0 (g/ml) ML






Date Received:

Date Analyzed

Dilution Factor:

7/9/2009

7/19/2009

1.0 Soil Extract Volume:

CAS NO.

95-47-6 100-42-5 75-25-2 79-34-5 96-18-4 541-73-1 106-46-7 95-50-1 96-12-8

(UL)

COMPOUND



o-Xylene Styrene Bromoform 1,1,2,2-Tetrachloroethane 1,2,3-Trichloropropane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-chloro-propane

____ 5

10

Q

U U U U U

U U

(uL)

FORM I VOA

-51 3/90


TENTATIVELY IDENTIFIED COMPOUNDS

EPA SAMPLE NO.



Contract: Casella

SAS No.:

VBLK02

SDG No.: CAS105

WATER

5_0

LOW

Matrix: (soil/water)

Sample wt/vol:

Level: (low/med)


GC Column: RTX-VO ID: 0_53


(g/ml) ML_



(mm)

(uL)



Dilution Factor: j_0

Soil Aliquot Volume: (uL)

Number TICs found:

CONCENTRATION UNITS:

(ug/L or ug/Kg) UG/L


FORM I VOA-TIC

- 5 2 -

3/90

U . S . EPA - CLP

3 BLANKS

nnest -a te L a b o r a t o r i e s , L a b Name: y£S taxe__ua __

Case No.

Inc.

Lab Code: 10170

Preparation Blank Matrix (soil/water)

Contract: 448355

SAS No.:

WATER

Pr eparation Blank Concentration

Units (ug/L or mg/kg) : mLk

SDG No.: CAS105

(Aluminum

JAntimony

(Arsenic

JBarium

(Beryllium

(cadmium

(Calcium |Chromium |Cobalt

(Copper

(iron

JLead (Magnesium

(Manganese

(Nickel

(potassium

(Selenium

(silver

(Sodium (Thallium

|vanadium

Zinc

Initial

Calib.

Blank

(ug/L)

Too.o| u 1 3 0 . 0

1 0 . 0 | U | 50 - OJ U (

3 .0(U | 5 .0(U (

1 0 0 0 . o ( u | 1 0 . 0 | U | 20 .0 (U ( 1 0 . 0 | O | 6 0 . 0 | U |

3 . 0 | U ( 1000.0(U (

i o . o | u | 30 .0 (U |

1000 . 0| U 5 . 0 | U

1 0 . 0 | U

1000 .o | 0 1 0 . o| u 30 . 0| U l o . o l o

100 . 0| u 174.0(

1 0 . 0 | U | 50 .0(U |

3 .0 | O ( 5 .0 |U |

1000.0( U | i o . o | u ( 2 0 . 0 | U ( i o .o (u I

60. 0| U | 3 . 0 ) 0 1

1000 .0 | U | i o . o ( u | 3 0 . 0 | U |

1000 .0 | U | 5 .4 | |

i o . o | u |

1000. o| u I i o . o | 0 ' 30. 0J U l o . o l o

.oool u .ooo| u .oool u I I .ooo| u I .oool u I .ooo( o I

i.ooo| u I i.ooo) u I ..oool u I 3.0001 U I D.000( U I 3.000J U I o.ooo| u I o.oooj u I o.ooo| u io. oool u 5.000) U

L0.000J U 30.000) U 10.ooo) u 30.000) U io .ooo) u

FORM I I I - I N

I L M 0 4 . -

• 5 3 -

U.S. EPA - CLP

BLANKS

Inc. Lab Name:

Lab Code: 10170

Preparation

C a s e No.

B l a n k M a t r i x ( s o i l / w a t e r ) :

P r e p a r a t i o n B l a n k C o n c e n t r a t

i o n U n i t s ( u g / L o r m g / k g ) :

SDG No. CAS105

A n a l y t e

(Aluminum

(Antimony (Arsen ic (Barium (Bery l l ium (Cadmium (ca lc ium (chromium (Cobal t (Copper ( i ron (Lead (Magnesium (Manganese

(Nickel (po tas s ium (Selenium ( S i l v e r (Sodium | T h a l l i u m (vanadium

Zinc

I n i t i a l

C a l i b . Blank

(ug/L)

l o o . o ( u 130.0( 1

i o . o ( u |

5 0 . 0 | U | 3 . 0 ( U | 5 .0(U |

1000 . o(u ( i o . o ( u ( 20 .0(U ( I O . O I U I

6 0 . 0 ( 0 | 3 . 0 ( 0 1

1000.o) 0 ( 1 0 . 0 ( 0 I 3 0 . 0 ( 0 |

1000 . o( o ( 5 . 0 ( 0

1 0 . 0 ( 0 1000 . 0 ( 0

i o . o | o 3 0 . 0 ( 0

io.oIu

RunNo: 4 4572

Continuing C a l i b r a t i o n

Blank (ug/L)

C 2 C

TooToTu) 174.0( I

i o . o | o |

50 . 0( O ( 3 . 0 ( 0 | 5 . 0 ( 0 |

1000.ol o 1 i o . o ( o | 20 .0(o( 10.0(0 | 60 .0(o(

3.0)0 | 1000.ol O |

10. ol o 1 30.0JO |

IOOO.ol o 1 5 .4 | 1

1 0 . 0 ( 0 1 1000.0( O (

1 0 . 0 ( 0 ' 3 0 . 0 | O 1 0 . 0 | O

MB-18583

Preparation

Blank

.oool O .oool 0 | 1 : .0001 0 | | .oool o | ( .ooojo I (

i.oool o ( I ).000| o ( I ).000| o I I 3.000(0 I I

o.ooo| o I I o.ooo(o I 3.000) O I o.ooo( o 1 .o.ooo| o ( iO.000)0 1 30.000) O 1 5.000( O 1

10.000(0 1

oo.ooo(o 1

IO.OOO) o !

30.000) O 10 . ooo) 0

FORM H I - I N

I L M 0 4 . 1

- 5 4 -

U . S . EPA - CLP

BLANKS

^ . 0 T n r , C o n t r a c t : 44J3355 Lab Name: ^ s t a t J L . ^ ^ ^

SAS No.: Lab Code: 10170 Case No.

Preparation Blank Matrix (soil/water): NA

Preparation Blank Concentration Units (ug/L or mg/kg): NA

SDG No.: CAS105

Initial

Calib. Blank (ug/L) C

~30.01 0

RunNo: 44780 Continuing Calibration

Blank (ug/L) 2 C 3

Preparation Blank M

FORM III ~ IN ILM04.1

-55-

U.S. EPA - CLP

3 BLANKS

Lab Name: UEstat^Laboratories^


Inc.

Preparation Blank Matr

Contract:

SAS No.:

448355

ix (soil/water):

Preparation Blank Concentration Units (ug/L or mg/kg):

SDG No.: CAS105

Analyte

Initial Calib. Blank (ug/L) C

ll".5


Blank (ug/L) 2 C 3

Preparation Blank M

FORM III - IN ILM04.1

-56-

U.S. EPA - CLP

3 BLANKS

Lab Name: UEstat^Laboratori^s^,!^

Lab Code: lOTTO Case No.

Preparation Blank Matrix (soil/water)

Preparation Blank Con

Contract: 448351

SAS No.:

WATER

centration Units (ug/L or mg/kg) UG/L

SDG No.: CAS105


Blank (ug/L) 2 C 3

MB-18575

Preparation Blank C


-57-

U.S. EPA - CLP

3 BLANKS

Lab Name: Ujo^tat^Laboratorles^^r^


Preparation Blank Matrix (soil/water):

Preparation Blank Concentration Units (ug/L or mg/kg):

SDG No.: CAS105

Analyte

Initial Calib. Blank (ug/L) C

<3~.2| 0


Blank (ug/L) 2 C 3

MB-18420

Preparation Blank C M

FORM III " IN ILM04.1

-58-

U . S . EPA - CLP

3 BLANKS

Lab Name: U _ E _ L t a ^ J i a b o r a t o r i e s t .

Case No.

Inc.

Lab Code: 10170

Preparation Blank Matrix (soil/water):

Contract: £48355

SAS No.:

WATER

Preparation Blank Co ncentration Units (ug/L or mg/kg): UG/L

SDG No.: CAS105


-59-

U.S . EPA - CLP

3 BLANKS

Lab Name: U^s ta t^ jLiabora tor ies^ Inc.

Case No.

Contract: 4£8355

SAS No.:

NA Lab Code: 101__0.

Preparatio„ Bla„_ MatriK .-oil/water,: sa

Ptepar,t-on _____ Concentrate Unit. C / L « «/*> • •&

SDG No.: CAS105

FORM III " IN ILM04.1

•60-

5A VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK

BROMOFLUOROBENZENE (BFB)



Lab File ID: C28611 .D

Instrument ID: 12.0

Contract: Casella


GC Column: RTX-VOLA ID: 0.53 (mm)

BFB Injection Date: 6/28/2009

BFB Injection Time: 8:54


m/e

50

75

95

96

173

174

175

176

177

ION ABUNDANCE CRITERIA

8.0 - 40.0% of mass 95 _

30.0 - 66.0% of mass 95

Base peak, 100% relative abundance

5.0 - 9.0% of mass 95 Less than 2.0% of mass 174

50.0 -120.0% of mass 95 __

4.0 - 9.0% of mass 174

93.0-101.0% of mass 174

5.0 - 9.0% of mass 176

% RELATIVE

ABUNDANCE

22.5

48.1

100.0

6.5 0.0 ( 0.0)1

64.9

4.7 ( 7.2)1

63.6 ( 98.0)1

4.0 ( 6.3)2

" l ^ i ^ l s ~ % ^ ^ 1 7 4 " T V a l u e i s % mass 176

THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS:

01 02 03 04 05 06

EPA

SAMPLE NO. VSTD003 VSTD010 VSTD020 VSTD050 VSTD100 VSTD200

LAB

SAMPLE ID ICAL-43403 3PPB ICAL-43403 10PPB ICAL-43403 20PPB ICAL-43403 50PPB ICAL-43403 100PPB ICAL-43403 200PPB

LAB

FILE ID

C28613.D C28614.D C28615.D C28616.D C28617.D C28618.D

DATE

ANALYZED 6/28/2009 6/28/2009 6/28/2009 6/28/2009 6/28/2009 6/28/2009

TIME

ANALYZED

10:28 11:07 11:45 12:24 13:03 13:41

page 1 of 1 FORM V VOA

- 6 1 -

3/90

5A

VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK BROMOFLUOROBENZENE (BFB)

Lab Name:

Lab Code:

Lab File ID:

Instrument ID

Upstate Labs Inc.

10170 Case No.:

C28985.D

Contract: Casella

SAS No.:. SDG No.: CAS105

12.0

GC Column: RTX-VOLA ID: 0 5 3 _ (mm)

BFB Injection Date: 7/17/2009



ION ABUNDANCE CRITERIA^

8.0 - 40.0% of mass 95 30.0 - 66.0% of mass 95 Base peak, 100% relative abundance


50.0 -120.0% of mass 95

4.0 - 9.0% of mass 174

93.0 -101.0% of mass 174

5.0 - 9.0% of mass 176 .

% RELATIVE

ABUNDANCE

22.9

49.3

100.0

6.8 0.0 ( 0.0)1

63.0 4.6 ( 7.4)1

'mJS/^sV/ 4.1 ( 6.5)2

T ^ k ^ i s ^ m a s s 174 2-Value is % mass 176

THIS CHECK APPL.ES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS

01 02 03 04 05 06

EPA

SAMPLE NO. VSTD050CC01 VMBS01 VBLK01 MW-28 DUPE VSTD050CC02

LAB

SAMPLE ID

CCV-43946 LCS-43946 MB-43946 U0907195-001H U0907195-003H CCV2

LAB

FILE ID C28986.D C28987.D C28988.D C29000.D C29001.D C29002.D

DATE

ANALYZED

7/17/2009 7/17/2009 7/17/2009 7/18/2009 7/18/2009 7/18/2009

TIME

ANALYZED

19:43 20:22 21:01 4:47 5:26 6:04


- 6 2 -

3/90

5A VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK

BROMOFLUOROBENZENE (BFB)

Lab Name:

Lab Code:

Lab File ID:

Instrument ID: 12.0

Upstate Labs Inc.

10170 Case No.

C29003.D

Contract: Casella


7/19/2009

GC Column: RTX-VOLA ID: 053__ (mm)

BFB Injection Date:



m/e

50

75

95

96

173

174

175

176

177

ION ABUNDANCE CRITERIA

8.0 - 40.0% of mass 95

30.0 - 66.0% of mass 95 Base peak, 100% relative abundance


50.0 -120.0% of mass 95

4.0 - 9.0% of mass 174

93.0 -101.0% of mass 174

5.0 - 9.0% of mass 176

% RELATIVE

ABUNDANCE

24.2

50.7

100.0

6.8

0.0 ( 0-0)1 ______

4.7 ( 7.5)1

"6T^T~97JJT ~~4xT{ ^6)2

^ i U ^ % ^ a s s 174 2-Value is % mass 176

THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS

01 02 03 04 05 06 07 08 09

EPA

SAMPLE NO. VSTD050CC03 VMBS02 VBLK02 MW-29 MW-29MS MW-29MSD HOLD BLANK ULI TRIP BLANK

"VSTD050CC04"

LAB

SAMPLE ID CCV-43964 LCS-43964 MB-43964

LAB

FILE ID C29004.D C29005.D

U0907195-002H U0907195-002HMS U0907195-002HMSD U0907195-004A U0907195-005A CCV-43966

C29006.D C29007.D C29008.D C29009.D C29010.D C29011.D C29020.D

DATE

ANALYZED 7/19/2009 7/19/2009 7/19/2009 7/19/2009 7/19/2009 7/19/2009 7/19/2009 7/19/2009 7/19/2009

TIME

ANALYZED

11:51 12:52 13:32 14:12 14:51 15:29 16:08 16:47 22:38


- 6 3 -

3/90

8A VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY

Lab Name: m ^ J ^ ^ C ° n t r a C t ^ ^ Lab Code: 10170

Lab File ID (Standard):

Instrument ID: 12.0

Case No.:

C28986.D


GC Column: RTX-VOLAT ID: 0 5 3 _ (mm)

12 HOUR STD

UPPER LIMIT

LOWER LIMIT

01

02

03

04

EPA SAMPLE NO.

VMBS01

VBLK01

MW-28

DUPE

IS1(PFB)

AREA #

1223893

2447786

611947

1219869

1218202

1173461

1165508

RT #

9.92

10.42

9.42

9.91

9.90

10.01

10.02

IS2

AREA

1432078

2864156

716039

1414306

1422454

1427557

1419334



Heated Purge (Y/N): N

RT #

12.91

13.41

12.41

12.91

12.90

13.00

12.99

IS3

AREA #

1160691 2321382

580346

1182554

1183858

1166999

1147945

RT #

19.68 20.18

T97T8r

19.70

19.68

19.76

19.76

IS1 (PFB) IS2 IS3 IS4 (DCB)

= Pentafluorobenzene = 1,4-Difluorobenzene = Chlorobenzene-d5 = 1,4-Dichlorobenzene-d4

AREA UPPER LIMIT = +100% of internal standard area AREA LOWER LIMIT = - 50% of internal standard area RT UPPER LIMIT = +0.50 minutes of internal standard RT RT LOWER LIMIT = -0.50 minutes of internal standard RT

# Column to be used to flag values outside QC limit with an asterisk.

* Values outside of contract required QC limits

FORM VIII VOA page 1 of 2

-64-

3/90


Lab Name: Upstate Labs inc. .


Contract: Casella


Instrument ID: 12.0

GC Column:

C28986.D

RTX-VOLA ID: 0.53 (mm)

12 HOUR STD

UPPER LIMIT

LOWER LIMIT

01

02

03

04

EPA SAMPLE NO.

