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2004 Amines Amines Q 0120 Rapid and Efficient Microwave-Assisted Amination of Electron-Rich Aryl Ha- lides Without a Transition-Metal Catalyst. — The present new direct amination method proceeds without any use of metal catalysts under microwave irradiation. It is applicable to various secondary aliphatic and aromatic amines to afford products in good yield. Additionally, both aryl chloride and aryl iodide [cf. (IV)] can be used for the process. A wide range of functional groups is tolerated. — (SHI, L.; WANG, M.; FAN, C.-A.; ZHANG, F.-M.; TU*, Y.-Q.; Org. Lett. 5 (2003) 19, 3515-3517; State Key Lab. Appl. Org. Chem., Inst. Org. Chem., Lanzhou Univ., Lanzhou 730000, Gansu, Peop. Rep. China; Eng.) — S. Adam 04- 062

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Page 1: Rapid and Efficient Microwave-Assisted Amination of Electron-Rich Aryl Halides Without a Transition-Metal Catalyst

2004 Amines

AminesQ 0120 Rapid and Efficient Microwave-Assisted Amination of Electron-Rich Aryl Ha-

lides Without a Transition-Metal Catalyst. — The present new direct amination method proceeds without any use of metal catalysts under microwave irradiation. It is applicable to various secondary aliphatic and aromatic amines to afford products in good yield. Additionally, both aryl chloride and aryl iodide [cf. (IV)] can be used for the process. A wide range of functional groups is tolerated. — (SHI, L.; WANG, M.; FAN, C.-A.; ZHANG, F.-M.; TU*, Y.-Q.; Org. Lett. 5 (2003) 19, 3515-3517; State Key Lab. Appl. Org. Chem., Inst. Org. Chem., Lanzhou Univ., Lanzhou 730000, Gansu, Peop. Rep. China; Eng.) — S. Adam

04- 062

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