re: west lake stormwater analysis workorder: 18071873semspub.epa.gov/work/07/30367972.pdf ·...

http://www.teklabinc.com/

August 14, 2018

WorkOrder: 18071873West Lake Stormwater AnalysisRE:

Dear Paul V. Rosasco, P.E.:

TEKLAB, INC received 3 samples on 7/31/2018 4:30:00 PM for the analysis presented in the following report.

Samples are analyzed on an as received basis unless otherwise requested and documented. The sample results contained in this report relate only to the requested analytes of interest as directed on the chain of custody. NELAP accredited fields of testing are indicated by the letters NELAP under the Certification column. Unless otherwise documented within this report, Teklab Inc. analyzes samples utilizing the most current methods in compliance with 40CFR. All tests are performed in the Collinsville, IL laboratory unless otherwise noted in the Case Narrative.

All quality control criteria applicable to the test methods employed for this project have been satisfactorily met and are in accordance with NELAP except where noted. The following report shall not be reproduced, except in full, without the written approval of Teklab, Inc.

If you have any questions regarding these tests results, please feel free to call.

Sincerely,

25923 Gateway DriveGolden, CO 80401

(303) 940-3426TEL:FAX:

Paul V. Rosasco, P.E.Engineering Management Support, Inc.

Emily PohlmanProject Manager(618)344-1004 ex [email protected]

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This reporting package includes the following:

Report Contents

Client Project: West Lake Stormwater Analysis

Client: Engineering Management Support, Inc.

Report Date: 14-Aug-18

Work Order: 18071873


Cover Letter 1

Report Contents 2

Definitions 3

Case Narrative 4

Accreditations 5

Laboratory Results 6

Sample Summary 12

Dates Report 13

Quality Control Results 16

Receiving Check List 25

Chain of Custody Appended

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Definitions






Abbr Definition* Analytes on report marked with an asterisk are not NELAP accredited

CCV Continuing calibration verification is a check of a standard to determine the state of calibration of an instrument between recalibration.

CRQL A Client Requested Quantitation Limit is a reporting limit that varies according to customer request. The CRQL may not be less than the MDL.

DF Dilution factor is the dilution performed during analysis only and does not take into account any dilutions made during sample preparation. The reported result is final and includes all dilution factors.

DNI Did not ignite

DUP Laboratory duplicate is a replicate aliquot prepared under the same laboratory conditions and independently analyzed to obtain a measure of precision.

ICV Initial calibration verification is a check of a standard to determine the state of calibration of an instrument before sample analysis is initiated.

IDPH IL Dept. of Public Health

LCS Laboratory control sample is a sample matrix, free from the analytes of interest,spiked with verified known amounts of analytes and analyzed exactly like a sample to establish intra-laboratory or analyst specific precision and bias or to assess the performance of all or a portion of the measurement system.

LCSD Laboratory control sample duplicate is a replicate laboratory control sample that is prepared and analyzed in order to determine the precision of the approved test method. The acceptable recovery range is listed in the QC Package (provided upon request).

MBLK Method blank is a sample of a matrix similar to the batch of associated sample (when available) that is free from the analytes of interest and is processed simultaneously with and under the same conditions as samples through all steps of the analytical procedures, and in which no target analytes or interferences should present at concentrations that impact the analytical results for sample analyses.

MDL "The method detection limit is defined as the minimum measured concentration of a substance that can be reported with 99% confidence that the measured concentration is distinguishable from method blank results."

MS Matrix spike is an aliquot of matrix fortified (spiked) with known quantities of specific analytes that is subjected to the entire analytical procedures in order to determine the effect of the matrix on an approved test method’s recovery system. The acceptable recovery range is listed in the QC Package (provided upon request).

MSD Matrix spike duplicate means a replicate matrix spike that is prepared and analyzed in order to determine the precision of the approved test method. The acceptable recovery range is listed in the QC Package (provided upon request).

MW Molecular weight

ND Not Detected at the Reporting Limit

NELAP NELAP Accredited

PQL Practical quantitation limit means the lowest level that can be reliably achieved within specified limits of precision and accuracy during routine laboratory operation conditions.

RL The reporting limit the lowest level that the data is displayed in the final report. The reporting limit may vary according to customer request or sample dilution. The reporting limit may not be less than the MDL.

RPD Relative percent difference is a calculated difference between two recoveries (ie. MS/MSD). The acceptable recovery limit is listed in the QC Package (provided upon request).

SPK The spike is a known mass of target analyte added to a blank sample or sub-sample; used to determine recovery deficiency or for other quality control purposes.

Surr Surrogates are compounds which are similar to the analytes of interest in chemical composition and behavior in the analytical process, but which are not normally found in environmental samples.

TIC Tentatively identified compound: Analytes tentatively identified in the sample by using a library search. Only results not in the calibration standard will be reported as tentatively identified compounds. Results for tentatively identified compounds that are not present in the calibration standard, but are assigned a specific chemical name based upon the library search, are calculated using total peak areas from reconstructed ion chromatograms and a response factor of one. The nearest Internal Standard is used for the calculation. The results of any TICs must be considered estimated, and are flagged with a "T". If the estimated result is above the calibration range it is flagged "ET"

TNTC Too numerous to count ( > 200 CFU )

Qualifiers# - Unknown hydrocarbon B - Analyte detected in associated Method Blank

C - RL shown is a Client Requested Quantitation Limit E - Value above quantitation range

H - Holding times exceeded I - Associated internal standard was outside method criteria

J - Analyte detected below quantitation limits M - Manual Integration used to determine area response

ND - Not Detected at the Reporting Limit R - RPD outside accepted recovery limits

S - Spike Recovery outside recovery limits T - TIC(Tentatively identified compound)

X - Value exceeds Maximum Contaminant Level

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Case Narrative






Cooler Receipt Temp: 4.82 °C

Per Paul Rosasco, also report results from 18071873-002 as 18071872-001. EEP 7/31/18

Hexavalent and total chromium analysis was performed by ALS Environmental. See attached report for results and QC. Trivalent Chromium was calculated based off of the subcontractor's results. EEP 8/13/18

