orbitals - dr. g's chemistry · this is the shape of p orbitals don’t forget:! an orbital is...

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Page 1: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

Orbitals...

Page 2: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

Electrons are part of what!makes an atom an atom

Page 3: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

Electrons are part of what!makes an atom an atom

atom

But where exactly are the!electrons inside an atom?

Page 4: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

Orbitals!are areas within atoms!

where there is a high probablility!of finding electrons.

Page 5: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

Knowing how electrons are!arranged in an atom is!

important!because that governs!

how atoms interact!with each other

Page 6: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

Knowing how electrons are!arranged in an atom is!

important!because that governs!

how atoms interact!with each other

Page 7: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

Knowing how electrons are!arranged in an atom is!

important!because that governs!

how atoms interact!with each other

Page 8: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

Knowing how electrons are!arranged in an atom is!

important!because that governs!

how atoms interact!with each other

Page 9: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

Knowing how electrons are!arranged in an atom is!

important!because that governs!

how atoms interact!with each other

Page 10: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

Knowing how electrons are!arranged in an atom is!

important!because that governs!

how atoms interact!with each other

Page 11: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

Knowing how electrons are!arranged in an atom is!

important!because that governs!

how atoms interact!with each other

Page 12: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

Let’s say you have a!room with flies flying!around in it

Page 13: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

The flies are not just!anywhere in the room.!They are inside boxes in!the room.

Page 14: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

You know where the!boxes are, and you!know the flies are!inside the boxes, but…

Page 15: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

you don’t know exactly!where the flies are!inside the boxes

Page 16: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

The room is an atom!The flies are electrons!The boxes are orbitals

Page 17: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

The room is an atom!The flies are electrons!The boxes are orbitals

Page 18: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

The room is an atom!The marbles are electrons!

The boxes are orbitals

Science has determined where the!orbitals are inside an atom, but it!is never known precisely where the!electrons are inside the orbitals

Page 19: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y
Page 20: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

Hey, where am I?

Page 21: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

So what are the!sizes and shapes!

of orbitals?

Page 22: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

The area where an electron can be found,!the orbital,!

is defined mathematically,!but we can see it as a specific shape!

in 3-dimensional space…

Page 23: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

x

y

z

Page 24: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

The 3 axes represent!3-dimensional space

x

y

z

Page 25: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

For this presentation, the!nucleus of the atom is at!the center of the three axes.

x

y

z

Page 26: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

The “1s” orbital is a!sphere, centered!around the nucleus

Page 27: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y
Page 28: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y
Page 29: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

The 2s orbital is also!a sphere.

Page 30: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

The 2s electrons have a !higher energy than the 1s!electrons. Therefore, the 2s!electrons are generally more!distant from the nucleus,!making the 2s orbital larger!than the 1s orbital.

Page 31: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

1s orbital

Page 32: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

2s orbital

Page 33: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

Don’t forget:!an orbital is the shape of the!space where there is a high!probability of finding electrons

Page 34: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

The s orbitals are spheres

Don’t forget:!an orbital is the shape of the!space where there is a high!probability of finding electrons

Page 35: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

There are three!2p orbitals

Page 36: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

The three 2p orbitals!are oriented!perpendicular!to each other

Page 37: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

This is!one 2p orbital!

(2py)

x

y

z

Page 38: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

another 2p orbital!(2px)

x

y

z

Page 39: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

the third 2p orbital!(2pz)

x

y

z

Page 40: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

Don’t forget:!an orbital is the shape of the!space where there is a high!probability of finding electrons

Page 41: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

This is the shape of p orbitals

Don’t forget:!an orbital is the shape of the!space where there is a high!probability of finding electrons

Page 42: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

x

y

z

Page 43: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

2px

x

y

z

Page 44: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

2px and 2pz

x

y

z

Page 45: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

The three 2p orbitals,!2px, 2py, 2pz

x

y

z

Page 46: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

once the!1s orbital!is filled,

Page 47: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

the 2s orbital!begins to fill

Page 48: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

once the 2s!orbital is!filled,

Page 49: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

the 2p orbitals!begin to fill

Page 50: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

each 2p orbital!intersects the!2s orbital and!the 1s orbital

Page 51: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

each 2p orbital!gets one electron!before pairing begins

Page 52: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

once each 2p orbital!is filled with a pair!of electrons, then

Page 53: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

the 3s orbital!gets the next!two electrons

Page 54: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

the 3s electrons!have a higher energy!than 1s, 2s, or 2p!electrons,

Page 55: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

so 3s electrons are!generally found!further from the!nucleus than 1s,!2s, or 2p electrons

Page 56: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

What does that have to

Page 57: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

the billions of interactions of atoms!constantly going on around you!depend on how the electrons!

are arranged in each atom

Page 58: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

the billions of interactions of atoms!constantly going on around you!

depend on how the electrons!are arranged in each atom

the arrangement of an atom’s electrons!(its orbitals)!

govern how that atom will interact!with other atoms

Page 59: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

the billions of interactions of atoms!constantly going on around you!

depend on how the electrons!are arranged in each atom

the arrangement of an atom’s electrons!(its orbitals)!

govern how that atom will interact!with other atoms

If atoms did not interact with each other,!you would not be sitting here reading this

Page 60: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

An interesting place!where electrons have!

a specific organization!within atoms,!

allowing for intersting!atom interactions

Page 61: Orbitals - Dr. G's Chemistry · This is the shape of p orbitals Don’t forget:! an orbital is the shape of the! space where there is a high! probability of finding electrons. x y

An interesting place!where electrons have!

a specific organization!within atoms,!

allowing for intersting!atom interactions

Not an interesting place,!where electrons have!

no specific organization!within atoms,!

where atoms wander!aimlessly about

(does not actually exist)