phosphoricacid85%

8/12/2019 phosphoricacid85%

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KIMIC CHEMITECH (S) PTE LTD623 Aljunied Rd #05-06B Aljunied Ind. Complex Singapore 389835 Tel: 6747-8377 Fax: 6747-8177

CHEMICAL SAFETY DATA SHEET1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

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PRODUCT NAME: Phosphoric acid 85%------------------------------------------------------------------------------------------------------------------------------

APPLICATION OF THE SUBSTANCE/ THE PREPARATION:Aqueous solution

SUPPLIERCompany: Kimic Chemitech (S) Pte LtdAddress: 623 Aljunied Road #05-06B Aljunied Industrial Complex Singapore 389835

Tel: 6747-8377Fax: 6747-8177

Email: [email protected]

2. HAZARDS IDENTIFICATION

Classification of substance or mixtureClassification (REGULATION EC No 1272/2008)

Skin corrosion, category 1B, H314Corrosive to metals, H290

Label ElementsPictogram and Symbol

Signal wordDANGER

EMERGENCY OVERVIEWHazard StatementCauses severe skin burns and eye damage

May be corrosive to metals

PRECAUTIONARY STATEMENTS

PreventionWear protective gloves/ protective clothing/ eye protection/ face protectionIf exposed or you feel unwell. Seek medical attention immediately


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ResponseContact with eyes: Rinse immediately with plenty of water for several minutes.

Contact on skin: Flush with plenty of water.If inhaled: Remove to fresh air. Keep warm and administer oxygen if necessary.

If swallowed: Do NOT induce vomiting. Give plenty of water.

StorageStore in cool and dry environment

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3. COMPOSITION/ INFORMATION ON INGREDIENTS

Formula H3PO4Cas no 7664-38-2Molar mass 98 g/mol

Weight % 85_________________________________________________________________________________________

4. FIRST AID MEASURES

Eye contact : Flush eyes with water for at least 15 minutes, lifting lower and uppereyelids occasionally. Seek medical attention immediately.

Skin contact : Flush skin with plenty of water. Remove contaminated clothing. Swabwith polyethylene glycol 400. Seek medical attention.

Ingestion : Make victim drink plenty of water. Avoid vomiting. Seek medical

advice immediately.Inhalation : Remove to fresh air. If breathing is difficult, call a physician

Important symptoms and effects

Acute and delayed : Irritation and corrosion, irritant effects, conjunctivities, pain,convulsions, shock, risk of blindness

Immediate medical attention

recommendation : No information available

5. FIRE-FIGHTING MEASURES

Specific risks : Not combustible. May develop hazardous vapours in event of fire. Firemay form oxides

Special protectiveequipment

: Wear full protective clothing and self-contained breathing apparatus.Prevent skin contact

Suitable extinguishing

media

: Water, foam, carbon dioxide, powder

Other information : Cool closed containers exposed to fire with water spray. Suppress gases/vapours with water spray jet

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Avoid substance contact. Avoid inhalation of vapours. Ensure adequateventilation. Wear protective equipment

Spill clean up : Take up with liquid absorbent and neutralising material. Disposeproperly. Clean up.

Environmental precautions : Do not allow to enter sewer/ surface or ground water


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7. HANDLING AND STORAGE

Handling : Avoid contact with eyes and skin.

Any incompatibilities : MetalsStorage : Keep in cool, well ventilated and dry place. Keep container tightly

closed.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure control

Engineering measures : Provide adequate ventiliation.

Personal protection equipment

Skin protection : lab coat, coveralls,boots and rubber glovesEye protection : protective goggles or full face shieldHygiene measures : Obey reasonable safety precautions and practise good housekeeping.

Remove all soiled clothing immediately

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Form : Liquid

Colour : colourlessOdour : odourless

Other data

pH, 200C : 0.5Solidification point : No informtion availableBoiling point : 1580C

Flash point : Does not flashEvaporating rate : No information available

Flammability : No applicableVapour pressure, 200C : 2 hPaRelative vapour density : No information available

Explosion limits, lower : Not applicableExplosion limits, upper : Not applicableRelative density at 200C : 1.71 g/cm3Solubility with water 200C : SolubleAutoignition temperature : No information available

Decompostion temperature : No information availableViscosity, dynamic : No information availableOxidising properties : No information availableExplosive properties : No information available

Ignition temperature : Not combustible


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Corrosivity : Corrosive to metals

10. STABILITY AND REACTIVITY

Reactivity : Corrosive effectChemical stability : Chemically stable under standard ambient conditions

Conditions to avoid : Strong heatingIncompatibles : Aluminium, iron/ iron containing compounds, mild steelPossible hazard reactions : Violent reactions possible with bases, metallic oxides

Risk of ignition or formation of inflammable gases or vapours withmetals, metal alloys.

Hazardous decomposition : See section 5

11. TOXICOLOGICAL INFORMATION

Acute oral toxicity : LD50 rat: 1.530 mg/kg

Symptoms- if ingested, severe burns of mouth and throat, plus danger ofperforation of oesophagus and stomach

Acute inhalation toxicity : LC50 rat: 0.85mg/m3/1hSymptoms-Mucosal irritations, cough, shortness of breath. Possible

damages damage of respiratory tract

Acute dermal toxicity : LD50 rabbit: 2.74 mg/kgAfter skin contact : Causes burnsAfter eye contact : Causes burns, risk of blindnessSensitisation : Human experience negative

Genotoxicity in vitro : Ames testSpecific target organtoxicity

: Single exposure not classifiedRepeated exposure not classified

Aspiration hazard : No aspiration toxicity classification

12. ECOLOGICAL INFORMATION

Toxicity : LC50 fish: 138 mg/l/96h gambusia affinis (mosquito fish)Biodegradability : No informationBioaccumulative potential : No informationMobility in soil : No information

Environmental fate : Harmful effect due to pH shift. Form corrosive mixture. Do not allowinto surface water and soil

13. DISPOSAL CONSIDERATIONS

Recommendations: Reduction

Reuse

Recycling

Disposal (if all else fails)

14. TRANSPORT INFORMATION

Labels required: corrosive solid

Land Trans ort UNDGUN 1805 hos horic acid 8 III


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Air Transport IATA:

UN 1805phosphoric acid, 8, III

Maritime Transport IMDG:

UN 1805, phosphoric acid, 8, IIIEMS Number: F-A S-B

15. REGULATORY INFORMATION

EU regulations : Major accident hazard, 96/82/ECLegistration : Directive 96/82/EC does not apply

Storage class : 8 B Non-combustible, corrosive substance

16. OTHER INFORMATION

H- Statement

H290 : May be corrosive to metals

H314 : Causes severe skin burns and eye damage

R-phase

R34 : Causes burns

Others

Training advice : Provide adequate information, instruction and training for operators

Issue number: OneIssue date: 15 Jan 2012

The information contained in this leaflet is the best of our knowledge accurate but is not warranted to be whether originatingwith the company or not. Recipients are advised to confirm in advance of need that information is current, applicable and

suitable to their circumstances.

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