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PLANT CARE SOLUTIONS Plant-based Solutions for Plant Nutrition, Formulation and Seed Treatment

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Formulation and Seed Treatment
CTS SERVICES
PLANT NUTRITION
Roquette is a global leader in plant-based ingredients and a pioneer of new vegetal proteins.
Thanks to a constant drive for innovation and a long-term vision, the Group is committed to improving the well-being of millions of people all over the world while taking care of resources and territories.
A transition to plant-based raw materials for formulation, plant nutrition and production of microbials is critical to meet modern society’s ever-evolving challenges.
Roquette provides a full range of solutions supporting this environmental transition, including:
• Ingredients for Plant Nutrition (Organic Fertilizers)
• Solutions for the production and stabilization of bio-intrants (biostimulants, biopesticides)
• Plant-based alternatives for existing chemical polymers
INNOVATING
• Develop a sustainable development journey inspired by our customers’ expectations
• Strengthen sustainability in our innovation processes
SOURCING
• Strengthen relationship with our raw materials suppliers
BIOREFINING
ACTING
• Put health, safety and well-being at the heart of our concerns
• Empower employees
INTRODUCTION
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• Do you want biodegradable materials?
• Do you need growth enhancers or carbohydrate sources?
• Would you like to remove, reduce or control the release of toxic materials?
• Are you developing bio-based alternatives?
Thanks to our plant science expertise, we are able to offer efficient and environmentally friendly solutions
for your plant-care. Our wide range of products derived from maize, wheat, potato and pea will help you
in a variety of applications from system design (agglomeration, encapsulation...) to nutritional solutions
(growth factor, glucose intake...).
SOLUBLEFRACTION FATTYFRACTION CELLULOSEFRACTION PROTEINFRACTION
INTRODUCTION
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OVERVIEW
• Increase nutrient absorption • Promote stress tolerance • Provide key nutrients and growth factors • Enable reduction of inorganic fertilizers • Stimulate root growth • Improve germination
These products are used in foliar and soil applications for fruits, vegetables, row crops, hydroponics, and in a wide range of other domains, like gardening for example.
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FUNCTIONALITIES SOLULYS® is a unique vegetable-based protein extract, valued for its nitrogen and critical growth-factor contents. The amino acids, peptides, vitamins, and trace elements located in the corn kernel are valuable additions to a variety of microbial biostimulants and plant nutrition formulations, including gardening and field foliar applications.
DEFINITION SOLULYS® is obtained via a biochemical process that includes a controlled fermentation step, resulting in a product with consistent composition and no observed seasonal variability. The strong acidity, osmotic pressure and low reducing sugar content guarantee the stability of the final product.
Our SOLULYS® product range has become one of the most commonly used growth factors in the world, thanks to its production at industrial scale, performance and cost effectiveness.
TURGESCENT GRAIN 44% H2O
Wrapper
Proteins
Starch
Germ
Releasing of starch granule
Swelling of germ
• SOLULYS® 048: corn extract at 48% dry matter.
• SOLULYS® 048P: corn extract with available phosphorus at 48% dry matter.
• SOLULYS® 095: corn extract powder at 95% dry matter.
PRODUCT INFORMATION Specifications*:
Reducing sugars 1% max. 1% max.
Amino nitrogen 2.5% 2.5%
Total nitrogen 7.1% 7.8%
Ash 19% 16%
(% dissolved solids basis) (% dissolved solids basis)
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Pantothenic acid (Vit. B5) 1.4 mg/100g
Pyrodoxin (Vit. B6) 3 mg/100g
Cholin (Vit. B7) 216 mg/100g
Biotin (Vit. B8) 8 ug/100g
Folic acid (Vit. B9) 124 ug/100g
Cyanocobalamin (Vit. B12) 1.8 ug/100g
Vitamins* Range Unit
• Kosher • BSE
• Halal • TSE
Packaging available: • Bulk
Manufacturing: • Europe • America
Storage conditions and sterilization: We recommend preserving the product in its unopened original packaging, preferably protected from wide variation of T° and humidity.
