progress on cellulose nanofiber - filled thermoplastic...

Progress on cellulose nanofiber-filled thermoplastic composites

Douglas J. Gardner, Yousoo Han, Alper Kiziltas, and Yucheng Peng

Session 5: The role of nanotechnology in green materials and sustainable

construction.

Overview

• Why cellulose nanofiber (CNF)-filled composites?

• UMaine’s cellulose nanocomposites research program

• Engineering thermoplastics• Thermoplastic starch carrier for CNF• Drying CNF without agglomeration• Challenges

Nanotech is 3rd Industrial RevolutionUS Gov. R&D in Nanotech = $1.5 billion/yrSurface of Nanos in 1 raindrop = 1 football fieldCellulose: Maine’s Niche to Compete in Nanotech

Stone Age ……. Bronze Age ………. Iron Age …….......... Nano Age?

“From the Sawmill to the Nanomill?”

Renewable resource and broad availability No impact of environmental pollution due to biodegradability No toxic by-products after combustion Low machine wear in processing Low density and high strength compared with inorganic fillers

Why cellulose nanofibrils?

Lignocellulose is a Renewable Resource Abundant in Maine

A Wealth of Cellulose Nanofibril (CNF) Architectures are Possible

Applications Range from Nano to Macro Components

bacterial cellulose nanofibrillated cellulose electrospun cellulose cellulose whiskers

Research Theme #1Synthesis of Nano-fibers

from Lignocellulose Sources

Objective: Produce inexpensive lignocellulosic-

based nanofibers with known and consistent properties.

Research Theme #2Functionalization of

Lignocellulose

Objective: Achieve precise control of nanofiber surface and interfacial chemistry to

obtain desired adhesion and dispersion.

Research Theme #3Materials

Characterization

Objective: Characterize cellulose nanofibril-derived

materials and determine structure/property relationships from nano- to macro- scales.

ResearchTheme #4Modeling and Visualization

Objective: Develop multi-scale micro- and nano-

simulation and visualization techniques to predict materials

performance.

Research Theme #5Structural Composites

Objective: Develop pilot-scale processes to utilize nanoscale lignocellulose derived fibers

and CNFs in structural composites.

Research Theme #6Smart Materials and

Devices

Objective: Develop nanoscale devices, structures, and films

for nanoelectronics, tissue engineering, sensing,

actuation, and separation membrane applications.

Nanoscale Imaging & Characterization Laboratory - LASST

Processing Lab for Cellulose Nanocomposites in Structural/

Off Shore Wind Applications - AEWC

Cellulose Nanofiber Production and Functionalization Laboratory - FBRI

Physical Infrastructure for Cellulose Nanotechnology

Because of the hydrophilic nature of cellulose nanofibrils many studies have focused on nanocomposites based on hydrophilic polymer matrices.

There have been very few research studies focusing on CNF in hydrophobic polymers such as PE and PP.

Challenges using CNF in Hydrophobic Polymers

Siro and Plackett, Cellulose 17, 459 (2010)

Why engineering thermoplastics (ETP)? ETP defined as materials which can be used structurally, typically

replacing metals, wood, glass, or ceramics. These high-performance polymers provide innovative solutions that

save weight and reduce costs.

Thermal stability The processing temperature of wood/natural fiber composites are

typically restricted to around 200 C. The earliest experiments to reinforce engineering thermoplastics

exhibited severe discoloration and pronounced pyrolyticdegradation.

Time (min)0 10 20 30 40 50 60 70

Mas

s C

han

ge

(%)

80

85

90

95

100

105

70 um WF50 um MCCNeat Nylon

Mas

s C

han

ge

(%)

Hea

t F

low

En

do

Up

(m

W)

Temperature (°C)0 100 200 300 400 500

0

20

40

60

80

100

60 um W.F50 um MCCDSC of PET-PTTDSC of Nylon 6

MCC decomposes

Wood decomposes

Isothermal TGA @ 250 °C

Methods-Production

ETPsMCC

Lubricant

High Speed Mixer

Melt BlendBrabender

Dry Ground Mixture

Injection Molding

ASTM Test Samples

nanofibrillated cellulose

Comparison of ETPC’s and Commodity Plastics

Mechanical Properties Melting Temperature

Temperature (°C)0 50 100 150 200 250

LDPE

HDPE

PP

PVC

PA

PET-PTT

Wood Degradation

Stiffness Enhancement of MCC-Filled ETPC’s Using Nanoclay

To investigate the reinforcement effects of Nanoclay on the stiffness of20% MCC- filled engineering thermoplastic composites.

To also investigate the effect of Nanoclay on the MCC/Nanoclay/PA 6composites thermal properties.

Thermoplastic Starch The literature is confusing and describes thermoplastic,

destructurized, gelatinized and plasticized starch. Structure is overcome with a combination of plasticizer,

heat and pressure to process the starch. Plasticization is the easiest and cheapest way to put

technological materials in a processable state.

