processing of polymers · 2016. 1. 2. · manufacturing, engineering & technology, fifth...
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PRODUCTION TECHNIQUES(MANUFACTRING PROCESSES)
ACADEMIC YEAR 94-95, SEMESTER ONE
PROCESSING OF POLYMERS
Manufacturing, Engineering & Technology, Fifth Edition, by Serope Kalpakjian and Steven R. Schmid.ISBN 0-13-148965-8. © 2006 Pearson Education, Inc., Upper Saddle River, NJ. All rights reserved.
Chapter 7Polymers: Structure, General Properties and Applications
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Polymers Polymers and Plastics Plastics are one of numerous polymeric materials and have
extremely large molecules (macromolecules or giant molecules)
Consumer and industrial products Replacing for metallic components in applications such as
automobiles, civilian and military aircraft, sporting goods, toys and so on because of their unique and diverse properties
Polymers characteristics Corrosion resistance and resistance to chemicals Low electrical and thermal conductivity Low density High strength-to-weight ratio (particularly when reinforced) Noise reduction Wide choice of colors and transparencies Ease of manufacturing and complexity of design possibilities Relative low cost Low strength and stiffness High coefficient of thermal expansion Low useful-temperature range- up to 350°C Lower dimensional stability in service over a period of time
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Manufacturing, Engineering & Technology, Fifth Edition, by Serope Kalpakjian and Steven R. Schmid.ISBN 0-13-148965-8. © 2006 Pearson Education, Inc., Upper Saddle River, NJ. All rights reserved.
Mechanical Properties of Engineering Plastics
Manufacturing, Engineering & Technology, Fifth Edition, by Serope Kalpakjian and Steven R. Schmid.ISBN 0-13-148965-8. © 2006 Pearson Education, Inc., Upper Saddle River, NJ. All rights reserved.
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Manufacturing, Engineering & Technology, Fifth Edition, by Serope Kalpakjian and Steven R. Schmid.ISBN 0-13-148965-8. © 2006 Pearson Education, Inc., Upper Saddle River, NJ. All rights reserved.
Structure of Polymer Molecules
Figure 7.2 Molecular structure of various polymers.
Manufacturing, Engineering & Technology, Fifth Edition, by Serope Kalpakjian and Steven R. Schmid.ISBN 0-13-148965-8. © 2006 Pearson Education, Inc., Upper Saddle River, NJ. All rights reserved.
Polymerization
Figure 7.3 Examples of polymerization. (a) Condensation polymerization of nylon 6,6 and (b) addition polymerization of polyethylene molecules from ethylene mers.
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Manufacturing, Engineering & Technology, Fifth Edition, by Serope Kalpakjian and Steven R. Schmid.ISBN 0-13-148965-8. © 2006 Pearson Education, Inc., Upper Saddle River, NJ. All rights reserved.
The Effect of Molecular Weight and Degree of Polymerization on Polymers
Figure 7.4 Effect of molecular weight and degree of polymerization on the strength and viscosity of polymers.
Manufacturing, Engineering & Technology, Fifth Edition, by Serope Kalpakjian and Steven R. Schmid.ISBN 0-13-148965-8. © 2006 Pearson Education, Inc., Upper Saddle River, NJ. All rights reserved.
Polymer Chains
Figure 7.5 Schematic illustration of polymer chains. (a) Linear structure – thermoplastics such as acrylics, nylons, polyethylene, and polyvinyl chloride have linear structures. (b) Branched structure, such as in polyethylene. (c) Cross-linked structure – many rubbers or elastomers have this structure, and the vulcanization of rubber produces this structure. (d) Network structure, which is basically highly cross-linked – examples are thermosetting plastics, such as expoxies and phenolics.
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Manufacturing, Engineering & Technology, Fifth Edition, by Serope Kalpakjian and Steven R. Schmid.ISBN 0-13-148965-8. © 2006 Pearson Education, Inc., Upper Saddle River, NJ. All rights reserved.
Behavior of Polymers
Figure 7.6 Behavior of polymers as a function of temperature and (a) degree of crystallinity and (b) cross-linking. The combined elastic and viscous behavior of polymers is known as viscoelasticity.
