present position. education awards and visiting …. khan, "anionic polymerization of 2-vinyl...

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THIEO E HOGEN-ESCH Curriculum Vitae Present Position. Professor of Chemistry, Loker Hydrocarbon Institute and Department of Chemistry, LHI 123, University of Southern California, University Park, Los Angeles, CA 90089-1661. Phone (213) 740-5980. Fax (213) 740-6679. E-mail: [email protected]. Education. University of Leiden, Netherlands, B.Sc. 1958; M.Sc., Physical Polymer Chemistry, 1961 State University of New York (Syracuse), Polymer Chemistry, Physical Organic Chemistry, 1963-66. University of Leiden, Netherlands, Ph.D. (Cum Laude), 1967, Physical Organic Chemistry. Awards and Visiting Professorships. . Visiting Professor Zhejiang University, P.R. China , October 2013. Visiting Professor Zhejiang University, P.R. China , May 2010. Visiting Professor University of Toulon, France Sept/Oct 2003. Visiting Professor University of Toulon France, May/June 2002 Visiting Professor, University of Bordeaux, May-June 1991 Fellow Japanese Society for the Promotion of Science, May 1987 University of Florida, Sigma Xhi Award, 1983-84 Who's Who in Science and Technology Visiting Professor, Johannes Gutenberg University, Mainz, West Germany, May-June, 1982 Visiting Professor, Laboratorium Voor Macromoleculaire en Organische Scheikunde, University of Leuven, Belgium, May-June 1977 Visiting Scientist, Centre des Recherches sur les Macromolecules, Strasbourg, France, Sept.-Oct. 1977 Visiting Professor, Universite Pierre et Marie Curie, Paris VI and Universite Paris-Nord, Nov.-Dec. 1977 Visiting Professor, University of Leiden, Netherlands, April-Sept. 1975 Professional Activities Executive Editorial Board, Polymer International 1998-2006. Editorial Board, Journal of Polymer Science, 1985-1989. Editorial Board, Receuil Des Traveaux Chimiques des Pay Bas, 1994-1997 Editorial Board “Designed Monomers and Polymers”1997- present USC Patent Committee Chair 2001/2002 ACS Polymer Division, Member Program Committee, 1981-1988; Organizer (with Prof. J. Smid) of International Symposium on "Advances in Anionic Polymerization", New York, NY, April 13-18, '86. Associate Director, Center for Macromolecular Science, University of Florida, 1971-1987. Director 1987-1988. University of Florida Patent Committee: Physical Sciences Review Committee, 1982. Utrecht-Florida University Exchange Committee, 1981-1983. University of Florida, Department of Chemistry Committees: Graduate Advisory and Curriculum Committee, Space Committee, Industrial and Alumni Relations Committee, Language Committee. Consulting: SCM Corporation, 1976-1977; Millchem, Inc., 1979-1980; Cooper Distributors, 1979-1980; Frontier Contact Lenses, Inc. 1980-1981; DuPont, 1982-1983; Dow Chemical, 1984-Present; W. R. Grace and Company, 1989-Present; American Cyanamid, 1993-1994; Reilly Industries, 1993, California Gas Co 1995. Chairman, Gainesville ACS Section, 1976. Recent USC Service Activities: Member Dornsife Faculty Council August 2013-2015 (two years)

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Ming Hsieh Institute for Cancer Research. (2010-2011)Served on a committee appointed by Vice President of Research Randolph Hall that was charged with the initial selection of research proposals to be funded by the recently established Ming Hsieh Institute for Cancer Research. This assignment involved a series of meetings during January-August 2011 aimed at organizing the approach for the funding of several seed proposals from USC academic community. This also involved making recommendations on six proposals from a larger number of proposal submitted by the USC Cancer Research Community. Current PhD committees: Lena Hoober, Kyu Min Kim, Dean Glass, Derek Moy, Anton Shikmin (geology)Phong Trinh, Ming Li, Janet Olsen, Sergei Mukhin, Merve Yurdakan, Xiaojie Yan. Lee McAuliffe, Marc Iuliucci, Byungsoo Kim. (Dparment of Mat. Science and Engneering)_ Current Research Interests:

Polymer Membranes with Applications in Fuel Cells and Reverse Osmosis. We have shown that the indirect synthesis of blends of polyvinylidenefluoride (PVDF) and polystyrenesulfonic acid (PSSA) leads to self-assembly giving tough and transparent polymer composite membranes with superior properties in direct methanol oxidation fuel cells (DMFC's). Applications in reverse osmosis membranes through incorporation of nano objects in membranes synthesized through interfacial polymerization are being explored im collaboration with the group of Professor Pirbazari of the Department of Environmental Engineering, College of Engineering.

Self-Assembly of Polymer Systems through Fluorophilic Association. Self-assembling Fluorocarbon (RF) end-functionalized polymers that associate in the solid state through the formation of perfluorocarbon nano-clusters. The polymers are shown to self assemble to give large sized clusters exceeding 100,000 nm. When sheared, these clusters fall apart but reassemble providing new materials with unprecedented strengths. These systems have potential applications in the formation of otherwise immiscible blends.

Synthesis of Helical Polymers for Non Linear Optical Properties. We have explored the synthesis of [5]helicenes conjugated through triple bond to aromatic rings the polarity of which is variable through substitution reactions. As these chiral polymers slowly lose optical rotations, current plans involve modifications to produce polymers with persistent optical rotations for non linear optical properties.

Teaching Physical Chemistry of Polymers Laboratory, Univ. of Leiden, Netherlands 1960, Undergraduate Organic Chemistry, Univ. of Florida, 1971-88, Undergraduate Quantum Applications to Organic Chemistry, Univ. of Florida, 1972-73, Graduate Polymer Chemistry, Univ. of Florida, 1980-1988. Graduate Physical Chemistry of Polymers, Univ. of Florida, 1974-85, Advanced Undergrad/Graduate Organic Chemistry of Polymers, Univ. of Florida, 1985-88. Polymer Synthesis, Chem. 561, Univ. of Southern Calofornia. 1990-present Univ. of Southern Cal. Undergraduate Organic Chem.322a and 322b, 1989-present. Ph.D. Dissertations 1. M. J. Plodinec, "Ion Pairing and Hydrogen Bonding in the Excited State of Alkali Carbanion Salts", Ph.D., University of Florida, December 1974. 2. R. E. Cambron,"Alkali Cation Binding to Nonionic Polymers", Ph.D., University of Florida, December 1976. 3. W. L. Jenkins, "Ion Pair Structure and Beta Carbon Stereochemistry in the Anionic Oligomerization of Vinyl Pyridines", Ph.D., University of Florida, June 1978.

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4. S. S. Huang, "Stereochemistry of Anionic Oligomerization of 2-Vinylpyridine. Preparation and Analyses by NMR and Chromatography", Ph.D., University of Florida, June 1981. 5. M. A. Buese, "Stereoselection and Stereoelection in the Anionic Oligomerization and Polymerization of Vinylphenylsulfoxide", Ph.D., University of Florida, September 1982. 6. C. C. Meverden, "Stereochemical and Mechanistic Studies on the Anionic Oligomerization of 2- and 4-Vinyl Pyridines", Ph.D., University of Florida, August 1983. 7. M. A. Doherty, "Synthesis and Characterization of Stereoblock Polymers of Poly(methylmethacrylate)," Ph.D., University of Florida, December 1984. 8. I. M. Khan, "Anionic Polymerization of 2-Vinyl Pyridines: Studies of Intermediate Carbanions and Their Role in the Stereochemistry of Polymerization", Ph.D., University of Florida, December 1984. 9. B. C. Bell, "Stereochemistry of Anionic Oligomerization of t-Butylvinylketone", Ph.D., University of Florida, June 1986. 10. William Toreki,"Synthesis of Well-Defined Cyclic Branched and Water-Soluble Polymers Via the Anionic Polymerization of 2-Vinylpyridine", Ph.D., University of Florida, May 1988. 11 R. S. Kanga, "Thermal Elimination of Poly(phenylvinylsulfoxide) and Its Styrene Block Copolymers", Ph.D., University of Florida, August 1988. 12 K. G. Bannerjee, "The Stereochemistry of Group Transfer Polymerization of Methyl- Diphenyl-methyl and Triphenylmethylmethacrylates", Ph.D., University of Florida, August 1988. 13 J. P. Mason, "The Synthesis and Characterization of Monodisperse Polydimethylsiloxane- poly(methyl-methacrylate) AB, ABA and Star Block Copolymers. Stereocomplex Formation with Isotactic Poly(methylmethacrylate)", Ph.D., Univ. of Southern California, December, 1989. 14. B. J. Ladd, "Synthesis and Characterization of Polybutadiene-PMMA Block Copolymers Stereocomplex Formation with Isotactic PMMA," Ph.D., University of Southern California, February 1990. 15. J. Sundararajan, "Synthesis and Characterization of Macrocyclic Poly(2-vinylpyridine) and Polystyrene", Ph.D., University of Southern California, May 1991. 16. R. Yin, “Synthesis and Properties of the First Macrocyclic Polystyrene-Polydimethylsiloxane Block Copolymers Synthesis and Characterization of Poly(2-vinylpyridine-Poly(t- butylmethacrylate) Block Copolymers" Ph.D., University of Southern California, May 1993. 17. F. S- Hwang, "Synthesis and Characterization of Hydrophobically Associating Water-Soluble Polymers," Ph.D., University of Southern California, August 1993. 18. Q. Jin, “Effect of Lithium Alkoxides on Stereochemistry of Polymrerization of 2- Vinylpyridine Initiated with tert-butyllithium in Toluene. April 1994. 19. M. Yassini, "Perfluorocarbon-Containing Hydrophobically Associating Polymers. Aqueous Copolymerization Mechanisms," University of Southern California, August 1994. 20. X. Xie, "Synthesis and Characterization of Poly (N,N-dimethylacrylamide). Well-defined Block Copolymers, Telechelic Polymers and Random Copolymers”, University of Southern California, December 1994.

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21. Y. Gan, “Synthesis and Characterization of Macrocyclic and Catenated Polystyrene and Poly(2-vinyl pyridine), Block Copolymers, University of Southern California, May 1995. 22. A.P. Zagala, “Anionic Synthesis of Narrow Molecular Weight Distribution Polymethyl Methacrylate, Poly(n- butylacrylate), Block Copolymers, University of Southern California, May 1995. 23. B.J. McCarthy,“Synthesis of Narrow Distribution Poly(Tetrahydrofuran) Cationic Ring Opening Polymerization of THF Initiated by Alkylboron Triflates, University of Southern California, August 1995. 24. D. Dong, “Synthesis and Characterization of Well-Defined Polystyrene and Poly(alphamethylstyrene), Simulation of Formation of Macrocycles by End to End Coupling” University of Southern California, December 1995. 25. T. Makino, “Anionic Synthesis of Highly Isotactic Polystyrene in the Presence of Lithium Hydroxides of Lithium Alkoxides and Controlled Living Polymerization of Methylmethacrylate by Atom Transfer Polymerization.” University of Southern California, May 1997. 26. H. Zhang, “Synthesis and Self-Assembly of Fluorocarbon-Modified Water Soluble Polymers” University of Southern California, Dec. 1997. 27. J. Pan “Synthesis and Characterization of Self Assembling Block Copolymers Containing NLO blocks” University of Southern California, May 1999. 28. J.A. Lee “Synthesis And Characterization of Block Copolymers of Polyvinylpyridine or

Polyalphamethyl- Styrene With Polydimethylsiloxane. Self-Assembly of Polyvinylpyridine –b--Polydimethylsiloxane with Polyvinylphenol” University of Southern California, May, 2000.

29. E. Tillman“Coupling Reactions Of Polystyrene Anions With Bifunctional Electriophiles” University of Southern California, May 2001. 30. G. G. Nossarev. “Living Anionic Polymerization of 2-Vinylnaphthalene. Synthesis and Characterization of Macrocyclic Poly(2-vinylnaphthalene)” University of Southern California, December 2001 31. Kurt Alberty “Synthesis and Chracterization of Macrocyclic Polystyrene” University of Southern California, December 2001. 32. William N. Warner “Kinetically Controlled Dimerization of 4-(N,N-Dimethylamino)styrene. Block Copolymerization of This and Related Monomers”. University of Southern California, December 2001. 33. Sandra Tomczak “Association of Perfluorocarbon Containing Water-Soluble Polymers”. University of Southern California, May 2002. 34. Jane Da “ Synthesis and chracterization of poly(N,N-dimethylacrylamide) with perfluorocarbon pendent groups connected through polyehylene glycol spacers” University of Southern California, May 2003. 35. Rong Chen “Synthesis and Characterization of Macrocyclic Vinyl Aromatic Homopolymers and Block Copolymers”. University of Southern California, August 2003. 36. Sudhakar Madhusoodhanan “Synthesis and characterization of functional oligomers and polymers for organic light emitting diodes”. University of Southern California, September 2004.

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37. Nadia Fomina “Studies Of Yamamoto And Suzuki Polymerizations Of Dibromofluorenes. Synthesis and Spectroscopy Of Fluorene Macrocycles And Copolymers “University of Southern California, May2009. 38. Jingguo Shen “Perfluorocarbon Mediated Self-Assembly of Vinyl Polymers”. University of Southern California, August 2009. 39. Victoria Piunova “ Blends of Perfluorocarbon End-Functionalized and Telechelic Polystyrene-Polybutylmethacrylate. Synthesis and Morphology Studies.” University of Southern California August 2011. 40. Janet Olson “The Design and Synthesis of Helicene-Based Macromolecules for Second-Order

Nonlinear Optics Applications”. June 2014.

41. Ming Li. “Development Of Polystyrene Sulfonic Acid-Polyvinylidene Fluoride Blends For

Direct Methanol Fuel Cells ” December 2014

MSc Dissertations 1 R. A. Smith, "Methylation and Alpha-Carbon Stereochemistry in the Anionic Oligomerization and Polymerization of 2-(2-Pyridyl)propene", M.Sc., University of Florida, March 1981. 2. C. R. Wince, "The Synthesis and Interactions of Oligopeptide Bis Intercalators with DNA", M.S., University of Florida, August 1982. 3. Scott M. Taylor, “Synthseis of Metal Nano Particles and Organic Perfluoroalkylated Chromophores. Effect of Fluorophilic Interactions on Fluorescence of Organic Chromophores” University of Southern California, December 2009. CURRENT AND PENDING RESEARCH SUPPORT (PI and co-PI, if any)

A. List any active research grants or other current financial support received for research. Give titles, amounts (annual direct costs; if more than one PI, indicate only your share of the granted amount), sources, time periods of awards, and relationship to this proposal. Use a separate page if necessary; indicate “none” if applicable.

Thieo E Hogen-Esch Funded: Title: Studies on Fluorocarbon Polymers. Institute Award Period: 01/01/13 – 12/31/14 Grant Number: LHI 0074 Funding: Loker Hydrocarbon Research. Funding level: $30,000 Grant Title: Novel Reverse Osmosis Membranes Using Polymeric and Nanomaterials for Water Desalination Coprincipal Investigator with M Pirbazari. Period : 08/01/13 – 7/31/2014 Grant Number USC 10209 6 months University of Southern California Total Dollars: $3,500.

Pending; ACS Petroleum Research Foundation. Period: 9/1/2015-8/ 31/ 2017. “Polymer Blend-Based Nano-Composites Through Selective Polymer Camouflage” $110,000. Applications Submitted (2013-2014 academic year): Not funded:

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DOE/Office of Science Program Office: Basic Energy Sciences. Period: 7/1/2014-6/30/2017. USC-Center For Sustainable Mega-Scale Energy Storage. $8,431,868 S Naryan PI, 8 Co-PI’sTHE portion is $ 572,402. NSF-CBET. Period: 08/16/14 - 08/15/16. High Performance Membranes for Water Reclamation Using Polymer Nanocomposites M Pirbazari PI, T Hogen-Esch co-PI. Total Budget: 341,727.. NSF-MEP, Period: 09/01/2014 – 08/31/2017. Polymers Reinforced with Self-Assembled Perfluorocarbon Micro Clusters. T. Hogen-Esch PI. O Franke co-PI. Total budget is $ 259,119. Applications Submitted not funded prior to 2013-2014 academic year: “Compatibilization of Polymer Blends based on Non Covalent Interactions”. NSF-DMR. Period: 05/01/13-04/30/16. $286,750. T. E. Hogen-Esch. ‘Heat Transfer Enhancement and Composition Studies of a New Class of Drag Reducing Additives in Aqueous Systems: Hydrophobically Modified Low Molecular Weight Polymers” Period: 7/1/13-06/30/14. ACS Petroleum Research Foundation.”. Budget: 149,649 Jack Zakin Ohio State University. (PI) and T.E. Hogen-Esch (co-PI) “Synthesis and Characterization of Blends of Polymers Functionalized with Perfluorocarbon Groups.” Period: 10/31/2011-09/30/2014. $525,583.00. T. E Hogen-Esch Dept. of Chemistry (PI) and Steve Nutt (co-PI), Dept of Chemical Engineering and Materials Science(co-PI). NSF-DMR. $ 385,470 ( “Self-Assembly of Fluorocarbon Modified Polymers in Solution and in the Solid State.” T. E Hogen-Esch Dept. of Chemistry (PI) and Steve Nutt (co-PI), Dept of Chemical Engineering and Materials Science(co-PI). New Coatings Based On Fluorocarbon Polymer Self-Assembly. Ameduri, B (PI), Hogen-Esch, T.E. )Co-Pi) Laschewsky, A (Co-Pi). 05/01/11/04/30/2014. $864, 670 (THE portion is $359,720) Past Grant Support (THE unless indicated otherwise). Merck Chemical Company, Title: “Applications Arising from a Perfluorocarbon Containing Polymers Platform. Funding Period: 06/01/2007-05/01/2011. Amount: $1,500,000. THE portion $ 500, 0000. Hydrocarbon Rsearch Foundation. “Development of New Perfluorinated Copolymer Systems” Funding Period: 01/01/2010 - 12/31/2011. Amount: $120,000.00 ACS Petroleum Research Foundation, Title: Phosphor Ylide Mediated Vinyl Polymerizations Funding Period: 09/01/05-8/31/07. Amount: $80,000 Avery Dennison Corporation. Title: “Synthesis of Polybutadiene -Based Macromonomers Funding Period: 09/01/05-8/31/07.Amount: $84,000 NIH, 263-MD-313251 Title: “Synthesis of AB Block copolymers.. Period: 7/1/03-5/31/04. Amount: $19,981 National Science Foundation. $538,270.00 «Acquisition of a 600 Mhz NMR Spectrometer at the University of Southern California» Richard W. Roberts, P.I., Mark Thompson Co-PI600. MHz NMR with BB direct probe, Triple HCN probe, Triple HCP probe. Coinvestigator along with 16 others. Science and Technology Center on Information Technology Research” Dr L.Dalton PI. Subcontract 594608, $ 50,000.

