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TRANSCRIPT
Product Guide
Liquid Polybutadienes 6
SMA® Resins 10
Hydrocarbon Resins
New Additive Technologies
Reference Guide
12
14
16
Dymalink® Monomers 8
Product Guide
Profile
Total Cray Valley (TCV) is a global organization dedicated to supplying specialty materials. As part of the Total Group, Total Cray Valley can leverage key petroleum feedstock positions to deliver high-quality products. The various product lines are marked by a diversity of chemistries, which enables a broad spectrum of end-use opportunities.
Total Cray Valley manufactures and supplies diene-based liquid homopolymers and copolymers, C5 and C9 hydrocarbon tackifying resins, styrene-maleic anhydride copolymers and derivatives, metallic monomer salts of acrylic and methacrylic acid, and specialty monomer products.
Total Cray Valley sells these products under the Ricon®, Ricobond®, Krasol™, Poly bd®, Wingtack®, Cleartack®, SMA® and Dymalink® brand names.
The Total Cray Valley organization focuses on two main markets, rubber and adhesives, while also supporting other traditional markets and new opportunities in the electronics, coatings, and plastics modification areas.
The many applications of Total Cray Valley products include: plasticizing polymeric systems; crosslinking saturated and unsaturated polymers or other resins systems; adhesion aids or components of adhesives and sealants; chemical intermediates including polyols for polyurethane synthesis; additives to improve the dispersion of fillers, pigments, or other materials; and additives used in the compounding of thermoplastic resins.
Total Cray Valley continues to create synergies between the core product lines and provide increased value to the market, building on a strong technology and manufacturing base, which enables Total Cray Valley to grow together with our customers.
Main Trademarks
•Ricon®
•Ricobond®
•Krasol™
•Polybd®
•Wingtack®
•Cleartack®
•SMA®
•Dymalink®
• Headquarters
Exton, Pa., USA Paris, France Guangzhou, China
• Laboratories
Exton, Pa., USA Verneuil, France Kralupy, Czech Republic
• Sales Offices
Exton, Pa., USA Paris, France Yokohama, Japan São Paolo, Brazil Guangzhou, China
• Manufacturing Sites
Grand Junction, Colo., USA Channelview, Texas, USA Beaumont, Texas, USA Chatom, Ala., USA Stratford, Conn., USA Carling, France Kralupy, Czech Republic Ravenna, Italy
Americas
Total Cray Valley (TCV) Eagleview Corporate Center 665 Stockton Drive, Suite 100 Exton, PA 19341 USA
Tel: 877-US1-CRAY (877-871-2729) Fax: 610-363-4198 E-mail: [email protected]
Europe & Africa
Cray Valley 16-32 rue Henri Regnault La Défense 6 92902 Paris La Défense Cedex France
Tel: +01 47 96 99 08 Fax: +01 47 96 99 86
Asia
Cray Valley (Guangzhou) Chemical Co., Ltd. Room 2507-09, The South Securities Building No. 140-148, Tiyu Dong Rd. Tianhe District Guangzhou 510620 P.R. China
Tel: +86 20 38879156 Fax: +86 20 28878495
Contacts Around the World
Global Presence
2 3
Rubber Market
Total Cray Valley has a long history serving the rubber marketplace with functional additive products.
Beginning with classic peroxide-cure coagent technologies, Total Cray Valley is a trusted provider of metallic monomers to belt, hose, seal, and wire and cable manufacturers. Total Cray Valley metallic monomer products are employed to improve rubber adhesion and dynamic properties in a variety of applications. Cured-in-place rubber to metal adhesion is enabled through the use of metallic monomer coagents and Ricobond resins. Other diene polymers can be used as functional additives for treating reinforcing textiles.
More recently, Total Cray Valley has developed a portfolio of products for the tire industry. Ricon liquid polybutadiene resins are established as performance-enhancing additives for tire applications. Ricon resins are employed to modify the viscoelastic response of the tread compound, enabling improvements to the traction/fuel economy/wear property balance.
Total Cray Valley is committed to supplying value-added specialty materials to the rubber market, and will work with customers to develop custom materials to meet their performance needs.
Adhesives and Sealants Market
Total Cray Valley is a well-known supplier of hydrocarbon resins to the adhesives marketplace. Wingtack and Cleartack grades tackifying resins are specified in a variety of adhesive applications, including hot melt adhesives, pressure sensitive tape and label adhesives, and formulated mastics.
