quality assurance project plan (qapp) - addendum 1 · evaluating solid waste: physical/chemical...
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SDMSDOC.D 46759!
US Army Corpsof Engineers
BALTIMORE DISTRICT October 2000
QUALITY ASSURANCE PROJECT PLAN
ADDENDUM No. 1
OU-4 Focussed Feasibility StudyGREENWOOD CHEMICAL SUPERFUND SITENEWTON, ALBEMARLE COUNTY, VIRGINIA
Prepared by:Hazardous Toxic and Radioactive Waste Branch
U.S. Army Engineer District, Baltimore10 South Howard StreetBaltimore, MD 21201
RR300357
QUALITY ASSURANCE PROJECT PLANTABLE OF CONTENTS
Section Title Page
1.0 INTRODUCTION 1
2.0 PROJECT DESCRIPTION 2
2.1 BACKGROUND INFORMATION 2
2.2 SAMPLING STRATEGY 2
3.0 QUALITY ASSURANCE OBJECTIVES 3
3.1 DATA REQUIREMENTS 3
3.2 DATA QUALITY OBJECTIVES 3
3.3 QUALITY ASSURANCE OBJECTIVES FOR MEASUREMENT 3
4.0 SAMPLE DOCUMENTATION, CUSTODY AND TRANSPORTATION 6
4.1 FIELD DOCUMENTATION 6
4.1.1 Field Notebook 6
4.1.2 Daily Quality Control Reports (DQCR) 7
4.1.3 Sample Identification 9
4.1.4 Sample Labels 9
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QUALITY ASSURANCE PROJECT PLANTABLE OF CONTENTS
(Continued)
Section Title Page
4.2 CHAIN OF CUSTODY 11
4.2.1 Chain of Custody Procedures 11
4.2.2 Chain of Custody Form 11
4.3 SAMPLE TRANSPORTATION 12
4.3.1 Packing and Transportation 12
4.3.2 Sample Packing Instructions 12
5.0 LABORATORY QUALITY ASSURANCE 14
5.1 INCOMING SAMPLES/COOLER RECEIPT FORM 14
5.2 INSTRUMENT PREVENTIVE MAINTENANCE, 15CALIBRATION AND FREQUENCY
5.3 LABORATORY ANALYTICAL METHODS 15
5.4 QUALITY CONTROL PROCEDURES 15
5.5 INTERNAL QUALITY CONTROL CHECKS 16
5.6 CORRECTIVE ACTION 16
5.7 DATA REDUCTION, EVALUATION AND DOCUMENTATION 17
6.0 CHEMICAL DATA DELIVERABLES 18
6.1 ANALYTICAL RESULTS 18
6.2 LABORATORY ANALYTICAL DATA REPORT PACKAGE 18
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QUALITY ASSURANCE PROJECT PLANTABLE OF CONTENTS
(Continued)
Section Title Page
6.3 QUALITY CONTROL SUMMARY REPORT 20
6.4 REPORT OF THIS OU-4 FSS 20
7.0 REFERENCES 21
APPENDIX A: STL Baltimore's MDLs and Reporting Limits
APPENDIX B : Kemron's MDLs and Reporting Limits
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QUALITY ASSURANCE PROJECT PLANTABLE OF CONTENTS
(Continued)
QUALITY ASSURANCE PROJECT PLAN TABLES
Number Title Page
QAPP-1 Sample Summary, Actual, Blanks, Duplicates 3(QA/QC Samples)
QAPP-2 Data Quality Objectives for Precision, Accuracy 4and Method Detection Limits
QAPP-3 Sample Container Requirements 5
QAPP-4 Sample Preservation and Maximum Holding Time 5Requirements
IV
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QUALITY ASSURANCE PROJECT PLANTABLE OF CONTENTS
(Continued)
QUALITY ASSURANCE PROJECT PLAN FIGURES
Number Title Page
QAPP-1 Daily Quality Control Report Form 8
QAPP-2 Sample Labels 10
QAPP-3 Chain of Custody Record 13
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QUALITY ASSURANCE PROJECT PLANADDENDUM No. 1
OU-4 Focussed Feasibility StudyGREENWOOD CHEMICAL SUPERFUND SITENEWTON, ALBEMARLE COUNTY, VIRGINIA
1.0 INTRODUCTION
The U.S. Environmental Protection Agency (EPA), Region III has tasked the U.S. Army Corpsof Engineers (USAGE), under an interagency agreement, to prepare a Focused Feasibility Study(FFS) for Operable Unit (OU) 4 at the Greenwood Chemical Superfund Site. OU-4 wasestablished to address deep soils contamination (defined as soils beyond the practical limit ofexcavation), above the water table. As part of the Focused Feasibility Study, the USAGE andEPA are working together to develop preliminary remediation goals for OU-4. This samplingevent was developed to gather the additional data necessary to develop remedial goals for OU-4.
This Quality Assurance Project Plan Addendum is to be used in conjunction with the GreenwoodChemical (OU-4) Sampling Plan Addendum No. 1.
The purpose of this QAPP Addendum is to describe the following items:
• Chemical Parameters and Analytical Methods required• Background Soil, Contaminated Areas and Target Wells to be sampled• Data Reduction, Evaluation, and Documentation• Data Assessment Procedures• Chemical Data Quality Management Reports
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2.0 PROJECT DESCRIPTION
2.1 BACKGROUND INFORMATION
This sampling event is to collect the additional data necessary to develop preliminaryremediation goals for the unsaturated soils. Background data will be collected and evaluated todevelop a remediation goal for arsenic in soil. Ten background locations have been selected fromupgradient on-site locations, in areas determined to be least likely to have been impacted by thepast site activities.
To develop preliminary remediation goals for the unsaturated soils, each contaminant of concernwill be evaluated for its potential to adversely impact the groundwater. This evaluation will beperformed by determining the concentration at which a contaminant will leach from the soil. Inorder to determine this value, soil samples must be collected and analyzed using SyntheticPrecipitation Leaching Procedure (SPLP) Extraction and standard extraction methods. To applySPLP Extraction in the formulation of remediation goals, samples with high, medium, and lowconcentrations of each contaminant of concern must be extracted and analyzed. Therefore,selection of the nine borings is based on previous data to capture a range of on-site conditions.The following locations are selected COO-2, BNE-1, DHA-2, AOO-601, BNO4, BNO1, BNO7,AOO-2, and AOO-5. Three samples per boring will be collected. See the Field Sampling PlanAddendum.
Groundwater samples will be collected to determine free verses total cyanide levels ingroundwater which will help determine the remediation goal for cyanide.
2.2 SAMPLING STRATEGY
• Soil samples will be collected from ten shallow subsurface soil borings in backgroundlocations, one sample per boring, to determine background levels of arsenic and othermetals.
• Soil samples will be collected from nine soil borings, three samples per boring, for SyntheticPrecipitation Leaching Procedure (SPLP) Extraction and analysis, and for standard extractionand analysis.
• Groundwater samples will be collected from five extraction wells for analysis of total andfree cyanide in groundwater.
Table QAPP-1 summarizes the chemical parameter, field and QA/QC samples for this project.
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Table QAPP-1 Sample Summary, Actual, Blanks, Duplicates (QA7QC Samples)
Sample LocationBackground Soil
Contaminated Area
Contaminated Area
Target Wells aroundContaminated AreaContaminated Area
Contaminated Area
Chemical Parameter23 Metals - Total
23 Metals - Total & SPLP
Cyanide - Total & Free
Cyanide - Total & Free
VOCs - Regular & SPLP
SVOCs- Regular & SPLP
Field Samples10 Soil Samples
54 Soil Samples
54 Soil Samples
1 0 Groundwater Samples
54 Soil Samples
54 Soil Samples
QA/QC Samples1D+1F+1R+1QA(Total) 6CH-2F+2R+2QA &(SPLP) 6CM-2QA(Total) 6CH-2F+2R+2QA &(Free) 6EH2QA(Total 2D+2F+2R+2QA &(Free) 2EH-2QA(Total) 6D+2F+2R+2QA+2T &(SPLP) 6D+2QA+2T(Total) 6EH2F+2R+2QA &(SPLP) 6CH-2QA
Notes: D= Duplicate Sample, F = Field Blank (Source Water), R = Rinsate Blank, T = Trip Blank23 Metals = Aluminum, Antimony, Arsenic, Barium, Beryllium, Cadmium, Calcium,
Chromium, Cobalt, Copper, Iron, Lead, Magnesium, Manganese, Mercury,Nickel, Potassium, Selenium, Silver, Sodium, Thallium, Vanadium and Zinc.
3.0 QUALITY ASSURANCE OBJECTIVES
3.1 DATA REQUIREMENTS
The objective of the project sampling program is to collect additional data of (1) arsenicand other metals in the background and contaminated soils, (2) total and free cyanide in thegroundwater and contaminated soils, and (3) volatile organic and semi-organic compounds in thecontaminated soils .
3.2 DATA QUALITY OBJECTIVES
The data quality objectives (DQOs) presented in the Project Work Management Plan andSampling Plan need to be supported by a certain level of quality which is based on the intended useof the data. The level of analytical quality control for the project laboratory work is DefinitiveData Level as defined by U. S. Environmental Protection Agency (EPA).
The samples collected will be analyzed by methods defined in the EPA Test Methods forEvaluating Solid Waste: Physical/Chemical Methods, SW-846, 3rd edition, including UPDATE III .July 1997.
3.3 QUALITY ASSURANCE OBJECTIVES FOR MEASUREMENT
The primary goal of this QAPP Addendum is to define procedures that will ensure thequality and integrity of samples, accuracy and precision of analyses, and representativeness.
comparability and completeness of results for the field work. The Quality Assurance Objectives forthe measurement of project field work and samples are presented in Table QAPP-2.
Table QAPP-2 Data Quality Objectives for Precision, Accuracy and Method Detection Limits
Analyte
23 Metals
-Total
23 Metals
-SPLP
Cyanide-Total
Cyanide-Free/SPLP
Cyanide-Total
Cyanide-Free/SPLP
VOCs-Regular
VOCs-SPLP
SVOCs-Regular
SVOCs-SPLP
Matrix
Soil
Soil
Soil
Soil
GW
GW
Soil
Soil
Soil
Soil
Prep. / Anal.MethodEPA3050/6010-7000EPA1 3 12/6010-7000EPA9012A/9012A
EPA1312A/W/WsteSTD 4500 CN-I
EPA90 12 A/901 2 A
EPA1312AAV&WsteSTD 4500 CN-I
EPA5035/8260B
EPA1312/8260B
EPA3540/8270C
EPA1312/8270C
Precision (RPD)
35%
35%
40%
45%
40%
45%
40%
45%
45%
50%
Accuracy(%Rec)
70%- 130%
70%- 130%
60% -140%
55% - 145%
60%- 140%
55% -145%
60% -140%
55%- 145%
60% -140%
55%- 145%
MDLand RL
MDL<MCL listed in VACand/or EPA Cleanup GoalsRL=5xMDLMDL<MCL listed in VACand/or EPA Cleanup GoalsRL=10xMDLMDL<MCL listed in VACand/or EPA Cleanup GoalsRL=5xMDLMDL<MCL listed in VACand/or EPA Cleanup GoalsRL=10xMDL
MDL=0.003 mg/L.
RL=0.01 mg/L
MDL=0.003 mg/L.