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8/01/02 to 7/31/03 “Design And Synthesis Of Phagocytosis Resistant Polymeric Surfactants For The Development Of Perfluorocarbon Emulsions” co PI with C. Peng (USC, Chem Engineering , PI ) NSF-BES 0003006, 09/01/01-05/31/04, $ 270,000. THE portion is $ 135,000) “Synthesis and Characterization of AB Block Copolymers Containing a Central Cyclodextrin or Sugar Moiety” National Institute of Arthritis and Musculo-skeletal and Skin Diseases: Research Contract. E. Kempner PI, March 20th-September 30th 2002. $ 19,981. “Synthesis of New Vinyl Monomers for Chemical Sensing Applications” Army Research Office STIR Program June 1st-November 30th 2001, $ 30,000. " Self-Assembly of Perfluorocarbon- Containing Polymers" Department of Energy, Office of Basic Energy Sciences 9/15/98 - 9/14/99, $ 46,982 “Synthesis of Monodisperse Poly(tetrahydrofuran) by Boron-Containing Lewis Acids” BASF 1/1/96 - 4/1/99, $120, 000. “Atom Transfer Polymerization of Macromonomers” Kodak Co., Rochester, N.Y. 7/1/98 - 6/30/99, $ 40,000. “Synthesis of New Vinyl Monomers for Chemical Sensing Applications” Army Research Office STIR Program June 1st-November 30th 2001, $ 30,000 "Synthesis and Luminescence of Macrocyclic Vinyl Polymers” NSF –DMR 9810283, 8/1/98 - 12/31/01 $270.004. “Materials and Processing on the Nanometer Scale” Multi-University Grant MURI - US Air Force with Dalton (PI), Olah, Prakash, Weber, Thompson, Grubbs (Cal Tech), Frechet (Cornell), Gorman (UNC). (12/95 - 12/99 is $ 6,650,000.00) “Studies in Metal Free Anionic Polymerization of Acrylate”, BASF 1/1/96 - 12/31-97 $80.000 “Studies in the Living Polymerization of MMA” Mitsubishi Rayon Co., 11/95 - 12/96 $25,000 "Synthesis of Topologically and Stereochemically Well Defined Polymers" NSF – DMR 4/15/91 - 3/31/96 $567.700 "Synthesis and Characterization of Self-Assembling Water Soluble Polymers" Department of Energy, Office of Basic Energy Science 12/92 - 12/95 $ 285,091.00 "Mechanism and Stereochemistry of Propagation in Living Ionic Polymerizations"Joint with S. Penczek, Lodz, Poland. Travel and per diem only 7/1/93 - 6/30/96 $12,000.00 "Studies in the Living Polymerization of MMA" Mitsubishi Rayon, Co., Ltd. Tokyo 11/94 - 10/95 $20,000.00 "Anionic Polymerization of Vinyl Monomers"Toagosei Co., Ltd. Tokyo 12/94 - 12/95 $20,000.00 "Copper Based Initiators for the Controlled Anionic Polymerization of Acrylates" Nippon Shokubai Co. 3/1/94 - 2/28/95 $ 30,000.00 "Studies in the Cationic Polymerization of Tetrahydrofuran" BASF America 1/96 - 12/96 $ 40,000.00 "Studies in the Metal-free Anionic Polymerization of Acrylates" BASF Ludwigshafen, Germany1/1/95 - 12/31/95 $ 40,000.00 Dupont de Nemours & Co., "New Lithium Ion Conducting Polymers", July 1, 1992 to June 30, 1992, $25,000.

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U. S. Department of Energy, Office of Basic Energy Sciences, "Synthesis and Characterization of Self-Assembling Water-Soluble Polymers", December 1992-December 1995, $285,091, (E. Amis, Co-investigator). "Spectroscopic Determination of the Polymer Microstructure and of Active Centers in Polymerization" (with S. Penczek, Lodz, Poland), travel only, May 1990-April 1992, $4,000. National Science Foundation, DMR Polymers Program, "Synthesis of Topologically and Stereochemically Well-Defined Polymers", April 1991-March 1995, $ 438,200. U. S. Dept. of Energy, "Synthesis of Novel Associating Water-Soluble Copolymers," Sept. 1989 to Nov. 1992, $315,400 (with Eric Amis, Principle Investigator). National Science Foundation Materials CBTE-MCCP, "Solution Properties and Membrane Formation of New Block Copolymers", July 1989-June 1992, $187,000 (with C. Cohen, Cornell University). National Science Foundation, Polymers Program, "Ion Pairs and the Stereochemistry of Anionic Vinyl Polymerization", 1972-76, $102,100; 1976-78, $64,500; 1978-80, $84,133; 1980-83, $150,200; 1983-86, $199,300; 1986-89, $234,100; 1989-91, $170,000. U. S. Department of Defense, Office of Naval Research, DARPA Program, "Electrically Conductive Polymers: Synthesis Measurement and Theory", 1986-l991, $3,400,000 (approximate), joint with K. B. Wagener (Chemistry); D. B. Tanner, H. J. Monkhorst, S. E. Nagler (Physics); C. D. Batich and J. W. Williams (Material Division). U. S. Dept. of Energy, "Synthesis and Characterization of Novel Polymers From Non-Petroleum Sources for Use in Enhanced Oil Recovery", 1978-1979, $70,000; 1979-1980, $84,000; 1980-1981, $95,000; 1981-1982, $110,000; 1982-1983, $120,000; (with G.B. Butler) U. S. Department of Energy, "Synthesis of Model Polymers and Related Structures in Support of Vinyl Monomer Grafting Studies", 1986-1989, $297,134, Principal Investigator (with G. B. Butler). U. S. Department of Defense, Army Research Office, "Synthesis and Properties of Linear and Star-Block Copolymers Capable of Thermally Reversible Crosslinking Through Formation of Poly(methylmethacrylate Stereocomplexes", 1986-1989, $269,101, Principal Investigator (with C. L. Beatty). Dow Corning, "Ultraviolet Degradation Studies on Octamethylcyclotetrasiloxane and Related Compounds", 1976-1977, $33,633, (with G. B. Butler and A. E. S. Green). National Science Foundation Equipment Grants: "Acquisition of an Infrared Spectrophotometer", 1978, $17,000 (with G. B. Butler). "Acquisition of an NMR Spectrometer", 1981, $24,000, Principal Investigator (with G. B. Butler). "Acquisition of a High Field NMR Spectro-meter Departmental 300 MHz Instrument", 1981, $150,000 (with W. Brey and G. B. Butler). "Acquisition of a Nuclear Magnetic Resonance Spectrometer", 1984, $81,000, Principal Investigator (with G. B. Butler and A. R. Katritzky). National Science Foundation, U. S. - France Cooperative Science Exchange Program/Division of Internal Programs (Travel), "Reactive Intermediates in the Stereoregular Anionic Oligo- and Polymerization of Vinyl Monomers", 1983-1986, $12,046 (collaboration with Professor M. Fontanille, University of Paris-Nord). Division of Sponsored Research, University of Florida, "Ion Bonding to Non-Electrolyte Polymers", 1976, $9,800. PRESENTATIONS (National and International only)

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ACS Meeting, Phoenix, AZ, January 1967, "Ion Pairs of Carbanion Salts." ACS Meeting, New York, September 1969, "The Structure of Fluorenyl Alkaline Earth Salts in Aprotic Media." ACS National Meeting, Boston, MA, April 1972, "Stepwise Solvation of Sr Salts in Tetrahydrofuran." ACS Meeting-in-Miniature, Clearwater, FL, May 1973, "Specific Cation Participation in Cyclic Ether Cleavage Reactions." ACS Conference on "Ion Pairs and Anion Activation", N. Falmouth, MA, October 1973, "The Structure of Ion Pairs in Protic Media". ACS Southeast Regional Meeting, Charleston, SC, November 1973, "Ion Pair Structure as a Factor in Carbanion Initiated Cyclic Ether Cleavage Reactions" and "Anionic Polymerization of Vinylpyridines. Spectroscopic and Conductometric Studies of the Active Site in Aprotic Solvents" and "Ion Pairing in Excited States of Alkali Carbanions. Cation and Solvent Effects". IUPAC International Symposium on Macromolecules, Madrid, Spain, September 1974, "Investigations of Ion Pair Structure and Its Effect on the Anionic Polymerization of Vinylpyridines." ACS National Meeting, Philadelphia, PA, April 1975, "The Structure of Ion Pair Aggregates" and "Ion Pair Effects in the Emission of Carbanions and Radical Anions." ACS Eighth Central Regional Meeting, Akron, OH, May 1976, "Cation and Solvent Effects on the Stereochemistry of Alkylation of Carbanions Derived from Dimers of Vinylpyridines". Gordon Research Conference on Polymers, New London, NH, July 1976, "Ion Pairs and the Stereochemistry of Anionic Oligomerization of Vinyl Monomers." ACS Southeast Regional Meeting, Gatlinburg, TN, October 1976, "Ion Binding to Neutral Polymers" with Rod Cambron. IUPAC International Symposium on Macromolecules, Dublin, Ireland, July 1977, “Stereoselective Anionic Oligomerization of Vinyl Monomers”, with C. F. Tien. ACS Southeast Regional Meeting, Tampa, FL, November 1977, "Beta-Carbon Stereochemistry in the Anionic Oligomerization of 2-Vinylpyridine", with W. L. Jenkins. ACS National Meeting, Miami, FL, September 1978, “Stereoselective Anionic Oligomerization of Vinylpyridines and Related Protonation and Alkylation Reactions" with C. F. Tien; "Anion Structure and Beta-Carbon Stereochemistry in Anionic Polymerization of Vinylpyridines”, with W. L. Jenkins. IUPAC International Symposium on Ions and Ion Pairs and Their Role in Chemical Reactions, Syracuse, NY, May-June 1978, "Stereochemical Effects of Ion Pairing in Carbanion Reactions" (Invited Lecture). NATO Advanced Study Institute, Pisa, Italy, October 1978, "Ion Pairs Effects on the Anionic Oligomerization Stereochemistry of Vinylpyridines and Related Monomers". IUPAC 26th International Symposium on Macromolecules, Mainz, Germany, September 1979, "Ion Pair Effects in the Stereochemistry of 2-Vinylpyridines and Related Monomers"; "Cation and Solvent Effects on the (E)-2-Vinylpyridines and Related Monomers". IUPAC 27th International Symposium on Macromolecules, Strasbourg, France, July 1981, “Mechanistic Studies on the Anionic Oligomerization of 2-Vinylpyridine in Tetrahydrofuran”, with C. Mathis.

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ACS Southeast Regional Meeting, Lexington, KN, 1981, "Stereochemistry of Anionic Oligomerization and Polymerization of 2-Vinylpyridine" with S. S. Huang. ACS National Meeting, Las Vegas, NV, March 1982, "Stereochemistry of Anionic Oligomerization and Polymerization of 2-(2-Pyridyl)- and 2-(4-Pyridyl)propene", with K. Hashimoto, C. F. Tien and R. A. Smith. ACS Meeting-in-Miniature, Orlando, FL, May 1982, "Mechanistic Studies on the Anionic Oligomerization of 2-Vinylpyridine", with C. C. Meverden; "Dimerization of Vinylphenyl Sulfoxides", with M. A. Buese. Japanese Chemical Society Spring Meeting, Tokyo, Japan, May 1982, "Stereochemistry of the Anionic Polymerization of Isopropenylpyridines", with K. Hashimoto. IUPAC Symposium on Macromolecules, Amherst, MA, July 1982, "Oligomerization of Vinyl Monomers, A Tool in the Elucidation of Polymer Stereochemistry", with C. Mathis, S. S. Huang and C. Meverden. "The Dimerization of Vinylphenyl Sulfoxide as a Model to Elucidate the Stereochemistry of Poly (vinylphenyl-sulfoxide): Stereoselectivity and Stereoelectivity," with M. A. Buese. ACS 34th Southeast Regional Meeting, Birmingham, AL, November 1982, "1H, 13C NMR Studies on Living Polymers of 2-Vinylpyridine", with I. M. Khan; "Studies on the Mechanism of the Anionic Oligomerization of 2-Vinylpyridine", with C. C. Meverden. ACS Meeting-in-Miniature, Jacksonville, FL, May 1983, "NMR and Conductometric Studies of the Carbanion Intermediates in the Polymerization of 2-Vinylpyridines", with I. M. Khan. ACS 186th National Meeting, Washington, DC, August-September 1983, "Stereochemical Analysis of Vinyl Polymers.

13C NMR of Labeled Terminal CH3 Groups" with A.H. Soum and S.S. Huang.

“Studies on the Active Centers in Anionic Oligomerization 2-Vinylpyridine in THF”, with I. M. Khan and C. C. Meverden. ACS 35th Southeast Regional Meeting, Charlotte, NC, November 1983, “Thermodynamics of Intramolecular Coordination in the Anionic Oligomerization of 2-Vinylpyridine” with C. C. Meverden. “Active Center of the Living Polymer of 2-Vinylpyridine and Its Role in the Polymerization Process” with I. M. Khan. “Synthesis of Stereoblock PMMA” with M. Doherty. ACS Meeting-in-Miniature, Lakeland, FL, May 1984, "Synthesis of Novel AB Stereo-block Copolymers", with M. Doherty. ACS 188th National meeting, Philadelphia, PA, August 1984, "Synthesis and Characterization of Stereoblock Poly(methylmethacrylate), with M. Doherty. ACS 36th Southeast Regional Meeting, Raleigh, NC, October '84, "Stereochemistry of Anionic polymerization of t-Butyl Vinyl Ketone", with B. C. Bell. ACS 190th National Meeting, Chicago, IL, September 1985, "Stereoregular Oligomerization and Polymerization of 3-Methyl-2-Vinylpyridine", with I. M. Khan. ACS 191st National Meeting, Symposium on “Recent Advances in Anionic Polymerization and Related Processes,” New York City, NY, April 1986. “Stereochemistry of the Anionic Polymerization of Vinyl Phenyl Sulfoxide,” with M. A. Buese; "Role of E- and Z-Carbanions in the Stereochemistry of Anionic Vinyl Polymerization”, with I. M. Khan. “Studies of Trifunctional Carbanion Initiators for the Preparation of Three-Arm Star Polymers”, with W. Toreki. Society of Polymer Science, 36th Annual Meeting, Kyoto, Japan, May 1987, Invited Speaker, "Stereochemistry of Anionic Oligomerization".

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IUPAC Congress, 31st Annual Meeting, Sofia, Bulgaria, June 1987, Invited Speaker, "Stereo-chemical Aspects of Vinyl Polymerization". ACS 193rd National Meeting, August 1987, New Orleans, LA, "Synthesis of Poly(butadiene)-Syndiotactic Poly(methylmethacrylate) Block Copolymers. Stereocomplex Formation with Isotactic PMMA", with G. Helary and B. J. Ladd; "Stereochemical Kinetics of Group-Transfer Polymerization of Methylmethacrylate. 13C NMR Analysis of PMMA Terminated with Labeled End Groups", with K. G. Banerjee; "Anionic Polymerization and Copolymerization of Phenyl Vinyl Sulfoxide and Thermal Degradation Studies of Poly(phenylvinylsulfoxide)" with R. Kanga and M. A. Buese; "Synthesis of Macrocyclic Poly (2-vinyl-pyridine)" with W. Toreki and G. B. Butler; "Stereochemistry of Oligomerization of MMA and Correlation with End-Group Stereochemistry of PMMA", with R. A. Volpe. ACS 195th National Meeting, September 1988, Los Angeles, CA, "Synthesis of Macrocyclic Poly(2-vinylpyridine) and Macrocyclic Poly(N-Alkyl-2-Vinylpyridinium) Bromide, A Cyclic Poly-electrolyte", with W. Toreki and G. B. Butler; "Effects of Chain Length and Stereochemistry on the Kinetics of Addition of 1-1 Diphenylethylene to Oligomeric Models of Living Poly(2-Vinyl-pyridine)-Lithium", with M. Fontanille, G. Helary and I. M. Khan; "Preparation of Isotactic and Syndiotactic Poly(2-Vinylpyridine) Initiated by 1-Butyllithium and 1-Butyllithium Trialkylaluminum in Toluene", with D. K. Dimov; "Synthesis of AB and ABA Block Copolymers of Styrene and Phenylvinylsulfoxide. Thermal Elimination Studies", with R. Kanga; "Spontaneous Dimerization of g Poly(2-Vinylpyridine)" with W. Toreki. ACS 196th National Meeting, April 1989, Dallas, TX, "Synthesis of Macrocyclic- and Star-Vinylpolymers", with W. Toreki; "Synthesis of Monodisperse Polydimethylsiloxane-Syndiotactic Polymethylmethacrylate AB and ABA Block Copolymers by Anionic Polymerization", with J. P. Mason and T. Hattori; "Synthesis of Polybutadiene-Syndiotactic Polymethylmethacrylate Block Copolymers. Stereocomplex Formation with Isotactic PMMA", with B. J. Ladd. ACS 197th National Meeting, September 1989, Miami Beach F., "Planarizing Polyaromatic Polymer Based On Inine Chemistry", with K. B. Al-Jumah and K. B. Wagener; ACS 197th National Meeting, September 1989, Miami Beach F., "A New Fluorocarbon-Containing Hydrophobically Associating Polyacrylamide Copolymer" with Y.-X. Zhang, A.-H. Da and G. B. Butler; ACS 197th National Meeting, September 1989, Miami Beach F., "Stereochemistry of Anionic Vinyl Polymerization. Stereochemical Roles of E- and Z- Isomers" with D. Dimov. IUPAC 33rd International Symposium on Macromolecules, Montreal, July 8-13, 1990, "Water-Soluble Graft Copolymer of 2,3-Dihydroxypropylcellulose with Acrylamide and with Sodium-2-Acrylamido-2-Methyl-propanesulfonate", Y-X. Zhang, A.H. Da and G. B. Butler; IUPAC 33rd International Symposium on Macromolecules, Montreal, July 8-13, 1990, "Synthesis and Stereocomplex Formation of Polydimethylsiloxane-PMMA Block- and Star-Copolymers; with J. P. Mason and T.E Hogen-Esch; IUPAC 33rd International Symposium on Macromolecules, Montreal, July 8-13, 1990, "Synthesis and Properties of Polybutadiene-Syndiotactic PMMA Block- and Star-Block Copolymers", with B. J. Ladd. ACS 198th National Meeting, August 26-31, 1990,Washington, DC, "Stereocomplex Formation of PMMA-Containing Block Copolymers Synthesis and Properties", with B. J. Ladd, J. P. Mason, G. Helary and G. Belorgey; ACS 198th National Meeting, August 26-31, 1990, Washington, DC M. Yassini, Y.X. Zhang, F. Huang, E. J. Amis and T. Seery.Synthesis and Characterization of Fluorocarbon Containing Polyacrylamides",

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ACS 199th National Meeting, April 1991, Atlanta, Georgia, 1) "Synthesis and Characterization of Macrocyclic Poly(2-vinylpyridine", T.E. Hogen-Esch and J. Sundararajan; 2) "Lithium Alkoxides as Modifiers for the Synthesis of Isotactic Poly(2-Vinylpyridine) in Toluene", Q. Jin, D. Dimov and T.E. Hogen-Esch; 3) "Synthesis and Characterization of Poly(2-vinylpyridine)-b-t-Butylmethacrylate Copolymers", R. Yin and T.E. Hogen-Esch, "Fluorocarbon-Modified Water-Soluble Cellulose Derivatives", F. Hwang and T.E. Hogen-Esch. Tenth International Symposium on Cationic Polymerization and Related Ionic Processes, Balatonfured, Hungary, August 26-29, 1991, "Recent Developments in the Stereochemistry of Anionic Polymerization of Polar Vinyl Monomers." ACS 201st National Meeting, April 4-9, 1992, San Francisco, California, "First Synthesis of a Macrocyclic Block Copolymer Macrocyclic Polystyrene-b-Polydimethylsiloxane", R. Yin and T.E. Hogen-Esch; "Fluorine Containing Hydrophobically Associating Polymers", M. Yassini and T.E. Hogen-Esch; "Polymerization of N,N-Dialkylacrylamide and -methacrylamide", X. Xie and T.E. Hogen-Esch; "Static and Dynamic Lightscattering Characterization of Hydrophobically Associating Fluorocarbon Containing Polymers", E.J. Amis, T.A. Seery, M. Yassini and T.E. Hogen-Esch; "Synthesis and Characterization of Poly(2-vinylpyridine) Macrocycles. Effect of Coupling Agent", J. Sundararajan and T.E. Hogen-Esch. Workshop on Anionic Polmerization, July 19-23, 1992, Mainz, Germany, “Kinetics and Mechanism of Anionic Syndrospecific Polmerization of 2-Vinyl Pyridine”, P. Hubert, A. Soum, M. Fontanille and T.E. Hogen-Esch; “Stereochemistry of Anionic Vinyl Polymerization”, T.E. Hogen-Esch. ACS 203rd National Meeting, March 28-April 2, 1993, Denver, Colorado, "PEO Based Lithium Ion Conducting Polymers", D. Dong, T.E. Hogen-Esch and J. Smid; "Effects of Water Soluble Spacers on the Hydrophobic Association of Fluorocarbon Modified Polyacrylamides", F.S. Hwang and T.E. Hogen-Esch; "Synthesis and Characterization of Macrocyclic Polystyrene-D-Poly(2-vinylpyridine) Block Copolymers", Y. Gan, J. Zoeller and T.E. Hogen-Esch; "Synthesis of Well-Defined Poly(N,N-dimethylacrylamide) Containing Perfluorooctanoyl End Groups", X. Xie and T.E. Hogen-Esch; "Anionic Polymerization of trimethylvinyl-silane and Phenyldimethyl Vinyl Silane. Towards the Synthesis of Well Defined Polyfluorodimethyl Vinyl Silane and Polyvinyl Alcohol", Y. Gan, T.E. Hogen-Esch, W.P. Weber, G.K.S. Prakash and G.A. Olah; "Synthesis and Anionic Polymerization of the Structurally Hindered Monomer 7-Methylene-8,9-cyclopentapyridine", B.J. McCarthy and T.E. Hogen-Esch; “Anionic Polymerization of Azo-Substituted Methacrylates", D.K. Dimov, L.R. Dalton and T.E. Hogen-Esch; “Side Reactions in the Synthesis of Polystyrene-Polydimethylsiloxane and Polystyrene-Polyethylenedisiloxane-Polydimethylsiloxane Block Copolymers”, R. Yin and T.E. Hogen-Esch; "Poly(2-vinylpyridine)-Polydimethylsiloxane Block Copolymers. Synthesis and Characterization via Anionic Polymerization", J.A. Lee and T.E. Hogen-Esch. International Conference on “Frontiers in Polymerization”, Liege, Belgium, October 6-8, 1993. “Role of Intramolecular Coordination in Anionic Vinyl polymerization (Invited Lecture). University of Groningen, Netherlands, November 16, 1993, Retirement Symposium of Professor G. Challa “Stereocomplex Formation in PMMA - Polybutadiene and PMMA - Polydimethylsiloxane Block Copolymers and Their Mixtures with Isotactic PMMA” (Invited Lecture). ACS 205th National Meeting, San Diego, CA March 13-18, 1994, M. Yassini and T.E. Hogen-Esch, ACS Div. Polym. Sci. Polym. Prepr., 35 (1), 478 (1994) “Fluorine-Containing Hydrophobically Associating Water-Soluble Polymers - Kinetics of Polymerization by 19F NMR”. X. Xie and T.E. Hogen-Esch, ACS Div. Polym. Sci. Polym. Prepr., 35 (1), 498 (1994) “Synthesis and Characterization of Hydrophobically Associating Poly (N,N-dimethylacrylamide)”. 35th International Symposium on Macromolecules, Akron, Ohio, July 11-15, 1994 “Hydrophobic Association in Perfluorocarbon-Containing Poly (N,N-dimethylacrylamide) - Surfactant Solutions (with X. Xie)”.

