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Process length scales as a framework for understanding flow, transport, and evolution of the karst Critical Zone Matt Covington – University of Arkansas Collaborators: Sid Jones (TDEC), Andrew Luhmann (U. Minnesota), Joe Myre (U. Arkansas), Matija Perne (U. Arkansas), Martin Saar (U. Minnesota), Carol Wicks (LSU)

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Page 1: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Process length scales as a framework for understanding flow, transport, and evolution of the

karst Critical ZoneMatt Covington – University of Arkansas

Collaborators: Sid Jones (TDEC), Andrew Luhmann (U. Minnesota), Joe

Myre (U. Arkansas), Matija Perne (U. Arkansas), Martin Saar (U. Minnesota), Carol Wicks (LSU)

Page 2: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

“It is nice to know that the computer

understands the problem, but I would like to understand it too.”

-Eugene Wigner

Page 3: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Descriptive:Statistical models

and black box models

Numerical simulations:Models built from basic physics and chemistry

Strength: Easy to apply, fewparameters, may accuratelypredict system behavior.

Weakness: connection to physical processes is frequently unclear. Predictivemodels may fail outside ofobserved range.

Strength: Direct connections to physical processes, assumptions clear.

Weakness: computationally expensive, many unknownparameters, and hard togeneralize.

Two typical approaches to mathematical modelingin the geosciences

Page 4: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Descriptive:Statistical models

and black box models

Numerical simulations:Models built from basic physics and chemistry

Strength: Easy to apply, fewparameters, may accuratelypredict system behavior.

Weakness: connection to physical processes is frequently unclear. Predictivemodels may fail outside ofobserved range.

Strength: Direct connections to physical processes, assumptions clear.

Weakness: computationally expensive, many unknownparameters, and hard togeneralize.

Simple models (toy models)Metrics and analytical solutions developed from process-based analysis

Two typical approaches to mathematical modelingin the geosciences

Page 5: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Descriptive:Statistical models

and black box models

Numerical simulations:Models built from basic physics and chemistry

Recession curve analysis

Reservoir models

System analysis

Neural networks

Reactive transport

Heat transport

Coupled conduit-matrix flow

CFD simulations

How can we interpret the physical and chemical variationsin flow at karst spring, cave stream, or drip site?

Page 6: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Descriptive:Statistical models

and black box models

Numerical simulations:Models built from basic physics and chemistry

Recession curve analysis

Reservoir models

System analysis

Neural networks

Reactive transport

Heat transport

Coupled conduit-matrix flow

CFD simulations

Simple models (toy models)Characteristic time scales,

characteristic length scales, dimensionless metrics

How can we interpret the physical and chemical variationsin flow at karst spring, cave stream, or drip site?

Page 7: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Process Lengths: A simple idea with many potential applications

Two requirements:

1. A process that occurs over a particular time scale

2. Flow that carries the process down a conduit(water or air)

Page 8: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

A characteristic length scale emergesA characteristic length scale emerges

Characteristic length scale

Length = (Time Scale) X (Flow Velocity)

Flow

Page 9: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Does a given process produce variations at a flowpathDoes a given process produce variations at a flowpathoutlet?outlet?

Covington et al., (2012). Process length scales and longitudinal damping in karst conduits. J. Geophys. Res.

Page 10: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Dissolutional Length ScalesDissolutional Length Scales

Using laminar flow: Using turbulent flow:

Longitudinal profiles of concentration are exponential, with e-folding length, λ.

(Covington et al., 2012, J. Geophys. Res.)

Page 11: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Decreasing head

gradient

Laminar/turbulenttransitions

(Covington et al., 2012, J. Geophys. Res.)

Typicalthickness ofkarst Critical

Zone

Page 12: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

(Covington et al., 2012, J. Geophys. Res.)

The “transmission fraction,” Fi,

is related to process length scale

Page 13: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Linear case:

(Covington et al., 2012, J. Geophys. Res.)

Page 14: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

(Covington et al., 2012, J. Geophys. Res.)