Our ApproachBase Polymer

(Hydrophobic Matrix)Nanoscale Additive

(Filler, Dispersed Phase NC)Carrier System

(Thermoplastic Starch)

Hydrophobic Thermoplastic Compositeswith better dispersion and improved properties

Native Starch

WaterGlycerol

HeatPressure

Thermoplastic Starch (TPS)

NCHydrophilic

NC filled TPS

PolymerHydrophobic

Dispersed NC in Hydrophobic Matrix

NC NC in Hydrophobic Matrix Conventional Composite

Formulations

17

Tensile Properties of the Composites

18

TPS and NCTPS filled PP composites showed comparable or lowertensile strength and modulus compared to control samples.

Group NamePP PP+S PP-TPS 5NCTPS 10NCTPS 15NCTPS

Tens

ile S

tres

s (M

Pa)

18

19

20

21

22

2304 Weeks8 Weeks


Ten

sile

Mo

du

lus

(GP

a)1.0

1.1

1.2

1.3

1.4

04 Week8 Week

Flexural Properties of the Composites

19

TPS and NCTPS filled PP composites showed comparable or lower flexuralstrength and modulus compared to control samples like tensile properties.


Flex

ural

Str

engt

h (M

Pa)

20

22

24

26

28

30

32

3404 Weeks8 Weeks


Fle

xura

l Mo

du

lus

(GP

a)0.8

0.9

1.0

1.1

1.204 Weeks8 Weeks

TGA and DTGA of Composites

20

TGA and DTGA results showed that thermal stability of compositesdecreased marginally with the addition of TPS and NCTPS.

Time(sec)0 1000 2000 3000 4000

Mass C

han

ge (

%)

0

20

40

60

80

100

TPS at 150°CTPS at 190°CTPS at 230°CTPS at 270°CS at 150°CS at 190°CS at 230°CS at 270°

SEM Micrographs of TPS-Based Comp.

The PP matrix was inert, we had no TPS–matrix interactions. From SEMobservation, we can visualize that the fibrils were embedded in TPS. This is due tostrong interactions between the cellulose fibrils and the plasticized starch matrix.

PP-T

PS

PP-5

NC

TPS

PP-1

0NC

TPS

PP-1

5NC

TPS

Challenges for scale-up of producing CNF• Major issue : Processing by classical

method (extrusion, injection) using cellulose micro-nanofibrils in dry state without any chemical modification.

• Scaling-up of homogenization technologies.

• Energy and enzymes consumption.• Reduction of clogging problems.• Controlling cellulose micro-nanofibrils

agglomeration.• Reduction of production costs.

Cellulose and Hydrogen Bonding

(Klemm et al. 1998)

(Wegner 2009)

Aggregation1) Inter and intra-molecular

hydrogen bonds2) van der Waals forces

Challenges• Aqueous nature of cellulose nanofibrils

because of the rich hydroxyl groups on the surface– Agglomeration

– Absorption of atmospheric moisture

– Poor compatibility between polar cellulose nanofibril and apolarpolymer matrix

Different morphologies of nanocellulose by different drying processes

Something like this?

Ideal dry form of cellulose nanofibrils for polymer processing with thermoplastics

Planned Surface Modification

• Methods• Physical

• Plasma

• Chemical• Esterification• Coupling agent treatment

(Selli et al. 2001)

Silane treated wood fibers for reinforcing fillers in thermoplastic composites

Silane 1:N-[3-(trimethoxysilyl)propyl]butylamine

Experimental ConceptSurface of cellulose or wood fiber treated with organic silanes which have two or more domains for fillers and matrices.

Silane 2:(3-Chloropropyl)triethoxysilane+ Cellulose

Experimental Results

Polyethylene

Flexural MOR, psi

control silane1 silane2 control silane1 silane2

Flexural MOE, psi

control silane1 silane2

Tensile strength, psi


Tensile modulus, psi


CTE, 10-2


Water weight percent gain, %

Dispersion of CNF in compositesCellulose nanofibrils were dispersed in the wood-inorganic composite through a sodium silicate solution.

Fracture surface of wood-inorganic composite (5 wt. % of cellulose nanofibrils)

Conclusions• Thermoplastic-CNF composites with enhanced material

properties are possible.• Ongoing challenges for scale-up of utilizing cellulose

nanofibrils in hydrophobic thermoplastics will be the need for obtaining large quantities of CNF in the dry state.

• For the process of producing nano-fibrillated cellulose on the commercial scale, scale up of adequate homogenization technologies is still needed.

• Control of CNF agglomeration and scalable drying technologies is also a big challenge.

• Surface treatment of CNF via physical and/or chemical modification methods will be important to tailor CNF surfaces for application in specific polymer matrices.

Acknowledgements: The authors thank the Army Corp of Engineers ERDC, USDAWood Utilization Research Special Grant, and McIntire Stennis for funding support.

progress on cellulose nanofiber - filled thermoplastic...

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