Locations

___________________________________Collinsville

5445 Horseshoe Lake Road

Collinsville, IL 62234-7425

(618) 344-1004

(618) 344-1005

[email protected]

___________________________________Springfield

3920 Pintail Dr

Springfield, IL 62711-9415

(217) 698-1004

(217) 698-1005

[email protected]

___________________________________Kansas City

8421 Nieman Road

Lenexa, KS 66214

(913) 541-1998

(913) 541-1998

[email protected]

___________________________________Collinsville Air

5445 Horseshoe Lake Road

Collinsville, IL 62234-7425

(618) 344-1004

(618) 344-1005

[email protected]

___________________________________Chicago

1319 Butterfield Rd.

Downers Grove, IL 60515

(630) 324-6855

[email protected]

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Accreditations






NELAPState Cert # Exp Date LabDept

Illinois 100226 1/31/2019 CollinsvilleNELAPIEPA

Kansas E-10374 4/30/2019 CollinsvilleNELAPKDHE

Louisiana 166493 6/30/2019 CollinsvilleNELAPLDEQ

Louisiana 166578 6/30/2019 CollinsvilleNELAPLDEQ

Arkansas 88-0966 3/14/2019 CollinsvilleADEQ

Illinois 17584 5/31/2019 CollinsvilleIDPH

Indiana C-IL-06 1/31/2019 CollinsvilleISDH

Kentucky 98006 12/31/2018 CollinsvilleKDEP

Kentucky 0073 1/31/2019 CollinsvilleUST

Louisiana LA170027 12/31/2018 CollinsvilleLDPH

Missouri 930 1/31/2019 CollinsvilleMDNR

Missouri 00930 5/31/2019 CollinsvilleMDNR

Oklahoma 9978 8/31/2018 CollinsvilleODEQ

Tennessee 04905 1/31/2019 CollinsvilleTDEC

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Laboratory Results






Analyses Result Units Date AnalyzedRL DFCertification Qual

Collection Date: 07/31/2018 13:30

Lab ID: 18071873-001 Client Sample ID: OU1-002

Matrix: WASTE WATER

Batch

EPA 1664AHexane Extractable Material 08/02/2018 10:565 mg/L 1< 5NELAP R250371

EPA 600 375.2 REV 2.0 1993 (TOTAL)Sulfate 08/01/2018 17:05200 mg/L 20322NELAP R250392

STANDARD METHODS 2540 D 1997Total Suspended Solids 08/02/2018 11:356 mg/L 121NELAP R250417

STANDARD METHODS 2540 F 1997Solids, Settleable 08/01/2018 9:240.1 ml/L 1< 0.1NELAP R250379

STANDARD METHODS 4500-CL E (TOTAL) 1997Chloride J 08/03/2018 15:105 mg/L 11NELAP R250525

STANDARD METHODS 4500-NH3 H MODIFIED (TOTAL) 1997Nitrogen, Ammonia (as N) 08/01/2018 17:300.10 mg/L 10.34NELAP R250352

STANDARD METHODS 5210 B 2001Biochemical Oxygen Demand 08/02/2018 12:505 mg/L 1< 5NELAP 144440

STANDARD METHODS 5220 D (TOTAL) 1997Chemical Oxygen Demand J 08/01/2018 12:3150 mg/L 125NELAP R250320

EPA 600 245.1 R3.0 (TOTAL)Mercury 08/01/2018 9:450.00020 mg/L 1< 0.00020NELAP 144360

EPA 600 4.1.4, 200.7R4.4, METALS BY ICP (TOTAL)Aluminum 08/01/2018 13:260.0250 mg/L 10.345NELAP 144375

Barium 08/01/2018 13:260.0025 mg/L 10.0526NELAP 144375

Beryllium 08/01/2018 13:260.0005 mg/L 1< 0.0005NELAP 144375

Cobalt 08/01/2018 13:260.0050 mg/L 1< 0.0050NELAP 144375

Copper J 08/01/2018 13:260.0050 mg/L 10.0019NELAP 144375

Iron 08/01/2018 13:260.0400 mg/L 10.256NELAP 144375

Nickel 08/01/2018 13:260.0050 mg/L 10.0068NELAP 144375

Silver 08/01/2018 13:260.0070 mg/L 1< 0.0070NELAP 144375

Zinc J 08/01/2018 13:260.010 mg/L 10.0087NELAP 144375

EPA 600 4.1.4, 200.8 R5.4, METALS BY ICPMS (TOTAL)Antimony 08/01/2018 17:150.0010 mg/L 5< 0.0010NELAP 144368

Arsenic 08/01/2018 17:150.0010 mg/L 50.0011NELAP 144368

Cadmium 08/01/2018 17:150.0010 mg/L 5< 0.0010NELAP 144368

Lead J 08/01/2018 17:150.0010 mg/L 50.0005NELAP 144368

Selenium 08/01/2018 17:150.0010 mg/L 50.0171NELAP 144368

Thallium 08/01/2018 17:150.0020 mg/L 5< 0.0020NELAP 144368

EPA 600 625.1 (MODIFIED), SEMI-VOLATILE ORGANIC COMPOUNDS BY GC/MSalpha-Terpineol 08/01/2018 16:520.008 mg/L 1ND* 144386

Benzoic acid 08/01/2018 16:520.041 mg/L 1ND* 144386

p-Cresol 08/01/2018 16:520.008 mg/L 1ND* 144386

Phenol 08/01/2018 16:520.004 mg/L 1ND* 144386

Surr: 2,4,6-Tribromophenol 08/01/2018 16:5228.4-122 %REC 159.5* 144386

Surr: 2-Fluorobiphenyl 08/01/2018 16:5236.3-102 %REC 156.4* 144386

Surr: 2-Fluorophenol 08/01/2018 16:5212.3-72.5 %REC 125.1* 144386

Surr: Nitrobenzene-d5 08/01/2018 16:5215-314 %REC 153.2* 144386

Surr: Phenol-d5 08/01/2018 16:528-424 %REC 118.4* 144386

Surr: p-Terphenyl-d14 08/01/2018 16:5210-112 %REC 134.0* 144386

Due to the absence of m,p-Cresol in the sample, p-Cresol is reported as non-detect.

