price quotation - sv seeker · description sales prod rex-sc kit qty kit price qty price per...
TRANSCRIPT
195.15
1951.53
6
73
2.08
1:1
640350815
640350807
10.0
72
2.08
1:1
640174686
640173597
10.0
START DATE: 11/23/2015
COMPLETION DATE: 03/01/2016
PURCHASE TYPE: Single Purchase
ACCOUNT NUMBER #: 3019-0749-9SV SEEKER2128 E UTE STTULSA, OK, 74110-2442(918) 630-4050
PROJECT: SV SEEKER
Kit Section
DESCRIPTION SALES PROD REX-SC KIT QTY KIT PRICE QTY
PRICE PERWORKINGGALLON/UNITPRICE
EXTENDEDPRICE
MACROPOXY 646 FAST CURE EPOXY MILL WHITE 10-GALLONKIT
620211516 I58W006100WI 40 $450.00 400.00 $45.00 $18,000.00
Additional Info
Kit Fill Gallons
MAC 646 HARD B
MAC 646 MILL WHT A
Mix Ratio
VOC
Volume Solids
SEAGUARD 5000 HS EPOXY BLACK 10-GALLON KIT 620213710 I11B003500WI 40 $394.50 400.00 $39.45 $15,780.00
Additional Info
Kit Fill Gallons
SG 5000HS BLACK PT A
SG 5000HS PART B
Mix Ratio
VOC
Volume Solids
DFT
CoverageSqftPerKit
CoverageSqftPerWorkingGallon
PRICE QUOTATION
11/23/2015Quote #: 2473444
We are Pleased to quote you as follows:
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DESCRIPTION SALES PROD REX-SC KIT QTY KIT PRICE QTY
PRICE PERWORKINGGALLON / UNITPRICE
EXTENDEDPRICE
Total: $33,780.00
We thank you for your consideration of Sherwin-Williams products and look forward to supplying these products to you.
TERMS OF THE SALE #:By: Stephen B Hallum
Quote Expires: 03/01/2016Store Address: 3699 S 73RD EAST AVE
City: TULSA, State: OK, ZIP: 74145-3231Phone: (918) 664-5694
Terms: As Agreed
NOTICE: Please take notice that the quotation set forth above is not a contract and is subject to and conditioned upon approval by Sherwin Williams. In the event suchapproval is not obtained, you will be provided with a revised quotation and the quotation set forth above shall be null, void and of no force or effect. The pricing andrecommendations detailed in this proposal represent confidential information provided by Sherwin Williams. We request that it not to be copied or shared with othersoutside your firm.Please refer to product data pages for surface prep, mixing and application instructions.Square footage amounts were estimated or given. Coverage of materials are estimated and actual coverages may differ. These guidelines should not be usedas absolutes. The Sherwin-Williams cannot assume responsibility for job site conditions.
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Data Pages
3 of 73
Revised: Sept. 29, 2015
MACROPOXY® 646FAST CURE EPOXY
PART A B58-600 SERiES
PART B B58V600 HARdEnER
Protective &
MarineCoatings
4.53
www.sherwin-williams.com/protective
Product descriPtionMACROPOXY 646 FAST CURE EPOXY is a high solids, high build, fast drying, polyamide epoxy designed to protect steel and concrete in industrial exposures. Ideal for maintenance painting and fabrica-tion shop applications. The high solids content ensures adequate protection of sharp edges, corners, and welds. This product can be applied directly to marginally prepared steel surfaces.• LowVOC • Chemicalresistant• Lowodor • Abrasionresistant• Outstandingapplicationproperties• MeetsClassArequirementsforSlipCoefficient,0.36@6mils/150micronsdft(MillWhiteonly)
Product characteristicsFinish: Semi-GlossColor: MillWhite,Blackandawiderange of colors available through tintingVolume Solids: 72%±2%,mixed,MillWhiteWeight Solids: 85%±2%,mixed,MillWhiteVOC (EPA Method 24): Unreduced: <250g/L;2.08lb/gal mixed Reduced10%: <300g/L;2.50lb/galMix Ratio: 1:1 by volume
Recommended Spreading Rate per coat:Minimum Maximum
Wet mils(microns) 7.0 (175) 13.5 (338)Dry mils(microns) 5.0* (125) 10.0* (250)~Coverage sq ft/gal (m2/L) 116 (2.8) 232 (5.7)Theoretical coverage sq ft/gal (m2/L)@1mil/25micronsdft 1152 (28.2)*May be applied at 3.0-10.0 mils (75-250 microns) dft as an interme-diate coat in a multi-coat system. Refer to Recommended Systems (page 2). See Performance Tips section also.
NOTE: Brush or roll application may require multiple coats to achieve maximum film thickness and uniformity of appearance.
Drying Schedule @ 7.0 mils wet (175 microns):@ 35°F/1.7°C @ 77°F/25°C @ 100°F/38°C
50% RHTo touch: 4-5 hours 2 hours 1.5 hoursTo handle: 48 hours 8 hours 4.5 hoursTo recoat:
minimum: 48 hours 8 hours 4.5 hoursmaximum: 1 year 1 year 1 year
To cure:Service: 10 days 7 days 4 days
Immersion: 14 days 7 days 4 daysIf maximum recoat time is exceeded, abrade surface before recoating.
Drying time is temperature, humidity, and film thickness dependent.Paint temperature must be at least 40°F(4.5°C)minimum.Pot Life: 10 hours 4 hours 2 hoursSweat-in-time: 30 minutes 30 minutes 15 minutes
When used as an intermediate coat as part of a multi-coat system:
Drying Schedule @ 5.0 mils wet (125 microns):@ 35°F/1.7°C @ 77°F/25°C @ 100°F/38°C
50% RHTo touch: 3 hours 1 hour 1 hourTo handle: 48 hours 4 hours 2 hoursTo recoat:
minimum: 16hours 4 hours 2 hoursmaximum: 1 year 1 year 1 year
continuedonback
Product characteristics (cont'd)
Shelf Life: 36months,unopenedStore indoors at 40°F (4.5°C)to 110°F (43°C).
Flash Point: 91°F(33°C),TCC,mixedReducer/Clean Up:InCalifornia:
Reducer, R7K15ReducerR7K111orOxsol100
Performance characteristics
Substrate*: SteelSurface Preparation*:SSPC-SP10/NACE2System Tested*: [email protected](150microns) dft
*unless otherwise noted belowTest Name Test Method Results
Abrasion Resistance ASTMD4060,CS17wheel,1000cycles,1kgload
84 mg loss
Accelerated Weathering-QUV1
ASTMD4587,QUV-A,12,000 hours Passes
Adhesion ASTMD4541 1,037 psi
Corrosion Weathering1 ASTMD5894,36cycles,12,000 hours
Rating10perASTMD714forblistering;Rating9perASTMD610perrusting
Nuclear Decontamination
ASTMD4256/ANSIN5.12
99%WaterWash;95%Overall
Direct Impact Resistance2 ASTMD2794 120 in. lb.Dry Heat Resistance ASTMD2485 250°F (121°C)Exterior Durability 1 year at 45° South Excellent,chalks
Flexibility ASTMD522,180° bend, 3/4" mandrel Passes
Fuel Contribution NFPA259 5764btu/lb
Humidity Resistance ASTMD4585,6000hours
Noblistering,cracking,orrusting
Immersion 1 year fresh and salt water
Passes, no rusting, blistering, or loss of adhesion
Radiation Tolerance ASTMD4082/ANSI5.12
Pass at 21 mils (525 microns)
Pencil Hardness ASTMD3363 3H
Salt Fog Resistance1 ASTMB117,6,500hours
Rating10perASTMD610forrusting;Rating9perASTMD1654forcorrosion
Slip Coefficient, Mill White*
AISCSpecificationforStruc-turalJointsUsingASTMA325orASTMA490Bolts
ClassA,0.36
Surface Burning ASTME84/NFPA255FlameSpreadIndex20;SmokeDevelopmentIndex 35 (at 18 mils or 450microns)
Water Vapor Permeance ASTMD1653,MethodB 1.16USpermsEpoxycoatingsmaydarkenordiscolorfollowingapplicationandcuring.*RefertoSlipCertificationdocumentFootnotes:1 Zinc Clad II Plus Primer2 Two coats of Macropoxy646FastCureEpoxy
disclaimerTheinformationandrecommendationssetforthinthisProductDataSheetarebasedupontestsconductedbyoronbehalfofTheSherwin-WilliamsCompany.Suchinformationandrecommendationssetforthhereinaresubjecttochangeandpertaintotheproductofferedatthetimeofpublication.ConsultyourSherwin-WilliamsrepresentativetoobtainthemostrecentProductDataInformationandApplicationBulletin.
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Revised: Sept. 29, 2015
MACROPOXY® 646FAST CURE EPOXY
PART A B58-600 SERiES
PART B B58V600 HARdEnER
Protective &
MarineCoatings
4.53
www.sherwin-williams.com/protective
surface PreParationSurface must be clean, dry, and in sound condition. Remove all oil, dust, grease, dirt, loose rust, and other foreign material to ensure adequate adhesion.
Refer toproductApplicationBulletin fordetailedsurfacepreparation in-formation.Minimumrecommendedsurfacepreparation: Iron & Steel Atmospheric: SSPC-SP2/3 Immersion: SSPC-SP10/NACE2,2-3mil(50-75micron)profile Aluminum: SSPC-SP1 Galvanizing: SSPC-SP1;SeeSurfacePreparationssectionon page3forapplicationofFIRETEXintumescent coating systems Concrete&Masonry Atmospheric: SSPC-SP13/NACE6,orICRINo.310.2R,CSP1-3 Immersion: SSPC-SP13/NACE6-4.3.1or4.3.2,or ICRINo.310.2R,CSP2-4
Surface Preparation StandardsCondition of Surface
ISO 8501-1BS7079:A1
Swedish Std.SIS055900 SSPC NACE
WhiteMetal Sa 3 Sa 3 SP 5 1NearWhiteMetal Sa 2.5 Sa 2.5 SP 10 2CommercialBlast Sa 2 Sa 2 SP6 3Brush-OffBlast Sa 1 Sa 1 SP 7 4HandToolCleaning Rusted CSt2 CSt2 SP 2 -
Pitted & Rusted DSt2 DSt2 SP 2 -PowerToolCleaning Rusted CSt3 CSt3 SP 3 -
Pitted & Rusted DSt3 DSt3 SP 3 -
tintingTintPartAwithMaxitonersat150%strength.Fiveminutesminimummix-ingonamechanicalshakerisrequiredforcompletemixingofcolor.
Tinting is not recommended for immersion service.
aPPlication conditionsTemperature: 35°F(1.7°C)minimum,120°F(49°C) maximum(airandsurface) 40°F(4.5°C)minimum,120°F(49°C) maximum(material) Atleast5°F(2.8°C)abovedewpointRelative humidity: 85% maximum
RefertoproductApplicationBulletinfordetailedapplicationinformation.
ordering informationPackaging: PartA: 1gallon(3.78L)and5gallon(18.9L)containers PartB: 1gallon(3.78L)and5gallon(18.9L)containers
Weight: 12.9±0.2lb/gal;1.55Kg/L mixed, may vary by color
safety Precautions
RefertotheMSDSsheetbeforeuse.Publishedtechnicaldataandinstructionsaresubjecttochangewithoutnotice.ContactyourSherwin-Williamsrepresentativeforadditionaltechnicaldataandinstructions.
WarrantyTheSherwin-WilliamsCompanywarrantsourproductstobefreeofmanufactur-ingdefectsinaccordwithapplicableSherwin-Williamsqualitycontrolprocedures.Liabilityforproductsprovendefective,ifany,islimitedtoreplacementofthedefec-tive product or the refund of the purchase price paid for the defective product as determinedbySherwin-Williams.NOOTHERWARRANTYORGUARANTEEOFANYKINDISMADEBYSHERWIN-WILLIAMS,EXPRESSEDORIMPLIED,STATUTORY,BYOPERATIONOFLAWOROTHERWISE,INCLUDINGMER-CHANTABILITYANDFITNESSFORAPARTICULARPURPOSE.
PROdUCT inFORMATiOnrecommended uses
• Marineapplications• Fabricationshops • Refineries• Pulpandpapermills • Chemicalplants• Powerplants • Tankexteriors• Offshoreplatforms • Watertreatmentplants• NuclearPowerPlants • DOENuclearFuelFacilities• Nuclearfabricationshops • DOENuclearWeaponsFacilities• MillWhiteandBlackareacceptableforimmersionuseforsalt water and fresh water, not acceptable for potable water• SuitableforuseinUSDAinspectedfacilities• AcceptableforuseinCanadianFoodProcessingfacilities,categories:D1,D2,D3(Confirmacceptanceofspecificpartnumbers/rexeswithyourSWSalesRepresentative)
• ConformstoAWWAD102OCS#5• ConformstoMPI#108• Thisproductmeetsspecificdesignrequirementsfornon-safetyrelatednuclearplantapplicationsinLevelII,IIIandBalanceofPlant,andDOEnuclearfacilities*.
*NuclearqualificationsareNRClicensespecifictothefacility.• SuitableforuseintheMining&MineralsIndustry• Acceptableforuseoverand/orunderLoxonS1andLoxonH1Caulking
recommended systems Dry Film Thickness / ct. Mils (Microns)Immersion and atmospheric:Steel:2cts. Macropoxy646FastCureEpoxy 5.0-10.0 (125-250)Concrete/Masonry, smooth:2cts. Macropoxy646FastCureEpoxy 5.0-10.0 (125-250)Concrete Block:1ct. KemCati-CoatHSEpoxy 10.0-20.0 (250-500) Filler/Sealer as needed to fill voids and provide a continuous substrate.2cts. Macropoxy646FastCureEpoxy 5.0-10.0 (125-250)Atmospheric:Steel: (Shopappliedsystem,newconstruction,AWWAD102,canalsobeused at 3 mils / 75 microns minimum dft when used as an intermediatecoataspartofamulti-coatsystem)1ct. Macropoxy646FastCureEpoxy 3.0-6.0 (75-150)1-2 cts. of recommended topcoatSteel:1ct. RecoatableEpoxyPrimer 4.0-6.0 (100-150)2cts. Macropoxy646FastCureEpoxy 5.0-10.0 (125-250)Steel:1 ct. Macropoxy646FastCureEpoxy 5.0-10.0 (125-250)1-2cts. Acrolon218Polyurethane 3.0-6.0 (75-150) or Hi-SolidsPolyurethane 3.0-5.0 (75-125) or SherThane2KUrethane 2.0-4.0 (50-100) or Hydrogloss 2.0-4.0 (50-100)Steel:2cts. Macropoxy646FastCureEpoxy 5.0-10.0 (125-250)1-2cts. Tile-CladHSEpoxy 2.5-4.0 (63-100)Steel:1ct. ZincCladIIPlus 2.0-4.0 (50-100)1 ct. Macropoxy646FastCureEpoxy 5.0-10.0 (125-250)1-2cts. Acrolon218Polyurethane 3.0-6.0 (75-150)Steel:1ct. ZincCladIIIHS 3.0-5.0 (75-125) or ZincCladIV 3.0-5.0 (75-125)1 ct. Macropoxy646FastCureEpoxy 3.0-10.0 (75-250)1-2cts. Acrolon218Polyurethane 3.0-6.0 (75-150)Aluminum:2cts. Macropoxy646FastCureEpoxy 5.0-10.0 (125-250)Galvanizing:2cts. Macropoxy646FastCureEpoxy 5.0-10.0 (125-250)FIRETEX M89/02, M90, M90/02, and M93/02:Steel & Galvanized Substrates being primed for FIRETEX only:1 ct. Macropoxy646FastCureEpoxy 2.0-5.0 (50-125)The systems listed above are representative of the product's use, other systems may be appropriate.