In order to limit precipitation during formulation/ dilution of SOLULYS®, it is advised to maintain a pH of 5.0 or lower.
Our technical team looks forward to sharing our recommendations to help you achieve your goals.
Calcium (Ca++) 0.06
Magnesium (Mg++) 1.4
Phosphorus (P+) 3.4
Potassium (K+) 5.3
Sodium (Na++) 0.6
Minerals* Range (%)
(*) Typical values
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FUNCTIONALITIES
GLUTALYS® HQD is a gluten-rich, non-hydrolyzed protein source from corn, intended for soil and plant
nutrition. GLUTALYS® HQD is mainly composed of prolamine-type proteins that are rich in leucine.
The other substances, namely albumin, globulin and glutelin, have relatively high levels of lysine and
tryptophan. Eventually, glutamic acid is the most represented amino acid.
The low water solubility of GLUTALYS® HQD enables a slow release of nitrogen for long-term nutrition
of soils and plants, while the soluble nitrogen fraction makes it a good short-term solution for easily
accessible nitrogen supplementation. Moreover, GLUTALYS® HQD exhibits a long shelf-life as a bagged
dry material, allowing it to be stored easily and applied to the soil when needed.
DEFINITION Concentrated protein extracted from corn through a wet milling process.
PRODUCT RANGE • GLUTALYS® HQD: corn gluten.
PRODUCT INFORMATION Specifications*:
Manufacturing: • Europe
GLUTALYS® HQD
Appearance Powder
(*) Indicative values
% AA in protein GLUTALYS®
Arginine*** 4.28
Histidine*** 1.96
Isoleucine*** 3.53
Leucine*** 10.86
Lysine*** 4.58
Methionine*** 2.43
Cysteine*** 1.37
Phenylalanine*** 4.49
*Tyrosine*** 3.38
Threonine*** 3.64
Tryptophan*** 1.14
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PRODUCT RANGE • NUTRALYS® H85: a pea protein hydrolysate.
PRODUCT INFORMATION Specifications*:
Protein (Nx6.25) 76% min.
CAS Number: • 90082-41-0
Quality information: • Kosher • Non-GMO** • Not a major allergen*
Packaging available: • Big bag • 20/25 kg bag Alternatives to be evaluated upon request.
Manufacturing: • Europe
(*) According to EU regulation 1169/2011 (**) According to EU regulation 1829/2003 - 1830/2003
DEFINITION NUTRALYS® H85 is a pea protein hydrolyzate containing free amino acids and peptides. Pea proteins are an ideal substitute for traditional organic protein or nitrogen sources. They are:
Amino Acid profile (%)
Threonine Serine Glutamic acid
Lysine Histidine Arginine Proline Tryptophan
• Rich in a variety of bioactive compounds like soluble peptides and amino acids • Supports for both plant and soil health
• Similar to soy in terms of nutritional profile • Non-GMO • Environmentally friendly
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It is an ideal solution for any application requiring diverse bioactivity, soluble peptides and a well- balanced amino acid profile. Soil microbes (bacteria and fungi), like Bacillus and Bradyrhizobium, will perform exceptionally well on TUBERMINE®.
PRODUCT RANGE • TUBERMINE® FV: fine particle lower than 50 microns.
• TUBERMINE® GP: standard particle distribution.
0
5
10
15
20
ASP THR SER GLU PRO GLY ALA VAL CYS MET ISO LEU TYR PHE LYS HIS ARG TRY 10Total AA (g) 4.5 4.5 8 4 4 4 5 1.5 2 4.5 8 4.5 5 6 1.5 4 1
Aspartic acid
Threonine Serine
Lysine Histidine Arginine TryptophanProline
Quality information: • Kosher • ISO 9001 • Halal • BSE/TSE • Non-GMO*
Packaging available: • Big bag and 25 kg bag Alternatives to be evaluated upon request.