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Laboratory Results









Matrix: WASTE WATER

Batch

EPA 600 624.1 (MODIFIED), VOLATILE ORGANIC COMPOUNDS BY GC/MSBenzene 08/03/2018 16:450.5 µg/L 1ND* 144498

Surr: 1,2-Dichloroethane-d4 08/03/2018 16:4579.6-118 %REC 197.7* 144498

Surr: 4-Bromofluorobenzene 08/03/2018 16:4583.9-115 %REC 1100.1* 144498

Surr: Dibromofluoromethane 08/03/2018 16:4584.9-113 %REC 1100.7* 144498

Surr: Toluene-d8 08/03/2018 16:4586.7-112 %REC 198.9* 144498

SEE ATTACHED FOR SUBCONTRACTING ANALYSISSubcontracted Analysis 08/07/2018 0:000 1See Attached* R250858

Subcontracted Analysis 08/04/2018 0:000 1See Attached* R250858

TRIVALENT CHROMIUMTrivalent Chromium 08/07/2018 0:000.020 mg/L 1< 0.020* R250858

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Laboratory Results









Matrix: WASTE WATER

Batch



STANDARD METHODS 2540 D 1997Total Suspended Solids 08/02/2018 11:3514 mg/L 2.33291NELAP R250417

STANDARD METHODS 2540 F 1997Solids, Settleable 08/01/2018 9:240.1 ml/L 10.1NELAP R250379

STANDARD METHODS 4500-CL E (TOTAL) 1997Chloride 08/03/2018 15:325 mg/L 130NELAP R250525


STANDARD METHODS 5210 B 2001Biochemical Oxygen Demand 08/02/2018 12:555 mg/L 137NELAP 144440

STANDARD METHODS 5220 D (TOTAL) 1997Chemical Oxygen Demand 08/01/2018 12:3250 mg/L 1207NELAP R250320

EPA 600 245.1 R3.0 (TOTAL)Mercury 08/01/2018 9:520.00020 mg/L 10.00230NELAP 144360


Barium 08/01/2018 13:320.0025 mg/L 10.0896NELAP 144375

Beryllium J 08/01/2018 13:320.0005 mg/L 10.0002NELAP 144375

Cobalt J 08/01/2018 13:320.0050 mg/L 10.0027NELAP 144375

Copper 08/01/2018 13:320.0050 mg/L 10.0216NELAP 144375

Iron 08/01/2018 13:320.0400 mg/L 15.26NELAP 144375

Nickel 08/01/2018 13:320.0050 mg/L 10.0124NELAP 144375

Silver 08/01/2018 13:320.0070 mg/L 1< 0.0070NELAP 144375

Zinc 08/01/2018 13:320.0100 mg/L 10.102NELAP 144375

EPA 600 4.1.4, 200.8 R5.4, METALS BY ICPMS (TOTAL)Antimony J 08/01/2018 17:230.0010 mg/L 50.0006NELAP 144368


Cadmium J 08/01/2018 17:230.0010 mg/L 50.0004NELAP 144368

Lead 08/01/2018 17:230.0010 mg/L 50.0139NELAP 144368





p-Cresol 08/01/2018 17:200.010 mg/L 1ND* 144386

Phenol 08/01/2018 17:200.004 mg/L 1ND* 144386





Surr: Phenol-d5 08/01/2018 17:208-424 %REC 124.9* 144386



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Laboratory Results









Matrix: WASTE WATER

Batch









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Laboratory Results









Matrix: WASTE WATER

Batch



STANDARD METHODS 2540 D 1997Total Suspended Solids 08/02/2018 11:356 mg/L 181NELAP R250417

STANDARD METHODS 2540 F 1997Solids, Settleable 08/01/2018 9:240.1 ml/L 1< 0.1NELAP R250379

STANDARD METHODS 4500-CL E (TOTAL) 1997Chloride 08/03/2018 15:3525 mg/L 547NELAP R250525


STANDARD METHODS 5210 B 2001Biochemical Oxygen Demand 08/01/2018 19:255 mg/L 117NELAP 144407

STANDARD METHODS 5220 D (TOTAL) 1997Chemical Oxygen Demand 08/01/2018 12:3250 mg/L 1144NELAP R250320

EPA 600 245.1 R3.0 (TOTAL)Mercury J 08/01/2018 9:540.00020 mg/L 10.00013NELAP 144360


Barium 08/01/2018 11:050.0025 mg/L 10.124NELAP 144375

Beryllium 08/01/2018 11:050.0005 mg/L 1< 0.0005NELAP 144375

Cobalt 08/01/2018 11:050.0050 mg/L 1< 0.0050NELAP 144375

Copper 08/01/2018 11:050.0050 mg/L 10.0362NELAP 144375

Iron 08/01/2018 11:050.0400 mg/L 11.79NELAP 144375

Nickel 08/01/2018 11:050.0050 mg/L 10.0100NELAP 144375

Silver 08/01/2018 11:050.0070 mg/L 1< 0.0070NELAP 144375

Zinc 08/01/2018 11:050.0100 mg/L 10.0884NELAP 144375

EPA 600 4.1.4, 200.8 R5.4, METALS BY ICPMS (TOTAL)Antimony 08/01/2018 17:560.0010 mg/L 50.0018NELAP 144368


Cadmium J 08/01/2018 17:560.0010 mg/L 50.0005NELAP 144368

Lead 08/01/2018 17:560.0010 mg/L 50.0128NELAP 144368





p-Cresol 08/01/2018 17:480.010 mg/L 1ND* 144386

Phenol 08/01/2018 17:480.004 mg/L 1ND* 144386





Surr: Phenol-d5 08/01/2018 17:488-424 %REC 124.5* 144386



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Laboratory Results









Matrix: WASTE WATER

Batch









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Lab Sample ID Client Sample ID Collection DateFractions

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Matrix

Sample Summary






18071873-001 OU1-002 07/31/2018 13:3011Waste Water

18071873-002 OU1-007 07/31/2018 13:5511Waste Water

18071873-003 OU1-001 07/31/2018 14:2011Waste Water

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Analysis Date/TimeTest Name Prep Date/Time

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Sample ID Client Sample ID Collection Date Received Date

