polymer products for personal care - derypol · polymer products for personal care ... use advanced...

Polymer products for personal care

derypol

“We make polymers, we care for the environment“

"We make polymers, we care for the environment" "We make polymers" means that derypol works to detect the market needs and to investigate and develop products. Our concern for the environment has become our main objective. For this reason, we only use processes and products that respect the environment. Our range of products for water treatment is the result of our commitment to innovate and to use advanced technologies for the development of specialized and progressive products. All our products are the fruit of extensive investigation and are made in accordance with the most demanding criteria and quality.

derypol

OPM504

OPM544

DER K228PF

DER K327PF

DER BCA42PF

DER K2PF

DER K6

DER K39PF

HIMOSAP GAS100

HYGEL CL1700

HYGEL LE766

HYGEL LE585

HYGEL LE305

HYGEL E375C

HYfix CX414

Contents Index

22-23 Styling Agent HYfix Series

12-21 Rheology Modifiers Himosap & HYgel Series

4-5 Opacifiers OPM Series

6-11 Conditioners DER Series

HYGEL E100FD

DER K11PF

Opacifiers OPM Series

4

The objective of an opacifier is to improve the appearance of the product, even if colouring compounds are used in its formulation.

Our OPM series guarantees a good opacifying capacity and good stability in a wide range of products formulations; however it is mandatory to check this compatibility at laboratory scale prior to progressing to industrial scale. Derypol has an equipped laboratory and expert staff for this testing in order to check formulation stabilities. These are the conditions to which the opacified formulations are submitted:

To get the most effective blend of the opacifier we recommend a previous dilution of the OPM product with water in a proportion of 1:5 or 1:10, and to dilute with between 10% and 20% in an intermediary phase of the addition of the products. The recommended doses are usually within the range of 0.2 – 1% depending on each particular case. Our OPM series are used in a wide range of products in cosmetics and detergency as Sunlight protection products, bath gels, hand soaps, face cleaning creams, shampoos, hair treatment creams and others.

OPM 504 & OPM 544

Properties

Applications

Estability

+ 0.5% OPM 544

Stability Test Control:

4 weeks of stove 45 ºC.

Centrifugation (special cases).

derypolOpacifiers OPM Series

5

OPM 504 OPM 544

Appearance White milky White milky

Solids 40% 40%

pH 2,1 – 3,5 2. – 3.5

Viscosity <100 cps < 100 cps

Density 1.10 gr/cc aprox 1.10 gr/cc aprox

Surfactants Anionic

Nonylphenol free Anionic

Nonylphenol free

Particle Size 150 - 350 nm 150 - 350 nm

INCI Styrene / Acrylates copolymer

Specifications

Conditioners DER Series

6

Compatible with most components of cosmetic formulations, as well as with most cationic, no ionic, anionic and amphoteric surfactants. Transparent and colourless cosmetic products.

Substantively properties to skin and hair.

The new DER K228PF does not contain parabens. The preservative used as an alternative is sodium benzoate.

Compatible with most components of cosmetic formulations, as well as with most cationic, no ionic, anionic and amphoteric surfactants.

Substantively properties to skin and hair (PQ22 is mainly used in hair care formulations due to its high cationicity).

Both products are parabens free. The preservative used as an alternative is sodium benzoate.

DER K228PF & DER K327PF

Applications

In Skin Care products: - Imparts a smooth, velvety feel and reduces tightness after drying skin. - Improves foam for liquid cleansing and liquid soaps. - Provides an excellent moisturization.

In Hair Care products: - Provides a luster and a soft silky feel. Reduce static and flyaway. Increase Shine, softness and body.

- Excellent lubricity and sang-free wet compatibility. - Imparts excellent dry compatibility when the hair is dried. Improve wet and dry combability. - Helps hold curl without flaking.

Properties

DER BCA42PF

Properties

Applications

In Skin Care products: - Imparts a smooth, velvety feel and reduces tightness after drying skin. - Improves foam for liquid cleansing and liquid soaps. - Provides an excellent moisturization.

In Hair Care products: - Provides a luster and a soft silky feel. - Excellent lubricity and sang-free wet compatibility. - Imparts excellent dry compatibility when the hair is dried. - Helps hold curl without flaking.

INCI: POLYQUATERNIUM 7



7

Compatible with most components of cosmetic formulations, as well as with most cationic, no ionic, anionic and amphoteric surfactants. Transparent and colourless cosmetic products.