Manufacturing, Engineering & Technology, Fifth Edition, by Serope Kalpakjian and Steven R. Schmid.ISBN 0-13-148965-8. © 2006 Pearson Education, Inc., Upper Saddle River, NJ. All rights reserved.
Amorphous and Crystalline Regions in a Polymer
Figure 7.8 Amorphous and crystalline regions in a polymer. The crystalline region (crystallite) has an orderly arrangement of molecules. The higher the crystallinity, the harder, stiffer, and less ductile the polymer.
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Manufacturing, Engineering & Technology, Fifth Edition, by Serope Kalpakjian and Steven R. Schmid.ISBN 0-13-148965-8. © 2006 Pearson Education, Inc., Upper Saddle River, NJ. All rights reserved.
Volume of Polymers as a Function of Temperature
Figure 7.9 Specific volume of polymers as a function of temperature. Amorphous polymers, such as acrylic and polycarbonate, have a glass-transition temperature, Tg, but do not have a specific melting point, Tm. Partly crystalline polymers, such as polyethylene and nylons, contract sharply while passing through their melting temperatures during cooling.
Manufacturing, Engineering & Technology, Fifth Edition, by Serope Kalpakjian and Steven R. Schmid.ISBN 0-13-148965-8. © 2006 Pearson Education, Inc., Upper Saddle River, NJ. All rights reserved.
Glass-Transition and Melting Temperatures of Polymers
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Manufacturing, Engineering & Technology, Fifth Edition, by Serope Kalpakjian and Steven R. Schmid.ISBN 0-13-148965-8. © 2006 Pearson Education, Inc., Upper Saddle River, NJ. All rights reserved.
Types of Plastics
Figure 7.10 General terminology describing the behavior of three types of plastics. PTFE (polytetrafluoroethylene) has Teflon as its trade name. Source: After R.L.E. Brown
Manufacturing, Engineering & Technology, Fifth Edition, by Serope Kalpakjian and Steven R. Schmid.ISBN 0-13-148965-8. © 2006 Pearson Education, Inc., Upper Saddle River, NJ. All rights reserved.
Effect of Temperature on the Stress-strain Curve for Cellulose Acetate
Figure 7.11 Effect of temperature on the stress-strain curve for cellulose acetate, a thermoplastic. Note the large drop in strength and the large increase in ductility with a relatively small increase in temperature. Source: After T.S. Carswell and H.K. Nason.
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Manufacturing, Engineering & Technology, Fifth Edition, by Serope Kalpakjian and Steven R. Schmid.ISBN 0-13-148965-8. © 2006 Pearson Education, Inc., Upper Saddle River, NJ. All rights reserved.
Effect of Temperature on Plastic Impact Strength
Figure 7.12 Effect of temperature on the impact strength of various plastics. Small changes in temperature can have a significant effect on impact strength. Source: After P.C. Powell
Manufacturing, Engineering & Technology, Fifth Edition, by Serope Kalpakjian and Steven R. Schmid.ISBN 0-13-148965-8. © 2006 Pearson Education, Inc., Upper Saddle River, NJ. All rights reserved.
Plastic Product Recommendations
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Manufacturing, Engineering & Technology, Fifth Edition, by Serope Kalpakjian and Steven R. Schmid.ISBN 0-13-148965-8. © 2006 Pearson Education, Inc., Upper Saddle River, NJ. All rights reserved.
Thermoplastic Polymer Trade Names
Manufacturing, Engineering & Technology, Fifth Edition, by Serope Kalpakjian and Steven R. Schmid.ISBN 0-13-148965-8. © 2006 Pearson Education, Inc., Upper Saddle River, NJ. All rights reserved.
Load-Elongation Curve for Rubbers
Figure 7.14 Typical load-elongation curve for rubbers. The clockwise loop, indicating the loading and the unloading paths, displays the hysteresis loss. Hysteresis gives rubbers the capacity to dissipate energy, damp vibration, and absorb shock loading, as is necessary in automobile tires and in vibration dampers placed under machinery.