RL=0.01 mg/L
MDL<MCL listed in VACand/or EPA Cleanup GoalsRL=5xMDLMDL<MCL listed in VACand/or EPA Cleanup GoalsRL=10xMDLMDL<MCL listed in VACand/or EPA Cleanup GoalsRL=5xMDLMDL<MCL listed in VACand/or EPA Cleanup GoalsRL=10xMDL
Notes: MDL = Method Detection Limit. RL = Reporting Limit.VAC= The Virginia Code: 9 VAC 20-60-261 to 263 & 9 VAC 20-110-10 to 130, etc.EPA Region III Cleanup Goals: See 4-11-00 Letter of Toxicologist Nancy Rios Jafolla:Recreational cleanup level for arsenic in soil=37 ppm.Cleanup goal for cyanide in groundwater =103 ug/L=0.103mg/LField and QC Samples including Rinsate and Source Water will be analyzed for 23 Metals,Cyanide, VOCs, and SVOCs - MDLs & RLs are listed in Applendix A, STL Baltimore'sMDLs and RLs for Aqueous & Soil Matrices. MDLs & RLs for 23 Metals, Cyanide,VOCs, and SVOCs QA Samples are listed in Applendix B, Kemron's MDLs and RLs forAqueous & Soil Matrices.
The quantity and types of sample containers required for the project samples and theirrespective analytical parameters are listed below in Table QAPP-3. All sample containers must beprecleaned and will be supplied by the laboratory.
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Table QAPP-3 Sample Container Requirements
Parameter23 Metals - Total and SPLP
Cyanide - Total and SPLP
VOCs- Regular
VOCs -SPLP
SVOCs - Regular and SPLP
Cyanide - Total and SPLP
23 Metals - Total and SPLP
VOCs -Regular and SPLP
SVOCs - Regular and SPLP
Sample MediaSoilSoilSoilSoilSoil
Ground Water/ Rinse Water
Rinse Water/Source Water
Rinse Water/ Source Water
Rinse Water/ Source Water
Container4 oz Clear Wide Mouth Jar4 oz Clear Wide Mouth Jar3 EnCore Samplers4 oz Clear Wide Mouth Jar4 oz Clear Wide Mouth Jar500 mL Nalgene1L Nalgene40 mL VOA2xlL Nalgene
All samples will be delivered to the contract laboratory at the end of each day. Thelaboratory will perform the required analyses within the maximum holding times as shown in TableQAPP-4.
Table QAPP-4 Sample Preservation and Maximum Holding Time Requirements
Parameter23 Metals - Total
23 Metals - SPLP
Cyanide - Total
Cyanide - SPLP
VOCs - Regular
VOCs -SPLP
SVOCs Regular
SVOCs - SPLP
Cyanide - Total
Cyanide- SPLP
23 Metals - Regular &SPLPVOC- Regular &SPLPSVOC Regular &SPLP
MatrixSoilSoilSoilSoilSoilSoilSoilSoil
GW/RinsateGW/RinsateRinsate/FB
Rinsate/FB
Rinsate/FB
PreservationCool to 4°CCool to 4°CCool to 4°C/NaOH
Cool to 4°CCool to 4°CCool to 4°CCool to 4°CCool to 4°CCool to 4°C/NaOHCool to 4°CCool to 4°C&add HNO3, pH<2
Cool to 4°C, 4 drops of HC1
Cool to 4°C
Maximum Hold TimeExt/ Anal: lwk/6 monthsExt/ Anal: lwk/6 monthsExt/Anal: 7/28 daysExt/ Anal: 7/28 daysExt/ Anal: 2/1 4 daysExt/ Anal: 2/1 4 daysExt/Anal: 7/1 4 daysExt/Anal: 7/1 4 daysExt/ Anal: 7/28 daysExt/Anal: 7/28 daysExt/ Anal: 7/28 days
Ext/Anal: 7/28 days
Ext/ Anal: 7/28 days
Notes: Ext = Extraction Anal = Analysis
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4.0 SAMPLE DOCUMENTATION, CUSTODY AND TRANSPORTATION
4.1 FIELD DOCUMENTATION
4.1.1 Field Notebook
A permanently bound field notebook with water resistant pages shall be maintained by thefield team leader to document all pertinent project activities. The notebook will be bound so thatpages can not be torn out and it will have water resistant pages. The following guidelines will befollowed when entering information into the logbook:
a. All entries will be made legibly with indelible, dark blue or black ink.
b. All time will be reported as military time.
c. All pages in the log will be numbered consecutively, signed and dated.
d. No blank pages or sections of pages will be allowed. If a page is not completelyfilled in, a line will be drawn through the blank portion and initialed by the person keepingthe log.
e. Errors will be corrected by drawing a single line through the error and initialing thechange.
f. At the end of each day, the log book will be signed and dated.
The field notebook will contain the following:
a. Record at the start of each day, the date, time and weather.
b. Note the people present throughout the day.
c. Record Personal Protective Equipment (PPE) levels and any changes made duringthe day.
d. Also note field instrument measurements and calibration.
e. Record action taken, project progress and observations.
f. Documentation of sample collection to include sample identification number(including QA/QC samples), description of the sampling method, sampling matrix, samplelocation (including depths), time of collection, sampling depth, results of field screening,sample description, and type of analysis requested.
g. Record the photographs taken.
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h. Any deviation from the sampling plan shall be noted and explained,
i. Record any unusual incidents, problems and accidents.
Sample location should be recorded in the form of a map or sketch, with reference points orsurveyed locations measured from existing permanent structures. Designate sample I.D. (includingQA/QC samples), directly on the figure. The Field Notebook serves as a permanent and traceablerecord of all field activities related to a project and it will become a part of the project files.
4.1.2 Daily Quality Control Report
During field investigation activities Daily Quality Control Reports (DCQR) will becompleted, dated and signed by the sampling technician at the end of each work day. Copies willbe distributed to the field supervisor and project chemist on a daily basis. These DQCRs shallinclude, but not be limited to, the minimum information described and listed below:
a. Weather conditions at the time of sampling.
b. Level of Personal Protective Equipment.
c. Samples collected including reference to applicable QAPP sections.
d. Field instrument measurements and calibrations.
e. Any deviations from the QAPP, problems identified, and corrective actions taken.
If a significant problem occurs during sampling, the DQCR will be provided to the projectchemist within 48 hours with a corrective action report accompanying the DQCR. The DQCR willbe written by the sampling technician and will be cross-checked against the field logbook, forcompleteness at the end of each day. A sample DQCR Form (which may be copied and used) isshown in Figure QAPP-1.
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Figure QAPP-1 Dairy Quality Control Report Form
A_E Daily Quality Control Report
Site NameWeather: Air Temp.
(Circle one)Purpose of Site Visit
Clear°C
CloudyWinds N NE
Rain SnowE SE
FogS SW W NW
Sleet(cst. Mph : )
Level of ProtectionSampling Performed (Circle one) GW Soil Sediment Rock Sludge OtherSample Type: Grab CompositeMethod: Bail Soil Auger Shelby Tube Split Spoon Rock Core Pump OtherField Analysis/Results: pH Temp. °C
Sp. Conductivity umhos/ OtherInstrument Calibration/Repairs: pH Sp. Cond.
Calib. Frequency Other (specify)Problems/Corrective Actions (give details)
Quality Control: QC Samples Y or N? If Y, type? (duplicate split alone)Xerox of Logbook Y or N? Chain of Custody Y or N?Pages attached
SignatureDate
(Day-Month-Year)
4.13 Sample Identification
Samples will be identified and labeled using the scheme related closely to GISKey Formatted
Sample Codes, version 3.1. Each sample will consist of a set of the following alpha-numeric
codes: SITEJD, MATRIX, SAMPJD, SAMP_DATE, SAMP_TIME, SAMP_DEPTH,
ANALYTE, METHOD, etc.
Example:SITEJD
AOO-5MW-23
MW-23
COO-2
COO-2
TripBlank
MATRIX
S (for soil)W (for water)
W (for water)
S (for soil)
S (for soil)
W (for water)
SAMP IDAOO-5-S1
MW-23-W1
MW-23-W1
COO-2-S1
COO-2-S1
MW-23-W1
TrpBk
SAMP_DATE
11/15/00
11/16/00
11/16/00
11/17/00
11/17/00
11/17/00
SAMP TIME
10:30
13:15
14:30
15:00
15:15
16:00
SAMP_DEPTH
31
15 '
15'5 '
15'
ANALYTE
svocTotal CN
Free CN
Metals-Total
Metals-SPLP
VOC
METHOD
EPA8270
EPA90I2
STD4500CN
EPA3050/
6010
EPA1312/
6010
EPA8260
4.1.4 Sample Labels
Field personnel are responsible for applying the unique coded identification and label to allsamples collected during a field investigation. All labeling will be completed in indelible ink andbe securely affixed to the sample container. An example of a sample label is shown in FigureQAPP-2. All sample labels should contain the following information:
a. Project site name.
b. Sample description:
Sample location
Sample type (soil or groundwater)
Chemical analysis parameters (analytes and EPA SW-846 method number)
Sampling date and time
Method of sample preservation
c. Initials of Environmental Health Technician
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Figure QAPP-2 Sample Labels
Severn Trent Laboratories - Baltimore
Company Name:Sample I. D.:
Date Sampled:_Time Sampled :Sampled By:Preserved With:Analysis :
19 Loveton CircleSparks, MD 21153Tel: (410)771-4920FAX: (410)7714407
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4.2 CHAIN OF CUSTODY
4.2.1 Chain of Custody Procedures
The purpose of sample custody procedures is to document the history of sample containersand samples from the time of preparation of sample containers through sample collection,shipment, and analysis.
An essential consideration for the validation of environmental data is demonstrating thatsamples have been obtained from the locations stated and that they have reached the laboratorywithout alteration. Evidence of sample traceability from collection to shipment, to laboratoryreceipt and custody while in the laboratory, until proper disposal, must be documented. A sampleis considered to be in a person's custody if the sample is:
a. In a person's actual possession
b. In view after being in a person's possession
c. Locked up so that no one can tamper with it after having been in physical custody.
d. In a secured area, restricted to authorized personnel.
Chain of custody procedures are initiated in the field following sample collection. Theprocedures consist of:
a. Preparing and attaching a unique sample label to each sample collected.
b. Completing the chain of custody form.
c. Preparing and packaging the samples for shipment.
4.2.2 Chain of Custody Form
Documentation will be accomplished through a Chain of Custody form that records eachsample and the individuals responsible for sample collection, transfer, shipment and receipt by thelaboratory. This form must also contain pertinent information about sampling location, date, andtimes, signature of sampling technician, types and numbers of samples collected and shipped foranalysis in each lot, parameters to be analyzed per sample, sample identification number and theproject name
Samples shall be accompanied by an approved and completed chain of custody form duringeach step of custody, transfer, and shipment. When physical possession of samples is transferred,both the individual relinquishing the samples and the individual receiving them shall sign, date, andrecord the time on the chain of custody form. Figure QAPP-3 is a sample Chain of Custody record.
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4.3 SAMPLE TRANSPORTATION
4.3.1 Packing and Transportation
Samples will be placed in individual containers compatible with the intended analysis,properly preserved, and sealed with a Teflon-lined screw cap prior to shipment to the laboratory.Sample labels, field notebook information, and chain of custody forms are checked to be sure thereare no errors in sample identification and to verify that all the required information has beensupplied. The samples are then packaged to prevent breakage and/or leakage.
As soon as the environmental sampler is ready to transport samples from the field to theContract Laboratory, the laboratory point of contact (POC) shall be notified by telephone of theshipment along with the estimated time of arrival.
No chemical analytical samples shall be held on site for more than 24 hours, unless thesamples are properly preserved during their onsite storage and the environmental sampler obtainsspecific prior approval from the USAGE project chemist. Samples will be shipped to the laboratoryvia overnight carrier.