5 of 73
Revised: Sept. 29, 2015
MACROPOXY® 646FAST CURE EPOXY
PART A B58-600 SERiES
PART B B58V600 HARdEnER
Protective &
MarineCoatings
4.53
www.sherwin-williams.com/protective
surface PreParationsSurface must be clean, dry, and in sound condition. Remove all oil, dust, grease, dirt, loose rust, and other foreign material to ensure adequate adhesion.Iron & Steel, Atmospheric Service:Minimumsurface preparation isHandToolClean perSSPC-SP2.Remove all oil and grease from surface bySolventCleaning perSSPC-SP1.Forbetterperformance,useCommercialBlastCleaningperSSPC-SP6/NACE3,blastcleanallsurfacesusingasharp,angularabrasiveforoptimumsurfaceprofile(2mils/50microns).Primeanybaresteelwithin8hoursorbeforeflashrustingoccurs.Iron & Steel, Immersion Service:Remove all oil and grease from surface bySolventCleaning perSSPC-SP1.MinimumsurfacepreparationisNearWhiteMetalBlastCleaningperSSPC-SP10/NACE2.Blastcleanallsurfacesusingasharp,angularabrasiveforoptimumsurfaceprofile(2-3mils/50-75microns).Removeallweldspatterandroundallsharpedgesbygrind-ing. Prime any bare steel the same day as it is cleaned.AluminumRemove all oil, grease, dirt, oxide and other foreign material by Solvent CleaningperSSPC-SP1.Galvanized SteelAllowtoweatheraminimumofsixmonthspriortocoating.SolventCleanperSSPC-SP1(recommendedsolventisVM&PNaphtha).Whenweathering is not possible, or the surface has been treated with chro-matesorsilicates,firstSolventCleanperSSPC-SP1andapplyatestpatch.Allowpainttodryatleastoneweekbeforetestingadhesion.Ifadhesionispoor,brushblastingperSSPC-SP7isnecessarytoremovethese treatments. Rusty galvanizing requires a minimum of Hand Tool CleaningperSSPC-SP2,primetheareathesamedayascleaned.InpreparinggalvanizedsteelsubstratesfortheapplicationofFIRE-TEXintumescentcoatingsystems,SurfacePreparationSpecificationSSPC-SP16mustbefollowedobtainingasurfaceprofileofminimum1.5mils(38microns).Optimumsurfaceprofilewillnotexceed2.0mils(50microns).Concrete and MasonryForsurfacepreparation, refer toSSPC-SP13/NACE6,or ICRINo.310.2R,CSP 1-3. Surfaces should be thoroughly clean and dry.Concreteandmortarmustbecuredatleast28days@75°F(24°C).Remove all loose mortar and foreign material. Surface must be free of laitance, concrete dust, dirt, form release agents, moisture curing membranes,loosecementandhardeners.Fillbugholes,airpocketsand other voids with Steel-Seam FT910. Concrete, Immersion Service:Forsurfacepreparation,refertoSSPC-SP13/NACE6,Section4.3.1or1.3.2orICRINo.310.2R,CSP2-4.Follow the standard methods listed below when applicable:ASTMD4258StandardPracticeforCleaningConcrete.ASTMD4259StandardPracticeforAbradingConcrete.ASTMD4260StandardPracticeforEtchingConcrete.ASTMF1869StandardTestMethod forMeasuringMoistureVaporEmissionRateofConcrete.SSPC-SP13/Nace6SurfacePreparationofConcrete.ICRINo.310.2RConcreteSurfacePreparation.Previously Painted SurfacesIf in sound condition, clean the surface of all foreign material. Smooth, hard or glossy coatings and surfaces should be dulled by abrading the surface.Applyatestarea,allowingpainttodryoneweekbeforetestingadhesion.Ifadhesionispoor,orifthisproductattacksthepreviousfinish,removalofthepreviouscoatingmaybenecessary.Ifpaintispeeling or badly weathered, clean surface to sound substrate and treat as a new surface as above.
Surface Preparation StandardsCondition of Surface
ISO 8501-1BS7079:A1
Swedish Std.SIS055900 SSPC NACE
WhiteMetal Sa 3 Sa 3 SP 5 1NearWhiteMetal Sa 2.5 Sa 2.5 SP 10 2CommercialBlast Sa 2 Sa 2 SP6 3Brush-OffBlast Sa 1 Sa 1 SP 7 4HandToolCleaning Rusted CSt2 CSt2 SP 2 -
Pitted & Rusted DSt2 DSt2 SP 2 -PowerToolCleaning Rusted CSt3 CSt3 SP 3 -
Pitted & Rusted DSt3 DSt3 SP 3 -
APPliCATiOn BUllETin
aPPlication conditions
Temperature: 35°F (1.7°C)minimum,120°F (49°C) maximum(airandsurface) 40°F(4.5°C)minimum,120°F(49°C) maximum(material) Atleast5°F(2.8°C)abovedewpoint
Relative humidity: 85% maximum
aPPlication equiPment
Thefollowingisaguide.Changesinpressuresandtipsizesmaybeneededforproperspraycharacteristics.Alwayspurgesprayequipmentbeforeusewithlistedreducer.AnyreductionmustbecompliantwithexistingVOCregulationsandcompatiblewiththeexisting environmental and application conditions.
Reducer/Clean Up ...........Reducer R7K15 InCalifornia ....................Reducer R7K111
Airless Spray Pump..............................30:1 Pressure.........................2800 - 3000 psi Hose...............................1/4"ID Tip ...................................017" - .023" Filter ...............................60mesh Reduction .......................Asneededupto10%byvolume
Conventional Spray Gun ................................DeVilbissMBC-510 Fluid Tip .........................E AirNozzle.......................704 AtomizationPressure .....60-65psi Fluid Pressure ................10-20 psi Reduction .......................Asneededupto10%byvolume Requires oil and moisture separators
Brush Brush..............................Nylon/PolyesterorNaturalBristle Reduction .......................Asneededupto10%byvolume
Roller Cover .............................3/8" woven with solvent resistant core Reduction .......................Asneededupto10%byvolume
Plural Component Spray ...Acceptable RefertoApril2010TechnicalBulletin-"ApplicationGuidelines for Macropoxy646FastCureEpoxy&RecoatableEpoxy Primer Utilizing Plural ComponentEquipment" Ifspecificapplicationequipmentisnotlistedabove,equivalent equipment may be substituted.
continuedonback
6 of 73
Revised: Sept. 29, 2015
MACROPOXY® 646FAST CURE EPOXY
PART A B58-600 SERiES
PART B B58V600 HARdEnER
Protective &
MarineCoatings
4.53
www.sherwin-williams.com/protective
APPliCATiOn BUllETin
aPPlication ProceduresSurface preparation must be completed as indicated.Mixcontentsofeachcomponentthoroughlywithlowspeedpoweragitation.Makecertainnopigmentremainsonthebottomofthecan.ThencombineonepartbyvolumeofPartAwithonepartbyvolumeofPartB.Thoroughlyagitatethemixturewithpoweragitation.Allowthematerialtosweat-inasindicatedpriortoap-plication. Re-stir before using.If reducer solvent is used, add only after both components have been thoroughly mixed, after sweat-in.Applypaintattherecommendedfilmthicknessandspreadingrate as indicated below:
Recommended Spreading Rate per coat:Minimum Maximum
Wet mils(microns) 7.0 (175) 13.5 (338)Dry mils(microns) 5.0* (125) 10.0* (250)~Coverage sq ft/gal (m2/L) 116 (2.8) 232 (5.7)Theoretical coverage sq ft/gal (m2/L)@1mil/25micronsdft 1152 (28.2)*May be applied at 3.0-10.0 mils (75-250 microns) dft in atmo-spheric conditions. Refer to Recommended Systems (page 2). See Performance Tips section also.
NOTE: Brush or roll application may require multiple coats to achieve maximum film thickness and uniformity of appearance.
Drying Schedule @ 7.0 mils wet (175 microns):@ 35°F/1.7°C @ 77°F/25°C @ 100°F/38°C
50% RHTo touch: 4-5 hours 2 hours 1.5 hoursTo handle: 48 hours 8 hours 4.5 hoursTo recoat:
minimum: 48 hours 8 hours 4.5 hoursmaximum: 1 year 1 year 1 year
To cure:Service: 10 days 7 days 4 days
Immersion: 14 days 7 days 4 daysIf maximum recoat time is exceeded, abrade surface before recoating.
Drying time is temperature, humidity, and film thickness dependent.Paint temperature must be at least 40°F(4.5°C)minimum.Pot Life: 10 hours 4 hours 2 hoursSweat-in-time: 30 minutes 30 minutes 15 minutes
When used as an intermediate coat as part of a multi-coat system:
Drying Schedule @ 5.0 mils wet (125 microns):@ 35°F/1.7°C @ 77°F/25°C @ 100°F/38°C
50% RHTo touch: 3 hours 1 hour 1 hourTo handle: 48 hours 4 hours 2 hoursTo recoat:
minimum: 16hours 4 hours 2 hoursmaximum: 1 year 1 year 1 year
Applicationofcoatingabovemaximumorbelowminimumrecommendedspreading rate may adversely affect coating performance.
clean uP instructionsCleanspillsandspattersimmediatelywithReducerR7K15.CleantoolsimmediatelyafterusewithReducerR7K15.InCaliforniauseReducerR7K111. Follow manufacturer's safety recommendations when using any solvent.
Performance tiPsStripe coat all crevices, welds, and sharp angles to prevent early failure in these areas.Whenusingsprayapplication,usea50%overlapwitheachpassof the gun to avoid holidays, bare areas, and pinholes. If necessary, cross spray at a right angleSpreading rates are calculated on volume solids and do not include anapplicationlossfactorduetosurfaceprofile,roughnessorpo-rosityofthesurface,skillandtechniqueoftheapplicator,methodof application, various surface irregularities, material lost during mixing, spillage, overthinning, climatic conditions, and excessive filmbuild.Excessivereductionofmaterialcanaffectfilmbuild,appearance,and adhesion.Donotmixpreviouslycatalyzedmaterialwithnew.Donotapplythematerialbeyondrecommendedpotlife.Inordertoavoidblockageofsprayequipment,cleanequipmentbefore use or before periods of extended downtime with Reducer R7K15.InCaliforniauseReducerR7K111.Tinting is not recommended for immersion service.UseonlyMillWhiteandBlackforimmersionservice.Insufficientventilation,incompletemixing,miscatalyzation,andexternal heaters may cause premature yellowing.Excessivefilmbuild,poorventilation,andcooltemperaturesmaycause solvent entrapment and premature coating failure.Quik-KickEpoxyAcceleratorisacceptableforuse.Seedatapage4.99 for details.Whencoatingoveraluminumandgalvanizing,recommendeddftis2-4mils(50-100microns).AcceptableforConcreteFloors.Canbeusedasametalizingsealer.ConsultTechnicalBulletin-SealersforThermalSprayMetalizing,oryourlocalSherwin-Williamsrepresentative.Refer to Product Information sheet for additional performance characteristics and properties.
safety PrecautionsRefertotheMSDSsheetbeforeuse.Publishedtechnicaldataandinstructionsaresubjecttochangewithoutnotice.ContactyourSherwin-Williamsrepresentativeforadditionaltechnicaldataandinstructions.
disclaimerTheinformationandrecommendationssetforthinthisProductDataSheetarebasedupontestsconductedbyoronbehalfofTheSherwin-WilliamsCompany.Suchinformationandrecommendationssetforthhereinaresubjecttochangeandpertaintotheproductofferedatthetimeofpublication.ConsultyourSherwin-WilliamsrepresentativetoobtainthemostrecentProductDataInformationandApplicationBulletin.
WarrantyTheSherwin-WilliamsCompanywarrantsourproductstobefreeofmanufacturingdefects inaccordwithapplicableSherwin-Williamsqualitycontrolprocedures.Liabilityforproductsprovendefective,ifany,islimitedtoreplacementofthede-fective product or the refund of the purchase price paid for the defective product asdeterminedbySherwin-Williams.NOOTHERWARRANTYORGUARANTEEOFANYKINDISMADEBYSHERWIN-WILLIAMS,EXPRESSEDORIMPLIED,STATUTORY,BYOPERATIONOFLAWOROTHERWISE,INCLUDINGMER-CHANTABILITYANDFITNESSFORAPARTICULARPURPOSE.
7 of 73
Revised: Sept. 29, 2015
MACROPOXY® 646FAST CURE EPOXY
PART A B58-600 SERiES
PART B B58V600 HARdEnER
Protective &
MarineCoatings
4.53
www.sherwin-williams.com/protective
Product descriPtionMACROPOXY 646 FAST CURE EPOXY is a high solids, high build, fast drying, polyamide epoxy designed to protect steel and concrete in industrial exposures. Ideal for maintenance painting and fabrica-tion shop applications. The high solids content ensures adequate protection of sharp edges, corners, and welds. This product can be applied directly to marginally prepared steel surfaces.• LowVOC • Chemicalresistant• Lowodor • Abrasionresistant• Outstandingapplicationproperties• MeetsClassArequirementsforSlipCoefficient,0.36@6mils/150micronsdft(MillWhiteonly)
Product characteristicsFinish: Semi-GlossColor: MillWhite,Blackandawiderange of colors available through tintingVolume Solids: 72%±2%,mixed,MillWhiteWeight Solids: 85%±2%,mixed,MillWhiteVOC (EPA Method 24): Unreduced: <250g/L;2.08lb/gal mixed Reduced10%: <300g/L;2.50lb/galMix Ratio: 1:1 by volume
Recommended Spreading Rate per coat:Minimum Maximum
Wet mils(microns) 7.0 (175) 13.5 (338)Dry mils(microns) 5.0* (125) 10.0* (250)~Coverage sq ft/gal (m2/L) 116 (2.8) 232 (5.7)Theoretical coverage sq ft/gal (m2/L)@1mil/25micronsdft 1152 (28.2)*May be applied at 3.0-10.0 mils (75-250 microns) dft as an interme-diate coat in a multi-coat system. Refer to Recommended Systems (page 2). See Performance Tips section also.
NOTE: Brush or roll application may require multiple coats to achieve maximum film thickness and uniformity of appearance.
Drying Schedule @ 7.0 mils wet (175 microns):@ 35°F/1.7°C @ 77°F/25°C @ 100°F/38°C
50% RHTo touch: 4-5 hours 2 hours 1.5 hoursTo handle: 48 hours 8 hours 4.5 hoursTo recoat:
minimum: 48 hours 8 hours 4.5 hoursmaximum: 1 year 1 year 1 year
To cure:Service: 10 days 7 days 4 days
Immersion: 14 days 7 days 4 daysIf maximum recoat time is exceeded, abrade surface before recoating.
Drying time is temperature, humidity, and film thickness dependent.Paint temperature must be at least 40°F(4.5°C)minimum.Pot Life: 10 hours 4 hours 2 hoursSweat-in-time: 30 minutes 30 minutes 15 minutes
When used as an intermediate coat as part of a multi-coat system:
Drying Schedule @ 5.0 mils wet (125 microns):@ 35°F/1.7°C @ 77°F/25°C @ 100°F/38°C
50% RHTo touch: 3 hours 1 hour 1 hourTo handle: 48 hours 4 hours 2 hoursTo recoat:
minimum: 16hours 4 hours 2 hoursmaximum: 1 year 1 year 1 year
continuedonback
Product characteristics (cont'd)
Shelf Life: 36months,unopenedStore indoors at 40°F (4.5°C)to 110°F (43°C).
Flash Point: 91°F(33°C),TCC,mixedReducer/Clean Up:InCalifornia:
Reducer, R7K15ReducerR7K111orOxsol100
Performance characteristics
Substrate*: SteelSurface Preparation*:SSPC-SP10/NACE2System Tested*: [email protected](150microns) dft
*unless otherwise noted belowTest Name Test Method Results
Abrasion Resistance ASTMD4060,CS17wheel,1000cycles,1kgload
84 mg loss
Accelerated Weathering-QUV1
ASTMD4587,QUV-A,12,000 hours Passes
Adhesion ASTMD4541 1,037 psi
Corrosion Weathering1 ASTMD5894,36cycles,12,000 hours
Rating10perASTMD714forblistering;Rating9perASTMD610perrusting
Nuclear Decontamination
ASTMD4256/ANSIN5.12
99%WaterWash;95%Overall
Direct Impact Resistance2 ASTMD2794 120 in. lb.Dry Heat Resistance ASTMD2485 250°F (121°C)Exterior Durability 1 year at 45° South Excellent,chalks
Flexibility ASTMD522,180° bend, 3/4" mandrel Passes
Fuel Contribution NFPA259 5764btu/lb
Humidity Resistance ASTMD4585,6000hours
Noblistering,cracking,orrusting
Immersion 1 year fresh and salt water
Passes, no rusting, blistering, or loss of adhesion
Radiation Tolerance ASTMD4082/ANSI5.12
Pass at 21 mils (525 microns)
Pencil Hardness ASTMD3363 3H
Salt Fog Resistance1 ASTMB117,6,500hours
Rating10perASTMD610forrusting;Rating9perASTMD1654forcorrosion
Slip Coefficient, Mill White*
AISCSpecificationforStruc-turalJointsUsingASTMA325orASTMA490Bolts
ClassA,0.36
Surface Burning ASTME84/NFPA255FlameSpreadIndex20;SmokeDevelopmentIndex 35 (at 18 mils or 450microns)
Water Vapor Permeance ASTMD1653,MethodB 1.16USpermsEpoxycoatingsmaydarkenordiscolorfollowingapplicationandcuring.*RefertoSlipCertificationdocumentFootnotes:1 Zinc Clad II Plus Primer2 Two coats of Macropoxy646FastCureEpoxy
disclaimerTheinformationandrecommendationssetforthinthisProductDataSheetarebasedupontestsconductedbyoronbehalfofTheSherwin-WilliamsCompany.Suchinformationandrecommendationssetforthhereinaresubjecttochangeandpertaintotheproductofferedatthetimeofpublication.ConsultyourSherwin-WilliamsrepresentativetoobtainthemostrecentProductDataInformationandApplicationBulletin.