Dates Report






18071873-001A OU1-002 07/31/2018 13:30 07/31/2018 16:30

EPA 600 625.1 (Modified), Semi-Volatile Organic Compounds by GC/MS 08/01/2018 16:5208/01/2018 9:49

18071873-001B OU1-002 07/31/2018 13:30 07/31/2018 16:30

Standard Methods 2540 F 1997 08/01/2018 9:24

18071873-001C OU1-002 07/31/2018 13:30 07/31/2018 16:30

EPA 600 375.2 Rev 2.0 1993 (Total) 08/01/2018 17:05

Standard Methods 2540 D 1997 08/02/2018 11:35

Standard Methods 4500-Cl E (Total) 1997 08/03/2018 15:10

Standard Methods 5210 B 2001 08/02/2018 12:5008/02/2018 11:23

18071873-001D OU1-002 07/31/2018 13:30 07/31/2018 16:30

EPA 600 245.1 R3.0 (Total) 08/01/2018 9:4507/31/2018 17:43

EPA 600 4.1.4, 200.7R4.4, Metals by ICP (Total) 08/01/2018 13:2607/31/2018 17:36

EPA 600 4.1.4, 200.8 R5.4, Metals by ICPMS (Total) 08/01/2018 17:1507/31/2018 17:35

18071873-001E OU1-002 07/31/2018 13:30 07/31/2018 16:30

See Attached for Subcontracting Analysis 08/04/2018 0:00

18071873-001F OU1-002 07/31/2018 13:30 07/31/2018 16:30

EPA 1664A 08/02/2018 10:56

18071873-001G OU1-002 07/31/2018 13:30 07/31/2018 16:30

Standard Methods 4500-NH3 H Modified (Total) 1997 08/01/2018 17:30

Standard Methods 5220 D (Total) 1997 08/01/2018 12:31

18071873-001H OU1-002 07/31/2018 13:30 07/31/2018 16:30


Trivalent Chromium 08/07/2018 0:00

18071873-001K OU1-002 07/31/2018 13:30 07/31/2018 16:30

EPA 600 624.1 (Modified), Volatile Organic Compounds by GC/MS 08/03/2018 16:45

18071873-002A OU1-007 07/31/2018 13:55 07/31/2018 16:30


18071873-002B OU1-007 07/31/2018 13:55 07/31/2018 16:30


18071873-002C OU1-007 07/31/2018 13:55 07/31/2018 16:30

EPA 600 375.2 Rev 2.0 1993 (Total) 08/01/2018 17:13




18071873-002D OU1-007 07/31/2018 13:55 07/31/2018 16:30

EPA 600 245.1 R3.0 (Total) 08/01/2018 9:5207/31/2018 17:43

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Dates Report








18071873-002E OU1-007 07/31/2018 13:55 07/31/2018 16:30


18071873-002F OU1-007 07/31/2018 13:55 07/31/2018 16:30

EPA 1664A 08/02/2018 10:57

18071873-002G OU1-007 07/31/2018 13:55 07/31/2018 16:30



18071873-002H OU1-007 07/31/2018 13:55 07/31/2018 16:30



18071873-002K OU1-007 07/31/2018 13:55 07/31/2018 16:30


18071873-003A OU1-001 07/31/2018 14:20 07/31/2018 16:30


18071873-003B OU1-001 07/31/2018 14:20 07/31/2018 16:30


18071873-003C OU1-001 07/31/2018 14:20 07/31/2018 16:30

EPA 600 375.2 Rev 2.0 1993 (Total) 08/06/2018 12:54




18071873-003D OU1-001 07/31/2018 14:20 07/31/2018 16:30

EPA 600 245.1 R3.0 (Total) 08/01/2018 9:5407/31/2018 17:43



18071873-003E OU1-001 07/31/2018 14:20 07/31/2018 16:30


18071873-003F OU1-001 07/31/2018 14:20 07/31/2018 16:30

EPA 1664A 08/02/2018 10:57

18071873-003G OU1-001 07/31/2018 14:20 07/31/2018 16:30



18071873-003H OU1-001 07/31/2018 14:20 07/31/2018 16:30


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Dates Report







18071873-003K OU1-001 07/31/2018 14:20 07/31/2018 16:30


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Quality Control Results






EPA 1664A

SampID: MBLK

SampType: MBLK mg/LUnitsR250371Batch

Analyses ResultDate

AnalyzedRL SpikeQual SPK Ref Val %REC Low Limit High Limit

Hexane Extractable Material 08/01/20185 3.500< 5 00 -100 100

SampID: LCS

SampType: LCS mg/LUnitsR250371Batch

Analyses ResultDate


Hexane Extractable Material 08/01/20185 40.0036 90.00 78 114

SampID: LCSD

SampType: LCSD mg/LUnitsR250371Batch RPD Limit 18

Analyses ResultDate

AnalyzedRL SpikeQual SPK Ref Val %REC RPD Ref Val %RPD

Hexane Extractable Material 08/01/20185 40.0034 85.2 5.420 36.00

EPA 600 375.2 REV 2.0 1993 (TOTAL)

SampID: ICB/MBLK


Analyses ResultDate


Sulfate 08/01/201810 5.000< 10 00 -100 100

SampID: ICV/LCS


Analyses ResultDate


Sulfate 08/01/201810 20.0019 94.30 90 110

SampID: ICB/MBLK


Analyses ResultDate


Sulfate 08/03/201810 5.000< 10 00 -100 100

SampID: ICV/LCS


Analyses ResultDate


Sulfate 08/03/201810 20.0020 97.80 90 110

SampID: ICB/MBLK


Analyses ResultDate


Sulfate 08/06/201810 5.000< 10 00 -100 100

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EPA 600 375.2 REV 2.0 1993 (TOTAL)