Manufacturing: • Europe (*) According to EU regulation 1829/2003 - 1830/2003
TUBERMINE®
Protein (Nx6.25) 76% min.
Particle size / Residue on 50 µ 2% max.
Ash 3% approx.*
TUBERMINE®
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DEFINITION Polyols are substances obtained by reducing simple or complex sugars. The majority of these products are derived from starch, vastly contained in cereals like corn or wheat. Thanks to their specific properties, Roquette polyols can be used in various applications such as food, pharmaceuticals, cosmetics, chemicals and the agricultural market. Polyols are described in the literature as agents helping the plant resist abiotic stress (e.g., high osmotic pressure). Moreover, polyols like mannitol and sorbitol perform well during a freeze-drying process as they impact the osmotic pressure of the solution: • Mannitol: freeze-dried powder. • Sorbitol: protein stabilization allowing storage at low and ultra-low temperature.
FUNCTIONALITIES Our polyols, like sorbitol and mannitol, are commonly used for their humectant and biostimulant properties in the plant care industry. As the global leader in polyols, Roquette has a strong expertise and technical skills for producing high- quality products, using time-tested methods that guarantee the reproducibility.
PRODUCT RANGE NEOSORB®
NEOSORB® is obtained by the hydrogenation of D-glucose, which is produced by the hydrolysis of cereal starch. NEOSORB® is a colorless and odorless syrup. It can also be further crystallized through a dehydration step, in order to form a white odorless sorbitol powder.
NEOSORB® is a hexitol, with a chemical structure similar to that of other polyols, such as glycerol, pentaerythritol, trimethylolpropane and glycols. It contains two primary and four secondary alcohol groups, providing unique properties to the molecule.
NEOSORB® is know for its • high water solubility • chemical stability • thermal stability • preservative functionality
This is a non-exhaustive list of our sorbitol range. Please contact our dedicated support team via our website in order to select the grade that will best match your requirements.
OH
OH
OH
GRADES SPECIFICATIONS
NEOSORB® P 20/60 Coarse NEOSORB® P 30/60 Decreasing NEOSORB® P 60 particle size NEOSORB® P 100 T Super fine
GRADES SPECIFICATIONS
Roquette’s primary grades of sorbitol
Liquid sorbitol
Powder sorbitol
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POLYOLS PRODUCT RANGE PEARLITOL®
PEARLITOL® is used as an excipient in numerous commercial formulations and is known for its low hygroscopicity.
Roquette produces mannitol through a catalytic hydrogenation of glucose and mannose solution, obtained from starch. Mannitol is isolated from the concentrated hydrogenation solution thanks to its lower solubility in water compared to sorbitol.
PEARLITOL®, a special grade of mannitol, has been developed by Roquette for specific pharmaceutical applications with high quality constraints.
OH
OH
OH
D-Mannitol
H2
This is a non-exhaustive list of our mannitol range. Please contact our dedicated support team via our website in order to select the grade that will best match your requirements.
MANNITOL 60 MANNITOL 35 MANNITOL 25
Coarse
Decreasing particle size
PEARLITOL® 160 C Coarse PEARLITOL® 110 C Decreasing PEARLITOL® 50 C particle size PEARLITOL® 25 C Super fine
Roquette’s primary grades of mannitol
GRADES SPECIFICATIONS
PEARLITOL® SD range Specific for spray dried PEARLITOL® DC range Specific for direct compression PEARLITOL® PF Pyrogen free
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PRODUCT RANGE Roquette dextrose monohydrate In order to best meet the needs of your application, Roquette offers you a range of dextrose monohydrate products with a variety of particle size distributions.
Roquette anhydrous dextrose The Roquette range includes various grades of anhydrous dextrose which differ mainly in their particle sizes.