8 of 73
Revised: Sept. 29, 2015
MACROPOXY® 646FAST CURE EPOXY
PART A B58-600 SERiES
PART B B58V600 HARdEnER
Protective &
MarineCoatings
4.53
www.sherwin-williams.com/protective
surface PreParationSurface must be clean, dry, and in sound condition. Remove all oil, dust, grease, dirt, loose rust, and other foreign material to ensure adequate adhesion.
Refer toproductApplicationBulletin fordetailedsurfacepreparation in-formation.Minimumrecommendedsurfacepreparation: Iron & Steel Atmospheric: SSPC-SP2/3 Immersion: SSPC-SP10/NACE2,2-3mil(50-75micron)profile Aluminum: SSPC-SP1 Galvanizing: SSPC-SP1;SeeSurfacePreparationssectionon page3forapplicationofFIRETEXintumescent coating systems Concrete&Masonry Atmospheric: SSPC-SP13/NACE6,orICRINo.310.2R,CSP1-3 Immersion: SSPC-SP13/NACE6-4.3.1or4.3.2,or ICRINo.310.2R,CSP2-4
Surface Preparation StandardsCondition of Surface
ISO 8501-1BS7079:A1
Swedish Std.SIS055900 SSPC NACE
WhiteMetal Sa 3 Sa 3 SP 5 1NearWhiteMetal Sa 2.5 Sa 2.5 SP 10 2CommercialBlast Sa 2 Sa 2 SP6 3Brush-OffBlast Sa 1 Sa 1 SP 7 4HandToolCleaning Rusted CSt2 CSt2 SP 2 -
Pitted & Rusted DSt2 DSt2 SP 2 -PowerToolCleaning Rusted CSt3 CSt3 SP 3 -
Pitted & Rusted DSt3 DSt3 SP 3 -
tintingTintPartAwithMaxitonersat150%strength.Fiveminutesminimummix-ingonamechanicalshakerisrequiredforcompletemixingofcolor.
Tinting is not recommended for immersion service.
aPPlication conditionsTemperature: 35°F(1.7°C)minimum,120°F(49°C) maximum(airandsurface) 40°F(4.5°C)minimum,120°F(49°C) maximum(material) Atleast5°F(2.8°C)abovedewpointRelative humidity: 85% maximum
RefertoproductApplicationBulletinfordetailedapplicationinformation.
ordering informationPackaging: PartA: 1gallon(3.78L)and5gallon(18.9L)containers PartB: 1gallon(3.78L)and5gallon(18.9L)containers
Weight: 12.9±0.2lb/gal;1.55Kg/L mixed, may vary by color
safety Precautions
RefertotheMSDSsheetbeforeuse.Publishedtechnicaldataandinstructionsaresubjecttochangewithoutnotice.ContactyourSherwin-Williamsrepresentativeforadditionaltechnicaldataandinstructions.
WarrantyTheSherwin-WilliamsCompanywarrantsourproductstobefreeofmanufactur-ingdefectsinaccordwithapplicableSherwin-Williamsqualitycontrolprocedures.Liabilityforproductsprovendefective,ifany,islimitedtoreplacementofthedefec-tive product or the refund of the purchase price paid for the defective product as determinedbySherwin-Williams.NOOTHERWARRANTYORGUARANTEEOFANYKINDISMADEBYSHERWIN-WILLIAMS,EXPRESSEDORIMPLIED,STATUTORY,BYOPERATIONOFLAWOROTHERWISE,INCLUDINGMER-CHANTABILITYANDFITNESSFORAPARTICULARPURPOSE.
PROdUCT inFORMATiOnrecommended uses
• Marineapplications• Fabricationshops • Refineries• Pulpandpapermills • Chemicalplants• Powerplants • Tankexteriors• Offshoreplatforms • Watertreatmentplants• NuclearPowerPlants • DOENuclearFuelFacilities• Nuclearfabricationshops • DOENuclearWeaponsFacilities• MillWhiteandBlackareacceptableforimmersionuseforsalt water and fresh water, not acceptable for potable water• SuitableforuseinUSDAinspectedfacilities• AcceptableforuseinCanadianFoodProcessingfacilities,categories:D1,D2,D3(Confirmacceptanceofspecificpartnumbers/rexeswithyourSWSalesRepresentative)
• ConformstoAWWAD102OCS#5• ConformstoMPI#108• Thisproductmeetsspecificdesignrequirementsfornon-safetyrelatednuclearplantapplicationsinLevelII,IIIandBalanceofPlant,andDOEnuclearfacilities*.
*NuclearqualificationsareNRClicensespecifictothefacility.• SuitableforuseintheMining&MineralsIndustry• Acceptableforuseoverand/orunderLoxonS1andLoxonH1Caulking
recommended systems Dry Film Thickness / ct. Mils (Microns)Immersion and atmospheric:Steel:2cts. Macropoxy646FastCureEpoxy 5.0-10.0 (125-250)Concrete/Masonry, smooth:2cts. Macropoxy646FastCureEpoxy 5.0-10.0 (125-250)Concrete Block:1ct. KemCati-CoatHSEpoxy 10.0-20.0 (250-500) Filler/Sealer as needed to fill voids and provide a continuous substrate.2cts. Macropoxy646FastCureEpoxy 5.0-10.0 (125-250)Atmospheric:Steel: (Shopappliedsystem,newconstruction,AWWAD102,canalsobeused at 3 mils / 75 microns minimum dft when used as an intermediatecoataspartofamulti-coatsystem)1ct. Macropoxy646FastCureEpoxy 3.0-6.0 (75-150)1-2 cts. of recommended topcoatSteel:1ct. RecoatableEpoxyPrimer 4.0-6.0 (100-150)2cts. Macropoxy646FastCureEpoxy 5.0-10.0 (125-250)Steel:1 ct. Macropoxy646FastCureEpoxy 5.0-10.0 (125-250)1-2cts. Acrolon218Polyurethane 3.0-6.0 (75-150) or Hi-SolidsPolyurethane 3.0-5.0 (75-125) or SherThane2KUrethane 2.0-4.0 (50-100) or Hydrogloss 2.0-4.0 (50-100)Steel:2cts. Macropoxy646FastCureEpoxy 5.0-10.0 (125-250)1-2cts. Tile-CladHSEpoxy 2.5-4.0 (63-100)Steel:1ct. ZincCladIIPlus 2.0-4.0 (50-100)1 ct. Macropoxy646FastCureEpoxy 5.0-10.0 (125-250)1-2cts. Acrolon218Polyurethane 3.0-6.0 (75-150)Steel:1ct. ZincCladIIIHS 3.0-5.0 (75-125) or ZincCladIV 3.0-5.0 (75-125)1 ct. Macropoxy646FastCureEpoxy 3.0-10.0 (75-250)1-2cts. Acrolon218Polyurethane 3.0-6.0 (75-150)Aluminum:2cts. Macropoxy646FastCureEpoxy 5.0-10.0 (125-250)Galvanizing:2cts. Macropoxy646FastCureEpoxy 5.0-10.0 (125-250)FIRETEX M89/02, M90, M90/02, and M93/02:Steel & Galvanized Substrates being primed for FIRETEX only:1 ct. Macropoxy646FastCureEpoxy 2.0-5.0 (50-125)The systems listed above are representative of the product's use, other systems may be appropriate.
9 of 73
Revised: Sept. 29, 2015
MACROPOXY® 646FAST CURE EPOXY
PART A B58-600 SERiES
PART B B58V600 HARdEnER
Protective &
MarineCoatings
4.53
www.sherwin-williams.com/protective
surface PreParationsSurface must be clean, dry, and in sound condition. Remove all oil, dust, grease, dirt, loose rust, and other foreign material to ensure adequate adhesion.Iron & Steel, Atmospheric Service:Minimumsurface preparation isHandToolClean perSSPC-SP2.Remove all oil and grease from surface bySolventCleaning perSSPC-SP1.Forbetterperformance,useCommercialBlastCleaningperSSPC-SP6/NACE3,blastcleanallsurfacesusingasharp,angularabrasiveforoptimumsurfaceprofile(2mils/50microns).Primeanybaresteelwithin8hoursorbeforeflashrustingoccurs.Iron & Steel, Immersion Service:Remove all oil and grease from surface bySolventCleaning perSSPC-SP1.MinimumsurfacepreparationisNearWhiteMetalBlastCleaningperSSPC-SP10/NACE2.Blastcleanallsurfacesusingasharp,angularabrasiveforoptimumsurfaceprofile(2-3mils/50-75microns).Removeallweldspatterandroundallsharpedgesbygrind-ing. Prime any bare steel the same day as it is cleaned.AluminumRemove all oil, grease, dirt, oxide and other foreign material by Solvent CleaningperSSPC-SP1.Galvanized SteelAllowtoweatheraminimumofsixmonthspriortocoating.SolventCleanperSSPC-SP1(recommendedsolventisVM&PNaphtha).Whenweathering is not possible, or the surface has been treated with chro-matesorsilicates,firstSolventCleanperSSPC-SP1andapplyatestpatch.Allowpainttodryatleastoneweekbeforetestingadhesion.Ifadhesionispoor,brushblastingperSSPC-SP7isnecessarytoremovethese treatments. Rusty galvanizing requires a minimum of Hand Tool CleaningperSSPC-SP2,primetheareathesamedayascleaned.InpreparinggalvanizedsteelsubstratesfortheapplicationofFIRE-TEXintumescentcoatingsystems,SurfacePreparationSpecificationSSPC-SP16mustbefollowedobtainingasurfaceprofileofminimum1.5mils(38microns).Optimumsurfaceprofilewillnotexceed2.0mils(50microns).Concrete and MasonryForsurfacepreparation, refer toSSPC-SP13/NACE6,or ICRINo.310.2R,CSP 1-3. Surfaces should be thoroughly clean and dry.Concreteandmortarmustbecuredatleast28days@75°F(24°C).Remove all loose mortar and foreign material. Surface must be free of laitance, concrete dust, dirt, form release agents, moisture curing membranes,loosecementandhardeners.Fillbugholes,airpocketsand other voids with Steel-Seam FT910. Concrete, Immersion Service:Forsurfacepreparation,refertoSSPC-SP13/NACE6,Section4.3.1or1.3.2orICRINo.310.2R,CSP2-4.Follow the standard methods listed below when applicable:ASTMD4258StandardPracticeforCleaningConcrete.ASTMD4259StandardPracticeforAbradingConcrete.ASTMD4260StandardPracticeforEtchingConcrete.ASTMF1869StandardTestMethod forMeasuringMoistureVaporEmissionRateofConcrete.SSPC-SP13/Nace6SurfacePreparationofConcrete.ICRINo.310.2RConcreteSurfacePreparation.Previously Painted SurfacesIf in sound condition, clean the surface of all foreign material. Smooth, hard or glossy coatings and surfaces should be dulled by abrading the surface.Applyatestarea,allowingpainttodryoneweekbeforetestingadhesion.Ifadhesionispoor,orifthisproductattacksthepreviousfinish,removalofthepreviouscoatingmaybenecessary.Ifpaintispeeling or badly weathered, clean surface to sound substrate and treat as a new surface as above.
Surface Preparation StandardsCondition of Surface
ISO 8501-1BS7079:A1
Swedish Std.SIS055900 SSPC NACE
WhiteMetal Sa 3 Sa 3 SP 5 1NearWhiteMetal Sa 2.5 Sa 2.5 SP 10 2CommercialBlast Sa 2 Sa 2 SP6 3Brush-OffBlast Sa 1 Sa 1 SP 7 4HandToolCleaning Rusted CSt2 CSt2 SP 2 -
Pitted & Rusted DSt2 DSt2 SP 2 -PowerToolCleaning Rusted CSt3 CSt3 SP 3 -
Pitted & Rusted DSt3 DSt3 SP 3 -
APPliCATiOn BUllETin
aPPlication conditions
Temperature: 35°F (1.7°C)minimum,120°F (49°C) maximum(airandsurface) 40°F(4.5°C)minimum,120°F(49°C) maximum(material) Atleast5°F(2.8°C)abovedewpoint
Relative humidity: 85% maximum
aPPlication equiPment
Thefollowingisaguide.Changesinpressuresandtipsizesmaybeneededforproperspraycharacteristics.Alwayspurgesprayequipmentbeforeusewithlistedreducer.AnyreductionmustbecompliantwithexistingVOCregulationsandcompatiblewiththeexisting environmental and application conditions.
Reducer/Clean Up ...........Reducer R7K15 InCalifornia ....................Reducer R7K111
Airless Spray Pump..............................30:1 Pressure.........................2800 - 3000 psi Hose...............................1/4"ID Tip ...................................017" - .023" Filter ...............................60mesh Reduction .......................Asneededupto10%byvolume
Conventional Spray Gun ................................DeVilbissMBC-510 Fluid Tip .........................E AirNozzle.......................704 AtomizationPressure .....60-65psi Fluid Pressure ................10-20 psi Reduction .......................Asneededupto10%byvolume Requires oil and moisture separators
Brush Brush..............................Nylon/PolyesterorNaturalBristle Reduction .......................Asneededupto10%byvolume
Roller Cover .............................3/8" woven with solvent resistant core Reduction .......................Asneededupto10%byvolume
Plural Component Spray ...Acceptable RefertoApril2010TechnicalBulletin-"ApplicationGuidelines for Macropoxy646FastCureEpoxy&RecoatableEpoxy Primer Utilizing Plural ComponentEquipment" Ifspecificapplicationequipmentisnotlistedabove,equivalent equipment may be substituted.
continuedonback
10 of 73
Revised: Sept. 29, 2015
MACROPOXY® 646FAST CURE EPOXY
PART A B58-600 SERiES
PART B B58V600 HARdEnER
Protective &
MarineCoatings
4.53
www.sherwin-williams.com/protective
APPliCATiOn BUllETin
aPPlication ProceduresSurface preparation must be completed as indicated.Mixcontentsofeachcomponentthoroughlywithlowspeedpoweragitation.Makecertainnopigmentremainsonthebottomofthecan.ThencombineonepartbyvolumeofPartAwithonepartbyvolumeofPartB.Thoroughlyagitatethemixturewithpoweragitation.Allowthematerialtosweat-inasindicatedpriortoap-plication. Re-stir before using.If reducer solvent is used, add only after both components have been thoroughly mixed, after sweat-in.Applypaintattherecommendedfilmthicknessandspreadingrate as indicated below:
Recommended Spreading Rate per coat:Minimum Maximum
Wet mils(microns) 7.0 (175) 13.5 (338)Dry mils(microns) 5.0* (125) 10.0* (250)~Coverage sq ft/gal (m2/L) 116 (2.8) 232 (5.7)Theoretical coverage sq ft/gal (m2/L)@1mil/25micronsdft 1152 (28.2)*May be applied at 3.0-10.0 mils (75-250 microns) dft in atmo-spheric conditions. Refer to Recommended Systems (page 2). See Performance Tips section also.
NOTE: Brush or roll application may require multiple coats to achieve maximum film thickness and uniformity of appearance.
Drying Schedule @ 7.0 mils wet (175 microns):@ 35°F/1.7°C @ 77°F/25°C @ 100°F/38°C
50% RHTo touch: 4-5 hours 2 hours 1.5 hoursTo handle: 48 hours 8 hours 4.5 hoursTo recoat:
minimum: 48 hours 8 hours 4.5 hoursmaximum: 1 year 1 year 1 year
To cure:Service: 10 days 7 days 4 days
Immersion: 14 days 7 days 4 daysIf maximum recoat time is exceeded, abrade surface before recoating.
Drying time is temperature, humidity, and film thickness dependent.Paint temperature must be at least 40°F(4.5°C)minimum.Pot Life: 10 hours 4 hours 2 hoursSweat-in-time: 30 minutes 30 minutes 15 minutes
When used as an intermediate coat as part of a multi-coat system:
Drying Schedule @ 5.0 mils wet (125 microns):@ 35°F/1.7°C @ 77°F/25°C @ 100°F/38°C
50% RHTo touch: 3 hours 1 hour 1 hourTo handle: 48 hours 4 hours 2 hoursTo recoat:
minimum: 16hours 4 hours 2 hoursmaximum: 1 year 1 year 1 year
Applicationofcoatingabovemaximumorbelowminimumrecommendedspreading rate may adversely affect coating performance.
clean uP instructionsCleanspillsandspattersimmediatelywithReducerR7K15.CleantoolsimmediatelyafterusewithReducerR7K15.InCaliforniauseReducerR7K111. Follow manufacturer's safety recommendations when using any solvent.