Substantively properties to skin and hair.

The new DER K228PF does not contain parabens. The preservative used as an alternative is sodium benzoate.

Compatible with most components of cosmetic formulations, as well as with most cationic, no ionic, anionic and amphoteric surfactants.

Substantively properties to skin and hair (PQ22 is mainly used in hair care formulations due to its high cationicity).

Both products are parabens free. The preservative used as an alternative is sodium benzoate.

100% cationic. High substantive power. Full compatibility with non-ionic and amphoteric ingredients. It imparts a smooth and velvety touch on the skin contributing greatly to maintain a maximum degree of hydration. Easy to dosage due to its solubility in water. DER K6 is a very high molecular weigh polymer.

Easy incorporation in formulations due to complete water solubility.

Compatible with a wide range of surfactants, including anionic and amphoteric ones.

Compatibility with ethanol for hair formulations (musses and sprays).

Acts as an antistatic agent, film former and hair fixative.

DER K2PF & DER K6

Properties

Applications

In Skin Care products: - Provides a luster and a soft silky feel. - Give to the skin a soft, velvety and non greasy after feel. - Improves the spreadability and the application of the final product.

In Hair Care products:

- Conditioning shampoos, blow-dry lotions, leave on or rinse off conditioners, hair relaxer creams. - Provides a luster and a soft silky feel. - Reduce Static and flyaway effect. - Increase Shine, softness and body. - Improving wet and dry combability. - Improves the spread ability and the application of the final product. - Strong conditioning effect, both products are mainly used in Afro-American products, damaged hair products and tightly curly hair.

DER K11PF

Properties Applications

Conditioner for styling gels. Hair Care; It can be formulated into styling mousses,

lotions and gels, conditioners, transparent shampoos and treatment products.

Improve wet and dry combability. Increase Shine, soft-ness and body.

Good curl retention. Form a non-tacky and continuous film. Suitable for Skin care products; liquid soaps, shower

gels, body lotions and shaving products.




8

Amphoteric terpolymer suited for liquid cleansing products. Compatible with anionic and amphoteric surfactants. For hair care products, it provides really good dry and wet combing properties. Preserved with Sodium Benzoate as an alternative to parabens.

Properties

DER K39PF

Applications

In Hair care products: - Excellent lubricity and slip, excellent wet combability without too much build-up. - Provides sheen to dry hair. - Excellent dry combability. - Superior conditioning properties for products with extreme pH ranges.

In Skin care products: - Contributes lubricity, which makes their application easier. - Reduces tightness of drying skin, and provides a smooth feel. - Excellent moisturization - Helps to reduce irritation resulting from liquid cleansers. - Liquid cleansers obtain a richer, thicker foam with better stability.



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pH Viscosity Solids Components INCI

DER K228PF 3 - 4.5 7.500 - 15.000 8 - 10% AAM

DADMAC Polyquaternium - 7

DER K327PF 6 - 7.5 7.500 - 15.000 17 - 20%

DER BCA42PF 4 - 5.5 3.000 - 6.000 39 - 43% AAC


DER K2PF 5 - 7 5.000 - 12.000 40%


DER K6 4 - 7 4.000 - 12.000 19 - 21%

DER K11PF 3 - 5 10.000 - 60.000 19 - 22% DMAEMA Polyquaternium - 11

DER K39PF 3.3 - 4.5 1000 - 6000 9 - 11% AAC AAM


Specifications

DADMAC: Diallyldimethylammonium Chloride AAC: Acrylic Acid AAM: Acrylamide

10

Himosap Series (Exclusive Derypol´s Technology)

Are well known polymers but in aqueous presentation form. Water dispersion polymers are not known in the cosmetic market thereby Himosap are special products and they work in a different way than others solids, emulsions or latex products. Advantages of Himosap products: Aqueous dispersion free of oils, solvents and surfactants. Water based polymers that permits a very easy preparation. Immediately dissolutions. Excellent salt tolerant, even better than other products in the market. Provides aqueous transparent solutions. Viscosity recovered after boiling it. Stable with polar solvents (glycolic acid, sorbitol, glycerine, propylenglicol…). pH independent.