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ACS 206th National Meeting, Washington, DC, August 21-26, 1994, Y. Gan, D. Dong, and T.E. Hogen-Esch, ACS Div. Polym. Sci. Polym. Prepr., 35 (2), 574 (1994) “Effects of Lithium Bromide on the Glass Transition Temperatures of Linear and Macrocyclic Poly (2-Vinylpyridine)”. J.Q. Jin and T.E. Hogen-Esch, ACS Div. Polym. Sci. Polym. Prepr., 35 (2), 576 (1994) “Stereochemical Effects of Lithium t-Butoxide Complexes in the Anionic Polymerization of 2-Vinylpyridine”. J.Q. Jin and T.E. Hogen-Esch, ACS Div. Polym. Sci. Polym. Prepr. 35 (2), 593 (1994) "Stereochemistry of Polymerization of 2-Vinylpyridine in the Presence of Lithium Alkoxide Complexes". ACS 207th National Meeting, Anaheim, CA, April 2-7, 1995 X. Xie & T.E. Hogen-Esch, "Hydrophobically Associating End-Functionalized Poly (N,N-dimethylacrylamide). Effect of Hydrophilic Spacers". Y. Gan, D. Dong & T.E. Hogen-Esch, "Synthesis and Characterization of a Catenated Poly (Styrene) - Poly (2-Vinylpyridine) Copolymers". Y. Gan & T.E. Hogen-Esch, "Fluorescence Studies of Linear and Macrocyclic Polystyrene - b - Poly (2-Vinylpyridine) Copolymers." APME Meeting, “Frontiers of Polymerization” Vassar College, NY, June 26, 1995, “Fluorescence of Isobaric Linear and Macrocyclic Polystyrene and Polystyrene - b - poly(2-vinylpyridine)” APME Meeting, “Frontiers of Polymerization” Vassar College, NY, June 27, 1995, “Synthesis of Catenated Polystyrene - b- Poly(2-vinylpyridine). A Novel Type of Block Copolymer.” “IUPAC International Symposium on Ionic Polymerization” Istanbul, September 4-8, 1995. “Anionic Synthesis of Narrow Molecular Weight Distribution Polymethylmethacrylate at Ambient Temperatures in the Presence of Tetraphenylphosphonium Cation”. “IUPAC International Symposium on Ionic Polymerization” Istanbul, September 4-8, 1995. “Kinetic Studies of Anionic Polymerization of Methylmethacrylate Using Tetraphenylphosphonium Counterion”. University of Liege Belgium, “Living Anionic Polymerizations of Mehtylmethacrykates in the Presence of Tetraphenylphosphonium Ion” September 18, 1995. College De France, Paris, “Hydrophobic Association of Perfluorocarbon Derivatives of Polyacrylamides” May 20, 1996. Universite Pierre et Marie Curie, Paric, France. “Living Cationic Polymerization of Tetrahydrofuran Initiated with Alkyl Boron Triflates” May 22, 1996. Universite de Bordeaux-1, France “Ylide-Mediated Living Polymerizationof Methacrylates” May 23, 1996. Institut Charles Sdron, Strassbourg, France “Fluorocarbon-Mediated Association of Water-soluble Polymers” May 23, 1996. Second International Conference On “Advanced Polymers Via Macromolecular Engineering” Orlando, April 19-24, 1997. “Synthesis of Highly Isotactic Polystyrene and the Corresponding cis-1,4-Polyisoprene-Polystyrene Block Copolymers by Anionic Polymerization” “IUPAC International Symposium on Ionic Polymerization” Paris, July 7-11, 1997. Ylide-Mediated Polymerizations of Methylmethacrylate. Aspects of Initiation and Termination Reactions.” December 15, 1997 "Anionic MMA Polymerization in Boiling THF" Mainz, Germany (with S. Juengling and A.H.E. Mueller) May 7, 1998, Tokyo Science University, Tokyo, Japan. “Enhanced Luminescence in Macrocyclic Polymers”.

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May 8, 1998, Tokyo Institute of Technology, Tokyo, Japan. “Hydrophobic Self-Assembly of Water-Soluble Polymers Containing Perfluorocarbon Groups”. May 12, 1998, Mitsubishi Rayon Co. Hiroshima, Japan. Living Polymerization of Methacrylates Mediated By Phosphor Ylides”. May 14, 1998, Kansai University, Osaka, Japan. “Hydrophobic Self-Assembly of Water-Soluble Polymers Containing Perfluorocarbon Groups". May 15, 1998, Osaka University, Osaka, Japan. “Hydrophobic Self-Assembly of Water-Soluble Polymers Containing Perfluorocarbon Groups". May 16, 1998, Osaka University, Osaka, Japan. “Living Polymerization of Methacrylates Mediated By Phosphor Ylides. May 18, 1998, Kyoto University, Kyoto, Japan. “Hydrophobic Self-Assembly of Water-Soluble Polymers Containing Perfluorocarbon Groups" May 20, 1998, Toagosei Co. Ltd., Nagoya, Japan. “Hydrophobic Self-Assembly of Water-Soluble Polymers Containing Perfluorocarbon Groups". May 21, 1998, Japan Synthetic Rubber Co. Yokaichi, Japan. ”Formation of Highly Isotactic Polystyrene by Anionic Polymerization”. May 21, 1998, Nagoya University, Nagoya, Japan. “Formation of Highly Isotactic Polystyrene by Anionic Polymerization” May 22, 1998, Nippon Zeon Co Ltd” Tokyo, Japan. “Living Polymerization of Methacrylates Mediated By Phosphor Ylides”. June 1, 1998, University of York, York, UK. “Excimer Fluorescence of Macrocyclic Polystyrene”. June 3, 1998, University of Birmingham, Birmingham, UK “Hydrophobic Self-Assembly of Water-Soluble Polymers Containing Perfluorocarbon Groups". June 19, 1998, Kodak Co., Rochester, NY, “Excimer Fluorescence of Macrocyclic Polystyrene” August 13, 1998, Lawrence Livermore National Laboratory, Livermore, CA. “Enhanced Excimer Fluorescence of Macrocyclic Polystyrene”. August 23 - 27, 1998. 216th ACS Meeting, Boston, “Complex Formation of β-Cyclodextrin and Perfluorocarbon-Modified Water Soluble Polymers.” August 23 - 27, 1998. 216th ACS Meeting, Boston, “Block Copolymerizations Aimed at Asymmetric Self-Assembly”. August 23 - 27, 1998. 216th ACS Meeting, Boston, “Synthesis of Block Copolymers Containing Main Chain NLO Segments”. August 23 - 27, 1998. 216th ACS Meeting, Boston, ACS Division of Division of Colloid and Surface Chemistry. “Fluorine-19 NMR Studie of Perfluorocarbon Derivativesof Polyethylene Glycols” December 8, 1998, USC Health Sciences Center. Pharmaceutical Sciences Center “Synthesis and properties of Water-soluble Polymers Containing Perfluorocarbon Groups” July 22, 1999, IUPAC International Symposium on Ionic Polymerization KYoto Japan. Invited Lecture “High Temperature Polymerization of Methylmethacrylate Mediated by Phosphor Ylides” (with W. Warner and D. Dimov) May 31, 1999, University of Louvain, Belgium. “Enhanced Luminescence in Macrocyclic Polymers”. May 18, 1999, University of Pisa, Italy “Unusual Excimer Emission of Macrocyclic Polystyrene”

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March 1999 Anaheim ACS Meeting March 1999 : S. Tomczak and T. E. Hogen-Esch “Polyacrylamides having Pendent Perfluorooctyl Groups. Effects of Temperature, Shear and the Presence Beta-cyclodextrin” J. Pan, M. Chen, M. He, L. Dalton and T. E. Hogen-Esch , “Toward the Synthesis of Block Polymer Copolymers Capable of H-Bond Mediated Self-Assembly”. W. N. Warner, D. K. Dimov and T. E. Hogen-Esch “Phosphor Ylide-Mediated Polymerization of Methyl Methacrylate at ElevatedTemperatures”. S. Carlotti and T. E. Hogen-Esch “Cationic Polymerization of Cyclic Ethers Initiated by Nafion”. M. Chen, J. Pan, M. He, L. R. Dalton and T. E. Hogen-Esch “Novel Block Copolymers Containing a NLO Chromophore.” S. Tomczak and T. E. Hogen-Esch “ Polyacrylamides having Pendent Perfluorooctyl Groups. Effects of Temperature, Shear and the Presence of Beta-cyclodextrin”. March 2000 San Francisco ACS Meeting: Alberty, K.; Hogen-Esch, T.E. “Novel Bifunctional Initiator for Anionic Vinyl Polymerizations”. Nossarev, G.G.; Hogen-Esch, T. E. “Anionic Polymerization of 2-Vinyl Naphthalene”.; Prakash,G.K.S.;Hu,J.;Olah,G.A.;Warner,W.;HogenEsch,T.E.“Triphenylmethyltrimethylsilyl/tetramethylammonium fluoride as a Metal-Free Anionic Polymerization Initiating System”; Tomczak, S.; Hogen-Esch, T.E. “Complex Formation of Beta-Cyclodextrin in Aqueous Media withPoly (N,N-dimethylacrylamide) Containing Pendent Perfluorooctylsulfonamido Groups.” Hogen-Esch, T.E.; Pan, J.; Chen, M.; Dalton, L. R.; Warner, W.; He, M. “Synthesis of Block Copolymers Containing a Main Chain Polymeric NLO Segment” ; Pan, J.; Hogen-Esch, T.E.; Chen, M.; Warner, W.; Dalton, L. R. “Hydrogen Bond-Mediated Self-Assembly of Block Copolymers Containing NLO Segments”. Thirtyeighth IUPAC Symposium, Warsaw Poland July 9-14th, 2000. Alberty, K Hogen–Esch, T. E. “A New Bifunctional Initiator for Anionic Vinyl Polymerization” August 20-25, 2000 Washington 220 th ACS meeting. Tillman, E. S. and Hogen –Esch, T. E. “Coupling reactions of Polystyryllithium with Bibromomethane. Comparisons with other dihalomethanes. February 22-23, 2001, Bordeaux France ”Synthesis and Properties of Macrocyclic Poly(2-vinylnaphthalene)” (G. G. Nossarev coauthor). Symposium honoring Professor Michel Fontanille. April 1-5th2001, 220 th ACS meeting, San Diego, CA.: Kurt Alberty, Eric Tillmana, Stephane Carlottia, Stephen E. Bradforth, and Thieo E Hogen-Escha“Formation of Cyclic Polystyrene by Anionic Polymerization: Fluorescence Studies” April 1-5th2001, 220 th ACS meeting, San Diego.: Gennadi G. Nossarev and Thieo E. Hogen-Esch “Living Anionic Polymerization of 2-Vinylnaphthalene in the Presence of Potassium Ion” April 1-5th,2001, 220 th ACS meeting, San Diego, CA.: Eric S. Tillman And Thieo E. Hogen-Esch “Evidence For Styrenic Structures In Polystyrene Dimers Formed With Dibromomethane” April 1-5th,2001, 220 th ACS meeting, San Diego, CA.: Gennadi G. Nossarev and Thieo E. Hogen-Esch “Synthesis And Characterization Of Macrocyclic Poly(2-Vinylnaphthalene)”

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April 1-5th,2001, 220 th ACS meeting, San Diego, CA.: Sandra Tomczak And Thieo E. Hogen-Esch “Poly(N,N-Dimethylacrylamide) Containing Pendent Perfluorooctyl Groups. Reversible Hydrogel Formation With Beta-Cyclodextrin And Sodium 1-Adamantanecarboxylate.” April 1-5th,2001, 220 th ACS meeting, San Diego, CA.: Gennadi G. Nossarev and Thieo E. Hogen-Esch“ Li Ion Mediated Anionic Polymerization of 2-Vinylnaphthalene in Toluene/THF ” April 1-5th,2001, 220 th ACS meeting, San Diego, CA.: William N. Warner And Thieo E. Hogen-Esch “Formation Of A Pure Tail To Tail Dimer Of 4-(N,N-Dimethylamino)Styrene. Block Copolymers With Styrene” April 1-5th,2001, 220 th ACS meeting, San Diego, CA.: Xi Zhang And Thieo E. Hogen-Esch, “Anionic Synthesis Of Polmers Of 9,9-Dimethyl-2-Vinyl-Fluorene, 9-Methyl-9-Trimethylsilyl-2-Vinylfluorene And 9-Methyl-2-Vinylfluorene” April 1-5th,2001, 220 th ACS meeting, San Diego, CA.: A. C. Germaine, J. A. Kloepfer, X. Zhang, K. Alberty , T. E. Hogen-Esch , S. E. Bradforth “Spectroscopic Investigation of Macrocyclic Poly(9,9-dimethylfluorene) as an Artificial Light Harvester” J. M. Johnson,. IUPAC International Symposium on Ionic Polymerization (IP 2001),Crete, Greece, October 22-26, 2001: Gennadi G. Nossarev, Xi Zhang, Eric S. Tillman, Jerainne Johnson , Stephen E. Bradforth and Thieo E. Hogen-Esch* “Synthesis Of Light Harvesting Macrocyclic Polymers Containing Pendent Donors And A Single Energy Acceptor. Energy Transfer Studies”. Invited Lecture. Seventh Pacific Polymer Coference Oaxaca Mexico December 3-7, 2001. Gennadi G. Nossarev and Thieo E. Hogen-Esch, “Living Polymerization Of 2-Vinylnaphthalene. Synthesis And Properties Of Macrocyclic Poly(2-Vinylnaphthalene. Invited Lecture. Department of Chemistry UC Santa Cruz Monday, May 13, 2002 “Synthesis, Characterization and Fluorescence of Macrocyclic Vinylaromatic Polymers" Boston ACS Meeting, August 18-22, 2002. Rong Chen and Thieo E. Hogen-Esch “Synthesis And Characterization Of Macrocyclic Poly(4-N,N-Dimethylaminostyrene)” Boston ACS Meeting, August 18-22, 2002. Ching-An Peng, Jie Da, Yu-Chih Hsu and Thieo E. Hogen-Esch, “Macrophage Response to Perfluorocarbon Emulsions Mediated by Polymeric Fluorosurfactants” Akron Ohio November 8th 2002. Michael Szwarc Memorial Symposium “Michael Szwarc in Syracuse and Beyond. Mechanisms of Anionic Polymerization” (Invited Lecture.) Akron Ohio November 8th 2002. Michael Szwarc Memorial Symposium “Michael Szwarc: Biography and Personal Remembrances”. Invited Presentation. Department of Chemistry U C Berkeley , Berkeley CA February 6th, 2002 “Synthesis, and Properties of Macrocyclic Vinylaromatic Polymers" New Orleans ACS meeting Sproing 2003, Rong Chen and Thieo E. Hogen-Esch “Synthesis And Spectroscopic Studies Of Macrocyclic Poly (9,9-Dimethyl-2-Vinylfluorene)”. New Orleans ACS meeting Sproing 2003 Jie Da and Thieo E. Hogen-Esch “Gel formation in Organic Solvents: Synthesis and Association Of Copolymers Of N,N-Dimethylacrylamide and Methacrylates Having Perfluorocarbon Pendent Groups Connected Through Polyethyleneoxide Spacers”. The 2003 Technical Conference Los Angeles Rubber Group May 7th 2003 “Synthesis of New Elastomers Using Carbanion and Radical Chemistry”

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French Polymer Symposium, Montpellier , France , June 6th 2003, " Self-Assembly of Copolymers of N,N-Dimethylacrylamide and Methacrylates Having Perfluorocarbon Pendent Groups Connected Through Long Polyethyleneoxide Spacers". Role of Spacer Length" University of Toulon , Toulon, France May 27th” 2003 “ Association of Water-Soluble Polymers Mediated by Pendent Perfluorocarbons Tethered by Polyethylene glycols. University of Toulon , Toulon, France May 30th, 2003 “ Synthesis and Fluorescence of Macrocyclic Vinylaromatic Polymers” University of Toulon , Toulon , France, June 4th 2003 “Recent Advances in Living Anionic Vinyl Polymerization” . Universite de Bordeaux, Boredeaux, France June 11th 2003 “Perfluorocarbon –Mediated Association of Water-Soluble Vinyl Copolymers” CNRS, Thiais, France June 12th 2003"Self-Assembly of Water –Soluble Copolymers Having Perfluorocarbon Pendent Groups Connected Through Polyethyleneoxide Spacers. The 26th Annual International Conference of the IEEE Engineering in Medicine and Biology Society San Francisco, CA, September 1-5, 2004. Sencil Project: Development of a Percutaneous Optical Biosensor, Liao, Kuo Chih; Richmond, Frances J.; Hogen-Esch, Thieo; Marcu, Laura; Loeb, Gerald E.; University of Southern California (1177) Universite de Toulon et du Var October 11 th 2004 “Association of Perfluorocarbon-Containing Polymers in Aqueous and Non Aqueous Solvents” Universite de Toulon et du Var October 13 th 2004 “ Emission Of Macrocyclic Vinylaromatic Polymers” Washington ACS Meeting August 2005. Shen, J-G; Hogen-Esch, T. E. “ Synthesis And Characterization Of Poly 2-phenyl-5-(4-vinylphenyl)-1,3,4-oxadiazole Using Atom Transfer Radical Polymerization.” USC Stauffer Symposium: April 6th 2005: Emission of Macrocyclic Vinylaromatic Polymers” . ACS Spring. 2006 National Meeting, Atlanta. Ga. Hong H.; Thompson M. E.; Zhang X.;. Hogen-Esch T. E “Poly (9,9-Dimethyl-2-vinyfluorene) as efficient hole transporters in the Organic Light Emitting Diode (OLED)” USC Stauffer Symposium April 8th 2006 : Fomina, N.; Hogen-Esch T. E. Madhusoodhanan S. Thompson. M “Synthesis and end-capping of poly(9,9'-dihexyl-2,7-fluorenes)”. ACS National Meeting, September 10-15th 2006 San Francisco, CA Ling, J.; Hogen-Esch, T. E. “Phosphor Ylide Mediated Polymerizations of MMA at Ambient Temperatures with Quantitative Initiator Efficiencies” ACS National Meeting, September 10-15th 2006 San Francisco, CA Fomina, F.; Hogen-Esch, T. E. “End-capping of Poly-9,9’-dihexylfluorenes” Clark Atalanta University Atlanta February 20th 2007. Synthesis and Properties of Perfluorocarbon –Containing Polymers. Summer Undergraduate Research Poster Session 8/2007, University of Southern California Yurdacan, H. M.; Shen, J.; Hogen-Esch T.E. “Self Assembly Behavior of perfluorocarbon end-functionalized Poly (styrene) and Poly(n-butyl methacrylate) blends”