VMBS01

VBLK01

MW-28

DUPE

IS4(DCB)

AREA #

655007

1310014

327504

RT #

24.23

673307

661461

650786

649066

23.73

24.73

24.27

24.24

24.32

24.31




Heated Purge (Y/N): Y_

AREA # RT # AREA # RT #






page 2 of 2 FORM VIII VOA

- 6 5 -

3/90

Lab Name:

Lab Code:


Instrument ID: 12.0

GC Column

8A

VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY

Upstate Labs Inc. Contract: Casella

Case No.: SAS No

C29004.D

10170

RTX-VOLAT ID: 0.53 (mm)

12 HOUR STD

UPPER LIMIT

LOWER LIMIT

01

02

03

04

05

06

07

EPA SAMPLE NO.

VMBS02

VBLK02

MW-29

MW-29MS

MW-29MSD

HOLD BLANK

ULI TRIP BLANK

IS1(PFB)

AREA #

1250727

2501454

625364

1236178

1234994 1241237

1242438

1224384

1193310

1183524

RT #

9.91

10.41

9.41

9.87

9.98 9.84

9.78

9.79

9.78

9.78

IS2

AREA #

1463820

2927640 731910

1451149

1435504

1433057

1425409

1409767

1405474

1394154

SDG No.: CAS105



Heated Purge (Y/N): N

RT #

12.92

13.42

12.42

12.89

12.95 12.85

12.80

12.79

12.80

12.80

IS3

AREA #

1179853

2359706 589927

1191317

1171653

1158874

1169716

1161105

1123263

1119330

RT #

19.74

20.24 T 9 ^ T

19.71

19.72

19.62

19.59 19.59

19.59

19.59






page 1 of 2 FORM VIII VOA

- 6 6 -

3/90


Contract: Casella Lab Name: Upstate Labs Inc.

Lab Code: 10170 Case No.: ________ SAS No.:

Lab File ID (Standard): C29004.D

Instrument ID: 12.0

SDG No.: CAS105



Column: RTX-VOLA ID: 0.53

01

0?

03

04

05

06

07

12 HOUR STD

UPPER LIMIT

LOWER LIMIT

EPA SAMPLE NO.

VMBS02

VBLK02

MW-29

MW-29MS

MW-29MSD

HOLD BLANK

ULI TRIP BLA

IS4(DCB)

AREA #

666284

1332568

333142

685158

660865

654564

658076

650983

644672

635688

(mm) Heated Purge

RT #

24.31

23.81

24.81

24.27

24.27

24.16

24.13

24.13

24.14

24.13

AREA # RT #

j (Y/N): Y

AREA #

.

RT #

.. ..

...

151 (PFB) = Pentafluorobenzene 152 = 1,4-Difluorobenzene 153 = Chlorobenzene-d5 154 (DCB) = 1,4-Dichlorobenzene-d4




FORM VIII VOA page 2 of 2 3/90

-67-

U.S. EPA - CLP

2A

INITIAL AND CONTINUING CALIBRATION VERIFICATION

Lab Name: U£S t a t e L a l D o r a t o r i e s i _ J _ n c ^

Case No. SDG N o . : CAS105

Lab Code: 10170

i n i t i a l C a l i b r a t i o n V e r i f i c a t i o n S o u r c e :

• • r a i i b r a t i o n V e r i f i c a t i o n S o u r c e : CPI C o n t i n u i n g C a l i b r a t i o n ^ C o n c e n t r a t i o n U n i t s : ug /L

A n a l y t e

Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper I ron Lead Magnesium Manganese Nickel Potassium Selenium S i l ve r Sodium Thallium Vanadium Zinc

I n i t i a l C a l i b r a t e True Found %

10000.0 2500.0 500.0

10000.0 250.0 250.0

12500.0 500.0 2500.0 1250.0 5000.0 250.0

12500.0 750.0 2000.0

|12500.0| 250.0 500.0

12500.0 500.0 2500.0 1000.0

9247.87 2462.21 502.07

10299.91 253.98 249.21

12268.89 489.67

2431.26 1242.95 4796.92 231.83

12033.52 760.44 1979.63 11130.77

263.83 473.69

11896.47 496.22 2484.56 997.64

True

I6OO0T0 4800.0 2000.0 16000.0

400.0 1000.0 20000.0

800.0 4000.0 2000.0 8000.0 2000.0 20000.0 1200.0

C o n t i n u i n g C a l i b r a t i o n

Found %R(D F o u n d %R(D

99.0 89.0 105.5 94.7 95.2 99.2 99.4

320 2000

15839.80 4942.19 2452.68 16039.92 400.99 1017.82 20981.16 790.68 3980.47 1960.60 7904.31 1985.39 20479.99 1217.94

0.0 I 3235.10

2000. 800. 20000 2000 4000 1600

0 0 .0 0 0 .0

0.0 j 19824.39 2462.63 810.88

123.1 101.4

20420.45 102.1 1965.43 98.3 3978.89 99-5

1619.12 101.2

15945.87 5013.45 2457.88 16234.33 405.83 1027.23 21053.51 797.75 4016.11 1973.75 7985.52 1998.14 20619.48 1227.80 3256.44 19913.61 2457.03 816.35 20478.05 1963.70 4021.93 .635.34

Control Limits: Mercury 80-12 ,; Other Metals 90-110; Cyanide 8

5-115

M

FORM II (Part 1) - IN ILM04.1

•68-

U.S. EPA - CLP

2A INITIAL AND CONTINUING CALIBRATION VERIFICATION

Lab Name: Uostate Laboratorlegz-iB^ Contract: 448355


Initial Calibration Verification Source: SPEX

Continuing Calibration Verification Source: CPI

SDG No.: CAS105


Analyte

Antimony Arsenic

I n i t i a l C a l i b r a t i o n True Found %R(1)

2500.0 500.0

2597.91 531.78

103.9 106.4

True

Continuing Calibration

Found %R(1) Found %R(D

4800.0 2000.0

4533.50 1970.51

94.4 98.5

M

(1) Control Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115

FORM II (Part 1) IN ILM04.1

-69-

U.S. EPA

2A

CLP

INITIAL AND CONTINUING CALIBRATION VERIFICATION



Contract: 448355





Analyte

Boron

Initial Calibration

True Found %R(1)

10000.0 10025.65 100.3


True Found %R(1) Found %R(1)

5000.0 5332.31 106.6

M

P



-70-

U.S. EPA - CLP




Contract: 448355

SAS No.: SDG No.




CAS105

Analyte

Mercury

Initial Calibration True Found %R(1)

2.0 1.78 89.2

Continuing Calibration True Found %R(1) Found %R(1)

4.0 3.96 98.9 4.05 101.2

M

CV



-71-

U.S. EPA - CLP




Contract:

SAS No.:

448355

SDG No.: CAS105




Analyte

Mercury


2.0 1.85 92.3


True Found %R(1) Found %R(1)

4.0 3.92 98.1 3.61 90.4

M

CV



-72-

U.S. EPA - CLP


Lab Name: Upstate Laboratories, Inc. Contract:


448355

SDG No.




CAS105

Analyte

Cyanide


200.0 207.00 103.5

Continuing Calibration True Found %R(1) Found %R(1)

171.0 163.00 95.3 162.00 94.7

M

C



-73-

U.S. EPA - CLP

2B CRDL STANDARD FOR AA AND ICP



AA CRDL Standard Source: CPI

ICP CRDL Standard Source: SPEX

Contract: 448355

SAS No.: SDG No. CAS105


Analyte

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

CRDL Standard for AA

True Found %R

CRDL Standard for ICP Initial Final

True Found %R Found

0.0 120.0 20.0 0.0 10.0 10.0 0.0 20.0 100.0 50.0 0.0 6.0 0.0 30.0 80.0 0.0 10.0 20.0 0.0 20.0 100.0 40.0

9.43 129.62 25.31 0.25 10.80 9.66

-159.38 19.55 95.15 49.85 17.03

31.94 74.77 -14.59 18.04 16.98 -76.93 18.92 100.36 40.04

0.0 108.0 126.6 0.0

108.0 96.6 0.0 97.8 95.1 99.7 0.0

121.8 0.0

106.5 93.5 0.0

180.4 84.9 0.0 94.6 100.4 100.1

-0.45 123.91 21.36 0.13 10.80 9.59

128.35 19.87 96.22 49.40 15.59 6. 1.

31. 75.36 -13.65 12.94 18.12

-132.28 17.35 101:39 40.33

%R

0.0 103.3 106 0.0

108.0 95 0.0 99.4 96.2 98.8 0.0

115.8 0.0

106.3 94.2 0.0

129.4 90.6 0.0 86.8 101.4 100.8


-74-

U.S. EPA CLP






Contract: 448355



Analyte

Antimony Arsenic


True Found %R


True Found %R Found %R

120.0 20.0

115.29 25.70

96.1 128.5

133.34 27.60

111.1 138.0


-75-

U.S. EPA - CLP






Contract: 448355



Analyte

Boron


True Found %R



500.0 637.99 127.6 597.31 119.5


-76-

U.S. EPA - CLP






Contract: 448355

SAS No.: SDG No. : CAS105


Analyte

Mercury


True Found %R

0.2 0.18 88.6




-77-

U.S. EPA - CLP






Contract: 448355



Analyte

Mercury


True Found %R

0.2 0.24 117.8




•78-

U.S. EPA CLP


Lab Name: Upstate Laboratories, Inc,




Contract: 448355

SAS No.: SDG No. : CAS105


Analyte

Cyanide Cyanide


True Found %R

25.0 25.0

26.50 25.80

106.0 103.2




-79-

U.S. EPA - CLP

ICP SERIAL DILUTIONS




Dupe

SDG No.: CAS105



Analyte

Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

Initial Sample

Result (I) C

4757.33 30.00 10.00

137.64 3.00

500.00 5.00

226823.16 10.00 20.00 10.96

6181.28 3.00

55696.91 810.93 30.00

3865.82 5.00

10.00 50578.39

34.86 30.00 51.84

U U B U U U

U U B

U

U B U U

U

Serial Dilution

Result (S) C

500.00 150.00 50.00

250.00 15.00

2500.00 25.00

195848.63 50.00 100.00 50.00 391.03 15.00

55061.43 697.45 150.00

5000.00 25.00 50.00

48956.15 50.00 150.00 168.95

U U U U U U U

U U U

U

U U U U

U U

% Differ

ence

0.0

0.0

13.7

0.0 93.7

1.1 14.0

0.0

3.2 0.0

225.9

Q

E

E

E

M

P P P P P P P P p P P P P p P P P P P P P P P

FORM IX IN ILM04.1

-80-

U.S. EPA CLP

ICP SERIAL DILUTIONS

Lab Name: Upstate Laboratories, Inc. -Contract: 448355

Lab Code: 10170

Dupe[Diss]

Case No.


SAS No. SDG No. : CAS105



Analyte

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

Initial Sample

Result (I) c

100.OC 30.00 10.00

108.16 3.00 5.00

206648.26 10.00 20.00 10.00

262.45 3.00

51371.03 636.85 30.00

2573.48 5.00

10.00 50604.38

30.01 30.00 53.52

U U U B U U

U U U

U

U B U U

U

Serial

Dilution

Result (S) C

12689.28 150.00 50.00

250.00 15.00 25.00

220335.06 50.00

100.00 50.00

11330.71 15.00

63796.56 1019.75 150.00

5374.04 25.00 50.00

48475.33 50.00

150.00 56.67

U U U U U

U U U

U

U

U U

U U

%

Differ

ence

0.0

6. 6

4217.3

24.2 60.1

108.8

4.2 0.0

5.9

Q

E E

M

p p p p

P p p p p p p p p p p P p p p p p

P

FORM IX - IN ILM04.1

-81-

Upstate Laboratories, Inc. Date: 14-Aug-09

CLIENT:

Work Orde r :

Project:

Casella

U0907195

Ontario Co. LF Phase III (Cont. Wells)

Sample ID: MB-R43789

Client ID: 77777

Analyte Result

Color ND

Sample ID: U0907195-002ADUP SampType: DUP

Client ID: MW-29 Batch ID: R43789

Analyte Result

Color 10.00

ANALYTICAL QC SUMMARY REPORT T e s t C o d e : 110.2

SampType: MBLK

Batch ID: R43789

TestCode: 110.2

TestNo: E110.2

Units: UNITS Prep Date:

Analysis Date: 7/9/2009

PQL SPK value SPKRefVal ° / o R E C LowLimit HighLimit RPDRefVal

RunNo: 43789

SeqNo: 849198

%RPD RPDLimit Qual 5.00

TestCode: 110.2

TestNo: E110.2

Units: UNITS Prep Date:


RunNo: 43789

SeqNo: 849203

PQL SPK value SPKRefVal %REC LowLimit HighLimit RPDRefVal %RPD RPDLimit Qual

5.00 10 20

Qualifiers: E Value above quantitation range

ND Not Detected at the Reporting Limit H Holding times for preparation or analysis exceeded R RPD outside accepted recovery limits

J Analyte detected below quantitation limits S Spike Recovery outside accepted recovery limits

Page I of 72

I CM OO

I

CLIENT: Casella Work Order: U0907195



Client ID: 77777

Analyte

SampType: MBLK

Batch ID: R43998

Result

Residue, Dissolved (TDS) ND

Sample ID: LCS-R43998

Client ID: 77777

Analyte

SampType: LCS

Batch ID: R43998

Result

Residue, Dissolved (TDS) 895.0


Client ID: ZZZZZ Batch ID: R43998

Analyte Result




Analyte Result




Analyte Result

Residue, Dissolved (TDS) 1205

ANALYTICAL QC SUMMARY REPORT TestCode: 160.1

TestCode: 160.1

TestNo: E160.1

Units: mg/L Prep Date:


RunNo: 43998

SeqNo: 854747

PQL SPKva,ue SPKRefVal % R E C LowLimit HighLimit RPDRefVal o / o R P D R p D L i m j t Q u a [

25 " — ~

TestCode: 160.1

TestNo: E160.1



RunNo: 43998

SeqNo: 854748

PQL SPKva,ue SPKRefVal °/0REC LowLimit HighLimit RPDRefVal °/0RPD R P D L i m i t Q u a |

50 970 n m l ™ 7Z. — ' " ~ 92.3 78 123

TestCode: 160.1

TestNo: E160.1



RunNo: 43998

SeqNo: 854751

PQL SPKvalue SPKRefVal °/o R E C LowLimit HighLimit RPDRefVal % R P D R P D L i m i t Q u a |

25 422.5

TestCode: 160.1

TestNo: E160.1

1.19 25



I CO oo I

RunNo: 43998

SeqNo: 854763

PQL SPKvalue SPKRefVal Q/0REC LowLimit HighLimit RPDRefVal o / o R p D R p D U m i t Q u g |

25 422.5 25

TestCode: 160.1

TestNo: E160.1



RunNo: 43998

SeqNo: 854771

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal o / o R p D R p D U m i t Q u g |

25 1012 17.4 25


ND Not Detected at the Reporting Limit H Holding times for preparation or analysis exceeded

R RPD outside accepted recovery limits J Analyte detected below quantitation limits


Page 2 of 72



Sample ID: U0907195-Q02AMS SampType: MS


Analyte Result

Bromide 51.42



Analyte Result

Bromide ND



Analyte Result

Bromide ND



Analyte Result

Bromide ND



Analyte Result

Bromide ND

ANALYTICAL QC SUMMARY REPORT TestCode: 300 IC

TestCode: 3 0 0 J C

TestNo: E300.1



PQL SPKvalue S P K R e f V a l % R E C LowLimit HighLimit R P D R e f V a l

2.0 50

RunNo: 43820

SeqNo: 849881

%RPD RPDLimit Qual

103 75 125

TestCode: 3 0 0 J C

TestNo: E300.1



PQL SPKvalue S P K R e f V a l %REC LowLimit HighLimit R P D R e f V a l

2.0

RunNo: 43820

SeqNo: 849801

%RPD RPDLimit Qual

TestCode: 3 0 0 J C

TestNo: E300.1

0 20



PQL SPKvalue S P K R e f V a l % R E C LowLimit HighLimit R P D R e f V a l

2.0

RunNo: 43820

SeqNo: 849821

%RPD RPDLimit Qual

20

TestCode: 3 0 0 J C

TestNo: E300.1



RunNo: 43820

SeqNo: 849825

PQL SPKvalue S P K R e f V a ! %REC LowLimit HighLimit R P D R e f V a l o / o R P D R p D L J m J t Q u g |