PRODUCT INFORMATION
Specifications*:
FUNCTIONALITIES Dextrose is introduced as a nutrient and carrier in a large variety of formulations. It can also be used in plant nutrition solutions and as carbon/energy source for the production of microbial solutions for agriculture applications.
DEFINITION Dextrose is the crystallized form of D-glucose. It is obtained via starch hydrolysis. Dextrose is a white powder available in two crystalline forms as well as in liquid form: • Dextrose monohydrate contains a water molecule and crystallizes in plates. • Anhydrous dextrose does not contain water and forms prism-shaped crystals. • Liquid dextrose contains dextrose at a concentration of 70% dry matter.
100 400 1000 2000 (µm)
DEXTROSE
Liquid Dextrose content 80% to 99%
pH at 50% 5 approx.*
Powder density 62 kg/l approx.*
Ash Low content
Granulometry Available in several forms or granulations to meet process specifications
(*) Indicative values
Polysaccharides
Liquid dextrose 100DE 99 1 70%
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Flowability:
The flowability characteristics of a powder
depend on the shape of crystals and on the size of
the particles. Roquette has developed a range of
dextrose powders with flowability characteristics
meeting our customers’ needs.
CAS Number: • Glucose syrup: 8029-43-4 • Dextrose monohydrate: 14431-43-7 • Dextrose anhydrous: 50-99-7
Quality information: • Halal • Human Nutrition: • Kosher FSSC 22000 • Non-GMO*
Packaging available: • 25 kg • 1000 kg • 2000 lbs • 500 kg • Bulk Alternatives to be evaluated upon request. (*) According to EU regulation 1829/2003 - 1830/2003
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FUNCTIONALITIES Sodium gluconate, gluconic acid and glucono-delta-lactone are used in a variety of plant care applications. Often used as a chelant or a solubilization agent, gluconate products help in nutrient availability and uptake while improving the efficacy of slow-release formulations.
The gluconate family of products are often used as a progressive acidifier and chelating agent for mineral
and metal ions.
DEFINITION Gluconic acid is first obtained through the oxidation of D-glucose via a fermentation process. It is then crystallized into glucono-delta-lactone through a dehydration step. Glucono-delta-lactone is a cyclic ester of gluconic acid.
Roquette, a major player on the global gluconate market, commercializes this product as a highly pure white crystalline powder, offering high-performing packaging that prevents lumping. Technical expertise
is available with numerous active patents in the field.
PRODUCT RANGE
• Sodium gluconate
• Gluconic acid
• Glucono-delta-lactone (GDL)
• pH at 10%: 6.5-7.5
• Reducing sugars: 0.5% max.
• Gluconate content: 99% min.
• Particle size:
• Non-toxic bioproduct • Non-GMO • Stable under alkaline conditions and high temperature
• Strong chelation properties at neutral/alkaline conditions • Stabilizing properties • Increased bioavailability of minerals, metal-ions...
GLUCONATES
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OVERVIEW
To face these challenges, Roquette offers several types of ingredients helping:
• Increase the biodegradability of the solution • Protect the active ingredient • Enhance the dissolution • Control the release of the active • Improve the germination
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• SOLUTAB® A Obtained from wood cellulose.
• SOLUTAB® EDP Obtained from cotton/linter cellulose.
SOLUTAB® is considered as a suitable dissolution aid for manufacturing any class of bioactive compounds.
PRODUCT INFORMATION
Specifications:
SOLUTAB®
FUNCTIONALITIES
SOLUTAB® is widely used in its solid form as an aid in active ingredient dissolution for a variety of applications. It can be applied in direct compression applications, but also in wet and dry granulation.
SOLUTAB® is composed of croscarmellose sodium, an insoluble hydrophilic polymer. The polymer structure facilitates both capillary wicking and swelling to achieve high capacity water absorption, resulting in a radial expansion. This leads to swelling and the rapid breakdown of formulations, with a high efficiency, even when used in low doses.