Performance tiPsStripe coat all crevices, welds, and sharp angles to prevent early failure in these areas.Whenusingsprayapplication,usea50%overlapwitheachpassof the gun to avoid holidays, bare areas, and pinholes. If necessary, cross spray at a right angleSpreading rates are calculated on volume solids and do not include anapplicationlossfactorduetosurfaceprofile,roughnessorpo-rosityofthesurface,skillandtechniqueoftheapplicator,methodof application, various surface irregularities, material lost during mixing, spillage, overthinning, climatic conditions, and excessive filmbuild.Excessivereductionofmaterialcanaffectfilmbuild,appearance,and adhesion.Donotmixpreviouslycatalyzedmaterialwithnew.Donotapplythematerialbeyondrecommendedpotlife.Inordertoavoidblockageofsprayequipment,cleanequipmentbefore use or before periods of extended downtime with Reducer R7K15.InCaliforniauseReducerR7K111.Tinting is not recommended for immersion service.UseonlyMillWhiteandBlackforimmersionservice.Insufficientventilation,incompletemixing,miscatalyzation,andexternal heaters may cause premature yellowing.Excessivefilmbuild,poorventilation,andcooltemperaturesmaycause solvent entrapment and premature coating failure.Quik-KickEpoxyAcceleratorisacceptableforuse.Seedatapage4.99 for details.Whencoatingoveraluminumandgalvanizing,recommendeddftis2-4mils(50-100microns).AcceptableforConcreteFloors.Canbeusedasametalizingsealer.ConsultTechnicalBulletin-SealersforThermalSprayMetalizing,oryourlocalSherwin-Williamsrepresentative.Refer to Product Information sheet for additional performance characteristics and properties.
safety PrecautionsRefertotheMSDSsheetbeforeuse.Publishedtechnicaldataandinstructionsaresubjecttochangewithoutnotice.ContactyourSherwin-Williamsrepresentativeforadditionaltechnicaldataandinstructions.
disclaimerTheinformationandrecommendationssetforthinthisProductDataSheetarebasedupontestsconductedbyoronbehalfofTheSherwin-WilliamsCompany.Suchinformationandrecommendationssetforthhereinaresubjecttochangeandpertaintotheproductofferedatthetimeofpublication.ConsultyourSherwin-WilliamsrepresentativetoobtainthemostrecentProductDataInformationandApplicationBulletin.
WarrantyTheSherwin-WilliamsCompanywarrantsourproductstobefreeofmanufacturingdefects inaccordwithapplicableSherwin-Williamsqualitycontrolprocedures.Liabilityforproductsprovendefective,ifany,islimitedtoreplacementofthede-fective product or the refund of the purchase price paid for the defective product asdeterminedbySherwin-Williams.NOOTHERWARRANTYORGUARANTEEOFANYKINDISMADEBYSHERWIN-WILLIAMS,EXPRESSEDORIMPLIED,STATUTORY,BYOPERATIONOFLAWOROTHERWISE,INCLUDINGMER-CHANTABILITYANDFITNESSFORAPARTICULARPURPOSE.
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SEAGUARD® 5000 HS EPOXY
PART A N11B350 BLACK PART A N11W350 OFF WHITE PART A N11R350 RED PART A N11G350 GREEN PART A N11H350 BUFF PART A N11A350 GRAY PART B N11V350 HARDENER
Protective &
MarineCoatings
9.40Revised: March 27, 2013
www.sherwin-williams.com/protective
PRODUCT DESCRIPTIONSEAGUARD 5000 HS EPOXY is a high performance and high solids, polyamine cured epoxy that is designed to be used as a part of an anticorrosive system for marine applications, or as a lining system for fuel, brine, ballast and non-potable water tanks.• Complies with IMO Performance Standard for Protective Coatings SOLAS REGULATIONS II-1/3-2 and XII/6.3• Corrosion resistant• Outstanding adhesion• Qualifi ed to MIL-PRF-24647 for underwater hull• Qualifi ed to MIL-PRF-23236 for ballast tanks and fuel tanks
PRODUCT CHARACTERISTICSFinish: Low Sheen
Color: Black, Off White, Red Deck, Green, Gray, Buff
Volume Solids: 73% ± 2% mixed
Weight Solids: 79% ± 2% mixed
VOC (EPA Method 24): <250 g/L; 2.08 lb/gal
Mix Ratio: 1:1 by volume (2 components)
Recommended Spreading Rate per coat:Minimum Maximum
Wet mils (microns) 7.0 (175) 10.0 (250)Dry mils (microns) 5.0 (125) 7.0 (175)~Coverage sq ft/gal (m2/L) 167 (4.1) 234 (5.7)Theoretical coverage sq ft/gal (m2/L) @ 1 mil / 25 microns dft 1168 (28.6)
NOTE: Brush or roll application may require multiple coats to achieve maximum fi lm thickness and uniformity of appearance.
Drying Schedule @ 7.0 mils wet (175 microns):@
35°F/1.7°C@
50°F/10°C@
77°F/25°C@
110°F/43°C50% RH
To touch: 8 hours 5 hours 4 hours 2 hoursTo recoat:
minimum: 24 hours 12 hours 6 hours 3 hoursmaximum*: 90 days 90 days 90 days 90 days
To cure: 20 days 14 days 7 days 7 days*Two weeks maximum for alkyd and urethane topcoats.If maximum recoat time is exceeded, abrade surface before recoating.Drying time is temperature, humidity, and fi lm thickness dependent.Pot Life: 8 hours 6 hours 2 hours 1 hourSweat-in-Time: None None None NoneApplication of the antifouling coating shall occur while the epoxy coat is still tacky. Refer to the Application Bulletin for the defi nition of "TACKY".
Shelf Life: 36 months, unopenedStore indoors at 40°F (4.5°C) to 100°F (38°C)
Flash Point (ADMIX): 110°F (43°C) PMCCReducer/Clean Up:Above 80°F (27°C):Below 80°F (27°C):
R7K130 (all temperatures)R7K100R2K5
continued on back
RECOMMENDED USES
For use as a coating for:• Fuel, brine, ballast and non-potable water tanks• Underwater hull with appropriate antifouling paint• Interior or exterior marine applications• Immersion service• Acceptable for use with UHP / waterjetted substrates
PERFORMANCE CHARACTERISTICS
Substrate*: SteelSurface Preparation*: SSPC-SP10/NACE 2System Tested*:
2 cts. SeaGuard 5000 HS Epoxy @ 5.0 mils (125 microns) dft/ct*unless otherwise noted below
Test Name Test Method ResultsSolvent Resistance ASTM D1308 Passed
Qualifi ed to MIL-PRF-23236, Type VI, Class 5 and 7, Grade C
Qualifi ed to MIL-PRF-24647, Type I, Class 1 and 2, Grade A and B, Application 1 and 4
Qualifi ed to MIL-PRF-24647, Type II, Class 1, Grade B, Application 1, 2, 3 and 4
Tested by Det Norske Veritas (DNV). According to DNV Procedure, testing and classifi cation of ballast tank coatings, REV-02. Tested to the DNV Procedure over a Zinc Shop Primer Steel.
Received Highest Obtainable rating B1
Epoxy coatings may darken or yellow following application and curing.
12 of 73
9.40
SEAGUARD® 5000 HS EPOXY
PART A N11B350 BLACK PART A N11W350 OFF WHITE PART A N11R350 RED PART A N11G350 GREEN PART A N11H350 BUFF PART A N11A350 GRAY PART B N11V350 HARDENER
Protective &
MarineCoatings
www.sherwin-williams.com/protective
SURFACE PREPARATIONSurface must be clean, dry, and in sound condition. Remove all oil, dust, grease, dirt, loose rust, and other foreign material to ensure adequate adhesion.Refer to product Application Bulletin for detailed surface prepara-tion information.Minimum recommended surface preparation:Immersion: Iron & Steel / Aluminum SSPC-SP10/NACE 2, 2.0 mil (50 micron) profi le or SSPC-SP12/NACE No.5 - WJ-2M / SC-2 with existing surface profi leAtmospheric: Iron & Steel / Aluminum minimum: SSPC-SP2, SSPC-SP3 preferred: SSPC-SP6/NACE 3, 2.0 mil (50 micron) profi le or SSPC-SP12/NACE No.5 - WJ-3M / SC-2 with existing surface profi le Galvanizing: SSPC-SP1
Surface Preparation StandardsCondition of Surface
ISO 8501-1BS7079:A1
Swedish Std.SIS055900 SSPC NACE
White Metal Sa 3 Sa 3 SP 5 1Near White Metal Sa 2.5 Sa 2.5 SP 10 2Commercial Blast Sa 2 Sa 2 SP 6 3Brush-Off Blast Sa 1 Sa 1 SP 7 4Hand Tool Cleaning Rusted C St 2 C St 2 SP 2 -
Pitted & Rusted D St 2 D St 2 SP 2 -Power Tool Cleaning Rusted C St 3 C St 3 SP 3 -
Pitted & Rusted D St 3 D St 3 SP 3 -
TINTING
Do not tint.
APPLICATION CONDITIONSTemperature: 35°F (1.7°C) minimum, 110°F (43°C) maximum (air, surface, and material) At least 5°F (2.8°C) above dew pointRelative humidity: 85% maximumRefer to product Application Bulletin for detailed application information.
ORDERING INFORMATIONPackaging: Part A: 1 gallon (3.78L) and 5 gallon (18.9L) containers Part B: 1 gallon (3.78L) and 5 gallon (18.9L) containersWeight: Part A: 12.73 ± 0.2 lb/gal; 1.5 Kg/L Part B: 11.43 ± 0.2 lb/gal; 1.4 Kg/L Mixed: 12.08 ± 0.2 lb/gal; 1.45 Kg/L
SAFETY PRECAUTIONSRefer to the MSDS sheet before use.
Published technical data and instructions are subject to change without notice. Contact your Sherwin-Williams representative for additional technical data and instructions.
WARRANTYThe Sherwin-Williams Company warrants our products to be free of manufactur-ing defects in accord with applicable Sherwin-Williams quality control procedures. Liability for products proven defective, if any, is limited to replacement of the defec-tive product or the refund of the purchase price paid for the defective product as determined by Sherwin-Williams. NO OTHER WARRANTY OR GUARANTEE OF ANY KIND IS MADE BY SHERWIN-WILLIAMS, EXPRESSED OR IMPLIED, STATUTORY, BY OPERATION OF LAW OR OTHERWISE, INCLUDING MER-CHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE.
PRODUCT INFORMATION
RECOMMENDED SYSTEMS
Dry Film Thickness / ct. Mils (Microns)Steel or Aluminum, immersion:2 cts. SeaGuard 5000 HS Epoxy 5.0-7.0 (125-175)
Steel or Aluminum, underwater hull:2 cts. SeaGuard 5000 HS Epoxy 5.0-7.0 (125-175)1-2 cts. SeaGuard antifoulant
Steel or Aluminum, atmospheric:1-2 cts. SeaGuard 5000 HS Epoxy 5.0-7.0 (125-175)1-2 cts. Sherthane 2K 2.0-4.0 (50-100)or1-2 cts. Polysiloxane XLE-80 HAPS Free 5.0-7.0 (125-175)or1-2 cts. SeaGuard 1000 2.0-3.0 (50-75)or1-2 cts. Hi-Solids Polyurethane 3.0-5.0 (75-125)Galvanized, atmospheric:1 ct. SeaGuard 5000 HS Epoxy 4.0-7.0 (100-175)1-2 cts. Sherthane 2K 2.0-4.0 (50-100)or1-2 cts. Polysiloxane XLE-80 HAPS Free 5.0-7.0 (125-175)or1-2 cts. SeaGuard 1000 2.0-3.0 (50-75)or1-2 cts. Hi-Solids Polyurethane 3.0-5.0 (75-125)
Seawater Ballast Tank ApplicationsIn accordance with IMO Resolution MSC.215(82) PSPC, allapplication requirements specifi ed in PSPC Table 1 have tobe strictly adhered to.• Substrate: Abrasive blasting to Sa 2.5 (ISO 8501-1),
SSPC-SP-10.• Surface profi le: 30 - 75 microns as per ISO 8503-1/3.• Water soluble contaminants: ≤ 50mg/m2 of sodium
chloride. Conductivity measured in accordance with ISO 8502-9.
• Dry fi lm thickness: PSPC stipulates a Nominal Dry Film Thickness (NDFT) of 320 microns obtained in 2 coats. The fi lm thickness distribution is measured in accordance with the 90/10 rule.
• Maximum total dry fi lm thickness not to exceed 1000 mi-crons/40 mils.
• Coating sequence: Red, followed by light grey.• Stripe coats: 2 strip coats in alternating colors must be ap-
plied as part of the system.The systems listed above are representative of the product's use, other systems may be appropriate.
DISCLAIMERThe information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams Company. Such information and recommendations set forth herein are subject to change and pertain to the product offered at the time of publication. Consult your Sherwin-Williams representative to obtain the most recent Product Data Information and Application Bulletin.
13 of 73
SEAGUARD® 5000 HS EPOXY
PART A N11B350 BLACK PART A N11W350 OFF WHITE PART A N11R350 RED PART A N11G350 GREEN PART A N11H350 BUFF PART A N11A350 GRAY PART B N11V350 HARDENER
Protective &
MarineCoatings
9.40Revised: March 27, 2013
www.sherwin-williams.com/protective
SURFACE PREPARATIONS
Surface must be clean, dry, and in sound condition. Remove all oil, dust, grease, dirt, loose rust, and other foreign material to ensure adequate adhesion.
Iron & Steel / Aluminum, Immersion Service:Remove all oil and grease from surface by Solvent Cleaning per SSPC-SP1. Minimum surface preparation is Near White Metal Blast Cleaning per SSPC-SP10/NACE 2 or SSPC-SP12/NACE No. 5. For SSPC-SP10/NACE 2, blast clean all surfaces using a sharp, angular abrasive for optimum surface profi le (2.0 mils / 50 microns). For SSPC-SP12/NACE No. 5, all surfaces to be coated shall be cleaned in accordance with WJ-2M/SC-2 standards. Pre-existing profi le should be approximately 2.0 mils (50 microns). Remove all weld spatter and round all sharp edges. Prime any bare steel the same day as it is cleaned.
Iron & Steel / Aluminum, Atmospheric Service:Minimum surface preparation is Hand Tool Clean per SSPC-SP2 or SSPC-SP12/NACE No. 5. For surfaces prepared by SSPC-SP2, fi rst remove all oil and grease from surface by Solvent Cleaning per SSPC-SP1. For better performance, use Commercial Blast Cleaning per SSPC-SP6/NACE 3, blast clean all surfaces using a sharp, angular abrasive for optimum surface profi le (2.0 mils / 50 microns). For surfaces prepared by SSPC-SP12/NACE No. 5, all surfaces shall be cleaned in accordance with WJ-3M/SC-2. Pre-existing profi le should be approximately 2.0 mils (50 microns). Prime any bare steel the same day as it is cleaned.
Galvanized Steel:Allow to weather a minimum of six months prior to coating. Solvent Clean per SSPC-SP1 (recommended solvent is VM&P Naphtha). When weathering is not possible, or the surface has been treated with chromates or silicates, fi rst Solvent Clean per SSPC-SP1 and apply a test patch. Allow paint to dry at least one week before test-ing adhesion. If adhesion is poor, brush blasting per SSPC-SP7 is necessary to remove these treatments. Rusty galvanizing requires a minimum of Hand Tool Cleaning per SSPC-SP2, prime the area the same day as cleaned.
Previously Painted SurfacesIf in sound condition, clean the surface of all foreign material. Smooth, hard or glossy coatings and surfaces should be dulled by abrading the surface. Apply a test area, allowing paint to dry one week before testing adhesion. If adhesion is poor, or if this product attacks the previous fi nish, removal of the previous coating may be necessary. If paint is peeling or badly weathered, clean surface to sound substrate and treat as a new surface as above.
Surface Preparation StandardsCondition of Surface
ISO 8501-1BS7079:A1
Swedish Std.SIS055900 SSPC NACE
White Metal Sa 3 Sa 3 SP 5 1Near White Metal Sa 2.5 Sa 2.5 SP 10 2Commercial Blast Sa 2 Sa 2 SP 6 3Brush-Off Blast Sa 1 Sa 1 SP 7 4Hand Tool Cleaning Rusted C St 2 C St 2 SP 2 -
Pitted & Rusted D St 2 D St 2 SP 2 -Power Tool Cleaning Rusted C St 3 C St 3 SP 3 -
Pitted & Rusted D St 3 D St 3 SP 3 -
APPLICATION BULLETIN
APPLICATION CONDITIONS
Temperature: 35°F (1.7°C) minimum, 110°F (43°C) maximum (air, surface, and material) At least 5°F (2.8°C) above dew point
Relative humidity: 85% maximum
APPLICATION EQUIPMENT
The following is a guide. Changes in pressures and tip sizes may be needed for proper spray characteristics. Always purge spray equipment before use with listed reducer. Any reduction must be compliant with existing VOC regulations and compatible with the existing environmental and application conditions.
