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Presented by: Tanya Shanoff, M.Sc., P.Geo Pilot Scale Test for beneficial re-use of contaminated sediment

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Page 1: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Presented by: Tanya Shanoff, M.Sc., P.Geo

Pilot Scale Test for beneficial re-use of contaminated sediment

Page 2: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Presentation Layout 1 Study Background & Context

2 Project Background

3 Test Program Set-up and Methodology

4 Study Results to Date

5 Next Steps & Conclusions

6 Questions

7 Acknowledgements

Page 3: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Study Background & Context 1

140 SWM Ponds in the City of Kitchener

64 SWM Ponds in the City of Waterloo

37m3/yr Estimated volume

of SWM pond sediment generated

per pond

77 SWM Ponds in the City of Cambridge

Page 4: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Primary COCs in SWM Pond Sediment: PAHs PHCs NaCl Organic Nitrogen

Study Background & Context 1

Page 5: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Study Background & Context 1

Numerous studies on SWM ponds and sediment management Non-impacted SWM pond sediment management options Impacted SWM pond sediment management options BMPs

References: Minnesota Pollution Control Agency (June 2012),Marsalek, Watt and Anderson (2008), MOE (4328a)

Page 6: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Study Background & Context 1

Many studies to date on options for treating low level PAHs impacts in sediment/soil PAHs are transferred, degraded and sequestered Aerobic degradation Anaerobic degradation Cometabolism Biostimulation Composting Landfarming Phytoremediation

References: Boving and Neary (2007), Eick, Haus, Sukkariyah, Haering & Daniels (2011), Johnsen, Wick and Harms (2005), Haritash & Kawshik (2009)

Page 7: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Study Background & Context 1

Regulatory Environment Ontario Regulation 153/04 Draft Guidance Soil Management Compost Guidelines

Page 8: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Project Background 2

Rehabilitation of Victoria Park Lake in Downtown Kitchener, Ontario

Work included: • Environmental Assessment Study • Detailed Design and Construction

o including management of >55,000 tonnes of impacted sediment in the Lake

Stantec approached Kitchener and the Region on innovative approach Kitchener and the Region entered into an agreement and received funding from MOE

Funding for this project was provided by the Showcasing Water innovation Grant through the Ontario Ministry of Environment (MOE). Such support from the MOE does not indicate endorsement by the Government of Ontario of the contents of this material

Page 9: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Questions we asked ourselves

?

Page 10: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Project Background 2

Broader scale applications may include:

Minimize Reuse Soil and Material Establish Stockpile Treat & Manage Reuse Treated vs. Recycling Products

Page 11: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Project Background 2 Project elements: Excavation Stabilization

Page 12: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Project Background 2 Project elements: Sampling In situ Ex situ At study site

Page 13: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Test Program Set-up and Methodology 3 Stockpiles: Untreated, Nutrient Added, Compost Sampling Program Reduction in concentrations of COCs Planned Beneficial End Use

Page 14: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

9 large

stockpiles

4 small

stockpiles +

Reorganized piles for study

program

Page 15: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Control Add

nutrients. Cover.

Exposed with

nutrients

Exposed without

nutrients

Covered with

nutrients

Covered without

nutrients

Test Pile Setup Based on Initial Sampling Results

Page 16: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Mix Material with Compost

Control

Pile E

20% material : compost

ratio

Pile B

add 10% material to the pile after 4

months

Pile C

add 20% material to the pile after 4

months

Pile D

10% material : compost

ratio

Pile A

Page 17: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Test Program Set-up and Methodology 3

Sampling Program Design Composites Appropriate Volume Representativeness

Reference: Lame, Honders, Derksen and Gadella (2005)

Page 18: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Test Program Set-up and Methodology 3

Challenges Funding Material State Winter Conditions

Page 19: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Study Results to Date 4

In situ vs. ex situ Elevated SAR Elevated organic nitrogen Elevated PHCs and PAHs

Page 20: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Study Results to Date 4

0100200300400500600700800900

1000

PHC F2 (>C10-C16range)

PHC F3 (>C16-C34range)

PHC F4 (>C34-C50range)

Average PHC Concentrations (µg/g) in Untreated Test Piles

In situ (May 2011) Ex situ (Dec 2011 and Jan 2012)

Control (Nov 2012) Untreated (May 2013)

Control (June 2013)

0100200300400500600700800900

1000

PHC F2 (>C10-C16range)

PHC F3 (>C16-C34range)

PHC F4 (>C34-C50range)

Average PHC Concentrations (µg/g) in Treated Test Piles

Control (Nov 2012) Nutrient (Nov 2012)

Control (June 2013) Nutrient (June 2013)

Page 21: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Study Results to Date 4

0200400600800

10001200140016001800

PHC F2 (>C10-C16range)

PHC F3 (>C16-C34range)

PHC F4 (>C34-C50range)

Maximum PHC Concentrations (µg/g) in Untreated Test Piles

In Situ (May 2011) Ex Situ (Dec 2011 and Jan 2012)

Control (Nov 2012) Untreated (May 2013)

Control (June 2013)

0200400600800

10001200140016001800

PHC F2 (>C10-C16range)

PHC F3 (>C16-C34range)

PHC F4 (>C34-C50range)

Maximum PHC Concentrations (µg/g) in Treated Test Piles

Control (Nov 2012) Nutrient (Nov 2012)

Control (June 2013) Nutrient (June 2013)

Page 22: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Study Results to Date 4

012345

Average Selected PAH Concentrations (µg/g) in

Untreated Test Piles

In Situ (May 2011) Ex situ (Dec 2011 and Jan 2012)

Control (Nov 2012) Untreated (May 2013)

Control (June 2013)

0

1

2

3

4

5

Average Selected PAH Concentrations (µg/g) in Treated

Test Piles

Control (Nov 2012) Nutrient (Nov 2012)

Control (June 2013) Nutrient (June 2013)

Page 23: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Study Results to Date 4

0123456789

1011

Maximum Selected PAH Concentrations (µg/g) in

Untreated Test Piles

In situ (May 2011) Ex situ (Dec 2011 and Jan 2012)

Control (Nov 2012) Untreated (May 2013)

Control (June 2013)

0123456789

1011

Maximum Selected PAH Concentrations (µg/g) in Treated

Test Piles

Control (Nov 2012) Nutrient (Nov 2012)

Control (June 2013) Nutrient (June 2013)

Page 24: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Study Results to Date 4

Summary Nutrient Value Reductions in PHCs, PAHs, & SAR Impact on Compost Quality

Page 25: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Study Results to Date 4

Summary Analysis/Sampling of study stockpiles – on going Compost study – on going Discussion on options for soil management in

the Region – on going

Page 26: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Next Steps & Conclusions 5 Additional sampling in 2013 Comparison of results Determination of end use

Page 27: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

? Questions 7

Page 28: Pilot Scale Test - ESAA · Elevated SAR . Elevated organic nitrogen ... range) Average PHC Concentrations (µg/g) in Untreated Test Piles In situ (May 2011) Ex situ (Dec 2011 and

Thanks to: Naz Ritchie & Mike Greenhill

(Regional Municipality of Waterloo) Melissa Ryan & Nick Gollan (City of Kitchener) Tiana Robinson, Mike Charles & David Wilson

(Stantec)

Acknowledgements 8