4.3.2 Sample Packing Instructions
In order to maintain chain of custody protocol and to prevent breakage of the samplecontainers, package the samples as follows:
a. After sample collection, make sure the lids are securely affixed to the properlylabeled sample containers, to prevent loosening and possible leakage of contents.
b. Place approximately a 3-inch layer of inert cushioning material in the bottom of awaterproof metal or equivalent strength plastic ice chest or cooler.
c. Enclose the bottles in clear plastic ZipLoc-type bags, through which labels arevisible, and seal the bag. Place the bottles so that they will remain upright, cushioned andseparated in the cooler during shipment.
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Figure QAPP-3 Chain of Custody Record
U.S. Army Corps of Engineers Chain of Custody Record (ER 1110-1 -263)
Proj. No. Project Name
Sampler : (Signature)
Date/Time Grab orComposite
P™»-mh<
Matrix
Sample Relinquished by: (Sig.)
Sample Relinquished by: (Sig.)
Sample Relinquished by: (Sig.)
Site Code / Sample Number
Date/Time
Date/Time
Date/Time
Custody Seal No:
Num
ber
of
Conta
iner*
Received by: (Sig.)
Received by: (Sig.)
Received by Lab (Sig )
OCDCM<n
2LU
u)U
5 TP
H-G
RO
(8
01 5
M)
Herb
icid
es (
81
51)
Date/Time
Date/Time
Date/Time
Lab Case No.:P
est
icid
es
(8081)
PC
Bs
(EP
A8
08
2) </>
So
£ocrCO
Remarks
Hazards Associated with Sample
Remarks at time of receipt:
ENG Form 5021-R, Oct 90
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d. Put in additional packing material to partially cover sample bottles (more thanhalfway), to ensure that they do not shift during transport.
e. Place sealed plastic bags of ice (double bagged in "ZipLoc" bags) around and ontop of the samples bottles. If chemical ice is used (i.e. blue ice), bagged similarly. NOTE:Use enough ice in order to maintain samples at a temperature of 4°C duringshipment.
f. Seal the appropriate chain of custody form(s) in a ZipLoc-type plastic bag, and tapeit securely to the inside lid of the cooler.
g. Tape the cooler/ice chest drain shut.
h. Close and lock/latch the cooler. Secure the lid by taping. Wrap the cooler completelywith strapping tape at a minimum of two locations. Do not cover any labels.
i. Attach a completed shipping label to the top of the cooler.
j. Put "This Side Up" labels on top of cooler and on all 4 sides. Put "Fragile" labels on atleast two sides.
k. Affix numbered and signed custody seals on front right and back left of cooler. Coverseals with wide, clear tape.
While packing each cooler for shipment, remember not to exceed the weight limit set by theshipper.
5.0 LABORATORY QUALITY ASSURANCE
5.1 INCOMING SAMPLES/COOLER RECEIPT FORM
Upon sample receipt, the laboratory representative responsible for accepting incomingsample shipments must compare the samples received against the list on the chain of custody form.All samples will be examined and information will be recorded on a "Cooler Receipt Form" or
equivalent to verify the condition of the samples upon receipt, and verify that sample holding timeshave not been exceeded.
Laboratory personnel shall measure the surface temperature of the samples to determine ifthe proper temperature was maintained during shipment. Any water samples (i.e. field blanks orrinsate blanks) that were preserved (acidic or alkaline) shall be checked with pH paper upon receipt.If any samples are observed as improperly preserved or damaged during transit, the USACE
chemist shall be notified immediately to decide if resampling will be required: Dr. Scott Chang,Phone (410) 962 6739.
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5.2 INSTRUMENT PREVENTIVE MAINTENANCE, CALIBRATION ANDFREQUENCY
The analytical instrumentation to be used for sample analysis shall have preventivemaintenance performed and calibrations done at a frequency which is specified and in accordancewith the procedures documented in the Laboratory's QA Manual. These shall be consistent with therequirements of the analytical method.
5.3 LABORATORY ANALYTICAL METHODS
The primary project samples will be analyzed by Severn Trent Laboratories (STL), 19Loveton Circle, Sparks, MD 21152 (POC: Mr. John O'Donnell, Tel: 410-771-4920 & FAX: 410-771-4407).
The QA Split samples will be analyzed by Kemron Environmental Services, 109 StarlitePark, Marietta, OH 45750 (POC: Ms. Cindy Arnold, TEL: 740-373-4226 & FAX: 740-373-0260).
The laboratory analytical methods needed for this project are stated in the Table QAPP-2.
23 Metals - Total in soils will be extracted by EPA Method 3050 that is a microwavedigestion. 23 Metal - SPLP in soil will be extracted by EPA Method 1312 that is a syntheticprecitation leaching procedure. The extracts of the 23-Metals samples will be analyzed by EPAMethods 6010 (ICP Method) and 7000 (Atomic Absorption Method). Total Cyanide in soils will beextacted and analyzed by EPA Method 9012A. Free Cyanide in soil will be extracted by EPAMethod 1312 (at pH 7) and analyzed by Method 4500 CN-I of Standard Methods for theExamination of Water and Waste Water (published by American Public Health Association). Thevolatiles in soils will be extracted, purged and trapped by EPA Method 5035. The purgedvolatiles will be analyzed by EPA Method 8260. The Method 8260 is a gas chromatographic/mass spectroscopy (GC/MS) method. The semi- volatiles in soils will be extracted, purged andtrapped by EPA Method 3540. The purged volatiles will be analyzed by EPA Method 8270. EPAMethod 8270 is also a GC/MS method.
5.4 QUALITY CONTROL PROCEDURES
Two types of quality assurance checks will be used to assess the production of analyticaldata of known and documented quality: program quality assurance and analytical method qualitycontrol. The objectives of the lab QA/QC program are to:
a. Verify that all administrative and/or technical procedures are documented.
b. Document that all analytical procedures comply with sound scientific principlesand have been validated.
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c. Monitor the performance of the lab by a systematic inspection program and providefor corrective action as necessary.
d. Verify that all data are properly recorded and archived.
In each data package provided, the lab will document that analytical QC functions havebeen met. Internal quality control procedures for analytical services should comply with thestandard operating procedures of the analytical method and QA/QC plan. Any samples analyzedthat are not in conformance with the QC criteria will be reanalyzed by the lab if the lab procedureswere not in control as assessed by lab control procedures and, if sufficient sample volume isavailable for reanalysis.
Quality Control check samples (method blanks, Matrix Spike/Matrix Spike Duplicate,duplicates, etc.) will be analyzed concurrently with the sample batch to which they are assigned.Any deviations or modification from the published EPA procedures must be documented andclearly noted in the case narrative.
5.5 INTERNAL QUALITY CONTROL CHECKS
Quality control checks are necessary to evaluate performance reliability for each measuredparameter. The lab will perform internal quality control checks on the method and instrumentblanks, surrogate spike samples, matrix spike samples, laboratory duplicates and/or matrix spikeduplicates and laboratory control samples in order to assess the precision, accuracy, andcompleteness of each measurement. At a minimum, these shall be run at rates specified within theindividual methods.
5.6 CORRECTIVE ACTION
The laboratory department supervisors will review the data generated to verify that allquality control samples have been run as specified in the protocol. Recoveries of matrix spikesamples, for consistency with method accuracy and matrix spike duplicate samples, for methodprecision, will be evaluated using the data quality goals discussed in Section 3. Analytical datagenerated with laboratory control samples which fall within the established control limits arejudged to be in control. Data generated with laboratory control samples that do not fall withincontrol limits are considered suspect and the analysis is repeated or the results reported withqualifiers if this is not possible.
Corrective actions are necessary if:
a. QC data are outside the warning or acceptable windows for precision and accuracyestablished for lab control samples.
16
A a J U U o / b
b. Blanks contain contaminants at concentrations above the levels specified in the QCplan for the target compound.
c. There are unusual changes in detection limits.
d. Undesirable trends are detected in matrix spike recoveries or relative percentdifference (RPD) between matrix spike duplicates.
If any nonconformances in analytical methodologies, quality control sample results, etc., areidentified by the analyst, corrective actions will be implemented immediately. Corrective actionsmay include, but will not be limited to:
a. Reanalyzing suspect samples;
b. Evaluating and amending sampling and/or analytical procedures;
c. Accepting data with an acknowledged level of uncertainty;
d. Recalibrating analytical instruments, and/or
e. Discarding the data.
Addtional samples will be collected for laboratory analysis if the 90% completeness ofPARCC parameters is not met.
Performance and systems audits may be conducted to verify the documentation orimplementation of the QA program, assess the effectiveness of the project QAPP, identify anynonconformances, and verify correction of identified deficiencies. The Project Chemist will beresponsible for initiating audits, selecting the audit team, and overseeing audit implementation.
5.7 DATA VALIDATION, EVALUATION AND DOCUMENTATION
Data validation shall be performed in accordance with the Level III procedures of theUSEPA Functional Guidances for Data Review by United States Environmental ProtectionAgency, Environmental Science Center, Office of Analytical Services & Quality Assurance, 701Mapes Road, Fort Meade, Maryland 20755-5350.
Data validation serves 3 main purposes:
a. It qualifies data for further use to ensure data are not inappropriately used;
17
« Pv 0 U U 0 . I-1
b. It serves as a check on a laboratory to ensure they are meeting contractualdeliverables and regulatory requirements;
c. It establishes due diligence and allows errors to be addressed sooner in a program,so that the impact will be less than if the errors were detected later.
For purposes of this investigation, the contract lab shall perform a Definitive Level typedata evaluation of all generated analytical data. The Definitive Level type data evaluation will beperformed consistent with EPA QA/G-4, Guidance for the Data Quality Objectives Process,September 1994.
Severn Trent Laboratories (STL) will present all the data in the data quality package, alongwith QC supporting data. STL will send a copy of this data quality package to United StatesEnvironmental Protection Agency, Environmental Science Center, Office of Analytical Services& Quality Assurance, 701 Mapes Road, Fort Meade, Maryland 20755-5350, POC: Mr. FredForeman (410) 305-2 6 2 9 for data validation and a copy to the USAGE Baltimore District ProjectChemist. The details of this package are explicated in Section 6.2.
6.0 CHEMICAL DATA DELIVERABLES
During the project, the chemical data deliverables to be submitted are listed in Sections 6.1to 6.4.
6.1 ANALYTICAL RESULTS
Chemical analysis results will be formatted in MS Excel spreadsheets/GISKey dbf files ande-mailed to the USAGE Baltimore District Project Chemist within one month of sample receipt.The hard copy of the analytical results with laboratory quality control/internal check data will bedelivered after the electronic package as soon as possible.
6.2 LABORATORY ANALYTICAL DATA REPORT PACKAGE
The laboratory's data shall be submitted as a raw chemical data packge to an independentfirm/validator for data validation and data quality review. This review encompasses anassessment of the internal quality control and method requirements, and enabling a evaluation ofthe data generated. This package of data shall be submitted within 30 days of receiving the lastsample. A complete data set shall also be submitted to the USAGE Baltimore District ProjectChemist, for him to review the submittal for completeness and verification that the DQOs weremet.