2.0

TestCode: 3 0 0 J C

TestNo: E300.1

20




0.20

RunNo: 43820

SeqNo: 849852

%RPD RPDLimit Qual

0 20

I

OO I





Page 3 of 72





Analyte

Bromide

Sample ID: CCB1

Client ID: 77777

Analyte

Bromide

Sample ID: CCB2

Client ID: 77777

Analyte

Bromide

Sample ID: CCB3

Client ID: ZZZZZ

Analyte

Bromide

Sample ID: CCB4

Client ID: 77777

Analyte

Bromide

Result

ND

SampType: CCB

Batch ID: R43820

Result

ND

Result

ND

SampType: CCB

Batch ID: R43820

Result

ND

SampType: CCB

Batch ID: R43820

Result

ND


TestCode: 300JC

TestNo: E300.1



PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal

2.0

TestCode: 300JC

TestNo: E300.1

Units: mg/L


Prep Date:


0.20

SampType: CCB

Batch ID: R43820

TestCode: 300JC

TestNo: E300.1

Units: mg/L


Prep Date:


0.20

TestCode: 300JC

TestNo: E300.1




0.20

TestCode: 300JC

TestNo: E300.1 Prep Date:


Units: mg/L


O 2 0 ~ ~ • ~ " —

RunNo: 43820

SeqNo: 849880

%RPD RPDLimit Qual

20

RunNo: 43820

SeqNo: 849805

%RPD RPDLimit Qual

RunNo: 43820

SeqNo: 849818

%RPD RPDLimit Qual

RunNo: 43820

SeqNo: 849834

%RPD RPDLimit Qual

RunNo: 43820

SeqNo: 849846

%RPD RPDLimit Qual

I m 00

I





Page 4 of72



Sample ID: CCB5

Client ID: 77777

Analyte

Bromide

Sample ID: CCB6

Client ID: 77777

Analyte

Bromide

Sample ID: CCB7

Client ID: 77777

Analyte

Bromide

Sample ID: CCV1

Client ID: 77777

Analyte

Bromide

Sample ID: CCV2

Client ID: ZZZZZ

Analyte

Bromide

SampType: CCB

Batch ID: R43820

Result

ND

SampType: CCB

Batch ID: R43820

Result

ND

SampType: CCB

Batch ID: R43820

Result

ND

Result

4.978

SampType: CCV

Batch ID: R43820

Result

5.139

ANALYTICAL QC SUMMARY REPORT TestCode: 300_IC

TestCode: 300JC

TestNo: E300.1



RunNo: 43820

SeqNo: 849860

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal %R P D RPDLimit Qual

0.20

TestCode: 300JC

TestNo: E300.1



RunNo: 43820

SeqNo: 849872

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal % R P D RPDLimit Qual

0.20

TestCode: 300JC

TestNo: E300.1



RunNo: 43820

SeqNo: 849884


0.20

SampType: CCV

Batch ID: R43820

TestCode: 300JC

TestNo: E300.1

Units: mg/L


Prep Date:


RunNo: 43820

SeqNo: 849804

0.20 0 99.6

%RPD RPDLimit Qual

90 110

TestCode: 300JC

TestNo: E300.1



RunNo: 43820

SeqNo: 849817


0.20 103 90 110

I CO oo





Page 5 of 72

CLIENT: Casella

Work Order: U0907195


Sample ID: CCV3

Client ID: ZZZZZ

Analyte

Bromide

Sample ID: CCV4

Client ID: 77777

Analyte

Bromide

Sample ID: CCV5

Client ID: ZZZZZ

Analyte

Bromide

Sample ID: CCV6

Client ID: ZZZZZ

Analyte

Bromide

Sample ID: CCV7

Client ID: ZZZZZ

Analyte

Bromide

Result

5.132

SampType: CCV

Batch ID: R43820

Result

5.090

SampType: CCV

Batch ID: R43820

Result

4.991

Result

5.235

Result

5.076


SampType: CCV

Batch ID: R43820

TestCode: 300JC

TestNo: E300.1



RunNo: 43820

SeqNo: 849833

PQL SPKvalue SPKRefVal % R E C LowLimit HighLimit R PD R efVa l % R P D R P DLimit Qual

0.20 103 90 110

TestCode: 300JC

TestNo: E300.1



RunNo: 43820

SeqNo: 849845

PQL SPKvalue SPKRefVal %R E C LowLimit HighLimit RPDRefVal o / o R P D R p D L i m j t Q u g |

0.20 102 90 110

TestCode: 300JC

TestNo: E300.1



RunNo: 43820

SeqNo: 849859

PQL SPKvalue SPKRefVal % R E C LowLimit HighLimit RPDRefVal % R P D R P D L i m i t Q u a |

0.20 99.8 90 110

SampType: CCV

Batch ID: R43820

TestCode: 300JC

TestNo: E300.1



RunNo: 43820

SeqNo: 849871

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal » / o R p D R p D y m i t Q u g |

0.20 105 90

SampType: CCV

Batch ID: R43820

110

TestCode: 300JC

TestNo: E300.1



RunNo: 43820

SeqNo: 849883


0.20 102 90 110

1

oo I





Page 6 of 72

CLIENT: Casella



Sample ID: 1CB

Client ID: ZZZZZ

Analyte

Bromide

Sample ID: ICV

Client ID: 77777

Analyte

Bromide

SampType: ICB

Batch ID: R43820

Result

ND

Result

8.054

ANALYTICAL QC SUMMARY REPORT

TestCode: 300 IC

TestCode: 3 0 0 J C

TestNo: E300.1




0.20

SampType: ICV

Batch ID: R43820

TestCode: 3 0 0 J C

TestNo: E300.1




0.20 101 90 110

RunNo: 43820

SeqNo: 849791

%RPD RPDLimit Qual

RunNo: 43820

SeqNo: 849790

%RPD RPDLimit Qual

I OO CO

I

Qualifiers: E Value above quantitation range ND Not Detected at the Reporting Limit

H Holding times for preparation or analysis exceeded R RPD outside accepted recovery limits


Page 7 of 72

CLIENT: Casella

WorkOrder: U0907195


Sample ID: U0907195-002DMS SampType: MS


Analyte Result

Alkalinity, Total (As CaCQ3) 420.0

Sample ID: U0907128-021 BDUP SampType: DUP


Analyte Result


Sample ID: U0907128-023BDUP SampType: DUP


Analyte Result




Analyte Result


Sample ID: U0907131-020DDUP SampType: DUP


Analyte Result



TestCode: 310.2W

TestCode: 310.2W

TestNo: E310.2

Units: mg/LCaC03 Prep Date:


RunNo: 43750

SeqNo: 847870

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal %R P D R P D L i m i t Q u a l

10 50 37fi aan o^ 7L~. " " ~ ~ 88.0 27 138

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847777

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal o / o R p D R p D | J m J t Q u g |

10 282 1.06 15

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847781

PQL SPKvalue SPKRefVal % R E C LowLimit HighLimit RPDRefVal % R p D RPDLimit Qual

10 278 1.07 15

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847808

PQL SPKvalue SPKRefVal % R E C LowLimit HighLimit (RPDRefVal % R P D RPDLimit Qual

10 307 5.01 15

TestCode: 310.2W

TestNo: E310.2



PQL SPKvalue SPKRefVal %R£C LowLimit HighLimit R PD R efVa l

RunNo: 43750

SeqNo: 847848

%RPD RPDLimit Qual 10

275 0.364 15

I

oo I




Page 8 of 72

CLIENT: Casella Work Order: U0907195 Project: Ontario Co. LF Phase III (Cont. Wells)

Sample ID: U0907195-002DDUP SampType: DUP


Analyte Result

Alkalinity, Total (As CaC03) 381.0



Analyte Result




Analyte Result




Analyte Result




Analyte Result



TestCode: 310.2W

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847869

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal %RPD RPDLimit Qual

10 376 1.32 15

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847886

PQL SPKvalue SPKRefVal % R E C LowLimit HighLimit RPDRefVal %RPD RPDLimit Qual

10 181 3.26 15

TestCode: 310.2W

TestNo: E310.2




RunNo: 43750

SeqNo: 847932

%RPD RPDLimit Qual

10 50.4 11.6 15

TestCode: 310.2W

TestNo: E310.2




RunNo: 43750

SeqNo: 847935

%RPD RPDLimit Qual

10 427 0 15

TestCode: 310.2W

TestNo: E310.2



RunNo: 43751

SeqNo: 847942


100 613 0.163 15

I O CD I




Page 9 of 72


Sample ID: CCB1

Client ID: 77777

Analyte

Alkalinity, Total (As CaC03)

Sample ID: CCB2

Client ID: 77777

Analyte

Alkalinity, Total (As CaCQ3)

Sample ID: CCB3

Client ID: 77777

Analyte


Sample ID: CCB4

Client ID: 77777

Analyte


Sample ID: CCB5

Client ID: 77777

Analyte


SampType: CCB

Batch ID: R43750

Result

ND

SampType: CCB

Batch ID: R43750

Result

ND

SampType: CCB

Batch ID: R43750

Result

ND

SampType: CCB

Batch ID: R43750

Result

ND

SampType: CCB

Batch ID: R43750

Result

ND


TestCode: 310.2W

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847735


10

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847736


10

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847737


10

TestCode: 310.2W

TestNo: E310.2




RunNo: 43750

SeqNo: 847738

%RPD RPDLimit Qual

10

TestCode: 310.2W

TestNo: E310.2




RunNo: 43750

SeqNo: 847739

%RPD RPDLimit Qual

10

I




Page 10 of 72


Sample ID: CCB6

Client ID: ZZZZZ

Analyte

SampType: CCB

Batch ID: R43750

Result

Alkalinity, Total (As CaCQ3) ND

Sample ID: CCB7

Client ID: 77777

Analyte

SampType: CCB

Batch ID: R43750

Result


Sample ID: CCB8

Client ID: 77777

Analyte

SampType: CCB

Batch ID: R43750

Result


Sample ID: CCB9

Client ID: 77777.

Analyte

SampType: CCB

Batch ID: R43750

Result


Sample ID: CCB10

Client ID: 77777

Analyte

SampType: CCB

Batch ID: R43750

Result



TestCode: 310.2W

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847740


10

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847741


10

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847742


10

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847743

PQL SPKvalue SPKRefVal %R E C LowLimit HighLimit RPDRefVal %RPD RPDLimit Qual

10

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847744


10

I CM OJ

I





Page 11 of 72


Sample ID: CCB11

Client ID: 77777

Analyte

SampType: CCB

Batch ID: R43750

Result


Sample ID: CCB12

Client ID: 77777

Analyte Result


Sample ID: CCB13

Client ID: 77777

Analyte

SampType: CCB

Batch ID: R43750

Result


Sample ID: CCB14

Client ID: 77777

Analyte Result


Sample ID: CCB15

Client ID: ZZZZZ

Analyte

SampType: CCB

Batch ID: R43750

Result


ANALYTICAL QC SUMMARY REPORT TestCode: 310.2W

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847745


10

SampType: CCB TestCode: 310.2W Units: mg/LCaC03 Prep Date:

Batch ID: R43750 TestNo: E310.2 A n a , y s i s D a t e : 7 / 1 0 / 2 0 o g

RunNo: 43750

SeqNo: 847746


10

TestCode: 310.2W

TestNo: E310.2




RunNo: 43750

SeqNo: 847747



Batch ID: R43750 TestNo: E310.2 Analysis Date: 7/10/2009 RunNo: 43750

SeqNo: 847748


10

TestCode: 310.2W

TestNo: E310.2




RunNo: 43750

SeqNo: 847749


i CO OJ I





Page 12 of 72

CLIENT: Casella



Sample ID: CCB16

Client ID: ZZZZZ

Analyte


Sample ID: CCB17

Client ID: ZZZZZ

Analyte


Sample ID: CCB18

Client ID: 77777

Analyte


Sample ID: CCB19

Client ID: 77777

Analyte


Sample ID: CCB20

Client ID: 77777

Analyte


SampType: CCB

Batch ID: R43750

Result

ND

Result

ND

Result

ND

Result

ND

SampType: CCB

Batch ID: R43750

Result

ND


TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847750


10


Batch ID: R43750 TestNo: E310.2 Analysis Date: 7/10/2009


RunNo: 43750

SeqNo: 847751

%RPD RPDLimit Qual

10


Batch ID: R43750 TestNo: E310.2 Analysis Date: 7/10/2009


RunNo: 43750

SeqNo: 847752

%RPD RPDLimit Qual

10


Batch ID: R43750 TestNo: E310.2 Analysis Date: 7/10/2009 RunNo: 43750

SeqNo: 847753


10

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847754


10

I

OJ I





Page 13 of 72



Sample ID: CCB21

Client ID: 77777

Analyte

SampType: CCB

Batch ID: R43750

Result

Alkalinity, Total (As CaC03) ND

Sample ID: CCB22

Client ID: 77777

Analyte

SampType: CCB

Batch ID: R43750

Result


Sample ID: CCB1

Client ID: 77777

Analyte

SampType: CCB

Batch ID: R43751

Result


Sample ID: CCV1

Client ID: 77777

Analyte

SampType: CCV

Batch ID: R43750

Result


Sample ID: CCV2

Client ID: ZZZZZ

Analyte

SampType: CCV

Batch ID: R43750

Result



TestCode: 310.2W

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847755


10

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847756


10

TestCode: 310.2W

TestNo: E310.2




10

RunNo: 43751

SeqNo: 847947

%RPD RPDLimit Qual

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847713


10 25 111 81.9 116

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847714


10 250 102 81.9 116

I IO OJ

I





Page 14 of 72


Sample ID: CCV3

Client ID: ZZZZZ

Analyte


Sample ID: CCV4

Client ID: ZZZZZ

Analyte


Sample ID: CCV5

Client ID: 77777

Analyte


Sample ID: CCV6

Client ID: 77777

Analyte


Sample ID: CCV7

Client ID: 77777

Analyte


SampType: CCV

Batch ID: R43750

Result

513.0

SampType: CCV

Batch ID: R43750

Result

27.90

SampType: CCV

Batch ID: R43750

Result

257.0

SampType: CCV

Batch ID: R43750

Result

507.0

SampType: CCV

Batch ID: R43750

Result

26.30


TestCode: 310.2W

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847715


10 500 0 103 81.9 116

TestCode: 310.2W

TestNo: E310.2




RunNo: 43750

SeqNo: 847716

%RPD RPDLimit Qual

10 25 112 81.9 116

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847717


10 250 103 81.9 116

TestCode: 310.2W

TestNo: E310.2




RunNo: 43750

SeqNo: 847718

%RPD RPDLimit Qual

10 500 0 101 81.9 116

TestCode: 310.2W

TestNo: E310.2




RunNo: 43750

SeqNo: 847719

%RPD RPDLimit Qual

10 25 105 81.9 116

I CO OJ I





Page 15 of 72


Sample ID: CCV8

Client ID: 77777

Analyte

SampType: CCV

Batch ID: R43750

Result


Sample ID: CCV9

Client ID: ZZZZZ

Analyte

SampType: CCV

Batch ID: R43750

Result


Sample ID: CCV10

Client ID: ZZZZZ

Analyte

SampType: CCV

Batch ID: R43750

Result


Sample ID: CCV11

Client ID: 77777

Analyte

SampType: CCV

Batch ID: R43750

Result


Sample ID: CCV12

Client ID: 77777

Analyte

SampType: CCV

Batch ID: R43750

Result



TestCode: 310.2W

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847720


10 250 0 102 81.9 116

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847721

PQL SPKvalue SPKRefVal %R E C LowLimit HighLimit RPDRefVal % R P D RPDLimit Qual

10 500 99.4 81.9 116

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847722


10 25 94.8 81.9 116

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847723


10 250 0 101 81.9 116

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847724


10 500 101 81.9 116

I r-OJ I





Page 16 of 72



Sample ID: CCV13

Client ID: 77777

Analyte

SampType: CCV

Batch ID: R43750

Result


Sample ID: CCV14

Client ID: 77777

Analyte

SampType: CCV

Batch ID: R43750

Result


Sample ID: CCV15

Client ID: 77777

Analyte

SampType: CCV

Batch ID: R43750

Result


Sample ID: CCV16

Client ID: 77777

Analyte

SampType: CCV

Batch ID: R43750

Result


Sample ID: CCV17

Client ID: 77777

Analyte

SampType: CCV

Batch ID: R43750

Result



TestCode: 310.2W

TestNo: E310.2




10

RunNo: 43750

SeqNo: 847725

%RPD RPDLimit Qual

25 0 117 81.9 116

TestCode: 310.2W

TestNo: E310.2




10 250

RunNo: 43750

SeqNo: 847726

%RPD RPDLimit Qual

102 81.9 116

TestCode: 310.2W

TestNo: E310.2



PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPD Fief Val

RunNo: 43750

SeqNo: 847727

%RPD RPDLimit Qual 10 500 0 101 81.9 116

TestCode: 310.2W

TestNo: E310.2




10

RunNo: 43750

SeqNo: 847728

%RPD RPDLimit Qual 25 102 81.9 116

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847729

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal % R p D RPDLimit Qual

10 250 100 81.9 116

I OO OJ I





Page 17 of 72

CLIENT: Casella

Work Order : U0907195


Sample ID: CCV18

Client ID: ZZZZZ

Analyte

SampType: CCV

Batch ID: R43750

Result


Sample ID: CCV19

Client ID: ZZZZZ

Analyte

SampType: CCV

Batch ID: R43750

Result


Sample ID: CCV20

Client ID: 77777

Analyte

SampType: CCV

Batch ID: R43750

Result


Sample ID: CCV21

Client ID: 77777

Analyte

SampType: CCV

Batch ID: R43750

Result


Sample ID: CCV22

Client ID: ZZZZZ

Analyte

SampType: CCV

Batch ID: R43750

Result



TestCode: 310.2W

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847730


10 500 102 81.9 116

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847731


10 25 112 81.9 116

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847732


10 250 102 81.9 116

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847733


10 500 101 81.9 116

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847734


10 25 118 81.9 116

I OJ OJ

i





Page 18 of 72


Sample ID: CCV1

Client ID: 77777

Analyte

SampType: CCV

Batch ID: R43751

Result


Sample ID: ICB

Client ID: 77777

Analyte

SampType: ICB

Batch ID: R43750

Result


Sample ID: ICB

Client ID: 77777

Analyte

SampType: ICB

Batch ID: R43751

Result


Sample ID: ICV

Client ID: 77777

Analyte

SampType: ICV

Batch ID: R43750

Result


Sample ID: ICV

Client ID: 77777

Analyte

SampType: ICV

Batch ID: R43751

Result



TestCode: 310.2W

TestNo: E310.2




RunNo: 43751

SeqNo: 847946

%RPD RPDLimit Qual

10 250 94.0 81.9 116

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847712


10

TestCode: 310.2W

TestNo: E310.2



RunNo: 43751

SeqNo: 847937


10

TestCode: 310.2W

TestNo: E310.2



RunNo: 43750

SeqNo: 847711


10 21.6 0 97.2 86 109

TestCode: 310.2W

TestNo: E310.2




RunNo: 43751

SeqNo: 847936

%RPD RPDLimit Qual

10 21.6 96.8 86 109

I CD O




Page 19 of 72

CLIENT: Casella



Sample ID: U0907195-002AMS SampType: MS


Analyte Result

Chloride 107.0



Analyte Result

Chloride 24.30



Analyte Result

Chloride 132.0



Analyte Result

Chloride 2.300

Sample ID: U0S07133-001ADUP SampType: DUP


Analyte Result

Chloride 2.830

ANALYTICAL QC SUMMARY REPORT TestCode: 325.2 W

TestCode: 325.2_W

TestNo: E325.2

Units: mg/L

PQL SPKvalue SPKRefVal

Prep Date:


%REC LowLimit HighLimit RPDRefVal

RunNo: 43749

SeqNo: 847645

%RPD RPDLimit Qual

1.00 50 49.3 115 51.5 156

TestCode: 325.2_W

TestNo: E325.2

Units: mg/L


Prep Date:



RunNo: 43749

SeqNo: 847538

%RPD RPDLimit Qual

1.00 25 2.84 15

TestCode: 325.2_W

TestNo: E325.2

Units: mg/L


Prep Date: RunNo: 43749

Analysis Date: 7/10/2009 SeqNo: 847568

%REC LowLimit HighLimit RPDRefVal %RPD RPDLimit Qual

1.00 133 0.755 15

TestCode: 325.2_W

TestNo: E325.2

Units: mg/L





1.00 2.06 11.0 15

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847585


1.00 2.7 4.70 15

CD

I





Page 20 of 72


Sampte ID: U0907131-020ADUP SampType: DUP


Analyte Result

Chloride 94.50



Analyte Result

Chloride 48.90



Analyte Result

Chloride 32.00



Analyte Result

Chloride 475.0

Sample ID: U09O7130-061ADUP SampType: DUP


Analyte Result

Chloride 7.360


TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847623

PQL SPKvalue S P K R e f V a l %REC LowLimit HighLimit R P D R e f V a l %RPD RPDLimit Qual

1.00 94.9 0.422 15

TestCode: 325.2_W

TestNo: E325.2

Units: mg/L

PQL SPKvalue S P K R e f V a l

Prep Date:


%REC LowLimit HighLimit R P D R e f V a l

RunNo: 43749

SeqNo: 847644

%RPD RPDLimit Qual

1.00 49.3 0.815 15

TestCode: 325.2_W

TestNo: E325.2

Units: mg/L


Prep Date:



1.00

RunNo: 43749

SeqNo: 847658

%RPD RPDLimit Qual

32.6 1.86 15

1 CM O

TestCode: 325.2_W

TestNo: E325.2

Units: mg /L Prep Date:


RunNo: 43749

SeqNo: 847682


10.0 477 0.420 15

TestCode: 325.2_W

TestNo: E325.2

Units: mg /L

PQL SPKva lue S P K R e f V a l

Prep Date:



RunNo: 43749

SeqNo: 847705

%RPD RPDLimit Qual

1.00 7.98 8.08 15




Page 21 of 72



Sample ID: CCB1

Client ID: 77777

Analyte

Chloride

Sample ID: CCB2

Client ID: 77777

Analyte

Chloride

Sampte ID: CCB3

Client ID: 77777

Analyte

Chloride

Sampte ID: CCB4

Client ID: ZZZZZ

Analyte

Chloride

Sampte ID: CCB5

Client ID: 77777

Analyte

Chloride

Result

ND

SampType: CCB

Batch ID: R43749

Result

ND

SampType: CCB

Batch ID: R43749

Result

ND

SampType: CCB

Batch ID: R43749

Result

ND

SampType: CCB

Batch ID: R43749

Result

ND


TestCode: 325.2 W

SampType: CCB

Batch ID: R43749

TestCode: 325.2_W

TestNo: E325.2





1.00

RunNo: 43749

SeqNo: 847496

%RPD RPDLimit Qual

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847497


1.00

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847498


1.00

TestCode: 325.2_W

TestNo: E325.2

Units: mg/L


Prep Date:



RunNo: 43749

SeqNo: 847499


TestCode: 325.2_W

TestNo: E325.2

Units: mg/L


Prep Date:



RunNo: 43749

SeqNo: 847500


I CO

o





Page 22 of 72


Sample ID: CCB6

Client ID: 77777

Analyte

Chloride

Sample ID: CCB7

Client ID: 77777

Analyte

Chloride

Sample ID: CCB8

Client ID: 77777

Analyte

Chloride

Sample ID: CCB9

Client ID: 77777

Analyte

Chloride

Sample ID: CCB10

Client ID: 77777

Analyte

Chloride


TestCode: 325.2 W

SampType: CCB

Batch ID: R43749

TestCode: 325.2_W

TestNo: E325.2

Units: mg/L

Result

ND

SampType: CCB

Batch ID: R43749

Result

ND

SampType: CCB

Batch ID: R43749

Result

ND

SampType: CCB

Batch ID: R43749

Result

ND

SampType: CCB

Batch ID: R43749

Result

ND


Prep Date:



1.00

RunNo: 43749

SeqNo: 847501

%RPD RPDLimit Qual

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847502


1.00

TestCode: 325.2_W

TestNo: E325.2

Units: mg/L


Prep Date:



RunNo: 43749

SeqNo: 847503

%RPD RPDLimit Qual

1.00

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847504


1.00

TestCode: 325.2_W

TestNo: E325.2

Units: mg/L


Prep Date:



1.00

RunNo: 43749

SeqNo: 847505

%RPD RPDLimit Qual

I " * •

O





Page 23 of 72

CLIENT: Casella

Work Orde r : U0907195


Sampte ID: CCB11

Client ID: 77777

Analyte

Chloride

Sample ID: CCB12

Client ID: 77777

Analyte

Chloride

Sampte ID: CCB13

Client ID: 77777

Analyte

Chloride

Sampte ID: CCB14

Client ID: 77777

Analyte

Chloride

Sample ID: CCB15

Client ID: 77777

Analyte

Chloride

SampType: CCB

Batch ID: R43749

Result

ND

SampType: CCB

Batch ID: R43749

Result

ND

SampType: CCB

Batch ID: R43749

Result

ND

SampType: CCB

Batch ID: R43749

Result

ND

SampType: CCB

Batch ID: R43749

Result

ND


TestCode: 325.2 W

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847506


1.00

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847507


1.00

TestCode: 325.2_W

TestNo: E325.2

Units: mg/L


Prep Date:



RunNo: 43749

SeqNo: 847508


TestCode: 325.2_W

TestNo: E325.2




%REC LowLimit HighLimit FlPDRefVal

1.00

RunNo: 43749

SeqNo: 847509

%RPD RPDLimit Qual

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847510


1.00

I m CD





Page 24 of 72



Sample ID: CCB16

Client ID: 77777

Analyte

Chloride

Sample ID: CCB17

Client ID: 77777

Analyte

Chloride

Sample ID: CCB18

Client ID: 77777

Analyte

Chloride

Sample ID: CCB19

Client ID: 77777

Analyte

Chloride

Sample ID: CCB20

Client ID: 77777

Analyte

Chloride

SampType: CCB

Batch ID: R43749

Result

ND

SampType: CCB

Batch ID: R43749

Result

ND

SampType: CCB

Batch ID: R43749

Result

ND

SampType: CCB

Batch ID: R43749

Result

ND

SampType: CCB

Batch ID: R43749

Result

ND


TestCode: 325.2 W

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847511

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal % R P D R P DLimit Qual

1.00

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847512

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal <>/oRPD R p D U m j t Q u g |

1.00

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847513


1.00

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847514

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal %RPD RPDLimit Qua!

1.00

TestCode: 325.2_W

TestNo: E325.2




RunNo: 43749

SeqNo: 847515


I

O




Page 25 of 72



Sample ID: CCB21

Client ID: 77777

Analyte

Chloride

Sample ID: CCB22

Client ID: 2ZZZZ

Analyte

Chloride

Sample ID: CCV1

Client ID: 77777

Analyte

Chloride

Sampte ID: CCV2

Client ID: 77777

Analyte

Chloride

Sampte ID: CCV3

Client ID: 77777

Analyte

Chloride

SampType: CCB

Batch ID: R43749

Result

ND

SampType: CCB

Batch ID: R43749

Result

ND

SampType: CCV

Batch ID: R43749

Result

18.60

SampType: CCV

Batch ID: R43749

Result

168.0

SampType: CCV

Batch ID: R43749

Result

298.0


TestCode: 325.2 W

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847516

PQL SPKvalue SPKRefVal ° / o R E C LowLimit HighLimit RPDRefVal %RPD RPDLimit Qual

1.00

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847517


1.00

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847474


1.00 20 93.0 83.2 119

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847475


1.00 150 112 83.2 119

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847476


1.00 300 99.3 83.2 119

I

O




Page 26 of 72

CLIENT: Casella



Sample ID: CCV4

Client ID: 77777

Analyte

Chloride

Sample ID: CCV5

Client ID: ZZZZZ

Analyte

Chloride

Sample ID: CCV6

Client ID: 77777

Analyte

Chloride

Sample ID: CCV7

Client ID: ZZZZZ

Analyte

Chloride

Sample ID: CCV8

Client ID: ZZZZZ

Analyte

Chloride


T e s t C o d e : 325.2 W

SampType: CCV

Batch ID: R43749

Result

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847477

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit R PD R efVa l %RPD IRPDLimit Qual

18.80 1.00 20 94.0 83.2 119

SampType: CCV

Batch ID: R43749

Result

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847478


169.0 1.00 150 113 83.2 119

SampType: CCV

Batch ID: R43749

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847479

Result PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal %RPD RPDLimit Qual

297.0 1.00 300 99.0 83.2 119

SampType: CCV

Batch ID: R43749

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847480

Result PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal %RPD RPDLimit Qual

18.70 1.00 20 93.5 83.2 119

SampType: CCV

Batch ID: R43749

TestCode: 325.2_W

TestNo: E325.2

Units: mg/L

Result PQL SPKvalue S P K R e f V a l

Prep Date:



170.0

RunNo: 43749

SeqNo: 847481

%RPD RPDLimit Qual

1.00 150 113 83.2 119

I OO

o





Page 27 of 72



Sample ID: CCV9

Client ID: ZZZZZ

Analyte

Chloride

Sampte ID: CCV10

Client ID: ZZZZZ

Analyte

Chloride

Sampte ID: CCV11

Client ID: 77777

Analyte

Chloride

Sample ID: CCV12

Client ID: 77777

Analyte

Chloride

Sample ID: CCV13

Client ID: ZZZZZ

Analyte

Chloride

SampType: CCV

Batch ID: R43749

Result

297.0

SampType: CCV

Batch ID: R43749

Result

19.00

SampType: CCV

Batch ID: R43749

Result

169.0

SampType: CCV

Batch ID: R43749

Result

301.0

SampType: CCV

Batch ID: R43749

Result

19.00


TestCode: 325.2 W

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847482


1.00 300 99.0 83.2 119

TestCode: 325.2_W

TestNo: E325.2





1.00

RunNo: 43749

SeqNo: 847483

%RPD RPDLimit Qual 20 95.0 83.2 119

TestCode: 325.2_W

TestNo: E325.2

Units: mg/L


Prep Date:



1.00

RunNo: 43749

SeqNo: 847484

%RPD RPDLimit Qual

150 113 83.2 119

TestCode: 325.2_W

TestNo: E325.2

Units: mg/L


Prep Date:



RunNo: 43749

SeqNo: 847485

%RPD RPDLimit Qual 1.00 300 100 83.2 119

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847486


1.00 20 95.0 83.2 119

I OJ CD





Page 28 of 72



Sample ID: CCV14

Client ID: 77777

Analyte

Chloride

Sample ID: CCV15

Client ID: 77777

Analyte

Chloride

Sample ID: CCV16

Client ID: 77777

Analyte

Chloride

Sample ID: CCV17

Client ID: 77777

Analyte

Chloride

Sample ID: CCV18

Client ID: ZZZZZ

Analyte

Chloride

Result

169.0

SampType: CCV

Batch ID: R43749

Result

301.0

SampType: CCV

Batch ID: R43749

Result

19.20

SampType: CCV

Batch ID: R43749

Result

170.0

SampType: CCV

Batch ID: R43749

Result

296.0


TestCode: 325.2 W

SampType: CCV

Batch ID: R43749

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847487

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal %RPD RPDLimit Qual 1.00 150 113 83.2 119

TestCode: 325.2_W

TestNo: E325.2




RunNo: 43749

SeqNo: 847488

%RPD RPDLimit Qual 1.00 300 0 100 83.2 119

TestCode: 325.2_W

TestNo: E325.2

Units: mg/L


Prep Date:


RunNo: 43749

SeqNo: 847489

%RPD RPDLimit Qual 1.00 20 96.0 83.2 119

TestCode: 325.2_W

TestNo: E325.2




RunNo: 43749

SeqNo: 847490


TestCode: 325.2_W

TestNo: E325.2




RunNo: 43749

SeqNo: 847491

%RPD RPDLimit Qual 1.00 300 98.7 83.2 119

I O





Page 29 of 72


Sampte ID: CCV19

Client ID: 77777

Analyte

Chloride

Sampte ID: CCV20

Client ID: 77777

Analyte

Chloride

Sampte ID: CCV21

Client ID: 77777

Analyte

Chloride

Sampte ID: CCV22

Client ID: 77777

Analyte

Chloride

Sampte ID: ICB

Client ID: 77777

Analyte

Chloride

SampType: CCV

Batch ID: R43749

Result

18.90

SampType: CCV

Batch ID: R43749

Result

169.0

SampType: CCV

Batch ID: R43749

Result

300.0

SampType: CCV

Batch ID: R43749

Result

19.00

SampType: ICB

Batch ID: R43749

Result

ND


TestCode: 325.2 W

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847492

PQL SPKvalue SPKRefVal % R E C LowLimit HighLimit RPDRefVal o / oRPD R p D U m i t Q u g |

1.00 20 94.5 83.2 119

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847493


1.00 150 113 83.2 119

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847494


1.00 300 100 83.2 119

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847495


1.00 20 95.0 83.2 119

TestCode: 325.2_W

TestNo: E325.2



RunNo: 43749

SeqNo: 847473


1.00





Page 30 of 72



Sample ID: ICV

Client ID: 77777

Analyte

SampType: ICV

Batch ID: R43749

TestCode: 325.2_W

TestNo: E325.2

Units: mg/L

Result


TestCode: 325.2 W

Prep Date:


RunNo: 43749

SeqNo: 847472

Chloride PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal %RPD RPDLimit Qual

43.70 1.00 38.6 113 91 .116

CM

T




Page 31 of 72


Sample ID: MB

Client ID: 77777

Analyte

SampType: MBLK

Batch ID: R43900

Result

Nitrogen, Ammonia (As NH3) ND

Sampte ID: LCS

Client ID: 77777

Analyte

SampType: LCS

Batch ID: R43900

Result

Nitrogen, Ammonia (As NH3) 6.260

Sample ID: U0907195-002BMS SampType: MS


Analyte Result


Sample ID: U0907128-021CDUP SampType: DUP


Analyte Result


Sample ID: U0S07130-016CDUP SampType: DUP


Analyte Result



TestCode: 350.1 W

TestCode: 350.1_W

TestNo: E350.1



RunNo: 43900

SeqNo: 851809


0.500

TestCode: 350.1_W

TestNo: E350.1



RunNo: 43900

SeqNo: 851810

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal <>/oRpD R P D L i m j t Q u a |

0.500 6.35 98.6 71.6 129

TestCode: 350.1_W

TestNo: E350.1





0.500

RunNo: 43848

SeqNo: 850641

%RPD RPDLimit Qual

0 124 60 135

TestCode: 350.1_W

TestNo: E350.1



RunNo: 43848

SeqNo: 850560


0.500 0 25

TestCode: 350.1_W

TestNo: E350.1



RunNo: 43848

SeqNo: 850588


0.500 25

I CO





Page 32 of 72





Analyte Result


Sampte ID: U0907130-040CDUP SampType: DUP


Analyte Result




Analyte Result





Analyte Result



TestCode: 350.1_W

TestNo: E350.1



RunNo: 43848

SeqNo: 850592

PQL SPKvalue SPKRefVal % R E C LowLimit HighLimit RPDRefVal % R P D R P D L i m i t Q u a l

0.500 25

TestCode: 350.1_W

TestNo: E350.1



RunNo: 43848

SeqNo: 850611

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal o / o R p D R p D L i m i t Q u g |

0.500 0 25

TestCode: 350.1_W

TestNo: E350.1



RunNo: 43848

SeqNo: 850631


0.500

Sample ID: U0907133-001 CDUP

Client ID: ZZZZZ

Analyte

SampType: DUP

Batch ID: R43848

Result

25

TestCode: 350.1_W

TestNo: E350.1



RunNo: 43848

SeqNo: 850635

PQL SPKvalue SPKRefVal % R E C LowLimit HighLimit RPDRefVal o / o R p D R p D L j m J t Q u g (

0.500 0 25

TestCode: 350.1_W

TestNo: E350.1



RunNo: 43848

SeqNo: 850640

PQL SPKvalue SPKRefVal %R E C LowLimit HighLimit RPDRefVal -> /oRpD R p D U m f t Q u g |

0.500 25

I <3"





Page 33 of 72





Analyte Result




Analyte Result


Sample ID: CCB1

Client ID: 7777.7

Analyte

SampType: CCB

Batch ID: R43900

Result


Sample ID: CCB2

Client ID: 77777

Analyte

SampType: CCB

Batch ID: R43900

Result


Sample ID: CCB3

Client ID: ZZZZZ

Analyte

Nitrogen, Ammonia (As NH3)

SampType: CCB

Batch ID: R43900

Result

ND


TestCode: 350.1 W

TestCode: 350.1_W

TestNo: E350.1

Units: mg/L

PQL SPKvalue SPKRefVal % R E C LowLimit HighLimit RPDRefVal

Prep Date:


0.500

RunNo: 43900

SeqNo: 851763

%RPD RPDLimit Qual

0.911 0.330 25

TestCode: 350.1_W

TestNo: E350.1



RunNo: 43900

SeqNo: 851793

PQL SPKvalue SPKRefVal °/0REC LowLimit HighLimit RPDRefVal o / o R p D RpDum Q u g |

0.500 4.26

TestCode: 350.1_W

TestNo: E350.1

0.235 25



RunNo: 43900

SeqNo: 851760

PQL SPKvalue SPKRefVal %R E C LowLimit HighLimit RPDRefVal % R P D RPDLimit Qual

0.500

TestCode: 350.1_W

TestNo: E350.1

Units: mg/L

I U3

Prep Date:



0.500

RunNo: 43900

SeqNo: 851776

%RPD RPDLimit Qual

TestCode: 350.1_W

TestNo: E350.1



RunNo: 43900

SeqNo: 851800

PQL SPKvalue SPKRefVal Q/0REC LowLimit HighLimit RPDRefVal o / o R p D R p D U m j t Q u g |

0.500





Page 34 of 72

CLIENT: Casella



Sample ID: CCB4

Client ID: 77777

Analyte

SampType: CCB

Batch ID: R43900

Result


Sampte ID: CCB5

Client ID: ZZZZZ

Analyte

SampType: CCB

Batch ID: R43900

Result


Sample ID: CCV1

Client ID: 77777 .

Analyte

SampType: CCV

Batch ID: R43900

Result


Sample ID: CCV2

Client ID: 77777

Analyte

SampType: CCV

Batch ID: R43900

Result


Sample ID: CCV3

Client ID: 77777

Analyte

SampType: CCV

Batch ID: R43900

Result



TestCode: 350.1 W

TestCode: 350.1_W

TestNo: E350.1




0.500

RunNo: 43900

SeqNo: 851812

%RPD RPDLimit Qual

TestCode: 350.1_W

TestNo: E350.1

Units: mg/L


Prep Date:


RunNo: 43900

SeqNo: 851816


TestCode: 350.1_W

TestNo: E350.1




0.500 1 103 90 110

TestCode: 350.1_W

TestNo: E350.1

Units: mg/L


Prep Date:


0.500 15 108 90 110

TestCode: 350.1_W

TestNo: E350.1

Units: mg/L

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit- RPDRefVal

Prep Date:


0.500 30 108 90 110

RunNo: 43900

SeqNo: 851759

%RPD RPDLimit Qual

RunNo: 43900

SeqNo: 851774

%RPD RPDLimit Qual

RunNo: 43900

SeqNo: 851799

%RPD RPDLimit Qual

I t o





Page 35 of 72

CLIENT: Casella

W o r k Order : U0907195


Sample ID: CCV4

Client ID: 77777

Analyte

Nitrogen, Ammonia (As NH3)

SampType: CCV

Batch ID: R43900

Result

1.040

Sample ID: CCV5

Client ID: 77777

Analyte

SampType: CCV

Batch ID: R43900

Result

Nitrogen, Ammonia (As NHS) 16.40

Sampte ID: ICB

Client ID: ZZZZZ

Analyte

SampType: ICB

Batch ID: R43900

Result


Sampte ID: ICV

Client ID: 77777

Analyte

SampType: ICV

Batch ID: R43900

Result



TestCode: 350.1 W

TestCode: 350.1_W

TestNo: E350.1



RunNo: 43900

SeqNo: 851811


0.500 1 0 104 90 110

TestCode: 350.1_W

TestNo: E350.1



RunNo: 43900

SeqNo: 851815

PQL SPKvalue SPKRefVal % R E C LowLimit HighLimit RPDRefVal o / o R P D R p D l J m i t Q u g |

0.500 15 109 90 110

TestCode: 350.1_W

TestNo: E350.1



RunNo: 43900

SeqNo: 851738

PQL SPKvalue SPKRefVal %R E C LowLimit HighLimit RPDRefVal %R P D RPDLimit Qual

0.500

TestCode: 350.1_W

TestNo: E350.1

Units: mg/L


Prep Date:



0.500

RunNo: 43900

SeqNo: 851737

%RPD RPDLimit Qual

10.6 116 74 125

I r-





Page 36 of 72

CLIENT: Casella



Sample ID: MB1

Client ID: ZZZZZ

Analyte

Nitrogen, Kjeldahl, Total

Sampte ID: MB2

Client ID: 77777

Analyte


Sampte ID: MB3

Client ID: 77777

Analyte


Sample ID: MB4

Client ID: 77777

Analyte


Sample ID: MB5

Client ID: ZZZZZ

Analyte


SampType: MBLK

Batch ID: R43848

Result

ND

SampType: MBLK

Batch ID: R43848

Result

ND

SampType: MBLK

Batch ID: R43848

Result

ND

SampType: MBLK

Batch ID: R43848

Result

ND

SampType: MBLK

Batch ID: R43848

Result

ND

ANALYTICAL QC SUMMARY REPORT T e s t C o d e : 351.2 W

TestCode: 351.2_W



Units: mg/L


0.500

RunNo: 43848

SeqNo: 850532

%RPD RPDLimit Qual

TestCode: 351.2_W

TestNo: E351.2



RunNo: 43848

SeqNo: 850534


0.500

TestCode: 351.2_W

TestNo: E351.2




0.500

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


Prep Date:


0.500

TestCode: 351.2_W

TestNo: E351.2




0.500

RunNo: 43848

SeqNo: 850536

%RPD RPDLimit Qual

RunNo: 43848

SeqNo: 850538

%RPD RPDLimit Qual

RunNo: 43848

SeqNo: 850540

%RPD RPDLimit Qual

I OO




Page 37 of 72

CLIENT: Casella



Sample ID: MB6

Client ID: ZZZZZ

Analyte


Sample ID: MB7

Client ID: 77777

Analyte


Sampte ID: MB8

Client ID: 77777

Analyte


Sampte ID: LCS1

Client ID: 77777

Analyte


Sampte ID: LCS2

Client ID: 77777

Analyte


SampType: MBLK

Batch ID: R43848

Result

ND

SampType: MBLK

Batch ID: R43848

Result

ND

SampType: MBLK

Batch ID: R43848

Result

ND

SampType: LCS

Batch ID: R43848

Result

8.830

SampType: LCS

Batch ID: R43848

Result

8.450


TestCode: 351.2 W

TestCode: 351.2_W

TestNo: E351.2



RunNo: 43848

SeqNo: 850542


0.500

TestCode: 351.2_W

TestNo: E351.2





0.500

RunNo: 43848

SeqNo: 850544

%RPD RPDLimit Qual

TestCode: 351.2_W

TestNo: E351.2


Units: mg/L Prep Date: R u n N o : 4 3 8 4 8



0.500 %RPD RPDLimit Qual

TestCode: 351,2_W

TestNo: E351.2





0.500 7.15

RunNo: 43848

SeqNo: 850533

%RPD RPDLimit Qual

123 64 126

TestCode: 351.2_W

TestNo: E351.2



RunNo: 43848

SeqNo: 850535


0.500 7.15 118 64 126

I OJ





Page 38 of 72



Sampte ID: LCS3

Client ID: ZZZZZ

Analyte


Sample ID: LCS4

Client ID: 77777

Analyte


Sample ID: LCS5

Client ID: 77777

Analyte


Sample ID: LCS6

Client ID: 77777

Analyte


Sample ID: LCS7

Client ID: 77777

Analyte


SampType: LCS

Batch ID: R43848

Result

8.350

SampType: LCS

Batch ID: R43848

Result

7.950

SampType: LCS

Batch ID: R43848

Result

7.850

SampType: LCS

Batch ID: R43848

Result

8.240

SampType: LCS

Batch ID: R43848

Result

8.000


TestCode: 351.2 W

TestCode: 351 .2_W

TestNo: E351.2

Units: mg/L


0.500

Prep Date:



RunNo: 43848

SeqNo: 850537

%RPD RPDLimit Qual

7.15 117 64 126

TestCode: 351 .2_W

TestNo: E351.2

Units: mg/L


0.500 7.15

TestCode: 351 .2_W

TestNo: E351.2

Units: mg/L


0.500 7.15

TestCode: 351 .2_W

TestNo: E351.2

Units: mg/L


0.500 7.15

TestCode: 351 .2_W

TestNo: E351.2

Units: mg/L


0.500 7.15

Prep Date:


RunNo: 43848

SeqNo: 850539

%REC LowLimit HighLimit R P D R e f V a l %RPD RPDLimit Qual

111 64 126

Prep Date:



RunNo: 43848

SeqNo: 850541

%RPD RPDLimit Qual

110 64 126

Prep Date:


RunNo: 43848

SeqNo: 850543


115 64 126

Prep Date:


RunNo: 43848

SeqNo: 850545


112 64 126

I O CM




Page 39 of 72


Sample ID: LCS8

Client ID: 77777

Analyte

SampType: LCS

Batch ID: R43848

Result

Nitrogen, Kjeldahl, Total 7.520

Sampte ID: U0907195-002BMS SampType: MS


Analyte Result


Sampte ID: U0907128-021 CDUP SampType: DUP

Client ID: 77777 Batch ID: R43848

Analyte Result

Nitrogen, Kjeldahl, Total ND



Analyte Result




Analyte Result



TestCode: 351.2 W

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


Prep Date:



RunNo: 43848

SeqNo: 850547

%RPD RPDLimit Qual

0.500 7.15 105 64 126

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


Prep Date:



RunNo: 43848

SeqNo: 850525

%RPD RPDLimit Qual

0.500 124 70 130

TestCode: 351.2_W

TestNo: E351.2





RunNo: 43848

SeqNo: 850423

%RPD RPDLimit Qual

0.500 19

TestCode: 351.2_W

TestNo: E351.2



RunNo: 43848

SeqNo: 850427


0.500 1.13 9.26 19

TestCode: 351.2_W

TestNo: E351.2





RunNo: 43848

SeqNo: 850464

%RPD RPDLimit Qual

0.500 0 19

I

T





Page 40 of 72




Analyte Result




Analyte Result




Analyte Result


Sample ID: U0907133-001 CDUP SampType: DUP


Analyte Result


Sampte ID: U0907195-002BDUP SampType: DUP


Analyte Result



TestCode: 351.2 W

TestCode: 351.2_W

TestNo: E351.2





0.500

RunNo: 43848

SeqNo: 850468

%RPD RPDLimit Qual

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


0.500

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


0.500

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


0.500

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


0.500

0 19

Prep Date:



RunNo: 43848

SeqNo: 850492

%RPD RPDLimit Qual

0 19

Prep Date:



RunNo: 43848

SeqNo: 850515

%RPD RPDLimit Qual

19

Prep Date:


RunNo: 43848

SeqNo: 850519


0 19

Prep Date:



RunNo: 43848

SeqNo: 850524

%RPD RPDLimit Qual

19

I CSI CM





Page 41 of 72



Sample ID: CCB1

Client ID: 77777

Analyte


Sample ID: CCB2

Client ID: ZZZZZ

Analyte


Sampte ID: CCB3

Client ID: 77777

Analyte


Sample ID: CCB4

Client ID: ZZZZZ

Analyte


Sample ID: CCB5

Client ID: 77777

Analyte


SampType: CCB

Batch ID: R43848

Result

ND

SampType: CCB

Batch ID: R43848

Result

ND

SampType: CCB

Batch ID: R43848

Result

ND

SampType: CCB

Batch ID: R43848

Result

ND

SampType: CCB

Batch ID: R43848

Result

ND


TestCode: 351.2 W

TestCode: 351.2_W

TestNo: E351.2



RunNo: 43848

SeqNo: 850324


0.500

TestCode: 351.2_W

TestNo: E351.2

Units: mg /L


Prep Date:



RunNo: 43848

SeqNo: 850326

%RPD RPDLimit Qual

0.500

TestCode: 351.2_W

TestNo: E351.2




RunNo: 43848

SeqNo: 850328

%RPD RPDLimit Qual

0.500

TestCode: 351.2_W

TestNo: E351.2



RunNo: 43848

SeqNo: 850330


0.500

TestCode: 351.2_W

TestNo: E351.2



RunNo: 43848

SeqNo: 850332


0.500

CO CM





Page 42 of 72

CLIENT: Casella



Sampte ID: CCB6

Client ID: ZZZZZ

Analyte


Sample ID: CCB7

Client ID: 77777

Analyte


Sample ID: CCB8

Client ID: ZZZZZ

Analyte


Sample ID: CCB9

Client ID: 77777

Analyte


Sampte ID: CCB10

Client ID: 77777

Analyte


SampType: CCB

Batch ID: R43848

Result

ND

SampType: CCB

Batch ID: R43848

Result

ND

SampType: CCB

Batch ID: R43848

Result

ND

SampType: CCB

Batch ID: R43848

Result

ND

SampType: CCB

Batch ID: R43848

Result

ND


TestCode: 351.2 W

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


Prep Date:



RunNo: 43848

SeqNo: 850334

%RPD RPDLimit Qual

0.500

TestCode: 351.2_W

TestNo: E351.2



RunNo: 43848

SeqNo: 850336


0.500

TestCode: 351.2_W

TestNo: E351.2





0.500

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


Prep Date:



0.500

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


Prep Date:



0.500

RunNo: 43848

SeqNo: 850338

%RPD RPDLimit Qual

RunNo: 43848

SeqNo: 850340

%RPD RPDLimit Qual

RunNo: 43848

SeqNo: 850342

%RPD RPDLimit Qual

I

CM





Page 43 of 72

CLIENT: Casella


Project: Ontario Co. LF Phase HI (Cont. Wells)

Sample ID: CCB11

Client ID: 77777

Analyte


Sampte ID: CCB12

Client ID: 77777

Analyte


Sampte ID: CCB13

Client ID: 77777

Analyte


Sampte ID: CCB14

Client ID: 77777

Analyte


Sampte ID: CCB15

Client ID: ZZZZZ

Analyte


SampType: CCB

Batch ID: R43848

Result

ND

SampType: CCB

Batch ID: R43848

Result

ND

SampType: CCB

Batch ID: R43848

Result

ND

SampType: CCB

Batch ID: R43848

Result

ND

SampType: CCB

Batch ID: R43848

Result

ND


TestCode: 351.2 W

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


Prep Date:



0.500

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


Prep Date:



0.500

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


Prep Date:



0.500

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


Prep Date:



0.500

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


Prep Date:



0.500

RunNo: 43848

SeqNo: 850346

%RPD RPDLimit Qual

RunNo: 43848

SeqNo: 850349

%RPD RPDLimit Qual

RunNo: 43848

SeqNo: 850351

%RPD RPDLimit Qual

RunNo: 43848

SeqNo: 850353

%RPD RPDLimit Qual

RunNo: 43848

SeqNo: 850355

%RPD RPDLimit Qual

I m CM





Page 44 of 72


Sample ID: CCB16

Client ID: 77777

Analyte


Sample ID: CCV1

Client ID: 77777

Analyte


Sample ID: CCV2

Client ID: 77777

Analyte


Sample ID: CCV3

Client ID: 77777

Analyte


Sample ID: CCV4

Client ID: ZZZZZ

Analyte


SampType: CCB

Batch ID: R43848

Result

ND

SampType: CCV

Batch ID: R43848

Result

9.960

SampType: CCV

Batch ID: R43848

Result

4.900

SampType: CCV

Batch ID: R43848

Result

9.940

SampType: CCV

Batch ID: R43848

Result

4.930


TestCode: 351.2 W

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


Prep Date:


%REC LowLimit HighLimit RPD Ref Val

RunNo: 43848

SeqNo: 850357

%RPD RPDLimit Qual

0.500

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


Prep Date:



RunNo: 43848

SeqNo: 850323

%RPD RPDLimit Qual

0.500 10 99.6 90 110

TestCode: 351.2_W

TestNo: E351.2





0.500

RunNo: 43848

SeqNo: 850325

%RPD RPDLimit Qual

98.0 90 110

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L





0.500 10 99.4 90 110

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


Prep Date:



RunNo: 43848

SeqNo: 850329

%RPD RPDLimit Qual

0.500 98.6 90 110

CO CM





Page 45 of 72

CLIENT: Casella


Project: Ontario Co. LF Phase III (Cont. WeUs)

Sample ID: CCV5

Client ID: 77777

Analyte


Sampte ID: CCV6

Client ID: 77777

Analyte


Sampte ID: CCV7

Client ID: ZZZZZ

Analyte


Sampte ID: GCV8

Client ID: 77777

Analyte


Sample ID: CCV9

Client ID: 77777

Analyte


SampType: CCV

Batch ID: R43848

Result

10.00

SampType: CCV

Batch ID: R43848

Result

5.150

SampType: CCV

Batch ID: R43848

Result

9.970

SampType: CCV

Batch ID: R43848

Result

5.140

SampType: CCV

Batch ID: R43848

Result

10.10


TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


Prep Date:



0.500 10

RunNo: 43848

SeqNo: 850331

%RPD RPDLimit Qual

100 90 110

TestCode: 351.2_W

TestNo: E351.2



RunNo: 43848

SeqNo: 850333


0.500 103 90 110

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


Prep Date:



RunNo: 43848

SeqNo: 850335

%RPD RPDLimit Qual 0.500 10 99.7 90 110

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


Prep Date:



RunNo: 43848

SeqNo: 850337

%RPD RPDLimit Qual 0.500 103 90 110

TestCode: 351.2_W

TestNo: E351.2



RunNo: 43848

SeqNo: 850339


0.500 10 101 90 110

I

CM





Page 46 of 72



Sampte ID: CCV10

Client ID: ZZZZZ

Analyte


Sampte ID: CCV11

Client ID: 77777

Analyte


Sample ID: CCV12

Client ID: ZZZZZ

Analyte


Sample ID: CCV13

Client ID: 77777

Analyte


Sample ID: CCV14

Client ID: 77777

Analyte


SampType: CCV

Batch ID: R43848

Result

5.040

SampType: CCV

Batch ID: R43848

Result

10.20

SampType: CCV

Batch ID: R43848

Result

5.030

SampType: CCV

Batch ID: R43848

Result

10.20

SampType: CCV

Batch ID: R43848

Result

5.020


TestCode: 351.2 W

TestCode: 351.2_W

TestNo: E351.2



RunNo: 43848

SeqNo: 850341

PQL SPKvalue SPKRefVal % R E C LowLimit HighLimit RPDRefVal <>/oRPD R P D L i m J t Q u g |

0.500 101 90 110

TestCode: 351.2_W

TestNo: E351.2



RunNo: 43848

SeqNo: 850343


0.500 10 102 90 110

TestCode: 351.2_W

TestNo: E351.2



RunNo: 43848

SeqNo: 850348

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal %RPD RPDLimit Qua!

0.500 101 90 110

TestCode: 351.2_W

TestNo: E351.2



RunNo: 43848

SeqNo: 850350

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal o / o R p D R p D U m j t Q u g |

0.500 10 102 90 110

TestCode: 351.2_W

TestNo: E351.2



RunNo: 43848

SeqNo: 850352


0.500 100 90 110

I OO CM





Page 47 of 72

CLIENT: Casella



Sample ID: CCV15

Client ID: ZZZZZ

Analyte


Sampte ID: CCV16

Client ID: 77777

Analyte


Sample ID: ICB

Client ID: 77777

Analyte


Sample ID: ICV

Client ID: 77777

Analyte


SampType: CCV

Batch ID: R43848

Result

10.00

SampType: CCV

Batch ID: R43848

Result

5.140

SampType: ICB

Batch ID: R43848

Result

ND

SampType: ICV

Batch ID: R43848

Result

24.80


TestCode: 351.2_W

TestNo: E351.2



RunNo: 43848

SeqNo: 850354

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit R PD R efVa l %RPD RPDLimit Qual

0.500 10 100 90 110

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


Prep Date:



RunNo: 43848

SeqNo: 850356

%RPD RPDLimit Qual

0.500 103 90 110

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


Prep Date:



RunNo: 43848

SeqNo: 850322

%RPD RPDLimit Qual

0.500

TestCode: 351.2_W

TestNo: E351.2

Units: mg/L


Prep Date:



0.500

RunNo: 43848

SeqNo: 850321

%RPD RPDLimit Qual

25 99.2 90 110

I OJ





Page 48 of 72





Analyte Result

Nitrogen, Nitrate (as N) 1.890



Analyte Result

Nitrogen, Nitrate (as N) 0.6820



Analyte Result

Nitrogen, Nitrate (as N) ND

Sample ID: U0907128-021 ADUP SampType: DUP


Analyte Result

Nitrogen, Nitrate (as N) ND

Sample ID: CCB2

Client ID: 77777

Analyte

Nitrogen, Nitrate (as N)

SampType: CCB

Batch ID: R43732

Result

ND


TestCode: 353.2_WN03

TestCode: 353.2_WN03 Units: mg/L




0.200

RunNo: 43732

SeqNo: 847992

%RPD RPDLimit Qual

94.5 35 125




RunNo: 43732

SeqNo: 847961

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal o / o R p D R p D L J m i t Q u g |

0.200 0.671 1.63 20 H




PQL SPKvalue SPKRefVal %R E C LowLimit HighLimit RPDRefVal

0.200

RunNo: 43732

SeqNo: 847991

%RPD RPDLimit Qual

20




RunNo: 43732

SeqNo: 848022


0.200


TestNo: E353.2

20

Prep Date:



RunNo: 43732

SeqNo: 847958


I O CO





Page 49 of 72

CLIENT: Casella




TestCode: 353.2 W N 0 3

Sample ID: CCB2

Client ID: ZZZZZ

Analyte


Sample ID: CCB3

Client ID: 77777

Analyte


Sampte ID: CCB4

Client ID: ZZZZZ

Analyte


Sample ID: CCB5

Client ID: 77777

Analyte


Sample ID: CCB5

Client ID: 77777

Analyte


SampType: CCB

Batch ID: R43732

Result

ND

SampType: CCB

Batch ID: R43732

Result

ND

SampType: CCB

Batch ID: R43732

Result

ND

SampType: CCB

Batch ID: R43732

Result

ND

SampType: CCB

Batch ID: R43732

Result

ND


TestNo: E353.2

Prep Date:


RunNo: 43732

SeqNo: 847972


0.200


TestNo: E353.2


Prep Date:



0.200

RunNo: 43732

SeqNo: 847986

%RPD RPDLimit Qual


TestNo: E353.2

Prep Date:


RunNo: 43732

SeqNo: 848002


0.200


TestNo: E353.2

Prep Date:



RunNo: 43732

SeqNo: 848004

%RPD RPDLimit Qual

0.200


TestNo: E353.2


Prep Date:



RunNo: 43732

SeqNo: 848016

%RPD RPDLimit Qual

0.200

I

CO

T





Page 50 of 72

CLIENT: Casella



Sample ID: CCB6

Client ID: 77777

Analyte


Sample ID: CCV1

Client ID: 77777

Analyte


Sample ID: CCV2

Client ID: ZZZZZ

Analyte


Sample ID: CCV3

Client ID: 77777

Analyte


Sample ID: CCV4

Client ID: 77777

Analyte


SampType: CCB

Batch ID: R43732

Result

ND

SampType: CCV

Batch ID: R43732

Result

11.20

SampType: CCV

Batch ID: R43732

Result

20.30

SampType: CCV

Batch ID: R43732

Result

0.9170

SampType: CCV

Batch ID: R43732

Result

11.20


TestCode: 353.2 WN03




RunNo: 43732

SeqNo: 848025


0.200




RunNo: 43732

SeqNo: 847957


0.200 10 0 112 85 115


TestNo: E353.2

Prep Date:


PQL SPKvalue SPKRefVal %REC LowLimit HighLimit R PD R efVa l

RunNo: 43732

SeqNo: 847971

%RPD RPDLimit Qual 0.200 20 102 85 115




RunNo: 43732

SeqNo: 847985


0.200 1 0 91.7 85 115




RunNo: 43732

SeqNo: 848001


0.200 10 112 85 115

I CN CO




Page 51 of 72



Sample ID: CCV5

Client ID: ZZZZZ

Analyte


Sampte ID: CCV5

Client ID: ZZZZZ

Analyte


Sample ID: CCV6

Client ID: 77777

Analyte


Sample ID: ICB

Client ID: ZZZZZ

Analyte


Sample ID: ICV

Client ID: 77777

Analyte


SampType: CCV

Batch ID: R43732

Result

1.070

SampType: CCV

Batch ID: R43732

Result

20.10

SampType: CCV

Batch ID: R43732

Result

0.9100

SampType: ICB

Batch ID: R43732

Result

ND

SampType: ICV

Batch ID: R43732

Result

4.110


TestCode: 353.2 WN03


TestNo: E353.2

Prep Date:


RunNo: 43732

SeqNo: 848003

PQL SPKvalue SPKRefVal % R E C LowLimit HighLimit RPDRefVal » / o R P D R p D L j m J t Q u g j

0.200 1 0 107 85 115


TestNo: E353.2

Prep Date:


RunNo: 43732

SeqNo: 848015


0.200 20 0 100 85 115


TestNo: E353.2

Prep Date:


RunNo: 43732

SeqNo: 848024


0.200 1 0 91.0 85 115


TestNo: E353.2

Prep Date:


RunNo: 43732

SeqNo: 847333


0.200


TestNo: E353.2




%REC LowLimit HighLimit RPDRefVal %RPD RPDLimit Qual 0.200 3.8 108 77 119

I CO CO

T





Page 52 of 72

CLIENT: Casella



Sampte ID: U0907195-002AMS SampType: MS


Analyte Result

Sulfate 408.3



Analyte

Sulfate

Sample ID: CCB

Client ID: 77777

Analyte

Sulfate

Sample ID: CCB

Client ID: ZZZZZ

Analyte

Sulfate

Sample ID: CCV

Client ID: 77777

Analyte

Sulfate

Result

348.4

SampType: CCB

Batch ID: R44109

Result

1.052

SampType: CCB

Batch ID: R44109

Result

1.152

SampType: CCV

Batch ID: R44109

Result

28.75


T e s t C o d e : 375.4 W

TestCode: 375.4_W

TestNo: E375.4



RunNo: 44109

SeqNo: 857313


50.0 100 331.4 76.9 29.3 158

TestCode: 375.4_W

TestNo: E375.4

Units: mg/L


Prep Date:



RunNo: 44109

SeqNo: 857312

%RPD RPDLimit Qual

50.0 331.4 4.99 10

TestCode: 375.4_W

TestNo: E375.4



RunNo: 44109

SeqNo: 857324


5.00

TestCode: 375.4_W

TestNo: E375.4

Units: mg/L


Prep Date:



RunNo: 44109

SeqNo: 857336

%RPD RPDLimit Qual

5.00

TestCode: 375.4_W

TestNo: E375.4

Units: mg/L


Prep Date:



RunNo: 44109

SeqNo: 857323

%RPD RPDLimit Qual

5.00 30 95.8 87.6 117

I

CO





Page 53 of 72


Sample ID: CCV

Client ID: 77777

Analyte

Sulfate

Sample ID: ICB

Client ID: 77777

Analyte

Sulfate

Sampte ID: ICV

Client ID: 77777

Analyte

Sulfate

SampType: CCV

Batch ID: R44109

Result

52.61

SampType: ICB

Batch ID: R44109

Result

0.7025

SampType: ICV

Batch ID: R44109

Result

24.56


TestCode: 375.4 W

TestCode: 375.4_W

TestNo: E375.4




5.00 60 87.7 87.6 117

TestCode: 375.4_W



Units: mg/L


5.00 " ~ " ~ ~ —

TestCode: 375.4_W

TestNo: E375.4

Units: mg/L


Prep Date:


5.00 25.8 95.2 77 118

RunNo: 44109

SeqNo: 857335

%RPD RPDLimit Qual

RunNo: 44109

SeqNo: 857310

%RPD RPDLimit Qual

RunNo: 44109

SeqNo: 857309

%RPD RPDLimit Qual I in co




Page 54 of 72



Sampte ID: MB-R43881

Client ID: 77777

Analyte

SampType: MBLK

Batch ID: R43881

Result

Biochemical Oxygen Demand ND

Sampte ID: LCS-R43881

Client ID: 77777

Analyte

SampType: LCS

Batch ID: R43881

Result

Biochemical Oxygen Demand 202.0

Sampte ID: U0907128-021 ADUP SampType: DUP


Analyte Result




Analyte Result

Biochemical Oxygen Demand 7.000



Analyte Result


TestCode: 405.1

TestNo: E405.1

Units: mg/L


4.00

TestCode: 405.1

TestNo: E405.1

Units: mg/L


4.00 200

TestCode: 405.1

TestNo: E405.1

Units: mg/L


4.00

TestCode: 405.1

TestNo: E405.1

Units: mg/L


4.00

TestCode: 405.1

TestNo: E405.1

Units: mg/L


4.00


TestCode: 405.1

Prep Date:



RunNo: 43881

SeqNo: 851175

%RPD RPDLimit Qual

Prep Date:



101 59.4 122

Prep Date:



Prep Date:



Prep Date:



RunNo: 43881

SeqNo: 851176

%RPD RPDLimit Qual

RunNo: 43881

SeqNo: 851206

%RPD RPDLimit Qual

20

RunNo: 43881

SeqNo: 851209

%RPD RPDLimit Qual

20

RunNo: 43881

SeqNo: 851246

%RPD RPDLimit Qual

20

I CO CO





Page 55 of 72





Analyte Result




Analyte Result




Analyte Result


Sample ID: U0907130-061 ADUP SampType: DUP


Analyte Result



TestCode: 405.1

TestCode: 405.1

TestNo: E405.1

Units: mg/L


Prep Date:


RunNo: 43881

SeqNo: 851281


0 20

TestCode: 405.1

TestNo: E405.1



RunNo: 43881

SeqNo: 851305

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal o / o R P D R p D L i m i t Q u g |

4.00 0 20

TestCode: 405.1

TestNo: E405.1



RunNo: 43881

SeqNo: 851328


4.00 0 20

TestCode: 405.1

TestNo: E405.1




RunNo: 43881

SeqNo: 851350


0 20

I

co





Page 56 of 72

CLIENT: Casella




Client ID: 77777

Analyte

Chemical Oxygen Demand

Sampte ID: MB-R44133

Client ID: 77777

Analyte



Client ID: 77777

Analyte



Client ID: 77777

Analyte


SampType: MBLK

Batch ID: R44133

Result

ND

SampType: MBLK

Batch ID: R44133

Result

ND

SampType: LCS

Batch ID: R44133

Result

31.41

SampType: LCS

Batch ID: R44133

Result

33.62

Sampte ID: U0907195-002BMS SampType: MS


Analyte Result

Chemical Oxygen Demand 76.69


TestCode: 410.4

TestNo: E410.4



RunNo: 44133

SeqNo: 857698


20.0

TestCode: 410.4

TestNo: E410.4



RunNo: 44133

SeqNo: 857743


20.0

TestCode: 410.4

TestNo: E410.4



RunNo: 44133

SeqNo: 857699


20.0 35.5 88.5 69 106

TestCode: 410.4

TestNo: E410.4



RunNo: 44133

SeqNo: 857744


20.0 35.5 94.7 69 106

TestCode: 410.4

TestNo: E410.4



RunNo: 44133

SeqNo: 857758


20.0 50 25.96 101 60 140

I CO CO




Page 57 of 72



TestCode: 410.4



Analyte Result

Chemical Oxygen Demand ND



Analyte Result


Sampte ID: U0907195-002BDUP SampType: DUP


Analyte Result


Sample ID: CCB1

Client ID: ZZZZZ

Analyte

SampType: CCB

Batch ID: R44133

Result


Sampte ID: CCB2

Client ID: 77777

Analyte

SampType: CCB

Batch ID: R44133

Result


TestCode: 410.4

TestNo: E410.4

Units: mg/L





20.0 0 15

TestCode: 410.4

TestNo: E410.4



RunNo: 44133

SeqNo: 857750


20.0 21.09 2.40 15

TestCode: 410.4

TestNo: E410.4

Units: mg/L


Prep Date:



RunNo: 44133

SeqNo: 857757

%RPD RPDLimit Qual

20.0 25.96 2.68 15

TestCode: 410.4

TestNo: E410.4

Units: mg/L


Prep Date:



RunNo: 44133

SeqNo: 857712

%RPD RPDLimit Qual

20.0

TestCode: 410.4

TestNo: E410.4





RunNo: 44133

SeqNo: 857739

%RPD RPDLimit Qual

20.0

I OJ CO





Page 58 of 72

CLIENT: Casella



Sampte ID: CCB3

Client ID: 77777

Analyte

SampType: CCB

Batch ID: R44133

Result


Sampte ID: CCB4

Client ID: 77777

Analyte

SampType: CCB

Batch ID: R44133

Result


Sampte ID: CCV1

Client ID: 77777

Analyte


Sample ID: CCV2

Client ID: 77777

Analyte


Sample ID: CCV3

Client ID: 77777

Analyte


SampType: CCV

Batch ID: R44133

Result

37.31

SampType: CCV

Batch ID: R44133

Result

83.26

SampType: CCV

Batch ID: R44133

Result

37.18


TestCode: 410.4

TestCode: 410.4

TestNo: E410.4



RunNo: 44133

SeqNo: 857760

PQL SPKvalue SPKRefVal % R E C LowLimit HighLimit RPDRefVal % R P D RPDLimit Qual

20.0

TestCode: 410.4

TestNo: E410.4



RunNo: 44133

SeqNo: 857785

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal » / o R P D R p D U m j t Q u g |

20.0

TestCode: 410.4

TestNo: E410.4



RunNo: 44133

SeqNo: 857711


20.0 50 74.6 74.5 126

TestCode: 410.4

TestNo: E410.4



RunNo: 44133

SeqNo: 857738

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal » / o R P D R p D U m i t Q u g |

20.0 75 111 74.5 126

TestCode: 410.4

TestNo: E410.4



RunNo: 44133

SeqNo: 857759


20.0 50 74.4 74.5 126

I O





Page 59 of 72

CLIENT: Casella



Sample ID: CCV4

Client ID: ZZZZZ

Analyte

SampType: CCV

Batch ID: R44133

Result


Sample ID: ICB

Client ID: 77777

Analyte

SampType: ICB

Batch ID: R44133

Result


Sampte ID: ICB

Client ID: ZZZZZ

Analyte


Sampte ID: ICV

Client ID: ZZZZZ

Analyte


Sample ID: ICV

Client ID: 77777

Analyte


SampType: ICB

Batch ID: R44133

Result

ND

SampType: ICV

Batch ID: R44133

Result

106.4

SampType: ICV

Batch ID: R44133

Result

98.78


TestCode: 410.4

TestNo: E410.4



RunNo: 44133

SeqNo: 857784

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal % R p D RPDLimit Qual

20.0 75 108 74.5 126

TestCode: 410.4

TestNo: E410.4



RunNo: 44133

SeqNo: 857697


20.0

TestCode: 410.4

TestNo: E410.4

Units: mg/L


Prep Date:



20.0

RunNo: 44133

SeqNo: 857741

%RPD RPDLimit Qual

TestCode: 410.4

TestNo: E410.4

Units: mg/L


Prep Date:



RunNo: 44133

SeqNo: 857696


TestCode: 410.4

TestNo: E410.4



RunNo: 44133

SeqNo: 857740


20.0 100 98.8 79.6 122

I

T





Page 60 of 72



Sampte ID: U0907195-002CMS SampType: MS


Analyte Result

Organic Carbon, Total 20.69

Sample ID: U0907133-001 EDUP SampType: DUP


Analyte Result

Organic Carbon, Total ND



Analyte Result

Organic Carbon, Total ND



Analyte Result


Sampte ID: U0907237-001DDUP SampType: DUP


Analyte Result



TestCode: 415.1

TestCode: 415.1

TestNo: E415.1

Units: mg/L


Prep Date:



RunNo: 43902

SeqNo: 851906

%RPD RPDLimit Qual

3.00 20 103 60 130

TestCode: 415.1

TestNo: E415.1

Units: mg/L


Prep Date:



RunNo: 43902

SeqNo: 851896

%RPD RPDLimit Qual

3.00 0 15

TestCode: 415.1

TestNo: E415.1

Units: mg/L


Prep Date:



RunNo: 43902

SeqNo: 851905

%RPD RPDLimit Qual

3.00 15

TestCode: 415.1

TestNo: E415.1

Units: mg/L


Prep Date:



RunNo: 43902

SeqNo: 851912

%RPD RPDLimit Qual

150 370.2 10.2 15

TestCode: 415.1

TestNo: E415.1



RunNo: 43902

SeqNo: 851921


3.00 3.1 5.55 15

I CM •si-





Page 61 of 72

CLIENT: Casella



Sampte ID: U0907238-002DDUP SampType: DUP


Analyte

Organic Carbon, Total

Sampte ID: CCB1

Client ID: 77777

Analyte


Sampte ID: CCB2

Client ID: 77777

Analyte


Sample ID: CCB3

Client ID: ZZZZZ

Analyte


Sampte ID: CCB4

Client ID: ZZZZZ

Analyte


Result

7.112

SampType: CCB

Batch ID: R43902

Result

ND

SampType: CCB

Batch ID: R43902

Result

ND

SampType: CCB

Batch ID: R43902

Result

ND

SampType: CCB

Batch ID: R43902

Result

ND


TestCode: 415.1

TestCode: 415.1

TestNo: E415.1

Units: mg/L


Prep Date:



RunNo: 43902

SeqNo: 851934


7.061 0.720 15

TestCode: 415.1

TestNo: E415.1

Units: mg /L


Prep Date:



RunNo: 43902

SeqNo: 851900

%RPD RPDLimit Qual

3.00

TestCode: 415.1

TestNo: E415.1

Units: mg/L


Prep Date:



RunNo: 43902

SeqNo: 851915

%RPD RPDLimit Qual

3.00

TestCode: 415.1

TestNo: E415.1

Units: mg/L


Prep Date:



RunNo: 43902

SeqNo: 851931

%RPD RPDLimit Qual

3.00

TestCode: 415.1

TestNo: E415.1



RunNo: 43902

SeqNo: 851945


3.00

I OO "5f





Page 62 of 72

CLIENT: Casella



Sample ID: CCB5

Client ID: 77777

Analyte


Sampte ID: CCV1

Client ID: ZZZZZ

Analyte


Sample ID: CCV2

Client ID: 77777

Analyte


Sample ID: CCV3

Client ID: ZZZZZ

Analyte


Sample ID: CCV4

Client ID: 77777

Analyte


SampType: CCB

Batch ID: R43902

Result

ND

SampType: CCV

Batch ID: R43902

Result

17.51

SampType: CCV

Batch ID: R43902

Result

39.47

SampType: CCV

Batch ID: R43902

Result

17.95

SampType: CCV

Batch ID: R43902

Result

40.17


TestCode: 415.1

TestCode: 415.1

TestNo: E415.1



RunNo: 43902

SeqNo: 852150


3.00

TestCode: 415.1

TestNo: E415.1

Units: mg/L


Prep Date:



RunNo: 43902

SeqNo: 851899

%RPD RPDLimit Qual 3.00 20 0 87.6 85 115

TestCode: 415.1

TestNo: E415.1

Units: mg/L


Prep Date:



3.00

RunNo: 43902

SeqNo: 851914

%RPD RPDLimit Qual

40 0 98.7 85 115

TestCode: 415.1

TestNo: E415.1

Units: mg/L


Prep Date:



RunNo: 43902

SeqNo: 851930

%RPD RPDLimit Qual

3.00 20 89.8 85 115

TestCode: 415.1

TestNo: E415.1

Units: mg/L





3.00 40 100 85 115

I





Page 63 of 72

CLIENT: Casella



Sample ID: CCV5

Client ID: ZZZZZ

Analyte


Sampte ID: ICB

Client ID: ZZZZZ

Analyte


Sampte ID: JCB2

Client ID: 77777

Analyte


Sample ID: ICV

Client ID: 77777

Analyte


Sampte ID: ICV2

Client ID: ZZZZZ

Analyte


SampType: CCV

Batch ID: R43902

Result

55.38

SampType: ICB

Batch ID: R43902

Result

ND

SampType: ICB

Batch ID: R43902

Result

ND

SampType: ICV

Batch ID: R43902

Result

11.25

SampType: ICV

Batch ID: R43902

Result

11.65


T e s t C o d e : 415.1

TestCode: 415.1

TestNo: E415.1




RunNo: 43902

SeqNo: 851953

%RPD RPDLimit Qual 3.00 40 138 85 115

TestCode: 415.1

TestNo: E415.1



RunNo: 43902

SeqNo: 851886

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal o / o R p D R p D U m i t Q u g |

3.00

TestCode: 415.1

TestNo: E415.1



RunNo: 43902

SeqNo: 851917


3.00

TestCode: 415.1

TestNo: E415.1



RunNo: 43902

SeqNo: 851885

PQL SPKvalue SPKRefVal % R E C LowLimit HighLimit RPDRefVal o / o R p D R p D L i m J t Q u g |