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USC Stauffer Symposium: Fomina, N.; Hogen-Esch T. E. Madhusoodhanan Rasul, G.; S. Thompson. M. April 10th 2007:Kinetic studies of Ni(0) catalyzed polymerization of 2,7-dibromofluorenes: chain length dependent reactivity Univerisité de Paris Jusssieux, France , June 3rd 2009. "Synthesis and Luminescence of Macrocyclic Vinylaromatic Polymers". Université de Montpelleir, France, June 5th 2009 “Synthesis and Properties of Perfluorocarbon -Functionalized Vinyl Polymers”. Université de Toulon et du Var , France , June 6th, 2009 “Synthesis and Mophologies of Perfluorocarbon -Functionalized Vinyl Polymers”. Zhejiang University, Hanzhou PRC, May 11th , 2010 “Blends of Vinyl Polymers End-Functionalized with Perfluorocarbon Groups" Zhejiang University, Hanzhou PRC, May 13th , 2010 “Personal Perspectives on Anionic Vinyl Polymerization”. Li, M; Fakrho; Hogen-Esch, T. E. "Fuel Cell Membranes by Sulfonation of Polyvinylidene/Polystyrene and Perfluorocarbon Modified Polystyrene Copolymer Blends” USC Dept of Chemistry REU Poster presentation August 2010. Institute of Organic Chemistry Academia Sinica, Shanghai PRC May 17th 2010. "Fluorophilic Interactions in Blends of Vinyl Polymers End-Functionalized with Perfluorocarbon Groups" Fluoropolymer Symposium 2010, Meze, France June 15th 2010 “Blends of Polystyrene and Polybutylmethacrylate End -Functionalized with Perfluorocarbon Groups” Department of Chemistry University of Minnesota, Minneapolis, Minnesota July 5th 2010 “Fluorophilic Interactions in Polymer Solutions and Polymer Blends" ACS Western Division Meeting November 11-10, 2011. Pionova, V. Hogen-Esch, T. E. “Polymer Blends Based on Perfluorocarbon Interactions”

“Mechanical Properties of perfluorocarbon-end functionalized Poly(styrene) and Poly(n-butyl methacrylate) blends” Yurdacan, H. M.; Zhang Y. ; Shen, J.; Nutt, S. ; Hogen-Esch T.E. 39th John Stauffer Lecture Poster Session 2011, University of Southern California “Mechanical Properties of perfluorocarbon end- or pendent- functionalized Polystyrene by Nanoindentation Measurements” Yurdacan, H. M.; Franke, O.; Nutt, S.; Hogen-Esch T. E. Southern California Society for Microscopy and Microanalysis Poster Session 4/ 2012. California Technology Institute of Technology Mechanical Properties of Perfluorocarbon Functionalized Polystyrene. Yurdacan, H. M.; Franke, O.; Nutt, S.; Hogen-Esch T. E. 40th John Stauffer Poster Session 4/12/2012, University of Southern California. Fakhro Y. G., Li M. ; Hogen-Esch T. E. * “Fuel Cell Membranes by Sulfonation of Polyvinylidenefluoride/Polystyrene and Perfluorocarbon Modified Polystyrene Copolymer Blends”. REU Presentation USC August 1st, 2012. Piunova, V.; Shen, J-G; Hogen-Esch, T. E. “Blends of Perfluorocarbon End-Functionalized and Telechelic Polystyrene/Poly N-Butyl Methacrylate: Synthesis and morphology studies”. 244th National Meeting American Chemical Society, Division of Materials Science National Meeting Philadelphia August 19-23rd, 2012.

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Olsen J.; Hogen-Esch T. E. “Synthesis of Alkyene-Functionalized Helicenes as Building Blocks in π-Conjugated Polymers”. 245th National Meeting of the American Chemical Society, New Orleans, LA, April 7-11, 2013. Yurdacan, H.M.; Franke, O.; Nutt, S.; Hogen-Esch, T.E. “Mechanical Properties of Perfluoroalkyl End- or Pendent-Functionalized Polystyrene by Nanoindentation Measurements” Abstract 245th National ACS meeting New Orleans, LA. April 7-11th 2013. Shen J., Piunova V., Yurdacan M., Zhang Y.; Oliver, F.; Nutt, S. Hogen-Esch T. E. “Morphologies of Blends of Perfluorocarbon End- Functionalized Polystyrene and Polybutylmethacrylate. Mechanical Properties of Perfluorocarbon Functionalized Polystyrene”. European Polymer Federation Symposium, Pisa Italy, June 18, 2013. G. G. Nossarev , J. Johnson , S. E. Bradforth and T. E. Hogen-Esch. “Observation of Two Excimer Populations in Macrocyclic and Linear Poly(2-vinylnaphthalene)” . European Polymer Federation Symposium, Pisa Italy, June 19, 2013.

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Refereed Publications 1. T.E. Hogen-Esch and J. Smid, Solvent-Separated Ion Pairs of Carbanions, J. Am.

Chem. Soc., 87, 669 (1965). 2. T.E. Hogen-Esch and J. Smid, Studies of Contact and Solvent-Separated Ion Pairs of

Carbanions. I. Effect of Temperature, Counterion and Solvent, J. Am Chem. Soc., 88, 307 (1966).

3. T.E. Hogen-Esch and J. Smid, Studies of Contact and Solvent-Separated Ion Pairs. II.

Conductivities and Thermo-Dynamics of Dissociation of Fluorenyllithium Sodium and Cesium, J. Am. Chem. Soc., 88, 318 (1966).

4. T.E. Hogen-Esch and J. Smid, Contact and Solvent-Separated Ion Pairs of

Carbanions. III. Reactivities in Proton Abstraction Reactions, J. Am. Chem. Soc., 89, 2764 (1967).

5. T.E. Hogen-Esch and J. Smid, Ion Pair Structures of Divalent Carbanion Salts, J. Am.

Chem. Soc., 91, 4580 (1969). 6. S. Kopolow, T.E. Hogen-Esch and J. Smid, Cation-Binding Properties of Polyvinyl

Macrocyclic Polyethers, Macromolecules, 4, 359 (1971). 7. U. Takaki, T.E. Hogen-Esch and J. Smid, Complexes of Macrocyclic Polyethers and

Ion Pairs, J. Am. Chem. Soc., 93, 6760 (1971). 8. U. Takaki, T.E. Hogen-Esch and J. Smid, Ion Pair Aggregation in Solutions of

Complexes of Carbanion Salts and Macrocyclic Polyethers, J. Phys. Chem., 76, 2151 (1972).

9. T.E. Hogen-Esch and J. Smid, Stepwise Solvation of Strontium Carbanion Salts in

Tetrahydrofuran, J. Am. Chem. Soc., 94, 9240 (1972). 10. T.E. Hogen-Esch, UV-Vis Spectroscopic Evidence for Hydrogen Bonded Alkali-

Carbanions n Protic Media. J. Am. Chem. Soc., 95, 639 (1973). 11. T.E. Hogen-Esch and J. Smid, Poly(vinyl macrocyclic polyethers), Synthesis and

Cation Binding Properties. Macromolecules, 6, 133 (1973). 12. C.J. Chang, R.F. Kiesel and T.E. Hogen-Esch, Specific Cation Catalysis in Base-

Initiated Cyclic Ether Cleavage Reactions, J. Am. Chem. Soc., 95, 8446 (1973). 13. M.J. Plodinec and T.E. Hogen-Esch, Ion Pairing in Excited States of Carbanions. I.

Cation and Solvent Effects, J. Am. Chem. Soc., 96, 5262 (1974). 14. C.J. Chang, R.F. Kiesel and T.E. Hogen-Esch, UV/Vis and Conductometric Studies

of Vinyl-pyridine Type Carbanions in Aprotic Media, J. Am. Chem. Soc., 97, 2805 (1975).

15. T.E. Hogen-Esch and J. Smid, Conductivities and Thermodynamics of Dissociation

of Fluorenyl Salts and Their Complexes with Dibenzo-18-crown-6, J. Am. Chem. Soc., 79, 233 (1975).

21

16. C.J. Chang and T.E. Hogen-Esch, Effect of Ion Pair Structure on the Equilibrium Addition of Carbanions to Substituted Vinyl-pyridines, Tetrahedron Lett., 5, 323 (1976).

17. T.E. Hogen-Esch and M.J. Plodinec, The Structure of Carbanion Aggregates. I.

Absorption and Emission Spectra of Bisfluorenyl-Barium and Its Crown Ether Complex in Tetrahydrofuran and Tetrahydropyran, J. Phys. Chem., 80, 1085 (1976).

18. T.E. Hogen-Esch and M.J. Plodinec, The Structure of Carbanion Aggregates. II.

Fluorescence Spectra of Fluorenyl Sodium and Cesium in Dioxane and Fluorenyllithium in Dioxane and Toluene, J. Phys. Chem., 80, 1090 (1976).

19. C.F. Tien and T.E. Hogen-Esch, Stereoselective Synthesis of a 2-Vinyl-pyridine

Dimer, Macromolecules, 9, 871 (1976). 20. C.F. Tien and T.E. Hogen-Esch, Oligomerization Stereochemistry of Vinyl

Monomers. II. Effect of Ion Pair Structure on the Methylation Stereochemistry of 1,3-Di(2-pyridyl) butane Anion, J. Am. Chem. Soc., 98, 7109 (1976).

21. T.E. Hogen-Esch, K.R. Shah and C.R. Fitzgerald, Development of Injectable

Poly(glycerylmethacrylate) Hydrogels for Vitreous Prostheses, J. Biomed. Mater. Res., 10, 975 (1976).

22. T.E. Hogen-Esch and C.F. Tien, The Anionic Oligomerization Stereochemistry of

Some Vinyl Monomers. Int. Symp. on Macromolecules, Dublin, Ireland, Vol. I, II (1977).

23. T.E. Hogen-Esch and M.J. Plodinec, S. Schulman and M. Vala, Spectrophotometric

Evidence for Aggregation of Fluoradene, an Aromatic Hydrocarbon, in Alcohols. Chem. Phys. Emission Ltrs., 50 (I), 120 (1977).

24. T.E. Hogen-Esch, Ion Pairing Effects in Carbanion Reactions. Advances in Phys.

Org. Chem., Vol. 15, 153, (l978), V. Gold and D. Bethell, Eds. 25. G.L. Collins, T.E. Hogen-Esch and J. Smid, Effect of Chain Length on the Glyme

Separated Ion Pair Formation in Bola Form Salts (9-Fluorenyl) polymethylenes, J. Sol. Chem., 7, 9 (1978).

26. C.F. Tien and T.E. Hogen-Esch, Oligomerization Stereochemistry of Vinyl

Monomers. 3. The Stereoselective Anionic Oligomerization of 2-Vinylpyridine in THF, J. Polym. Sci., B16, 297 (1978).

27. W.L. Jenkins, C.F. Tien and T.E Hogen-Esch, Oligomerization Stereochemistry of

Vinyl Monomers. 4. Ion Pair Structure and Carbon Stereochemistry in Anionic Oligomerization of 2-Vinylpyridine. J. Polym. Sci., B16, 501 (1978).

28. T.E. Hogen-Esch and M.J. Plodinec, Ion Pairing in Excited States of Carbanions. 2.

Cation, Solvent and Carbanion Effects on the Emission and Excitation Spectra of Fluorenyl & Fluoradenyl Alkali Salts in Ether and Alcohols. J. Am. Chem. Soc., 100, 7633 (1978).

22

29. W.L. Jenkins, C.F. Tien and T.E. Hogen-Esch, Stereochemical Effects of Ion Pairing in Anionic in Anionic Vinyl Oligomerization and Related Carbanion Reactions. J. Pure Appl. Chem., 51, 139 (1979).

30. T.E. Hogen-Esch and C.F. Tien, Oligomerization of Vinyl Monomers. 5. Methyl-,

Isopropyl- and t-Butyl Acrylates. J. Polym. Sci., 17, 281 (1979). 31. T.E. Hogen-Esch and C.F. Tien, Stereochemistry of Anionic Oligomerization of

Vinyl Monomers. VI. Low Molecular Weight Stereoregular Polymers of 2-Vinylpyridine Prepared with Li Salts as Initiators in THF. J. Polym. Sci., Polym. Ltrs. Ed., 17, 431 (1979).

32. T.E. Hogen-Esch and C.F. Tien, Oligomerization Stereochemistry of Vinyl

Monomers. 7. Diastereomeric Ion Pairs as Intermediates in the Stereoregular Anionic Oligomerization of 2-Vinylpyridines. A Proposed Mechanism. Macromolecules, 13, 207 (1980).

33. W.L. Jenkins, R.A. Smith, C.F. Tien and T.E. Hogen-Esch, In Pair Effects on the

Anionic Oligomerization Stereochemistry of Vinylpyridines and Related Monomers. In "Preparation and Properties of Stereoregular Polymers", R.W. Lenz and F. Ciardelli, Eds. Reidel Pub. Co., Boston, 1980, pp. 191 to 194.

34. J.J. Meister, H. Pledger, Jr., T.E. Hogen-Esch and G.B. Butler, Retention of

Polyacrylamide by Berea Sandstone, Baker Dolomite and Sodium Kaolinite During Polymer Flooding. Soc. of Petroleum Engrs., Paper #SPE8981, Presented at the 5th Intern'l Symp. on Oil Field and Geothermal Chem., Stanford, CA, 1980.

35. T.E. Hogen-Esch and W.L. Jenkins, Oligomerization Stereochemistry of Vinyl

Monomers. 8. Beta-Carbon Stereochemistry and Carbanion Structure in the Oligomerization of 2- and 4-Vinylpyridines. Macromolecules, 14, 510 (1989).

36. T.E. Hogen-Esch, R.A. Smith, D. Ades and M. Fontanille, Stereochemistry of

Anionic Oligomerization of Vinyl Monomers. 9. Preparation of Stereoregular Oligomers of 2-(2-Pyridyl)propene. J. Polym. Sci., Polym. Ltrs. Ed., 19, 309 (1981).

37. Pledger, H; Meister, J.J.; Hogen-Esch, T.E; Butler, G.B. Starch-Acrylamide Graft-

Copolymers For Use In Enhanced Oil-Recovery Abstracts Of Papers Of The American Chemical Society Volume: 182, 52-53, 1981

38. Y. Abe, G.B. Butler and T.E. Hogen-Esch, Ultraviolet Degradation of

Octamethylcyclotetrasiloxane and Related Compounds. J. Macromol. Sci. Chem., A16, (2), 461 (1981).

39. T.E. Hogen-Esch and W.L. Jenkins NMR and Conductometric Studies of 2-Pyridyl-

Substituted Carbanions. 2. Effects of Cation Size and Coordination. J. Am. Chem. Soc., 103, 3666 (1981).

40. T.E. Hogen-Esch, W.L. Jenkins, R.A. Smith and C.F. Tien, Ion Pair Structure and

Stereochemistry in Anionic Oligomerization and Polymerization of Some Vinyl Monomers. ACS Symp. Series, 166, Ch. 16, 1981, p. 231-238.

23

41. S.S. Huang, C. Mathis and T.E. Hogen-Esch, Oligomerization of Vinyl Monomers. 10. C-13 NMR and Chromatographic Studies of Oligomers of 2-Vinylpyridine. Macromolecules, 14, 1802 (1981).

42. C. Mathis and T.E. Hogen-Esch, Evidence for a Conformationally Restrained Six-

Membered Ring-Containing Lithium Ion. J. Am. Chem. Soc., 104, 634 (1982). 43. P.D. Avenel, D. Ades, R.A. Smith and T.E. Hogen-Esch, Structure d'un Tetramere de

(Pyridyl-2)-2-Propene [Tetramethyl-2,4,6,8-Tetra(pyridyl-2)-2,4,6,8-Nonane]. Acta Cryst. B38, 1611 (1982).

44. M.A. Buese and T.E. Hogen-Esch, The Dimerization of Vinylphenylsulfoxide as a

Model to Elucidate the Stereochemistry of Poly(vinylphenylsulfoxide), Stereoelectivity and Stereoselectivity. Proc. IUPAC 28th Macromolecular Symp., Amherst, MA July 12-16, 1982, p. 131.

45. T.E. Hogen-Esch, C. Mathis, S.S. Huang and C. Meverden, Oligomerization of Vinyl

Monomers, A Tool in the Elucidation of Polymer Stereochemistry. Proc. IUPAC 28th Macromolecular Symp., Amherst, MA, July 12-16, 1982, p. 209.

46. G.B. Butler, T.E. Hogen-Esch, H. Pledger, Jr. and J.J. Meister, Water-Soluble Graft

Copolymers of Starch-Acrylamide and Uses Thereof. U.S. Patent #188,999, Aug. 23, 1983.

47. A.H. Soum, C.F. Tien and T.E. Hogen-Esch, N. D'Accorso, and M. Fontanille,

Stereoregular Anionic Polymerization of 2-Isopropenylpyridine. Makromol. Chem., Rapid Comm., 4, 243 (1983).

48. S.S. Huang, A.H. Soum and T.E. Hogen-Esch, Stereochemical Kinetics of Anionic

Vinyl Polymerization. I. Trapping of Stereoisomeric Anions in the Polymerization of 2-Vinylpyridine. J. Polym. Sci., Polym. Ltrs. Ed., 21, 559 (1983).

49. I.M. Khan and T.E. Hogen-Esch, Oligomerization of Vinyl Monomers. 15. 1H and

13C NMR Studies of Carbanion Intermediates in the Polymerization of 2-Vinylpyridines in THF. Dimeric and Trimeric Models. Makromol. Chem. Rapid Comm., 4, 569 (1983).

50. K. Hashimoto and T.E. Hogen-Esch, Oligomerization of Vinyl Monomers. 12.

Anionic Oligomerization of 4-Isopropenylpyridine, Preparation and 1H NMR Spectroscopic Analysis of Stereoisomeric Oligomers. Macromolecules, 16, 1805 (1983).

51. K. Hashimoto and T.E. Hogen-Esch, Oligomerization of Vinyl Monomers. 13.

Anionic Oligomerization of 2- and 4-Isopropenylpyridine. Stereoselectivity of Monomer Addition and Methylation Determined by End Group 13C Labels. Macromolecules, 16, 1809 (1983).

52. C.C. Meverden and T.E. Hogen-Esch, Oligomerization of Vinyl Monomers. 14.

Thermodynamics of Intramolecular Cation Coordination in the Anionic Oligomerization of 2-Vinylpyridine. Makromol. Chem. Rapid Comm., 4, 563 (1983).