Page 15: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

(Covington et al., 2012, J. Geophys. Res.)

F=0.5

Page 16: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

(Covington et al., 2012, J. Geophys. Res.)

F=0.5

F=0.95

Page 17: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

(Covington et al., 2012, J. Geophys. Res.)

F=0.5

F=0.95 F=0.95

Page 18: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Response of Conduit Networks

Physical Interpretation: factors that control signal amplitude

1. Input signal amplitude

2. The capability of individual flow paths to transmit or dampen the signal

3. The distribution of flow among paths with different transmission factors

(Covington et al., 2012, J. Geophys. Res.)

Page 19: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Response of Conduit Networks

Physical Interpretation: factors that control signal amplitude

1. Input signal amplitude

2. The capability of individual flow paths to transmit or dampen the signal

3. The distribution of flow among paths with different transmission factors

(Covington et al., 2012, J. Geophys. Res.)

Page 20: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Response of Conduit Networks

Physical Interpretation: factors that control signal amplitude

1. Input signal amplitude

2. The capability of individual flow paths to transmit or dampen the signal

3. The distribution of flow among paths with different transmission factors

(Covington et al., 2012, J. Geophys. Res.)

Page 21: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Response of Conduit Networks

Physical Interpretation: factors that control signal amplitude

1. Input signal amplitude

2. The capability of individual flow paths to transmit or dampen the signal

3. The distribution of flow among paths with different transmission factors

(Covington et al., 2012, J. Geophys. Res.)

Page 22: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Spe

cific

Con

duct

ance

(S

/cm

)

Borsato (1997). Data from two drip sitesin Grotta di Ernesto

Tem

pera

ture

(C

)

Page 23: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Covington et al., 2012, J. Geophys. Res.

Fraction of signal transmitted

Fra

ctio

n o

f re

char

ge

Spe

cific

Con

duct

ance

(S

/cm

)

Page 24: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Length scales and epikarst evolution

A rich playground of length scalesand time scales!

Page 25: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Length scales and epikarst evolution

Gabrovšek (2007), Acta Carsologica

Page 26: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Length scales and epikarst evolutionWhat about CO

2?

Depth (m)

PC

O2

(atm

)

Frequently, CO2

increases with depth

in the vadose zone

Atkinson (1977), Journal ofhydrology.

Page 27: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

CO2 at depth may be an important

driver in speleogenesis and diagenesis

Gulley et al (2013). ESPL.

See also Whitaker andSmart (2007).

Hydrol. Process.

Page 28: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

CO2 production and diffusion: the basics

Increasing CO2

Dep

th b

elo

w s

urf

ace

Surface

Wood (1985). Geology.

● Diffusion is a slow process

● With even a small amount of CO

2 production at depth, we

can reach high concentrations.

● Without a significant CO2 sink at

depth, have to establish a significant gradient to allow diffusion to the surface.

● For the same CO2 production,

deeper vadose zones will have higher CO

2

Page 29: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

● Diffusion is a slow process

● With even a small amount of CO

2 production at depth, we

can reach high concentrations.

● Without a significant CO2 sink at

depth, have to establish a significant gradient to allow diffusion to the surface.

● For the same CO2 production,

deeper vadose zones will have higher CO

2

CO2 production and diffusion: the basics

Increasing CO2

Dep

th b

elo

w s

urf

ace

Surface

Wood (1985). Geology.

Production=Flux∼D(Cdeep−C surface)

h

Page 30: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

What about advection?

Photo: Hazel Barton

Page 31: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

What about advection?

CO2 (ppm)

Dep

th (

m)

Figure from Benavente et al. (2010).

Vadose Zone J.

Diffusion abhors

sharp edges!

Page 32: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Seasonal airflow patterns as a strong control on cave CO

2

Wong et al.(2011), GCA.

See also:

Frisia et al.(2011), GCA.

and

Breecker et al.(2012), GCA.

