regiochemical control of the catalytic asymmetric hydroboration of 1,2-diarylalkenes

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2006 Enantioselective syntheses O 0031 Regiochemical Control of the Catalytic Asymmetric Hydroboration of 1,2-Diarylalkenes. — The regio- and stereochemical control of hydroboration of stilbenes (I) and related disubstituted alkenes (V) is achieved using Rh-QUINAP com- plexes. — (BLACK, A.; BROWN*, J. M.; PICHON, C.; Chem. Commun. (Cambridge) 2005, 42, 5284-5286; Chem. Res. Lab., Dep. Chem., Univ. Oxford, Oxford OX1 3TA, UK; Eng.) — M. Paetzel 11- 032

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Page 1: Regiochemical Control of the Catalytic Asymmetric Hydroboration of 1,2-Diarylalkenes

2006

Enantioselective synthesesO 0031 Regiochemical Control of the Catalytic Asymmetric Hydroboration of

1,2-Diarylalkenes. — The regio- and stereochemical control of hydroboration of stilbenes (I) and related disubstituted alkenes (V) is achieved using Rh-QUINAP com-plexes. — (BLACK, A.; BROWN*, J. M.; PICHON, C.; Chem. Commun. (Cambridge) 2005, 42, 5284-5286; Chem. Res. Lab., Dep. Chem., Univ. Oxford, Oxford OX1 3TA, UK; Eng.) — M. Paetzel

11- 032