Reducer/Clean Up ...........Reducer #130, R7K130
Airless Spray Pressure.........................2400 psi Hose...............................1/4" ID Tip ...................................017" - .031" Filter ...............................60 mesh Reduction .......................As needed, up to 5% by volume
Brush Brush..............................Natural Bristle Reduction .......................Not recommended
Roller Cover .............................3/8" - 1/2" woven with solvent resistant
core Reduction .......................Not recommended
If specifi c application equipment is not listed above, equivalent equipment may be substituted.
continued on back
14 of 73
9.40
SEAGUARD® 5000 HS EPOXY
PART A N11B350 BLACK PART A N11W350 OFF WHITE PART A N11R350 RED PART A N11G350 GREEN PART A N11H350 BUFF PART A N11A350 GRAY PART B N11V350 HARDENER
Protective &
MarineCoatings
www.sherwin-williams.com/protective
APPLICATION BULLETIN
APPLICATION PROCEDURESSurface preparation must be completed as indicated.Mix contents of each component thoroughly with low speed power agitation. Make certain no pigment remains on the bottom of the cans. Then combine one part by volume of Part A with one part by volume of Part B. Thoroughly agitate the mixture with power agitation. Allow the material to sweat-in as indicated. Re-stir before using.
If reducer solvent is used, add only after both components have been thoroughly mixed, after sweat-in.
Apply paint at the recommended fi lm thickness and spreading rate as indicated below:
Recommended Spreading Rate per coat:Minimum Maximum
Wet mils (microns) 7.0 (175) 10.0 (250)Dry mils (microns) 5.0 (125) 7.0 (175)~Coverage sq ft/gal (m2/L) 167 (4.1) 234 (5.7)Theoretical coverage sq ft/gal (m2/L) @ 1 mil / 25 microns dft 1168 (28.6)
NOTE: Brush or roll application may require multiple coats to achieve maximum fi lm thickness and uniformity of appearance.
Drying Schedule @ 7.0 mils wet (175 microns):@
35°F/1.7°C@
50°F/10°C@
77°F/25°C@
110°F/43°C50% RH
To touch: 8 hours 5 hours 4 hours 2 hoursTo recoat:
minimum: 24 hours 12 hours 6 hours 3 hoursmaximum*: 90 days 90 days 90 days 90 days
To cure: 20 days 14 days 7 days 7 days*Two weeks maximum for alkyd and urethane topcoats.If maximum recoat time is exceeded, abrade surface before recoating.Drying time is temperature, humidity, and fi lm thickness dependent.Pot Life: 8 hours 6 hours 2 hours 1 hourSweat-in-Time: None None None NoneApplication of the antifouling coating shall occur while the epoxy coat is still tacky. Refer to the Application Bulletin for the defi nition of "TACKY".
Application of coating above maximum or below minimum recommended spreading rate may adversely affect coating performance.
CLEAN UP INSTRUCTIONSClean spills and spatters immediately with Reducer #130, R7K130. Clean tools immediately after use with Reducer #130, R7K130. Follow manufacturer's safety recommendations when using any solvent.
DISCLAIMERThe information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams Company. Such information and recommendations set forth herein are subject to change and pertain to the product offered at the time of publication. Consult your Sherwin-Williams representative to obtain the most recent Product Data Information and Application Bulletin.
PERFORMANCE TIPSStripe coat all crevices, welds, and sharp angles to prevent early failure in these areas.
When using spray application, use a 50% overlap with each pass of the gun to avoid holidays, bare areas, and pinholes. If necessary, cross spray at a right angle.
Spreading rates are calculated on volume solids and do not include an application loss factor due to surface profi le, roughness or po-rosity of the surface, skill and technique of the applicator, method of application, various surface irregularities, material lost during mixing, spillage, overthinning, climatic conditions, and excessive fi lm build.
Excessive reduction of material can affect fi lm build, appearance, and adhesion.
Excessive fi lm build, poor ventilation, and cool temperatures may cause solvent entrapment and premature coating failure.
For Immersion Service: (if required) Holiday test in accordance with ASTM D5162 for steel, or ASTM D4787 for concrete.
Do not apply the material beyond recommended pot life.
Do not mix previously catalyzed material with new.
In order to avoid blockage of spray equipment, clean equipment before use or before periods of extended downtime with Reducer #130, R7K130.
Material must be at least 50°F/10°C prior to catalyzing.
Application of the antifoulant coating shall occur when the last coat of epoxy anticorrosive is still tacky. If the epoxy is hard, apply a tack coat of epoxy anticorrosive at 1-2 mils (25-50 microns) WFT over previously painted surfaces. "Tacky" is defi ned as that curing (drying) stage when a fi ngertip pressed lightly against the fi lm leaves only a slight impression and none of the fi lm sticks to the fi nger.
Application of solvent based alkyd coating, such as MIL-PRF-24635, shall be applied when the epoxy is "dry to the touch, but not fully cured." (For example prior to 7 days @ 77°F/25°C).
Refer to Product Information sheet for additional performance characteristics and properties.
SAFETY PRECAUTIONSRefer to the MSDS sheet before use.Published technical data and instructions are subject to change without notice. Contact your Sherwin-Williams representative for additional technical data and instructions.
WARRANTYThe Sherwin-Williams Company warrants our products to be free of manufacturing defects in accord with applicable Sherwin-Williams quality control procedures. Liability for products proven defective, if any, is limited to replacement of the de-fective product or the refund of the purchase price paid for the defective product as determined by Sherwin-Williams. NO OTHER WARRANTY OR GUARANTEE OF ANY KIND IS MADE BY SHERWIN-WILLIAMS, EXPRESSED OR IMPLIED, STATUTORY, BY OPERATION OF LAW OR OTHERWISE, INCLUDING MER-CHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE.
15 of 73
SEAGUARD® 5000 HS EPOXY
PART A N11B350 BLACK PART A N11W350 OFF WHITE PART A N11R350 RED PART A N11G350 GREEN PART A N11H350 BUFF PART A N11A350 GRAY PART B N11V350 HARDENER
Protective &
MarineCoatings
9.40Revised: March 27, 2013
www.sherwin-williams.com/protective
PRODUCT DESCRIPTIONSEAGUARD 5000 HS EPOXY is a high performance and high solids, polyamine cured epoxy that is designed to be used as a part of an anticorrosive system for marine applications, or as a lining system for fuel, brine, ballast and non-potable water tanks.• Complies with IMO Performance Standard for Protective Coatings SOLAS REGULATIONS II-1/3-2 and XII/6.3• Corrosion resistant• Outstanding adhesion• Qualifi ed to MIL-PRF-24647 for underwater hull• Qualifi ed to MIL-PRF-23236 for ballast tanks and fuel tanks
PRODUCT CHARACTERISTICSFinish: Low Sheen
Color: Black, Off White, Red Deck, Green, Gray, Buff
Volume Solids: 73% ± 2% mixed
Weight Solids: 79% ± 2% mixed
VOC (EPA Method 24): <250 g/L; 2.08 lb/gal
Mix Ratio: 1:1 by volume (2 components)
Recommended Spreading Rate per coat:Minimum Maximum
Wet mils (microns) 7.0 (175) 10.0 (250)Dry mils (microns) 5.0 (125) 7.0 (175)~Coverage sq ft/gal (m2/L) 167 (4.1) 234 (5.7)Theoretical coverage sq ft/gal (m2/L) @ 1 mil / 25 microns dft 1168 (28.6)
NOTE: Brush or roll application may require multiple coats to achieve maximum fi lm thickness and uniformity of appearance.
Drying Schedule @ 7.0 mils wet (175 microns):@
35°F/1.7°C@
50°F/10°C@
77°F/25°C@
110°F/43°C50% RH
To touch: 8 hours 5 hours 4 hours 2 hoursTo recoat:
minimum: 24 hours 12 hours 6 hours 3 hoursmaximum*: 90 days 90 days 90 days 90 days
To cure: 20 days 14 days 7 days 7 days*Two weeks maximum for alkyd and urethane topcoats.If maximum recoat time is exceeded, abrade surface before recoating.Drying time is temperature, humidity, and fi lm thickness dependent.Pot Life: 8 hours 6 hours 2 hours 1 hourSweat-in-Time: None None None NoneApplication of the antifouling coating shall occur while the epoxy coat is still tacky. Refer to the Application Bulletin for the defi nition of "TACKY".
Shelf Life: 36 months, unopenedStore indoors at 40°F (4.5°C) to 100°F (38°C)
Flash Point (ADMIX): 110°F (43°C) PMCCReducer/Clean Up:Above 80°F (27°C):Below 80°F (27°C):
R7K130 (all temperatures)R7K100R2K5
continued on back
RECOMMENDED USES
For use as a coating for:• Fuel, brine, ballast and non-potable water tanks• Underwater hull with appropriate antifouling paint• Interior or exterior marine applications• Immersion service• Acceptable for use with UHP / waterjetted substrates
PERFORMANCE CHARACTERISTICS
Substrate*: SteelSurface Preparation*: SSPC-SP10/NACE 2System Tested*:
2 cts. SeaGuard 5000 HS Epoxy @ 5.0 mils (125 microns) dft/ct*unless otherwise noted below
Test Name Test Method ResultsSolvent Resistance ASTM D1308 Passed
Qualifi ed to MIL-PRF-23236, Type VI, Class 5 and 7, Grade C
Qualifi ed to MIL-PRF-24647, Type I, Class 1 and 2, Grade A and B, Application 1 and 4
Qualifi ed to MIL-PRF-24647, Type II, Class 1, Grade B, Application 1, 2, 3 and 4
Tested by Det Norske Veritas (DNV). According to DNV Procedure, testing and classifi cation of ballast tank coatings, REV-02. Tested to the DNV Procedure over a Zinc Shop Primer Steel.
Received Highest Obtainable rating B1
Epoxy coatings may darken or yellow following application and curing.
16 of 73
9.40
SEAGUARD® 5000 HS EPOXY
PART A N11B350 BLACK PART A N11W350 OFF WHITE PART A N11R350 RED PART A N11G350 GREEN PART A N11H350 BUFF PART A N11A350 GRAY PART B N11V350 HARDENER
Protective &
MarineCoatings
www.sherwin-williams.com/protective
SURFACE PREPARATIONSurface must be clean, dry, and in sound condition. Remove all oil, dust, grease, dirt, loose rust, and other foreign material to ensure adequate adhesion.Refer to product Application Bulletin for detailed surface prepara-tion information.Minimum recommended surface preparation:Immersion: Iron & Steel / Aluminum SSPC-SP10/NACE 2, 2.0 mil (50 micron) profi le or SSPC-SP12/NACE No.5 - WJ-2M / SC-2 with existing surface profi leAtmospheric: Iron & Steel / Aluminum minimum: SSPC-SP2, SSPC-SP3 preferred: SSPC-SP6/NACE 3, 2.0 mil (50 micron) profi le or SSPC-SP12/NACE No.5 - WJ-3M / SC-2 with existing surface profi le Galvanizing: SSPC-SP1
Surface Preparation StandardsCondition of Surface
ISO 8501-1BS7079:A1
Swedish Std.SIS055900 SSPC NACE
White Metal Sa 3 Sa 3 SP 5 1Near White Metal Sa 2.5 Sa 2.5 SP 10 2Commercial Blast Sa 2 Sa 2 SP 6 3Brush-Off Blast Sa 1 Sa 1 SP 7 4Hand Tool Cleaning Rusted C St 2 C St 2 SP 2 -
Pitted & Rusted D St 2 D St 2 SP 2 -Power Tool Cleaning Rusted C St 3 C St 3 SP 3 -
Pitted & Rusted D St 3 D St 3 SP 3 -
TINTING
Do not tint.
APPLICATION CONDITIONSTemperature: 35°F (1.7°C) minimum, 110°F (43°C) maximum (air, surface, and material) At least 5°F (2.8°C) above dew pointRelative humidity: 85% maximumRefer to product Application Bulletin for detailed application information.
ORDERING INFORMATIONPackaging: Part A: 1 gallon (3.78L) and 5 gallon (18.9L) containers Part B: 1 gallon (3.78L) and 5 gallon (18.9L) containersWeight: Part A: 12.73 ± 0.2 lb/gal; 1.5 Kg/L Part B: 11.43 ± 0.2 lb/gal; 1.4 Kg/L Mixed: 12.08 ± 0.2 lb/gal; 1.45 Kg/L
SAFETY PRECAUTIONSRefer to the MSDS sheet before use.
Published technical data and instructions are subject to change without notice. Contact your Sherwin-Williams representative for additional technical data and instructions.
WARRANTYThe Sherwin-Williams Company warrants our products to be free of manufactur-ing defects in accord with applicable Sherwin-Williams quality control procedures. Liability for products proven defective, if any, is limited to replacement of the defec-tive product or the refund of the purchase price paid for the defective product as determined by Sherwin-Williams. NO OTHER WARRANTY OR GUARANTEE OF ANY KIND IS MADE BY SHERWIN-WILLIAMS, EXPRESSED OR IMPLIED, STATUTORY, BY OPERATION OF LAW OR OTHERWISE, INCLUDING MER-CHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE.
PRODUCT INFORMATION
RECOMMENDED SYSTEMS
Dry Film Thickness / ct. Mils (Microns)Steel or Aluminum, immersion:2 cts. SeaGuard 5000 HS Epoxy 5.0-7.0 (125-175)
Steel or Aluminum, underwater hull:2 cts. SeaGuard 5000 HS Epoxy 5.0-7.0 (125-175)1-2 cts. SeaGuard antifoulant
Steel or Aluminum, atmospheric:1-2 cts. SeaGuard 5000 HS Epoxy 5.0-7.0 (125-175)1-2 cts. Sherthane 2K 2.0-4.0 (50-100)or1-2 cts. Polysiloxane XLE-80 HAPS Free 5.0-7.0 (125-175)or1-2 cts. SeaGuard 1000 2.0-3.0 (50-75)or1-2 cts. Hi-Solids Polyurethane 3.0-5.0 (75-125)Galvanized, atmospheric:1 ct. SeaGuard 5000 HS Epoxy 4.0-7.0 (100-175)1-2 cts. Sherthane 2K 2.0-4.0 (50-100)or1-2 cts. Polysiloxane XLE-80 HAPS Free 5.0-7.0 (125-175)or1-2 cts. SeaGuard 1000 2.0-3.0 (50-75)or1-2 cts. Hi-Solids Polyurethane 3.0-5.0 (75-125)
Seawater Ballast Tank ApplicationsIn accordance with IMO Resolution MSC.215(82) PSPC, allapplication requirements specifi ed in PSPC Table 1 have tobe strictly adhered to.• Substrate: Abrasive blasting to Sa 2.5 (ISO 8501-1),
SSPC-SP-10.• Surface profi le: 30 - 75 microns as per ISO 8503-1/3.• Water soluble contaminants: ≤ 50mg/m2 of sodium
chloride. Conductivity measured in accordance with ISO 8502-9.
• Dry fi lm thickness: PSPC stipulates a Nominal Dry Film Thickness (NDFT) of 320 microns obtained in 2 coats. The fi lm thickness distribution is measured in accordance with the 90/10 rule.
• Maximum total dry fi lm thickness not to exceed 1000 mi-crons/40 mils.
• Coating sequence: Red, followed by light grey.• Stripe coats: 2 strip coats in alternating colors must be ap-
plied as part of the system.The systems listed above are representative of the product's use, other systems may be appropriate.
DISCLAIMERThe information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams Company. Such information and recommendations set forth herein are subject to change and pertain to the product offered at the time of publication. Consult your Sherwin-Williams representative to obtain the most recent Product Data Information and Application Bulletin.
17 of 73
SEAGUARD® 5000 HS EPOXY
PART A N11B350 BLACK PART A N11W350 OFF WHITE PART A N11R350 RED PART A N11G350 GREEN PART A N11H350 BUFF PART A N11A350 GRAY PART B N11V350 HARDENER
Protective &
MarineCoatings
9.40Revised: March 27, 2013
www.sherwin-williams.com/protective
SURFACE PREPARATIONS
Surface must be clean, dry, and in sound condition. Remove all oil, dust, grease, dirt, loose rust, and other foreign material to ensure adequate adhesion.
Iron & Steel / Aluminum, Immersion Service:Remove all oil and grease from surface by Solvent Cleaning per SSPC-SP1. Minimum surface preparation is Near White Metal Blast Cleaning per SSPC-SP10/NACE 2 or SSPC-SP12/NACE No. 5. For SSPC-SP10/NACE 2, blast clean all surfaces using a sharp, angular abrasive for optimum surface profi le (2.0 mils / 50 microns). For SSPC-SP12/NACE No. 5, all surfaces to be coated shall be cleaned in accordance with WJ-2M/SC-2 standards. Pre-existing profi le should be approximately 2.0 mils (50 microns). Remove all weld spatter and round all sharp edges. Prime any bare steel the same day as it is cleaned.