SOLUTAB® helps the dissolution by preventing a gel formation that would encapsulate the active ingredient.
Croscarmellose Sodium
Nature Ionic Ionic Ionic
pH Neutral/Acidic Neutral/Acidic Neutral/Acidic
A A-IP EDP
Retained on 200 mesh (%) NMT 10 NMT 10 NMT 2
Retained on 325 mesh (%) / / NMT 10
Loss on drying (%) NMT 10 NMT 6 NMT 10
A A-IP EDP
DISINTEGRANTS
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FUNCTIONALITIES MICROCEL™ is a pure, partially depolymerized cellulose and multifunctional excipient. It is used as a diluent, a binder and also as a disintegrant.
FEATURES • Natural origin • Reproducible granulometric distribution
• Inert and chemically stable • Plant-derived
• Enhanced disintegration • Environmentally friendly
DEFINITION MICROCEL™ is a vegetable-derived cellulose with a natural origin and safe for agricultural applications.
It is chemically stable and inert, reducing the risk of reactions with active ingredients used in the farming and plant care industry.
MICROCEL™ can be used to make powder formulations, including tablets, granules and pellets, while demonstrating enhanced disintegration properties and serving as a binder, compression agent, flow aid, or extrusion aid.
PRODUCT RANGE • MICROCEL™: Microcrystalline Cellulose
PRODUCT INFORMATION CAS Number: • 9004-34-6
SMALLER AVERAGE
PARTICLE SIZE
10% - 50%
(™) MICROCEL™ is a registered trademark in Benelux, Brazil, Canada, Chile, France, Germany, Italy, Mexico, the United Kingdom, and the United States of America and is pending in other countries or regions.
DISINTEGRANTS
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• GLYCOLYS® LV, for high-shear granulation addition in intra granular phase.
• GLYCOLYS® Low pH, for acidic compounds.
• GLYCOLYS®
GLYCOLYS®
FUNCTIONALITIES
Reliable super-disintegrant efficiency comes with Roquette’s long-standing experience in the field. GLYCOLYS® is a super-disintegrant derived from reticulated carboxymethylstarch sodium salt.
GLYCOLYS® has been developed and produced exclusively by Roquette for more than 30 years. The experience gained by Roquette with our GLYCOLYS® range of sodium starch glycolates has made the company a supplier of choice when help is needed to develop formulations.
DEFINITION Roquette has developed an optimized production process for ideal disintegration properties:
• To maximize the surface exposed to water potato starch is the preferred raw material for GLYCOLYS®, as its granules are relatively large.
• To avoid viscosity development during the disintegration process, which would delay bioactive compound dissolution, cross-linking is performed on potato starch.
• For a maximum speed of disintegration, the starch ability to swell is significantly increased by rendering it more hydrophilic through a carboxymethylation step.
• For a maximum purity in our GLYCOLYS® products, neutralization and washing is performed.
DISINTEGRANTS
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*IT grades = granulated powder for easier handling dispersion and dissolution.
MAIN GRADES
1 Potato based
9 Potato based
12 17 19 21 29 33 38 39 40 472 Waxy Maize
based
Standard grades
IT grades
5 max.
FUNCTIONALITIES Maltodextrins are frequently introduced as stabilization or delivery agents and as nutritional solutions in the agriculture industry. Our plant-based solutions perform well as additives in the production and formulation of biopesticides, microbial biostimulants and various bioactive ingredients. Our range of maltodextrins enable the encapsulation of various compounds and provide:
• Final product stabilization • Production of live culture solutions • Protectant during freeze-drying • Production of actives • Ambient storage formulation • Encapsulation of microbials
Maltodextrin is widely used for the granulation or encapsulation of a large range of molecules. Thanks to their high solubility, pea maltodextrins are specifically equipped to handle liquid dosage forms or any form requiring complete solubilization.