18
-. f~ f. r-
r\ j u u
This deliverable shall contain at a minimum all of the items listed below to allow the datavalidator to perform an adequate data evaluation (Data shall be presented in tabular formatwhenever possible):
a. Sample Identification - Prepare a tabular presentation which matches the contractlaboratory sample identifications to the field identification numbers assigned to eachsample. This list shall identify all field splits/duplicates.
b. Cooler Receipt Forms - Provide copies from all sample shipments received at thecontract laboratory.
c. Chain of Custody Record Forms - Provide copies from all sample shipmentsreceived by the contract laboratory.
d. General Organic and Inorganic Reports - For each analytical method run, reportresults of all analytes for each sample (concentration detected or less than the specificquantitation limit). On the sample's data sheets, clearly identify the specific analytical batchthe sample belongs to and the corresponding QC data reported. Report any dilution factors,as well as date of extraction (if applicable) and date of analysis for each sample. Soilsamples shall be reported on a dry-weight basis.
e. Internal Quality Control (QC) Reports - For each analytical batch, report a completeset of QC results. At a minimum, Internal QC samples shall be analyzed at rates specifiedin the methods. The following Internal QC results shall be submitted:
(1) Laboratory Blanks (Method and Instrument Blanks) - Report all analytesfor each laboratory blank analyzed per sample batch.
(2) Surrogate Spike Samples - Report recoveries with all organic methodreports, where applicable (i.e. when the method requires surrogate spikes). Also specify thecontrol limits for surrogate spike results, and the concentration used for the spike.
(3) Matrix Spike Samples - Report recoveries for all organic and inorganicanalyses. Also specify the control limits for matrix spike results, each method, and matrix.General sample results shall be designated as corresponding to a particular matrix spikesample.
(4) Laboratory Duplicates and/or Matrix Spike Duplicate Pairs - Report theRelative Percent Difference (RPD) for each duplicate pair and the analyte/matrix-specificcontrol limits.
(5) Laboratory Control Samples - When run for a method's internal QC, reportthe results of the laboratory control sample (LCS) with the corresponding project sampledata. Also specify the control limits for the LCSs.
19RR30038
(6) Field Duplicates - Field duplicates shall be identified by the USAGEBaltimore District Project Chemist, after analysis but just before completion of the DataReport Package. Report the Relative Percent Difference for all field duplicate pairs.
f. Rinsates, Trip Blanks and Source Water/Field Blanks - To check crosscontamination and carry-over in field sampling and sample shipping.
6.3 QUALITY CONTROL SUMMARY REPORT
This report shall address QA/QC practices employed throughout the project. Include theChemical Quality Assurance Report (CQAR) for the QA split samples and a discussion of all datapoints which may have been influenced or compromised and their impact on the DQOs. TheUSAGE Baltimore District Chemist will complete this report within 30 days of the availability ofresults.
6.4 REPORT OF THIS OU-4 FFS
One report of this OU-4 FFS will be developed to compile the results of laboratoryanalyses and findings. The Baltimore District will write a report for the study that include asummary of findings, tabulations of chemical analyses performed, an assessment of theenvironmental conditions at the site, a discussion of potential risks to the environments, humanhealth and recommendations for any further action.
20
flR300382
7.0 REFERENCES
1. U.S. Environmental Protection Agency, Test Methods for Evaluating Solid Waste:Physical/Chemical Methods, SW-846, Third Edition, including UPDATE III, July, 1997.
2. EPA QA/G-4, Guidance for the Data Quality Objectives Process, September 1994.
3. 40 CFR 136: Definition and Procedures for the Determination of the Method Detection
4. 40 CFR 136.3e: Required Containers, Preservation Techniques, and Holding Times
5. EPA 600/4-79-020, Methods for Chemical Analysis of Water and Wastes, March 1983.
6. USAGE Engineering Regulation 1110-1-263, Chemical Data Quality Management forHazardous Waste Remedial Activities, updated April 1998.
7. USAGE Engineering Manual 200-1-3, Requirements for the Preparation of Sampling andAnalysis Plans, 1 September 1994.
8. USAGE Engineering Manual 200-1-6, Chemical Quality Assurance for HTRW Projects,10 October 1997.
9. USAGE Shell for Analytical Chemistry Requirements, Version 1.0, 2 Nov 1998.
21 R R 3 0 0 3 8 3
APPENDIX A
STL Baltimore's MDLs and Reporting Limits
A R 3 0 0 3 8 1 4
Analyte
INORGANICS
Cyanide, total
Cyanide, weak and dissociable
METALS
Aluminum
Barium
Beryllium
Calcium
Chromium
Cobalt
Copper
Iron
Magnesium
Manganese
Potassium
Sodium
Vanadium
Zinc
Antimony
Arsenic
Cadmium
Lead
Nickel
Selenium
Silver
Thallium
Mercury
ORGANICS
Acetone
Benzene
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
Carbon Disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Method
SW9012A
SM 4500 CN-I
SW3010A/6010B
SW3010A/6010B
SW3010A/6010B
SW3010A/6010B
SW3010A/6010B
SW3010A/6010B
SW3010A/6010BSW3010A/6010B
SW3010A/6010B
SW3010A/6010B
SW3010A/6010B
SW3010A/6010B
SW3010A/6010B
SW3010A/6010B
SW3010A/6010B
SW3010A/6010B
SW3010A/6010B
SW3010A/6010B
SW3010A/6010B
SW3010A/6010B
SW3010A/6010B
SW3020A/7010
SW7470A
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B--25mL
SW5030B/8260B--25mL
SW5030B/8260B--25mL
SW5030B/8260B-25mL
SW5030B/8260B--25mL
SW5030B/8260B--25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B--25mL
Description
Colormetric
Colonmetric
ICP
ICP
ICP
ICP
ICP
ICP
ICP
ICP
ICP
ICP
ICP
ICP
ICP
ICP
ICP - Trace
ICP - Trace
ICP -Trace
ICP -Trace
ICP - Trace
ICP - Trace
ICP - Trace
Furnace AA
Cold Vapor
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
Unit
mg/L
mg/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
MDL
0.0029
-
57.6
12.3
043
556
25
7.5
3.3
428
956
66
174
278
5.6
2 3
3.0
1.7
0.24
1.1
2.4
1.8
3.2
2.4
0.039
1
0.3
0.3
0.3
0.4
0.9
0.3
0.4
0.3
0.3
0.3
0.4
Laboratory RL
0.010
0.010
200
200
5.0
1000
10.0
500
10.0
100
1000
150
1000
1000
50.0
20.0
6.0
100
5.0
3.0
10.0
5.0
10.0
100
020
5
1
1
1
1
5
1
1
1
1
1
1
A R 3 0 0 3 8 5
Dibromochloromethane
1,1-Dichloroethane
1 ,2-Dichloroethane
1,1-Dichloroethene
cis-1 ,2-Dichloroethene
trans-1 ,2-Dichloroethene
1 ,2-Dichloropropane
cis-1 ,3-Dichloropropene
trans-1 ,3-Dichloropropene
Ethylbenzene
2-Hexanone
Methylene chloride
4-Methyl-2-Pentanone
Styrene
1 , 1 ,2 ,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl chloride
m&p-Xylenes
o-Xylene
Acenaphthene
Acenaphthylene
Anthracene
Benzofajanthracene
Benzo[b]fluoranthene
Benzo[k]fluoranthene
Benzo[a]pyrene
Benzo[ghi]perylene
bis(2-chloroethyl) ether
bis(2-chloroethoxy) methane
bis(2-ethylhexyl) phthalate
4-Bromophenyl phenyl ether
Butylbenzylphthalate
Carbazole
4-Chloroaniline
4-Chloro-3-methylphenol
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenyl phenyl ether
Chrysene
Dibenzo[a,h]anthracene
Dibenzofuran
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW5030B/8260B-25mL
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.3
03
0.3
0.4
0.3
03
0.3
03
0.3
03
0.8
0.5
0.8
0.3
0.4
0.5
0.3
0.3
04
0.3
04
0.5
0.3
2
2
2
2
3
3
2
2
2
2
2
3
2
3
8
1
2
1
2
2
3
2
1
1
1
1
1
1
1
1
1
1
5
1
5
1
1
1
1
1
1
1
1
1
1
10
10
10
10
10
10
10
10
10
10
10
10
10
10
20
10
10
10
10
10
10
10
A R 3 0 0 3 8 6
Dhn-butyl phthalate
1 ,2-Dichlorobenzene
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
3,3'-Dichlorobenzidine
2,4-Dichlorophenol
Diethyl phthalate
4,6-Dinrtro-2-methylphenol
2,4-Dimethylphenol
Dimethyl phthalate
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octyl phthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Hexachlorocyclopentadiene
lndeno[1 ,2,3-cd]pyrene
Isophorone
2-Methylnaphthalene
2-Methylphenol
4-Methylphenol
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
N-Nitrosodiphenylamine
N-Nitroso-di-n-propylamine
2,2'-Oxybis(1 -chloropropane)
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1,2,4-Trichlorobenzene
2,4 , 5-Trichlorophenol
2,4,6-Trichlorophenol
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
SW3520C/8270C
GC/MS
GC/MS
GC/MS
GC/VS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
GC/MS
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
4
2
2
2
7
2
3
5
4
3
23
2
2
3
3
2
3
2
2
4
2
2
1
2
2
2
3
2
1
3
3
4
4
4
1
2
2
2
3
2
3
2
10
10
10
10
20
10
10
. 50
10
10
50
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
50
50
50
10
10
50
10
10
10
50
10
10
10
10
50
10
A R 3 0 0 3 8 7
APPENDIX B
Kemron's MDLs and Reporting Limits
R R 3 Q Q 3 8 8
Metal
Aluminum (6010)Antimony (6020)Arsenic (6020)Barium (6010)Beryllium (6010)Cadmium (6010)Calcium (6010)Chromium (6010)Cobalt (6010)Copper(6010)Iron (6010)Lead (6020)Magnesium (6010)Manganese(6010)Mercury (7470)Nickel (6010)Potassium (6010)Selenium (6020)Silver (6010)Sodium (6010)Thallium (6020)Vanadium (6010)Zinc (6010)
Soil mg/Kg Water mg/LKEMRON's MDL KEMRON's RL KEMRON's MDL KEMRON's RL
1.5870.010.010.0180.0060.0391.9360.140.0480.1780.7910.025
3.20.254
0.0019631.8273.1220.010.2090.4890.0050.2710.491
50.20.50.5
0.0250.110
0.250.25
12
0.5250.50.25
2500.20.5250.10.51
0.0495330.0000160.0000520.0016050.0000350.0001730.0452340.0006470.0002
0.0010370.015280.0001250.009914
0.0010.000016
0.0010.1299430.0001260.000450.0544690.000010.0039060.003174
0.10.0010.0010.01
0.00050.0005
0.10.0050.0060.0050.020.0010.5
0.0030.00020.010.5
0.0010.004
0.50.00020.010.01
Metals LCS criteria 80-120Metals MS/MSD criteria 75-125
A R 3 0 Q 3 8 9
Automated Compliance Systems. Inc
LIST DEFINITIONS REPORT (pmtlist)
Oct 24, 2000 12:36 pm
ListJoin LigttypeParameter
Process MatclaasReplid Parmtype
PkeyM Units MDL
CFlac| ExpiredMDL Units RDL
ChainRDL Units
LJ12985 fJ60Header InformationAcetoneBenieneflromobenzeneBromochlororaethaneBromodichlorome thaneBrotnoforaB rotnome t han e2 - Butanonen-Butylbenienesec-Butylbenzenetert - ButylbenzeneCarbon disulfideCarbon tetrachlorideChlorobenieneChlorodibromome thaneChloroethane2 Chloroethyl vinyl etherChloroformChloronthane2 -chlorocoluene4 - Chlorocoluene1 , 2 -Dibrono- 3-chloropropane1,2- DibronoethaneDibromomethane1 , 2 - Dichlorobenzene1 , 3 -Dichlorobenzene1 , 4 - DichlorobenzeneDichlorodif luorome thane1.1- Dichloroethane1, 2-Dichloroethane1 , 1 -Dichloroethenecia-l,2-Dichloroethenetrans- 1, 2 -Dichloroethene1,2- Dichloropropane1.3- Dichloropropane2,2- Dichloropropanecis - 1 , 3 -Dichloropropenetrana-1, 3 -Dichloropropene1 , 1 -DichloropropeneEthylbenaene2 HexanoneHexachlorobutadieneI eopropylbenzenep I Bopropyl tol uene4 -Methyl -2-pentanoneMethylene chlorideNaphthalenen- PropylbenzeneStyrene1,1,1,2 Tetrachloroethane1,1.2, 2-TetrachloroeithAneTetrachloroetheneToluene1,2,3 -Trichlorobenzene1,2,4- Trichlorobenzer, e1,1, 1 -Trichloroethane1,1, 2 -TrichloroethaneTrichloroethene
ALL MATESOVERHEADREG
REG
REGREG
REGREG
REG
REG
REGREG
REG
REG
REG
REG
REG
REG
REG
REG
RBG
REGREG
REGREGREG
REG
REG
REG
REG
REG
REG
REG
REG
REGREG
REG
REGREGREG
REGREG
REGREG
REG
REG
REG
REG
REG
REGREG
REGREGREG
REGREGREG
REC
REG
REG
STD
YN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LK ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/L
N ug/L
N ug/L
N ug/L
N ug/L
N ug/L
N ug/L
N ug/L
1 .84
. 17
. 3
19
.25
.45
.251 . 17
. 37
.33
.36
15
.3
.24
.29
221.07
.19
56
.3
.26
.78
. 15
.19
.37
.32
. 38
25
.18
.33
.27
.14
.21
.12
. 17
.23
. 14
. 16
.212
1 . 1946. 2
. 33
1.09.6
.48
.26.2
.2539.2
.16
.33
. 25
.25
.28
. 17
Y
ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Luq/L
ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/ Lug/L
100
5
5
5
55
10100
55
5
5
5
5
5
10
10
5
10
5
55
55
55
5
10
5
5
5
5
5
5
5
555
55
10
55
5
10
5
10
55
555
5555
5
5
ORG- DILUTION
ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/i.ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L
Page 1
RR300390
Automated Compliance Systems, Inc.