Iron & Steel / Aluminum, Atmospheric Service:Minimum surface preparation is Hand Tool Clean per SSPC-SP2 or SSPC-SP12/NACE No. 5. For surfaces prepared by SSPC-SP2, fi rst remove all oil and grease from surface by Solvent Cleaning per SSPC-SP1. For better performance, use Commercial Blast Cleaning per SSPC-SP6/NACE 3, blast clean all surfaces using a sharp, angular abrasive for optimum surface profi le (2.0 mils / 50 microns). For surfaces prepared by SSPC-SP12/NACE No. 5, all surfaces shall be cleaned in accordance with WJ-3M/SC-2. Pre-existing profi le should be approximately 2.0 mils (50 microns). Prime any bare steel the same day as it is cleaned.
Galvanized Steel:Allow to weather a minimum of six months prior to coating. Solvent Clean per SSPC-SP1 (recommended solvent is VM&P Naphtha). When weathering is not possible, or the surface has been treated with chromates or silicates, fi rst Solvent Clean per SSPC-SP1 and apply a test patch. Allow paint to dry at least one week before test-ing adhesion. If adhesion is poor, brush blasting per SSPC-SP7 is necessary to remove these treatments. Rusty galvanizing requires a minimum of Hand Tool Cleaning per SSPC-SP2, prime the area the same day as cleaned.
Previously Painted SurfacesIf in sound condition, clean the surface of all foreign material. Smooth, hard or glossy coatings and surfaces should be dulled by abrading the surface. Apply a test area, allowing paint to dry one week before testing adhesion. If adhesion is poor, or if this product attacks the previous fi nish, removal of the previous coating may be necessary. If paint is peeling or badly weathered, clean surface to sound substrate and treat as a new surface as above.
Surface Preparation StandardsCondition of Surface
ISO 8501-1BS7079:A1
Swedish Std.SIS055900 SSPC NACE
White Metal Sa 3 Sa 3 SP 5 1Near White Metal Sa 2.5 Sa 2.5 SP 10 2Commercial Blast Sa 2 Sa 2 SP 6 3Brush-Off Blast Sa 1 Sa 1 SP 7 4Hand Tool Cleaning Rusted C St 2 C St 2 SP 2 -
Pitted & Rusted D St 2 D St 2 SP 2 -Power Tool Cleaning Rusted C St 3 C St 3 SP 3 -
Pitted & Rusted D St 3 D St 3 SP 3 -
APPLICATION BULLETIN
APPLICATION CONDITIONS
Temperature: 35°F (1.7°C) minimum, 110°F (43°C) maximum (air, surface, and material) At least 5°F (2.8°C) above dew point
Relative humidity: 85% maximum
APPLICATION EQUIPMENT
The following is a guide. Changes in pressures and tip sizes may be needed for proper spray characteristics. Always purge spray equipment before use with listed reducer. Any reduction must be compliant with existing VOC regulations and compatible with the existing environmental and application conditions.
Reducer/Clean Up ...........Reducer #130, R7K130
Airless Spray Pressure.........................2400 psi Hose...............................1/4" ID Tip ...................................017" - .031" Filter ...............................60 mesh Reduction .......................As needed, up to 5% by volume
Brush Brush..............................Natural Bristle Reduction .......................Not recommended
Roller Cover .............................3/8" - 1/2" woven with solvent resistant
core Reduction .......................Not recommended
If specifi c application equipment is not listed above, equivalent equipment may be substituted.
continued on back
18 of 73
9.40
SEAGUARD® 5000 HS EPOXY
PART A N11B350 BLACK PART A N11W350 OFF WHITE PART A N11R350 RED PART A N11G350 GREEN PART A N11H350 BUFF PART A N11A350 GRAY PART B N11V350 HARDENER
Protective &
MarineCoatings
www.sherwin-williams.com/protective
APPLICATION BULLETIN
APPLICATION PROCEDURESSurface preparation must be completed as indicated.Mix contents of each component thoroughly with low speed power agitation. Make certain no pigment remains on the bottom of the cans. Then combine one part by volume of Part A with one part by volume of Part B. Thoroughly agitate the mixture with power agitation. Allow the material to sweat-in as indicated. Re-stir before using.
If reducer solvent is used, add only after both components have been thoroughly mixed, after sweat-in.
Apply paint at the recommended fi lm thickness and spreading rate as indicated below:
Recommended Spreading Rate per coat:Minimum Maximum
Wet mils (microns) 7.0 (175) 10.0 (250)Dry mils (microns) 5.0 (125) 7.0 (175)~Coverage sq ft/gal (m2/L) 167 (4.1) 234 (5.7)Theoretical coverage sq ft/gal (m2/L) @ 1 mil / 25 microns dft 1168 (28.6)
NOTE: Brush or roll application may require multiple coats to achieve maximum fi lm thickness and uniformity of appearance.
Drying Schedule @ 7.0 mils wet (175 microns):@
35°F/1.7°C@
50°F/10°C@
77°F/25°C@
110°F/43°C50% RH
To touch: 8 hours 5 hours 4 hours 2 hoursTo recoat:
minimum: 24 hours 12 hours 6 hours 3 hoursmaximum*: 90 days 90 days 90 days 90 days
To cure: 20 days 14 days 7 days 7 days*Two weeks maximum for alkyd and urethane topcoats.If maximum recoat time is exceeded, abrade surface before recoating.Drying time is temperature, humidity, and fi lm thickness dependent.Pot Life: 8 hours 6 hours 2 hours 1 hourSweat-in-Time: None None None NoneApplication of the antifouling coating shall occur while the epoxy coat is still tacky. Refer to the Application Bulletin for the defi nition of "TACKY".
Application of coating above maximum or below minimum recommended spreading rate may adversely affect coating performance.
CLEAN UP INSTRUCTIONSClean spills and spatters immediately with Reducer #130, R7K130. Clean tools immediately after use with Reducer #130, R7K130. Follow manufacturer's safety recommendations when using any solvent.
DISCLAIMERThe information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams Company. Such information and recommendations set forth herein are subject to change and pertain to the product offered at the time of publication. Consult your Sherwin-Williams representative to obtain the most recent Product Data Information and Application Bulletin.
PERFORMANCE TIPSStripe coat all crevices, welds, and sharp angles to prevent early failure in these areas.
When using spray application, use a 50% overlap with each pass of the gun to avoid holidays, bare areas, and pinholes. If necessary, cross spray at a right angle.
Spreading rates are calculated on volume solids and do not include an application loss factor due to surface profi le, roughness or po-rosity of the surface, skill and technique of the applicator, method of application, various surface irregularities, material lost during mixing, spillage, overthinning, climatic conditions, and excessive fi lm build.
Excessive reduction of material can affect fi lm build, appearance, and adhesion.
Excessive fi lm build, poor ventilation, and cool temperatures may cause solvent entrapment and premature coating failure.
For Immersion Service: (if required) Holiday test in accordance with ASTM D5162 for steel, or ASTM D4787 for concrete.
Do not apply the material beyond recommended pot life.
Do not mix previously catalyzed material with new.
In order to avoid blockage of spray equipment, clean equipment before use or before periods of extended downtime with Reducer #130, R7K130.
Material must be at least 50°F/10°C prior to catalyzing.
Application of the antifoulant coating shall occur when the last coat of epoxy anticorrosive is still tacky. If the epoxy is hard, apply a tack coat of epoxy anticorrosive at 1-2 mils (25-50 microns) WFT over previously painted surfaces. "Tacky" is defi ned as that curing (drying) stage when a fi ngertip pressed lightly against the fi lm leaves only a slight impression and none of the fi lm sticks to the fi nger.
Application of solvent based alkyd coating, such as MIL-PRF-24635, shall be applied when the epoxy is "dry to the touch, but not fully cured." (For example prior to 7 days @ 77°F/25°C).
Refer to Product Information sheet for additional performance characteristics and properties.
SAFETY PRECAUTIONSRefer to the MSDS sheet before use.Published technical data and instructions are subject to change without notice. Contact your Sherwin-Williams representative for additional technical data and instructions.
WARRANTYThe Sherwin-Williams Company warrants our products to be free of manufacturing defects in accord with applicable Sherwin-Williams quality control procedures. Liability for products proven defective, if any, is limited to replacement of the de-fective product or the refund of the purchase price paid for the defective product as determined by Sherwin-Williams. NO OTHER WARRANTY OR GUARANTEE OF ANY KIND IS MADE BY SHERWIN-WILLIAMS, EXPRESSED OR IMPLIED, STATUTORY, BY OPERATION OF LAW OR OTHERWISE, INCLUDING MER-CHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE.
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MACROPOXY® 646 Fast Cure Epoxy Coating (Part B)Hardener
Not available.
Liquid.
(216) 566-2917
SAFETY DATA SHEET
Product name
Other means of identification
Product type
Emergency telephone number of the company
Section 1. Identification:
:
:
:
Manufacturer : THE SHERWIN-WILLIAMS COMPANY101 PROSPECT AVENUE, NWCLEVELAND, OHIO 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
B58V600
B58V600Product code :
Product Information Telephone Number
: (800) 524-5979
Regulatory Information Telephone Number
: (216) 566-2902
Transportation Emergency Telephone Number
: (800) 424-9300
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 2ACUTE TOXICITY (inhalation) - Category 4SKIN CORROSION/IRRITATION - Category 2SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2ASKIN SENSITIZATION - Category 1CARCINOGENICITY - Category 2SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Classification of the substance or mixture
:
Signal word : Danger
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 85.3%
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Highly flammable liquid and vapor.Harmful if inhaled.Causes serious eye irritation.Causes skin irritation.May cause an allergic skin reaction.Suspected of causing cancer.May cause damage to organs through prolonged or repeated exposure.
:Hazard statements
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Section 2. Hazards identificationPrevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces,sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor.Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage : Store locked up. Store in a well-ventilated place. Keep cool.
Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations.
Hazards not otherwise classified
:None known.
Please refer to the SDS for additional information. Do not transfer contents to other containers for storage.
Supplemental label elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY. Contains Formaldehyde - a potential cancer hazard. This product must be mixed with other components before use. Before opening the packages, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS. Adequate ventilation required when sanding or abrading the dried film. If Adequate ventilation cannot be provided wear an approved particulate respirator (NIOSH approved). Follow respirator manufacturer's directions for respirator use. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film may release Crystalline Silica which has been shown to cause lung damage and cancer under long term exposure.
Section 3. Composition/information on ingredients
Epoxy Polymer 13.7 25085-99-8Epoxy Polymer 13.7 61788-97-4Methyl Isobutyl Ketone 6.6 108-10-1Xylene 4.4 1330-20-7Ethylbenzene 0.8 100-41-4
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Other means of identification
: Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
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Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.Get medical attention. If necessary, call a poison center or physician. If unconscious,place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments : No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation : Harmful if inhaled.
Irritating to mouth, throat and stomach.:Ingestion
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:irritationredness
:
:
:
Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness
Potential acute health effects
Indication of immediate medical attention and special treatment needed, if necessary
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Section 4. First aid measuresSee toxicological information (Section 11)
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials:carbon dioxidecarbon monoxide
Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back.Runoff to sewer may create fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
Use dry chemical, CO₂, water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing media
:
Unsuitable extinguishing media
:
Special protective actions for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact
:
: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
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Section 6. Accidental release measuresinformation and Section 13 for waste disposal.
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage,including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Methyl Isobutyl Ketone ACGIH TLV (United States, 4/2014). TWA: 20 ppm 8 hours. STEL: 75 ppm 15 minutes.NIOSH REL (United States, 10/2013). TWA: 50 ppm 10 hours. TWA: 205 mg/m³ 10 hours. STEL: 75 ppm 15 minutes. STEL: 300 mg/m³ 15 minutes.OSHA PEL (United States, 2/2013). TWA: 100 ppm 8 hours. TWA: 410 mg/m³ 8 hours.
Xylene ACGIH TLV (United States, 4/2014). TWA: 100 ppm 8 hours. TWA: 434 mg/m³ 8 hours. STEL: 150 ppm 15 minutes. STEL: 651 mg/m³ 15 minutes.OSHA PEL (United States, 2/2013). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours.
Ethylbenzene ACGIH TLV (United States, 4/2014). TWA: 20 ppm 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Section 8. Exposure controls/personal protectionNIOSH REL (United States, 10/2013). TWA: 100 ppm 10 hours. TWA: 435 mg/m³ 10 hours. STEL: 125 ppm 15 minutes. STEL: 545 mg/m³ 15 minutes.OSHA PEL (United States, 2/2013). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours.
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.
:
Environmental exposure controls
: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas,vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
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Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.62
3.45 [Air = 1]
0.28 kPa (2.133 mm Hg) [at 20°C]
Not available.Odor
pH
Not available.Color
Evaporation rate 1.62 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 18°C (64.4°F) [Pensky-Martens Closed Cup]
Not available.
Viscosity Kinematic (room temperature): >0.205 cm2/s (>20.5 cSt)Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Not available.Odor threshold
Partition coefficient: n-octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point : 113°C (235.4°F)
Flammability (solid, gas) : Not available.
Lower and upper explosive (flammable) limits
: Lower: 1%Upper: 7.5%
Decomposition temperature : Not available.
Heat of combustion : 0.000003913 kJ/g
Aerosol product
Molecular weight : Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
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Section 11. Toxicological information
Acute toxicity
Methyl Isobutyl Ketone LD50 Oral Rat 2080 mg/kg -Xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours
LD50 Oral Rat 4300 mg/kg -Ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 3500 mg/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Methyl Isobutyl Ketone Eyes - Moderate irritant Rabbit - 24 hours 100 microliters
-
Eyes - Severe irritant Rabbit - 40 milligrams -Skin - Mild irritant Rabbit - 24 hours 500
milligrams-
Xylene Eyes - Mild irritant Rabbit - 87 milligrams -Eyes - Severe irritant Rabbit - 24 hours 5
milligrams-
Skin - Mild irritant Rat - 8 hours 60 microliters
-
Skin - Moderate irritant Rabbit - 24 hours 500 milligrams
-
Skin - Moderate irritant Rabbit - 100 Percent -Ethylbenzene Eyes - Severe irritant Rabbit - 500
milligrams-
Skin - Mild irritant Rabbit - 24 hours 15 milligrams
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Information on toxicological effects
Classification
Methyl Isobutyl Ketone - 2B -Xylene - 3 -Ethylbenzene - 2B -
Product/ingredient name NTPIARCOSHA
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Section 11. Toxicological information
Specific target organ toxicity (repeated exposure)
Methyl Isobutyl Ketone Category 3 Not applicable. Respiratory tract irritation and Narcotic effects
Xylene Category 3 Not applicable. Respiratory tract irritation and Narcotic effects
Ethylbenzene Category 3 Not applicable. Respiratory tract irritation and Narcotic effects
Name Category
Name Category
Methyl Isobutyl Ketone Category 2 Not determined Not determinedXylene Category 2 Not determined Not determinedEthylbenzene Category 2 Not determined Not determined
Aspiration hazard
Name Result
Xylene ASPIRATION HAZARD - Category 1Ethylbenzene ASPIRATION HAZARD - Category 1
Route of exposure
Target organs
Route of exposure
Target organs
Information on the likely routes of exposure
Inhalation : Harmful if inhaled.
Irritating to mouth, throat and stomach.:Ingestion
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:irritationredness
:
:
:
Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness
Delayed and immediate effects and also chronic effects from short and long term exposure
: Not available.
Potential acute health effects
Potential immediate effects
: Not available.
Short term exposure
Potential delayed effects : Not available.
Potential immediate effects
: Not available.
Long term exposure
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Not available.
May cause damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
General :
Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Potential chronic health effects
Numerical measures of toxicity
Oral 3491 mg/kgInhalation (gases) 16829.4 ppm
Route ATE value
Acute toxicity estimates
Potential delayed effects : Not available.
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
Xylene - 8.1 to 25.9 low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Methyl Isobutyl Ketone - - ReadilyXylene - - ReadilyEthylbenzene - - Readily
Toxicity
Methyl Isobutyl Ketone Acute LC50 505000 µg/l Fresh water Fish - Pimephales promelas 96 hoursChronic NOEC 78 mg/l Fresh water Daphnia - Daphnia magna 21 daysChronic NOEC 168 mg/l Fresh water Fish - Pimephales promelas -
Embryo33 days
Xylene Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes pugio
48 hours
Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hoursEthylbenzene Acute EC50 4600 µg/l Fresh water Algae - Pseudokirchneriella
subcapitata72 hours
Acute EC50 3600 µg/l Fresh water Algae - Pseudokirchneriella subcapitata
96 hours
Acute EC50 6530 µg/l Fresh water Crustaceans - Artemia sp. -Nauplii
48 hours
Acute EC50 2930 µg/l Fresh water Daphnia - Daphnia magna -Neonate
48 hours
Acute LC50 4200 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Mobility in soil
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Section 12. Ecological information
Other adverse effects : No known significant effects or critical hazards.
Soil/water partition coefficient (KOC)
: Not available.
Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
PAINT RELATED MATERIAL
3
II
PAINT RELATED MATERIAL.Marine pollutant (Epoxy Polymer,Epoxy Polymer)
3
II
UN1263 UN1263
Special provisionsNot Applicable
The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
Emergency schedules (EmS)F-E, S-E
DOT Classification
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Additional information
Environmental hazards
No. Yes.
TDG Classification
UN1263
PAINT RELATED MATERIAL
3
II
No.
Special provisionsNot Applicable
Mexico Classification
UN1263
PAINT RELATED MATERIAL
3
II
No.
Special provisions(ERG#128)
IATA
UN1263
PAINT RELATED MATERIAL
3
II
No.
The environmentally hazardous substance mark may appear if required by other transportation regulations.
Special provisionsNot Applicable
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Section 14. Transport informationSpecial precautions for user
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not available.
:
Proper shipping name :
Ship type : Not available.
Pollution category : Not available.
Not available.
: Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.
Section 15. Regulatory informationU.S. Federal regulations :
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.
California Prop. 65
State regulations
Section 16. Other information
Notice to reader
Hazardous Material Information System (U.S.A.)
2
3
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
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Section 16. Other informationIt is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.
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MACROPOXY® 646 Fast Cure Epoxy Coating (Part A)Mill White
Not available.
Liquid.
(216) 566-2917
SAFETY DATA SHEET
Product name
Other means of identification
Product type
Emergency telephone number of the company
Section 1. Identification:
:
:
:
Manufacturer : THE SHERWIN-WILLIAMS COMPANY101 PROSPECT AVENUE, NWCLEVELAND, OHIO 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
B58W610
B58W610Product code :
Product Information Telephone Number
: (800) 524-5979
Regulatory Information Telephone Number
: (216) 566-2902
Transportation Emergency Telephone Number
: (800) 424-9300
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 3SKIN CORROSION/IRRITATION - Category 2SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1SKIN SENSITIZATION - Category 1CARCINOGENICITY - Category 2SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2ASPIRATION HAZARD - Category 1
Classification of the substance or mixture
:
Signal word : Danger
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 40.1%
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Flammable liquid and vapor.Causes serious eye damage.Causes skin irritation.May cause an allergic skin reaction.Suspected of causing cancer.May be fatal if swallowed and enters airways.May cause damage to organs through prolonged or repeated exposure.
:Hazard statements
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Section 2. Hazards identificationPrevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Do not breathe vapor.Wash hands thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or physician.
Storage : Store locked up. Store in a well-ventilated place. Keep cool.
Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations.
Hazards not otherwise classified
:None known.
Please refer to the SDS for additional information. Do not transfer contents to other containers for storage.
Supplemental label elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY. This product must be mixed with other components before use. Before opening the packages, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS.
Section 3. Composition/information on ingredients
Titanium Dioxide ≥25 - <50 13463-67-7Methylstyrenated Phenolic Resin ≥10 - <25 68512-30-1Xylene ≥10 - <14.9 1330-20-7Polyamide ≥10 - <25 68410-23-1Ethylbenzene ≥2 - <3 100-41-4Triethylene Tetramine ≥0.3 - <1 112-24-3
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of identification
: Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
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Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician.
Get medical attention immediately. Call a poison center or physician. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments : No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation : No known significant effects or critical hazards.
May be fatal if swallowed and enters airways.:Ingestion
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye damage.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
Adverse symptoms may include the following:stomach painsnausea or vomiting
Adverse symptoms may include the following:pain or irritationrednessblistering may occur
:
:
:
Eye contact : Adverse symptoms may include the following:painwateringredness
Potential acute health effects
Indication of immediate medical attention and special treatment needed, if necessary
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Section 4. First aid measuresProtection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials:carbon dioxidecarbon monoxidemetal oxide/oxides
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back.Runoff to sewer may create fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
Use dry chemical, CO₂, water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing media
:
Unsuitable extinguishing media
:
Special protective actions for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
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Section 6. Accidental release measuresStop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
Large spill :
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage,including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Titanium Dioxide ACGIH TLV (United States, 3/2015). TWA: 10 mg/m³ 8 hours.OSHA PEL (United States, 2/2013). TWA: 15 mg/m³ 8 hours. Form: Total dust
Methylstyrenated Phenolic Resin None.Xylene ACGIH TLV (United States, 3/2015).
TWA: 100 ppm 8 hours. TWA: 434 mg/m³ 8 hours. STEL: 150 ppm 15 minutes. STEL: 651 mg/m³ 15 minutes.OSHA PEL (United States, 2/2013). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Section 8. Exposure controls/personal protectionPolyamide None.Ethylbenzene ACGIH TLV (United States, 3/2015).
TWA: 20 ppm 8 hours.NIOSH REL (United States, 10/2013). TWA: 100 ppm 10 hours. TWA: 435 mg/m³ 10 hours. STEL: 125 ppm 15 minutes. STEL: 545 mg/m³ 15 minutes.OSHA PEL (United States, 2/2013). TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours.
Triethylene Tetramine AIHA WEEL (United States, 10/2011).Absorbed through skin. TWA: 1 ppm 8 hours.
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.
:
Environmental exposure controls
: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas,vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
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Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.46
3.66 [Air = 1]
0.13 kPa (0.946 mm Hg) [at 20°C]
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 0.8 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 29°C (84.2°F) [Pensky-Martens Closed Cup]
Not available.
Not available.
Viscosity Kinematic (room temperature): <0.205 cm2/s (<20.5 cSt)Kinematic (40°C (104°F)): <0.205 cm2/s (<20.5 cSt)
Not available.Odor threshold
Partition coefficient: n-octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point : 136°C (276.8°F)
Flammability (solid, gas) : Not available.
Lower and upper explosive (flammable) limits
: Lower: 1%Upper: 7%
Decomposition temperature : Not available.
Heat of combustion : 5.517 kJ/g
Aerosol product
Molecular weight : Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
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Section 11. Toxicological information
Acute toxicity
Xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hoursLD50 Oral Rat 4300 mg/kg -
Ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -LD50 Oral Rat 3500 mg/kg -
Triethylene Tetramine LD50 Dermal Rabbit 805 mg/kg -LD50 Oral Rat 2500 mg/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 Micrograms Intermittent
-
Xylene Eyes - Mild irritant Rabbit - 87 milligrams -Eyes - Severe irritant Rabbit - 24 hours 5
milligrams-
Skin - Mild irritant Rat - 8 hours 60 microliters
-
Skin - Moderate irritant Rabbit - 24 hours 500 milligrams
-
Skin - Moderate irritant Rabbit - 100 Percent -Ethylbenzene Eyes - Severe irritant Rabbit - 500
milligrams-
Skin - Mild irritant Rabbit - 24 hours 15 milligrams
-
Triethylene Tetramine Eyes - Moderate irritant Rabbit - 24 hours 20 milligrams
-
Eyes - Severe irritant Rabbit - 49 milligrams -Skin - Severe irritant Rabbit - 24 hours 5
milligrams-
Skin - Severe irritant Rabbit - 490 milligrams
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Information on toxicological effects
Classification
Titanium Dioxide - 2B -Xylene - 3 -Ethylbenzene - 2B -
Product/ingredient name NTPIARCOSHA
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Section 11. Toxicological information
Specific target organ toxicity (repeated exposure)
Xylene Category 3 Not applicable. Respiratory tract irritation and Narcotic effects
Ethylbenzene Category 3 Not applicable. Respiratory tract irritation and Narcotic effects
Name Category
Name Category
Xylene Category 2 Not determined Not determinedEthylbenzene Category 2 Not determined Not determined
Aspiration hazard
Name Result
Xylene ASPIRATION HAZARD - Category 1Ethylbenzene ASPIRATION HAZARD - Category 1
Route of exposure
Target organs
Route of exposure
Target organs
Information on the likely routes of exposure
Inhalation : No known significant effects or critical hazards.
May be fatal if swallowed and enters airways.:Ingestion
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye damage.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
Adverse symptoms may include the following:stomach painsnausea or vomiting
Adverse symptoms may include the following:pain or irritationrednessblistering may occur
:
:
:
Eye contact : Adverse symptoms may include the following:painwateringredness
Delayed and immediate effects and also chronic effects from short and long term exposure
: Not available.
Potential acute health effects
Potential immediate effects
: Not available.
Short term exposure
Potential delayed effects : Not available.
Potential immediate effects
: Not available.
Long term exposure
Potential delayed effects : Not available.
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Not available.
May cause damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
General :
Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Potential chronic health effects
Numerical measures of toxicity
Oral 14345.4 mg/kgInhalation (gases) 20303.1 ppm
Route ATE value
Acute toxicity estimates
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
Titanium Dioxide - 352 lowXylene - 8.1 to 25.9 low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Xylene - - ReadilyEthylbenzene - - Readily
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hoursXylene Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes
pugio48 hours
Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hoursEthylbenzene Acute EC50 4600 µg/l Fresh water Algae - Pseudokirchneriella
subcapitata72 hours
Acute EC50 3600 µg/l Fresh water Algae - Pseudokirchneriella subcapitata
96 hours
Acute EC50 6530 µg/l Fresh water Crustaceans - Artemia sp. -Nauplii
48 hours
Acute EC50 2930 µg/l Fresh water Daphnia - Daphnia magna -Neonate
48 hours
Acute LC50 4200 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hoursTriethylene Tetramine Acute EC50 3700 µg/l Fresh water Algae - Pseudokirchneriella
subcapitata96 hours
Acute LC50 33900 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Mobility in soil
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Section 12. Ecological information
Other adverse effects : No known significant effects or critical hazards.
Soil/water partition coefficient (KOC)
: Not available.
Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
PAINT
3
III
PAINT
3
III
UN1263 UN1263
Special provisionsNot Applicable
Emergency schedules (EmS)F-E, S-E
DOT Classification
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Additional information
Environmental hazards
No. No.
TDG Classification
UN1263
PAINT
3
III
No.
Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3).
Special provisionsNot Applicable
Mexico Classification
UN1263
PAINT
3
III
No.
Special provisions(ERG#128)
IATA
UN1263
PAINT
3
III
No.
Special provisionsNot Applicable
128
ERG No.
128 128
ERG No. ERG No.
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Section 14. Transport informationSpecial precautions for user
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not available.
:
Proper shipping name :
Ship type : Not available.
Pollution category : Not available.
Not available.
: Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.
Section 15. Regulatory informationSARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.
California Prop. 65
Section 16. Other information
11/5/2015
History
Date of printing
Date of issue/Date of revision
Version
Date of previous issue
:
:
:
:
11/5/2015
7/30/2015
1.04
Hazardous Material Information System (U.S.A.)
3
3
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Procedure used to derive the classification
Classification Justification
Flam. Liq. 3, H226 On basis of test dataSkin Irrit. 2, H315 Calculation methodEye Dam. 1, H318 Calculation methodSkin Sens. 1, H317 Calculation methodCarc. 2, H351 Calculation methodSTOT RE 2, H373 Calculation methodAsp. Tox. 1, H304 Calculation method
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Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.
Notice to reader
Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations
Date of issue/Date of revision : 11/5/2015 Date of previous issue : 7/30/2015 Version : 1.04 13/13
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SEAGUARD™ 5000 HS EPOXY Hi-Solid Epoxy Coating (Part B)Clear Hardener
Not available.
Liquid.
(216) 566-2917
SAFETY DATA SHEET
Product name
Other means of identification
Product type
Emergency telephone number of the company
Section 1. Identification:
:
:
:
Manufacturer : THE SHERWIN-WILLIAMS COMPANY101 Prospect Avenue N.W.Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
N11V350
N11V350Product code :
Product Information Telephone Number
: Not available.
Regulatory Information Telephone Number
: (216) 566-2902
Transportation Emergency Telephone Number
: (800) 424-9300
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 3SKIN CORROSION/IRRITATION - Category 2SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2ASKIN SENSITIZATION - Category 1CARCINOGENICITY - Category 2SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2ASPIRATION HAZARD - Category 1
Classification of the substance or mixture
:
Signal word : Danger
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 85%
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Flammable liquid and vapor.Causes serious eye irritation.Causes skin irritation.May cause an allergic skin reaction.Suspected of causing cancer.May be fatal if swallowed and enters airways.May cause damage to organs through prolonged or repeated exposure.
:Hazard statements
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Section 2. Hazards identificationPrecautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection.Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Do not breathe vapor.Wash hands thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage : Store locked up. Store in a well-ventilated place. Keep cool.
Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations.
Hazards not otherwise classified
:None known.
Please refer to the SDS for additional information. Do not transfer contents to other containers for storage.
Supplemental label elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY. This product must be mixed with other components before use. Before opening the packages, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS. Adequate ventilation required when sanding or abrading the dried film. If Adequate ventilation cannot be provided wear an approved particulate respirator (NIOSH approved). Follow respirator manufacturer's directions for respirator use. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film may release Crystalline Silica which has been shown to cause lung damage and cancer under long term exposure.
Section 3. Composition/information on ingredients
Epoxy Polymer ≥25 - <50 25068-38-61,2,4-Trimethylbenzene ≥6 - <10 95-63-6Light Aromatic Hydrocarbons ≥4 - <5 64742-95-61,3,5-Trimethylbenzene ≥1.4 - <2.7 108-67-8Cumene ≥0.3 - <1 98-82-8
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of identification
: Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
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Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments : No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation : No known significant effects or critical hazards.
May be fatal if swallowed and enters airways.:Ingestion
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
Adverse symptoms may include the following:nausea or vomiting
Adverse symptoms may include the following:irritationredness
:
:
:
Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials:carbon dioxidecarbon monoxidehalogenated compoundsmetal oxide/oxides
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back.Runoff to sewer may create fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
Use dry chemical, CO₂, water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing media
:
Unsuitable extinguishing media
:
Special protective actions for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
:
: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
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Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage,including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Epoxy Polymer None.1,2,4-Trimethylbenzene ACGIH TLV (United States, 3/2015).
TWA: 25 ppm 8 hours. TWA: 123 mg/m³ 8 hours.NIOSH REL (United States, 10/2013). TWA: 25 ppm 10 hours. TWA: 125 mg/m³ 10 hours.
Light Aromatic Hydrocarbons None.1,3,5-Trimethylbenzene ACGIH TLV (United States, 3/2015).
TWA: 25 ppm 8 hours. TWA: 123 mg/m³ 8 hours.NIOSH REL (United States, 10/2013). TWA: 25 ppm 10 hours. TWA: 125 mg/m³ 10 hours.
Cumene ACGIH TLV (United States, 3/2015). TWA: 50 ppm 8 hours.NIOSH REL (United States, 10/2013).Absorbed through skin. TWA: 50 ppm 10 hours. TWA: 245 mg/m³ 10 hours.OSHA PEL (United States, 2/2013).Absorbed through skin. TWA: 50 ppm 8 hours. TWA: 245 mg/m³ 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Section 8. Exposure controls/personal protection
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.
:
Environmental exposure controls
: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas,vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid.
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 0.23 (butyl acetate = 1)
Flash point Closed cup: 38°C (100.4°F) [Pensky-Martens Closed Cup]
Not available.
Not available.Odor threshold
:
:
:
:
:
:
:
:
Appearance
Boiling point : 153°C (307.4°F)
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Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
Solubility
1.37
4.1 [Air = 1]
0.067 kPa (0.506 mm Hg) [at 20°C]
Not available.
Auto-ignition temperature Not available.
Not available.
Viscosity Kinematic (room temperature): <0.205 cm2/s (<20.5 cSt)Kinematic (40°C (104°F)): <0.205 cm2/s (<20.5 cSt)
Partition coefficient: n-octanol/water
:
:
:
:
:
:
:
Flammability (solid, gas) : Not available.
Lower and upper explosive (flammable) limits
: Lower: 0.7%Upper: 7%
Decomposition temperature : Not available.