24

53. H. Vankerckhoven, F.C. DeSchrijver, M. VanBeylen and T.E. Hogen-Esch, Adsorption and Emission of Alkaline Earth Carbanion Salts in Ethers, J. Chem. Soc., Perkin Trans. II, 383 (1984).

54. M.A. Buese and T.E. Hogen-Esch, Oligomerization of Vinyl Monomers. 16.

Stereoselection and Stereoelection in the Anionic Dimerization of Vinylphenylsulfoxide. Macromolecules, 17, 118 (1984).


Studies of Side Reactions Occuring in Oligomeric Models of "Living" Poly(2 vinylpyridine). Makromol. Chem. Rapid. Comm., 5, 749 (1984).

56. M.A. Doherty and T.E. Hogen-Esch, Synthesis and Properties of Stereoblock

PMMA. Polym. Preprints, 25 (2), 5 (1984), Philadelphia, PA, Nat'l ACS Meeting. 57. G. Belorgey, A. H. Soum and T.E. Hogen-Esch, Study of Thermal Properties of

Stereoregular Poly(2- isopropenyl pyridine) Oligomers and Polymers. Polym. Comm., 26, 315 (1985).

58. H. Pledger, Jr., T.S. Young, G-S. Wu, G.B. Butler and T.E. Hogen-Esch, Synthesis

and Characterization of Water-Soluble Starch-Acrylamide Graft Copolymers. J. Macromol. Sci. Chem., (1985).A22 (4), 413.

59. T.S. Young, X. Yan, T.E. Hogen-Esch, and G.B. Butler, Measurement of

Hydrodynamic Sizes of Ultra-Large Water-Soluble Polymers by Nucleopore Filtration and Multi-Cell Equilibrium Dialysis. J. Macromol. Sci. Chem., A22, 437 (1985).


Stereochemistry of Anionic Oligomerization of 4-Vinyl-pyridine. J. Polym. Sci. Chem. Ed., 23, 159 (1985).

61. H. Pledger, Jr., G-S Wu, T.S. Young, T.E. Hogen-Esch and G.B. Butler, Graft

Copolymerizations of Polysaccharides. II. Acrylamides Grafting to Yellow Dextrin. J. Macromol. Sci. Chem., A22 (9), 1297(1985).

62. A.H. Soum and T.E. Hogen-Esch, Stereochemical Kinetics of Anionic Vinyl

Polymerization. 2. Carbon-13 NMR Analysis of Poly(2- and 4 vinylpyridine) Terminated with Labeled End Groups. Macromolecules, 18 (4), 690 (1985).

63. M.A. Buese and T.E. Hogen-Esch, Oligomerization of Vinyl Monomers. 17.

Stereoselective Methylation of I-Lithio-1,3-di(phenylsulfinyl)butane. Kinetic vs. Thermodynamic Control in the Formation of Diastereomeric Ion Pairs. J. Am. Chem. Soc., 107, 4509 (1985).

64. S.S. Huang and T.E. Hogen-Esch, Oligomerization of Vinyl Monomers. 20. Carbon-

13 NMR of Oligomers of 2- Vinylpyridine Studies of Labeled Compounds. J. Polym. Sci. 23 (4), 1203 (1985).

65. M.A. Doherty and T.E. Hogen-Esch, Synthesis and Characterization of Stereoblock

Polymethyl Methacrylate. B Advances in Polymer Synthesis. M. Culbertson, J.E. McGrath, Eds., Plenum Press, 31, 363 (1985).

25

66. M.A. Doherty and T.E. Hogen-Esch, Synthesis of Stereoblock PMMA. Makromol.

Chem., 187, 61 (1986). 67. A. Aboudalle, A. Soum, M. Fontanille and T.E. Hogen-Esch, Equilibrium Anionic

Polymerization of 2-Isopropenyl Pyridine: Kinetic and Thermodynamic Aspects. Makromol. Chem., Rapid Comm., 7, 671 (1986).

68. M. Takaki, R. Asmi, S. Tanaka, H. Hayashi and T.E. Hogen-Esch, Preparation of (p-

Vinylbenzyl) poly(2-vinylpyridine) Macromers. Macromolecules, 19, 2900 (1986). 69. H. Yajima, K. Kato, Y. Murato, T. Ishii and T.E. Hogen-Esch, Excimer Emission of

Protonated 2,4-Di(2-pyridyl) Pentane in Solution. Reports Prog. Polym. Phys., Jampan, XXIX, 515 1986.

70. M.A. Buese and T.E. Hogen-Esch, Anionic Oligomerization and Polymerization of

Vinyl Monomers. 21. Stereoelection and Stereoselectivity in the Anionic Polymerization of Vinyl Sulfoxide. Macromolecules, 20, 1509 (1987).

71. M.A. Buese and T.E. Hogen-Esch, Stereoelective Vinyl Polymerization of Chiral

Sulfoxides via Interconverting Ion Pair Epimers. Chapter 16 in "Recent Advances in Anionic Polymerization", T.E. Hogen-Esch and J. Smid, Eds., Elsevier Publ. Co., New York, NY, 1987.

72. M.A. Buese and T.E. Hogen-Esch, W-Y. Xu and J. Smid., Related Affinities of

Mono and Difunctional Sulfoxides for Lithium Picrate in Toluene. Effects of Structure and Stereochemistry. Makromol. Chem., 188, 1631 (1987).

73. I.M. Khan and T.E. Hogen-Esch, Synthesis and Stereochemical Characterization of

Isotactic Poly(3-methyl-2-vinylpyridine). Macromolecules, 20, 2335 (1987). 74. A. Aboudalle, A. Soum, M. Fontanille and T.E. Hogen-Esch, Kinetics and

Thermodynamics of Anionic Polymerization of 2- Isopropenylpyridine. Chapter 9 in "Recent Advances in Anionic Polymerization", T.E. Hogen-Esch and J. Smid, Eds., Elsevier Publ. Co., New York, NY, 1987.

75. I.M. Khan and T.E. Hogen-Esch, Role of E- and Z-Carbanions in the Stereochemistry

of Anionic Vinyl Polymerization. Chapt. 18 in "Recent Advances in Anionic Polymerization", T.E. Hogen-Esch and J. Smid, Eds., Elsevier Publ. Co., New York, NY, 1987.

76. T.E. Hogen-Esch, Book Review of "Processing Structure and Properties of Block

Copolymers", M.J. Folkes, Ed., Elsevier Applied Sci. Publ., London, NY, 1985. J. Am. Chem. Soc., 109, 6567 (1987).

77. A.H.E. Mueller and T.E. Hogen-Esch, Stereochemistry of Anionic Vinyl

Polymerization. Effect of Ion Pair Prochirality on Chain Statistics. Macromolecules, 21, 2336 (1988).

78. I.M. Khan and T.E. Hogen-Esch, Characterization of Carbanions in THF by

Conductance and 7 Li NMR. Evidence for the Occurrence and Nature of Triple Ion Formation. J. Polym. Sci., 26, 2553 (1988).

26

79. J-C. Chen, Y-X. Zhang, D. Patil, G.B. Butler and T.E. Hogen-Esch, Synthesis and Characterization of 2,3-Dihydroxypropyl Cellulose. J. Macromol. Sci., A25 (8), 955 (1988).

80. J-C. Chen, Y-X. Zhang, D. Patil, G.B. Butler and T.E. Hogen-Esch, Synthesis of 2,3-

Dihydroxypropyl Cellulose-g-Polyacryl Amide Graft Copolymers. J. Macromol. Sci., A25 (8), 971 (1988).

81. Dong G. Helary, M. Fontanille, I.M. Khan and T.E. Hogen-Esch, Stereochemistry of

Anionic Oligomerization. 22. Effects of Chain Length and Stereochemistry on the Kinetics of Addition of 1,1-Diphenyl-ethylene to Oligomeric Models of Living Poly-(2-vinylpyridine) Lithium. Makromol. Chem., 190, 341-348 (1989).

82. Y-X. Zhang, A-H. Da, Y-C. Chen, G.B. Butler and T.E. Hogen-Esch, Synthesis and

Solution Properties of Water-Soluble Sulfonated Cellulose-Based Polymers and Their Polyacrylamide Graft Copolymers. J. Macromol. Sci., A 27 (5), 593 (1990).

83. Zhang Y-X., Da A-H., Hogen-Esch T.E., A Fluorocarbon-Containing

Hydrophobically Associating Polymer. J. Polym. Sci., C. Polym. Lett. 1990, 28, 213-218.

84. R. Volpe and T.E. Hogen-Esch, Oligomerization of Vinyl Monomers. 24. Anionic

Oligomerization of MMA in Tetrahydrofuran and Toluene. Macromolecules, 23, 4196 (1990).

85. R.S. Kanga, T.E. Hogen-Esch, E. Rancerian, A. Soum and M. Fontanille, Studies of

the Anionic Polymerization of Phenylvinylsulfoxide and Its Copolymers with Styrene. Macromolecules, 23, 4235 (1990).

86. R.S. Kanga, T.E. Hogen-Esch, E. Rancerian, A. Soum and M. Fontanille, Thermal

Elimination of Poly(phenyl-vinylsulfoxide) and Its Block Copolymers. Macromolecules, 23, 4241 (1990).

87. Y-X Zhang, A-H Da, G.B. Butler and T.E. Hogen-Esch, Water-Soluble Graft

Copolymer of 2,3-Dihydroxypropylcellulose With Acrylamide and Sodium 2-Acrylamido-2-methylpropane Sulfonate. Proceed. 33rd IUPAC Symp. Macromolecules, 1990.

88. T.E. Hogen-Esch and B.J. Ladd, Synthesis and Properties of Polybutadiene-

Syndiotactic PMMA. Block- and Star-Block Copolymers. Proceed. 33rd IUPAC Symp. Macromolecules, 1990.

89. T.E. Hogen-Esch and J.P. Mason, Synthesis and Stereocomplex Formation of

Polydimethylsiloxane-PMMA Block- and Star-Block-Copolymers. Proceed. 33rd IUPAC Symp. Macromolecules, 1990.

90. J. Baumgarten, A.H. Mueller and T.E. Hogen-Esch, Determination of E/Z and Meso-

Racemic End Group Stereochemistry in the Anionic Polymerization of Methylmethacrylate in THF. Macromolecules 24, 353 (1991).

91. T.E. Hogen-Esch, J. Sundararajan and W. Toreki, Synthesis and Characterization of

Topologically Interesting Vinyl Polymers. Makromol. Chem., Macromol. Symp., 47, 23 (1991).

27

92. Y-X Zhang, A-H Da and T.E. Hogen-Esch, New Fluorocarbon-Containing

Hydrophobically-Associating Polyacrylamide Copolymers.Chapter 10, ACS Symposium Series, No. 467, "Water-Soluble Polymers", S. Shalaby, C.L. McCormick and G.B. Butler, Eds., pp. 159-174, 1991.

93. S. Gopalkrishnan, G.B. Butler, T.E. Hogen-Esch and N.Z. Zhang,Hydrophobically

Associating Ionic Copolymers of Methyl Diallyl 1,1- Dihydropentadecafluorooctoxyethyl- ammonium Chloride. Chapter 11, ACS Symposium Series, No. 467, "Water-Soluble Polymers", S. Shalaby, C.L. McCormick and G.B. Butler, Eds., pp. 175-188, 1991.

94. T.E. Hogen-Esch, J.R. Mason, B.J. Ladd, G. Helary and G. Belorgey, Crosslinking of

PMMA Elastomer Block Copolymers Through PMMA Stereocomplexes. "Contemporary Topics in Polymer Science," Vol. 7, p. 339: Advances in New Materials, J. Riffle and J.C. Salamone, Eds., Plenum Press, New York, 1992.

95. G. Helary, G. Belorgey, B. Ladd and T.E. Hogen-Esch, Stereocomplex Formation in

Polybutadiene-Syndiotactic Polymethylmethacrylate Block Copolymers Blended with Isotactic PMMA. Polymer, 33(9), 1953 (1992).

96. Zhang, Y.; Da, A.; G.B. Butler; Hogen-Esch. T.E. A Fluoride-Containing

Hydrophobically Associating Polymer I. Synthesis and Solution Properties of Copolymers of Acrylamide and Fluorine-Containing Acrylates or Methacrylates. J. Polym. Sci., Chem. Ed., 30, 1383 (1992).

97. J. Sundararajan and T.E. Hogen-Esch, Synthesis and Characterization of Macrocyclic

Poly(2-vinylpyridine) and the Effect of a Rigid Coupling Agent on its Properties, in "Contemporary Topics in Polymer New Materials, J. Riffle and J.C. Salamone, Eds., Plenum Press, New York, 1992.

98. K. Bannerjee and T.E. Hogen-Esch, Stereochemistry of Polymerization of

Triphenylmethyl and Diphenylmethylmethacrylate Under GTP Conditions. Macromolecules, 26, 926 (1993).

99. R. Volpe, T.E. Hogen-Esch, F. Gores and A.H. Mueller, Stereochemistry of Living

PMMA Anions As Determined by NMR Analysis of Carbon-13 Labeled Methyl End Groups. Macromolecules, 25 (13), 3553 (1992).

100. T.A.P. Seery, M. Yassini, T.E. Hogen-Esch and E.J. Amis, Static and Dyanamic

Light Scattering of Solutions of Hydrophobically Associating Fluorocarbon-Containing Polymers. Macromolecules, 25, 4784 (1992).

101. T.E. Hogen-Esch, Stereochemistry of Anionic Vinyl Polymerization. Makromol.

Chem., Makromol. Symp., 67, 43 (1993). 102. M. Dimonie, D. Mardare, S. Coca, T.E. Hogen-Esch and J. Zoeller, Organocuprates

as Initiators for the Polymerization of Methylmethacrylate in THF. Makromol. Chem., Makromol. Symp., 67, 175 (1993).

103. F.S. Hwang and T.E. Hogen-Esch, Fluorocarbon-Modified Water-Soluble Cellulose

Derivatives. Macromolecules, 26, 3156 (1993).

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104. R. Yin and T.E. Hogen-Esch, Synthesis and Characterization of Polystyrene-

Polydimethylsiloxane Macrocyclic Block Copolymers and their Isobaric Precursors. Macromolecules, 26, 6952 (1993).

105. F. Hwang, T.E. Hogen-Esch and Y.-X. Zhang, Fluorocarbon-modified Water Soluble

Polymers. Chapter 7 in "Macromolecular Complexes in Chemistry and Biology", P. Dublin, J. Bock, R.M. Davies, D.N. Schulz and C. Thies, Editors. Part 1, "Hydrophobically Associating Polymers" pgs. 95-116, Springer Verlag, 1994.

106. Y.D. Gan, J. Zoeller, R. Yin and T.E. Hogen-Esch, Synthesis and Characterization of

Macrocyclic Polystyrene Block Copolymers. Makromol. Chem., Makromol. Symp., 77, 93 (1994).

107. R. Yin and T.E. Hogen-Esch, Synthesis and Characterization of Poly(2-

vinylpyridine)-b-poly(t-butylmethacrylate). J. Polym. Sci. (Chem. Ed.) 32, 363 (1994).

108. R. Yin, E.J. Amis, and T.E. Hogen-Esch, Synthesis of Macrocyclic Polystyrene-

Polydimethylsiloxane Block Copolymers. Makromol. Chem., Macromol. Symp., 85, 217 (1994).

109. P. Hubert, A. Soum, M. Fontanille, T.E. Hogen-Esch, and D. Dimov, Structure and

Reactivity of Propagating Centers in the Anionic Polymerization of 2-Vinylpyridine Initiated by t-Butyllithium-Triethyl-aluminum. Makromol. Chem., Macromol. Symp., 85, 313 (1994).

110. K. Bannerjee and T.E. Hogen-Esch, Stereochemical Kinetics of Polymerization of

MMA under GTP Conditions. Carbon-13 NMR Analysis of PMMA Terminated with Labeled End Groups. Macromolecules 27, 2187 (1994).

111. M.P. Berkouchi, G. Helary, G. Belorgey and T.E. Hogen-Esch, Stereocomplex

Formation in Polybutadiene - PMMA Block Copolymers Blended with Isotactic PMMA. Influence of Molar Masses. Polym. Bull., 32, 297 (1994).

112. T.E. Hogen-Esch and C. Meverden, The Role of Intra-Molecular Coordination in the

Stereochemistry of Anionic Vinyl Polymerization, Makromol. Chem., Macromol. Symp. 88, 35-53 (1994)

113. Hogen-Esch T.E.; Amis, E.J. Fluorocarbon-Containing Association Polymers. Trends

in Polymer Science 1995, 3(13), 98. 114. Gan, Y.; Dong, D.; Hogen-Esch, T.E. Effects of Lithium Bromide on the Glass

Transition Temperatures of Linear and Macrocyclic Poly(2-Vinylpyridine) and Polystyrene. Macromolecules 1995, 28, 383.

115. Deuring, H.; Alberda, G.O. R.; Ekenstein, V.; Challa, G.; Mason J.P.; Hogen-Esch,

T.E. Stereocomplex Formation in Block Copolymers of PMMA and Polydimethylsiloxane. DSC and DMTA Studies. Macromolecules 1995, 28, 1952.

116. Hwang, F.S.; Hogen-Esch, T.E. Effects of Water-Soluble Spacers on the

Hydrophobic Association of Fluorocarbon-Modified Polyacrylamides. Macromolecules 1995, 28, 3328-3335.

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117. Hogen-Esch, T.E.; Jin, Q.; Dimov, D. Stereochemical Control In Anionic

Polymerizations of 2-Vinylpyridine and Related Vinyl Monomers. J. Phys. Org. Chem. 1995, 8, 222.

118. Lescanec, R.L.; Hajduk, D.A.; Kim, G.Y.; Gan, Y.; Yin, R.; Gruner, S.M.; Hogen-

Esch, T.E.; Thomas, E.L. Comparison of the Lamellar Morphology of Microphase-Separated Cyclic Block Copolymers and Their Linear Precursors. Macromolecules 1995, 28, 3485.

119. Pratt, L.M.; Hogen-Esch T.E.; Khan, I.M. Anionic Polymerization of 2-Vinyl

Pyridine. A Computational Study of Solvent Effects on Polymerization Stereochemistry. Tetrahedron 1995, 51(21), 5955.

120. Amis, E.J.; Hu, N.; Seery, T.A.P.; Hogen-Esch, T.E.; Yassini, M.; Hwang, F.

Associating Polymers Containing Fluorcarbon Hydrophobic Units. Chapter 16 in Hydrophilic Polymers, Performance with Environmental Acceptability; ACS Advances in Chemistry Series 248, Glass, J.E., Ed.; American Chemical Society: Washington DC, 1995.

121. Hogen-Esch, T.E.; Dimov, D. Carbon-13 NMR Stereochemical Assignments of C-2

Carbon of Poly(2-vinylpyridine). Macromolecules 1995, 28, 7394. 122. Xie, X.; Hogen-Esch, T.E. Copolymers of N,N-Dimethylacrylamide and 2-(N-

ethylperfluorooctane Sulfonamido)ethylacrylate (FOSA). Synthesis and Properties. Macromolecules 1996, 29, 1734.

123. Xie, X.; Hogen-Esch, T.E. Anionic Synthesis and Characterization of Monodisperse

Poly(N,N-dialkyl)acrylamides. Macromolecules 1996, 29, 1746. 124. Zagala, A.P.; Hogen-Esch, T.E. Anionic Synthesis of Narrow Molecular Weight

Distribution Polymethylmethacrylate at Ambient Temperatures in the Presence of Tetraphenylphosphonium Cation. Macromolecules 1996, 29, 3038.

125. McCarthy, B.J.; Hogen-Esch, T.E. Synthesis of Narrow Distribution Poly(THF)

Initiated by Butylboron Triflates. Macromolecules 1996, 29, 3035. 126. Dong, D.; Hogen-Esch T.E.; Schaeffer, J.S. Formation of Macrocyclic Polymers by

Intramolecular Coupling of α,ω Di-functional Precursors Numerical Evaluations. Macromol. Chem. Phys. 1996, 197, 3397.