Our maltodextrins are branded GLUCIDEX® and correspond to specific starch hydrolysis processes.
Grades of GLUCIDEX®, standardized as Dextrose Equivalent (DE), are used to meet the saccharide and oligosaccharide needs for multiple agricultural application and processes.
ENCAPSULATION AND GRANULATION
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GLUCIDEX®
and implementation of advanced purification
techniques (fixed-bed activated carbon, ion
exchange resins, ultrafiltration) has enabled
Roquette to consistently produce high quality
starch hydrolysates.
solution.
Specifications*:
• Maltodextrin >20 DE: 68131-37-3
Typical particle sizes are:
(*) Indicative values
ENCAPSULATION AND GRANULATION
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FUNCTIONALITIES Roquette has developed a wide range of carriers for encapsulation, using a variety of vegetable sources. Our solutions are designed to solubilize a large range of molecules. Encapsulation agents and carriers can be chosen based on a variety of criteria, including oxidation resistance, amylose content, solubility, dispersion, viscosity and impact on glass transition points.
DEFINITION KLEPTOSE® Betacyclodextrin is very stable in alkaline conditions or in the presence of enzymes (amylases). The rigid truncated cone shape of the betacyclodextrin structure limits the interaction between hydrophobic parts of the active compound and the surrounding aqueous environment.
Betacyclodextrin is frequently used for its inclusion and association capabilities, helping with:
• The delivery of hydrophobic ingredients.
• The solubilization of organic compounds.
• The stabilization of volatile compounds.
• The protection of sensitive molecules against oxygen, light or temperature variations, etc.
• The emulsification of lipid-based products.
• The carrier for pesticide/insecticide molecules.
PRODUCT RANGE
at 50°C*
at 80°C*
7585-39-9
C12H70O33
1/35
Hydrophobic cavity
Secondary Hydroxyls
Primary Hydroxyls
ENCAPSULATION AND GRANULATION
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Our team offers:
• Seed coating formulation, including the delivery of active ingredients or microbials
• Formulation and screening capabilities
• A vast portfolio of products and technical solutions for new product development and formulation stabilization
• Equipment for coating, encrusting and pelleting, including › rotary coaters, fluidized bed dryers › measurement of moisture content, flow, dusting, mass… › performance testing (germination rate…)
• A highly skilled internal support network for pharmaceutical compound delivery and biologics formulation
• A starch application team (binders, carriers, excipients…) for industrial uses such as paper or specialty chemical among others
• A valuable external network of partners including contract laboratories for assistance in formulation performance testing and technical support with customer studies
• Fully equipped fermentation laboratories to evaluate growth and development of beneficial microbes used in plant care solutions If you have a need for seed coating, please consider partnering with Roquette CTS by contacting us via our website.
COLLABORATION AND INNOVATION
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Microbial solutions are a growing field within the agricultural market.
Roquette supports the production and application of microbials with a full range of plant-derived products, including carbohydrates, processing aids, nitrogen sources and growth promotors.
Please see our Fermentation brochure or visit our website for more information.
FERMENTATION
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www.roquette.com
Request a sample
® Registered trademark(s) of Roquette Freres, Blanver Farmoquimica Ltda.or Itacel Farmoquimica Ltda. Registrations vary depending on local regulations. The information contained in this document is to the best of our knowledge true and accurate but all instructions, recommendations or suggestions are made without any guarantee. Since the conditions of use are beyond our
control, we disclaim any liability for loss and/or damage suffered from use of these data or suggestions. Furthermore, no liability is accepted if use of any product in accordance with these data or suggestions infringes any patent. No part of this document may be reproduced by any process without our prior written permission.
For questions about a product’s compliance with additional countries’ standards not listed above, please contact your local Roquette representative.
IN_PLANT-CARE-SOLUTIONS-Br-04.2e.02/2020
CONTACT US
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