LIST DEFINITIONS REPORT (prntlist)
Oct 24, 2000 12:36 pm
ListJoin LUttypeParameter
Tr ichlorof luorome thane1,2,3 -Trichloropropane1.2,4 Trimethylbenzene1,3, 5 -TrimethylbenzeneVinyl acetateVinyl chlorideo-Xylenem-Xylenep XyleneDibromof luorome thane1, 2-Dichloro«thane-d4Toluene-d84 -Bromof luorobeniene
Matn SI prod Pointer1 8260 122 8260 121 826 TETRACHLOROETHAN 81 826 TETRACHLOROETHAN1 8260-UNPRESERVED
Process Mate! ass PfceyReplid Parratyp*
REGREGREGREGREGREGREGREGREGSURRSURRSURRSURR
Stored Parameter
M Units
N ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN % RecoveryN * RecoveryN % RecoveryN % Recovery
Chain
CFlag Expired ChainMDL MDL Units
.4$ ug/L
.41 ug/L
.23 ug/L
.22 ug/L4.43 ug/L.48 ug/L.16 ug/L.33 ug/L.33 ug/L
» Recovery% Recovery% Recovery% Recovery
DescriptionVolatile List - 8260Volatile List - B260
Tetrachloroe thane
Volatile List - 8260
RDL RDL Units
10 ug/L5 ug/L5 ug/L5 ug/L10 ug/L10 ug/L5 ug/L5 ug/L5 ug/L
* Recovery% Recovery* Recovery1 Recovery
LinXIDLL379LL380
LL117BBLL11786
LL14765
Page 2
RR30035
Automated Compliance Systems, Inc.
LIST DEFINITIONS REPORT (prntlist)
Oct 24, 2000 12 :37 p»
Li4tJoin ListtypeParameter
Procesa MatclassReplid Parmtype
PkeyM Units HDL
CFlag Expired Cha_inHDL Units RDL RDL Units
LJ13750 8JTOHeader InformationPhenolBis <2-Chloroethyl ) ether2 -Chlorophenol1.3 Dichlorobenzene1 , 4 DichlorobenzeneBenzyl alcohol1 , 2 -Dichlorobenzene2-Methylphenol3-Methylphenolbia (2 -Chloroisopropyl) ether*- Methyl phenolN Nitroso-di-n propylamineHexachloroethaneNitrobenzeneI sophorone2-Nitrophenol2,4- DimethylphenolBenzole acidBis (2 -chloro«thoxy) Methane2,4- Dichlorophenol1 , 2 , 4-TrichlorobenzeneNaphthalene4-ChloroantlineHexachlorobutadiene4-Chloro-3-Bethylphenol2 MethylnaphthaleneHexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4,5 -Trichlorophenol2 - Chi oronapht ha 1 ene2 NitroanilineDimethylphthalateAcenaphthylene2 , 6-Dinitrotoluene3 - Nitroanil ineAcenaphtherie2.4 Dlnitrophenol4 -Ni trophenolDibenzofuran2 , 4 DinitrotolueneDiethylphthalate4 -Chlorophenyl -pheriyl etherFluorene4 - Ni troani 1 ine4,6 Dinltro 2 methyl phenolN NitroBodlphenylaminc4 -Bromophenyl - phenyletherHexachlorobenzenePentachlorophenolPhenanthreneAnthraceneDi-N-ButylphthalateFluoranthenef^reneBut ylbenzylphlha late1,3' -DichlorobenzidineBenzo (a) anthraceneChrysene
ALL WATEROVERHEADREGREGREGREGREGREGREGREGREGREGREGREGREGREGREGREGREGREGREGREGREGREGREGREGREGREGREGREGREGREGREGREGREGREGREGREG
REGREGREGREGREGRBGREG
RBGREGREGREGREGREGREGREGREG
REG
REGREG
REGHEG
REG
STDYN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/I,N ug/[.N ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/L
.453.94
.BBS.81.875.928.626. 8741 .54.908.829
1 . 183.891.93
1.153.9211.96
15 .841 .0211 .018.848.809
1 .494.91
.763826.614.949.88
.842
.567
.998
.9831 .264
. 501
.954
7.5721 .001
. 9421 . 085
. 981
.929
.982
.7861 . 564
. 945
.7941 .01.9B
. 775
. 84. 665
.69
.81
794
5 .066.733
1 016
t OWJ-DILUTIOH
55555
555
555555555
25555555
55
5555
25555
255
2525
55
555
2525555
25555
5
55
105•j
Page 1
A R 3 0 0 3 9 2
Automated Compliance Systems, Inc.
LIST DEFINITIONS REPORT (prntliat;
Oct 24, 2000 12:37 pm
LiatJoin Listtypeparameter
bis (2 - Ethylhexyl ) phthalateDi -n-octylphthalateBenzo (b) f luorantheneBenzo (k) f luorantheneBenzo(a)pyreneIndeno(l,2, 3-cd)pyreneDibenzo (a, h) AnthraceneBenzo(g,h, 1) Perylene2-FluorophenolPhenol -d5Nitrobenxene-dr,2 - Fluorobiphenyl2,4, 6-Tribroraophenolp-Terphenyl dl 4
Matn SI prod pointer1 625 HUNT A 101 8270 101 JRH TEST 102 8270 10
Process M«tclaa» Pk.ey CFlag ExpiredRep lid Parwitype
REGREGREGREGREGREGREGREGSURRSURRSURRSURRSURRSURH
Stored Parameter
M Units MDL HDL Units
N ug/L 1.322N ug/L 1.408N ug/L .876N ug/L .959N ug/L .74N ug/L .912N ug/L .972N ug/L 2 .24N RecoveryN RecoveryN RecoveryN RecoveryN RecoveryN Recovery
Chain Description625 HTSemivolatile OrganicsSemi Volatile CompoundsSemivolatile Organics
ChainRDL RDL units
5555s555
LinKIDLL121B3LL8652LL950BLL8653
Page 2
A R 3 0 0 3 9 3
Autonated Compliance System*, Inc
LIST DEFINITIONS REPORT (prntlist)
Oct 24, 2000 12:37 pra
ListJOln Listtype Process Matelass PXey CFlag Expired ChainParameter Replid Parwtype M Units HDL HDL Units RDL RDL Units
LJ12748 CM ALL IUTBR STD Y ISOHB- PILOT! OBCyanide " REG N mg/L .0025 tng/L .01 mg/L
Matn 81 prod Pointer stored Parameter Chain Description LinfcID1 CN 13 CYANIDE CYANIDE LL55372 CN U CYANIDE CYANIDE LLS5824 CV 13 CYANIDE CYANIDE LL6432
Page 1
A R 3 0 0 3 9 I *
APPENDIX A
STL Baltimore's MDLs and Reporting Limits
flR300395
AnalyteINORGANICS
Cyanide, totalCyanide, weak and dissociable
METALSAluminumBariumBerylliumCalciumChromiumCobaltCopperIronMagnesiumManganesePotassiumSodiumVanadiumZinc
AntimonyArsenicCadmiumLeadNickelSeleniumSilver
Thallium
Mercury
ORGANICSAcetoneBenzeneBromodichloromethaneBromoformBromomethane2-ButanoneCarbon DisulfideCarbon tetrachlorideChlorobenzeneChloroethaneChloroformChloromethaneDibromochloromethane1.1-Dichloroethane1.2-Dichloroethane1.1-Dichloroethenecis-1.2-Dichloroethenetrans-1 ,2-Dichloroethene1,2-Dichloropropanecis-1 ,3-Dichloropropenetrans-1 ,3-DichloropropeneEthylbenzene2-HexanoneMethylene chloride4-Methyl-2-Pentanone
Method
SW9012ASM 4500 CN-I
SW3010A/6010BSW3010A/6010BSW3010A/6010BSW3010A/6010BSW3010A/6010BSW3010A/6010BSW3010A/6010BSW3010A/6010BSW3010A/6010BSW3010A/6010BSW3010A/6010BSW3010A/6010BSW3010A/6010BSW3010A/6010B
SW3010A/6010BSW3010A/6010BSW3010A/6010BSW3010A/6010BSW3010A/6010BSW3010A/6010BSW3010A/6010B
SW3020A/7010
SW7470A
SW5030B/8260B--25mLSW5030B/8260B-25mLSW5030B/8260B-25mLSW5030B/8260B~25ml_SW5030B/8260B-25mLSW5030B/8260B-25mLSW5030B/8260B-25mLSW5030B/8260B-25mLSW5030B/8260B-25mLSW5030B/8260B-25mLSW5030B/8260B--25mLSW5030B/8260B--25mLSW5030B/8260B-25mLSW5030B/8260B-25mLSW5030B/8260B--25mLSW5030B/8260B-25mLSW5030B/8260B-25mLSW5030B/8260B-25mLSW5030B/8260B--25mLSW5030B/8260B-25mLSW5030B/8260B-25mLSW5030B/8260B--25mLSW5030B/8260B-25mLSW5030B/8260B-25mLSW5030B/8260B-25mL
Description
ColormetricColormetric
ICPICPICPICPICPICPICPICPICPICPICPICPICPICP
ICP - TraceICP - TraceICP - TraceICP - TraceICP - TraceICP - TraceICP - Trace
Furnace AA
Cold Vapor
GC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MS
Unit
mg/Lmg/L
ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L
ug/Lug/Lug/Lug/Lug/Lug/Lug/L
ug/L
ug/L
ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L
MDL
00029-
57.612.30435562.57.533
42 89566.61742785.62.3
3.01.7
0.241.12 41.83 2
2.4
0.039
