power and co emissions to methanol carbon recycling...
TRANSCRIPT
CarbonRecyclingInternational
PowerandCO2emissionstomethanol
BenediktStefanssonDirectorofBusinessDevelopment2015EuropeanMethanolPolicyForumBrusselsOctober132015
2007 2008 2009 2010 2011 2012 2013 2014 2015
Company launched in Reykjavik
Technologydevelopment
Pilot plantproduction
Plantengineering
Plant construction
Plantopening with1,300t/yrcapacity
Firstsales(exportsanddomestic)Methanexinvests
Plantexpanded to4,000t/yrcapacity
Marketing oftechnology&partnerships
Geely(ownerofVolvoCars)invests
BriefhistoryofCRI
3
Methanol(orderivatives)
CO2
Lowcarbonintensitymethanol:energycarrier
Transportandindustry
Renewablepowerorbyproducthydrogen
CRIPower-to-Liquidstechnology
Fluegasemissions
CO2
CRI’s Power-to-Liquidsplatform
CleanConversion
Lowcarbon-intensity
methanolCH3OH
CO2 Capture
HydrogenGeneration
Industrypartners CRIintegratedCCUandPtLsolutionIndustryemissions
Electricity
IndustryH2 byproduct
Offtake
ETLmassenergybalanceandefficiency:electrolysis
CarbonCapture
Electrolysis
Compression Reaction Distillation 1tMeOH
0.193tH2;6.45MWhLHV
1.4tCO2
!=99%
0.59tH2O
Fluegas
9
Electricity 5.58MWhLHV
O2
Totalelectricalenergy9.5MWh/tmethanolwithoverallefficiencyof60%
Water
0.8MWhLHV thermal 0.45MWhLHV electric
CarbonRecyclingInternational- Confidential
CRIfirstofitskindPower-to-LiquidsfacilityinIceland
GeorgeOlahCO2 tomethanolplant,Orkubraut2,Grindavik, IcelandFirstcommissioning:2012Capacityexpansion:2015CCUthroughput:5,600t/yrCO2Electrolyzercapacity:800t/yrH2 (1200Nm3/hr)Productioncapacity:4,000t/yrmethanol
ReykjavikGOPlantCleanConversion
CO2 Capture
HydrogenGenerationFlueGasSource
Product
CO2 CO2
CO2 CO2 CO2
FrameworktocompareCO2 lifecycleemissionsoffuelsGasoline&diesel
=84gCO2/MJ
1-8gCO2/MJ
=33-54gCO2/MJ
Biofuels
7
CO2
CO2CO2
FirstPtL plantwithISCC+certificationofsustainability
10/11/15 8
kgCO2e/tRM gCO2e/MJRMLHVEmissions relatedtoraw-material: 0 0Emissions ofelectricityproduction (grid) 134 6.71Emissions ofsteamproduction 4 0.22Emissions ofprocessspecific inputs: 4 0.21Emissions ofwastewatertreatment: 1 0.06Totalprocess-specificemissions: 143 7.2Plant-to-port(50kmbyroad) 7 0.34Port-to-port(2000kmcontainer ship) 20 1.00Totaltransport-specificemissions 27 1.3TotalemissionsCIFRotterdam 170 8.5Comparedtoreferencevalueof83.8gCO2e/MJfossil >90%reduction
ActualGHGemissionvaluesusingISCCEUGHGmodule*
*BasedonEUdirective2009/30/EC(FQD)
StreamsofinnovationCRIfirsts AchievementUsedCO2 capturefromindustrialsourcestomaketransport fuel
� Processes15mt CO2 /dayintotransportfuel
Implementedlarge-scale electrolysisforpower-to-liquidsapplications
� Installedcapacity ofmulti-MWalkalineelectrolyzersforhydrogen production
Deliveredrenewablefuelofnon-biologicalorigintoEUmarket
� Gasolineblending andinbiodiesel inNetherlands,SwedenandIceland
Receivedcertificationfor renewablefuelofnon-biologicalorigin
� Certificationof90%reductionofCO2accordingtoEURenewableEnergyDirective
9
The MHPSECRIPartnership
10/11/1510