SampID: ICV/LCS


Analyses ResultDate


Sulfate 08/06/201810 20.0019 93.70 90 110

SampID: 18071873-003CMS

SampType: MS mg/LUnitsR250554Batch

Analyses ResultDate


Sulfate 08/06/2018100 100.0275 90.0185.1 90 110

SampID: 18071873-003CMSD

SampType: MSD mg/LUnitsR250554Batch RPD Limit 10

Analyses ResultDate


Sulfate 08/06/2018100 100.0275 90.1 0.03185.1 275.1

STANDARD METHODS 2540 D 1997

SampID: MBLK


Analyses ResultDate


Total Suspended Solids 08/02/20186 4.000< 6 00 -100 100



Total Suspended Solids 08/02/20180.5 < 0.5

SampID: LCS


Analyses ResultDate


Total Suspended Solids 08/02/20186 100.089 89.00 85 115

SampID: LCSQC

SampType: LCSQC mg/LUnitsR250417Batch

Analyses ResultDate





SampID: 18071873-001CDUP

SampType: DUP mg/LUnitsR250417Batch RPD Limit 5

Analyses ResultDate


Total Suspended Solids 08/02/20186 20 4.8821.00

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STANDARD METHODS 4500-CL E (TOTAL) 1997

SampID: ICB/MBLK


Analyses ResultDate


Chloride 08/01/20185 0.5000< 5 00 -100 100

SampID: ICV/LCS


Analyses ResultDate


Chloride 08/01/20185 20.0020 100.10 90 110

SampID: ICB/MBLK


Analyses ResultDate


Chloride 08/03/20185 0.5000< 5 00 -100 100

SampID: ICV/LCS


Analyses ResultDate


Chloride 08/03/20185 20.0020 102.20 90 110

SampID: 18071873-003CMS


Analyses ResultDate


Chloride 08/03/201825 100.0140 93.646.62 85 115

SampID: 18071873-003CMSD


Analyses ResultDate


Chloride 08/03/201825 100.0141 94.3 0.4746.62 140.2

SampID: ICB/MBLK


Analyses ResultDate


Chloride 08/06/20185 0.5000< 5 00 -100 100

SampID: ICV/LCS


Analyses ResultDate


Chloride 08/06/20185 20.0021 103.40 90 110

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STANDARD METHODS 4500-NH3 H MODIFIED (TOTAL) 1997

SampID: ICB/MBLK


Analyses ResultDate


Nitrogen, Ammonia (as N) 08/01/20180.10 0.04600< 0.10 00 -100 100

SampID: ICV/LCS


Analyses ResultDate


Nitrogen, Ammonia (as N) 08/01/20180.10 1.0001.04 103.90 90 110

SampID: 18071873-001GMS


Analyses ResultDate


Nitrogen, Ammonia (as N) 08/01/20180.10 2.0002.24 94.90.3420 85 115

SampID: 18071873-001GMSD


Analyses ResultDate


Nitrogen, Ammonia (as N) 08/01/20180.10 2.0002.23 94.4 0.490.3420 2.240

SampID: ICB/MBLK


Analyses ResultDate



SampID: ICV/LCS


Analyses ResultDate



SampID: CCB/MBLK


Analyses ResultDate



SampID: CCV/LCS


Analyses ResultDate



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STANDARD METHODS 5210 B 2001

SampID: LCS-BOD-2-080118

SampType: LCS mg/LUnits144407Batch

Analyses ResultDate


Biochemical Oxygen Demand 08/01/20185 198.0221 111.60 84.6 115.4

SampID: LCS-BOD-1-080218


Analyses ResultDate


Biochemical Oxygen Demand 08/02/20185 198.0220 111.10 84.6 115.4

SampID: 18071873-001CDUP

SampType: DUP mg/LUnits144440Batch RPD Limit 40

Analyses ResultDate


Biochemical Oxygen Demand 08/02/20185 < 5 0.000

STANDARD METHODS 5220 D (TOTAL) 1997

SampID: MBLK


Analyses ResultDate


Chemical Oxygen Demand 08/01/201850 13.00< 50 00 -100 100

SampID: LCS


Analyses ResultDate


Chemical Oxygen Demand 08/01/201850 200.0209 104.70 90 110

SampID: 18071873-001GMS


Analyses ResultDate


Chemical Oxygen Demand 08/01/2018100 10001090 106.925.01 85 115

SampID: 18071873-001GMSD


Analyses ResultDate


Chemical Oxygen Demand 08/01/2018100 10001060 104.0 2.7025.01 1094

EPA 600 245.1 R3.0 (TOTAL)

SampID: MBLK-144360

SampType: MBLK mg/LUnits144360Batch

Analyses ResultDate


Mercury 08/01/20180.00020 0.00005500< 0.00020 00 -100 100

of 25







EPA 600 245.1 R3.0 (TOTAL)

SampID: LCS-144360


Analyses ResultDate


Mercury 08/01/20180.00020 0.0050000.00513 102.60 85 115

SampID: 18071873-001DMS

SampType: MS mg/LUnits144360Batch

Analyses ResultDate


Mercury 08/01/20180.00020 0.0050000.00503 100.60 75 125

SampID: 18071873-001DMSD

SampType: MSD mg/LUnits144360Batch RPD Limit 15

Analyses ResultDate


Mercury 08/01/20180.00020 0.0050000.00498 99.6 0.960 0.005028

EPA 600 4.1.4, 200.7R4.4, METALS BY ICP (TOTAL)

SampID: MBLK-144375


Analyses ResultDate


Aluminum 08/01/20180.0250 0.009100< 0.0250 00 -100 100

Barium 08/01/20180.0025 0.0007000< 0.0025 00 -100 100

Beryllium 08/01/20180.0005 0.0002000< 0.0005 00 -100 100

Cobalt 08/01/20180.0050 0.002000< 0.0050 00 -100 100

Copper 08/01/20180.0050 0.001300< 0.0050 00 -100 100

Iron 08/01/20180.0400 0.02000< 0.0400 00 -100 100

Nickel 08/01/20180.0050 0.001600< 0.0050 00 -100 100

Silver 08/01/20180.0070 0.002700< 0.0070 00 -100 100

Zinc 08/01/20180.0100 0.005000< 0.0100 00 -100 100

SampID: LCS-144375


Analyses ResultDate


Aluminum 08/01/20180.0250 2.0001.95 97.50 85 115

Barium 08/01/20180.0025 2.0001.92 96.00 85 115

Beryllium 08/01/20180.0005 0.050000.0493 98.60 85 115

Cobalt 08/01/20180.0050 0.50000.473 94.50 85 115

Copper 08/01/20180.0050 0.25000.240 96.00 85 115

Iron 08/01/20180.0400 2.0001.94 97.20 85 115

Nickel 08/01/20180.0050 0.50000.493 98.60 85 115

Silver 08/01/20180.0070 0.050000.0484 96.80 85 115

Zinc 08/01/20180.0100 0.50000.493 98.50 85 115

of 25







EPA 600 4.1.4, 200.7R4.4, METALS BY ICP (TOTAL)