Water based Himosap GAS100

Aqueous emulsion HYgel CL1700

Emulsion

HYgel LE585

HYgel LE766

HYgel LE305

HYgel LE375C

Powder HYgelE100FD

Rheology Modifiers Himosap Series (Exclusive Deryol´s Technology)

Classification

HIMOSAP GAS 100

INCI: Acrylamide / Sodium acryloyldimethyltaurate / Acrylic acid copolymer in aqueous dispersion with ammonium and sodium sulphate

11

100

1000

10000

100000

1000000

0 2 4 6 8 10

pH

Vis

co

sid

ad

(c

ps

), 4

@0

.6 r

pm

Cross-linked copolymer with anionic content at 20% of actives. pH independent. Doesn’t need neutralization before using it. High molecular weight. The polymer thickens in all the pH range, even acid pH. Compatible with non-ionic surfactants.

Rheology Modifiers Himosap Series (Exclusive Deryol´s Technology)

HIMOSAP GAS 100

Properties

Applications

GAS100 is recommended for transparent gel formulations as: Aloe Vera, anti-cellulite gels, hot and cold effect gels, depilatories, peelings, water hairstyle, etc…

Thickening ability at different pH

1

10

100

1000

10000

100000

1000000

0 0,2 0,4 0,6 0,8 1 1,2

Viscosity (cps) Brookfield LVT

spindle [email protected] rpm

% NaCl

Emulsion product, 4,4%

commercial product

HIMOSAP GAS 100, 10%

commercial product

Thickening ability at different concentrations of NaCl

12

Water

Sorbitol 50% : Water 50%

Glycerine 50% : Water 50%

Propylene glycol 50% : Water 50%

Ethanol 10% : Water 90%

Sodium Chloride

Compatibilities

Cationic Surfactant

Hydrogen peroxide

Incompatibilities

Specifications

GAS 100

Appearance White milky Liquid

Actives 20%

Density 1.2

Product Viscosity < 3.000 cps

Ionic character Anionic

INCI

Acrylamide/sodium acryloyl-dimethyltaurate/acrylic acid copolymer

Compatibilities and Incompatibilities

Rheology Modifiers HYgel Series

Non-ionic surfactants

Glicolic acid

13


Hygel Series

HYgel CL1700

Polymer of acrylic monomers in aqueous emulsion with a high suspending ability. Anionic rheology modifier which provides clear formulations which contains high level of surfactants Compatible with electrolytes and surfactants (non-ionic, anionic and amphoteric surfactants). Solutions are pseudoplastic and non thixotropic. Neutralization at pH7. Wide pH range, pH can be reduced with Citric Acid. It is compatible with most of the more common surfactants used in personal care:

- Sodium Lauryl Sulfate - Sodium Laureth Sulfate - Cocamidopropyl Betaine - Sodium lauroyl sarcosinate - Disodium Laureth Sulfosuccinate

Properties

Aqueous Emulsion

Applications

It is usually used on clear shampoos, bath gels and 2 in 1 conditioning shampoos. Antidandruff shampoos. Baby shampoos. Facial Cleanesers. Conditioning body washes. Sanitizing gels. Low pH formulations. Pearlized Cleanising Products.

INCI: ACRYLATES COPOLYMER

14

HYgel CL 1700

Nature White milky Liquid

Viscosity (in solution) 1%: 4000-7000

Viscosity (commercial product)

< 100 cps

Acitve Content 30%

Shelf Life 6 months

pH 2.1 – 4* (Solution 1%)

INCI Acrylates Copolymer

Specifications


Factor When factor is… Suspending and viscosity

properties…

Polymer concentration Added/Increased Increase

Surfactant concentration: Sodium Lauryl Sulfate

Sodium Laureth Sulfate Cocamidopropyl Betaine

Sodium lauroyl sarcosinate Disodium Laureth Sulfosuccinate

Increased Increase

Salt Added / Increased Increase

15


Anionic acrylic copolymer dispersed in medicinal grade white oil. Those polymers are tipically used to thicken aqueous solutions and to formulate stable O/W emulsions. The polymers swell immediately in water without any neutralisation, and at room temperature. Solutions are pseudoplastic and non thixotropic. Suspension of solid particles (only the LE585) Compatible with surfactants.

Properties

HYgel LE585

Make up and sun screen formulations with a non greasy and non sticky after feel. Rub-in and spreadability of highly thick and compact creams are easier and more uniform. Cream-like gels (light textures white glossy products) Serums. Sensitive creams and baby care. Cleansing lotions and creams (compatibility with surfactants) Nail varnish remover. High pH formulations: depilatory creams, perm lotions… Hydroalcoholic gels.

