on-line sorting technologies for cca treated wood july 24, 2001

54
On-line Sorting Technologies for CCA Treated Wood July 24, 2001

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Page 1: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

On-line Sorting Technologies for CCA Treated Wood

July 24, 2001

Page 2: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Objective

To design and implement an automated system to effectively sort CCA-treated wood from other wood types at C&D facilities

Page 3: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Project Tasks

Task 1: Construct Shelter

Task 2: Construct Conveyor

Task 3: Lab Test and Develop Detector

Task 4: Install and Field Test Conveyor & Detector

Task 5: Operate Sorting System and Document Performance

Page 4: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Description 2000 2001

M A M J J A S O N D J F M A M J J A S

Task 1: Construct Shelter X

Task 2 Construct Conveyor X

Task 3: Develop Detector X X

Task 4: Install/Test X

Task 5: Operate X

Environ. Cert. & Scope X

Progress Reports X X X X

Final Report X

Page 5: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

SHELTER

Page 6: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Participants

• Metal shelter design, fabrication and assembly – Trident

• Concrete slab design – Sarasota County• Concrete form, control room – Meyer and

Gabbert• Concrete pour, anchor bolts and project

management – Anderson and Ellis• Electrical – Claxton Electric

Page 7: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Pull permit, construct concrete

form, electrical

Permit Review by BDAnd Zoning

6 Wks

1.5 Wks

1 Wk

Pour concrete and allow for curing

Permit application completed and submitted to building department (BD)

Delivery and assembly of

shelter

Schedule and Timeline

October

18 25

November

9 16 30

December

8 18 30

2+ WksPull permit,

construct concrete form

Permit Review by BDAnd Zoning

6 Wks

3 Wks

1 Wk

Pour concrete and allow for curing

Permit application completed and submitted to building department (BD)

Delivery and assembly of

shelterSchedule and Timeline

October

18 25

November

9 16 30

December

8 21 27 29

3 days

January 2001

5 8

Electrical conduits installed

***Control room and final electrical wiring installed on January 23, 2001

Page 8: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Shelter Completed in January 2001• Interior control room built with recycled

materials (from on-site) by Meyer and Gabbert

• Electrical installation will continue with wiring for conveyor and control room

Page 9: On-line Sorting Technologies for CCA Treated Wood July 24, 2001
Page 10: On-line Sorting Technologies for CCA Treated Wood July 24, 2001
Page 11: On-line Sorting Technologies for CCA Treated Wood July 24, 2001
Page 12: On-line Sorting Technologies for CCA Treated Wood July 24, 2001
Page 13: On-line Sorting Technologies for CCA Treated Wood July 24, 2001
Page 14: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Control Room

Page 15: On-line Sorting Technologies for CCA Treated Wood July 24, 2001
Page 16: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Control Room

Page 17: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

CONVEYOR

Page 18: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

CCA-TREATED

WOOD

INCLINE CONVEYOR

OT

HE

R W

OO

DT

YP

ES

RO

L L- OF

F

30’2.5’

4.5’2.5’10’10’26’

5’

10.5’ Horizontal Guideto Align Wood

1’

Electric Panel for Conveyor

ROLLERCONVEYOR

BELTCONVEYOR

40’

North

IncomingMixed Wood

SPUR CONVEYOR

7’

Roof SupportColumn

10’45o

4’

Shear Arm

Conveyor Layout: February 6, 2001

ControlRoom

Page 19: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Conveyor – Cross Section

Ta b le Ro lle r C o nve yo r Be lt C o nve yo rInc line d

Be lt C o nve yo r

Ro ll-o ff

12 ’

305’ 10’ 15’

3 ’

O

XRF De te c to r

La se rC o nve yo r, 5’ wid e

Page 20: On-line Sorting Technologies for CCA Treated Wood July 24, 2001
Page 21: On-line Sorting Technologies for CCA Treated Wood July 24, 2001
Page 22: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Removable Roller

Spur Conveyor

Mounting For Shear Arm

Page 23: On-line Sorting Technologies for CCA Treated Wood July 24, 2001
Page 24: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Wood Sort

• Pallet Study 100 pallets tested and 0 were CCA-treated

• Wood Sort3 construction piles and 1 demolition piles were sorted

Page 25: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Wood Sort

Page 26: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Wood Sort

Page 27: On-line Sorting Technologies for CCA Treated Wood July 24, 2001
Page 28: On-line Sorting Technologies for CCA Treated Wood July 24, 2001
Page 29: On-line Sorting Technologies for CCA Treated Wood July 24, 2001
Page 30: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Waste Pile 1

Page 31: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Waste Pile 2

Page 32: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Waste Pile 3

Page 33: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Waste Pile 4

Page 34: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

DETECTORS

laser

x-ray

Page 35: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

0

500

1000

1500

2000

2500

3000

320 340 360 380 400 420 440 460

Laser Induced Breakdown Spectroscopy (LIBS)

PulsedLaser Atomic

EmissionCollection

FiberOptic

Spectrometer

Laser InducedPlasma

WoodSample

Line position provides species identification

0

500

1000

1500

2000

2500

3000

320 340 360 380 400 420 440 460Wavelength (nm)

Rel

ativ

e In

tens

ity (

a.u.