Expansion into new adhesive technologies is made possible by leveraging other product lines. Reactive urethane and epoxy-based adhesives may benefit through the use of maleic-anhydride functional resins, polybutadiene diols, and metallic monomers.
In addition, Total Cray Valley supplies Poly bd and Krasol polyols to a variety of urethane-based sealant applications, including the insulated glass sealant market. Adhesive tie layers can be formed from our unique thermoplastic urethane products.
Rubber Adhesives & Sealants Thermoplastics Specialty Markets
Ricon®Packaging, Coatings,
Electronics
Poly bd®Fuel Binders, Urethanes,
Electronics
Krasol™Urethanes, Coatings,
Electronics
Wingtack®Waxes, Casting,
Coatings
Cleartack® Coatings
SMA®Electronics, Leather,
Inks, Sizing, Dispersions
Dymalink®Coatings,
Sporting Goods
Main Markets
4 5
Specialty Markets
The Total Cray Valley product lines are utilized in a number of other market segments that take advantage of the unique structure/property relationships inherent in the specialty grades.
Most notably, many of the reactive polymer products have found utility in the thermoplastic modification market. The high Tg resins can impart increased heat distortion resistance to many commodity plastic grades, SMA resins are used to improve the properties of virgin and recycled polyaramids, and metallic monomers are capable of improving the physical properties of standard polyolefins. The diene-based polymer products are also finding utility as additives to thermoplastics packaging, improving the oxygen barrier properties of films. Ricon MA and other functional grades are used to improve the dispersion of organic and inorganic fillers in many thermoplastic compound formulations.
There are many other markets that have taken advantage of the diversity of chemistry and material properties including electronics, industrial coatings, and polyurethanes. Our goal is to work with every customer to provide value-added specialty materials that increase the performance of their products.
Market Breakdown
Total Cray Valley offers a diverse selection of specialty liquid polybutadiene grades including low and high vinyl polybutadiene homopolymers and poly(styrene-butadiene) copolymers. Ricon grades offer a complete selection of microstructures, which translates to a wide spectrum of glass transition temperatures. In addition to the base product line, functional derivatives are available. The Ricon MA and Ricobond series include maleic anhydride grafted grades. Poly bd hydroxyl-terminated poly-butadienes are available, and our unique Krasol product line consists of both unsaturated and fully hydrogenated telechelic polybutadiene diols.
The products are used in an equally broad spectrum of markets and applications. Low-viscosity liquid polybutadienes are used as processing aids, and the wide Tg range allows for modification of tire performance properties. In addition, high vinyl grades are useful as coagents for the peroxide cure of rubber. Functional grades expand the utility of the polybutadiene resins to many other applications, including polyurethanes, hydrophobic sealants and coatings, and thermoplastic modification.
Liquid Polybutadienes
Product Description Typical Properties Availability
Molecular Weight (Mn, g/mol) 1,2 Vinyl (%) Viscosity (cps) Tg (°C)
Specific Gravity @ 25 °C MA (/chain) -OH (/chain) Epoxy
(eq. wt.)