Heat of combustion : 7.679 kJ/g
Aerosol product
Molecular weight : Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
1,2,4-Trimethylbenzene LC50 Inhalation Vapor Rat 18000 mg/m³ 4 hoursLD50 Oral Rat 5 g/kg -
Light Aromatic Hydrocarbons LD50 Oral Rat 8400 mg/kg -1,3,5-Trimethylbenzene LC50 Inhalation Vapor Rat 24000 mg/m³ 4 hours
LD50 Oral Rat 5000 mg/kg -Cumene LC50 Inhalation Vapor Rat 39000 mg/m³ 4 hours
LD50 Oral Rat 1400 mg/kg -
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
Information on toxicological effects
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Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Epoxy Polymer Eyes - Mild irritant Rabbit - 100 milligrams
-
Skin - Moderate irritant Rabbit - 24 hours 500 microliters
-
Skin - Severe irritant Rabbit - 24 hours 2 milligrams
-
Light Aromatic Hydrocarbons Eyes - Mild irritant Rabbit - 24 hours 100 microliters
-
1,3,5-Trimethylbenzene Eyes - Mild irritant Rabbit - 24 hours 500 milligrams
-
Skin - Moderate irritant Rabbit - 24 hours 20 milligrams
-
Cumene Eyes - Mild irritant Rabbit - 24 hours 500 milligrams
-
Eyes - Mild irritant Rabbit - 86 milligrams -Skin - Mild irritant Rabbit - 24 hours 10
milligrams-
Skin - Moderate irritant Rabbit - 24 hours 100 milligrams
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
1,2,4-Trimethylbenzene Category 3 Not applicable. Respiratory tract irritation and Narcotic effects
Light Aromatic Hydrocarbons Category 3 Not applicable. Respiratory tract irritation and Narcotic effects
1,3,5-Trimethylbenzene Category 3 Not applicable. Respiratory tract irritation and Narcotic effects
Cumene Category 3 Not applicable. Respiratory tract irritation and Narcotic effects
Name Category Route of exposure
Target organs
Classification
Cumene - 2B Reasonably anticipated to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
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Section 11. Toxicological informationName Category
1,2,4-Trimethylbenzene Category 2 Not determined Not determinedLight Aromatic Hydrocarbons Category 2 Not determined Not determined1,3,5-Trimethylbenzene Category 2 Not determined Not determinedCumene Category 2 Not determined Not determined
Aspiration hazard
Name Result
1,2,4-Trimethylbenzene ASPIRATION HAZARD - Category 1Light Aromatic Hydrocarbons ASPIRATION HAZARD - Category 11,3,5-Trimethylbenzene ASPIRATION HAZARD - Category 1Cumene ASPIRATION HAZARD - Category 1
Route of exposure
Target organs
Not available.
Information on the likely routes of exposure
Inhalation : No known significant effects or critical hazards.
May be fatal if swallowed and enters airways.:Ingestion
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
May cause damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
General :
Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.
Carcinogenicity :
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
Adverse symptoms may include the following:nausea or vomiting
Adverse symptoms may include the following:irritationredness
:
:
:
Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
: Not available.
Potential acute health effects
Potential immediate effects
: Not available.
Short term exposure
Potential delayed effects : Not available.
Potential immediate effects
: Not available.
Long term exposure
Potential delayed effects : Not available.
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No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Numerical measures of toxicity
Oral 8849.2 mg/kgInhalation (vapors) 40.35 mg/l
Route ATE value
Acute toxicity estimates
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects : No known significant effects or critical hazards.
Product/ingredient name
Epoxy Polymer - 31 low1,2,4-Trimethylbenzene - 243 lowLight Aromatic Hydrocarbons - 10 to 2500 high1,3,5-Trimethylbenzene - 161 lowCumene - 94.69 low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Light Aromatic Hydrocarbons - - Readily
Toxicity
1,2,4-Trimethylbenzene Acute LC50 4910 µg/l Marine water Crustaceans - Elasmopus pectenicrus - Adult
48 hours
Acute LC50 7720 µg/l Fresh water Fish - Pimephales promelas 96 hours1,3,5-Trimethylbenzene Acute LC50 13000 µg/l Marine water Crustaceans - Cancer magister -
Zoea48 hours
Acute LC50 12520 µg/l Fresh water Fish - Carassius auratus 96 hoursChronic NOEC 400 µg/l Fresh water Daphnia - Daphnia magna 21 days
Cumene Acute EC50 2600 µg/l Fresh water Algae - Pseudokirchneriella subcapitata
72 hours
Acute EC50 7400 µg/l Fresh water Crustaceans - Artemia sp. -Nauplii
48 hours
Acute EC50 10600 µg/l Fresh water Daphnia - Daphnia magna -Neonate
48 hours
Acute LC50 2700 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition coefficient (KOC)
: Not available.
Mobility in soil
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Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
PAINT
3
III
PAINT. Marine pollutant (1,3,5-Trimethylbenzene)
3
III
UN1263 UN1263
This product may be re-classified as "Combustible Liquid," unless transported by vessel or aircraft.Non-bulk packages (less than or equal to 119 gal) of combustible liquids are not regulated as hazardous materials in package sizes less than the product reportable quantity.
Special provisionsNot Applicable
The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
Emergency schedules (EmS)F-E, S-E
DOT Classification
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Additional information
Environmental hazards
No. Yes.
TDG Classification
UN1263
PAINT
3
III
No.
Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3).
Special provisionsNot Applicable
Mexico Classification
UN1263
PAINT
3
III
No.
Special provisions(ERG#128)
IATA
UN1263
PAINT
3
III
No.
The environmentally hazardous substance mark may appear if required by other transportation regulations.
Special provisionsNot Applicable
ERG No. ERG No. ERG No.
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Section 14. Transport information
Special precautions for user
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not available.
:
Proper shipping name :
Ship type : Not available.
Pollution category : Not available.
Not available.
: Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.
128 128 128
Section 15. Regulatory informationSARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.
California Prop. 65
Section 16. Other information
11/3/2015
History
Date of printing :
: 11/3/2015
Hazardous Material Information System (U.S.A.)
2
2
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Procedure used to derive the classification
Classification Justification
Flam. Liq. 3, H226 On basis of test dataSkin Irrit. 2, H315 Calculation methodEye Irrit. 2A, H319 Calculation methodSkin Sens. 1, H317 Calculation methodCarc. 2, H351 Calculation methodSTOT RE 2, H373 Calculation methodAsp. Tox. 1, H304 Calculation method
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Section 16. Other informationDate of issue/Date of revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.
Notice to reader
Date of previous issue
:
:
Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations
9/30/2015
2.01
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SEAGUARD™ 5000 HS EPOXY Hi-Solid Epoxy Coating (Part A)Black
Not available.
Liquid.
(216) 566-2917
SAFETY DATA SHEET
Product name
Other means of identification
Product type
Emergency telephone number of the company
Section 1. Identification:
:
:
:
Manufacturer : THE SHERWIN-WILLIAMS COMPANY101 Prospect Avenue N.W.Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
N11B350
N11B350Product code :
Product Information Telephone Number
: Not available.
Regulatory Information Telephone Number
: (216) 566-2902
Transportation Emergency Telephone Number
: (800) 424-9300
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 3ACUTE TOXICITY (oral) - Category 4SKIN CORROSION/IRRITATION - Category 2SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1SKIN SENSITIZATION - Category 1CARCINOGENICITY - Category 2SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -Category 3SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Classification of the substance or mixture
:
Signal word : Danger
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 62.2%
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
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Section 2. Hazards identification
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection.Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. IF ON SKIN (or hair):Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse.If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing. Immediately call a POISON CENTER or physician.
Storage : Store locked up. Store in a well-ventilated place. Keep cool.
Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations.
Hazards not otherwise classified
:None known.
Flammable liquid and vapor.Harmful if swallowed.Causes serious eye damage.Causes skin irritation.May cause an allergic skin reaction.Suspected of causing cancer.May cause respiratory irritation.May cause drowsiness and dizziness.May cause damage to organs through prolonged or repeated exposure.
:Hazard statements
Please refer to the SDS for additional information. Do not transfer contents to other containers for storage.
Supplemental label elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY. This product must be mixed with other components before use. Before opening the packages, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS. Adequate ventilation required when sanding or abrading the dried film. If Adequate ventilation cannot be provided wear an approved particulate respirator (NIOSH approved). Follow respirator manufacturer's directions for respirator use. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film may release Crystalline Silica which has been shown to cause lung damage and cancer under long term exposure.
Section 3. Composition/information on ingredients
Other means of identification
: Not available.
Substance/mixture
CAS number/other identifiers
: Mixture
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Section 3. Composition/information on ingredients
1-Butanol ≥14 - <25 71-36-3Polyamide ≥10 - <25 68410-23-1Phenylmethanol ≥7 - <10 100-51-6Carbon Black ≥3 - <5 1333-86-4Polyamidoamine ≥1 - <3 68953-36-6Triethylene Tetramine ≥0.3 - <1 112-24-3Tetraethylene Pentamine ≥0.1 - <0.3 112-57-2
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician.Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician.
Get medical attention immediately. Call a poison center or physician. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation.
Harmful if swallowed. Can cause central nervous system (CNS) depression.:Ingestion
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye damage.:Eye contact
Potential acute health effects
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Section 4. First aid measures
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:respiratory tract irritationcoughingnausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousness
Adverse symptoms may include the following:stomach pains
Adverse symptoms may include the following:pain or irritationrednessblistering may occur
:
:
:
Eye contact : Adverse symptoms may include the following:painwateringredness
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials:carbon dioxidecarbon monoxidenitrogen oxidesmetal oxide/oxides
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back.Runoff to sewer may create fire or explosion hazard.
Use dry chemical, CO₂, water spray (fog) or foam.
Extinguishing media
:
:
Do not use water jet.
Suitable extinguishing media
:
Unsuitable extinguishing media
:
Special protective actions for fire-fighters
:
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Section 5. Fire-fighting measuresFire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
:
: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Section 7. Handling and storage
Advice on general occupational hygiene
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
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Section 7. Handling and storageConditions for safe storage,including any incompatibilities
Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
:
1-Butanol ACGIH TLV (United States, 3/2015). TWA: 20 ppm 8 hours.NIOSH REL (United States, 10/2013).Absorbed through skin. CEIL: 50 ppm CEIL: 150 mg/m³OSHA PEL (United States, 2/2013). TWA: 100 ppm 8 hours. TWA: 300 mg/m³ 8 hours.
Polyamide None.Phenylmethanol AIHA WEEL (United States, 10/2011).
TWA: 10 ppm 8 hours.Carbon Black NIOSH REL (United States, 10/2013).
TWA: 3.5 mg/m³ 10 hours. TWA: 0.1 mg of PAHs/cm³ 10 hours.OSHA PEL (United States, 2/2013). TWA: 3.5 mg/m³ 8 hours.ACGIH TLV (United States, 3/2015). TWA: 3 mg/m³ 8 hours. Form: Inhalable fraction
Polyamidoamine None.Triethylene Tetramine AIHA WEEL (United States, 10/2011).
Absorbed through skin. TWA: 1 ppm 8 hours.
Tetraethylene Pentamine AIHA WEEL (United States, 10/2011).Absorbed through skin. Skin sensitizer. TWA: 5 mg/m³ 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Environmental exposure controls
: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas,vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Control parameters
Individual protection measures
Occupational exposure limits
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Section 8. Exposure controls/personal protection
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.
:
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Skin protection
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.32
2.55 [Air = 1]
0.098 kPa (0.733 mm Hg) [at 20°C]
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 0.43 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 38°C (100.4°F) [Pensky-Martens Closed Cup]
Not available.
Not available.
Not available.Odor threshold
Partition coefficient: n-octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point : 117°C (242.6°F)
Flammability (solid, gas) : Not available.
Lower and upper explosive (flammable) limits
: Lower: 1.4%Upper: 11.2%
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Section 9. Physical and chemical properties
Viscosity Kinematic (room temperature): >0.205 cm2/s (>20.5 cSt)Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
:
Decomposition temperature : Not available.
Heat of combustion : 11.7 kJ/g
Aerosol product
Molecular weight : Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
1-Butanol LC50 Inhalation Vapor Rat 24000 mg/m³ 4 hoursLD50 Dermal Rabbit 3400 mg/kg -LD50 Oral Rat 790 mg/kg -
Phenylmethanol LD50 Dermal Rabbit 2000 mg/kg -LD50 Oral Rat 1230 mg/kg -
Carbon Black LD50 Oral Rat >15400 mg/kg -Triethylene Tetramine LD50 Dermal Rabbit 805 mg/kg -
LD50 Oral Rat 2500 mg/kg -Tetraethylene Pentamine LD50 Oral Rat 3990 mg/kg -
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
1-Butanol Eyes - Severe irritant Rabbit - 24 hours 2 milligrams
-
Eyes - Severe irritant Rabbit - 0.005 Mililiters -Skin - Moderate irritant Rabbit - 24 hours 20
milligrams-
Phenylmethanol Skin - Mild irritant Man - 48 hours 16 milligrams
-
Skin - Moderate irritant Pig - 100 Percent -Skin - Moderate irritant Rabbit - 24 hours 100
milligrams-
Triethylene Tetramine Eyes - Moderate irritant Rabbit - 24 hours 20 milligrams
-
Product/ingredient name Result Score Exposure ObservationSpecies
Information on toxicological effects
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Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Eyes - Severe irritant Rabbit - 49 milligrams -Skin - Severe irritant Rabbit - 24 hours 5
milligrams-
Skin - Severe irritant Rabbit - 490 milligrams
-
Tetraethylene Pentamine Eyes - Moderate irritant Rabbit - 24 hours 100 milligrams
-
Eyes - Moderate irritant Rabbit - 5 milligrams -Skin - Severe irritant Rabbit - 24 hours 5
milligrams-
Skin - Severe irritant Rabbit - 495 milligrams
-
Sensitization
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
1-Butanol Category 3 Not applicable. Respiratory tract irritation and Narcotic effects
Phenylmethanol Category 3 Not applicable. Respiratory tract irritation and Narcotic effects
Name Category
Name Category
1-Butanol Category 2 Not determined Not determinedPhenylmethanol Category 2 Not determined Not determined
Aspiration hazard
Not available.
Route of exposure
Target organs
Route of exposure
Target organs
Classification
Carbon Black - 2B -
Product/ingredient name NTPIARCOSHA
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Not available.
Information on the likely routes of exposure
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation.
Harmful if swallowed. Can cause central nervous system (CNS) depression.:Ingestion
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye damage.:Eye contact
May cause damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
General :
Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:respiratory tract irritationcoughingnausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousness
Adverse symptoms may include the following:stomach pains
Adverse symptoms may include the following:pain or irritationrednessblistering may occur
:
:
:
Eye contact : Adverse symptoms may include the following:painwateringredness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
: Not available.
Potential acute health effects
Potential immediate effects
: Not available.
Short term exposure
Potential delayed effects : Not available.
Potential immediate effects
: Not available.
Long term exposure
Potential delayed effects : Not available.
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Oral 1178.5 mg/kgDermal 3622.9 mg/kg
Route ATE value
Acute toxicity estimates
Section 12. Ecological information
Bioaccumulative potential
Other adverse effects : No known significant effects or critical hazards.
Not available.
Product/ingredient name Aquatic half-life Photolysis Biodegradability
1-Butanol - - ReadilyPhenylmethanol - - Readily
Toxicity
1-Butanol Acute EC50 1983000 µg/l Fresh water Daphnia - Daphnia magna 48 hoursAcute LC50 1730000 µg/l Fresh water Fish - Pimephales promelas 96 hours
Phenylmethanol Acute LC50 10000 µg/l Fresh water Fish - Lepomis macrochirus 96 hoursTriethylene Tetramine Acute EC50 3700 µg/l Fresh water Algae - Pseudokirchneriella
subcapitata96 hours
Acute LC50 33900 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition coefficient (KOC)
: Not available.
Mobility in soil
Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
:Disposal methods
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Section 14. Transport information
PAINT
3
III
PAINT
3
III
UN1263 UN1263
This product may be re-classified as "Combustible Liquid," unless transported by vessel or aircraft.Non-bulk packages (less than or equal to 119 gal) of combustible liquids are not regulated as hazardous materials in package sizes less than the product reportable quantity.
Special provisionsNot Applicable
Emergency schedules (EmS)F-E, S-E
DOT Classification
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Additional information
Environmental hazards
Special precautions for user
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
No. No.
Not available.
:
Proper shipping name :
Not available.
:
TDG Classification
UN1263
PAINT
3
III
No.
Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3).
Special provisionsNot Applicable
Mexico Classification
UN1263
PAINT
3
III
No.
Special provisions(ERG#128)
Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.
IATA
UN1263
PAINT
3
III
No.
Special provisionsNot Applicable
128
ERG No.
128 128
ERG No. ERG No.
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Section 14. Transport informationShip type : Not available.
Pollution category : Not available.
Section 15. Regulatory informationSARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.
California Prop. 65
Section 16. Other information
11/3/2015
History
Date of printing
Date of issue/Date of revision
Version
Notice to reader
Date of previous issue
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Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations
11/3/2015
9/12/2015
1.03
Hazardous Material Information System (U.S.A.)
3
2
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Procedure used to derive the classification
Classification Justification
Flam. Liq. 3, H226 On basis of test dataAcute Tox. 4, H302 Calculation methodSkin Irrit. 2, H315 Calculation methodEye Dam. 1, H318 Calculation methodSkin Sens. 1, H317 Calculation methodCarc. 2, H351 Calculation methodSTOT SE 3, H335 Calculation methodSTOT SE 3, H336 Calculation methodSTOT RE 2, H373 Calculation method
Date of issue/Date of revision : 11/3/2015 Date of previous issue : 9/12/2015 Version : 1.03 13/14
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Section 16. Other informationIt is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.
Date of issue/Date of revision : 11/3/2015 Date of previous issue : 9/12/2015 Version : 1.03 14/14
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