SampID: 18071873-003DMS


Analyses ResultDate


Aluminum 08/01/20180.0250 2.0003.08 105.80.9681 75 125

Barium 08/01/20180.0025 2.0002.07 97.30.1243 75 125

Beryllium 08/01/20180.0005 0.050000.0500 100.00 75 125

Cobalt 08/01/20180.0050 0.50000.473 94.70 75 125

Copper 08/01/20180.0050 0.25000.281 98.00.03620 75 125

Iron 08/01/20180.0400 2.0004.01 110.91.791 75 125

Nickel 08/01/20180.0050 0.50000.503 98.60.01000 75 125

Silver 08/01/20180.0070 0.050000.0490 98.00 75 125

Zinc 08/01/20180.0100 0.50000.581 98.40.08840 75 125



Analyses ResultDate


Aluminum 08/01/20180.0250 2.0003.10 106.4 0.390.9681 3.085

Barium 08/01/20180.0025 2.0002.06 97.0 0.290.1243 2.070

Beryllium 08/01/20180.0005 0.050000.0501 100.2 0.200 0.05000

Cobalt 08/01/20180.0050 0.50000.475 95.0 0.360 0.4734

Copper 08/01/20180.0050 0.25000.282 98.5 0.500.03620 0.2811

Iron 08/01/20180.0400 2.0004.04 112.7 0.871.791 4.009

Nickel 08/01/20180.0050 0.50000.505 99.0 0.400.01000 0.5029

Silver 08/01/20180.0070 0.050000.0484 96.8 1.230 0.04900

Zinc 08/01/20180.0100 0.50000.584 99.2 0.650.08840 0.5806

EPA 600 4.1.4, 200.8 R5.4, METALS BY ICPMS (TOTAL)

SampID: MBLK-144368


Analyses ResultDate


Antimony 08/01/20180.0010 0.0004500< 0.0010 00 -100 100

Arsenic 08/01/20180.0010 0.0003800< 0.0010 00 -100 100

Cadmium 08/01/20180.0010 0.0001300< 0.0010 00 -100 100

Lead 08/01/20180.0010 0.0001800< 0.0010 00 -100 100

Selenium 08/01/20180.0010 0.0002800< 0.0010 00 -100 100

Thallium 08/01/20180.0020 0.0008500< 0.0020 00 -100 100

SampID: LCS-144368


Analyses ResultDate


Antimony 08/01/20180.0010 0.50000.500 99.90 85 115

Arsenic 08/01/20180.0010 0.50000.533 106.70 85 115

Cadmium 08/01/20180.0010 0.050000.0486 97.10 85 115

Lead 08/01/20180.0010 0.50000.515 103.10 85 115

Selenium 08/01/20180.0010 0.50000.527 105.40 85 115

Thallium 08/01/20180.0020 0.25000.236 94.30 85 115

of 25







EPA 600 4.1.4, 200.8 R5.4, METALS BY ICPMS (TOTAL)

