one feedstock, various possibilities 2014 methanol ... · one feedstock, various possibilities 2014...
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One Feedstock, Various Possibilities2014 Methanol Technology and Policy2014 Methanol Technology and Policy CongressFrankfurt, Dec. 2014 l Martin Gorny and Martin Rothaemel l Techno AL Global E&C Solutions and Air Liquide R&D
Agenda
■ Methanol downstream processes
■ Introduction of the MTP® Process
De elopment of the MTP® Process■ Development of the MTP® Process
■ Integration of Lurgi MegaMethanol® and MTP® plant■ Integration of Lurgi MegaMethanol and MTP plant
■ Conclusion
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Methanol downstream processes
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We can do more than only MegaMethanol®
Propyleneoxide
Polypropylene
MTP®
py
Acrylic Acid
O th i
Lurgi MegaMethanol®Syngas
Natural Gas
Coal
Oxo synthesis
AcrylonitrileMegaMethanol
ProcessSyngasCoal
Crude OilDME
MeOH to Olefins
Fuels
Ethylene, Propylene (Poly-Olefins)
ASU MeOH to Aromatics
(Poly Olefins)
Benzene, Xylenes
F lMeOH to Gasoline
MeOH to Glycol
Fuels
Ethylene Glycol
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Introduction of the MTP® Process
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Overview Flowsheet
Fuel Gas Internal use
MegaMethanol®1,667 Mt/a = 5,000 t/d Optional
Ethylene60 t/d
DMEPre-
Propylene1 410 t/d 1)
Ethylene
ProductConditioning MTP-LPG
109 t/d
Pre-Reactor
1,410 t/d 1)
MTP-Gasoline 540 t/d
Olefin RecycleProduct
Fractionation
MTP Reactors(2 Operating + 1 Regenerating)
Process Water 2,800 t/dInternal Use (+)
Water Recycle
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1) Propylene Purity 99.6 wt. %
MTP® – Products Description
Propylene (PG) Purity > 99.60 % wt
Ethylene (PG) Purity > 99.90 % wt..
MTP-LPG CompositionC2 Hydrocarbons < 0.2 Vol % C3 Hydrocarbons > 10 Vol % C H d b 90 V l %C4 Hydrocarbons < 90 Vol % C5 Hydrocarbons < 1.5 Vol % Total Sulphur Components, maximum < 0.1 ppm wt.
MTP-Gasoline PropertiesDensity at 15° C 740 - 790 kg/m3
Equivalent dry vapour pressure 35 - 70 kPaResearch Octane Number 90 - 95 RON
CompositionParaffins 15 - 35 % wt.Olefins (increasing over run time of catalyst) 30 - 60 % wt.Aromatics (decreasing over run time of catalyst) 50 15 % wtAromatics (decreasing over run time of catalyst) 50 - 15 % wt.Benzene < 1 % wt.Total Sulphur Components < 0.1 ppm wt.
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Excellent characteristics as a blending stock. Processing to pump-grade gasoline available.
MTP® Technical Highlights
■ Maximized Propylene ProductionSelectivity > 65 % (Product Slate)Yield > 28 % Wt. on Methanol Feed
■ Main Co-Product: MTP-Gasoline: Valuableblendstock to any gasoline pool
■ Proprietary Zeolite CatalystShenhua Ningxia Coal Industry Group Co. Ltd
p y y
■ Methanol Conversion > 99%
■ Low Coking Catalyst (< 0.5% Carbon Loss)
■ In-Situ Regeneration■ In-Situ Regeneration
■ Option for some Ethylene production
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MTP® Our Track RecordPanorama view of SNCG site, Aug. 2010
Lurgi MegaM h l®
MTP®Poly-
PropyleneASU
Coal-FiredPower Plant
Methanol® ASU
DME CoalGasification
R ti lSulfurRecovery
DME
■ Three MTP® plants under commercial operation:
RectisolRecoveryAIR LIQUIDETechnologies
■ Three MTP plants under commercial operation:Datang Power Corporation (DTP: Duolon) – start-up 2011Shenhua Ningxia Coal Industry Group (SNCG: Ningdong) – start-up 2010Shenhua Ningxia Coal Industry Group (SNCG: Ningdong) – start-up 2014
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Shenhua Ningxia Coal Industry Group (SNCG: Ningdong) start up 2014
Development of the MTP® Processp
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R&D for the MTP® Process / Pilot Plants
Pilot Plant – Frankfurt, Germany
Concept andBackground
operation as close as possible to commercial plant, including recycles and product purification
Deliverables andResults
design base for commercial process, support for specific plant operationplant operation
Timeframe Dec 1999 – Dec 2002 (PDU 1)Jul 2003 – today (PDU 2)
Scale 500 – 1500 g MeOH / hScale 500 – 1500 g MeOH / h
th 30 000 h t !more than 30,000 hours-on-stream!Air LiquideResearch and Technology Center Frankfurt
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Frankfurt
Scale Up
■ Reactor Section guarantee direct scale-up from pilot to demo to commercial scale
■ Recycle Streams realize all important streams in pilot plant
■ Purification demonstrate product and by-product quality in pilot plant incl. polymer-grade
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R&D for the MTP® Process / Verification
SNCG MTP IPilot Plant
P lPropyleneGasolineLPGLight ends
■ The pilot plant in Frankfurt delivered a very good prediction of yields and product properties in comparison to actual performance of the commercial plant
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SNCG MTP I
■ MTP downstream a coal based methanol production. ■ First World Scale MTP® Plant (1410 t/d)■ First World Scale MTP Plant (1410 t/d)
■ Project History:■ BE Contract Signed October 2006■ Start of Construction April 2008■ First MeOH feed in September 2010 4 years■ First On-spec Propylene produced October 2010■ First Operation at 100% August 2011■ Performance Test Run May 2012
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SNCG MTP II
■ Coal based methanol as feed stock■ Second plant at SNCG site■ Second plant at SNCG site
■ Project History:■ BE Contract Signed July 2011■ Start of Construction June 2012■ First MeOH feed in August 2014
3 years, 1 month
■ First On-spec Propylene produced August 2014■ First Operation at 100% September 2014
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Integration Lurgi MegaMethanol® and MTP® plantMTP® plant
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Independent plant design
IntermediateStorage
Reforming DME andMethanol Methanol MTP
ReactionDistillation EvaporationMethanol Liquid
Grade AA
Methanol Synthesis
Purification
Lurgi MegaMethanol® Plant MTP® Plant
Utilities
Steam and Condensate System
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Integrated plant design
IntermediateStorage
Reforming DME andMethanol Methanol Vapour
MTP Reaction
Distillation
Methanol Synthesis
PurificationMethanol Liquid
Grade AA
Lurgi MegaMethanol® Plant MTP® Plant
Utilities
Steam and Condensate System
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Conclusion
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Conclusion
■ MTP® Process mature technology■ MTP Process mature technology
■ MTP® Process offers feedstock independent on purpose propylene d tiproduction
■ Integration with Lurgi Megamethanol® Technology reduces CAPEX eg a o u g ega e a o ec o ogy educes Cand OPEX
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End of presentationThank you for your attentionThank you for your attention