pete 203: thermodynamics

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PETE 203: Thermodynamics Prepared by: Brosk Frya Ali Zangana Koya University, Faculty of Engineering, Petroleum Engineering Department 2013 2014 Lecture no. ( 6 & 7)

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Page 1: PETE 203: Thermodynamics

PETE 203: Thermodynamics

Prepared by:

Brosk Frya Ali Zangana

Koya University, Faculty of Engineering,

Petroleum Engineering Department

2013 – 2014

Lecture no. (6 & 7)

Page 2: PETE 203: Thermodynamics

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Thermodynamics Lecture NO. 6 & 7

Properties of pure substance

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Phases of a pure substance

Thermodynamics Lecture NO. 6 & 7

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Thermodynamics Lecture NO. 6 & 7

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Phase – Change Processes Of Pure Substances

Thermodynamics Lecture NO. 6 & 7

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Thermodynamics Lecture NO. 6 & 7

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Thermodynamics Lecture NO. 6 & 7

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Thermodynamics Lecture NO. 6 & 7

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Thermodynamics Lecture NO. 6 & 7

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Figure 1: T-v diagram representing phase change for water at constant pressure.

Thermodynamics Lecture NO. 6 & 7

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Saturation Temperature And Saturation Pressure

Thermodynamics Lecture NO. 6 & 7

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Thermodynamics Lecture NO. 6 & 7

Property Diagrams for Phase Change Processes

T-v Diagram

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Thermodynamics Lecture NO. 6 & 7

Figure 2: T-v diagram.

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Thermodynamics Lecture NO. 6 & 7

Figure 3: T-v diagram and

saturation lines.

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Thermodynamics Lecture NO. 6 & 7

P-v Diagram

Figure 4: P-v diagram.

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Thermodynamics Lecture NO. 6 & 7

Figure 5: P-v diagram for a substance that contracts during freezing (left) and for a substance that expends during freezing

(right).

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Thermodynamics Lecture NO. 6 & 7

Triple point

Until now, we have defined the equilibrium between two phases.

However, under certain conditions, water can exist at the same time as

ice (solid), liquid and vapor. Theses conditions define the so called

triple point.

On a P-T diagram, these conditions are represented by a point.

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Thermodynamics Lecture NO. 6 & 7

Figure 6: P-T diagram and

the triple point.