10.30.30.30.40.90.3040.30 30.30 40.30.30.30.40.30.30.30.30.30.30.80.50.8
Laboratory RL
00100010
2002005.0
1000100500100100
100015.01000100050.0200
6.01005.03 01005 010 0
100
0.20
51111511111111
| 11111111515
flR300396
Styrene1 , 1 ,2.2-TetrachloroethaneTetrachloroetheneToluene1,1.1-Trichloroethane1,1 ,2-TrichloroethaneTrichloroetheneVinyl chloridem&p-Xyleneso-Xylene
AcenaphtheneAcenaphthyleneAnthraceneBenzo[a]anthraceneBenzo[b]fluorantheneBenzo[k]fluorantheneBenzo[a]pyreneBenzo[ghi]perylenebis(2-chloroethyl) etherbis(2-chloroethoxy) methanebis(2-ethylhexyl) phthalate4-Bromophenyl phenyl etherButylbenzylphthalateCarbazole4-Chloroaniline4-Chloro-3-methylphenol2-Chloronaphthalene2-Chlorophenol4-Chlorophenyl phenyl etherChryseneDibenzo[a,h]anthraceneDibenzofuranDi-n-butyl phthalate1 .2-Dichlorobenzene1 ,3-Dichlorobenzene1,4-Dichlorobenzene3,3'-Dichlorobenzidine2,4-DichlorophenolDiethyl phthalate4,6-Dmitro-2-methylphenol2,4-DimethylphenolDimethyl phthalate2,4-Dinitrophenol2,4-Dinitrotoluene2.6-DinitrotolueneDi-n-octyl phthalateFluorantheneFluoreneHexachlorobenzeneHexachlorobutadieneHexachloroethaneHexachlorocyclopentadienelndeno[1 ,2,3-cd]pyreneIsophorone2-Methylnaphthalene2-Methylphenol4-MethylphenolNaphthalene2-Nitroaniline
SW5030B/8260B--25mLSW5030B/8260B--25mLSW5030B/8260B-25mLSW5030B/8260B--25mLSW5030B/8260B--25mLSW5030B/8260B-25mLSW5030B/8260B-25mLSW5030B/8260B-25mLSW5030B/8260B-25mLSW5030B/8260B--25mL
SW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270C
GC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MS
GC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MS
ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L
ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L
0.30.40.50.30.30.40.30.40.50.3
22223322222323812122324222723543
232233232242212223
1111111111
10101010101010101010101010102010101010101010101010102010105010105010101010101010101010101010101050
A R 3 0 0 3 9 7
3-Nitroaniline4-NitroanilineNitrobenzene2-Nitrophenol4-NitrophenolN-NitrosodiphenylamineN-Nitroso-di-n-propylamine2,2'-Oxybis(1 -chloropropane)PentachlorophenolPhenanthrenePhenolPyrene1 ,2,4-Trichlorobenzene2.4,5-Tnchlorophenol2,4,6-Tnchlorophenol
SW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270CSW3520C/8270C
GC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MSGC/MS
ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L
213344412223232
505010105010101050101010105010
APPENDIX B
Kemron's MDLs and Reporting Limits
A R 3 0 0 3 3 8
A R 3 0 P 3 9 9
Automated Compliance Systems, In".
LIST DEFINITIONS REPORT i prr.tlia t •
Oct 24, 2300 11:54 am
ListiToin Lia t tyParameter
L±H°.§ 92 a 2£0Header Inf nonar i onAcetcneBenzeneBromobcnzeneBromoctiloromethn.-.eB r ociod i c h 1 o rome r :i a r. eDrorrcf orm,Bromorr.ethane2 Butanonen Butylbenzenesec Butylbenzenetert Bu*_ylbenzeneCdrbcn d i su l t ideCa rbon r.c t rachl c; r i JeOhlorcibenzeneC h 1 o r o d i b r c T>om o *- r. a n P1'hloroethane2 "h \ crcethyl v i :.y I'Jhlorof ormThilor omethane2 Chlorotolucne» Chlorctoluene1 , 2 D ib romo- 3 -Ch 1 oropr-'- pa1 , 2 Dibrcmoethan*--D i b r -jriome t hane1, 2 Dichlorobenzer.el, .J - Dichlorobenzer.n1, -4 Dichlorobenz^nen i r'". I orodi f luori:>me t:..y IT?l , 1 - D ie :h i oroeLhar.el , 2 - D i c h l o r o e t h ^ n el, l - Dichloroether:ecis I , 7. Dichlorocthor.^trar.s 1. 2 - D ich lo rop r hr -n1, 2 :;ichlnropropane1 , .1 Dichloropruuanr2, 2 Dichloropropar.ec^s - l. '•> Dichlor v-prcprnetrans 1,3 Dichloropropenel, 1 Dict i loropron^neKtihyi benzene2 -Hexanonel lexachlorobi i tad i 'T.PI scpropylbenzen11
p Isopropyltoluene4 Met hyl - 2 - per.ta:r_;ii(_'M e L h y l e n e chlor : dt?N'aphthal ener; [' r c u y 1 b e n z e n eSt.yr ent;1 , l , 1 , 2 -TetrachloroeLhane1 . 1 , 2 , 2 - Tetrachl oruerhar.eTetrachl or oether.eToluene1.2.3 -Trichlorcbenzer.e1.2.4 Trichlorcbenzer.e1 , 1 , 1 Tr ichlorcethciiie1 , 1 , 2 Ti ichloroe ̂ hanf;Tri chloroethene
Process MatclastReplid Parmtype
ALL SOLIDOVERHEADREG
REG
REG
REGREG
REG
REG
REG
REG
REG
REGREG
REG
REG
REG
REG
e ! REGREGREG
REG
REG
pa:ie REGREGREG
REG
REG
REG
REG
PEG
REG
RF.G
REG
e REGREG
REG
REG
REG
ne REGREGREG
REGREGREG
REG
REGREG
REGREG
REG
ne REGne REG
REGREGREGREGREGREG
REG
3
M
V
M
N
N
NN"N'
N
NN
N
N
N
N
N
N
N
NNN'
N
N
N
NN'
1C
1CN-
N
Nt;1C.',"
NNNN
M
N
N
NNN
K
N'
MNK
1C
N
N
N
NN'
NNN*
PxeyUn : t a
STD
ug/<gug/kgug/kgug/kgug/kgug/kguq/kq-M/kgug/kgug/kgug/kgug/kguq/kg..g/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kg,g/kg--I/kgug/x.g•jg/kgig/kgug/kgug/kgug/kgug/kgug/kg,:g/kgug/kg•:g/*gun/krjug/kgug/kgUCT/ kg
ug/kgug/kg•jg/.<gug/kgug/kgug/kgug/kgug/kguq/kgug/kg..g/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kg
VDL
3 . 903. 433. 244. 6R7.49
. 246. 95
3 .622.27.29
.305
.684
. 571
. 24
.21
1.4212 q 7486
62
. 41.247.752.705.624. 2212327
76. 495
584
9
.431
.419
.506
542593. 47
.561
.56".. 2 6
4 . 197. 34. 3
. 2443 . 957
61
.562. 23
.232. 2 9
.467
.439
.499487
.466
.721
.593
.624
CFlag Ex]MDL Units
V
ug/kgug/kgug/kgug/kgug/ <guq/kqug/kaug/kgug/kgug/kgug/kcuq/kaug/kgug/kcug/kcug/kgug/kgug/kgug/kqug/kgug/kgug/kgug/kgug/kguq/kgug/kgug/kgug/kgug/kgug/kgua/'kgug/kgug/kgug/kgug/kguq/kqug/kguq/kgug/kgug/kguq/kgug/kguq/kquq/kgug/kgug ! kgug/kgug/kquq / kg
ug/kgug/kgug/kgug/kgug/kgug/kgug/kquq/kcuq/kq
DiredRDL
100C
c;
C
c;
5
1 0IOC
55
5
5
5
b
1?
10
5105
5'-,5-.,5
5
b1 •"5nc
5
57,
D
5
5
5r,5
10
5
510
5
1 0555
55
5
5
5
5
55
Cha i nR2I, Units
ORG- DILUTION DRY H7
ug/kgug/kgug/kgug/kgug / kgug/kgug / kgug/kgug/kgug/kqug/kqug/kgug/kgug/kgug/kgug/<gug/kgug/kgug/kgug/kgug / kgug/kq•ug/kc:ug/kcug/kgug/kq•ug/kgug/kcug/kr:ug/kgug/kcug/kg•ug/kgug/kguq/kqug/kqug/kgug/kgug/kqug/kgug/kgug ./kgug/kqug/kquu/'kquu / kgug/kgug/kqug/kgug/kgug/kgug/kgug/kqug/kgug/kgug/kgug/kgug/kg
Page l
Automated Compliance Systems . [~o
LIST DEFINITIONS REPORT : prntl l :;r. i
Oct 24, 2000
ListJoin I.isttype
Parameter
Tr ichlcrof luoi';met::ci::e1,2,3- Trichloropr op.nr.e1,2.4- Trimethylbenzcr:!'1 , 3 , :; TriT.ethy 1 ripH7er:eVinvl acetateVinvl chlorideo - Xvl ene
in Xy'.enep XyleneD 1 broino f 1 uororre - na ne3,2 Dichl oroeth.ine --)•••Toluene dB4 Hrornt 1 uorob^r /•:•::*<
Xatn 31 pi^-J Pointer10 8260 12^ 8260 128 R 2 6 0 12
Process MatolasReplid Parir.type
REGREGREGREGREGREGREGREGREGSURRSURRSURRSURR
Stored Parameter
aK
N
N
N
N
N
NN't;t-iN
NN
N
Ch
PkeyUnits
ug/kg
ug/kguq/kg
ug/kgug/kgug/kgug/kquq/kcj
ug/kg% Recovery% Recovery% Recovery% Recovery
am
Vo
Vo
Vo
MDL
1 . 43
.804
. 223
4 ,C7S
1 06
226
. 46
. 46
rescriptla t i 1 e Llatile Llatile I.