127. Gan, Y.; Prakash, G.K.S.; Olah, G.A.; Weber, W.P.; Hogen-Esch T.E. Anionic

Synthesis of Narrow Molecular Weight Distribution Poly(trimethylvinylsilane) and Poly(dimethylphenylvinyl) Silane and Poly(fluorodimethylvinylsilane). Macromolecules 1996, 29, 8285.

128. Wang, Q.; Zhang, H.; Prakash, G.K.S.; Hogen-Esch T.E.; Olah, G.A. Cationic Ring-

Opening Polymerization of Cyclosiloxanes Initiated by Electron Deficient Organosilicon Reagents. Macromolecules 1996, 29, 6691.

129. Pratt, L.M.; Khan I.M.; Hogen-Esch, T. E. Anionic Polymerization of 2-

Vinylpyridine. A computational Studies of Solvent Effects on Polymerization Stereochemistry. Macromol. Chem. Phys. 1996, 197, 3555.

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130. Hogen-Esch, T. E. Stereochemistry of Anionic Polymerization of Polar Vinyl

Monomers. Chapter 10 in Stereocontrol of Vinyl Polymerization and Oligomerization In Macromolecular Design of Polymeric Materials; Hatada, K., Kitayama, T., Vogl, O., Eds.; Marcel Dekker Inc.: New York, 1996.

131. Baskaran, D.; Mueller, A. H. E.; Kolshorn, H.; Zagala, A. P.; Hogen-Esch, T. E.

Polymerization of Methacrylates in the presence of Tetraphenylphophonium Cation. 2. Evidence for Phosphorylide -Mediated Polymerizations, Macromolecules 1997, 30, 6695.

132. Zhang, H.; Pan, J.; Hogen-Esch, T.E. “Synthesis and Characterization of One-Ended

Perfluorocarbon-Functionalized Derivatives of Poly(ethylene glycol)s”. Macromolecules 1998, 31, 2815.

133. Zhang, H.; Hogen-Esch, T.E.; Boschet, F.; Margaillan, A. “Complex Formation of

Cyclodextrin- and Perfluorocarbon-Modified Water-Soluble Polymers. Langmuir 1998, 14, 4972.

134. Zagala, A.P.; Dimov, D.; Hogen-Esch, T.E. Ylide Mediated Polymerization of

Methacrylates and Acrylates in the Presence of Tetraphenylphosphonium cation, 3”. Macromol. Chem. Phys. Macromol. Symp. 1998, 132, 309,

135. Baskaran, D.; Sivaram, S.; Chakrapani, S.; Hogen-Esch, T.E.; Mueller, A.H.E.

“Anionic Polymerization of Alkyl(Meth)acrylates Using Metal-Free Initiators: Effect of Ion Pairing on Initiation”. Macromolecules 1999, 32, 2865.

136. Makino, T.; Hogen-Esch, T.E.” Anionic Synthesis of Highly Isotactic Polystyrene in

Hexane in the presence of Lithium Hydroxides”. Macromolecules 1999, 32, 5712. 137. Dimov, D.K.; Warner, W.N.; Hogen-Esch, T.E. “Phosphorylide-Mediated

Polymerizations . Synthesis of PMMA and PMMA Block Copolymers at Elevated Temperatures”. Macromol. Chem. Phys., Macromol. Symposia. 2000, 157, 171.

138. Hogen-Esch, T. E. ; Dimov, D. K.; Jungling, S.; Warzelhan, V.;Gausepohl, H.

“Method For Preparing (Co) Polymers By Metal-Free Anionic Polymerization In The Presence Of A Phosphonium Cation Containing At Least One Annellated Aromatic Ring” United States Patent 6,143,847, November 2000.

139. Pan, J.; Chen, M.; Warner, W.; He, M.; Dalton, L. R.; Hogen-Esch, T.E. “Synthesis

of Block Copolymers Containing a Main Chain Polymeric NLO Segment”. Macromolecules 2000, 33(11), 4673.

140. Gan, Y.; Dong, D.; Carlotti, S.; Hogen-Esch, T.E. “Enhanced Fluorescence of

Macrocyclic Polystyrene”., J. Am. Chem. Soc. 2000, 122(9), 2130. 141. Hogen-Esch, T.E. “Comments on “Living Polymerization: Rationale for Uniform

Technology” by Darling et al.” J. Polym. Sci. Part A: Polymer Chemistry, 2000, 38(10), 1726.

142. Zhang, Y.; Fang, Q.; Fu, Y.; Da, A.; Zhang, Y.; Wu, C.; Hogen-Esch, T.E “Synthesis

and Characterization of Fluorocarbon-Modified Poly(isopropylacrylamide)”, Polym. Int. 2000, 49, 763-774.

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143. Pan, J.; Chen, M.; Warner, W. N.; He, M.; W.; Dalton, L. R.; Hogen-Esch, T.E.

“Synthesis and Self-assembly of Diblock Copolymers Through Hydrogen Bonding Semi Quantitative Determination of Binding Constants”, Macromolecules, 2000, 33 ,7835.

144. Zhang, Y.; Fang, Q.; Fu, Y.; Da, A.; Zhang, Y.; Wu, C.; Hogen-Esch, T.E.

“Synthesis and Solution Properties of Fluorocarbon-Modified Poly(N,N-dimethylacrylamide)”, Polym. Int. 2000,(50) ,148.

145. Hogen-Esch, T.E.; Zhang, H.; Xie, X. “ Synthesis and Characterization of Well

Defined End-Functionalized Hydrocarbon and Perfluorocarbon Derivatives of Polyethyleneglycol and Poly(N.N-dimethylacrylamide)” Chapter 11, in “Associative Polymers in Aqueous Solutions” ACS Symposium Series Vol. 765 , pp 179-203, J. E. Glass Editor, 2000 .

146. Zhang X.; Hogen –Esch T. E. “ Synthesis and Anionic Polymerization of 9,9 –

Dimethyl-2-vinylfluorene” Macromolecules, 2000, 33, 9176. 147. James A. Lee and Thieo E. Hogen-Esch” Synthesis and Characterization of Poly(2-

vinylpyridine)-poly(dimethylsiloxane) and Poly(4-vinylpyridine)-poly(dimethylsiloxane) Block Copolymers Via Anionic Polymerization”Macromolecules 2001, 34, 2805.

148. James Lee and Thieo E. Hogen-Esch “Synthesis and Characterization of

Poly(alphamethylstyrene)-Polydimethylsiloxane Block Copolymers” Macromolecules 2001, 34, 2095.

149. Xie, D.; Tomczak, S.; Hogen-Esch T. E. “Synthesis and Hydrophobic Association of

Poly(N,N-Dimethylacrylamide) (PDMA) End-Functionalized with Perfluorocarbon and Hydrocarbon Groups" J. Polym. Sci. Part A: Polymer Chemistry, 2001, 39, 1403-1418.

150. Chen, J.; Du, L.B.; Zhang, Y.X. ; Hogen-Esch, T.E.; Jiang, M. Synthesis and

solution properties of fluorocarbon-modified poly(N,N-dimethylacrylamide) Polymer International. 2001, 50 (1),148-156.

151. Gennadi G. Nossarev and Thieo E. Hogen-Esch “Living Anionic Polymerization of

2-Vinylnaphthalene in THF in the Presence of Lithium Ion. Role of Monomer Purification” .Macromolecules, 2001,34,5373.

152. Nossarev G.G.; Tillman E.; Hogen-Esch T. E. “Reactions of Polystyryllithiums and

Model Lithium Carbanions with 9,10-Bis(halomethyl)anthracenes”. J. Polym. Sci. Part A: Polymer Chemistry, 2001,39, 3121.

153. Nossarev, G.G.; Hogen-Esch, T. E. “Alkyllithium -Initiated Anionic Polymerization

of 2-Vinylnaphthalene in Toluene/THF mixtures”. J. Polym Sci. Part A: Polymer Chemistry, 2001, 39, 3034.

154. Dong, D.; Hogen-Esch, T.E. “Synthesis and Characterization of Macrocyclic

Poly(alpha-methylstyrene).” E-Polymers 2001. 007.

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155. G. Tae, J. A. Kornfield,J. A. Hubbell, D. Johannsmann, T. E. Hogen-Esch “Hydrogels with Controlled Heterogeneous Erosion Chractersitics from Sefl-Assembly of Fluoroalkyl-Ended Polyethyleneglycol” Macromolecules 2001, 34, 6409.

156. Tillman, E. S. and Hogen–Esch, T. E “Synthesis of Macrocyclic Polystyrene and

Macrocyclic Poly(9,9-dimethyl-2-vinylfluorene) Containing a Single 9,10 Anthracenylidene Unit” Macromolecules, 2001,34, 6616.

157. Gennadi G. Nossarev and Thieo E. Hogen-Esch “Potassium Ion Mediated Living and

Controlled Anionic Polymerization of 2-Vinylnaphthalene (2VN). Synthesis of P2VN-b-Poly(α-methylstyrene) and P2VN-b-Poly(9,9-dimethyl-2-vinylfluorene) Block Copolymers”. Macromolecules, 2001,34,6866.

158. Hui Zhou, Guo-Qiang Song, Yun-Xiang Zhang Junyan Chen, Ming Jiang Thieo E

Hogen-Esch, Reinhold Dieing, Lian Ma, Lukas Haeussling.“Hydrophobically Modified Polyelectrolytes: IV. Synthesis and Solution Properties of Fluorocarbon-Containing Poly(acrylic acid)” Makromol. Chem. and Phys. 2001, 202, 3057-3064.

159. Nossarev, G.G.; Hogen-Esch, T. E. “Synthesis and Thermal Properties of

Macrocyclic Poly(2-vinylnaphthalene) Containing Single 1,4-Benzylidene or 9,10-Anthracenylidene Groups” Macromolecules, 2002, 35,1604.

160. Yun-xiang Zhang, Shouping Liu, Libin Du, Dongqing Zhuang, Junyan Chen, Ming

Jiang, Thieo E. Hogen-Esch, Shuguang Wu, Graham Swift “Synthesis And Characterization Of Fluorocarbon-Containing Hydrophobically Associative Poly(Acrylic Acid-Co-Rf-PEG) Macromonomer” J Appl Polym. Sci. 2002, 84, 1035-1047.

161. Alberty K.; Chen R.; Hogen-Esch T.E “A New Bifunctional Initiator for use in

Anionic Polymerizations” J. Polym Sci. Part A: Polymer Chemistry, 2002, 40, 2108. 162. Alberty, K. A. ; Tillman, E. ; Carlotti, S. ; King, K.; Bradforth, S. E.; Parker, D. ;

Feast, W. J.; Hogen-Esch T. E “Characterization and Fluorescence of Macrocyclic Polystyrene by Anionic End to End Coupling. Role of Coupling Reagents” Macromolecules, 2002, 35, 3856 .

163. Warner, W. and Hogen-Esch Thieo E. “ Kinetically Controlled Radical Anion

Mediated Dimerization of 4-Dimethylaminostyrene” Macromolecules 2002, 35, 3787.

164. Keary, C.; Zhang, X.; Hogen-Esch, T. E. “Towards the synthesis of polystyrene-

PMMA block copolymers by a one-pot solution copolymerization via atom transfer polymerization”. Polymer Int. 2002, 51, 647.

165. Emami, S. H.; Hogen-Esch, T. E.; Salovey, R. “Peroxide-Mediated Crosslinking of

Polyethylene Oxide”. J. Polym Sci. Part A 2002, 40, 3021.

166. Tillman, E. S. and Hogen–Esch, T. E. “Coupling Reactions of Polystyryllithium with Dihalomethanes”. J. Polym. Sci Part A: Polymer Chemistry, 2002, 40, 1081.

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167. Gan, Y-D and Hogen Esch T..E. “Synthesis and Characterization of Catenated PS-Poly(2-vinylpyridine) Block Copolymers”. Macromolecules 2002, 35, 7699.

168. "Spectroscopy of macrocyclic poly(9,9-dimethyl-2-vinyl-fluorene) as an artificial

light harvester", J. M. Johnson, X. Chen, A. C. Germaine, X. Zang, K. Alberty; Hogen-Esch T. E.;Bradforth S.E.. in “Ultrafast Phenomena XIII” , ed. Miller, Springer-Verlag (2003)

169. Emami, S. H. Salovey R. Hogen-Esch T. E. “Degradable Polyethylene Oxide

Hydrogels Formed By Crosslinking With tert-Butylperoxybenzoate”. ”. J. Polym Sci. Part A 2003, 41, 520.

170. S. Madhusoodhanan, Hogen-Esch T. E.; Thompson, M.E. "Phosphorescence

Quenching by Conjugated Polymers." J. Am. Chem. Soc. 2003, 125(26),7796. 171. Chen R.; Zhang, X.; Hogen-Esch T. E. “Synthesis and Thermal Properties of

Macrocyclic Poly(9,9-dimethyl-2-vinylfluorene) Containing Single 1,4-Benzylidene or 9,10-Anthracenylidene Linking Units” Macromolecules 2003, 36, 7477.

172. Smid, J; Hogen-Esch T.E. “International Rubber Science Hall of Fame Inductee

Michael Szwarc 1909-2000” Rubber Chem. Technol. 2003,76 (2), 2. 173. Da J.; Hogen-Esch T. E. Poly(N,N-dimethylacrylamide) with Perfluorocarbon

Pendent Groups Connected Through Polyethylene-glycol Tethers Give Physical Gels in Organic Solvents. Macromolecules 2003, 36, 9559-9563.

174. Zhang, X.; Hogen-Esch T E. “Anionic Synthesis of Poly(9-methyl-9-trimethylsilyl-

2-vinylfluorene) (PMSVF). Spontaneous Deprotection-Protonation of PMSVF with Potassium Methoxide/Methanol gives Poly(9,9-dimethyl-2-vinylfluorene)” Macromolecules 2003, 36, 7959-7963.

175. Chen R.; Johnson, J.; Bradforth, S.E. Hogen-Esch T. E “UV-Vis Absorption and

Fluorescence Emission Spectroscopic Studies of Macrocyclic and Linear Poly(9,9-dimethyl-2-vinylfluorene). Evidence for Ground State Chromophore Interactions” Macromolecules 2003, 36, 9966-9970.

176. Onishi ,Y., Butler G. B. , Hogen-Ecsh T. E. “Study of PDO-Cellulose-Acrylamide

Graft Copolymers” J Appl. Polym. Sci. 2004, 9, 3022-3029. 177. Jinbo Hu, William N. Warner, G.K. Surya Prakash, George A. Olah, and Thieo E.

Hogen-Esch “High Molecular Weight Narrow Distribution Polymethylmethacrylate by a Metal-Free Tetramethylammonium Triphenylmethide-Mediated Anionic Polymerization”.J. Pol. Sci. A. (Chem. Ed.) 2004, 41, 237.

178. Madhusoodhanan S., Thompson M.E., Hogen-Esch T.E. “Reactive Oligomer

Intermediates In The Yamamoto Coupling Mediated Polymerization of 2,7-Dibromofluorenes.” Polymer Preprints (American Chemical Society, Division of Polymer Chemistry) 2004, 45(1), 263.

179. Da J.; Hogen-Esch T. E. “Synthesis and Association of Poly(N,N-

dimethylacrylamide) Copolymers with Perfluorocarbon Pendent Groups Connected Through Polyethylene-glycol Tethers”. J. Pol. Sci. A. ( Chem. Ed.) 2004, 42, 360.

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180. Zhuang, D.Q.; Hogen-Esch, T.E., Zhang, Y.X. “Rheological investigation on the interaction of a fluorocarbon and hydrocarbon comodified PAA with a nonionic surfactant in the presence of salt “ J. Appl. Polym. Sci. 2004, 92 (2), 1279-1285.

181. Chen R.; Nossarev, G.G.; Hogen-Esch T. E “Synthesis and Properties of

Macrocyclic Vinylaromatic Polymers Containing a Single 1,4-Benzylidene or 9,10-Anthracenylidene Group”. Makromol. Chem. Macromol. Symp. 2004, 215, 67-79.

182. Chen R. Hogen-Esch T. E. “Synthesis and Thermal and Spectroscopic Properties of

Macrocyclic Vinyl Aromatic Polymers”. J. Pol. Sci. A. (Chem. Ed.) 2004, 42, 5488 183. Boschet, F. ; Branger, C. ; Margaillan, A. ; Hogen-Esch* T.E. “Associative Properties

Of Perfluorooctyl End-Functionalized Polystyrene-Poly(Ethylene Oxide) Diblock Copolymers” Polymer International, 2005, 54, 90-95.

184. K. Liao, T.E. Hogen-Esch, F. J. Richmond, L. Marcu, G. E. Loeb .”Design and

Fabrication of Disposable, Percutaneous Chemical Sensors. Optical Fibers and Sensors for Medical Applications V”, edited by Israel Gannot, Proceedings of SPIE 2005, 5691, 129.

185. Alberty, K. A.; Hogen-Esch; T.E.; Carlotti S. “Characterization and Fluorescence of

Macrocyclic Polystyrene-2. Molecular Weight Dependent Properties”.Macromol. Chem. Phys. 2005 , 206 (10) 1034.

186. Hogen-Esch T. E. “Synthesis and Characterization of Macrocyclic Vinyl Aromatic

Polymers” J. Pol. Sci. A. (Chem. Ed.) 2006, 44 (7): 2139-2155. (Invited “Highlight” Review).

187. Peng C.A., Da J., Hsu. Y-C, Hogen-Esch T. E. “Polymeric fluorosurfactant-

mediated perfluorocarbon emulsions” Journal of Dispersion Science And Technology 2006, 27 (3): 377-387.

188. Smid, J.; Van Beylen, M.; Hogen-Esch, T. E. “Perspectives on the Contribution of

Michael Szwarc to Living Polymerization” Prog. Polym. Sci. 2006, 09, 001.

189. Jun Ling and Thieo E. Hogen-Esch “Mechanism of Phosphor Ylide-Mediated Living Polymerizations of MMA and Nature of Side Reactions in the Formation of Initiators” Macromolecules 2006, 39, 9665-9667.

190. Ling, J. Hogen-Esch, T.E. Mechanism of phosphor ylide-mediated living

polymerizations of MMA. Nature of side reactions in the formation of initiators Macromolecules 2007, 40(9), 3514.

191. Franta, E. Hogen-Esch T.E., Van Beylen, M.; Smid J. “Fifty Years of Living

Polymers” ” J. Pol. Sci. A. (Chem. Ed.) 2007, 45 (12), 2576-2579.

192. Jun Ling and Thieo E. Hogen-Esch “Alkylation and Coupling of Living Poly(Methyl Methacrylate) Ylides at Ambient Conditions”, Macromolecules 2007, 40, 5706-5709.

193. Liao, K; Hogen-Esch T. E.; Richmond, F. J.; Marcu, L.; Clifton W.; Loeb, G. E.

“Percutaneous Fiber-optic Sensor for Chronic Glucose Monitoring in vivo” Science Direct, Biosensors and Bioelectronics 2008, 23,1458–1465.

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194. Fomina, F.; Hogen-Esch, T. E. “Synthesis and Characterization of Macrocyclic Poly(fluorene-3,6-diyl)” Macromolecules, 2008, 41, 3765-3768.

195. Ling, J. ; Fomina N.; Golam, R.; Hogen-Esch T. E. DFT Based Monte Carlo

simulations of Poly(9,9-dihexylfluorene-2,7-diyl) and Related Polymers in Solution” J. Phys Chem.B 2008, 112 (33), 10116-10122.

196. Jingguo Shen and and Thieo E. Hogen-Esch “ Fluorocarbon mediated Polymer

Blends and Methods for Making Thereof. Patent application. 10_08.

197. Shen J.; Hogen-Esch T.E. “Block Copolymer –Like Morphologies from the Self Assembly in Polymer Blends Mediated by Fluorophilic Interactions” J. Am. Chem. Soc. 2008, 130, 10866-10867.