Ricon Low Vinyl Content
Ricon 130 Homopolymer of Butadiene 2,500 28 750 @ 25 °C -86 0.89 -- -- -- US, EU, Asia
Ricon 131 Homopolymer of Butadiene 4,500 28 2,750 @ 25 °C -84 0.89 -- -- -- US, EU, Asia
Ricon 134 Homopolymer of Butadiene 8,000 28 15,000 @ 25 °C -81 0.89 -- -- -- US, EU, Asia
Ricon 138 Homopolymer of Butadiene 2,000 40 8,000 @ 25 °C -73 0.89 -- -- -- US, EU, Asia
High Vinyl Content
Ricon 150 (Ricon 150D) Homopolymer of Butadiene (Dry Liquid 70% Active) 3,900 70 40,000 @ 25 °C -40 0.89 -- -- -- US, EU, Asia
Ricon 152 (Ricon 152D) Homopolymer of Butadiene (Dry Liquid 70% Active) 2,900 80 20,000 @ 45 °C -30 0.89 -- -- -- US, EU, Asia
Ricon 153 (Ricon 153D) Homopolymer of Butadiene (Dry Liquid 65% Active) 4,700 85 60,000 @ 45 °C -28 0.89 -- -- -- US, EU, Asia
Ricon 154 (Ricon 154D) Homopolymer of Butadiene (Dry Liquid 65% Active) 5,200 90 250,000 @ 45 °C -15 0.89 -- -- -- US, EU, Asia
Ricon 156 Homopolymer of Butadiene 1,400 70 1,600 @ 25 °C -56 0.89 -- -- -- US, EU, Asia
Ricon 157 Homopolymer of Butadiene 1,800 70 6,000 @ 25 °C -51 0.89 -- -- -- US, EU, Asia
Styrene-Butadiene Copolymers
Ricon 100 Butadiene-Styrene Random Copolymer (25% Styrene) 4,500 70 40,000 @ 45 °C -15 0.90 -- -- -- US, EU, Asia
Ricon 181 Butadiene-Styrene Random Copolymer (28% Styrene) 3,200 30 17,500 @ 25 °C -65 0.90 -- -- -- US, EU, Asia
Ricon 184 Butadiene-Styrene Random Copolymer (28% Styrene) 8,600 30 75,000 @ 25 °C -57 0.90 -- -- -- US, EU, Asia
Ricon 250* Butadiene-Styrene Random Copolymer (35% Styrene) 5,300 70 900 @ 25 °C -- 0.90 -- -- -- US, EU, Asia
Ricon MA, Ricobond Low Vinyl Content
Ricon 130MA8 Maleinized Polybutadiene 3,100 28 6,500 @ 25 °C -82 0.90 2 -- -- US, EU, Asia
Ricon 131MA5 Maleinized Polybutadiene 4,700 28 15,000 @ 25 °C -83 0.90 2 -- -- US, EU, Asia
Ricobond 1731 (Ricobond 1731HS) Maleinized Polybutadiene (Dry Liquid 69% Active) 5,400 28 50,000 @ 45 °C -72 0.91 9 -- -- US, EU, Asia
High Vinyl Content
Ricobond 1756 (Ricobond 1756HS) Maleinized Polybutadiene (Dry Liquid 69% Active) 2,500 70 140,000 @ 55 °C -18 0.91 3 -- -- US, EU, Asia
Krasol** Diol
Krasol LBH 2000 Hydroxyl-Terminated Polybutadiene 2,100 65 13,000 @ 25 °C -35 0.89 -- 1.9 -- US, EU, Asia
Krasol LBH-P 2000 Hydroxyl-Terminated Polybutadiene (Primary-OH) 2,100 65 13,000 @ 25 °C -35 0.89 -- 1.9 -- US, EU, Asia
Krasol LBH 3000 Hydroxyl-Terminated Polybutadiene 3,000 65 20,000 @ 25 °C -35 0.89 -- 1.9 -- US, EU, Asia
Krasol LBH-P 3000 Hydroxyl-Terminated Polybutadiene (Primary-OH) 3,200 65 20,000 @ 25 °C -35 0.89 -- 1.9 -- US, EU, Asia
Krasol LBH 5000 Hydroxyl-Terminated Polybutadiene 5,000 65 30,000 @ 25 °C -35 0.89 -- 1.9 -- US, EU, Asia
Hydrogenated Diols
Krasol HLBH-P 2000 Hydroxyl-Terminated Hydrogenated Polybutadiene 2,100 -- 1,750 @ 60 °C -46 0.88 -- 1.9 -- US, EU, Asia
Krasol HLBH-P 3000 Hydroxyl-Terminated Hydrogenated Polybutadiene 3,100 -- 3,000 @ 60 °C -46 0.88 -- 1.9 -- US, EU, Asia
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(Liquid Polybutadienes list continues on next page)
*52% Solids in Toluene**Krasol and Poly bd products require a license for export
Total Cray Valley provides a selection of metallic monomers. Straight-grade and scorch-retarding rubber coagent monomers are available for peroxide-cure applications, while our specialty monomers are used in a wide variety of cure systems, including accelerated sulfur vulcanization and metal oxide cure.
Our products find utility in a variety of applications including tires, power transmission belts, rubber sealing systems, coatings, thermoplastics, and adhesives.