Page 33: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Modes of advective flow in karstEntrance zone convection cells

Entrancewithcool

externaltemperatures

Page 34: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Modes of advective flow in karstEntrance zone convection cells

Similar mechanismsmay drive convectivecells through fracture

networks

Page 35: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Modes of advective flow in karstChimney-effect airflow

When outsidetemperature

is cooler thancave temperature

airflow is driven fromlower to higher

entrances

Page 36: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Modes of advective flow in karstChimney-effect airflow

When outsidetemperature

is warmer thancave temperature

airflow is driven fromhigher to lower

entrances

Page 37: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Advective flow dominates in caves, but what about fractures?

Photo: Hazel Barton

Page 38: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Advection vs. Diffusion:The Peclet Number

Pe=t diff

t adv

=VLD

Pe=a2 g

12νD (ΔTT ext )H

If Pe >> 1: advective

If Pe << 1: diffusive

For a 1 mm fracture in a 10 m vadose zone, with a 3% temperature difference, Pe~3x105 !!!

For chimney-effect airflow, we get:

a = fracture aperture

H

Cave

Page 39: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Can advection really influencethe bulk of the vadose zone

or just isolated regions around caves and fractures?

Diffusioncontrolled

Advectioncontrolled

Page 40: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Can advection really influencethe bulk of the vadose zone

or just isolated regions around caves and fractures?

Diffusioncontrolled

Advectioncontrolled

Diffusion time to the nearestfracture is the important factor

rather than diffusion to the surface

Page 41: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Wind-driven advective flows

Roland et al. (2013), Biogeosciences.

Page 42: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Loads of lengths

CO2 production

length scales:Filtration

Decay of organic matterRoot depth distribution

Air-water CO2

exchange length scale:Controls whether water equilibrates

to air CO2 or lags behind it with

depth

Ratio of dissolution length scale to lengthscale over which CO

2 changes

Controls vertical distribution of dissolution

Page 43: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Simple models allow rapid generation of relevant questions and

testable hypotheses

Page 44: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Temperature changes with depthTemperature changes with depthfrom surface conductionfrom surface conduction

(periodic forcing)(periodic forcing)

skin depth∼√αrTπ

For diurnal variations: ~10 cm

For annual variations: ~3 m

Page 45: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Propagation of periodic thermal signalsPropagation of periodic thermal signalsthrough advection down fracturesthrough advection down fractures

A periodic change in recharge water temperature leads to a thermal penetration length given by

=w c p , w

r c p , rwhere

V is the flow velocity, DH is the hydraulic diameter,

r is the thermal diffusivity of rock,

and is the angular frequency of temperature variations.

Luhmann et al. (in prep)

Page 46: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Propagation of periodic thermal signalsPropagation of periodic thermal signalsthrough advection down fracturesthrough advection down fractures

∇h=0.01

∇h=1∇h=0.1

Typical Karst Critical Zone Thickness

Page 47: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Propagation of periodic thermal signalsPropagation of periodic thermal signalsthrough advection down fracturesthrough advection down fractures

∇h=0.01

∇h=1∇h=0.1

Typical Karst Critical Zone Thickness

Caveat: this length scale can be significantlyenhanced by exchange of air through the

vadose zone (e.g. Luetscher and Jeannin, 2004, Terra Nova)

Page 48: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Decreasing head

gradient

Laminar/turbulenttransitions

(Covington et al., 2012, J. Geophys. Res.)

Typicalthickness ofkarst Critical

Zone

Example: DH = 1 mm, ∇h=0.01

~3 m

Page 49: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Decreasing head

gradient

Laminar/turbulenttransitions

(Covington et al., 2012, J. Geophys. Res.)

Typicalthickness ofkarst Critical

Zone

Example: DH = 1 mm, ∇h=0.01

~5 m

Signal is damped

Page 50: Process length scales as a framework for understanding flow, transport, and evolution ... · 2013. 12. 4. · Process length scales as a framework for understanding flow, transport,

Decreasing head

gradient

Laminar/turbulenttransitions

(Covington et al., 2012, J. Geophys. Res.)

Typicalthickness ofkarst Critical

Zone

Signal is undamped