SampID: 18071873-003DMS


Analyses ResultDate


Antimony 08/01/20180.0010 0.50000.517 103.00.001798 70 130

Arsenic 08/01/20180.0010 0.50000.537 106.80.003146 70 130

Cadmium 08/01/20180.0010 0.050000.0506 100.20.0004620 70 130

Lead 08/01/20180.0010 0.50000.547 106.80.01276 70 130

Selenium 08/01/20180.0010 0.50000.535 106.30.003881 70 130

Thallium 08/01/20180.0020 0.25000.248 99.10 70 130



Analyses ResultDate


Antimony 08/01/20180.0010 0.50000.504 100.5 2.520.001798 0.5170

Arsenic 08/01/20180.0010 0.50000.544 108.1 1.170.003146 0.5374

Cadmium 08/01/20180.0010 0.050000.0493 97.7 2.530.0004620 0.05058

Lead 08/01/20180.0010 0.50000.535 104.3 2.260.01276 0.5467

Selenium 08/01/20180.0010 0.50000.526 104.3 1.860.003881 0.5354

Thallium 08/01/20180.0020 0.25000.244 97.5 1.690 0.2479

EPA 600 625.1 (MODIFIED), SEMI-VOLATILE ORGANIC COMPOUNDS BY GC/MS

SampID: MBLK-144386


Analyses ResultDate


alpha-Terpineol 08/01/20180.010 ND

Benzoic acid 08/01/20180.050 ND

p-Cresol 08/01/20180.010 ND

Phenol 08/01/20180.004 ND

Surr: 2,4,6-Tribromophenol 08/01/20180.050000.047 93.7 57.3 139

Surr: 2-Fluorobiphenyl 08/01/20180.025000.017 69.3 53.9 116

Surr: 2-Fluorophenol 08/01/20180.050000.023 45.8 35 85.5

Surr: Nitrobenzene-d5 08/01/20180.025000.015 61.0 15 314

Surr: Phenol-d5 08/01/20180.050000.015 31.0 8 424

Surr: p-Terphenyl-d14 08/01/20180.025000.019 76.9 56.5 127

SampID: LCS-144386


Analyses ResultDate


Phenol 08/01/20180.004 0.050000.016 32.80 17 120

Surr: 2,4,6-Tribromophenol 08/01/20180.050000.047 93.9 60 140

Surr: 2-Fluorobiphenyl 08/01/20180.025000.017 68.1 60 140

Surr: 2-Fluorophenol 08/01/20180.050000.023 46.5 35 85.5

Surr: Nitrobenzene-d5 08/01/20180.025000.018 73.8 15 314

Surr: Phenol-d5 08/01/20180.050000.016 31.6 8 424

Surr: p-Terphenyl-d14 08/01/20180.025000.018 72.3 60 140

of 25







EPA 600 625.1 (MODIFIED), SEMI-VOLATILE ORGANIC COMPOUNDS BY GC/MS

SampID: LCSD-144386

SampType: LCSD mg/LUnits144386Batch RPD Limit 40

Analyses ResultDate


Phenol 08/01/20180.004 0.050000.014 28.5 14.040 0.01639

Surr: 2,4,6-Tribromophenol 08/01/20180.050000.047 93.3

Surr: 2-Fluorobiphenyl 08/01/20180.025000.016 65.6

Surr: 2-Fluorophenol 08/01/20180.050000.021 42.1

Surr: Nitrobenzene-d5 08/01/20180.025000.017 69.2

Surr: Phenol-d5 08/01/20180.050000.015 29.3

Surr: p-Terphenyl-d14 08/01/20180.025000.018 73.8

EPA 600 624.1 (MODIFIED), VOLATILE ORGANIC COMPOUNDS BY GC/MS

SampID: MBLK-T180803A-1

SampType: MBLK µg/LUnits144498Batch

Analyses ResultDate


Benzene 08/03/20180.5 ND

Surr: 1,2-Dichloroethane-d4 08/03/201850.0048.4 96.7 79.6 118

Surr: 4-Bromofluorobenzene 08/03/201850.0049.8 99.6 83.9 115

Surr: Dibromofluoromethane 08/03/201850.0049.8 99.7 84.9 113

Surr: Toluene-d8 08/03/201850.0048.2 96.4 86.7 112

SampID: LCSD-T180803A-1

SampType: LCSD µg/LUnits144498Batch RPD Limit 40

Analyses ResultDate


Benzene 08/03/20180.5 50.0044.9 89.8 2.990 46.24

Surr: 1,2-Dichloroethane-d4 08/03/201850.0046.1 92.2

Surr: 4-Bromofluorobenzene 08/03/201850.0048.4 96.8

Surr: Dibromofluoromethane 08/03/201850.0050.4 100.8

Surr: Toluene-d8 08/03/201850.0048.9 97.8

SampID: LCS-T180803A-1

SampType: LCS µg/LUnits144498Batch

Analyses ResultDate


Benzene 08/03/20180.5 50.0046.2 92.50 77.8 120

Surr: 1,2-Dichloroethane-d4 08/03/201850.0047.6 95.2 79.6 118

Surr: 4-Bromofluorobenzene 08/03/201850.0048.3 96.7 83.9 115

Surr: Dibromofluoromethane 08/03/201850.0051.4 102.9 84.9 113

Surr: Toluene-d8 08/03/201850.0049.1 98.2 86.7 112

of 25

Receiving Check List






Received By: AMDCarrier: Nick Reed

Completed by: Reviewed by:

On:

31-Jul-18

On:

31-Jul-18

Shipping container/cooler in good condition? Yes No Not Present

Chain of custody present? Yes No

Chain of custody signed when relinquished and received? Yes No

Chain of custody agrees with sample labels? Yes No

Samples in proper container/bottle? Yes No

Sample containers intact? Yes No

Sufficient sample volume for indicated test? Yes No

All samples received within holding time? Yes No

Container/Temp Blank temperature in compliance? Yes No

Temp °C

When thermal preservation is required, samples are compliant with a temperature between 0.1°C - 6.0°C, or when samples are received on ice the same day as collected.

The sample was checked for chlorine upon arrival at the laboratory. Chlorine was not present; analysis will be performed from the Hydrochloric Acid-preserved vials. - bvetter/nharer - 7/31/2018 5:19:15 PM

Water – at least one vial per sample has zero headspace? Yes No No VOA vials

Water - pH acceptable upon receipt? Yes No NA

Type of thermal preservation? None Ice Blue Ice Dry Ice

Chain of custody 1 Extra pages included 10

Reported field parameters measured: Field Lab NA

Water - TOX containers have zero headspace? No TOX containersYes No

NPDES/CWA TCN interferences checked/treated in the field? Yes No NA

Amber M. Dilallo Marvin L. Darling

of 25

13-Aug-2018

Teklab, Inc.Emily Pohlman

Dear Emily,

Re: 18071873 Work Order: 1808135

Fax:Tel: (618) 344-1004

5445 Horseshoe Lake RoadCollinsville, IL 62234

ALS Environmental received 3 samples on 03-Aug-2018 10:20 AM for the analyses presented in the following report.

Project ManagerShawn Smythe

Shawn SmytheElectronically approved by: Shawn Smythe

The analytical data provided relates directly to the samples received by ALS Environmental and for only the analyses requested.

QC sample results for this data met laboratory specifications. Any exceptions are noted in the Case Narrative, or noted with qualifiers in the report or QC batch information. Should this laboratory report need to be reproduced, it should be reproduced in full unless written approval has been obtained from ALS Laboratory Group. Samples will be disposed in 30 days unless storage arrangements are made.

The total number of pages in this report is 10.

If you have any questions regarding this report, please feel free to contact me.

Sincerely,

ADDRESS 4388 Glendale Milford Rd Cincinnati, OH 45242- | PHONE (513) 733-5336 | FAX (513) 733-5347ALS GROUP USA, CORP. Part of the ALS Group An ALS Limited Company

Date: 13-Aug-18ALS Environmental

Project: 18071873Client: Teklab, Inc.

Work Order: 1808135Work Order Sample Summary

Lab Samp ID Client Sample ID Collection DateTag Number Date ReceivedMatrix Hold1808135-01 18071873-001 Water 7/31/2018 13:30 8/3/2018 10:201808135-02 18071873-002 Water 7/31/2018 13:55 8/3/2018 10:201808135-03 18071873-003 Water 7/31/2018 14:20 8/3/2018 10:20

SS Page 1 of 1



Work Order: 1808135Case Narrative

The analytical data provided relates directly to the samples received by ALS Environmental and for only the analyses requested.

Results relate only to the items tested and are not blank corrected unless indicated.

QC sample results for this data met laboratory specifications. Any exceptions are noted in the Case Narrative, or noted with qualifiers in the report or QC batch information. Should this laboratory report need to be reproduced, it should be reproduced in full unless written approval has been obtained from ALS Environmental. Samples will be disposed in 30 days unless storage arrangements are made.