Dymalink® Monomers
Product Description Typical Properties Availability
Appearance Specific Gravity @ 25 °C Percent Actives
Specialty Monomers Straight Grade
Dymalink 636 Calcium Diacrylate white powder 1.44 100 US, EU, Asia
Dymalink 705 Zinc Diacrylate white powder 1.68 100 US, EU, Asia
Dymalink 706 Zinc Diacrylate white powder 1.68 100 US
Dymalink 708 Zinc Dimethacrylate white powder 1.49 100 US, EU, Asia
Dymalink 709 Zinc Monomethacrylate white powder 1.88 100 US, EU, Asia
Scorch Retarding
Dymalink 633 Zinc Diacrylate off-white powder 1.59 100 US, EU, Asia
Dymalink 634 Zinc Dimethacrylate off-white powder 1.48 100 US, EU, Asia
8 9
Liquid Polybutadienes (continued)Liquid Polybutadienes (continued from previous page)
**Krasol and Poly bd products require a license for export.
Product Description Typical Properties Availability
Molecular Weight (Mn, g/mol) 1,2 Vinyl (%) Viscosity (cps) Tg (°C)
Specific Gravity @ 25 °C MA (/chain) -OH (/chain) Epoxy
(eq. wt.)
Krasol** Monol
Krasol LBH 5000M Hydroxyl-Terminated Polybutadiene 5,000 65 25,000 @ 25 °C -45 0.89 -- 0.98 -- US, EU, Asia
Krasol HLBH 5000M Hydroxyl-Terminated Hydrogenated Polybutadiene 5,000 -- 65,000 @ 25 °C -57 0.88 -- 0.92 -- US, EU, Asia
Poly bd** Polyol
Poly bd R-45HTLO Hydroxyl-Terminated Polybutadiene 2,800 20 5,000 @ 30 °C -75 0.90 -- 2.5 -- US, EU, Asia
Poly bd R-45V Hydroxyl-Terminated Polybutadiene 2,800 20 5,000 @ 30 °C -75 0.90 -- 2.5 -- EU, Asia
Poly bd R-20LM Hydroxyl-Terminated Polybutadiene 1,200 20 1,400 @ 30 °C -70 0.91 -- 2.5 -- US, EU, Asia
Epoxidized
Poly bd 605E Epoxidized Hydroxyl-Terminated Polybutadiene 1,450 20 12,000 @ 30 °C -47 1.01 -- 2.5 450 US, EU, Asia
Poly bd 700I Epoxidized Hydroxyl-Terminated Polybutadiene 3,000 20 10,000 @ 30 °C -65 1.01 -- 2.5 400 US, EU, Asia
Total Cray Valley produces a line of low molecular weight styrene-maleic anhydride copolymer resins with an extended range of monomer ratios. Based on these platforms, a number of value-added derivatives are formed, including specialty esters and imides. In addition, the base products can be esterified to form a variety of water-soluble salts.
The product diversification allows for an equally broad spectrum of end-use applications. The inherent heat resistance properties as well as reactive MA groups can provide value in polymer modification and electronics applications. The liquid forms are excellent dispersants over a broad pH range, providing utility in the coatings, inks, and paper industries. An abundance of MA groups allows SMA resins to be used in applications where targeted chemistry is required, including reactive modification of thermoplastics.