Applications

INCI LE755: Sodium Polyacrylate Mineral Oil, Trideceth - 6

INCI LE585: Acrylamide/Sodium Acrylate Copolymer Mineral Oil, Trideceth - 6

It is an anionic acrylic copolymer dispersed in Hidrogenated Polydecene as an alternative to mineral oil, and does not contain acrylamide.

It is normally used to thicken aqueous solutions and to stabilize O/W emulsions. It is pseudoplastic and non thixotropic. Its solutions do not show significant changes in viscosity and stability at high temperature. LE766 helps to stabilise suspensions. It is supplied in ready to use form, so it is no necessary neutralization. The addition can be made at any stage of

the manufacturing process (at room temperature). Compatible with surfactants.

Emulsion

HYgel LE766

Properties

INCI: Sodium Polyacrylate, Hydrogenate Polydecene, Trideceth - 6


16

Properties

It is a cationic acrylic copolymer dispersed in medicinal grade white oil. Normally used to thicken cationic aqueous solutions and to stabilize O/W emulsions. It is supplied in ready to use form, so neutralization is no necessary. It swells immediately in water at

room temperature. Solutions are pseudoplastic and non thixotropic. LE375C helps to stabilise suspensions.

Applications

Formulations that contain cationic ingredients. Make up and sun screen formulations with a non greasy and non sticky after feel. Self-tanning emulsions. Sunscreen. Skin care with AHA, acid fruits, DHA… Hair care: after-shampoos (conditioning effect)

INCI: Polyquaternium 37 Mineral Oil, Trideceth - 6

HYgel LE375C

Properties

LE305 is An anionic thickening and stabilizing agent ready to use as a fluid inverse emulsion. It has emulsifying properties with oil phases, providing gel-cream texture. HYGEL LE305 thickens extreme media (highly acidic, highly alkaline or oxidizing) and stabilizes mineral addi-

tives. This is a ready to use polymer which swells immediately in water at room temperature and without any

neutralization. LE305 allows allows the formulation of highly stable suspensions under a wide range of pH (from 2 to 11).

Applications

In Hair care products: - Creams, lotions, - Sun Care (sunscreens, self-tanning creams, …) - Hair Care - Make up

INCI: Polyacrilamide & C13-14 Isoparaffin & Laureth-7

HYgel LE305


17

HYgel LE 766 HYgel LE305 HYgel LE 585 HYgel LE 375C

Character Anionic Anionic Anionic Cationic

Nature White milky Translucent Emulsion White milky White milky

Odor Slightly acetic Slyghtly acrylic Slightly acetic Slightly acetic

Viscosity (in solution)

1%: 15000- 25000 cps

2%: 18000—32000 cps

1%: 20000-32000 cps

2%: 25000-45000 cps

Viscosity (prod. Cial.)

400 – 2000 cps 1500—5500 cps <1500 cps 200-3000 cps

Acitve Con-tent

55 - 58 %* 45 –55 % 57.5%* 53 %*

Shelf Life 12 months 12 months 12 months 12 months

pH 5 -7

(Solution 1%) 5-7

(Solution 1%) 5 – 7

(Solution 1%) 3.5 – 5

(Solution 2%)

INCI

Sodium Polyacrylate, Hydrogenate Polyde-

cene, Trideceth - 6

Polyacrilamide & C13-14 Isoparaffin &

Laureth-7

Acrylamide/Sodium Acry-late Copolymer

Polyquaternium 37

Mineral Oil (Paraffinum Liquidum), Trideceth - 6

Specifications

18


Powder

Applications

Acrylic-based polymer in powder form, typically used to formulate transparent gels. HYgel E100FD is an optimized grade of Carbomer with better clarity, handling and less foam. Thickening agent for aqueous solutions. Solutions are pseudoplastic and non thixotropic. It has a high yield value. So it is an effective agent for emulsion stabilization and stable suspen-

sion of solid particles.

HYgel E100FD (Fast Dispersion Version)

Properties

Has a very high yield value, so it is an effective agent for emulsion stabilization and stable. It used in hair care and skin care products, for gel, lotion and cream formulation. Hidro-alcoholic gels.