CFlag SxfMDL Units
ug/kgjn / ka:,c/kg
uq/'kgi.io / Kgua/kque.'kqiw/kyug/kg
% Reooverv% xer'overv* Recovery^ Recovery
ion
l.st S26C1st =2601st =260
)ired ChainRDI, RD^ Units
10 ug/kg
5 ug/Xg5 ug/kg
~ ug/kg10 ug/kg10 ug/kg5 ug/kg5 ug/kg5 ug/kg
% Recoveryt Recovery% Reccvery* Recovery
Link IDI.L362
I.LJbl:,Lfl404
Page
O c t 2 4 . 2 0 0 0
LiatJoin Li at type
Parameter
LJ12744 8270Header InformationPhenolBis (2 -Chloroethyl } pfher2 -Chlorcohenoi1 , 3 Pi chlorobenzcne1 , 4 Dichlorobenzeiie
Benzyl alcohol1 , 2 Dichloroben^nc2 Methylphenol"> Methyl phenolbis ;2 -Chloroisopropyl i o-her4 MothylrihenolN -Ni trosodipropyl am_:;i.'Hexacrhl o roe thane
NitrobenzeneIsophcrone2 -Nitre-phenol2 , 1 - Dimethyipheri'; 1Den zoic acidBis ( 2 -ChloroeLhoxy } Ke thane2,4- Dichloropherol
":,2,4 TnchlorofconzeneNaphthalene<\ Cr. 1 nroan i 1 inoHexachlcrobutad i er.o
•1 Chlcro- 3 - methylp:;er:c:l2 -Methylnaphthal;.'rieHexachlcrocyclopcr.t -irlier.es ,-1 ,6 Trichlorophp:-'-,:2 , -1 , 5 Tricr.loropher. . 12 - Chi crcnaphthd It-.-.u2 - Ni troaiiil ine£ i T.C t hy 1 ph t ha 1 .} T- PAcenaphthylene2 , 6 Dinitrotolurnp3 - N 1 1 roam 1 ineAcpriaphr here2,4 Dir.itrophet;^:4 Hi :.iophenolciberizofuran2.4 r> i n 1 1. r o t o 1 u e n oci utr.ylph thai ate4 Chlorophenyl - pher.yi etherFluor one4 Ni troanil ine4 , 6 -Dinit.ro 2 methyl p:i«no:N Nin OGOdiph.cr.y \ an> IT.P4 - Bronophenyl - pheny . o'.rierHexachlorobenzenePentachl orophenolrhenanthreneAnthraceneDi N ButylphthalateFlucranthenePyreneButyltenzylphth.il ate3, i1 Di rhlorobenz iciir.eRenzt3 (a) anthracene"hrysene
Process MatclasRep 1 id Pa rm type
All, SOL 1 3OVERHEADREG
REG
REGREG
REG
REGREG
REG
REG
REG
REG
REGREG
REGREG
PEG
REG
REG
REG
REG
!* F3?.EG
RES
Ri3
KE3^ F3
REG
RE3
REG-
REG
REG
R~G
R=OREG
REG
REG
REG
REG
REGR KC-REGREGREG
REGREG
REG
REG
REGREG
REG
REGREG
REGREGREGREG
REG
REG
sK
Y
N
NNfj
N
K
K
NN
N
N
N
NN
NMN
MN"
M
N
N>J
N
N
N
UN
N
NN
NX
NN
N
N
KNN
NNK.\
NN
NNH\
N
NNNNNN
PkeyUnits
STD
-a /kgug/kq•.Hj/kq•jq/XguQ/'<guq/kglag/kcug/kgug/kqug/kgug/kqug/kcug/kgv:q/kcug/kgug/kq
uq/ Kgug/kgug/kgnq/kgug/kg
uq/kgug/kgug/kgug/kgu-J/kgug/kgug/kqug/kgug/kg.:g/kguq/kgug/kquq/kgug/kgug/kgug/kgug/kguq/kqi.,j/ky
-9 /kgug/kqug / kg
uq/kquc:/Vg
V.<1/ kgug/kg
ug / kgug/kgug/ kg\ic/ ̂ gug/kqug/ky
x^g/kgug/kgug/kaug/kgug/kq
M
17 .".3 .17 .17 .
13.25.IS .
26.41n .21 .
131 5 .
1 327 .
2126 .
239.17 .
27.
20.
23 .
60.21.
4S.24 .
21 .25.29.21 .
34 .2 2
10.
29.
60.26 .
130.51 .26 .:, 2 .21 .20.30.33 .
Ill .24 .17 .
31.2 '3 .
1.13D .4D .33 .33 .32 .
195 .37 .bl .
DL
21
SSS3f,t
6b
35C6
5 9
.3B7681209122 .'
. 4C, j
1261- j6205b /
C9799873•'.20644
3845
23
H8157
'n51
294 9
39
12334767
02
6827
75
48
C932
34
2147
: i6413
CFlag ExpiMDL Unitis
Y
ug/kguq/kqug/kquo / kaug/kgua/kqug/kgug/kgug/kgug/kq
ug/xgug/kgug/kguq/kgug/kgL.q/kgug/kgug/kgug/kgug/kguq/knuq/ka
ug/kqug/kgug/kguq/kqug/kgug/kgug/kgug/kgug/kgug/kqug/kgug/kgug/kgug/kgug/kg..g.'kqug/kgug/kg
uq/kgug/kqug/kgug/ kgug/kgun / kaug/kguc / kgug/kgug/kgug/kguq/kqug/kg
uq/kgug/kgug/kgug / kqug/kg
redRDL
165
165165163165165165165165165165165165
16516b
165155= 25
1S5155
16515515 i
165
155
155
165
1 = 5
R251 1 5
62516:
16E
165
825
1G5
82582516b16 5
165165'.65825825
165165
165325
165
165
165165165
165330165165
Chair.RE I, Unit: 3
DSG-D:L-JT:CN DRY WT
uq/kgug/kg•ug/kgud/kgug/ko^g / kguq/Kg
ug/kgug/kgug/kgug/ kquc/kgua/kgua/kgug/kyug/kquc/kqug/kgua/ kgug/kqug/kqug/kq
-:g/kq
ug/'-qug/kquq/kgug/kgug/<gug/<gug / ̂ auq/kcug/kc
ug/kgug/kgug/kgug/kgug/kqug/kgug/kgug/kgug/kg•ug/kgug/kgug/kgug/kgug/kgug/kgug/knug/kgug/kgug/kgug/kg
ug/kgug/kgug/kgug/kgug/kgug/kg
Page
- p rj r»A ft 0 U G 2
Automated Compliance Systems, Inc
LIST DEFINITIONS REPORT prntlint
Oct 24, 2000 1 1 - 5 4 aT.
ListJoin ListtypeParameter
bis (2 Ethylhexyl :phth.ilate
V'~ n octylphtha 1 ateBenzolb; f luorar.* hr-r.---
Benzc (k) flue-rant hen>-Eenzo iu) pyrene
Indeno : 1 , 2 , 3 - cd pyr erieDibcnzo !a , hi Ant r.r.iccr.;.
Benzc (g, h, i'i Pery.er.e2 F'. uoroohenolPhenol -d5Ki trcbe:izene-dc.2 - Fluorobipheriy 12,4,6- Tribromop.'i^ no-p- Terphenyl - dl-1
Matn SI pro.! PointerID 8270 1 •}~> 8270 in3 8270 • ',:•
Process MatclassReplid Parn-f/pe M
REGREG
REG
REGREGREGRFCREGSURRSURRS'JRRSURRSURRSURR
Stored Parameter
NNNNNNKr;N
N
NN
N
N
FkeyUnits
ug/kaug/kguq/kg
ug/kgug/kg
ug/kgug/kgug/kg% Rec> Rec
CFIag Expired
352-1
ib
45
3344
KDL yDL Units
. 2 "7 ug / rig
.76 ug- 1 1 UC!
. 3 3 uc
.23 ug96 u<:
44.9 ua•; •;
overyovery
% Recovery% Hec% KecV Rec
Chair.
overyoveryovery
DesSemi vSemiv
.96 uc'.%%%%i1
-riptior.ol at i lrolatileolatile
/kg/.<g/ kg/••-.g/Kq
/kg/kgKecovervRecoveryRecoveryRecoveryRecoveryRecovery
ChalRDL RDL
165165165165165165165165
ug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kg% Recc% Reco4 Recc
r.L'n i t s
veryveryvery
% Recovery
1 Recovery* Reco
LinkID
very
Oroar.ica LL8656OrganicsOrnanics
LLE-154LL8655
Page 2
R 3 0 0
Automated Corr.pl iancc Systems, Ir.c.
LI.ST D E F I N I T I O N S REPORT Ipr.-.c l ist i
CCC 24 , 200: 11:54 am
LlstJoin Li3tCyT)e f.r_°SS-25 Matclaaa Pkey CFlag ExpiredParameter Replid Parrr.type M Unit:s KDI, MDL "Jnita
CN ALL SOLID STD_ _____ _ __ ____ _Cyanide REG N ng/Xg .125 mq/kg
Store"! Paranpt:C'r Chain Descriptior._ ~CYANID2
CYANIDECYANIDE
Page 1
Automated CoTpl lance Systems, ".nc
LIST DHFINITTCN'S PEPORT :pmtllst'.
O o t 2 4 , 2 C O D 1 2 : 3 6 p m
ListJoin ListtypeParameter
LJ12985 8260Header InformationAcetoneDer.i'.rr.earonnbenzeneBromochlorome thaneBrciT.odichlorome thaneBlLUi.uf oim
Brcromethane2 Putanor.en Butylbenzenesec Butylbenzer.etert -Sutylber.zeneCarbon disulfirieCarton tetrachl~i i deChlcrobenzoneChlorod ibromone* har.rCM loroet hane2 Chloi uet hyl vinyl ot.hnrChloroformChloromethane2 Cniorotoluene4 Chlorotoiuene.,2 Dibromo 3 chloropropane1." - L ibromoethar.erv. brcmome thane1 . 2 - Cichlorobenzene1. 3 L" ichl orobenz ene1 , -1 DichlorobenzeneCi ohl 0 rod if iuoromethar.r1 , 1 Ijifhloroethar.e1,2 Dichloroethrti.e1,1 LicLloroetheuecis 1 , 2 - Dichloroer.nenetrar.s 1,2 Dich: oror-r hr;nr-1,? Dichloropropane1 , 1 - Di rr.ioroprnpan"2,2 Pi chl oroprcparie- - i s - 1,3 u* chlop- pr-:p>"ne
trans 1 , 3 Dachl' u oprcipene1,- Dichloroprcper.eR t liy 1 bcr. z cp.o
2 HexanoneHexachlorobutadiencI sop ropyl benzenep laopropyl toluene•1 -Methyl 2 pentanone^ethylene chlcr::leNaphthalenen PrcpylbenzeneStyi ene1 , 1 , 1 , 2 Tetrachlcroethane1, 1 , 2 , 2 Tetrach 1 c-roethaneTetraohloroether.cToluene1 , 2 , 3 Trichlorotenzene1,2,4 Trichlorobenzcne1,1,1 Trichloroet hane1,1,2 Trichlorort haneTrichloroethene
Process MatclassReplid Parmtype
ALL WATEROVERHEADREGRSGREGREGREGREG
REG
REG
REGREG
REG
REG
REG
REG
REGREG
REGREG
REG
REG
REGREG
REG
REG
REGREGREGREG
REGREG
RF:GRE3
REGREG
REO
SEGHEGREG
HEGRET;REGREGREGREG
REGREGREGREGREG
REGREG
REG
REGREGREG
RSGREG
REG
PkeyM 'Jr.ir.3
STDYN' no /I,
N ug/-N 'jq/LN ,;4/:.N nq/L
N ug/L
N ug/L
N ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/1.^: ug/t.N" uq/LN Uq/L
N v.g/l.N uq/L
N ug/LM ug/LN ug/LN ug/LN ua/LN uq/L
N uq/LN uq/L
N ug/LN ug/LN ug/LN ug/LM ug/LV ug/LN uq/L
N v:q/L
M uy/LN .:-j/L
N ug/L
N ug/LN '̂ :l/L
N ug/LN ug/LN ug/LN ug/LN uq/LN ug/LN' ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN ug/LN' ug/LN aq/LN ,:g/L
MDL
1 B4. n
"i. 19. £. ̂
. 4 =
2 5
, j ̂
. 3 3
. j 6
. 15
- 3. 24
. 29
.221 . .">?