3.00 12.2 92.2 88 122

TestCode: 415.1

TestNo: E415.1



RunNo: 43902

SeqNo: 851916


3.00 12.2 95.5 88 122

I

m





Page 64 of 72

CLIENT: Casella




Sample ID: MB-18372

Client ID: ZZZZZ

Analyte

SampType: MBLK

Batch ID: 18372

TestCode: 420.4

TestNo: E420.4

Units: mg/L

(E420.4)

Prep Date: 7/15/2009


RunNo: 43939

SeqNo: 852626

Result PQL SPKvalue SPKRefVal

Phenolfcs, Total Recoverable ND 0.00500


Sample ID: LCS-18372

Client ID: ZZZZZ

Analyte

SampType: LCS

Batch ID: 18372

Result

TestCode: 420.4

TestNo: E420.4

Units: mg/L

(E420.4)


Phenolics, Total Recoverable

Prep Date: 7/15/2009 RunNo: 43939



0.1200 0.00500

%RPD RPDLimit Qual

0.147 0 81.6 38.1 123.8

Sampte ID: UO907195-002FMS SampType: MS

Client ID: MW-29 Batch ID: 18372

TestCode: 420.4

TestNo: E420.4

Units: mg/L

(E420.4)

Analyte Result PQL SPKvalue SPKRefVal





0.05140 0.00500

RunNo: 43939

SeqNo: 852645

%RPD RPDLimit Qual

0.05 0 103 75 125

Sample ID: U0907195-002FDUP SampType: DUP

Client ID: MW-29 Batch ID: 18372

TestCode: 420.4

TestNo: E420.4

Units: mg/L

(E420.4)






ND 0.00500

RunNo: 43939

SeqNo: 852644

%RPD RPDLimit Qual

10

Sampte ID: U0907130-018EDUP SampType: DUP

Client ID: ZZZZZ Batch ID: 18372

TestCode: 420.4

TestNo: E420.4

Units: mg/L

(E420.4)






ND 0.00500

RunNo: 43939

SeqNo: 852649

%RPD RPDLimit Qual

0 10

I t o





Page 65 of 72

CLIENT: Casella



Sample ID: CCB1

Client ID: 77777

Analyte

SampType: CCB

Batch ID: R43939

Result

Phenolics, Total Recoverable ND

Sampte ID: CCB2

Client ID: ZZZZZ

Analyte

SampType: CCB

Batch ID: R43939

Result


Sampte ID: CCB3

Client ID: 77777

Analyte

SampType: CCB

Batch ID: R43939

Result


Sampte ID: CCB4

Client ID: ZZZZZ

Analyte

SampType: CCB

Batch ID: R43939

Result


Sample ID: CCB5

Client ID: ZZZZZ

Analyte

SampType: CCB

Batch ID: R43939

Result


TestCode: 420.4

TestNo: E420.4

Units: mg/L

ND


0.00500

TestCode: 420.4

TestNo: E420.4

Units: mg/L


0.00500

TestCode: 420.4

TestNo: E420.4

Units: mg/L


0.00500

TestCode: 420.4

TestNo: E420.4

Units: mg/L


0.00500

TestCode: 420.4

TestNo: E420.4

Units: mg/L



0.00500

Prep Date:



RunNo: 43939

SeqNo: 852579

%RPD RPDLimit Qual

Prep Date:



RunNo: 43939

SeqNo: 852591

%RPD RPDLimit Qual

Prep Date:



RunNo: 43939

SeqNo: 852609

%RPD RPDLimit Qual

Prep Date:



RunNo: 43939

SeqNo: 852621

%RPD RPDLimit Qual




I





Page 66 of 72

CLIENT: Casella



Sampte ID: CCB6

Client ID: 77777

Analyte

SampType: CCB

Batch ID: R43939

Result


Sampte ID: CCB7

Client ID: 77777

Analyte

SampType: CCB

Batch ID: R43939

Result


Sample ID: CCB8

Client ID: 77777

Analyte

SampType: CCB

Batch ID: R43939

Result


Sample ID: CCB9

Client ID: ZZZZZ

Analyte

SampType: CCB

Batch ID: R43939

Result


Sampte ID: CCB10

Client ID: 77777

Analyte

SampType: CCB

Batch ID: R43939

Result

Phenolics, Total Recoverable 0.05230

TestCode: 420.4

TestNo: E420.4

Units: mg/L


0.00500

TestCode: 420.4

TestNo: E420.4

Units: mg/L


0.00500

TestCode: 420.4

TestNo: E420.4

Units: mg/L


0.00500

TestCode: 420.4

TestNo: E420.4

Units: mg/L


Prep Date:



RunNo: 43939

SeqNo: 852655

%RPD RPDLimit Qual

Prep Date:

Analysis Date: 7/17/2009 RunNo: 43939

SeqNo: 852679


Prep Date:


RunNo: 43939

SeqNo: 852691


Prep Date:


RunNo: 43939

SeqNo: 852711

PQL SPKvalue SPKRefVal %REC LowLimit HighLimit RPDRefVal %RPD R p D L i m i t Qual

0.00500

TestCode: 420.4

TestNo: E420.4



RunNo: 43939

SeqNo: 852723


0.00500

I oo




Page 67 of 72



TestCode: 420.4

Sample ID: CCB11

Client ID: 77777

Analyte

SampType: CCB

Batch ID: R43939

TestCode: 420.4

TestNo: E420.4



Result



RunNo: 43939

SeqNo: 852731

%RPD RPDLimit Qual ND 0.00500

Sample ID: CCV1

Client ID: 77777

Analyte

SampType: CCV

Batch ID: R43939

TestCode: 420.4

TestNo: E420.4

Units: mg/L


Phenolics, Total Recoverable 0.1010

Prep Date:



RunNo: 43939

SeqNo: 852576

%RPD RPDLimit Qual

0.00500 0.1 101 90 110

Sampte ID: CCV2

Client ID: 77777

Analyte

SampType: CCV

Batch ID: R43939

TestCode: 420.4

TestNo: E420.4

Units: mg/L



Prep Date:



RunNo: 43939

SeqNo: 852590

%RPD RPDLimit Qual 0.05050 0.00500 0.05 101 90 110

Sampte ID: CCV3

Client ID: ZZZZZ

Analyte

SampType: CCV

Batch ID: R43939

Result

TestCode: 420.4

TestNo: E420.4



RunNo: 43939

SeqNo: 852608



0.1020 0.00500 0.1 102 90 110

Sampte ID: CCV4

Client ID: 77777

Analyte

SampType: CCV

Batch ID: R43939

Result

TestCode: 420.4

TestNo: E420.4



RunNo: 43939

SeqNo: 852620


Phenolics, Total Recoverable 0.05130 0.00500 0.05 103 90 110

I OJ





Page 68 of 72


Sample ID: CCV5

Client ID: 77777

Analyte


Sample ID: CCV6

Client ID: ZZZZZ

Analyte


Sample ID: CCV7

Client ID: 77777

Analyte


Sample ID: CCV8

Client ID: ZZZZZ

Analyte


Sample ID: CCV9

Client ID: 77777

Analyte


SampType: CCV

Batch ID: R43939

Result

0.1020

SampType: CCV

Batch ID: R43939

Result

0.05250

SampType: CCV

Batch ID: R43939

Result

0.05200

SampType: CCV

Batch ID: R43939

Result

0.1030

SampType: CCV

Batch ID: R43939

Result

0.05230


TestCode: 420.4

TestCode: 420.4

TestNo: E420.4



RunNo: 43939

SeqNo: 852638


0.00500 0.1 102 90 110

TestCode: 420.4

TestNo: E420.4



RunNo: 43939

SeqNo: 852654


0.00500 0.05 105 90 110

TestCode: 420.4

TestNo: E420.4

Units: mg/L


Prep Date:



RunNo: 43939

SeqNo: 852678

%RPD RPDLimit Qual

0.00500 0.05 104 90 110

TestCode: 420.4

TestNo: E420.4

Units: mg/L


Prep Date:


%REC LowLimit HighLimit RPD Ref Val

RunNo: 43939

SeqNo: 852690

%RPD RPDLimit Qual 0.00500 0.1 103 90 110

TestCode: 420.4

TestNo: E420.4



RunNo: 43939

SeqNo: 852710


0.00500 0.05 105 90 110

I CD m





Page 69 of 72

CLIENT: Casella



Sampte ID: CCV10

Client ID: 77777

Analyte


Sampte ID: CCV11

Client ID: 77777

Analyte


Sampte ID: ICB

Client ID: 77777

Analyte


Sample ID: ICV

Client ID: 77777

Analyte



TestCode: 420.4

SampType: CCV

Batch ID: R43939

TestCode: 420.4

TestNo: E420.4



RunNo: 43939

SeqNo: 852722


0.1030 %REC LowLimit HighLimit RPDRefVal %RPD RPDLimit Qual

0.00500 0.1 103 90 110

SampType: CCV

Batch ID: R43939

Result

0.05230

SampType: ICB

Batch ID: R43939

Result

ND

SampType: ICV

Batch ID: R43939

Result

0.2000

TestCode: 420.4

TestNo: E420.4

Units: mg/L


Prep Date:


RunNo: 43939

SeqNo: 852730

%RPD RPDLimit Qual 0.00500 0.05 105 90 110

TestCode: 420.4

TestNo: E420.4



RunNo: 43939

SeqNo: 852529


0.00500

TestCode: 420.4

TestNo: E420.4



RunNo: 43939

SeqNo: 852528

PQL SPKvalue SPKRefVal % R E C LowLimit HighLimit RPDRefVal %RPD RPDLimit Qual

0.00500 0.2 0 100 90 110

I

I




Page 70 of 72





Analyte Result

Hexavalent chromium 1.055



Analyte

Hexavalent chromium

Sampte ID: CCB

Client ID: 77777

Analyte

Hexavalent chromium

Sample ID: CCV

Client ID: 77777

Analyte

Hexavalent chromium

Sample ID: OCB

Client ID: 77777

Analyte

Hexavalent chromium

Result

ND

SampType: CCB

Batch ID: R43834

Result

ND

SampType: CCV

Batch ID: R43834

Result

1.103

SampType: ICB

Batch ID: R43834

Result

ND


TestCode: C R 6 W

TestCode: CR6_W

TestNo: SM3500

Units: mg/L


Prep Date:


0.010

RunNo: 43834

SeqNo: 850068

%RPD RPDLimit Qual

1 105 68.4 129

TestCode: Cr6_W

TestNo: SM3500



RunNo: 43834

SeqNo: 850067


0.010 0 20

TestCode: CR6_W

TestNo: SM3500

Units: mg/L


Prep Date:



RunNo: 43834

SeqNo: 850073


TestCode: CR6_W

TestNo: SM3500

Units: mg/L


Prep Date:


0.010

RunNo: 43834

SeqNo: 850072

%RPD RPDLimit Qual

0 110 85.5 114

TestCode: CR6_W

TestNo: SM3500



RunNo: 43834

SeqNo: 850061


0.010

I CM LO





Page 71 of 72



Sample ID: ICV

Client ID: ZZZZZ

Analyte

SampType: ICV

Batch ID: R43834

TestCode: CR6_W

TestNo: SM3500

Units: mg/L

Result

ANALYTICAL QC SUMMARY REPORT TestCode: CR6_W

Prep Date:


Hexavalent chromium 0.4266


0.010 0.478

RunNo: 43834

SeqNo: 850060

%RPD RPDLimit Qual

82.8 120

I CO LO




Page 72 of 72

Chain-of-Custody


•154-

CJl cn

I

Upstate Laboratories, Inc. 6034 Corporate Drive E. Syracuse New York 13057 (315)437 0255 Fax 437 1209

Chain of Custody Record r

CASELLA Client Contact

BRIAN MCGRATH Sample ID

MW-28

MW-29 DUPE

Phone #

263-2774

Date

7/q/°l

i

Project #1 Project Name

ONTARIO CO. LF PHASE III CONT Location (city/state) Address ~"

ONTARIO, NEW YORK Time

I ?:oi

Matrix

GW GW

GW

GRAB

OR COMP

GRAB GRAB

GRAB

ULI Internal Use Only

Parameter and Method

fr) T-CN $)T-PHENOLS

1) FIELD PH,TEMP,EH,SPEC COND.TURB.SWL Sample bottle:

No.

of Conta

M W

2)BOD5,COLOR,CR+6,NQ3,TDS,S04,CL-,BROMIDE 3) TKN.NH3.C0D 4) ALKALINITY

9) TOC fi)T-AL,SB*,AS*,BA,BE,CD,CA,CR,CO.CU.FE.PB*.MG.

B,IVIN,HG,NA.NI,K,SE*,AG.TL*,V,ZN + HARDNESS S)D-AL,SB*,AS*,BA,BE,CD,CA,CR,CO,CU,FE,PBMVIG.

B,MN,HG,NA.NI,K,SE*,AG.TL*.V.ZN 10 EPA 8260 BASELINE LIST

Syracuse Rochester

TyPe

N/A PLASTIC PLASTIC GLASS

PLASTIC AMBER PLASTIC PLASTIC

PLASTIC

Size Preservative

11

o

2L

il

v-

3L

- f c s I

41

ia

•* u_4

§L >0

s

C»

m. m

2000ml 500ml

8oz 2000ml

32oz 120ml 500ml

GLASS 40 ML

500ml

NONE H2S04 NONE NOAH H2S04 1:1 HCL HN03

HN03

1:1 HCL

Remarks

ASP CAT B 1998 part 360 Baseline list

MS/MSD

Sampled by (Print) ^p5 f g 3 / K , 0(LO

Company: g < L Relinquished by:(sign)

Relinquished by:(sign)

Relinquished by:(sign)

Buffalo Albany

Date

7h\o?t

Date

Date

Time

7 Time

Time

yt^t^S'

Name of Courier

Received by: (sign)

Received by: (sign)

Rec'd for Lab by:

Binghamton Fair Lawn (NJ) Jl A. n^p

Upstate Laboratories, Inc. Internal Laboratory Sign-Out Log SF- 10-03 Revised 3/98

Project:

SDG No.:

ULI ID No.:

CsS^MetJ

uo^oniHS ULI Number or

_Range of ULI Numbers

•156-


Client Name CASELLA-MAIN

Work Order Numbe U0907195

Sample Receipt Checklist

Date and Time Receive

Received by TC

7/9/2009 3:35:00 PM

Checklist completed by P i 'JUJIO? ^ / ^ 3 9 Reviewed by P P P 1 - | A - A Q Initials Dale

Matrix: Carrier name: Client

Shipping container/cooler in good condition?

Custody seals intact on shippping container/cooler?

Custody seals intact on sample bottles?

Chain of custody present?

Chain of custody signed when relinquished and received?

Chain of custody agrees with sample labels?

Samples in proper container/bottle?

Sample containers intact?

Sufficient sample volume for indicated test?

All samples received within holding time?

Container/Temp Blank temperature in compliance?

Water - VOA vials have zero headspace?

Water - pH acceptable upon receipt?

Yes 0

Yes •

Yes •

Yes 0

Yes 0

Yes 0

Yes 0

Yes 0

Yes 0

Yes 0

Yes 0

No VOA vials submitted •

Yes 0

Adjusted?

S-D'

N o D

N o D

N o D

N o D

N o D

N o D

N o D

N o D

N o D

N o D

N o D

Yes 0

N o D

Checked by

Not Presen •

Not Presen 0

Not Presen 0

N o D

Any No and/or NA (not applicable) response must be detailed in the comments section be

Client contacted

Contacted by:

Comments:

Date contacted:

Regarding:

Person contacted

Corrective Action

•157-

old.bartonandloguidice.comold.bartonandloguidice.com/portals/22/assets/ontario county deis... ·...

Documents