SMA® Resins
Product Description Typical Properties Liquid Forms Availability
Ratio Styrene/Maleic Appearance Molecular Weight (Mn, g/mol) Tg (°C) Weight % MA Amine Index
(meq/g)
SMA Base Resins
SMA 1000 Base Resin 1 F, P 2,100 155 42 -- H, HNa, MA US, EU, Asia
SMA 2000 Base Resin 2 F, P 2,700 135 29 -- H US, EU, Asia
SMA 2021 Base Resin 2 F, P 12,000 155 29 -- H US, EU, Asia
SMA 3000 Base Resin 3 F, P 3,050 125 23 -- H, HNa US, EU, Asia
SMA EF30 Base Resin 3 F, P 3,050 125 23 -- -- US, EU, Asia
SMA 3024 Base Resin 3 F, P 10,000 141 23 -- -- US, EU, Asia
SMA 4000 Base Resin 4 F, P 3,600 115 19 -- -- US, EU, Asia
SMA EF40 Base Resin 4 F, P 3,600 115 19 -- -- US, EU, Asia
SMA EF50 Base Resin 5 F, P 5,000 110 16 -- -- US, EU, Asia
SMA EF60 Base Resin 6 F, P 5,500 106 13 -- -- US, EU, Asia
SMA EF80 Base Resin 8 F, P 7,500 104 11 -- -- US, EU, Asia
Esters
SMA 1440 Ester Resin -- F 2,900 60 -- -- H, HLS, HK US, EU, Asia
SMA 17352 Ester Resin -- F, P 2,900 125 -- -- H US, EU, Asia
SMA 2625 Ester Resin -- F, P 3,100 110 -- -- H US, EU, Asia
SMA 3840 Ester Resin -- F 4,100 75 -- -- -- US, EU, Asia
Imides
SMA 1000I Imide Resin 1 P 2,100 85 -- 3.15 -- US, EU, Asia
SMA 2000I Imide Resin 2 P 2,700 88 -- 2.5 -- US, EU, Asia
SMA 3000I Imide Resin 3 P 3,050 90 -- 2.15 -- US, EU, Asia
SMA 4000I Imide Resin 4 P 3,600 90 -- 1.75 -- US, EU, Asia
Key
F Flake
P Powder
H Ammonia Hydrolyzed
HNa Sodium Hydrolyzed
HK Potassium Hydrolyzed
HLS Ammonia Hydrolyzed Low Solids
MA Methyl Amine Amic Acid
10 11
Hydrocarbon Resins
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Total Cray Valley’s hydrocarbon resin products complete a diverse portfolio. The Wingtack and Cleartack lines cover a wide spectrum of aliphatic and aromatic grades. The Wingtack grades are high-quality, low-color C5 and C5/C9 resins. The Cleartack W series are colorless pure-monomer resins.
Hydrocarbon resins from Total Cray Valley have utility in many markets. In adhesives, hydrocarbon resins are used in hot melts, pressure sensitive tapes and labels, construction mastics and many specialty applications. Hydrocarbon resins are also excellent tackifiers and compatibilization aids in the rubber market. In addition, hydrocarbon resins have found utility in coatings, investment wax casting compounds and thermoplastic modification.
***50% Toluene Solution
Product Description Typical Properties Availability
Softening Point (RB, °C) Appearance Gardner Color*** Specific Gravity @ 20 °C Molecular Weight
(Mn, g/mol) Tg (°C)
Wingtack
Wingtack 10 C5 Hydrocarbon Resin 10 Light yellow liquid 1.5 0.90 370 -31 US, EU, Asia
Wingtack 86 C5 Hydrocarbon Resin 87 Light yellow solid 1.2 0.98 650 42 US, EU, Asia
Wingtack 95 C5 Hydrocarbon Resin 98 Light yellow solid 1.7 0.94 1100 52 US, EU, Asia
Wingtack 98 C5 Hydrocarbon Resin 98 Light yellow solid 2.3 0.95 1000 48 US, EU, Asia
Wingtack RWT-7850 C5 Hydrocarbon Resin 102 Light yellow solid 2.4 0.95 1000 56 US, EU, Asia
Wingtack Plus C5 Hydrocarbon Resin 96 Light yellow solid 1.6 0.95 1000 50 US, EU, Asia
Wingtack EXTRA C5 Hydrocarbon Resin 97 Light yellow solid 1.4 0.96 1100 52 US, EU, Asia
Wingtack ET C5 Hydrocarbon Resin 95 Light yellow solid 2.0 0.96 1000 47 US, EU, Asia
Wingtack STS C5 Hydrocarbon Resin 94 Light yellow solid 3.0 0.97 1000 44 US, EU, Asia
Softening Point (RB, °C) Appearance Hazen Color*** Specific Gravity @ 20 °C Molecular Weight
(Mn, g/mol) Tg (°C)
Cleartack
Cleartack W-85 Pure Monomer Resin 85 Colorless solid <40 1.06 600 35 US, EU, Asia
Cleartack W-90 Pure Monomer Resin 90 Colorless solid <40 1.06 650 40 US, EU, Asia
Cleartack W-100 Pure Monomer Resin 100 Colorless solid <40 1.06 750 50 US, EU, Asia
Cleartack W-110 Pure Monomer Resin 110 Colorless solid <40 1.06 850 60 US, EU, Asia
Cleartack W-120 Pure Monomer Resin 120 Colorless solid <40 1.06 950 70 US, EU, Asia
Cleartack W-130 Pure Monomer Resin 130 Colorless solid <40 1.06 1100 80 US, EU, Asia
Cleartack W-140 Pure Monomer Resin 140 Colorless solid <40 1.06 1200 90 US, EU, Asia
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New Additive Technologies
14
Total Cray Valley is always introducing new and unique additives for the markets we service. Whether aimed at our core markets of rubber and adhesives, focus areas such as polymer modification, or new development areas such as water-based coatings, Total Cray Valley continues to provide industry with new and creative chemistries to solve the toughest challenges.