19C £
. j. 25. 71
. 15
. IS
. 37i 2
. ;e
. ?-•
. i e
. 33
.21- 14
.21
. 12
. 17
.23
. 14
. 16
212
1 1 3452
. 33
1.09. ~
. 48
.21=
. 2
2539
.2
. 16
. 33
.25
.25
. 28
. 17
CFlag ExpiredKDL Unit 3 RDL
Y
uq/L
ug/Lug/Luq/L
ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lua/Lug/Lug/Lug/Luq/L
ug/Lug/Lug/Luo / L
uq/L
uq/L
ug/Lug/Lny/Luq / : ,ug/Lug/Lug/Iug/L_g/Luq/L
uq/Lug/L
ug/Lug/L•ig/:
ug/Lug/Lug/Lug/Luq/L
ug/Lug/Lug/Lug/Lug/L
ug/Lug/Lug/Luq/Luq/L
ug/1.ug/L
ug/L
1005q
555
1CIOC
5"i5555510105
10
5
5
5
5C
5
^5
'. Zmj
'-
'̂:•
5
5!;
C
C,
5
5
^i :5r.
3
i:5
1 „
r-
5
~̂
5̂
5c;
5
'
ChainRDL Units
ORG-DILUTION
ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Luc/Lur: / L
ug/Lug/Luq/L
ua/L
ug/Lug/Lug/Lug/Lug/Lug/Luq / L
ug/Luq / L
ua/L
ua/L
ug/L\:n / L
U!j; -.
ug/LUC/L
ug/Lug/Luq/ Lug/Lug/Lug/Lug/Lug/Lug/i.ug/Lug/Lug/Luq/L
ug/Lug/Lug/Lug/Lug/LUrj/L
uq/L
ug / Lug/Lug/Lug/Lug/Lug/Lug/L
Page
•- — o r- •'•'- K • i , 'r\ i \ O U ;. 5
Automated Compliance Systerrs, I n c .
LI3T D E F I N I T I O N S REPGRT ip r r . t l l s t )
Oct 24 , 12:36 prr
ListJoin LiattypeParameter
Process^ Matclass Pkey CF_iag_Expired ChainReplid Parmtype M Units MDL MCL Units RDL K'JL Units
Tr ichlorof luorcTechan1 . 2 . 3 -Trichloropropar.e1 . 2 . 4 -TriT.ethylhenzor.1 , "3 , 7i -Trircethylh»r-.7 t>-:Vinyl acetateV i n y i chlorideo • Xylene•n -Xylcnep - X y l e n eDihroToC luoromet ha HP1 , 2 - Dirhloroethane - _KTclueiie -dB4 - BroT.otluorobenzer.c
Mdtr. SI prnrl
e REGe REG(• REGe REG
REGREGREGREGREGSURRSURRSURRSURR
NT
NX
SNNN
NN
N
NN
N
ug/Li:g/Lug/Li.g/Lug/L-g/Lug/Lug/Lug/L^ Recovery% Recovery% Recoveiy% Recovery
. 46
.41
.23
.224.43.43. 1 633
. 33
ug/Lug/Lug / Lug/Lug/Lug/Lug/Lug/Lug/L% Recovery* Recovery* Recovery% Recovery
i: uq/L5 ug/Li ug/Li ug / L
'. : ug / L: : ug/:.= ug / L7 UJ/L5 ug/L
% Recovi* Recovi% RfrCCVI% Reccv(
i'ointe-
B260826-TKTPAr-HI050ET82 6 -TETRACHLCROETHAN8260-'. iy PRSP EHVED
Stored Parameter DescriptionVolatile List 3260Volatile List 8260
Trt rachloro-? thane
32 SO
Page 2
Automated Compliance Systems, Inc
LIS'I1 DEFINITIONS REPORT iprntlist;
0--t 24 , 20:0 12. 37 pm
List Join List type Process
Par a met er ^-epl *
LJ137SO 8270 AL:,Header In format ion
FiieirolDis •', ?. Chloroethyl ; el her'* Chlcrophenol1, i Ulchlorobenzenc1 , 4 - DichlorobenzcrieBenzyl alcohol1 , 2 Dichlorobenzpnr-
2-Methylphenol3 Methylphenolbis (2 - Chloroisopi cpyl ', ether4 -MethylphenolN Nitroso-di-n proaylariir.ellrxnchlcroethanoNit rcbenzene
I sophoronei - Nit rcphenol'2 . 4 -Cirr.ethylpheiH.l
B e n z o i c Acidbis :2 -Chloroethoxy) Mer.har.e2 . 4 Cichloropher.ol
1 ? 4 Tr ichlorchpnzor.rN"4pr." hei 1 ene4 Chloroanil ineHexdchlorobuttidiene
4 - Chloro - 3 -mechylphcnol? MethylnaphthaloneHoxrichlorocyclopf-r.t^clicnc2 , 4 , •• -Tr ichloropnpnol2,4,5 Tr ichlorc.pr.enoL2 Chlcroaaphthalene2 N: troar.il meDimrthylphthal .i:.r-Acenaphthyler.e2 , 6 -Cini'1_rotolv.'rne3 N~, t roam 1 ine"iCenaC'hthene
2 . 4 Cini trophenoi4 NicrophenolDihpr.zof uran2,4 C i::i Crctol ut:::̂DiethylphthalaT.*4 Ch 1 o r opheny 1 :, deny I e *, n e rFluorene4 Mi troani 1 ine-t . 6 -Dinitro-2 irethy* phenolN" Nl trosndiphe:.yl ariir:'1
•1 Broinophenyl - phuriyl^'.herj-ex^cr.lorobenzer.cI 'en tachloropher.nlPhonanthrcneAnthraceneDi N ButylphthalateKluoranthenePvrer.eButylbenzyiphth-^ 1 a:.f1,3' - Di chlorobenz id HIPBenzo ; d) anthrareMeChiyse:ie
Mat-"lasB
1 Par-ntypc
WATER
OVERHEADRFGREGREGREG
REGREG
REGREGR ?.'.',REGREGREGREGREGREGREGREGREGREGREGREGREGHEGREGRF.GREGREGREGREGREG
REG
REGREGREG
REG
REGREGREGREGREG
REGREGREG
REG
REGREGREG
REGREG
REG
REGREGREGRF.GREG
REG
REG
REG
M
V
:juNKKN
KV
S"NN
NNNNNN
NNNN
S
NNNNNN
NN
NN
N1
M
M
M
NN
NNN
M
NNNM
NNN'
MNU
U
N
N
N
v^ey"Jr. 1 1 3
ETC
ua.'L-y.e / L
Ufj/LU--J/L• .q / L
l.q/I.U.I / L
i.g/Lua/I.
ug/Lug/I.uq/Lug/Luq/Lug/I.ug/I,ug/Lug/I,
uq/La-i/l.iio/Lug/L
ug/Lug/Lui/Lug/Lug/Lu g / L
u g / Lu.g/1.uq / L
ug/Lug/Lua/Luq/Luq/L
uq / L
ug/Lug/Luy/L
ug/I.
ug/I.uq/L
>W/L
uq/Luq/Lug/L
uq/Luq/Lug/Luq/L
ug/LUq/L
ug/Lug/Lug/L
ug/Luq/L
MDL
.453.94
.886. 81
875928
.826
.E74
1 -54. 90S.629
1 183891. 93
1. 153921
1.96lr> 841 02'.1 018
. 848
-8C9
: . 49-;. 91
.763826614
949.8684 /567
.998
.9831 .264
. b 0 1
. 9r,4
7.572I . C 0 1. '• •", 2
1 . Q 3 T'
. 591
.929
.992
.736
1 . 564945
. 794
1.01.93
. 775
.84
. 56r)
.69
.81. 794
5 . 056.733
1 . 016
CFlag Expired Chair.
MDL Units REL RDL Units
v DRG-r/IiAJTIOli
3
5
5
5i;
S
55
.̂
=
-rq
-5
b25
3"3
=
3
-J
3
=>
3
3
=
'- '
s
3
•: =q
2r,
25
55r
Sb
2525=55
2555
5
S
5
3
: a5t;
Page 1
" O f1 o Ir\ 0 U U 4 iU
Automated Ccnpliance Systems, Inc.
LIST DEFINITIONS REPORT Iprr.tUs!:1
Oct 24,
L i 31J oin L i 3C typPParameter
bis 12 - Ethylhexy i: pDi ri-uctylphthaldtBenzoIb) f luorant. J.i^:i3enzo;k) f luorant her;Benzo ta)pyreneIndenc [ 1 , 2 , 3 • c^i pyrDibenzc (a , h) An Li :r a-.-Benzo (g , h, i ) Peryl er.2 rluorophenolPhenol ;i$Nitrobenzene- rir>2 -Fluorobipheny12,4,6 Tribromophcr.;p- Terpliunyl -dl4
.v.acn SI pr;;dT SZS-'HCNT1 82701 JRM TEST2 8 2 7 0
Process MatclassReplici Parmtvpe
e REG
REGREGREGSEGREGREr,
RESSURRSURRSURRSURRSURRSURR
inter Stored Parameter
f.
NN
NNNNNN
NK
KN
N
N
c
pkey CFlag Expired ChainUnits MCI. MDL Unti HDL RD^ Ur.-tr,
uq/L 1.322 5ug/L 1 408•ig/L .676 bug/L .9^9uq/L . 74ug/L .9:3 5ug/l, .972 ;ug/L 2 . 21 5% Recovery% Recovery% Recovery% Recovery% Recovery% Recovery
hair. description Lir.kID62b K- I L121B3Sei:u vo la t 11 e Orqar.ics L L B G "2Semi Vola t l". e Co-npou:ids L L 9 b G 3Semivolat i 1 e Cr ' j a r i i c r s Ll.96^3
oU
Automated Compliance Systems, Inc.
LIST DEFINITION'S REPORT (prntlist;
U12748 CN•Cyanide
LiatJoin Li3ttypeParameter" .....
Oct 24, 2000 12:37 pn
Matclasa P'ipy CFlag Expired_~Replid Parmtype M Units RDL RDL Units
WATER INCSG-DILU7ION
Matn S'l prcd Stored Pa r<t rr.c c e r
.0025
DescriptionCYANIDECYANIBECYAK:i>3
CYANIDECYAHIDECYANIDF
L L r ) 5 3 VLI .5582L L C 4 3 2
Metal
Aluminum (6010)Antimony (6020)Arsenic (6020)Barium (6010)Beryllium (6010)Cadmium (6010)Calcium (6010)Chromium (6010)Cobalt (6010)Copper(6010)Iron (6010)Lead (6020)Magnesium (6010)Manganese(6010)Mercury (7470)Nickel (6010)Potassium (6010)Selenium (6020)Silver (6010)Sodium (6010)Thallium (6020)Vanadium (6010)Zinc (6010)
Soil mg/Kg Water mg/LKEMRON'S MDL KEMRON's RL KEMRON's MDL KEMRON's RL
1.5870.010.01
0.0180.0060.0391.9360.14
0.0480.1780.7910.0253.2
0.2540.001963
1.8273.1220.010.2090.4890.0050.2710.491
50.2
0.50.5
0.0250.110
0.250.25
1
2
0.5250.5
0.252
500.2
0.5250.10.5
1
0.0495330.0000160.0000520.0016050.0000350.0001730.0452340.000647
0.00020.0010370.01528
0.0001250.009914
0.0010.000016
0.0010.1299430.0001260.00045
0.0544690.00001
0.0039060.003174
0.10.0010.0010.01
0.00050.0005
0.1
0.0050.0060.0050.02
0.0010.5
0.0030.0002
0.010.5
0.0010.0040.5
0.00020.010.01
Metals LCS criteria 80-120Metals MS/MSD criteria 75-125
RR3001*