ALS is an EPA recognized NLLAP laboratory for lead paint, soil, and dust wipe analyses under its AIHA-LAP accreditation.

Hexavalent Chromium samples were buffered and field filtered before lab receipt.

CN Page 1 of 1

Project: 18071873Sample ID: 18071873-001Collection Date: 7/31/2018 01:30 PM Matrix: WATER

Analyses Result Qual Units Date AnalyzedReport Limit

Client: Teklab, Inc.Work Order: 1808135

Dilution Factor

Lab ID: 1808135-01

ALS Environmental Date: 13-Aug-18

DISSOLVED HEXACHROM IN WATER BY EPA 218.6 E218.6 Analyst: MHWChromium, Hexavalent 8/4/2018 10:40 PM0.0020 mg/L 1ND

METALS BY ICP SW6010B Analyst: SRLPrep Date: 8/7/2018Chromium 8/7/2018 04:22 PM0.020 mg/L 1ND

AR Page 1 of 3

Note:




Dilution Factor

Lab ID: 1808135-02




AR Page 2 of 3

Note:




Dilution Factor

Lab ID: 1808135-03




AR Page 3 of 3

Note:


Project: 18071873


QC BATCH REPORT

Batch ID: R154951 Instrument ID HPLC3 Method: E218.6

QualRPD Limit

Analysis Date: 8/4/2018 10:05 PMPrep Date:

Analyte Result %REC %RPD

Units: mg/L

PQL

Client ID: SeqNo: 1802625

MBLK

Run ID: HPLC3_180804B

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID MBLK-R154951

Chromium, Hexavalent 0.0020ND

QualRPD Limit



Units: mg/L

PQL


LCS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID LCS-R154951

001Chromium, Hexavalent 98.8 88.6-1150.00200.9881

QualRPD Limit



Units: mg/L

PQL

Client ID: 18071873-001 SeqNo: 1802631

MS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID 1808135-01A

00.0019031Chromium, Hexavalent 96.3 70-1300.0020 H0.9645

QualRPD Limit



Units: mg/L

PQL

Client ID: 18071873-001 SeqNo: 1802632

MSD


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID 1808135-01A

0.96450.0019031Chromium, Hexavalent 95.8 70-130 200.0020 0.484 H0.9598

The following samples were analyzed in this batch: 1808135-01A 1808135-02A 1808135-03A

QC Page: 1 of 2Note: See Qualifiers Page for a list of Qualifiers and their explanation.

Project: 18071873


QC BATCH REPORT

Batch ID: 52454 Instrument ID ICP1 Method: SW6010B

QualRPD Limit

Analysis Date: 8/7/2018 04:00 PMPrep Date: 8/7/2018


Units: mg/L

PQL


MBLK

Run ID: ICP1_180807C

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID mblk-52454-52454

Chromium 0.020ND

QualRPD Limit



Units: mg/L

PQL


LCS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID lcs-52454-52454

001.1Chromium 96.6 80-1200.0201.063

QualRPD Limit



Units: mg/L

PQL


LCSD


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID lcsd-52454-52454

1.06301.1Chromium 96.3 80-120 200.020 0.3321.059

QualRPD Limit



Units: mg/L

PQL


MS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID 1808148-15e ms

00.0049021.1Chromium 91.2 75-1250.0201.008

QualRPD Limit



Units: mg/L

PQL


MSD


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID 1808148-15e msd

1.0080.0049021.1Chromium 91.4 75-125 200.020 0.1961.01

The following samples were analyzed in this batch: 1808135-01B 1808135-02B 1808135-03B

QC Page: 2 of 2Note: See Qualifiers Page for a list of Qualifiers and their explanation.


QUALIFIERS, ACRONYMS, UNITS


WorkOrder: 1808135

Units Reported Description

Qualifier Description

Acronym Description

mg/L

Value exceeds Regulatory Limit*Not accreditedaAnalyte detected in the associated Method Blank above the Reporting LimitBValue above quantitation rangeEAnalyzed outside of Holding TimeHAnalyte detected below quantitation limitJNot offered for accreditationnNot Detected at the Reporting LimitNDSample amount is > 4 times amount spikedODual Column results percent difference > 40%PRPD above laboratory control limitRSpike Recovery outside laboratory control limitsSAnalyzed but not detected above the MDLU

Method DuplicateDUPEPA MethodELaboratory Control SampleLCSLaboratory Control Sample DuplicateLCSDMethod BlankMBLKMethod Detection LimitMDLMethod Quantitation LimitMQLMatrix SpikeMSMatrix Spike DuplicateMSDPost Digestion SpikePDSPractical Quantitaion LimitPQLSample Detection LimitSDLSW-846 MethodSW

QF Page 1 of 1

ALS Environmental

Sample Receipt Checklist

Client Name: TEKLAB-COLLINSVILLE

Work Order: 1808135

Date/Time Received: 03-Aug-18 10:20

Received by: SNH

Checklist completed byeSignature Date

Reviewed by:DateeSignature

Matrices:Carrier name: FedEx

Shipping container/cooler in good condition? Yes No Not Present

Custody seals intact on shipping container/cooler? Yes No Not Present

Custody seals intact on sample bottles? Yes No Not Present

Chain of custody present? Yes No

Chain of custody signed when relinquished and received? Yes No

Chain of custody agrees with sample labels? Yes No

Samples in proper container/bottle? Yes No

Sample containers intact? Yes No

Sufficient sample volume for indicated test? Yes No

All samples received within holding time? Yes No

Container/Temp Blank temperature in compliance? Yes No

Yes No No VOA vials submittedWater - VOA vials have zero headspace?

Water - pH acceptable upon receipt? Yes No N/A

Temperature(s)/Thermometer(s): 3.2

Login Notes:

Cooler(s)/Kit(s):

03-Aug-18 08-Aug-18 Jan Wilcox Shawn Smythe

pH adjusted? Yes No N/ApH adjusted by:

CorrectiveAction:

Comments:

Client Contacted: Date Contacted: Person Contacted:

Contacted By: Regarding:

SRC Page 1 of 1

re: west lake stormwater analysis workorder: 18071873semspub.epa.gov/work/07/30367972.pdf ·...

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