Product Typical Properties
Appearance Viscosity (cps @ 25 °C)
Molecular Weight
(Mn, g/mol)Tg (°C)
Specific Gravity @ 20 °C Aromaticity
Ricon 300 Viscous Liquid 750 2,500 -85 0.89 No
Ricon 330 Solid N/A 600 35 1.06 Yes
Ricon 340 Viscous Liquid 30,000 400 -31 0.90 No
Ricon 350 Solid N/A 1,000 45 0.97 Yes
Product Typical Properties
Appearance Percent Actives
Targeted Systems
Specific Gravity @ 20 °C Application
SMA 9001 Pellets Concentrate 40 Polyamide 1.03 Viscosity Modification
SMA 9002 Pellets Concentrate 30 Polyamide 0.99 Recycled Polyamide
SMA 9003 Pellets Concentrate 35 Polyamide 0.94 Reinforced Polyamide
Dymalink 9100 White Powder 100 Polyethylene 1.51 Ionomeric Crosslinker
Dymalink 9200 White Powder 100 Polypropylene 1.68 Ionomeric Crosslinker
Dymalink 9201 Pellets Concentrate 70 Polypropylene 1.29 Ionomeric Crosslinker
Plastics
Rubber
15
Product Typical Properties
Appearance Solids pH Viscosity (cps @ 25 °C) Salt Form
Ricobond 7002 Milky Liquid 28 8.5 100 Sodium
Ricobond 7004 Lt. Brown Liquid 30 8.5 500 Ammonium
Product Typical Properties
Appearance Viscosity (Pa.s @ 25 °C) Tg (°C)
Acid Value mg KOH/g Affinity
Ricobond 5112 Viscous Yellow Liquid 350 -30 50 Aliphatic Polymers
Ricobond 5122 Viscous Yellow Liquid 300 -50 185 Aromatic Polymers
Water-Based Coatings and Dips
Adhesives
Reference Guide
16
-100 -50 0 50 100 150 200
°C
Ricon® Cleartack®
Poly bd® Wingtack®
Krasol™ SMA®
Glass Transition Temperature (Tg)
Ricon®
Poly bd®Wingtack®
Krasol™
Cleartack® SMA®
100 1000 10000 100000
g/mol in log scale
Molecular Weight (Mn)
17
Technology
Total Cray Valley (TCV) and the Total Group
Total Cray Valley is part of Total Refining and Chemicals Global Polymers Division.
Total’s Refining and Chemicals is a major production hub covering refining, petrochemicals and specialty chemicals. Petrochemicals encompasses base chemicals and polymer derivatives. Specialty Chemicals spans elastomer processing, lubricants, general metal finishing, and surface finishing.
Backed by the financial resources and technical services of the Polymers Division of Total, Total Cray Valley provides a strong global approach to R&D, manufacturing, and customer support.
Plasticizer Crosslinking AdhesionChemical
Intermediate/Polymerization
Dispersion/Surface
ModificationOther
Ricon®
Poly bd®
Krasol™
Wingtack®
Cleartack®
SMA®
Dymalink®
www.crayvalley.com
Email: [email protected]
877-US1-CRAY
877-871-2729
www.crayvalley.com
Total Cray Valley (TCV)
Eagleview Corporate Center
665 Stockton Drive, Suite 100
Exton, PA 19341 USA
The information in this bulletin is believed to be accurate, but all recommendations are made without warranty since the conditions of use are beyond Total Cray Valley’s control. The listed properties are illustrative only and not product specifications. Total Cray Valley disclaims any liability in connection with the use of the information and does not warrant against infringement by reason of the use of its products in combination with other material or in any process.
01/2015