Mitsubishi-HitachiPowerSystemsEurope(MHPSE)andCRIhavecombinedtheirresourcestoofferintegratedindustrialsolutionsforcarboncaptureandpower-to-methanolproduction.Byjoiningforces,thetwocompaniescanofferclientsacompletesuiteofservicesfrom:§ Feasibilitystudies;§ Turn-keycontracts,includingdesign,constructionofmodularizedsystems§ Pre-commissioning,erection,on-sitecommissioning,operatortraining;§ Post-purchaseservicesandoff-takecontracts
CarbonRecyclingInternational– Proprietary– Donotquote
Duisburg Reykjavik
ThreeapplicationsofCRIPtL platformRenewableFuelEnergyUpgrade CapacityUtilization
Recoverhydrogenreleasedbychemicalandsteelplants
Useexcessthermalcapacitytomakehydrogen
Userenewableenergytomakehydrogen
12
Project at Steag Lünen coal-power plant, Germany
Input: 1MWelectric+500t/yrCO2Output: 400t/yrmethanolCapacity:1t/day
CO2capture
HydrogenproductionCleanconversion
MethCO2 Horizon2020(€8.6/m)CollaborationwithSTEAG,MHPSE,Hydrogenics andEUuniversities
SourcesofCarbonDioxide
13CarbonRecyclingInternational– Proprietary– Donotquote
ConcentratedCO2 inEU:>1.3billiontons
CO2Mt/year
Numberofsources
CO2 percent influe-gas
Powerplants 1033 795 15%
Steel 153 62 15-30%
Cement 125 215 15-30%
Ammonia 17 42 100%
1328 1114
LocationsofconcentratedCO2
Capturingcarbondioxidefromfluegaswithconcentration>15%
Equivalentto>27000siteswith100t/daycapacity
Sourcesofhydrogen
14CarbonRecyclingInternational– Proprietary– Donotquote
Chemicalproduction siteswithH2 asaby-productandconcentratedCO2
Equivalentto>100siteswith100t/daycapacity
Longtermtotalproduction ofmethanol6million tonsperyear
FocusingonlocationswithconcentratedsourcesofH2 inEurope
ETLmassenergybalanceandefficiency:capturedH2
CarbonCapture
PSA
Compression Reaction Distillation 1tMeOH
0.193tH2;6.45MWhLHV
1.4tCO2
!=99%
0.59tH2O
Fluegas
9
COG 5.58MWhLHV
Offgas
Totalenergy input:7.7MWh/tmethanolwithoverallefficiency>70%
*Notincluding PSA
0.8MWhLHV thermal 0.45MWhLHV electric
Ironandsteelwastegasorbyproduct gas
Sodiumchlorideelectrolysis
Waterelectrolysis
Hydrocarbonarcfurnace
Electricity
Hydrogenseparationprocess
H2
Petrochemicalwasteandbyproductgas
Wasteorresidues
GasificationMSW
Syngas
CO2
Lowcarbonintensitymethanol
LowCarbonIntensityMethanolproductionprocesses
2015CarbonRecyclingInternational– Allrightsreserved
Energysource Upstreamtechnology LCIMfeedstocks LCIMoutput
Opportunitiesforpower-to-methanolinEU-28
Diesel2970TWh/a
Gasoline970TWh
Gas210TWh
RES660TWh
Electricitydemand2140TWh
Unusedcapacitynuclearandthermal2330TWh
Electricitymarket5120TWh* Roadfuelmarket4157TWh*
Energyrecovery
Hydrogen fromcoke-ovengas37TWhHydrogen fromchlor-alkaliprocess9TWh
20%
20%
640TWh
SupplyofPtLmethanolPower-to-liquids
390TWh**
**33millionmetrictonsofoilequivalentCurrentgasolinecons.
Source:Eurostat2012, Eurochlor 2013,Eurocoal 2011
LowCO2 methanol310TWh
“Green”methanol80TWh
*Totalgeneratingcapacity
*Totalconsumption
MethanolfromCO2andelectricityfortransitiontorenewablepowerandcleanfuel
18
Intermittentenergysources Load-balancingpowergeneration
LowCO2 liquid fuel
CO2
1 2
4
6 Balancedgridsupply
Load-balancingPtL production3
M15-M100Fuel blend
5
Power
Distribution
Consumers