)

Wavelength (nm)

Inte

nsi

ty Ca

Cr

Ca

Ca

Page 36: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Field Unit

Spectrometer

Laser PowerSupply

Nd:YAG Laser1064 nm 200 mJ

DelayGenerator

Fiber Optic

FlashlampTTL Sync

Delayed TTL Sync

Power, Q-Switch Sync, Cooling Lines

MultichannelOutput Board Conditional

TTL Output

StrobePower Supply

Sample

Spectra

10 ns Pulses at 2Hz

TTL Output

Plasma

Focused Emission

Strobe Array

Mirror1064 nm

BroadbandPiercedMirror

FocusingLens

(355-532 nm AR)

FocusingLens

(1064 nm AR)

Page 37: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

July 3rd Field Trial

• Increased the internal spectrometer gain

• Conducted sorting trial to determine:– Accuracy of the detector– Accuracy of the human observer

• Single-shot spectra collection– Determine thresholds and accuracy

Page 38: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Chromium Peak and Base Intensities

75

125

175

225

275

325

375

425

250 260 270 280 290 300

Sample

Inte

ns

ity

(a

.u.)

Base

Peak

Page 39: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Average Peak-to-Base Ratios

0

1

2

3

4

5

6

7

8

0 5 10 15 20 25 30 35 40 45 50 55 60

Sample

Pe

ak

to

Ba

se

Ra

tio

Treated

Untreated

Page 40: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

0

2

4

6

8

10

0 50 100 150 200 250 300 350 400 450 500

Sample

Pe

ak

to

Ba

se

Ra

tio

Untreated

0

2

4

6

8

10

0 50 100 150 200 250 300 350 400 450

Sample

Pe

ak

to

Ba

se

Ra

tio

CCA Treated

Peak-to-Base Ratios on a Shot-by-Shot Basis

Page 41: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Single-Shot Analysis

Peak Width Separation ThresholdMean Mean P/B Ratio

1539 5 Pixels 3.98 1.44 1.69 0.35 0.50 2.23

1 Shot 5 Shots 10 Shots 1 Shot 5 Shots 10 Shots1539 5 Pixels 91.6% 96.7% 100.0% 95.2% 96.7% 98.9%

CCA Treated Untreated

5.42

2.04

2.54

1.34

3.98

1.69

1.0

2.0

3.0

4.0

5.0

6.0

CCA Treated Untreated

Pe

ak

-to

-Ba

se

Ra

tio

Mean

Separation

Mean

Mean1539 5 Pixels 3.98 1.44 1.69 0.35 0.50 2.23

Peak Width1 Shot 5 Shots 10 Shots 1 Shot 5 Shots 10 Shots

1539 5 Pixels 91.6% 96.7% 100.0% 95.2% 96.7% 98.9%

CCA Treated Wood Accuracy Untreated Wood Accuracy

Page 42: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Analysis of Results

• Flexibility of the LIBS detector– Settings can be optimized for extremely rapid analysis

and accurate analysis– Different settings for different disposal paths

• Field trials demonstrate:– Accuracies that would allow burning or mulching of wood

identified as untreated– Identification of painted wood– Can accurately differentiate CCA from alternates

Page 43: On-line Sorting Technologies for CCA Treated Wood July 24, 2001
Page 44: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

X-Ray Fluorescence Technology

• Proven to work well and has been used extensively by many wood treating plants to test retention levels.

• Standardized by the AWPA.

• Using the Spectro/Asoma model 400 unit (different from the wood treatment industry).

Page 45: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Theory of X-Ray Fluorescence• Incident X-ray from the

analyzer strikes an electron occupying the lowest shell

• Electron is ejected• An upper-shell electron

drops down to fill the vacancy

• X-ray characteristic to this elements’ energy is emitted

Incident X-Ray

Ejectede-

EmittedX-Ray

Transitionede-

Nucleus

Page 46: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

XRF Field Photos

¾”

Page 47: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Treated vs. Untreated Wood

0

100

200

300

400

No paint Thompson'sWaterseal

Oilbased paint WoodPreservative

WaterbasedWood Stain

WaterbasedExterior Paint

As

Co

un

ts

Treated

Untreated

Page 48: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Dry vs. Wet Treated Wood

0

100

200

300

400

No paint Thompson'sWaterseal

Oilbased paint WoodPreservative

WaterbasedWood Stain

WaterbasedExterior Paint

As

Co

un

ts

Dry

Wet

Page 49: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Dry vs. Wet Untreated Wood

0

20

40

60

80

100

No paint Thompson'sWaterseal

Oilbasedpaint

WoodPreservative

WaterbasedWood Stain

WaterbasedExterior Paint

As

Co

un

ts

Dry

Wet

Page 50: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Alternative Chemicals

0

100

200

300

400

500

CCA Untreated CDDC ACQ CC CBA

As

Co

un

ts

1400

Page 51: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Heartwood vs. Sapwood

0

200

400

600

800

1000

1200

1400

1600

1800

Wood sample

As

Co

un

ts

A B

Heartwood portion of sample

Page 52: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Distance readings

0

200

400

600

800

1000

1200

1400

Distance (in)

As

Co

un

ts

0 211/80211/8

Treated

Untreated

Page 53: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Summary• Advantages

– Very consistent.– It can not only differentiate between treated and untreated

wood but gives the actual amount treated in specific units.• Disadvantages

– Non-customized equipment• Hit analyze key long print time.

– Limited to no more than 1” distance.– Due to the radiation, a minimum 6” radial distance must be

maintained at all times.

Page 54: On-line Sorting Technologies for CCA Treated Wood July 24, 2001

Questions

www.eng.miami.edu/~hmsolo/sarasota/index_sara.htm