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  • 7/30/2019 p130.pdf

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    Proceedings of the 4th International Conference on

    Nanostructures (ICNS4)12-14 March 2012, Kish Island, I.R. Iran

    Abstract Book|INST| Sharif University of Technology|130

    APP 199APP

    APP 197

    APP 200

    We have magnetizedSaccharomyces Cervisiaecellswith nano-magnet-

    ic particles. This procedure enables a simple separation of modied

    cells by a at magnetic separator or strong permanent magnets. It al-

    lows using the magnetic yeast cells as a new fast and cheap magnetic

    adsorbent for the removal of water impurities. Magnetically modied

    cells were characterized by Scanning electron microscopy (SEM).

    Blue aniline dyewas used to study the adsorption process.The adsorp-

    tion of the tested dye occurred quickly and reached equilibrium in ap-

    proximately 50-70 min.

    Keywords: Saccharomyces Cervisiae cell; Ferro uid; Dyes; Adsorption

    R. Hosseinifara, N. Maleki-Jirsaraeia*, S. Rouhaniba Complex systems Lab, Department of Physics, University of Alzahra, Tehran,

    Iranb Department of Physics, Sharif University of Technology, Tehran, Iran

    *[email protected]

    Magnezed Saccharomyces Cervisiae as an Adsorbentfor Dyes Removal

    Photocatalytic reduction is a useful technology to purication of indus-

    trial wastewater. In this paper, the removal of ammonia from petrochem-

    ical wastewater by photocatalytic process, under UV light irradiation

    was investigated.TiO2nano particles were used as photocatalyst which

    coated on mesoporous support. A simple and efcient method was used

    to preparation of catalyst. HPLC analyses were used for measuring the

    concentration of components, and Scanning electron microscopy (SEM)

    analyse was carried out for characterization including crystal size and

    morphology of prepared catalysts. The obtained results showed ef-

    ciency of ammonia degradation for TiO2/Leca excited by UV irradiation

    systems after 360 min irradiated is 51%. Also, well and uniform coating

    of nano particles TiO2 on support was conrmed by SEM method.

    Keywords: Industrial wastewater; Photocatalyst; Ammonia; TiO2; Leca

    M.Zendehzaban a, Y. Shavisib, S. Kakehazarb, M.A.Khadivib, Sh.Sharifniab*aFaculty of Eng., Islamic Azad University, South Tehran branch, Tehran,

    1584743311, IranbCatalyst Research Center, Depart. Chem. Eng., Razi University, Kerman-

    shah, 67149- 67246, Iran.

    *[email protected]

    Removal of Ammonia from Petrochemical Wastewater

    by Photocatalyc Process

    In this study poly-styrene (PS) Nano-Fibers are produced via Electro -

    spinning method and made a composite by Iron oxide Nano particles

    for removal of Arsenic from water and making it potable. In fact the

    arsenic can be removed by Iron Oxide NPs ion exchange ability which

    is caused by nano ber composite (NFC) . Synthesized NFC has been

    characterized using scanning electron microscopy (SEM), X-ray dif-

    fraction (XRD) and energy dispersive X-ray (EDAX). According to

    the Analysis results the size of the synthesized particle and compos-

    ited Nano bers were about 17 and 82 nm, respectively. Finally NFCis applied in lab ltering pilot to evaluate its efciency on Arsenic

    removal from water.

    Keywords: Nano ber composite; Iron oxide; Arsenic and ltering

    M. Mirjanikahakia, F. Jokarisheshdehb, M. Meskinfamb*a Department of chemistry, University of Islamic Azad University North Teh-

    ran, Tehran, IranbDepartment of chemistry, Islamic Azad University University, Lahijan

    branch, Lahijan, Iran

    *[email protected]

    Synthesis of Nano Fiber Composite (NFC) for Arsenic

    Removalfrom Drinking Water

    SYN 196

    The electrochemical treatment of solutions containing C.I. Direct Red

    23 (DR23) has been studied under recirculation mode with an UV ir-

    radiation of 15 W. Decolorization experiments were performed in the

    presence of sulfate electrolyte media at pH 3.0 with carbon nanotube-

    polytetrauoroethylene (CNT-PTFE) electrode as cathode. A compar-

    ison of electro- Fenton (EF) and photoelectro-Fenton (PEF) processes

    for decolorization of DR23 solution was carried out. Color removal

    efciency was 66.22 and 94.29% for EF and PEF processes after 60min of treatment, respectively. The effect of operational parameters

    on the PEF process such as applied current, initial Fe 3+ concentration

    and initial dye concentration was studied in an attempt to reach high

    decolorization efciency. Results indicated that the optimal conditions

    for decolorization process were applied current of 0.3 A, initial Fe3+

    concentration of 0.05 mM and initial dye concentration of 10 mgrL-1.

    Keywords:Carbon nanotube; Photoelectro-Fenton; Reactive dye; Water

    treatment

    A.R. Khataee a*, B. Vahidb, B. Behjatia, M. Safarpoura, M. Zareia Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz,

    Tabriz, Iranb Young Researchers Club, Tabriz Branch, Islamic Azad University, Tabriz, Iran

    *[email protected]

    Applicaon of Carbon Nanotube-PTFE Cathode for Elec-

    trochemical Treatment of a Reacve Dye Soluon in aFlow Plant

    APP 198

    Multiwalled carbon nanotubes (MWCNTs) were acidied by H2O2,

    KMnO4 and HNO3, which they were, employed as adsorbent to study

    the adsorption characteristic for Pb+2 and Cu+2 from aqueous solu-

    tion. The results show that adsorption capacity of MWCNTs treated

    by oxidizing can be greatly enhanced. The larger adsorption capac-

    ity of acidied MWCNTs is mainly due to the exogenous functional

    groups formed on the surface of acidied MWCNTs. Therefore, oxida-

    tion process improves their dispersivity and increases a large amount

    of oxygen-containing functional groups like COOH, OH, or C=O

    on the surface site of CNTs.Our results suggest that MWCNTs can be

    good Pb+2 and Cu+2 absorbers and have great potential applications in

    environmental protection.

    Keywords:Carbon nanotubes; Oxidation; Adsorption; Functional groups

    A. Sabzalizade Farhood*, P.AberomandAzar

    Department of Science, Science and Research Branch, Islamic Azad Uni-

    versity, Tehran, Iran

    *[email protected]

    Removal of Cu+2and Pb+2 from Aqueous Soluons by

    Oxidized Mulwalled Carbon Nanotubes