198. Johnson, J. M.; Chen,; Chen, X.; Moskun, A. C.; Zhang, X.; Hogen-Esch T. E.;

Bradforth S. E. “Investigation of Macrocyclic Polymers as Artificial Light Harvesters: Sub-Picosecond Energy Transfer In Poly(9,9-Dimethyl-2-Vinyl-Fluorene)”. J. Phys. Chem B. 2008 ,112, 16367-16382.

199. Dimitrov P. ; Van Beylen, M.; Hogen-Esch T.E. 1,4-Dilithio-1,1,4,4-

tetraphenylbutane an Effective Initiator for the Living Anionic Polymerization of Dienes in Diethyl Ether. J.Pol. Sci.-A. 2009, 2198-, 2206.

200. Ling J. ; Hogen-Esch T. E. “A Density Functional Theory Study of the Mechanisms

of Scandium-Alkoxide Initiated Coordination-Insertion Ring-Opening Polymerization of Cyclic Esters” Polymer 2009, 50, 3575-3581.

201. Nadezda F.; Bradforth S. E.; Hogen-Esch T. E. Synthesis and Spectroscopy of

Poly(9,9-dihexylfluorene-2,7-dlyl-co-9, 9-dihexylfluorene-3,6-diyl)s and Their Model Oligomers Macromolecules 2009, 42 (17), 6440-6447.

202. Chen, R.; Ling, J.; Hogen-Esch, T. E . “Synthesis and Spectroscopic Studies of

Macrocyclic Polystyrene Containing Two Fluorene units and Single 9,10-Anthracenylidene Group” Macromolecules, 2009, 42(16), 6015-6022.

203. Philip Dimitrov, Thieo E. Hogen-Esch, Rishikesh Bharadwaj, Prakash Mallya and

Pradeep Iyer “Controlled Synthesis of High Molecular Weight Polyacrylates Having a Dumbbell Topology” Macromolecules, 2009, 42 (18), 6873-6877.

204. Zhuang, D.; Hogen-Esch T. E. “Controlled Color Output Through Fluorescent

Polymer Nano-Pigments” Macromolecules, 2010, 43 (19), 8170–8176.

205. Ring-Opening Polymerization of epsilon-Caprolactone Catalyzed by Yttrium Trisphenolate in the Presence of 1,2-Propanediol. Do Both Primary and Secondary Hydroxyl Groups Initiate Polymerization? Jun Ling, Jinzhi Liu, Zhiquan Shen, Thieo E. Hogen-Esch J. Polym. Sci. A. 2011, 49 (9) 2081-2089.

206. Shi F.; Ling J.; Lu J.; Han B.; Lu, L.; Hogen-Esch T.E. “Synthesis of Isotactic-

Polystyrene in Hydrocarbons by Initiation with t-BuLi in the Presence of Sodium Dodecylbenzene sulfonate” Polymer 2012, 53, 94-105.

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207. You, L.; Hogen-Esch, T. E.; Zhu, Y.; Ling J,; Shen, Z. “Brønsted Acid-Free Controlled Polymerization of Tetrahydrofuran Catalyzed by Recyclable Rare Earth Triflates in the Presence of Epoxides”. Polymer. 2012, 19, 1953-1058 (Aug).

208. Shen, J.;. Hogen-Esch, T. E. “Fluorocarbon Mediated Polymer Blends and Methods

for Making Thereof” US Patent 8236902, September 12th, 2012.

209. Lin, Y.; Zheng, Z.; Hogen-Esch, T. E.; Ling, J.; Shen, Z. “Well-Defined Novel Fluorene-Containing Polymers: Synthesis, Fluorescent Properties and Micellization Behaviors” J. Colloid Interface Sci. 2013-390, 105-113.

210. Nossarev G G.; Johnson, J.M.; Bradforth S. E.; Hogen-Esch T. E. Emission of

Macrocyclic and Linear Poly(2-vinylnaphthalene): Observation of Two Excimer Populations in Macrocycles. J. Phys. Chem., 2013, 117(20), 10244-10256.

211. Shen J, Piunova V.A, Nutt S, Hogen-Esch T.E. “Blends of Polystyrene and Poly (n-

Butyl Methacrylate) Mediated by Perfluorocarbon End Groups, Polymer, 2013, 54, (21) 5790–5800.

212. Deng, C., Peng J., Shen, X.B., Ling J., Hogen-Esch T. E. “White Light Emission of

Multi-Chromophore-Photoluminescent Nanoparticles using Polyacrylate Scaffolds Copolymers with Pendent Polyfluorene Groups.” Polymer Chemistry 2014, 05(17), 5109-5115.

In preparation (11/2013) 1. Victoria A. Piunova and Thieo E. Hogen-Esch “Synthesis of Telechelic Perfluorocarbon

Functionalized Polystyrene and Polybutylmethacrylate and Characterization of Their Blends” In submission.

2. Li, M., Fakhro ,Y. ;Prakash, G.K.S.; Hogen-Esch, T. E. “ Synthesis of Polymer Blend Membranes based on Polyvinylidene fluoride and Poly(styrenesulfonic acid) Copolymers, I. .

3. Li, M.; Prakash, G.K.S.; Hogen-Esch, T. E. Polymer Blend Membranes based on

Polyvinylidene fluoride and Poly(styrenesulfonic acid) Copolymers, II. Applications in Methanol Fuel Cells.

4. Olsen, J. Hogen-Esch T. E. “Synthesis of Helicene-Based Macromolecules”

5. Madhusoodhanan, S.; Ling, J.; Fomina, N.; Golam, R. Thompson M. E.; Hogen-Esch T.E “Kinetics of Yamamoto Polymerization of 9,9-Dihexyl-2,7-dibromofluorene”. In Preparation.

6. Dimitrov, D. : Iyer, P. Hogen-Esch, T. E. In preparation. “Synthesis and

Characterization of Hydrogenated Polybutadiene Macromonomers”

7. Boschet, F.; McGrath, K.; Olah, G. A.; Surya Prakash, G. K.; Hogen-Esch T. E. Hydrogels for Fuel Delivery in Direct Methanol Fuel Cells. In preparation

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8. Tomczak, S. Hogen-Esch T. E “Cyclodextrin Mediated Association of

Perfluorocarbon Functionalized Polydimethylacrylamide Copolymers” In Preparation.

9. Tomczak, S. Hogen-Esch T. E. : Fluorescence of Perfluorooctanoylpyrene In

Perfluorocarbon Functionalized Polydimethylacrylamide” In Preparation. 10. Warner, W. and Hogen-Esch Thieo E. “Synthesis and Properties of Styrene-4-

(N,N-Dimethylamino)styrene Block Copolymers” In Preparation.

11. T. Makino and T.E Hogen-Esch “Isotactic Polystyrene by Anionic Polymerization” In preparation.

12. Xie, X.; Hogen-Esch, T.E. Synthesis and Characterization of Block Copolymers

of N,N-Dimethyl-acrylamide and Methyl-methacrylate. J. Polym. Sci. (Chem. Ed.) In preparation.

13. James Lee and Thieo E. Hogen-Esch “Hydrogen Bond-Mediated Association of

Polyvinylpyridine-Poly dimethylsiloxane Block Copolymers with Polyvinylphenol in Tetrahydrofuran” J. Polym. Sci. (Chem. Ed.) In preparation.

Books:

Recent Advances in Anionic Polymerization; Hogen-Esch, T. E., Smid, J., Ed.; Elsevier, New York, 1987.

Non refereed publications

1. T.E. Hogen-Esch, R.A. Smith and C.F. Tien, Ion Pair Effects in the Stereochemistry of

Anionic Vinyl Oligomerization of 2-Vinylpyridines and Related Monomers. Proc. 26th Intern'l Symp. on Macromolecules, Vol. 1, 252, (1979).

2. T.E. Hogen-Esch, W.L. Jenkins and C.F. Tien, Cation and Solvent Effects of (E)- (Z)Equilibria

of the Carbanion Site in Anionic Polymerization of 2-Vinylpyridines and Related Monomers and Their Role in Beta-Carbon Stereochemistry. Proc. 26th Intern'l Symp. on Macromolecules, Vol. 1, 254 (1979).

3. H. Pledger, Jr., J.J. Meister, T.E. Hogen-Esch and G.B. Butler, Starch-Acrylamide

Graft Copolymers For Use in Enhanced Oil Recovery. Soc. of Petroleum Engrs. Paper #SPE8422, presented at 54th Annual Fall Tech. Conf., Las Vegas, NV, 1979.

4. T.E. Hogen-Esch, W.L. Jenkins, C.F. Tien and R.A. Smith, Ion Pair Structure and

Stereochemistry in Anionic Oligomerization and Polymerization of Some Vinyl Monomers. ACS Div. Polym. Sci. Polym. Prepr. 21 (1), 13 (1980).

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5. C.J. Chang, R.F. Kiesel and T.E. Hogen-Esch, Investigations of Ion Pair Structure of Vinylpyridine Type Carbanions and Its Effect on the Anionic Polymerization of Vinylpyridines., Madrid, IUPAC International Symposium on Macromolecules, Madrid, Spain, September 1974 Spain, Vol. I, 142.

6. T.E. Hogen-Esch, K. Hashimoto, C.F. Tien and R.A. Smith, Stereochemistry of

Anionic Oligomerization and Polymerization of 2-(2-Pyridyl and 2-(4-Pyridyl) propene. ACS Div. Polym. Sci. Polym. Prepr., 23, (1), 296 (1982).

7. A.H. Soum, S.S. Huang and T.E. Hogen-Esch, Stereochemical Analysis of Vinyl

Polymers. 13C NMR of Labeled Terminal CH3 Groups.ACS Div. Polym. Sci. Polym. Prepr., 24, (2), 149 (1983).

8. I.M. Khan, C.C. Meverden and T.E. Hogen-Esch, Studies on the Active Centers in

Anionic Polymerization of 2-Vinylpyridine in the THF. ACS Div. Polym. Sci. Polym. Prepr. 24 (2), 151 (1983).

9. B.C. Bell and T.E. Hogen-Esch, Stereochemistry of the Anionic Oligomerization of t-

Butyl Vinyl Ketone. ACS Div. Polym. Sci. Polym. Prepr., 26 (1), 152 (1985).

10. I.M. Khan and T.E. Hogen-Esch, Stereoregular Oligomerization and Polymerization of 3-Methyl-2- Vinylpyridine. ACS Div. Polym. Sci. Polym. Prepr., 26 (2), 273 (1985).

11. B.C. Bell and T.E. Hogen-Esch, Stereochemistry of the Anionic Oligomerization of t-

Butyl Vinyl Ketone. ACS Div. Polym. Sci. Polym. Prepr., 26 (1), 152 (1985).

12. D.R. Patil, G.B. Butler and T.E. Hogen-Esch, Synthesis of 2,3-Dihydroxypropyl- cellulose and Its Polyacrylamide Graft Copolymer. ACS Div. Polym. Sci. Polym. Prepr., 27 (2), 34 (1986).

13. A. Aboudalle, A. Soum, M. Fontanille and T.E. Hogen-Esch, Kinetics and

Thermodynamics of Anionic Polymerization of 2- Isopropenylpyridine in Toluene. ACS Div. Polym. Sci. Polym. Prepr. 27 (1), 143 (1986).

14. D.R. Patil, H. Pledger, Jr., G.B. Butler and T.E. Hogen-Esch, Synthesis and

Characterization of Water-Soluble Polyacrylamide Graft Copolymers of Starch and 2,3 Dihydroxypropylcellulose. PMSE Preprs. ACS 1986 Anaheim, CA, Meeting.

15. M.A. Buese and T.E. Hogen-Esch, Stereochemistry of the Anionic Polymerization of

Vinyl Phenyl Sulfoxide. ACS Div. Polym. Sci. Polym. Prepr., 27 (1), 155 (1986). 16. T.E. Hogen-Esch and I.M. Khan, Role of E and Z-Carbanions in the Stereochemistry

of Anionic Vinyl Polymerization. ACS Div. Polym. Sci. Polym. Prepr., 27 (1), 159 (1986).

17. W. Toreki and T.E. Hogen-Esch, Studies of Trifunctional Carbanion Initiators for the

Preparation of Three- Arm Star Polymers. ACS Div. Polym. Sci. Polym. Prepr., 27 (1), 355 (1986).

18. R. Kanga, M.A. Buese and T.E. Hogen-Esch, Anionic Polymerization and

Copolymerization of Phenyl Vinyl Sulfoxide and Thermal Degradation Studies of Poly(phenylvinylsulfoxide). ACS Div. Polym. Sci. Polym. Prepr., 28, (2), 322 (1987).

19. R.A. Volpe, T.E. Hogen-Esch, A.H.E. Mueller and F. Gores, Stereochemistry of

Oligomerization of MMA and Correlation with End-Group Stereochemistry of PMMA. ACS Div. Polym. Sci. Polym. Prepr. 28 (2), 423 (1987).

39

20. K. G. Bannerjee and T.E. Hogen-Esch, Stereochemical Kinetics of Group Transfer Polymerization of Methylmethacrylate. Carbon-13 NMR Analysis of PMMA Terminated with Labeled End-Groups. ACS Div. Polym. Sci. Polym. Prepr., 28 (2), 320 (1987).

21. W. Toreki, T.E. Hogen-Esch and G.B. Butler, Synthesis of Macrocyclic Poly(2

vinylpyridine.ACS Div. Polym. Sci. Polym. Prepr., 28 (2), 343 (l987). 22. G. Helary, B.J. Ladd and T.E. Hogen-Esch, Synthesis of Poly(butadiene Syndiotactic

Poly(methylmethacrylate) Block Copolymers. Stereocomplex Formation with Isotactic PMMA. ACS Div. Polym. Sci. Polym. Prepr. 28 (2), 318 (1987).

23. W. Toreki, G.B. Butler and T.E. Hogen-Esch, Synthesis of Macrocyclic Poly(2- (2),

Vinylpyridine and Macrocyclic Poly(N-17 methyl-2-vinylpyridinium bromide) , a Cyclic Polyelectrolyte. ACS Div. Polym. Sci. Polym. Prepr. 29(1988).

24. M. Fontanille, G. Helary, I.M. Khan and T.E. Hogen-Esch, Effects of Chain Length

and Stereochemistry on the Kinetics of Addition of 1,1-Diphenylethylene to Oligomeric Models of Living Poly(2-vinylpyridine)-Lithium. ACS Div. Polym. Sci. Polym. Prepr., 29 (2)31-32 (1988).

25. W. Toreki and T.E. Hogen-Esch, Spontaneous Dimerization of Living Poly(2-

vinylpyridine). ACS Div. Polym. Sci. Polym. Prepr., 29 (2), 416 (1988).

26. R. Kanga, T.E. Hogen-Esch, M. Fontanille and A. Soum, Synthesis of AB and ABA Block Copolymers of Styrene and Phenylvinylsulfoxide Thermal Elimination Studies. Polym. Prepr., 29 (2), 326 (1988).

27. W. Toreki and T.E. Hogen-Esch, Synthesis of Macrocyclic- and Star-Vinyl Polymers.

ACS Div. Polym. Sci. Polym. Prepr., 30 (1), 129 (1989) 28. J.P. Mason, T. Hattori and T.E. Hogen-Esch, Synthesis of Monodisperse

Polydimethylsiloxane-Syndiotactic PMMA, AB and ABA Block Copolymers by Anionic Polymerization. ACS Div. Polym. Sci. Polym. Prepr., 30 (1), 259 (1989).

29. B.J. Ladd and T.E. Hogen-Esch, Synthesis of Polybutadiene-Syndiotactic PMMA,

ABA Block Copolymers. Stereocomplex Formation with Isotactic PMMA. ACS Div. Polym. Sci. Polym. Prepr., 30 (1), 261 (1989).

30. K.B. Al-Jumah, K.B. Wagener, T.E. Hogen-Esch, J. Musfeldt and D.B. Tanner,

Planarizing Polyaromatic Polymers Based On Imine Chemistry. ACS Div. Polym. Sci. Polym. Prepr., 30 (2), 173 (1989).

31. T.E. Hogen-Esch and D. Dimov, Stereochemistry of Anionic Vinyl Polymerization.

Stereochemical Roles of E- and Z-Isomers. ACS Div. Polym. Sci. Polym. Prepr., 30 (2), 429 (1989).

32. Y-X. Zhang, A-H. Da, G.B. Butler and T.E. Hogen-Esch, A New Fluorocarbon

Containing , Hydrophobically Associating Polyacrylamide Copolymers. ACS Div. Polym. Sci. Polym. Prepr. 30 (2), 338 (1989).

33. J.P. Mason and T.E. Hogen-Esch, Synthesis of Monodisperse Polydimethylsiloxane-

Syndiotactic PMMA Star- and ABA Block Copolymers. Stereocomplex Formation With Isotactic PMMA. ACS Div. Polym. Sci. Polym. Prepr., 31 (1), 510 (1990).

34. T.E. Hogen-Esch, B.J. Ladd, J.P. Mason, J. Helary and G. Belorgey, Stereocomplex

Formation of PMMA-Containing Block Copolymers. Synthesis and Properties. ACS Div. Polym. Sci. Polym. Prepr., 31 (2), 405 (1990).

40

35. T.E. Hogen-Esch, M. Yassini, Y-X Zhang, F. Huang, E.J. Amis and T. Seery,

Synthesis and Characterization of Fluorocarbon Containing Polyacrylamides. ACS Div. Polym. Sci. Polym. Prepr., 31 (2), 460 (1990).

36. F. Hwang and T.E. Hogen-Esch, Fluorocarbon-Modified Water-Soluble Cellulose

Derivatives. ACS Div. Polym. Sci. Polym. Prepr., 32 (1), 581 (1991). 37. J. Sundararajan and T.E. Hogen-Esch, Synthesis and Characterization of Macrocyclic

Poly(2-vinylpyridine). ACS Div. Polym. Sci. Polym. Prepr., 32 (1),63 (1991). 38. Q. Jin, D. Dimov and T.E. Hogen-Esch, Lithium Alkoxides as Modifiers for the

Synthesis of Isotactic Poly(2-vinyl-pyridine). ACS Div. Polym. Sci. Polym. Prepr., 32 (1), 465 (1991).

39. R. Yin and T.E. Hogen-Esch, Synthesis and Characterization of Poly(2-vinylpyridine)

b-t-Butylmethacrylate Copolymers. ACS Div. Polym. Sci. Polym. Prepr., 32 (1), 539 (1991).

40. J. Sundararajan and T.E. Hogen-Esch, Synthesis and Characterization of Macrocyclic

Polystyrene Effect of Molecular Weight on Glass Transition Temperature. ACS Div. Polym. Sci. Polym. Prepr., 32 (2) 604 (1991).

41. R. Yin and T.E. Hogen-Esch, First Synthesis of a Macrocyclic Block Copolymer

Macrocyclic Polystyrene-b-polydimethylsiloxane. ACS Div. Polym. Sci. Polym. Prepr., 33 (1), 2391 (1992).

42. M. Yassini and T.E. Hogen-Esch, Fluorine Containing Hydrophobically Associating

Polymers. ACS Div. Polym. Sci. Polym. Prepr., 33 (1), 933 (1992). 43. X. Xie and T.E. Hogen-Esch, Anionic Polymerization of N,N-Dialkyl-acrylamide and -

methacrylamide. ACS Div. Polym. Sci. Polym. Prepr. 33 (1), 241 (1992). 44. E.J. Amis, T.A. Seery, M. Yassini and T.E. Hogen-Esch, Static and Dynamic

Lightscattering Characterization of Hydrophobically Associating Fluorocarbon Containing Polymers. ACS Div. Polym. Sci. Polym. Prepr. 33 (1), 935 (1992).

45. J. Sundararajan and T.E. Hogen-Esch, Synthesis and Characterization of Poly(2-

vinylpyridine) Macrocycles. Effect of Coupling Agent. ACS Div. Polym. Sci. Polym. Prepr. 33 (1), 162 (1992).