INCI: Carbomer

19

Hygel E100 FD

Nature

White granulated powder

Odor Slightly acetic

Water content 5 % max

Viscosity (in solution) 0.2%: 20000-30000 cps 0.5%: 45000-65000 cps

Solvent residual 1000 ppm max

Shelf Life 24 months

pH 2,7 – 3,5

(0,5% solution)

INCI Carbomer


Specifications

20

Styling Agents HYfix Series

HYfix CX414

Anionic copolymers in aqueous solution for applications in hair and skin products. Easy incorporation into formulations without heating and without neutralization. Is recommended a previous dilution to obtain better results. It provides transparent forumlations.

Properties

In Hair Care Products: - Adapted for styling gels, waxes, Creams,.. - Helps to provide high curl retention in a high humidity environment. - Contributes to a silky, dry hair feel. - Washes out easily. - Curl retantion. - It does not leave White particles once dryed - Suggested strarting concentration in Styling: 5% as supplied. - Suggested strarting concentration in Shampoos: 1.5% as supplied. In skin Care Products: - Lotions, Liquid cleanising Products, Shaving, moisturing creams. - Enhances skin smoothness. - Improve spreadibility of lotions and creams. - Suggested strarting concentration in Skin Care: 1.5% as supplied.

Applications

INCI: Methacrylic Acid/Sodium Acrylamidomethyl Propane Sulfonate Copolymer

21

Styling Agents HYfix Series

Specifications

HYfix CX414

Appearance Liquid, viscous, colorless, hazy

Odor Without scent

Colour, APHA ≤ 50

Ionic character Anionic

Solids % 10.5 – 13.1

pH 5 - 7

Viscosity 7.500 – 25.000 cps

Intrinsec Viscosity 3,5 – 4,5

INCI Methacrylic Acid/Sodium Acrylamidomethyl Propane Sulfonate

Copolymer

Product Type

Product Name

INCI

Opacifier OPM504

Styrene / acrylates copolymer

Opacifier OPM544

Conditioner DER K228PF

Polyquaternium - 7


Conditioner DER BCA42PF Polyquaternium - 22


Polyquaternium - 6

Conditioner DER K6

Conditioner DER K11PF Polyquaternium - 11

Conditioner DER K39PF Polyquaternium - 39

Rheology modifier GAS100 Copolymer of acrylic acid, 2-propenamide and sodi-um acryloyldimethyltaurate in aqueous dispersion

with ammonium and sodium sulfate.

Rheology modifier HYgel CL1700 Acrylates Copolymer

Rheology modifier HYgel LE766 Sodium Polyacrylate / Hydrogenate Polydecene / Tri-

deceth-6

Rheology modifier HYgel LE585 Acrylamide / Sodium Acrylate Copolymer / Mineral

Oil (Paraffinum Liquidum), Trideceth - 6

Rheology modifier HYgel LE305 Polyacrylamide &

C13-14 Isoparaffin & Laureth-7

Rheology modifier HYgel LE375 C Polyquaternium 37/ Mineral Oil (Paraffinum

Liquidum), Trideceth - 6

Rheology modifier HYgel E100FD Carbomer

Styling Agent HYfix CX414 Methacrylic Acid/Sodium Acrylamidomethyl Propane

Sulfonate Copolymer.

PRODUCT APPLICATIONS / INCI NAME

PRODUCT APPLICATIONS / INCI NAME

We are working hard everyday to be able to offer new discoveries so that may:

- Improve our customers’ water quality. - Reach more profitable and sustainable treatments. - Adapt ourselves to the new government demands. - Contribute to the effort of keeping our planet blue.

Our range of products, reflective of our beliefs, is continuously evolving, because we focus our efforts specially on finding new chemicals. Our success is due to our partners, colleagues and customers, and to their spirit of innovation. We understand that our strength is in our research and development of practical application, as well as our focus on meeting the needs of our clients. To discover means that we have a great ability to adapt to the needs of the market and customers, thanks to an organization that works with dynamism, creativity, effort, and overall with illusion.

We make polymers, we care for the environment.

derypol

derypol

Derypol, S.A.

Offices: C/ Plató, Nº 6 Entlo. 5º Tel. +34 93 238 90 90, Fax +34 93238 90 91 08021 Barcelona (Spain) mail: [email protected] Factory and Laboratories: C/de Cal Gabatx, s/n. Tel. +34 93 849 61 88 – Fax +34 93 846 41 93 08520 Les Franqueses del Vallès Barcelona - Spain

www.derypol.com

polymer products for personal care - derypol · polymer products for personal care ... use advanced...

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