46. D. Dong, T.E. Hogen-Esch and J. Smid, PEO Based Lithium Ion Conducting

Polymers. ACS Div. Polym. Sci. Polym. Prepr., 34 (1), 550 (1993). 47. F.S. Hwang and T.E. Hogen-Esch, Effects of Water Soluble Spacers on the

Hydrophobic Association of Fluorocarbon Modified Polyacrylamides. ACS Div. Polym. Sci. Polym. Prepr., 34 (1), 405 (1993)

48. Y. Gan, J. Zoeller and T.E. Hogen-Esch, Synthesis and Characterization of

Macrocyclic Polystyrene-b-Poly(2-vinylpyridine) Block Copolymers. ACS Div. Polym. Sci. Polym. Prepr., 34 (1), 69 (1993).

49. X. Xie and T.E. Hogen-Esch, Synthesis of Well-Defined Poly(N,N-

dimethylacrylamide) Containing Perfluorooctanoyl End Groups. ACS Div. Polym. Sci. Polym. Prepr., 34 (1), 118 (1993).

50. G.Y. Kim, E.L. Thomas, R. Yin, Y. Gan and T.E. Hogen-Esch, Macrocyclic Diblock

Copolymers. A Morphological Study. Abstract Am. Phys. Soc. 1993 Meeting.

41

51. E.J. Amis, D.F. Hodgson, R. Yin and T.E. Hogen-Esch, Characterization of Diblock

Ring Copolymers in Dilute Solution. Abstract Am. Phys. Soc. 1993 Meeting. 52. Y. Gan, T.E. Hogen-Esch, W.P. Weber, G.K.S. Prakash and G.A. Olah, Anionic

Polymerization of Trimethylvinylsilane and Phenyldimethyl Vinyl Silane. Towards the Synthesis of Well Defined Polyfluorodimethyl Vinyl Silane and Polyvinyl Alcohol. ACS Div. Polym. Sci. Polym. Prepr., 34 (1), 548 (1993).

53. B.J. McCarthy and T.E. Hogen-Esch, Synthesis and Anionic Polymerization of the

Structurally Hindered Monomer 7-Methylene-8,9-cyclopentapyridine. ACS Div. Polym. Sci. Polym. Prepr., 34 (1), 552 (1993).

54. D.K. Dimov, L.R. Dalton and T.E. Hogen-Esch, Anionic Polymerization of Azo-

Substituted Methacrylates. ACS Div. Polym. Sci. Polym. Prepr., 34 (1), 26 (1993). 55. R. Yin and T.E. Hogen-Esch, Side Reactions in the Synthesis of Polystyrene-

Polydimethylsiloxane and Polystyrene-Polyethylenedisiloxane-Polydimethylsiloxane Block Copolymers. ACS Div. Polym. Sci. Polym. Prepr., 34 (1), 554 (1993).

56. J.A. Lee and T.E. Hogen-Esch, Poly(2-vinylpyridine)-Polydimethylsiloxane Block

Copolymers. Synthesis and Characterization via Anionic Polymerization. ACS Div. Polym. Sci. Polym. Prepr., 34 (1), 556 (1993).

57. F. Hwang and T.E. Hogen-Esch, Effects of Water-Soluble Spacers on the Hydrophobic

Association of Fluorocarbon-modified Polyacrylamide. ACS Div. Polym. Sci. Polym. Prepr., 34 (1), 405 (1993).

58. M. Yassini and T.E. Hogen-Esch, Fluorine-Containing Hydrophobically Associating

Water-Soluble Polymers. Kinetics of Polymerization by 19F NMR. ACS Div. Polym. Sci. Polym. Prepr., 35 (1), 478 (1994)

59. X. Xie and T.E. Hogen-Esch, Synthesis and Characterization of Hydrophobically

Associating Poly (N,N-dimethylacrylamide). ACS Div. Polym. Sci. Polym. Prepr., 35 (1), 498 (1994)

60. Y. Gan, D. Dong and T.E. Hogen-Esch, Effects of Lithium Bromide on the Glass

Transition. Temperature of Linear and Macrocyclic Poly(2-Vinylpyridine). ACS Div. Polym. Sci. Polym. Prepr., 35 (2), 574 (1994)

61. J.Q. Jin and T.E. Hogen-Esch, Stereochemical Effects of Lithium t-Butoxide

Complexes in the Anionic Polymerization of 2-Vinylpyridine. ACS Div. Polym. Sci. Polym. Prepr., 35 (2), 576 (1994)

62. J.Q. Jin and T.E. Hogen-Esch, Stereochemistry of Polymerization of 2-Vinylpyridine

in the Presence of Lithium Alkoxide Complexes. ACS Div. Polym. Sci. Polym. Prepr., 35 (2), 593 (1994)

63. Xie, X.; Hogen-Esch, T.E. Hydrophobically Associating End-Functionalized Poly

(N,N- dimethylacrylamide). Effect of Hydrophilic Spacers. ACS Div. Polym. Sci. Polym. Prepr. 1995, 36(1), 404.

64. Gan, Y.; Dong, D.; Hogen-Esch, T.E. Synthesis and Characterization of a Catenated

Poly(Styrene) - Poly(2-Vinylpyridine) Copolymers. ” ACS Div. Polym. Sci, Polym. Prepr. 1995, 36(1), 408.

42

65. Gan, Y.; Hogen-Esch, T.E. Fluorescence Studies of Linear and Macrocyclic Polystyrene - b - Poly(2-Vinylpyridine) Copolymers. ACS Div. Polym. Sci. Polym. Prepr. 1995, 36(1), 406.

66. Dong, D.; Hogen-Esch, T.E. Synthesis of Macrocyclic Polystyrenes By End to End Coupling Below -70°C. ACS Div. Polym. Sci. Polym. Prepr. 1996, 37(1), 589.

67. Lee, J.A.; Hogen-Esch T.E. The Synthesis and Characterization of Poly(2-

vinylpyridine)-poly(dimethylsiloxane) and Poly4-vinylpyridine)-poly(dimethylsiloxane) Block Copolymers Via Anionic Polymerization. ACS Div. Polym. Sci. Polym. Prepr. 1996, 37(1), 591.

68. Dong, D.; Hogen-Esch, T.E.; Shaffer, S. Computer Simulation of α, ω-Difunctional

Living Polymer Reacting, with Linking Agent in the Presence of Termination Reaction. ACS Div. Polym. Sci. Polym. Prepr. 1996, 37(1), 593.

69. Dong, D.; Hogen-Esch, T.E. Synthesis and Characterization of Macrocyclic

Poly(alpha-methylstyrene). ACS Div. Polym. Sci. Polym. Prepr. 1996, 37(1), 595. 70. Pratt, L.M.; Khan, I.M.; Hogen-Esch, T.E. Anionic Polymerization of 2-Vinylpyridine:

A Computational Study of Solvent Effects on Polymerization Stereochemistry. ACS Div. Polym. Sci. Polym. Prepr. 1996, 37(1), 630.

71. Dimov, D.K.; Hogen-Esch, T.E. Polymerization of MMA By Copper- Based Initiators:

Nature of the Enolate Reaction Intermediates. ACS Div. Polym. Sci. Polym. Prepr. 1996, 37(1), 632.

72. Lee, J.A.; Hogen-Esch T.E. A Viscometric Study of Complex Formation of Poly(2-

vinylpyridine)-poly(dimethylsiloxane) and Poly(4-vinylpyridine-poly(dimethyl siloxane) Block Copolymers with Polyvinylphenol in THF. ). ACS Div. Polym. Sci. Polym. Prepr. 1996, 37(1), 727.

73. Zhang, H.; Hogen-Esch T.E.; Boschet, F.; Margaillan, A. Complex Formation of β-

Cyclodextrin and Telechelic Fluorocarbon Functionalized Poly(Ethylene Glycol). ACS Div. Polym. Sci. Polym. Prepr. 1996, 37(1), 729.

74. Zhang, H.; Hogen-Esch T.E.; Boschet, F.; Margaillan, A. Fluorine-19NMR and

Viscometric Studies of A Telechelic Fluorocarbon Derivative of Poly(ethylene glycol). ACS Div. Polym. Sci. Polym. Prepr. 1996, 37(1), 731.

75. Olah, G.A.; Wang, Q.; Rasul, G.; Prakash, G.K.S.; Zhang, H.; Hogen-Esch T.E.

Cationic Ring-opening Polymerization Initiated by Well-defined Trimethylsilycarboxonium or Onium Ions. ACS Div. Polym. Sci. Polym. Prepr. 1996, 37(1), 805.

76. Makino, T.; Hogen-Esch, T.E. Anionic Synthesis of Highly Isotactic Polystyrene In The Presence of Lithium Hydroxide or Lithium Alkoxides. ACS Div. Polym. Sci. Polym. Prepr. 1997, 38(1), 164.

77. Dimov, D.K.; Hogen-Esch, T.E. Termination Reactions in the

Tetraphenylphosphonium Ion Mediated Anionic Polymerization of Acrylates. ACS Div. Polym. Sci. Polym. Prepr. 1997, 38(1), 469.

78. Dimov, D.K.; Hogen-Esch, T.E. Tetraphenylphosphonium Mediated Polymerization of

Methylmethacrylate. Aspects of Initiation and Termination Reactions. ACS Div. Polym. Sci. Polym. Prepr. 1997, 38(1), 494.

79. Zhang, H.; Pan, J.; Hogen-Esch, T.E. Synthesis and Characterization of One-ended

Fluorocarbon Derivatives of Poly(ethylene glycol)s. ACS Div. Polym. Sci. Polym. Prepr. 1997, 38(1), 620.

43

80. Zagala, A.; Hogen-Esch, T.E. “Block Copolymers and a Novel Method for Preparing

Block (Co)polymers Having a Narrow molecular weight Distribution by Metal Free Anionic Polymerization in the Presence of a Phosphonium Cation.” US Patent 5,610,248, (1997).

81. Makino, T.; Tokunaga, E.; Hogen-Esch, T.E. “Controlled Atom Transfer Radical

Polymerization of Methylmethacrylate Under Micellar conditions.” ACS Div. Polym. Sci. Polym. Prepr. 1998, 39(1), 288.

82. Zhang, H.; Hogen-Esch, T.E.; Boschet, F.; Margaillan, A. “Complex Formation of β-

Cyclodextrin and Perfluorocarbon-Modified Water Soluble Polymers.” ACS Div. Polym. Sci. Polym. Prepr. 1998, 39(2), 890.

83. Pan, J.; Warner, W.; Dalton, L. R.; Hogen-Esch, T.E. “ Block Copolymerizations

Aimed at Asymmetric Self-Assembly”. ACS Div. Polym. Sci. Polym. Prepr. 1998, 39(2), 576.

84. Pan, J.; Huang, D.; Chen, M.; He, M.; Weber, W.; Dalton, L. R.; Hogen-Esch, T.E.

“Synthesis of Block Copolymers Containing Main Chain NLO Segments”. ACS Div. Polym. Sci. Polym. Prepr. 1998, 39(2), 578.

85. Pan, J.; Chen, M.; He, M.; Dalton, L. R.; Hogen-Esch, T.E. “Toward the Synthesis of

Block Copolymers Capable of H-Bond Mediated Self-Assembly”., ACS Div. Polym. Sci. Polym. Prepr. 1999, 40(1), 72.

86. Carlotti, S.; Hogen-Esch, T.E. “Cationic Polymerization of Cyclic Ethers Initiated by

Nafion”. ACS Div. Polym. Sci. Polym. Prepr. 1999, 40(1), 76. 87. Chen, M.; Pan, J.; He, M.; Hogen-Esch, T.E.; Dalton, L. R. “Novel Block Copolymers

Containing a NLO Chromophore”. ACS Div. Polym. Sci. Polym. Prepr. 1999, 40(1), 158.

88. Tomczak, S.; Hogen-Esch, T.E. “Polyacrylamides having Pendent Perfluorooctyl

Groups. Effects of Temperature, Shear and the Presence of Beta-cyclodextrin”. ACS Div. Polym. Sci. Polym. Prepr. 1999, 40(1), 163.

89. Alberty, K.; Hogen-Esch, T.E. “Novel Bifunctional Initiator for Anionic Vinyl

Polymerizations”. ACS Div. Polym. Sci. Polym. Prepr. 2000, 41(1), 81-82. 90. Nossarev, G.G.; Hogen-Esch, T. E. “Anionic Polymerization of 2-Vinyl Naphthalene”,

ACS Div. Polym. Sci. Polym. Prepr. 2000, 41(1), 135-136. 91. Prakash, G.K.S.; Hu, J.; Olah, G.A.; Warner, W.; Hogen-Esch, T.E.

“Triphenylmethyltrimethylsilyl/tetramethylammonium fluoride as a Metal-Free Anionic Polymerization Initiating System”, ACS Div. Polym. Sci. Polym. Prepr. 2000, 41(1), 204.

92. Tomczak, S.; Hogen-Esch, T.E. “Complex Formation of Beta-Cyclodextrin in Aqueous

Media with Poly (N,N-dimethylacrylamide) Containing Pendent Perfluorooctylsulfonamido Groups”. ACS Div. Polym. Sci. Polym. Prepr. 2000, 41(1), 281.

93. Hogen-Esch, T.E.; Pan, J.; Chen, M.; Dalton, L. R.; Warner, W.; He, M. “Synthesis of

Block Copolymers Containing a Main Chain Polymeric NLO Segment” ACS Div. Polym. Sci. Polym. Prepr. 2000, 41(1), 940.

44

94. Pan, J.; Hogen-Esch, T.E.; Chen, M.; Warner, W.; Dalton, L. R. “Hydrogen Bond-Mediated Self-Assembly of Block Copolymers Containing NLO Segments”, ACS Div. Polym. Sci. Polym. Prepr. 2000, 41(1), 963.

95. Tillman, E. S. and Hogen –Esch, T. E. “Coupling reactions of polystyryllithium with

dibromomethane. Comparisons with Other Dihalomethanes”. ACS Div. Polym. Sci Polym. Prepr. 2000, 41(2), 1376.

96. Nossarev, G.G.; Hogen-Esch, T. E. “Synthesis and Characterization of Macrocyclic

Poly(2-vinylnaphthalene)” ACS Div. Polym. Sci, Polym. Prepr. 2001, 42(1), 590. 97. Nossarev, G.G.; Hogen-Esch, T. E “Controlled Anionic Polymerization of 2-

Vinylnaphthalene in Toluene-Tetrahydrofuran Mixtures” ACS Div. Polym. Sci, Polym. Prepr. 2001, 42(1), 483.

98. Nossarev, G.G.; Hogen-Esch, T. E “Living Anionic Polymerization of 2-

Vinylnaphthalene in the Presence of Potassium Ion”; ACS Div. Polym. Sci, Polym. Prepr. 2001, 42(1), 516.

99. Zhang X. Hogen-Esch, T.E. “Synthesis and Anionic Polymerization of 9,9-Dimethyl-

2-vinylfluorene and 9-Methyl-9-trimethylsilyl-2-vinylfluorene” ACS Div. Polym. Sci Polym. Prepr. 2001, 42(1), 464.

100. Warner W. N.; Hogen-Esch, T.E “Synthesis of Block Copolymers of 4-(N,N-

dimethylamino)- styrene and Styrene or p-Cyanostyrene” ACS Div. Polym. Sci, Polym. Prepr. 2001, 42(1), 580.

101. “Formation of cyclic polystyrene by anionic polymerization: Fluorescence studies.”

Alberty K.A., Tillman E.S., Carlotti S, Bradforth S.E., Hogen-Esch T.E. ACS Div. Polym. Sci, Polym. Prepr. 2001, 42(1), 584.

102. Tillman, E. S. and Hogen–Esch, T. E “Evidence for Styrenic Structures in Polystyrene

Dimers Formed with Dibromomethane” ACS Div. Polym. Sci, Polym. Prepr. 2001, 42(1), 576.

103. Sandra Tomczak and Thieo E. Hogen-Esch“ Poly(N,N-dimethylacrylamide)

containing pendent perfluorooctyl groups. Reversible Hydrogel Formation with Beta-Cyclodextrin and Sodium 1-Adamantanecarboxylate” ACS Div. Polym. Sci, Polym. Prepr. 2001, 42(1),562.

104. Rong Chen And Thieo E. Hogen-Esch “Synthesis And Characterization Of Macrocyclic Poly(4-N,N-Dimethylaminostyrene)” ACS Div. Polym. Sci, Polym. Prepr. 2002, 43(2),1142.

105. Ching-An Peng, Jie Da, Yu-Chih Hsu and Thieo E. Hogen-Esch,” Macrophage

Response to Perfluorocarbon Emulsions Mediated by Polymeric Fluorosurfactants” ACS Div. Polym. Sci, Polym. Prepr. 2002, 43(2),751.

106. Chen R.; Hogen-Esch T. E. “Synthesis And Spectroscopic Studies Of Macrocyclic

Poly (9,9-Dimethyl-2-Vinylfluorene)” ACS Div. Polym. Sci, Polym. Prepr. 2003, 44(1),972.

107. Da J.; Hogen-Esch T. E. “Gel Formation In Organic Solvents: Synthesis And

Association Of Copolymers Of N,N-Dimethylac rylamide And Methacrylates Having Perfluorocarbon Pendent Groups Connected Through Polyethyleneoxide Spacers. ACS Div. Polym. Sci, Polym. Prepr. 2003, 44(1), 933.

45

108. Tomczak, S,J.; Hogen-Esch, T.E. “Fluorescence studies of hydrophobic association of fluorocarbon-modified poly(N,N-dimethylacrylamide)”. Polymer Preprints (American Chemical Society, Division of Polymer Chemistry) 2003, 44(1), 144.

109. Shen, J-‐G; Hogen-‐Esch, T. E. “ Synthesis and characterization of poly 2-‐phenyl-‐5-‐(4-‐vinylphenyl)-‐1,3,4-‐oxadiazole using atom transfer radical polymerization.” Polymer Preprints (American Chemical Society, Division of Polymer Chemistry) 2005, 46(2), 1030.

110. Hong H.; Thompson M. E.; Zhang X.;. Hogen-Esch T. E “Poly (9,9-Dimethyl-2-

vinyfluorene) as efficient hole transporters in the Organic Light Emitting Diode (OLED)” PMSE Preprs. ACS 2006, 94, 817..

111. Hogen-Esch T. E. Taylor S. M. “Synthesis and Homopolymerization of Sodium

HEMA Xanthate” Polymer Preprints (American Chemical Society, Division of Polymer Chemistry) 2006, 47(2), 664.

112. Ling, J.; Hogen-Esch, T. E. “Phosphor Ylide Mediated Polymerizations of MMA

at Ambient Temperatures with Quantitative Initiator Efficiencies” Polymer Preprints (American Chemical Society, Division of Polymer Chemistry) 2006, 47(2), 595.

113. Fomina, F.; Hogen-Esch, T. E. “End-capping of Poly-9,9’-dihexylfluorenes” ”

Polymer Preprints (American Chemical Society, Division of Polymer Chemistry) 2006, 47(2), 511.

114. Piunova, V.; Shen, J-G; Hogen-Esch, T. E. Blends of Perfluorocarbon End-

Functionalized and Telechelic Polystyrene/Poly (n-butylmethacrylate): Synthesis and Morphology Studies. PMSE Preprs. ACS, 2012, xx, xxx.

115. Olsen, J.; Hogen-Esch. T. E. “Synthesis of alkyne-functionalized helicenes as

building blocks in π-conjugated polymers.” ORGN Div. ACS NationlMeeting New Orleans April 7-11, 2013.

116. Yurdacan, H.M.; Franke, O.; Nutt, S.; Hogen-Esch, T.E. “Mechanical Properties of

Perfluoroalkyl End- or Pendent- Functionalized Polystyrene by Nanoindentation Measurements” Volume: 245 Meeting Abstract: -‐PMSE Preprs. 2013, 447 Published: APR 7 2013

Book: Recent Advances in Anionic Polymerization; Hogen-Esch, T. E., Smid, J., Ed.; Elsevier: New York, 1987.

present position. education awards and visiting …. khan, "anionic polymerization of 2-vinyl...

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